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#$Date: 2020-07-06 06:10:46 +0300 (Mon, 06 Jul 2020) $
#$Revision: 253905 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/45/7704520.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7704520
loop_
_publ_author_name
'Sugamata, Koh'
'Urao, Yukiko'
'Minoura, Mao'
_publ_section_title
;
 (Thio)(silyl)carbene and (seleno)(silyl)carbene gold(i) complexes from
 the reaction of bis(methylene)-λ⁴-sulfane and
 bis(methylene)-λ⁴-selane with chloro(dimethylsulfide)gold(i).
;
_journal_issue                   23
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7688
_journal_page_last               7691
_journal_paper_doi               10.1039/d0dt00967a
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C43 H45 Au2 Cl S2 Si3'
_chemical_formula_sum            'C43 H45 Au2 Cl S2 Si3'
_chemical_formula_weight         1139.56
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/1
_audit_update_record
;
2020-02-21 deposited with the CCDC.	2020-05-27 downloaded from the CCDC.
;
_cell_angle_alpha                96.6060(10)
_cell_angle_beta                 107.2010(10)
_cell_angle_gamma                93.5620(10)
_cell_formula_units_Z            2
_cell_length_a                   10.55870(10)
_cell_length_b                   12.72580(10)
_cell_length_c                   16.3375(2)
_cell_measurement_reflns_used    44790
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      21.7630
_cell_measurement_theta_min      1.5300
_cell_volume                     2072.41(4)
_computing_cell_refinement       'CrysAlisPro 1.171.40.67a (Rigaku OD, 2019)'
_computing_data_collection       'CrysAlisPro 1.171.40.67a (Rigaku OD, 2019)'
_computing_data_reduction        'CrysAlisPro 1.171.40.67a (Rigaku OD, 2019)'
_computing_molecular_graphics    'SHELXL-2018/1 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXL-2018/1 (Sheldrick, 2018)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type
'esperanto-CrysAlisPro-abstract goniometer imported esperanto images'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.4118
_diffrn_reflns_av_R_equivalents  0.0419
_diffrn_reflns_av_unetI/netI     0.0259
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            46266
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        14.305
_diffrn_reflns_theta_max         15.509
_diffrn_reflns_theta_min         1.508
_diffrn_source                   synchrotron
_exptl_absorpt_coefficient_mu    1.781
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.62548
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.67a (Rigaku Oxford Diffraction, 2019)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.826
_exptl_crystal_description       prism
_exptl_crystal_F_000             1104
_exptl_crystal_size_max          0.010
_exptl_crystal_size_mid          0.010
_exptl_crystal_size_min          0.010
_refine_diff_density_max         2.702
_refine_diff_density_min         -1.143
_refine_diff_density_rms         0.120
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     465
_refine_ls_number_reflns         9492
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.068
_refine_ls_R_factor_all          0.0215
_refine_ls_R_factor_gt           0.0208
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0244P)²+4.1721P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0558
_refine_ls_wR_factor_ref         0.0562
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9099
_reflns_number_total             9492
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0dt00967a3.cif
_cod_data_source_block           CSCAu_
_cod_depositor_comments
'Adding full bibliography for 7704520--7704521.cif.'
_cod_database_code               7704520
_shelx_shelxl_version_number     2018/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.982
_shelx_estimated_absorpt_t_max   0.982
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.8752(3) 0.1132(2) 0.21953(17) 0.0138(5) Uani 1 1 d . . . . .
C2 C 0.6894(3) 0.2482(2) 0.25989(16) 0.0123(5) Uani 1 1 d . . . . .
S1 S 0.82512(6) 0.17151(5) 0.29661(4) 0.01249(12) Uani 1 1 d . . . . .
Si1 Si 1.03399(7) 0.04723(6) 0.25814(5) 0.01199(13) Uani 1 1 d . . . . .
C3 C 1.1138(3) 0.0941(2) 0.37617(18) 0.0150(5) Uani 1 1 d . . . . .
C4 C 1.1673(3) 0.2004(2) 0.40232(19) 0.0192(5) Uani 1 1 d . . . . .
