#------------------------------------------------------------------------------
#$Date: 2019-11-06 05:25:50 +0200 (Wed, 06 Nov 2019) $
#$Revision: 223398 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/18/7701815.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7701815
loop_
_publ_author_name
'Capel Berdiell, Izar'
'Farmiloe, Sarah E.'
'Kulmaczewski, Rafal'
'Halcrow, Malcolm'
_publ_section_title
;
 Molecular Squares, Coordination Polymers and Mononuclear Complexes
 Supported by 2,4-Dipyrazolyl-6H-1,3,5-triazine and
 4,6-Dipyrazolylpyrimidine Ligands
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/C9DT04003J
_journal_year                    2019
_chemical_formula_moiety         'C68 H76 Ag4 N28, 4(Cl O4), C H3 N O2'
_chemical_formula_sum            'C69 H79 Ag4 Cl4 N29 O18'
_chemical_formula_weight         2175.89
_chemical_name_systematic
'Tetrakis-[2,4-di(4,5,6,7-tetrahydroindazol-2-yl)-6H-1,3,5-triazine]-tetrasilver(I) tetraperchlorate nitromethane solvate'
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2019-07-09
_audit_creation_method
;
  Olex2 1.2
  (compiled Apr 23 2013 17:54:37, GUI svn.r4466)
;
_audit_update_record
;
2019-11-03 deposited with the CCDC.	2019-11-05 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 131.404(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   20.7165(11)
_cell_length_b                   33.8226(13)
_cell_length_c                   15.6449(6)
_cell_measurement_reflns_used    3162
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      73.40
_cell_measurement_theta_min      4.83
_cell_volume                     8222.3(7)
_computing_cell_refinement       'CrysAlisPro, Agilent Technologies'
_computing_data_collection       'CrysAlisPro, Agilent Technologies'
_computing_data_reduction        'CrysAlisPro, Agilent Technologies'
_computing_molecular_graphics    'XSEED (Barbour, 2001)'
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 5.3095
_diffrn_measured_fraction_theta_full 0.841
_diffrn_measured_fraction_theta_max 0.824
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Cu) X-ray Source'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0554
_diffrn_reflns_av_unetI/netI     0.0764
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       41
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            10874
_diffrn_reflns_theta_full        72.00
_diffrn_reflns_theta_max         73.85
_diffrn_reflns_theta_min         4.59
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    9.462
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.714
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
CrysAlisPro, Agilent Technologies,
Version 1.171.36.24 (release 03-12-2012 CrysAlis171 .NET)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.758
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             4384
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: nitromethane-diethyl ether'
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.288
_refine_diff_density_min         -0.883
_refine_diff_density_rms         0.115
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     580
_refine_ls_number_reflns         6881
_refine_ls_number_restraints     26
_refine_ls_restrained_S_all      1.062
_refine_ls_R_factor_all          0.0964
_refine_ls_R_factor_gt           0.0635
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0684P)²+43.6977P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1500
_refine_ls_wR_factor_ref         0.1682
_reflns_number_gt                4861
