#------------------------------------------------------------------------------
#$Date: 2019-10-22 03:55:44 +0300 (Tue, 22 Oct 2019) $
#$Revision: 219446 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/13/7701396.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7701396
loop_
_publ_author_name
'Anker, Mathew David'
'Altaf, Yasir'
'Lein, Matthias'
'Coles, Martyn P.'
_publ_section_title
;
 Reactions of In--Zn Bonds with Organic Azides: Products that Result from
 Hetero- and Homo-bimetallic Behaviour
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/C9DT03990B
_journal_year                    2019
_chemical_formula_moiety         'C56 H92 In2 N4 O2 Si4'
_chemical_formula_sum            'C56 H92 In2 N4 O2 Si4'
_chemical_formula_weight         1195.33
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4.3
_audit_creation_date             2019-10-17T15:11:24-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_update_record
;
2019-10-17 deposited with the CCDC.    2019-10-21 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 103.6751(14)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.6869(2)
_cell_length_b                   12.03733(15)
_cell_length_c                   16.2305(2)
_cell_measurement_reflns_used    14310
_cell_measurement_temperature    120.01(10)
_cell_measurement_theta_max      73.549
_cell_measurement_theta_min      4.621
_cell_measurement_wavelength     1.54184
_cell_volume                     2977.90(7)
_computing_cell_refinement       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_molecular_graphics    'Ortep for Windows (Farrugia, 2012)'
_computing_publication_material  'WinGX publication routines (Farrugia, 2012)'
_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2014)'
_diffrn_ambient_temperature      120.01(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 8.0856
_diffrn_measured_fraction_theta_full 0.9997
_diffrn_measured_fraction_theta_max 0.9997
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, EosS2'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.036741
_diffrn_orient_matrix_UB_12      -0.0345803
_diffrn_orient_matrix_UB_13      0.0762605
_diffrn_orient_matrix_UB_21      -0.0894528
_diffrn_orient_matrix_UB_22      0.0509998
_diffrn_orient_matrix_UB_23      -0.0431864
_diffrn_orient_matrix_UB_31      -0.0292721
_diffrn_orient_matrix_UB_32      -0.1121774
_diffrn_orient_matrix_UB_33      -0.0431717
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0289
_diffrn_reflns_av_unetI/netI     0.0397
_diffrn_reflns_Laue_measured_fraction_full 1
_diffrn_reflns_Laue_measured_fraction_max 1
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            19907
_diffrn_reflns_point_group_measured_fraction_full 1
_diffrn_reflns_point_group_measured_fraction_max 1
_diffrn_reflns_theta_full        68.1328
_diffrn_reflns_theta_max         68.248
_diffrn_reflns_theta_min         3.5243
_diffrn_source                   'micro-focus sealed X-ray tube'
_exptl_absorpt_coefficient_mu    7.264
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.291
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
        CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Numerical absorption correction based on gaussian integration over
                        a multifaceted crystal model
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.333
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1252.0
_exptl_crystal_size_max          0.347
_exptl_crystal_size_mid          0.198
_exptl_crystal_size_min          0.079
_refine_diff_density_max         0.321
_refine_diff_density_min         -0.876
_refine_diff_density_rms         0.071
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.075
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     340
_refine_ls_number_reflns         5458
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.075
_refine_ls_R_factor_all          0.0229
_refine_ls_R_factor_gt           0.0223
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0268P)²+1.5527P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0558
_refine_ls_wR_factor_ref         0.0562
_reflns_number_gt                5300
_reflns_number_total             5458
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9dt03990b2.cif
_cod_data_source_block           Compound-A'
_cod_original_cell_volume        2977.89(7)
_cod_database_code               7701396
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_disorder_assembly
_atom_site_disorder_group
In In 1.08360(2) 0.50912(2) -0.01231(2) 0.01076(5) Uani 1 d . .
Si1 Si 1.10073(3) 0.26302(4) -0.08320(4) 0.02040(12) Uani 1 d . .
Si2 Si 0.92106(3) 0.22897(4) -0.03226(3) 0.01124(10) Uani 1 d . .
O O 1.01233(8) 0.27933(11) -0.04913(9) 0.0196(3) Uani 1 d . .
N1 N 1.14988(9) 0.39198(12) -0.06782(10) 0.0141(3) Uani 1 d . .
