#------------------------------------------------------------------------------
#$Date: 2019-11-05 19:41:40 +0200 (Tue, 05 Nov 2019) $
#$Revision: 223351 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/17/7701753.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7701753
loop_
_publ_author_name
'Zhao, Na'
'Li, Yu'
'Gu, Jin-Zhong'
'Kirillova, Marina V.'
'Kirillov, Alexander M.'
_publ_section_title
;
 Hydrothermal generation, structural versatility and properties of
 metal(ii)-organic architectures driven by a pyridine-tricarboxylic acid.
;
_journal_issue                   23
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8361
_journal_page_last               8374
_journal_paper_doi               10.1039/c9dt01253b
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C26 H17 Cd N3 O7'
_chemical_formula_weight         595.83
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-10-30 deposited with the CCDC.	2019-05-13 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 91.444(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.2808(3)
_cell_length_b                   12.9097(3)
_cell_length_c                   17.7636(4)
_cell_measurement_reflns_used    7668
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.046
_cell_measurement_theta_min      3.356
_cell_volume                     2356.87(10)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APE-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0324
_diffrn_reflns_av_unetI/netI     0.0545
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       5
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            7668
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.046
_diffrn_reflns_theta_max         25.046
_diffrn_reflns_theta_min         3.358
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    0.980
_exptl_absorpt_correction_T_max  0.806
_exptl_absorpt_correction_T_min  0.785
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.679
_exptl_crystal_description       block
_exptl_crystal_F_000             1192
_exptl_crystal_size_max          0.260
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.230
_exptl_transmission_factor_max   0.798
_exptl_transmission_factor_min   0.775
_refine_diff_density_max         0.387
_refine_diff_density_min         -0.399
_refine_diff_density_rms         0.078
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     335
_refine_ls_number_reflns         4159
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0468
_refine_ls_R_factor_gt           0.0330
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0289P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0684
_refine_ls_wR_factor_ref         0.0780
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3342
_reflns_number_total             4159
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9dt01253b2.cif
_cod_data_source_block           370-10Cd
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7701753
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.785
_shelx_estimated_absorpt_t_max   0.806
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Cd1 Cd 0.33155(2) 0.64840(2) 0.01392(2) 0.02630(10) Uani 1 1 d . .
N1 N -0.3158(3) 0.2502(2) 0.37505(15) 0.0280(7) Uani 1 1 d . .
N2 N 0.1226(3) 0.7138(2) -0.02223(15) 0.0306(7) Uani 1 1 d . .
N3 N 0.3582(3) 0.7902(2) -0.06699(16) 0.0329(7) Uani 1 1 d . .
O1 O 0.2433(3) 0.51699(19) 0.07282(15) 0.0446(7) Uani 1 1 d . .
O2 O 0.3671(3) 0.4004(2) 0.13229(15) 0.0510(8) Uani 1 1 d . .
O3 O -0.1707(2) 0.60767(19) 0.15279(14) 0.0363(6) Uani 1 1 d . .
H3 H -0.2237 0.6544 0.1583 0.055 Uiso 1 1 calc R U
O4 O -0.2350(3) 0.56015(19) 0.26693(15) 0.0450(7) Uani 1 1 d . .
O5 O -0.6573(2) 0.25049(19) 0.34499(15) 0.0400(7) Uani 1 1 d . .
O6 O -0.5381(2) 0.17083(18) 0.43448(14) 0.0344(6) Uani 1 1 d . .
O7 O 0.4099(2) 0.54259(17) -0.07431(12) 0.0309(6) Uani 1 1 d . .
H1W H 0.4847 0.5559 -0.0907 0.037 Uiso 1 1 d R U
H2W H 0.4093 0.4787 -0.0699 0.037 Uiso 1 1 d R U
C1 C 0.2638(4) 0.4470(3) 0.12111(19) 0.0295(8) Uani 1 1 d . .
C2 C 0.1464(3) 0.4177(3) 0.16554(19) 0.0261(8) Uani 1 1 d . .
C3 C 0.0443(3) 0.4867(2) 0.16937(18) 0.0273(8) Uani 1 1 d . .