_reflns_number_total             6881
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c9dt04003j2.cif
_cod_data_source_block           sf26-3
_cod_original_cell_volume        8222.3(6)
_cod_database_code               7701815
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 Cl5A-O57A = Cl5A-O58A = Cl5A-O59A = Cl5A-O60A
 1.43 with sigma of 0.02
 Cl5B-O57B = Cl5B-O58B = Cl5B-O59B = Cl5B-O60B
 1.43 with sigma of 0.02
 O57A-O58A = O57A-O59A = O57A-O60A = O58A-O59A = O58A-O60A = O59A-O60A
 2.34 with sigma of 0.02
 O57B-O58B = O57B-O59B = O57B-O60B = O58B-O59B = O58B-O60B = O59B-O60B
 2.34 with sigma of 0.02
 C69-N70
 1.45 with sigma of 0.02
 N70-O71 = N70-O72
 1.22 with sigma of 0.02
 O71-O72
 2.09 with sigma of 0.02
 C69-O71 = C69-O72
 2.34 with sigma of 0.02
3. Others
 Fixed Sof: Cl51(0.5) O52(0.5) O53(0.5) O54(0.5) O55(0.5) Cl5A(0.33)
 O57A(0.33) O58A(0.33) O59A(0.33) O60A(0.33) Cl5B(0.17) O57B(0.17) O58B(0.17)
 O59B(0.17) O60B(0.17) Cl61(0.5) O62(0.5) O63(0.5) O64(0.5) O65(0.5) C69(0.5)
 H69A(0.5) H69B(0.5) H69C(0.5) N70(0.5) O71(0.5) O72(0.5)
4.a Secondary CH2 refined with riding coordinates:
 C12(H12A,H12B), C13(H13A,H13B), C14(H14A,H14B), C15(H15A,H15B), C21(H21A,
 H21B), C22(H22A,H22B), C23(H23A,H23B), C24(H24A,H24B), C36(H36A,H36B),
 C37(H37A,H37B), C38(H38A,H38B), C39(H39A,H39B), C45(H45A,H45B), C46(H46A,H46B),
  C47(H47A,H47B), C48(H48A,H48B)
4.b Me refined with riding coordinates:
 C69(H69A,H69B,H69C)
4.c Aromatic/amide H refined with riding coordinates:
 C6(H6), C17(H17), C26(H26), C30(H30), C41(H41), C50(H50)
;
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, y, -z+1/2'
3 'x+1/2, y+1/2, z'
4 '-x+1/2, y+1/2, -z+1/2'
5 '-x, -y, -z'
6 'x, -y, z-1/2'
7 '-x+1/2, -y+1/2, -z'
8 'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.36816(5) 0.661058(16) 0.34709(6) 0.04427(19) Uani 1 1 d . . .
Ag2 Ag 0.75245(5) 0.592135(16) 0.85173(6) 0.0466(2) Uani 1 1 d . . .
N3 N 0.5360(4) 0.55096(15) 0.4917(5) 0.0241(12) Uani 1 1 d . . .
C4 C 0.4810(5) 0.58090(19) 0.4393(6) 0.0262(15) Uani 1 1 d . . .
N5 N 0.4791(4) 0.61289(16) 0.4874(6) 0.0311(14) Uani 1 1 d . . .
C6 C 0.5456(5) 0.61564(19) 0.5982(7) 0.0321(17) Uani 1 1 d . . .
H6 H 0.5475 0.6380 0.6366 0.038 Uiso 1 1 calc R B .
N7 N 0.6099(4) 0.58991(16) 0.6605(5) 0.0286(13) Uani 1 1 d . . .
C8 C 0.5990(5) 0.55772(18) 0.6032(6) 0.0248(14) Uani 1 1 d . . .
N9 N 0.4171(4) 0.57747(16) 0.3213(5) 0.0260(12) Uani 1 1 d . B .
N10 N 0.3600(4) 0.60778(16) 0.2576(5) 0.0273(13) Uani 1 1 d . B .
C11 C 0.3145(5) 0.5965(2) 0.1522(7) 0.0308(16) Uani 1 1 d . . .
C12 C 0.2475(5) 0.6215(2) 0.0511(7) 0.0356(18) Uani 1 1 d . . .
H12A H 0.2756 0.6431 0.0432 0.043 Uiso 1 1 calc R . .
H12B H 0.2099 0.6336 0.0620 0.043 Uiso 1 1 calc R . .
C13 C 0.1942(6) 0.5965(3) -0.0553(8) 0.043(2) Uani 1 1 d . . .
H13A H 0.1592 0.6141 -0.1227 0.052 Uiso 1 1 calc R B .
H13B H 0.1542 0.5802 -0.0562 0.052 Uiso 1 1 calc R . .
C14 C 0.2476(6) 0.5698(3) -0.0648(7) 0.044(2) Uani 1 1 d . . .
H14A H 0.2888 0.5859 -0.0622 0.053 Uiso 1 1 calc R . .
H14B H 0.2095 0.5558 -0.1389 0.053 Uiso 1 1 calc R . .
C15 C 0.2975(5) 0.5393(2) 0.0324(7) 0.0382(18) Uani 1 1 d . . .
H15A H 0.2573 0.5187 0.0182 0.046 Uiso 1 1 calc R B .
H15B H 0.3413 0.5262 0.0345 0.046 Uiso 1 1 calc R . .
C16 C 0.3403(5) 0.5585(2) 0.1437(7) 0.0288(15) Uani 1 1 d . . .
C17 C 0.4065(5) 0.5477(2) 0.2536(7) 0.0289(16) Uani 1 1 d . . .
H17 H 0.4392 0.5241 0.2786 0.035 Uiso 1 1 calc R B .
N18 N 0.6604(4) 0.52811(16) 0.6620(5) 0.0250(12) Uani 1 1 d . B .