N2 N 0.85316(9) 0.33999(12) -0.02970(9) 0.0114(3) Uani 1 d . .
C1 C 1.21543(11) 0.41741(15) -0.11357(12) 0.0145(3) Uani 1 d . .
C2 C 1.19165(12) 0.47087(16) -0.19331(12) 0.0170(4) Uani 1 d . .
C3 C 1.25532(15) 0.48958(16) -0.23847(14) 0.0225(4) Uani 1 d . .
H3 H 1.2394 0.526 -0.2918 0.027 Uiso 1 calc . .
C4 C 1.34169(13) 0.45619(18) -0.20736(14) 0.0248(4) Uani 1 d . .
H4 H 1.3842 0.4685 -0.2395 0.03 Uiso 1 calc . .
C5 C 1.36499(12) 0.40508(17) -0.12951(14) 0.0234(4) Uani 1 d . .
H5 H 1.4242 0.3828 -0.1081 0.028 Uiso 1 calc . .
C6 C 1.30389(12) 0.38495(15) -0.08103(12) 0.0172(4) Uani 1 d . .
C7 C 1.09893(14) 0.51424(17) -0.22972(13) 0.0206(4) Uani 1 d . .
H7 H 1.0589 0.4758 -0.1993 0.025 Uiso 1 calc . .
C8 C 1.09475(16) 0.63828(19) -0.21242(15) 0.0337(5) Uani 1 d . .
H8A H 1.1151 0.652 -0.1514 0.051 Uiso 1 calc . .
H8B H 1.0341 0.6642 -0.232 0.051 Uiso 1 calc . .
H8C H 1.1324 0.6784 -0.2427 0.051 Uiso 1 calc . .
C9 C 1.06458(16) 0.49165(19) -0.32485(14) 0.0286(5) Uani 1 d . .
H9A H 1.0984 0.5355 -0.3569 0.043 Uiso 1 calc . .
H9B H 1.0025 0.5126 -0.3423 0.043 Uiso 1 calc . .
H9C H 1.0709 0.4125 -0.3361 0.043 Uiso 1 calc . .
C10 C 1.33586(12) 0.33106(16) 0.00565(12) 0.0202(4) Uani 1 d . .
H10 H 1.2833 0.3132 0.028 0.024 Uiso 1 calc . .
C11 C 1.39320(15) 0.4120(2) 0.06748(15) 0.0333(5) Uani 1 d . .
H11A H 1.4448 0.432 0.0464 0.05 Uiso 1 calc . .
H11B H 1.4122 0.3768 0.1232 0.05 Uiso 1 calc . .
H11C H 1.3594 0.4792 0.0724 0.05 Uiso 1 calc . .
C12 C 1.38570(13) 0.22240(17) 0.00129(15) 0.0275(5) Uani 1 d . .
H12A H 1.3502 0.1737 -0.0418 0.041 Uiso 1 calc . .
H12B H 1.3974 0.1853 0.0566 0.041 Uiso 1 calc . .
H12C H 1.4414 0.2388 -0.0136 0.041 Uiso 1 calc . .
C15 C 0.87194(13) 0.13182(17) -0.11877(14) 0.0261(4) Uani 1 d . .
H15A H 0.8606 0.1711 -0.1732 0.039 Uiso 1 calc . .
H15B H 0.8167 0.1027 -0.1094 0.039 Uiso 1 calc . .
H15C H 0.9126 0.0702 -0.1196 0.039 Uiso 1 calc . .
C16 C 0.95502(14) 0.15308(18) 0.07013(13) 0.0272(5) Uani 1 d . .
H16A H 0.9923 0.09 0.0634 0.041 Uiso 1 calc . .
H16B H 0.9028 0.1259 0.0871 0.041 Uiso 1 calc . .
H16C H 0.9878 0.2033 0.1138 0.041 Uiso 1 calc . .
C17 C 0.76705(11) 0.34105(14) -0.08472(11) 0.0120(3) Uani 1 d . .
C18 C 0.75249(11) 0.39145(15) -0.16565(11) 0.0152(4) Uani 1 d . .
C19 C 0.66785(12) 0.39146(16) -0.21808(12) 0.0196(4) Uani 1 d . .
H19 H 0.6576 0.4266 -0.2719 0.024 Uiso 1 calc . .
C20 C 0.59878(12) 0.34138(16) -0.19313(12) 0.0201(4) Uani 1 d . .
