#------------------------------------------------------------------------------
#$Date: 2020-07-06 05:53:15 +0300 (Mon, 06 Jul 2020) $
#$Revision: 253854 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/45/7704539.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7704539
loop_
_publ_author_name
'Cabeza, Javier A.'
'García-Álvarez, Pablo'
'Laglera-Gándara, Carlos J'
'Pérez-Carreño, Enrique'
_publ_section_title
;
 Phosphane-functionalized heavier tetrylenes: synthesis of silylene- and
 germylene-decorated phosphanes and their reactions with Group 10 metal
 complexes.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8331
_journal_page_last               8339
_journal_paper_doi               10.1039/d0dt01727b
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C36 H58 Ge N3 Ni P'
_chemical_formula_sum            'C36 H58 Ge N3 Ni P'
_chemical_formula_weight         695.12
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2020-05-06 deposited with the CCDC.	2020-06-01 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 109.118(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   20.5915(11)
_cell_length_b                   8.8479(3)
_cell_length_c                   20.8528(8)
_cell_measurement_reflns_used    4847
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      22.6230
_cell_measurement_theta_min      2.5870
_cell_volume                     3589.7(3)
_computing_cell_refinement
'CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)'
_computing_data_collection
'CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)'
_computing_data_reduction
'CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)'
_computing_molecular_graphics
'MERCURY (Cambridge Crystallographic Data Centre: Cambridge, UK, 2018)'
_computing_publication_material  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SIR-97 (Giacovazzo, 1999)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.936
_diffrn_measurement_device_type  'Xcalibur, Ruby, Gemini'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.1668
_diffrn_reflns_av_unetI/netI     0.2034
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.936
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            51967
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.936
_diffrn_reflns_theta_full        25.240
_diffrn_reflns_theta_max         31.443
_diffrn_reflns_theta_min         2.413
_exptl_absorpt_coefficient_mu    1.434
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.78012
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            pink
_exptl_crystal_density_diffrn    1.286
_exptl_crystal_description       fragment
_exptl_crystal_F_000             1480
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.09
_refine_diff_density_max         0.766
_refine_diff_density_min         -0.622
_refine_diff_density_rms         0.128
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     391
_refine_ls_number_reflns         11120
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.011
_refine_ls_R_factor_all          0.1865
_refine_ls_R_factor_gt           0.0747
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0017P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0798
_refine_ls_wR_factor_ref         0.1084
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5388
_reflns_number_total             11120
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0dt01727b2.cif
_cod_data_source_block           3Ni-Ge
_cod_depositor_comments
'Adding full bibliography for 7704536--7704539.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7704539
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   multi-scan
_shelxl_version_number           2014-3
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.7565(3) 0.0257(5) 0.2276(2) 0.0410(13) Uani 1 1 d . . . . .
H1A H 0.7880 0.0972 0.2584 0.062 Uiso 1 1 calc R U . . .
H1B H 0.7430 -0.0523 0.2541 0.062 Uiso 1 1 calc R U . . .
H1C H 0.7155 0.0797 0.1995 0.062 Uiso 1 1 calc R U . . .
C2 C 0.7448(2) -0.1675(5) 0.13645(18) 0.0354(12) Uani 1 1 d . . . . .
H2A H 0.7019 -0.1192 0.1090 0.053 Uiso 1 1 calc R U . . .
H2B H 0.7347 -0.2462 0.1649 0.053 Uiso 1 1 calc R U . . .
H2C H 0.7675 -0.2130 0.1065 0.053 Uiso 1 1 calc R U . . .
C3 C 0.8581(2) -0.1270(5) 0.2257(2) 0.0447(14) Uani 1 1 d . . . . .
H3A H 0.8840 -0.1636 0.1968 0.067 Uiso 1 1 calc R U . . .
H3B H 0.8461 -0.2126 0.2495 0.067 Uiso 1 1 calc R U . . .
H3C H 0.8864 -0.0551 0.2590 0.067 Uiso 1 1 calc R U . . .
C4 C 0.7924(2) -0.0486(4) 0.18186(18) 0.0249(10) Uani 1 1 d . . . . .
C5 C 0.8479(2) 0.1812(5) 0.14579(18) 0.0226(10) Uani 1 1 d . . . . .
C6 C 0.8856(2) 0.2485(5) 0.21351(18) 0.0245(10) Uani 1 1 d . . . . .
C7 C 0.8545(2) 0.3655(5) 0.23754(18) 0.0268(10) Uani 1 1 d . . . . .
H7 H 0.8108 0.4018 0.2102 0.032 Uiso 1 1 calc R U . . .
C8 C 0.8865(2) 0.4297(5) 0.30083(19) 0.0347(12) Uani 1 1 d . . . . .
H8 H 0.8650 0.5103 0.3163 0.042 Uiso 1 1 calc R U . . .
C9 C 0.9495(2) 0.3760(5) 0.3411(2) 0.0373(13) Uani 1 1 d . . . . .