N19 N 0.7345(4) 0.53352(16) 0.7740(5) 0.0285(13) Uani 1 1 d . . .
C20 C 0.7807(5) 0.5015(2) 0.7978(7) 0.0309(16) Uani 1 1 d . . .
C21 C 0.8677(5) 0.4947(2) 0.9117(7) 0.0388(18) Uani 1 1 d . . .
H21A H 0.8620 0.4864 0.9672 0.047 Uiso 1 1 calc R B .
H21B H 0.9016 0.5194 0.9396 0.047 Uiso 1 1 calc R . .
C22 C 0.9138(6) 0.4623(3) 0.9009(8) 0.044(2) Uani 1 1 d . . .
H22A H 0.9330 0.4733 0.8623 0.053 Uiso 1 1 calc R . .
H22B H 0.9655 0.4536 0.9780 0.053 Uiso 1 1 calc R . .
C23 C 0.8563(5) 0.4267(2) 0.8340(8) 0.043(2) Uani 1 1 d . . .
H23A H 0.8355 0.4160 0.8710 0.051 Uiso 1 1 calc R B .
H23B H 0.8903 0.4057 0.8352 0.051 Uiso 1 1 calc R . .
C24 C 0.7781(5) 0.4376(2) 0.7088(7) 0.0342(17) Uani 1 1 d . . .
H24A H 0.7970 0.4408 0.6653 0.041 Uiso 1 1 calc R . .
H24B H 0.7349 0.4161 0.6730 0.041 Uiso 1 1 calc R . .
C25 C 0.7384(4) 0.47541(19) 0.7052(6) 0.0252(15) Uani 1 1 d . . .
C26 C 0.6623(5) 0.49293(18) 0.6204(6) 0.0239(14) Uani 1 1 d . B .
H26 H 0.6184 0.4827 0.5459 0.029 Uiso 1 1 calc R . .
N27 N 0.2093(4) 0.69739(17) 0.4445(6) 0.0335(14) Uani 1 1 d . . .
C28 C 0.2569(5) 0.6909(2) 0.4165(7) 0.0319(16) Uani 1 1 d . . .
N29 N 0.3078(5) 0.65931(17) 0.4468(6) 0.0382(16) Uani 1 1 d . . .
C30 C 0.3070(6) 0.6336(2) 0.5102(7) 0.0394(19) Uani 1 1 d . . .
H30 H 0.3454 0.6119 0.5393 0.047 Uiso 1 1 calc R B .
N31 N 0.2579(4) 0.63506(18) 0.5374(6) 0.0361(15) Uani 1 1 d . . .
C32 C 0.2096(5) 0.6678(2) 0.4997(7) 0.0336(17) Uani 1 1 d . . .
N33 N 0.2540(4) 0.71937(16) 0.3517(6) 0.0311(14) Uani 1 1 d . B .
N34 N 0.2965(4) 0.71542(17) 0.3126(6) 0.0338(14) Uani 1 1 d . B .
C35 C 0.2718(5) 0.74586(19) 0.2440(7) 0.0326(17) Uani 1 1 d . . .
C36 C 0.3020(6) 0.7539(2) 0.1820(7) 0.0393(19) Uani 1 1 d . . .
H36A H 0.3026 0.7292 0.1487 0.047 Uiso 1 1 calc R . .
H36B H 0.3612 0.7648 0.2351 0.047 Uiso 1 1 calc R . .
C37 C 0.2399(7) 0.7842(3) 0.0865(9) 0.052(2) Uani 1 1 d . . .
H37A H 0.2664 0.7943 0.0564 0.062 Uiso 1 1 calc R B .
H37B H 0.1861 0.7704 0.0234 0.062 Uiso 1 1 calc R . .
C38 C 0.2179(7) 0.8183(3) 0.1230(9) 0.052(2) Uani 1 1 d . . .
H38A H 0.1815 0.8369 0.0585 0.062 Uiso 1 1 calc R . .
H38B H 0.2716 0.8323 0.1857 0.062 Uiso 1 1 calc R . .
C39 C 0.1711(6) 0.8064(2) 0.1627(8) 0.0375(18) Uani 1 1 d . . .
H39A H 0.1101 0.8008 0.0958 0.045 Uiso 1 1 calc R B .
H39B H 0.1729 0.8285 0.2058 0.045 Uiso 1 1 calc R . .