H3A H 0.0519 0.5512 0.1467 0.033 Uiso 1 1 calc R U
C4 C -0.0693(3) 0.4625(2) 0.20614(18) 0.0244(8) Uani 1 1 d . .
C5 C -0.1693(3) 0.5474(3) 0.2124(2) 0.0298(8) Uani 1 1 d . .
C6 C -0.0830(3) 0.3647(3) 0.23923(18) 0.0259(8) Uani 1 1 d . .
C7 C 0.0208(3) 0.2960(3) 0.23570(19) 0.0296(8) Uani 1 1 d . .
H7 H 0.0131 0.2308 0.2573 0.035 Uiso 1 1 calc R U
C8 C 0.1356(3) 0.3220(3) 0.20082(19) 0.0296(8) Uani 1 1 d . .
H8 H 0.2049 0.2756 0.2010 0.036 Uiso 1 1 calc R U
C9 C -0.2067(3) 0.3317(2) 0.27314(19) 0.0251(8) Uani 1 1 d . .
C10 C -0.2073(3) 0.2827(3) 0.34272(19) 0.0296(8) Uani 1 1 d . .
H10 H -0.1281 0.2720 0.3681 0.035 Uiso 1 1 calc R U
C11 C -0.4302(3) 0.2647(2) 0.33876(19) 0.0254(8) Uani 1 1 d . .
C12 C -0.5516(3) 0.2262(3) 0.3760(2) 0.0287(8) Uani 1 1 d . .
C13 C -0.4382(3) 0.3115(3) 0.2687(2) 0.0306(8) Uani 1 1 d . .
H13 H -0.5183 0.3208 0.2442 0.037 Uiso 1 1 calc R U
C14 C -0.3251(3) 0.3442(2) 0.2360(2) 0.0303(8) Uani 1 1 d . .
H14 H -0.3287 0.3748 0.1886 0.036 Uiso 1 1 calc R U
C15 C 0.0086(4) 0.6788(3) -0.0002(2) 0.0393(10) Uani 1 1 d . .
H15 H 0.0055 0.6131 0.0212 0.047 Uiso 1 1 calc R U
C16 C -0.1063(4) 0.7344(3) -0.0072(2) 0.0453(11) Uani 1 1 d . .
H16 H -0.1837 0.7072 0.0103 0.054 Uiso 1 1 calc R U
C17 C -0.1040(4) 0.8285(3) -0.0398(2) 0.0474(11) Uani 1 1 d . .
H17 H -0.1804 0.8667 -0.0450 0.057 Uiso 1 1 calc R U
C18 C 0.0134(4) 0.8694(3) -0.0661(2) 0.0384(10) Uani 1 1 d . .
C19 C 0.1257(4) 0.8087(3) -0.05518(19) 0.0298(9) Uani 1 1 d . .
C20 C 0.0226(5) 0.9670(3) -0.1029(2) 0.0517(12) Uani 1 1 d . .
H20 H -0.0517 1.0075 -0.1093 0.062 Uiso 1 1 calc R U
C21 C 0.1362(5) 1.0018(3) -0.1288(2) 0.0556(13) Uani 1 1 d . .
H21 H 0.1391 1.0654 -0.1533 0.067 Uiso 1 1 calc R U
C22 C 0.2531(4) 0.9422(3) -0.1191(2) 0.0430(10) Uani 1 1 d . .
C23 C 0.2489(4) 0.8471(3) -0.08066(19) 0.0324(9) Uani 1 1 d . .
C24 C 0.3732(5) 0.9743(3) -0.1461(3) 0.0623(14) Uani 1 1 d . .
H24 H 0.3792 1.0367 -0.1719 0.075 Uiso 1 1 calc R U
C25 C 0.4801(5) 0.9156(3) -0.1350(3) 0.0625(13) Uani 1 1 d . .
H25 H 0.5595 0.9358 -0.1542 0.075 Uiso 1 1 calc R U
C26 C 0.4693(4) 0.8234(3) -0.0939(2) 0.0468(11) Uani 1 1 d . .
H26 H 0.5438 0.7839 -0.0852 0.056 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Cd1 O7 91.28(9) . .