H1 H 1.159376 0.247048 0.360075 0.023 Uiso 1 1 calc R U . . .
C5 C 1.2320(3) 0.2390(3) 0.4890(2) 0.0260(6) Uani 1 1 d . . . . .
H2 H 1.267931 0.311346 0.505576 0.031 Uiso 1 1 calc R U . . .
C6 C 1.2435(3) 0.1713(3) 0.5509(2) 0.0277(7) Uani 1 1 d . . . . .
H3 H 1.288394 0.196969 0.610005 0.033 Uiso 1 1 calc R U . . .
C7 C 1.1899(3) 0.0668(3) 0.5267(2) 0.0262(6) Uani 1 1 d . . . . .
H4 H 1.197567 0.020720 0.569354 0.031 Uiso 1 1 calc R U . . .
C8 C 1.1248(3) 0.0282(2) 0.44014(19) 0.0202(6) Uani 1 1 d . . . . .
H5 H 1.087322 -0.043751 0.424388 0.024 Uiso 1 1 calc R U . . .
C9 C 0.9866(3) -0.0994(2) 0.23524(17) 0.0144(5) Uani 1 1 d . . . . .
C10 C 0.8817(3) -0.1465(2) 0.25886(19) 0.0187(5) Uani 1 1 d . . . . .
H6 H 0.833196 -0.102974 0.287363 0.022 Uiso 1 1 calc R U . . .
C11 C 0.8473(3) -0.2556(3) 0.2413(2) 0.0251(6) Uani 1 1 d . . . . .
H7 H 0.776491 -0.286231 0.258470 0.030 Uiso 1 1 calc R U . . .
C12 C 0.9160(3) -0.3198(2) 0.1990(2) 0.0265(7) Uani 1 1 d . . . . .
H8 H 0.891787 -0.394348 0.186462 0.032 Uiso 1 1 calc R U . . .
C13 C 1.0197(3) -0.2751(2) 0.1751(2) 0.0252(6) Uani 1 1 d . . . . .
H9 H 1.067325 -0.319339 0.146425 0.030 Uiso 1 1 calc R U . . .
C14 C 1.0552(3) -0.1655(2) 0.19268(18) 0.0186(5) Uani 1 1 d . . . . .
H10 H 1.126523 -0.135616 0.175620 0.022 Uiso 1 1 calc R U . . .
Au1 Au 0.79955(2) 0.10966(2) 0.09329(2) 0.01586(4) Uani 1 1 d . . . . .
Cl1 Cl 0.72403(8) 0.10123(7) -0.05408(5) 0.03001(17) Uani 1 1 d . . . . .
S2 S 0.41772(7) 0.14513(6) -0.00322(5) 0.01957(14) Uani 1 1 d . . . . .
Au2 Au 0.56616(2) 0.19699(2) 0.13370(2) 0.01353(4) Uani 1 1 d . . . . .
C15 C 1.1419(3) 0.0895(2) 0.19418(19) 0.0190(5) Uani 1 1 d . . . . .
H11 H 1.230028 0.064725 0.216481 0.028 Uiso 1 1 calc R U . . .
H12 H 1.150962 0.167235 0.198881 0.028 Uiso 1 1 calc R U . . .
H13 H 1.101723 0.058839 0.133355 0.028 Uiso 1 1 calc R U . . .
C16 C 0.2577(3) 0.1754(3) 0.0068(2) 0.0270(7) Uani 1 1 d . . . . .
H14 H 0.265155 0.248502 0.035575 0.040 Uiso 1 1 calc R U . . .
H15 H 0.228734 0.126115 0.041167 0.040 Uiso 1 1 calc R U . . .
H16 H 0.192220 0.168061 -0.050852 0.040 Uiso 1 1 calc R U . . .
C17 C 0.4470(3) 0.2509(3) -0.0626(2) 0.0275(7) Uani 1 1 d . . . . .
H17 H 0.386764 0.236479 -0.122053 0.041 Uiso 1 1 calc R U . . .
H18 H 0.539578 0.254801 -0.063558 0.041 Uiso 1 1 calc R U . . .
H19 H 0.430641 0.318670 -0.034428 0.041 Uiso 1 1 calc R U . . .