C40 C 0.2126(5) 0.76979(19) 0.2383(7) 0.0292(16) Uani 1 1 d . . .
C41 C 0.2020(5) 0.75238(19) 0.3061(7) 0.0311(16) Uani 1 1 d . . .
H41 H 0.1658 0.7612 0.3196 0.037 Uiso 1 1 calc R B .
N42 N 0.1550(4) 0.67161(17) 0.5207(6) 0.0322(14) Uani 1 1 d . B .
N43 N 0.1483(4) 0.64168(17) 0.5744(6) 0.0349(14) Uani 1 1 d . . .
C44 C 0.0858(5) 0.6543(2) 0.5715(6) 0.0326(16) Uani 1 1 d . . .
C45 C 0.0534(6) 0.6309(2) 0.6178(8) 0.043(2) Uani 1 1 d . . .
H45A H 0.1027 0.6207 0.6943 0.051 Uiso 1 1 calc R B .
H45B H 0.0194 0.6081 0.5673 0.051 Uiso 1 1 calc R . .
C46 C -0.0021(7) 0.6569(3) 0.6255(10) 0.057(3) Uani 1 1 d . . .
H46A H -0.0364 0.6398 0.6339 0.069 Uiso 1 1 calc R . .
H46B H 0.0357 0.6735 0.6946 0.069 Uiso 1 1 calc R . .
C47 C -0.0620(7) 0.6831(3) 0.5238(11) 0.065(3) Uani 1 1 d . . .
H47A H -0.0978 0.6981 0.5335 0.077 Uiso 1 1 calc R B .
H47B H -0.1010 0.6663 0.4553 0.077 Uiso 1 1 calc R . .
C48 C -0.0178(6) 0.7123(3) 0.5032(9) 0.050(2) Uani 1 1 d . . .
H48A H -0.0599 0.7231 0.4249 0.060 Uiso 1 1 calc R . .
H48B H 0.0061 0.7346 0.5576 0.060 Uiso 1 1 calc R . .
C49 C 0.0537(5) 0.6912(2) 0.5189(7) 0.0370(17) Uani 1 1 d . . .
C50 C 0.0974(5) 0.7015(2) 0.4852(7) 0.0358(18) Uani 1 1 d . B .
H50 H 0.0896 0.7247 0.4451 0.043 Uiso 1 1 calc R . .
Cl51 Cl 0.4738(2) 0.55355(9) 0.7203(3) 0.0315(10) Uani 0.50 1 d P A -1
O52 O 0.3819(8) 0.5494(3) 0.6529(11) 0.045(3) Uiso 0.50 1 d P A -1
O53 O 0.4980(7) 0.5360(3) 0.6610(10) 0.030(2) Uiso 0.50 1 d P A -1
O54 O 0.5209(9) 0.5342(4) 0.8288(12) 0.046(3) Uiso 0.50 1 d P A -1
O55 O 0.4897(11) 0.5948(2) 0.7335(13) 0.036(2) Uiso 0.50 1 d P A -1
Cl5A Cl 0.5104(5) 0.66895(17) 0.2845(5) 0.0465(14) Uiso 0.33 1 d PD B -1
O57A O 0.4733(18) 0.6924(7) 0.316(3) 0.107(11) Uiso 0.33 1 d PD B -1
O58A O 0.5441(9) 0.6337(3) 0.3482(12) 0.031(3) Uiso 0.33 1 d PD B -1
O59A O 0.5747(11) 0.6902(5) 0.2923(18) 0.046(5) Uiso 0.33 1 d PD B -1
O60A O 0.4452(17) 0.6568(9) 0.1652(14) 0.164(19) Uiso 0.33 1 d PD B -1
Cl5B Cl 0.5035(11) 0.6972(5) 0.2796(13) 0.078(5) Uiso 0.17 1 d PD B -2
O57B O 0.4984(17) 0.6945(7) 0.367(2) 0.025(6) Uiso 0.17 1 d PD B -2
O58B O 0.518(3) 0.7385(6) 0.271(4) 0.104(18) Uiso 0.17 1 d PD B -2
O59B O 0.5730(17) 0.6737(10) 0.310(3) 0.043(10) Uiso 0.17 1 d PD B -2
O60B O 0.4227(15) 0.6855(10) 0.1726(19) 0.037(9) Uiso 0.17 1 d PD B -2
Cl61 Cl 0.5062(5) 0.70558(10) 0.7766(5) 0.0442(13) Uani 0.50 1 d P C -1
O62 O 0.4208(16) 0.6891(7) 0.693(2) 0.089(8) Uiso 0.50 1 d P C -1
O63 O 0.5265(12) 0.7065(5) 0.8828(15) 0.082(5) Uiso 0.50 1 d P C -1
O64 O 0.5656(9) 0.6822(4) 0.7749(12) 0.031(3) Uiso 0.50 1 d P C -1
O65 O 0.5138(11) 0.7460(3) 0.758(2) 0.055(3) Uiso 0.50 1 d P C -1
Cl66 Cl 0.0000 0.52630(8) 0.7500 0.0460(7) Uani 1 2 d S . .