H20 H 0.5414 0.3433 -0.2291 0.024 Uiso 1 calc . .
C21 C 0.61385(12) 0.28843(16) -0.11541(12) 0.0184(4) Uani 1 d . .
H21 H 0.5666 0.2521 -0.0992 0.022 Uiso 1 calc . .
C22 C 0.69699(11) 0.28718(15) -0.06030(11) 0.0143(3) Uani 1 d . .
C23 C 0.82684(13) 0.44556(18) -0.19658(12) 0.0214(4) Uani 1 d . .
H23 H 0.8833 0.4186 -0.1594 0.026 Uiso 1 calc . .
C24 C 0.82495(15) 0.57227(19) -0.18769(15) 0.0309(5) Uani 1 d . .
H24A H 0.7715 0.6017 -0.2254 0.046 Uiso 1 calc . .
H24B H 0.8764 0.6044 -0.2031 0.046 Uiso 1 calc . .
H24C H 0.8257 0.5917 -0.1289 0.046 Uiso 1 calc . .
C25 C 0.82658(15) 0.4130(2) -0.28790(14) 0.0325(5) Uani 1 d . .
H25A H 0.8281 0.3319 -0.2925 0.049 Uiso 1 calc . .
H25B H 0.8782 0.4448 -0.3033 0.049 Uiso 1 calc . .
H25C H 0.7732 0.4415 -0.3264 0.049 Uiso 1 calc . .
C26 C 0.71004(12) 0.22730(16) 0.02382(12) 0.0188(4) Uani 1 d . .
H26 H 0.7743 0.2283 0.0511 0.023 Uiso 1 calc . .
C27 C 0.68162(17) 0.10570(17) 0.01217(14) 0.0327(5) Uani 1 d . .
H27A H 0.6181 0.1018 -0.011 0.049 Uiso 1 calc . .
H27B H 0.6968 0.0677 0.0671 0.049 Uiso 1 calc . .
H27C H 0.7118 0.0696 -0.027 0.049 Uiso 1 calc . .
C28 C 0.66293(14) 0.28664(18) 0.08372(13) 0.0262(4) Uani 1 d . .
H28A H 0.6822 0.3643 0.0904 0.039 Uiso 1 calc . .
H28B H 0.677 0.2498 0.1391 0.039 Uiso 1 calc . .
H28C H 0.5994 0.2839 0.06 0.039 Uiso 1 calc . .
C13 C 1.0904(17) 0.2071(16) -0.1834(16) 0.047(4) Uani 0.41(3) d A 1
H13A H 1.0623 0.134 -0.1861 0.071 Uiso 0.41(3) calc A 1
H13B H 1.1487 0.199 -0.1949 0.071 Uiso 0.41(3) calc A 1
H13C H 1.0545 0.2564 -0.2257 0.071 Uiso 0.41(3) calc A 1
C14 C 1.1624(9) 0.1553(13) 0.0011(17) 0.040(4) Uani 0.41(3) d A 1
H14A H 1.1695 0.1864 0.0582 0.06 Uiso 0.41(3) calc A 1
H14B H 1.2203 0.1394 -0.0092 0.06 Uiso 0.41(3) calc A 1
H14C H 1.1283 0.0865 -0.0035 0.06 Uiso 0.41(3) calc A 1
C13A C 1.0611(9) 0.2295(10) -0.2035(6) 0.0331(19) Uani 0.59(3) d A 2
H13D H 1.0367 0.1542 -0.2106 0.05 Uiso 0.59(3) calc A 2
H13E H 1.1107 0.2345 -0.2303 0.05 Uiso 0.59(3) calc A 2
H13F H 1.0157 0.2829 -0.2301 0.05 Uiso 0.59(3) calc A 2
C14A C 1.1618(7) 0.1442(9) -0.0351(11) 0.040(2) Uani 0.59(3) d A 2
H14D H 1.1847 0.158 0.0257 0.06 Uiso 0.59(3) calc A 2
H14E H 1.2107 0.1306 -0.0617 0.06 Uiso 0.59(3) calc A 2
H14F H 1.1233 0.079 -0.0428 0.06 Uiso 0.59(3) calc A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In 0.0822 5.0449 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
4 0 -10 0.119
-10 1 2 0.0704
10 -2 -1 0.0798
10 0 1 0.0385
8 4 -4 0.0743
8 1 -8 0.0855
3 6 -6 0.0802
-3 -6 -5 0.1636
-6 3 -6 0.063
6 -3 6 0.0825
-8 -2 -3 0.0864
0 6 -7 0.0791
-9 0 -1 0.0337
-2 7 4 0.1677
3 -7 -3 0.1888
-6 0 -7 0.0774
-5 -7 4 0.0968
-4 -1 10 0.1347
-1 4 9 0.1452
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 In N2 118.68(6) . 3_765
N1 In In 126.85(4) . 3_765
N2 In In 114.46(4) 3_765 3_765
O Si1 N1 103.34(7) . .