Si2 Si 0.57551(7) 0.23502(6) 0.32962(5) 0.01155(13) Uani 1 1 d . . . . .
C18 C 0.6583(3) 0.2919(2) 0.44654(17) 0.0148(5) Uani 1 1 d . . . . .
C19 C 0.6260(3) 0.3865(2) 0.48389(19) 0.0208(6) Uani 1 1 d . . . . .
H20 H 0.558941 0.423466 0.449715 0.025 Uiso 1 1 calc R U . . .
C20 C 0.6895(3) 0.4281(3) 0.5698(2) 0.0245(6) Uani 1 1 d . . . . .
H21 H 0.666446 0.493277 0.593398 0.029 Uiso 1 1 calc R U . . .
C21 C 0.7861(3) 0.3751(2) 0.62110(19) 0.0226(6) Uani 1 1 d . . . . .
H22 H 0.828275 0.402984 0.680161 0.027 Uiso 1 1 calc R U . . .
C22 C 0.8212(3) 0.2813(2) 0.58608(19) 0.0225(6) Uani 1 1 d . . . . .
H23 H 0.888533 0.244977 0.620700 0.027 Uiso 1 1 calc R U . . .
C23 C 0.7571(3) 0.2403(2) 0.49961(18) 0.0187(5) Uani 1 1 d . . . . .
H24 H 0.781255 0.175550 0.476186 0.022 Uiso 1 1 calc R U . . .
C24 C 0.5231(3) 0.0908(2) 0.32804(17) 0.0138(5) Uani 1 1 d . . . . .
C25 C 0.5286(3) 0.0081(2) 0.26527(18) 0.0165(5) Uani 1 1 d . . . . .
H25 H 0.569269 0.022573 0.222556 0.020 Uiso 1 1 calc R U . . .
C26 C 0.4756(3) -0.0949(2) 0.26430(19) 0.0203(6) Uani 1 1 d . . . . .
H26 H 0.481076 -0.150162 0.221498 0.024 Uiso 1 1 calc R U . . .
C27 C 0.4150(3) -0.1172(2) 0.3255(2) 0.0199(6) Uani 1 1 d . . . . .
H27 H 0.377055 -0.187333 0.323883 0.024 Uiso 1 1 calc R U . . .
C28 C 0.4095(3) -0.0373(2) 0.38896(19) 0.0187(5) Uani 1 1 d . . . . .
H28 H 0.368785 -0.052673 0.431491 0.022 Uiso 1 1 calc R U . . .
C29 C 0.4636(3) 0.0651(2) 0.39028(18) 0.0160(5) Uani 1 1 d . . . . .
H29 H 0.460186 0.119357 0.434473 0.019 Uiso 1 1 calc R U . . .
Si3 Si 0.77016(7) 0.38707(6) 0.26455(5) 0.01339(14) Uani 1 1 d . . . . .
C30 C 0.4226(3) 0.3030(2) 0.28934(18) 0.0158(5) Uani 1 1 d . . . . .
H30 H 0.375840 0.273183 0.229082 0.024 Uiso 1 1 calc R U . . .
H31 H 0.447448 0.379253 0.292771 0.024 Uiso 1 1 calc R U . . .
H32 H 0.364016 0.292411 0.324974 0.024 Uiso 1 1 calc R U . . .
C31 C 0.6329(3) 0.4776(2) 0.2375(2) 0.0171(5) Uani 1 1 d . . . . .
C32 C 0.5353(3) 0.4675(2) 0.1567(2) 0.0224(6) Uani 1 1 d . . . . .
H33 H 0.541673 0.416943 0.110918 0.027 Uiso 1 1 calc R U . . .
C33 C 0.4298(3) 0.5297(3) 0.1419(2) 0.0274(7) Uani 1 1 d . . . . .
H34 H 0.365123 0.521758 0.086419 0.033 Uiso 1 1 calc R U . . .
C34 C 0.4186(3) 0.6035(3) 0.2082(3) 0.0290(7) Uani 1 1 d . . . . .
H35 H 0.345704 0.645569 0.198495 0.035 Uiso 1 1 calc R U . . .