O67 O 0.0751(5) 0.5016(2) 0.8249(6) 0.0606(18) Uani 1 1 d . . .
O68 O 0.0102(5) 0.5502(2) 0.6846(6) 0.0640(19) Uani 1 1 d . . .
C69 C 0.0349(15) 0.5836(5) 0.315(2) 0.075(6) Uiso 0.50 1 d PD D -1
H69A H 0.0375 0.5827 0.3800 0.112 Uiso 0.50 1 calc PR D -1
H69B H 0.0929 0.5805 0.3424 0.112 Uiso 0.50 1 calc PR D -1
H69C H -0.0019 0.5621 0.2620 0.112 Uiso 0.50 1 calc PR D -1
N70 N -0.0007(18) 0.6215(4) 0.257(3) 0.068(4) Uiso 0.50 1 d PD D -1
O71 O -0.0696(11) 0.6332(5) 0.2267(18) 0.082(6) Uiso 0.50 1 d PD D -1
O72 O 0.0399(13) 0.6437(5) 0.2450(19) 0.088(6) Uiso 0.50 1 d PD D -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N5 Ag1 N29 89.18(19) . .
N5 Ag1 O57A 91.8(6) . .
N5 Ag1 O57B 84.5(5) . .
N10 Ag1 N5 70.3(2) . .
N10 Ag1 N29 120.1(2) . .
N10 Ag1 O57A 86.6(5) . .
N10 Ag1 O57B 93.6(5) . .
N29 Ag1 O57A 151.8(6) . .
N29 Ag1 O57B 141.2(5) . .
N34 Ag1 N5 148.5(2) . .
N34 Ag1 N10 140.2(2) . .
N34 Ag1 N29 69.3(2) . .
N34 Ag1 O57A 96.9(4) . .
N34 Ag1 O57B 97.9(5) . .
N19 Ag2 N7 71.0(2) . .
N19 Ag2 N31 151.6(2) . 2_656
N19 Ag2 N43 134.3(2) . 2_656
N31 Ag2 N7 107.0(2) 2_656 .
N43 Ag2 N7 126.5(2) 2_656 .
N43 Ag2 N31 70.7(2) 2_656 2_656
C4 N3 C8 112.0(6) . .
N3 C4 N5 127.2(7) . .
N3 C4 N9 115.5(6) . .
N5 C4 N9 117.3(6) . .
C4 N5 Ag1 113.1(5) . .
C6 N5 Ag1 132.0(4) . .
C6 N5 C4 113.7(6) . .
N5 C6 H6 117.1 . .
N5 C6 N7 125.8(6) . .
N7 C6 H6 117.1 . .
C6 N7 Ag2 133.7(5) . .
C6 N7 C8 113.6(6) . .
C8 N7 Ag2 112.3(5) . .
N3 C8 N18 114.7(6) . .
N7 C8 N3 127.1(6) . .
N7 C8 N18 118.1(6) . .
N10 N9 C4 120.5(5) . .
C17 N9 C4 127.7(6) . .
C17 N9 N10 111.5(6) . .
N9 N10 Ag1 118.6(4) . .
C11 N10 Ag1 136.5(5) . .
C11 N10 N9 104.9(5) . .
N10 C11 C12 124.2(6) . .
N10 C11 C16 112.2(7) . .
C16 C11 C12 123.5(7) . .
C11 C12 H12A 109.7 . .
C11 C12 H12B 109.7 . .
C11 C12 C13 109.9(6) . .
H12A C12 H12B 108.2 . .
C13 C12 H12A 109.7 . .
C13 C12 H12B 109.7 . .
C12 C13 H13A 108.9 . .
C12 C13 H13B 108.9 . .
C12 C13 C14 113.3(7) . .
H13A C13 H13B 107.7 . .