O1 Cd1 O6 107.10(9) . 2
O7 Cd1 O6 90.62(8) . 2
O1 Cd1 N3 161.41(10) . .
O7 Cd1 N3 89.86(9) . .
O6 Cd1 N3 91.43(10) 2 .
O1 Cd1 N1 89.67(10) . 2
O7 Cd1 N1 161.55(9) . 2
O6 Cd1 N1 71.52(9) 2 2
N3 Cd1 N1 95.07(10) . 2
O1 Cd1 N2 91.22(10) . .
O7 Cd1 N2 111.39(9) . .
O6 Cd1 N2 151.25(9) 2 .
N3 Cd1 N2 71.14(10) . .
N1 Cd1 N2 87.01(9) 2 .
C10 N1 C11 118.8(3) . .
C10 N1 Cd1 127.3(2) . 2_545
C11 N1 Cd1 113.5(2) . 2_545
C15 N2 C19 117.7(3) . .
C15 N2 Cd1 126.8(2) . .
C19 N2 Cd1 113.9(2) . .
C26 N3 C23 118.5(3) . .
C26 N3 Cd1 126.2(3) . .
C23 N3 Cd1 115.0(2) . .
C1 O1 Cd1 144.3(3) . .
C5 O3 H3 109.5 . .
C12 O6 Cd1 118.5(2) . 2_545
Cd1 O7 H1W 117.5 . .
Cd1 O7 H2W 122.4 . .
H1W O7 H2W 104.1 . .
O2 C1 O1 126.1(3) . .
O2 C1 C2 119.4(3) . .
O1 C1 C2 114.5(3) . .
C3 C2 C8 118.8(3) . .
C3 C2 C1 119.0(3) . .
C8 C2 C1 122.2(3) . .
C2 C3 C4 121.9(3) . .
C2 C3 H3A 119.0 . .
C4 C3 H3A 119.0 . .
C3 C4 C6 119.6(3) . .
C3 C4 C5 117.1(3) . .
C6 C4 C5 123.2(3) . .
O4 C5 O3 124.8(3) . .
O4 C5 C4 123.7(3) . .
O3 C5 C4 111.3(3) . .
C7 C6 C4 118.0(3) . .
C7 C6 C9 120.1(3) . .
C4 C6 C9 121.7(3) . .
C8 C7 C6 121.9(3) . .
C8 C7 H7 119.0 . .
C6 C7 H7 119.0 . .
C7 C8 C2 119.6(3) . .
C7 C8 H8 120.2 . .
C2 C8 H8 120.2 . .
C14 C9 C10 117.1(3) . .
C14 C9 C6 121.9(3) . .
C10 C9 C6 121.0(3) . .
N1 C10 C9 123.3(3) . .
N1 C10 H10 118.4 . .
C9 C10 H10 118.4 . .
N1 C11 C13 121.7(3) . .
N1 C11 C12 117.9(3) . .
C13 C11 C12 120.4(3) . .
O5 C12 O6 125.6(3) . .
O5 C12 C11 116.4(3) . .
O6 C12 C11 118.1(3) . .
C11 C13 C14 118.7(3) . .
C11 C13 H13 120.6 . .
C14 C13 H13 120.6 . .
C9 C14 C13 120.4(3) . .
C9 C14 H14 119.8 . .
C13 C14 H14 119.8 . .
N2 C15 C16 123.8(4) . .
N2 C15 H15 118.1 . .
C16 C15 H15 118.1 . .
C17 C16 C15 118.8(4) . .
C17 C16 H16 120.6 . .
C15 C16 H16 120.6 . .
C16 C17 C18 120.4(4) . .
C16 C17 H17 119.8 . .
C18 C17 H17 119.8 . .
C17 C18 C19 116.9(3) . .
C17 C18 C20 123.5(4) . .
C19 C18 C20 119.5(4) . .
N2 C19 C18 122.3(4) . .
N2 C19 C23 118.3(3) . .
C18 C19 C23 119.3(3) . .
C21 C20 C18 121.5(4) . .
C21 C20 H20 119.3 . .