C35 C 0.5139(3) 0.6155(2) 0.2885(2) 0.0268(7) Uani 1 1 d . . . . .
H36 H 0.506825 0.666095 0.334045 0.032 Uiso 1 1 calc R U . . .
C36 C 0.6199(3) 0.5537(2) 0.3025(2) 0.0211(6) Uani 1 1 d . . . . .
H37 H 0.685403 0.563408 0.357704 0.025 Uiso 1 1 calc R U . . .
C37 C 0.8708(3) 0.3870(2) 0.18640(19) 0.0163(5) Uani 1 1 d . . . . .
C38 C 1.0097(3) 0.3994(2) 0.2177(2) 0.0202(6) Uani 1 1 d . . . . .
H38 H 1.052246 0.406312 0.278354 0.024 Uiso 1 1 calc R U . . .
C39 C 1.0878(3) 0.4019(3) 0.1622(2) 0.0274(7) Uani 1 1 d . . . . .
H39 H 1.182244 0.409829 0.185068 0.033 Uiso 1 1 calc R U . . .
C40 C 1.0275(3) 0.3927(3) 0.0741(2) 0.0295(7) Uani 1 1 d . . . . .
H40 H 1.080166 0.395445 0.036109 0.035 Uiso 1 1 calc R U . . .
C41 C 0.8904(3) 0.3797(3) 0.0415(2) 0.0291(7) Uani 1 1 d . . . . .
H41 H 0.848419 0.372769 -0.019222 0.035 Uiso 1 1 calc R U . . .
C42 C 0.8134(3) 0.3766(3) 0.0972(2) 0.0224(6) Uani 1 1 d . . . . .
H42 H 0.719048 0.367139 0.073667 0.027 Uiso 1 1 calc R U . . .
C43 C 0.8871(3) 0.4388(2) 0.3740(2) 0.0223(6) Uani 1 1 d . . . . .
H43 H 0.932516 0.507613 0.372184 0.033 Uiso 1 1 calc R U . . .
H44 H 0.953137 0.388357 0.391517 0.033 Uiso 1 1 calc R U . . .
H45 H 0.836975 0.447551 0.415710 0.033 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C -0.0001 0.0005 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -0.4757 3.6066 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.0550 0.0526 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.0441 0.0406 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0266 0.0227 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S1 C1 Si1 114.53(15) . . ?
S1 C1 Au1 128.91(15) . . ?
Si1 C1 Au1 116.45(13) . . ?
S1 C2 Si2 108.38(13) . . ?
S1 C2 Si3 104.77(13) . . ?
Si2 C2 Si3 116.09(13) . . ?
S1 C2 Au2 114.97(13) . . ?
Si2 C2 Au2 104.38(12) . . ?
Si3 C2 Au2 108.62(12) . . ?
C1 S1 C2 113.94(13) . . ?
C15 Si1 C9 111.41(13) . . ?
C15 Si1 C3 111.00(13) . . ?
C9 Si1 C3 112.24(12) . . ?
C15 Si1 C1 106.01(13) . . ?
C9 Si1 C1 107.09(12) . . ?
C3 Si1 C1 108.79(12) . . ?
C8 C3 C4 117.8(3) . . ?
C8 C3 Si1 123.5(2) . . ?
C4 C3 Si1 118.7(2) . . ?
C5 C4 C3 121.3(3) . . ?
C6 C5 C4 119.5(3) . . ?
C7 C6 C5 120.1(3) . . ?
C6 C7 C8 120.4(3) . . ?
C7 C8 C3 120.8(3) . . ?
C14 C9 C10 118.0(3) . . ?
C14 C9 Si1 120.3(2) . . ?
C10 C9 Si1 121.7(2) . . ?
C11 C10 C9 121.1(3) . . ?
C12 C11 C10 120.1(3) . . ?
C13 C12 C11 119.8(3) . . ?
C12 C13 C14 120.5(3) . . ?
C13 C14 C9 120.5(3) . . ?
C1 Au1 Cl1 176.29(8) . . ?
C1 Au1 Au2 85.38(8) . . ?
Cl1 Au1 Au2 98.33(2) . . ?