C14 C13 H13A 108.9 . .
C14 C13 H13B 108.9 . .
C13 C14 H14A 109.4 . .
C13 C14 H14B 109.4 . .
C13 C14 C15 111.2(7) . .
H14A C14 H14B 108.0 . .
C15 C14 H14A 109.4 . .
C15 C14 H14B 109.4 . .
C14 C15 H15A 109.5 . .
C14 C15 H15B 109.5 . .
H15A C15 H15B 108.1 . .
C16 C15 C14 110.8(7) . .
C16 C15 H15A 109.5 . .
C16 C15 H15B 109.5 . .
C11 C16 C15 122.2(7) . .
C17 C16 C11 104.5(7) . .
C17 C16 C15 133.3(6) . .
N9 C17 H17 126.5 . .
C16 C17 N9 107.0(6) . .
C16 C17 H17 126.5 . .
N19 N18 C8 120.6(5) . .
C26 N18 C8 128.0(6) . .
C26 N18 N19 111.1(6) . .
N18 N19 Ag2 117.1(4) . .
C20 N19 Ag2 138.3(5) . .
C20 N19 N18 103.8(6) . .
N19 C20 C21 122.6(7) . .
N19 C20 C25 112.5(7) . .
C25 C20 C21 124.9(7) . .
C20 C21 H21A 109.9 . .
C20 C21 H21B 109.9 . .
C20 C21 C22 109.1(7) . .
H21A C21 H21B 108.3 . .
C22 C21 H21A 109.9 . .
C22 C21 H21B 109.9 . .
C21 C22 H22A 109.1 . .
C21 C22 H22B 109.1 . .
H22A C22 H22B 107.9 . .
C23 C22 C21 112.3(7) . .
C23 C22 H22A 109.1 . .
C23 C22 H22B 109.1 . .
C22 C23 H23A 109.3 . .
C22 C23 H23B 109.3 . .
C22 C23 C24 111.6(7) . .
H23A C23 H23B 108.0 . .
C24 C23 H23A 109.3 . .
C24 C23 H23B 109.3 . .
C23 C24 H24A 109.7 . .
C23 C24 H24B 109.7 . .
H24A C24 H24B 108.2 . .
C25 C24 C23 109.9(7) . .
C25 C24 H24A 109.7 . .
C25 C24 H24B 109.7 . .
C20 C25 C24 123.0(7) . .
C26 C25 C20 105.3(6) . .
C26 C25 C24 131.6(7) . .
N18 C26 H26 126.4 . .
C25 C26 N18 107.2(6) . .
C25 C26 H26 126.4 . .
C32 N27 C28 113.8(6) . .
N27 C28 N29 126.2(7) . .
N27 C28 N33 116.4(6) . .
N29 C28 N33 117.4(6) . .
C28 N29 Ag1 110.5(5) . .
C30 N29 Ag1 136.2(5) . .
C30 N29 C28 112.9(7) . .
N29 C30 H30 116.5 . .
N29 C30 N31 127.0(7) . .
N31 C30 H30 116.5 . .
C30 N31 Ag2 131.6(5) . 2_656
C30 N31 C32 113.2(6) . .
C32 N31 Ag2 115.1(5) . 2_656
N27 C32 N31 126.4(7) . .
N27 C32 N42 115.8(7) . .
N31 C32 N42 117.8(6) . .
C28 N33 C41 126.1(6) . .
N34 N33 C28 122.3(6) . .
N34 N33 C41 111.2(6) . .
N33 N34 Ag1 120.1(4) . .
C35 N34 Ag1 133.4(5) . .
C35 N34 N33 105.6(6) . .
N34 C35 C36 124.7(7) . .
N34 C35 C40 110.3(6) . .
C40 C35 C36 125.0(7) . .
C35 C36 H36A 110.1 . .
C35 C36 H36B 110.1 . .
C35 C36 C37 108.1(7) . .
H36A C36 H36B 108.4 . .
C37 C36 H36A 110.1 . .
C37 C36 H36B 110.1 . .
C36 C37 H37A 108.7 . .
C36 C37 H37B 108.7 . .
H37A C37 H37B 107.6 . .
C38 C37 C36 114.4(8) . .
C38 C37 H37A 108.7 . .
C38 C37 H37B 108.7 . .
C37 C38 H38A 108.9 . .
C37 C38 H38B 108.9 . .
C37 C38 C39 113.3(8) . .
H38A C38 H38B 107.7 . .