C18 C20 H20 119.3 . .
C20 C21 C22 120.9(4) . .
C20 C21 H21 119.6 . .
C22 C21 H21 119.6 . .
C24 C22 C23 117.6(4) . .
C24 C22 C21 123.0(4) . .
C23 C22 C21 119.4(4) . .
N3 C23 C22 121.6(4) . .
N3 C23 C19 119.1(3) . .
C22 C23 C19 119.4(3) . .
C25 C24 C22 120.5(4) . .
C25 C24 H24 119.7 . .
C22 C24 H24 119.7 . .
C24 C25 C26 118.6(4) . .
C24 C25 H25 120.7 . .
C26 C25 H25 120.7 . .
N3 C26 C25 123.0(4) . .
N3 C26 H26 118.5 . .
C25 C26 H26 118.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cd1 O1 2.201(2) .
Cd1 O7 2.244(2) .
Cd1 O6 2.310(2) 2
Cd1 N3 2.347(3) .
Cd1 N1 2.379(3) 2
Cd1 N2 2.381(3) .
N1 C10 1.335(4) .
N1 C11 1.340(4) .
N1 Cd1 2.379(3) 2_545
N2 C15 1.324(5) .
N2 C19 1.359(4) .
N3 C26 1.321(5) .
N3 C23 1.359(4) .
O1 C1 1.260(4) .
O2 C1 1.233(4) .
O3 C5 1.314(4) .
O3 H3 0.8200 .
O4 C5 1.206(4) .
O5 C12 1.246(4) .
O6 C12 1.265(4) .
O6 Cd1 2.310(2) 2_545
O7 H1W 0.8471 .
O7 H2W 0.8285 .
C1 C2 1.506(5) .
C2 C3 1.379(4) .
C2 C8 1.391(5) .
C3 C4 1.388(4) .
C3 H3A 0.9300 .
C4 C6 1.401(4) .
C4 C5 1.508(5) .
C6 C7 1.390(5) .
C6 C9 1.483(4) .
C7 C8 1.388(5) .
C7 H7 0.9300 .
C8 H8 0.9300 .
C9 C14 1.380(5) .
C9 C10 1.389(5) .
C10 H10 0.9300 .
C11 C13 1.384(5) .
C11 C12 1.512(5) .
C13 C14 1.379(5) .
C13 H13 0.9300 .
C14 H14 0.9300 .
C15 C16 1.385(5) .
C15 H15 0.9300 .
C16 C17 1.347(5) .
C16 H16 0.9300 .
C17 C18 1.408(6) .
C17 H17 0.9300 .
C18 C19 1.405(5) .
C18 C20 1.423(5) .
C19 C23 1.444(5) .
C20 C21 1.343(6) .
C20 H20 0.9300 .
C21 C22 1.434(6) .
C21 H21 0.9300 .
C22 C24 1.398(6) .
C22 C23 1.406(5) .
C24 C25 1.345(6) .
C24 H24 0.9300 .
C25 C26 1.402(5) .
C25 H25 0.9300 .
C26 H26 0.9300 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C25 H25 O4 0.93 2.56 3.459(5) 161.6 4_675
C13 H13 O2 0.93 2.51 3.309(4) 144.9 1_455
O7 H2W O6 0.83 2.01 2.810(3) 163.6 4_665
O7 H1W O2 0.85 1.80 2.642(3) 171.8 3_665
O3 H3 O5 0.82 1.74 2.556(3) 171.0 2_455
O3 H3 O5 0.82 1.74 2.556(3) 171.0 2_455
O7 H1W O2 0.85 1.80 2.642(3) 171.8 3_665
O7 H2W O6 0.83 2.01 2.810(3) 163.6 4_665
C13 H13 O2 0.93 2.51 3.309(4) 144.9 1_455
C25 H25 O4 0.93 2.56 3.459(5) 161.6 4_675
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
Cd1 O1 C1 O2 -34.4(7) .
Cd1 O1 C1 C2 148.3(3) .
O2 C1 C2 C3 161.6(3) .
O1 C1 C2 C3 -20.8(5) .
O2 C1 C2 C8 -20.6(5) .