C16 S2 C17 99.01(16) . . ?
C16 S2 Au2 104.77(11) . . ?
C17 S2 Au2 103.38(11) . . ?
C2 Au2 S2 176.05(7) . . ?
C2 Au2 Au1 88.36(7) . . ?
S2 Au2 Au1 95.588(18) . . ?
C30 Si2 C24 108.14(12) . . ?
C30 Si2 C18 107.75(12) . . ?
C24 Si2 C18 106.60(12) . . ?
C30 Si2 C2 111.23(12) . . ?
C24 Si2 C2 109.97(12) . . ?
C18 Si2 C2 112.93(12) . . ?
C19 C18 C23 117.0(3) . . ?
C19 C18 Si2 122.4(2) . . ?
C23 C18 Si2 120.6(2) . . ?
C20 C19 C18 121.6(3) . . ?
C21 C20 C19 120.2(3) . . ?
C20 C21 C22 119.7(3) . . ?
C21 C22 C23 119.6(3) . . ?
C22 C23 C18 121.8(3) . . ?
C25 C24 C29 117.3(2) . . ?
C25 C24 Si2 125.1(2) . . ?
C29 C24 Si2 117.4(2) . . ?
C26 C25 C24 121.2(3) . . ?
C27 C26 C25 120.1(3) . . ?
C26 C27 C28 120.0(3) . . ?
C27 C28 C29 119.7(3) . . ?
C28 C29 C24 121.7(3) . . ?
C43 Si3 C37 106.74(13) . . ?
C43 Si3 C31 108.66(14) . . ?
C37 Si3 C31 111.26(13) . . ?
C43 Si3 C2 112.14(13) . . ?
C37 Si3 C2 110.39(12) . . ?
C31 Si3 C2 107.68(12) . . ?
C36 C31 C32 117.1(3) . . ?
C36 C31 Si3 119.2(2) . . ?
C32 C31 Si3 123.5(2) . . ?
C33 C32 C31 121.6(3) . . ?
C32 C33 C34 120.0(3) . . ?
C35 C34 C33 119.7(3) . . ?
C34 C35 C36 120.0(3) . . ?
C35 C36 C31 121.7(3) . . ?
C42 C37 C38 117.0(3) . . ?
C42 C37 Si3 123.2(2) . . ?
C38 C37 Si3 119.9(2) . . ?
C37 C38 C39 121.7(3) . . ?
C40 C39 C38 119.8(3) . . ?
C41 C40 C39 119.6(3) . . ?
C40 C41 C42 120.1(3) . . ?
C41 C42 C37 121.7(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 S1 1.626(3) . ?
C1 Si1 1.893(3) . ?
C1 Au1 1.973(3) . ?
C2 S1 1.779(3) . ?
C2 Si2 1.898(3) . ?
C2 Si3 1.898(3) . ?
C2 Au2 2.090(3) . ?
Si1 C15 1.854(3) . ?
Si1 C9 1.867(3) . ?
Si1 C3 1.870(3) . ?
C3 C8 1.396(4) . ?
C3 C4 1.400(4) . ?
C4 C5 1.393(4) . ?
C5 C6 1.386(5) . ?
C6 C7 1.378(5) . ?
C7 C8 1.391(4) . ?
C9 C14 1.398(4) . ?
C9 C10 1.399(4) . ?
C10 C11 1.388(4) . ?
C11 C12 1.382(5) . ?
C12 C13 1.379(5) . ?
C13 C14 1.396(4) . ?
Au1 Cl1 2.2889(7) . ?
Au1 Au2 2.97948(14) . ?
S2 C16 1.806(3) . ?
S2 C17 1.810(3) . ?
S2 Au2 2.3138(7) . ?
Si2 C30 1.861(3) . ?
Si2 C24 1.879(3) . ?
Si2 C18 1.885(3) . ?
C18 C19 1.394(4) . ?
C18 C23 1.397(4) . ?
C19 C20 1.389(4) . ?
C20 C21 1.381(5) . ?
C21 C22 1.383(4) . ?
C22 C23 1.395(4) . ?
C24 C25 1.399(4) . ?
C24 C29 1.402(4) . ?