O Si1 C13 118.0(8) . .
N1 Si1 C13 115.2(6) . .
O Si1 C14A 111.1(5) . .
N1 Si1 C14A 118.7(4) . .
O Si1 C13A 105.7(4) . .
N1 Si1 C13A 111.0(3) . .
C14A Si1 C13A 106.4(4) . .
O Si1 C14 99.4(6) . .
N1 Si1 C14 111.3(6) . .
C13 Si1 C14 108.6(6) . .
O Si2 N2 106.76(7) . .
O Si2 C15 109.34(9) . .
N2 Si2 C15 111.18(8) . .
O Si2 C16 104.73(9) . .
N2 Si2 C16 114.16(8) . .
C15 Si2 C16 110.33(10) . .
Si1 O Si2 149.86(9) . .
C1 N1 Si1 117.84(12) . .
C1 N1 In 124.87(11) . .
Si1 N1 In 114.89(7) . .
C17 N2 Si2 119.42(11) . .
C17 N2 In 119.81(11) . 3_765
Si2 N2 In 115.62(7) . 3_765
C2 C1 C6 119.31(16) . .
C2 C1 N1 120.26(16) . .
C6 C1 N1 120.38(17) . .
C3 C2 C1 119.30(18) . .
C3 C2 C7 118.56(18) . .
C1 C2 C7 122.07(17) . .
C4 C3 C2 121.5(2) . .
C4 C3 H3 119.3 . .
C2 C3 H3 119.3 . .
C5 C4 C3 119.22(18) . .
C5 C4 H4 120.4 . .
C3 C4 H4 120.4 . .
C4 C5 C6 121.76(18) . .
C4 C5 H5 119.1 . .
C6 C5 H5 119.1 . .
C5 C6 C1 118.91(18) . .
C5 C6 C10 118.31(17) . .
C1 C6 C10 122.77(16) . .
C8 C7 C2 110.02(17) . .
C8 C7 C9 109.81(18) . .
C2 C7 C9 113.87(17) . .
C8 C7 H7 107.6 . .
C2 C7 H7 107.6 . .
C9 C7 H7 107.6 . .
C7 C8 H8A 109.5 . .
C7 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C7 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C7 C9 H9A 109.5 . .
C7 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C7 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C6 C10 C11 110.41(17) . .
C6 C10 C12 112.39(17) . .
C11 C10 C12 110.28(17) . .
C6 C10 H10 107.9 . .
C11 C10 H10 107.9 . .
C12 C10 H10 107.9 . .
C10 C11 H11A 109.5 . .
C10 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C10 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C10 C12 H12A 109.5 . .
C10 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C10 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
Si2 C15 H15A 109.5 . .
Si2 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
Si2 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
Si2 C16 H16A 109.5 . .
Si2 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
Si2 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C22 C17 C18 119.47(15) . .
C22 C17 N2 120.21(15) . .
C18 C17 N2 120.25(15) . .
C19 C18 C17 119.13(16) . .
C19 C18 C23 119.42(16) . .
C17 C18 C23 121.45(16) . .
C20 C19 C18 121.30(17) . .
C20 C19 H19 119.3 . .
C18 C19 H19 119.3 . .
C19 C20 C21 119.44(17) . .
C19 C20 H20 120.3 . .
C21 C20 H20 120.3 . .
C20 C21 C22 121.45(17) . .
C20 C21 H21 119.3 . .
C22 C21 H21 119.3 . .
C21 C22 C17 119.12(17) . .
C21 C22 C26 119.30(16) . .
C17 C22 C26 121.57(15) . .
C18 C23 C25 112.51(17) . .
C18 C23 C24 111.20(16) . .
C25 C23 C24 110.48(17) . .
C18 C23 H23 107.5 . .
C25 C23 H23 107.5 . .