C39 C38 H38A 108.9 . .
C39 C38 H38B 108.9 . .
C38 C39 H39A 109.6 . .
C38 C39 H39B 109.6 . .
C38 C39 C40 110.4(7) . .
H39A C39 H39B 108.1 . .
C40 C39 H39A 109.6 . .
C40 C39 H39B 109.6 . .
C35 C40 C39 122.0(6) . .
C41 C40 C35 106.5(6) . .
C41 C40 C39 131.4(6) . .
N33 C41 H41 126.8 . .
C40 C41 N33 106.3(6) . .
C40 C41 H41 126.8 . .
C32 N42 N43 120.4(6) . .
C50 N42 C32 127.3(6) . .
C50 N42 N43 112.1(6) . .
N42 N43 Ag2 115.2(5) . 2_656
C44 N43 Ag2 141.3(5) . 2_656
C44 N43 N42 103.3(6) . .
N43 C44 C45 123.2(7) . .
N43 C44 C49 112.3(6) . .
C49 C44 C45 124.4(7) . .
C44 C45 H45A 109.7 . .
C44 C45 H45B 109.7 . .
C44 C45 C46 109.8(7) . .
H45A C45 H45B 108.2 . .
C46 C45 H45A 109.7 . .
C46 C45 H45B 109.7 . .
C45 C46 H46A 108.9 . .
C45 C46 H46B 108.9 . .
H46A C46 H46B 107.7 . .
C47 C46 C45 113.5(8) . .
C47 C46 H46A 108.9 . .
C47 C46 H46B 108.9 . .
C46 C47 H47A 108.6 . .
C46 C47 H47B 108.6 . .
C46 C47 C48 114.7(9) . .
H47A C47 H47B 107.6 . .
C48 C47 H47A 108.6 . .
C48 C47 H47B 108.6 . .
C47 C48 H48A 109.9 . .
C47 C48 H48B 109.9 . .
H48A C48 H48B 108.3 . .
C49 C48 C47 108.9(7) . .
C49 C48 H48A 109.9 . .
C49 C48 H48B 109.9 . .
C44 C49 C48 123.4(7) . .
C50 C49 C44 106.0(7) . .
C50 C49 C48 130.6(7) . .
N42 C50 H50 126.9 . .
C49 C50 N42 106.3(7) . .
C49 C50 H50 126.9 . .
O53 Cl51 O52 109.9(7) . .
O54 Cl51 O52 110.8(8) . .
O54 Cl51 O53 108.6(7) . .
O55 Cl51 O52 105.6(8) . .
O55 Cl51 O53 110.6(9) . .
O55 Cl51 O54 111.4(8) . .
O57A Cl5A O58A 111.1(12) . .
O57A Cl5A O59A 112.3(12) . .
O57A Cl5A O60A 110.5(14) . .
O58A Cl5A O59A 111.4(10) . .
O58A Cl5A O60A 105.7(13) . .
O59A Cl5A O60A 105.6(12) . .
Cl5A O57A Ag1 122.0(15) . .
O57B Cl5B O58B 107.5(15) . .
O59B Cl5B O57B 109.7(14) . .
O59B Cl5B O58B 109.8(16) . .
O59B Cl5B O60B 112.4(15) . .
O60B Cl5B O57B 109.2(15) . .
O60B Cl5B O58B 108.1(15) . .
Cl5B O57B Ag1 127.1(15) . .
O62 Cl61 O64 108.2(10) . .
O63 Cl61 O62 107.7(13) . .
O63 Cl61 O64 115.2(10) . .
O63 Cl61 O65 103.2(12) . .
O65 Cl61 O62 114.8(13) . .
O65 Cl61 O64 107.9(9) . .
O67 Cl66 O67 109.3(6) . 2_556
O68 Cl66 O67 108.6(4) 2_556 2_556
O68 Cl66 O67 109.7(4) . 2_556
O68 Cl66 O67 109.7(4) 2_556 .
O68 Cl66 O67 108.6(4) . .
O68 Cl66 O68 110.8(6) . 2_556
H69A C69 H69B 109.5 . .
H69A C69 H69C 109.5 . .
H69B C69 H69C 109.5 . .
N70 C69 H69A 109.5 . .
N70 C69 H69B 109.5 . .
N70 C69 H69C 109.5 . .
O71 N70 C69 120.0(17) . .
O72 N70 C69 121.0(17) . .