C25 C26 1.389(4) . ?
C26 C27 1.382(4) . ?
C27 C28 1.383(4) . ?
C28 C29 1.386(4) . ?
Si3 C43 1.864(3) . ?
Si3 C37 1.887(3) . ?
Si3 C31 1.889(3) . ?
C31 C36 1.397(4) . ?
C31 C32 1.400(4) . ?
C32 C33 1.386(4) . ?
C33 C34 1.388(5) . ?
C34 C35 1.382(5) . ?
C35 C36 1.387(4) . ?
C37 C42 1.390(4) . ?
C37 C38 1.395(4) . ?
C38 C39 1.396(4) . ?
C39 C40 1.378(5) . ?
C40 C41 1.379(5) . ?
C41 C42 1.390(4) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Si1 C1 S1 C2 171.91(14) . . . . ?
Au1 C1 S1 C2 -4.1(2) . . . . ?
Si2 C2 S1 C1 143.63(14) . . . . ?
Si3 C2 S1 C1 -91.84(15) . . . . ?
Au2 C2 S1 C1 27.30(18) . . . . ?
S1 C1 Si1 C15 -132.66(16) . . . . ?
Au1 C1 Si1 C15 43.87(17) . . . . ?
S1 C1 Si1 C9 108.29(16) . . . . ?
Au1 C1 Si1 C9 -75.18(16) . . . . ?
S1 C1 Si1 C3 -13.24(19) . . . . ?
Au1 C1 Si1 C3 163.29(13) . . . . ?
C15 Si1 C3 C8 -131.1(2) . . . . ?
C9 Si1 C3 C8 -5.7(3) . . . . ?
C1 Si1 C3 C8 112.6(2) . . . . ?
C15 Si1 C3 C4 48.0(3) . . . . ?
C9 Si1 C3 C4 173.4(2) . . . . ?
C1 Si1 C3 C4 -68.3(2) . . . . ?
C8 C3 C4 C5 1.3(4) . . . . ?
Si1 C3 C4 C5 -177.8(2) . . . . ?
C3 C4 C5 C6 -0.2(5) . . . . ?
C4 C5 C6 C7 -0.7(5) . . . . ?
C5 C6 C7 C8 0.4(5) . . . . ?
C6 C7 C8 C3 0.8(5) . . . . ?
C4 C3 C8 C7 -1.6(4) . . . . ?
Si1 C3 C8 C7 177.5(2) . . . . ?
C15 Si1 C9 C14 15.0(3) . . . . ?
C3 Si1 C9 C14 -110.2(2) . . . . ?
C1 Si1 C9 C14 130.5(2) . . . . ?
C15 Si1 C9 C10 -164.3(2) . . . . ?
C3 Si1 C9 C10 70.5(3) . . . . ?
C1 Si1 C9 C10 -48.8(3) . . . . ?
C14 C9 C10 C11 0.6(4) . . . . ?
Si1 C9 C10 C11 179.9(2) . . . . ?
C9 C10 C11 C12 -0.7(5) . . . . ?
C10 C11 C12 C13 0.7(5) . . . . ?
C11 C12 C13 C14 -0.5(5) . . . . ?
C12 C13 C14 C9 0.3(5) . . . . ?
C10 C9 C14 C13 -0.4(4) . . . . ?
Si1 C9 C14 C13 -179.7(2) . . . . ?
S1 C2 Si2 C30 -174.88(13) . . . . ?
Si3 C2 Si2 C30 67.62(17) . . . . ?
Au2 C2 Si2 C30 -51.89(15) . . . . ?
S1 C2 Si2 C24 -55.11(16) . . . . ?
Si3 C2 Si2 C24 -172.61(13) . . . . ?
Au2 C2 Si2 C24 67.88(14) . . . . ?
S1 C2 Si2 C18 63.81(17) . . . . ?
Si3 C2 Si2 C18 -53.69(18) . . . . ?
Au2 C2 Si2 C18 -173.20(11) . . . . ?
C30 Si2 C18 C19 -15.6(3) . . . . ?
C24 Si2 C18 C19 -131.5(2) . . . . ?