O1 C1 C2 C8 157.0(3) .
C8 C2 C3 C4 -1.2(5) .
C1 C2 C3 C4 176.7(3) .
C2 C3 C4 C6 -1.4(5) .
C2 C3 C4 C5 174.8(3) .
C3 C4 C5 O4 -142.8(4) .
C6 C4 C5 O4 33.3(5) .
C3 C4 C5 O3 34.2(4) .
C6 C4 C5 O3 -149.7(3) .
C3 C4 C6 C7 1.9(5) .
C5 C4 C6 C7 -174.1(3) .
C3 C4 C6 C9 -174.4(3) .
C5 C4 C6 C9 9.6(5) .
C4 C6 C7 C8 0.1(5) .
C9 C6 C7 C8 176.5(3) .
C6 C7 C8 C2 -2.6(5) .
C3 C2 C8 C7 3.1(5) .
C1 C2 C8 C7 -174.7(3) .
C7 C6 C9 C14 -128.5(4) .
C4 C6 C9 C14 47.7(5) .
C7 C6 C9 C10 48.7(5) .
C4 C6 C9 C10 -135.0(3) .
C11 N1 C10 C9 0.4(5) .
Cd1 N1 C10 C9 172.3(2) 2_545
C14 C9 C10 N1 -1.6(5) .
C6 C9 C10 N1 -179.0(3) .
C10 N1 C11 C13 0.5(5) .
Cd1 N1 C11 C13 -172.4(3) 2_545
C10 N1 C11 C12 179.3(3) .
Cd1 N1 C11 C12 6.4(4) 2_545
Cd1 O6 C12 O5 -175.1(3) 2_545
Cd1 O6 C12 C11 6.5(4) 2_545
N1 C11 C12 O5 172.5(3) .
C13 C11 C12 O5 -8.6(5) .
N1 C11 C12 O6 -8.9(5) .
C13 C11 C12 O6 170.0(3) .
N1 C11 C13 C14 -0.2(5) .
C12 C11 C13 C14 -179.0(3) .
C10 C9 C14 C13 1.9(5) .
C6 C9 C14 C13 179.2(3) .
C11 C13 C14 C9 -1.0(5) .
C19 N2 C15 C16 -1.6(5) .
Cd1 N2 C15 C16 163.0(3) .
N2 C15 C16 C17 1.6(6) .
C15 C16 C17 C18 -0.1(6) .
C16 C17 C18 C19 -1.2(6) .
C16 C17 C18 C20 178.2(4) .
C15 N2 C19 C18 0.1(5) .
Cd1 N2 C19 C18 -166.4(3) .
C15 N2 C19 C23 -179.0(3) .
Cd1 N2 C19 C23 14.5(4) .
C17 C18 C19 N2 1.2(5) .
C20 C18 C19 N2 -178.2(3) .
C17 C18 C19 C23 -179.7(3) .
C20 C18 C19 C23 0.9(5) .
C17 C18 C20 C21 -178.3(4) .
C19 C18 C20 C21 1.1(6) .
C18 C20 C21 C22 -0.9(7) .
C20 C21 C22 C24 178.9(4) .
C20 C21 C22 C23 -1.4(6) .
C26 N3 C23 C22 -3.2(5) .
Cd1 N3 C23 C22 170.9(3) .
C26 N3 C23 C19 176.6(3) .
Cd1 N3 C23 C19 -9.3(4) .
C24 C22 C23 N3 2.9(6) .
C21 C22 C23 N3 -176.9(4) .
C24 C22 C23 C19 -177.0(4) .
C21 C22 C23 C19 3.3(6) .
N2 C19 C23 N3 -3.8(5) .
C18 C19 C23 N3 177.1(3) .
N2 C19 C23 C22 176.0(3) .
C18 C19 C23 C22 -3.1(5) .
C23 C22 C24 C25 -0.2(7) .
C21 C22 C24 C25 179.5(4) .
C22 C24 C25 C26 -2.0(7) .
C23 N3 C26 C25 1.0(6) .
Cd1 N3 C26 C25 -172.5(3) .
C24 C25 C26 N3 1.6(7) .