O72 N70 O71 118.7(16) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 Ag2 7.0322(9) 2_656
Ag1 Ag2 6.9287(11) .
Ag1 N5 2.466(7) .
Ag1 N10 2.219(6) .
Ag1 N29 2.566(7) .
Ag1 N34 2.195(6) .
Ag1 O57A 2.74(2) .
Ag1 O57B 2.75(2) .
Ag2 N7 2.447(6) .
Ag2 N19 2.225(6) .
Ag2 N31 2.378(6) 2_656
Ag2 N43 2.287(6) 2_656
N3 C4 1.327(9) .
N3 C8 1.336(10) .
C4 N5 1.333(9) .
C4 N9 1.394(10) .
N5 C6 1.323(11) .
C6 H6 0.9500 .
C6 N7 1.329(10) .
N7 C8 1.331(9) .
C8 N18 1.385(9) .
N9 N10 1.372(8) .
N9 C17 1.369(9) .
N10 C11 1.302(10) .
C11 C12 1.496(11) .
C11 C16 1.431(9) .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C12 C13 1.508(12) .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C13 C14 1.511(11) .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
C14 C15 1.538(12) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C15 C16 1.483(11) .
C16 C17 1.360(11) .
C17 H17 0.9500 .
N18 N19 1.380(9) .
N18 C26 1.369(8) .
N19 C20 1.325(9) .
C20 C21 1.493(12) .
C20 C25 1.402(11) .
C21 H21A 0.9900 .
C21 H21B 0.9900 .
C21 C22 1.535(12) .
C22 H22A 0.9900 .
C22 H22B 0.9900 .
C22 C23 1.521(12) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C23 C24 1.550(12) .
C24 H24A 0.9900 .
C24 H24B 0.9900 .
C24 C25 1.501(10) .
C25 C26 1.352(10) .
C26 H26 0.9500 .
N27 C28 1.336(9) .
N27 C32 1.320(9) .
C28 N29 1.346(9) .
C28 N33 1.371(9) .
N29 C30 1.326(10) .
C30 H30 0.9500 .
C30 N31 1.338(10) .
N31 C32 1.339(9) .
C32 N42 1.377(10) .
N33 N34 1.370(8) .
N33 C41 1.378(9) .
N34 C35 1.323(10) .
C35 C36 1.486(10) .
C35 C40 1.422(9) .
C36 H36A 0.9900 .
C36 H36B 0.9900 .
C36 C37 1.547(12) .
C37 H37A 0.9900 .
C37 H37B 0.9900 .
C37 C38 1.485(12) .
C38 H38A 0.9900 .
C38 H38B 0.9900 .
C38 C39 1.511(11) .
C39 H39A 0.9900 .
C39 H39B 0.9900 .
C39 C40 1.526(10) .
C40 C41 1.353(10) .
C41 H41 0.9500 .
N42 N43 1.380(8) .
N42 C50 1.369(9) .
N43 C44 1.335(10) .
C44 C45 1.498(10) .
C44 C49 1.398(11) .
C45 H45A 0.9900 .
C45 H45B 0.9900 .
C45 C46 1.513(13) .
C46 H46A 0.9900 .
C46 H46B 0.9900 .
C46 C47 1.499(15) .
C47 H47A 0.9900 .
C47 H47B 0.9900 .
C47 C48 1.518(12) .
C48 H48A 0.9900 .
C48 H48B 0.9900 .
C48 C49 1.510(11) .
C49 C50 1.359(11) .
C50 H50 0.9500 .
Cl51 O52 1.448(13) .
Cl51 O53 1.441(13) .
Cl51 O54 1.439(15) .
Cl51 O55 1.416(9) .
Cl5A O57A 1.404(14) .
Cl5A O58A 1.409(12) .
Cl5A O59A 1.446(13) .
Cl5A O60A 1.464(15) .
Cl5B O57B 1.435(16) .
Cl5B O58B 1.454(16) .
Cl5B O59B 1.421(17) .
Cl5B O60B 1.433(17) .
Cl61 O62 1.45(3) .
Cl61 O63 1.419(19) .
Cl61 O64 1.477(14) .
Cl61 O65 1.427(12) .
Cl66 O67 1.441(7) .
Cl66 O68 1.426(7) .
C69 H69A 0.9800 .
C69 H69B 0.9800 .
C69 H69C 0.9800 .
C69 N70 1.458(16) .
N70 O71 1.236(17) .
N70 O72 1.231(16) .