C2 Si2 C18 C19 107.6(2) . . . . ?
C30 Si2 C18 C23 165.1(2) . . . . ?
C24 Si2 C18 C23 49.2(2) . . . . ?
C2 Si2 C18 C23 -71.7(3) . . . . ?
C23 C18 C19 C20 0.3(4) . . . . ?
Si2 C18 C19 C20 -179.0(2) . . . . ?
C18 C19 C20 C21 -0.9(5) . . . . ?
C19 C20 C21 C22 1.2(5) . . . . ?
C20 C21 C22 C23 -1.0(5) . . . . ?
C21 C22 C23 C18 0.5(5) . . . . ?
C19 C18 C23 C22 -0.1(4) . . . . ?
Si2 C18 C23 C22 179.2(2) . . . . ?
C30 Si2 C24 C25 102.2(2) . . . . ?
C18 Si2 C24 C25 -142.2(2) . . . . ?
C2 Si2 C24 C25 -19.4(3) . . . . ?
C30 Si2 C24 C29 -72.1(2) . . . . ?
C18 Si2 C24 C29 43.5(2) . . . . ?
C2 Si2 C24 C29 166.3(2) . . . . ?
C29 C24 C25 C26 0.8(4) . . . . ?
Si2 C24 C25 C26 -173.6(2) . . . . ?
C24 C25 C26 C27 0.6(4) . . . . ?
C25 C26 C27 C28 -1.4(4) . . . . ?
C26 C27 C28 C29 0.8(4) . . . . ?
C27 C28 C29 C24 0.6(4) . . . . ?
C25 C24 C29 C28 -1.4(4) . . . . ?
Si2 C24 C29 C28 173.4(2) . . . . ?
S1 C2 Si3 C43 -54.79(17) . . . . ?
Si2 C2 Si3 C43 64.69(18) . . . . ?
Au2 C2 Si3 C43 -178.12(12) . . . . ?
S1 C2 Si3 C37 64.09(16) . . . . ?
Si2 C2 Si3 C37 -176.42(14) . . . . ?
Au2 C2 Si3 C37 -59.24(15) . . . . ?
S1 C2 Si3 C31 -174.28(13) . . . . ?
Si2 C2 Si3 C31 -54.79(17) . . . . ?
Au2 C2 Si3 C31 62.39(15) . . . . ?
C43 Si3 C31 C36 -11.5(3) . . . . ?
C37 Si3 C31 C36 -128.8(2) . . . . ?
C2 Si3 C31 C36 110.1(2) . . . . ?
C43 Si3 C31 C32 173.7(2) . . . . ?
C37 Si3 C31 C32 56.4(3) . . . . ?
C2 Si3 C31 C32 -64.6(3) . . . . ?
C36 C31 C32 C33 -0.6(4) . . . . ?
Si3 C31 C32 C33 174.3(2) . . . . ?
C31 C32 C33 C34 -0.4(5) . . . . ?
C32 C33 C34 C35 0.8(5) . . . . ?
C33 C34 C35 C36 -0.2(5) . . . . ?
C34 C35 C36 C31 -0.8(5) . . . . ?
C32 C31 C36 C35 1.2(4) . . . . ?
Si3 C31 C36 C35 -173.9(2) . . . . ?
C43 Si3 C37 C42 -165.1(2) . . . . ?
C31 Si3 C37 C42 -46.7(3) . . . . ?
C2 Si3 C37 C42 72.8(3) . . . . ?
C43 Si3 C37 C38 13.9(3) . . . . ?
C31 Si3 C37 C38 132.3(2) . . . . ?
C2 Si3 C37 C38 -108.2(2) . . . . ?
C42 C37 C38 C39 0.3(4) . . . . ?
Si3 C37 C38 C39 -178.7(2) . . . . ?
C37 C38 C39 C40 0.5(5) . . . . ?
C38 C39 C40 C41 -0.9(5) . . . . ?
C39 C40 C41 C42 0.5(5) . . . . ?
C40 C41 C42 C37 0.4(5) . . . . ?
C38 C37 C42 C41 -0.8(4) . . . . ?
Si3 C37 C42 C41 178.3(3) . . . . ?