C24 C23 H23 107.5 . .
C23 C24 H24A 109.5 . .
C23 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C23 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C23 C25 H25A 109.5 . .
C23 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
C23 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
C22 C26 C27 111.77(16) . .
C22 C26 C28 111.59(16) . .
C27 C26 C28 110.79(16) . .
C22 C26 H26 107.5 . .
C27 C26 H26 107.5 . .
C28 C26 H26 107.5 . .
C26 C27 H27A 109.5 . .
C26 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C26 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
C26 C28 H28A 109.5 . .
C26 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C26 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
Si1 C13 H13A 109.5 . .
Si1 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
Si1 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
Si1 C14 H14A 109.5 . .
Si1 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
Si1 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
Si1 C13A H13D 109.5 . .
Si1 C13A H13E 109.5 . .
H13D C13A H13E 109.5 . .
Si1 C13A H13F 109.5 . .
H13D C13A H13F 109.5 . .
H13E C13A H13F 109.5 . .
Si1 C14A H14D 109.5 . .
Si1 C14A H14E 109.5 . .
H14D C14A H14E 109.5 . .
Si1 C14A H14F 109.5 . .
H14D C14A H14F 109.5 . .
H14E C14A H14F 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
In N1 2.0794(14) .
In N2 2.1043(14) 3_765
In In 2.7537(2) 3_765
Si1 O 1.6217(13) .
Si1 N1 1.7250(15) .
Si1 C13 1.731(19) .
Si1 C14A 1.795(11) .
Si1 C13A 1.946(10) .
Si1 C14 1.966(17) .
Si2 O 1.6364(13) .
Si2 N2 1.7156(15) .
Si2 C15 1.850(2) .
Si2 C16 1.860(2) .
N1 C1 1.437(2) .
N2 C17 1.432(2) .
N2 In 2.1043(14) 3_765
C1 C2 1.414(3) .
C1 C6 1.418(2) .
C2 C3 1.390(3) .
C2 C7 1.527(3) .
C3 C4 1.389(3) .
C3 H3 0.95 .
C4 C5 1.375(3) .
C4 H4 0.95 .
C5 C6 1.398(3) .
C5 H5 0.95 .
C6 C10 1.522(3) .
C7 C8 1.524(3) .
C7 C9 1.535(3) .
C7 H7 1 .
C8 H8A 0.98 .
C8 H8B 0.98 .
C8 H8C 0.98 .
C9 H9A 0.98 .
C9 H9B 0.98 .
C9 H9C 0.98 .
C10 C11 1.530(3) .
C10 C12 1.534(3) .
C10 H10 1 .
C11 H11A 0.98 .
C11 H11B 0.98 .
C11 H11C 0.98 .
C12 H12A 0.98 .
C12 H12B 0.98 .
C12 H12C 0.98 .
C15 H15A 0.98 .
C15 H15B 0.98 .
C15 H15C 0.98 .
C16 H16A 0.98 .
C16 H16B 0.98 .
C16 H16C 0.98 .
C17 C22 1.411(2) .
C17 C18 1.416(2) .
C18 C19 1.397(2) .
C18 C23 1.521(2) .
C19 C20 1.382(3) .
C19 H19 0.95 .
C20 C21 1.383(3) .
C20 H20 0.95 .
C21 C22 1.396(2) .
C21 H21 0.95 .
C22 C26 1.514(2) .
C23 C25 1.532(3) .
C23 C24 1.533(3) .
C23 H23 1 .
C24 H24A 0.98 .
C24 H24B 0.98 .
C24 H24C 0.98 .
C25 H25A 0.98 .
C25 H25B 0.98 .
C25 H25C 0.98 .
C26 C27 1.529(3) .
C26 C28 1.530(3) .
C26 H26 1 .
C27 H27A 0.98 .
C27 H27B 0.98 .
C27 H27C 0.98 .
C28 H28A 0.98 .
C28 H28B 0.98 .
C28 H28C 0.98 .
C13 H13A 0.98 .
C13 H13B 0.98 .
C13 H13C 0.98 .
C14 H14A 0.98 .
C14 H14B 0.98 .
C14 H14C 0.98 .
C13A H13D 0.98 .
C13A H13E 0.98 .
C13A H13F 0.98 .
C14A H14D 0.98 .
C14A H14E 0.98 .
C14A H14F 0.98 .