H9 H 0.9710 0.4175 0.3849 0.045 Uiso 1 1 calc R U . . .
C10 C 0.9813(2) 0.2622(6) 0.3177(2) 0.0399(13) Uani 1 1 d . . . . .
H10 H 1.0251 0.2267 0.3453 0.048 Uiso 1 1 calc R U . . .
C11 C 0.9500(2) 0.1984(5) 0.25397(18) 0.0309(11) Uani 1 1 d . . . . .
H11 H 0.9726 0.1206 0.2381 0.037 Uiso 1 1 calc R U . . .
C12 C 0.8816(2) 0.3727(5) 0.06926(18) 0.0258(10) Uani 1 1 d . . . . .
C13 C 0.8505(2) 0.5212(5) 0.08377(19) 0.0323(11) Uani 1 1 d . . . . .
H13A H 0.8004 0.5171 0.0636 0.048 Uiso 1 1 calc R U . . .
H13B H 0.8682 0.6057 0.0640 0.048 Uiso 1 1 calc R U . . .
H13C H 0.8631 0.5356 0.1329 0.048 Uiso 1 1 calc R U . . .
C14 C 0.9587(2) 0.3670(5) 0.10746(19) 0.0365(12) Uani 1 1 d . . . . .
H14A H 0.9668 0.3782 0.1562 0.055 Uiso 1 1 calc R U . . .
H14B H 0.9816 0.4493 0.0918 0.055 Uiso 1 1 calc R U . . .
H14C H 0.9772 0.2699 0.0989 0.055 Uiso 1 1 calc R U . . .
C15 C 0.8699(2) 0.3618(5) -0.00738(17) 0.0346(12) Uani 1 1 d . . . . .
H15A H 0.8894 0.2669 -0.0171 0.052 Uiso 1 1 calc R U . . .
H15B H 0.8923 0.4473 -0.0215 0.052 Uiso 1 1 calc R U . . .
H15C H 0.8205 0.3643 -0.0324 0.052 Uiso 1 1 calc R U . . .
C16 C 0.8909(2) -0.0465(5) 0.0195(2) 0.0304(11) Uani 1 1 d . . . . .
H16 H 0.9231 0.0132 0.0530 0.036 Uiso 1 1 calc R U . . .
C17 C 0.9076(2) -0.1500(5) -0.02112(19) 0.0320(11) Uani 1 1 d . . . . .
H17 H 0.9525 -0.1748 -0.0211 0.038 Uiso 1 1 calc R U . . .
C18 C 0.8451(2) -0.2129(5) -0.06313(18) 0.0284(11) Uani 1 1 d . . . . .
H18 H 0.8401 -0.2882 -0.0969 0.034 Uiso 1 1 calc R U . . .
C19 C 0.7927(2) -0.1453(4) -0.04627(17) 0.0212(10) Uani 1 1 d . . . . .
C20 C 0.7177(2) -0.1804(4) -0.07033(17) 0.0238(10) Uani 1 1 d . . . . .
H20A H 0.7064 -0.2251 -0.0317 0.029 Uiso 1 1 calc R U . . .
H20B H 0.7096 -0.2597 -0.1056 0.029 Uiso 1 1 calc R U . . .
C21 C 0.6796(2) 0.0371(5) -0.18197(17) 0.0236(10) Uani 1 1 d . . . . .
C22 C 0.7043(2) -0.0885(5) -0.21966(18) 0.0326(11) Uani 1 1 d . . . . .
H22A H 0.6674 -0.1623 -0.2378 0.049 Uiso 1 1 calc R U . . .
H22B H 0.7445 -0.1390 -0.1881 0.049 Uiso 1 1 calc R U . . .
H22C H 0.7168 -0.0441 -0.2570 0.049 Uiso 1 1 calc R U . . .
C23 C 0.7391(2) 0.1510(4) -0.15484(18) 0.0278(11) Uani 1 1 d . . . . .
H23A H 0.7530 0.1886 -0.1926 0.042 Uiso 1 1 calc R U . . .
H23B H 0.7782 0.1009 -0.1216 0.042 Uiso 1 1 calc R U . . .
H23C H 0.7238 0.2359 -0.1332 0.042 Uiso 1 1 calc R U . . .
C24 C 0.6192(2) 0.1204(5) -0.23348(17) 0.0307(11) Uani 1 1 d . . . . .
H24A H 0.6362 0.1784 -0.2648 0.046 Uiso 1 1 calc R U . . .
H24B H 0.5980 0.1892 -0.2093 0.046 Uiso 1 1 calc R U . . .
H24C H 0.5851 0.0466 -0.2592 0.046 Uiso 1 1 calc R U . . .
C25 C 0.5737(2) -0.1436(5) -0.13723(17) 0.0252(10) Uani 1 1 d . . . . .
C26 C 0.5695(2) -0.2318(4) -0.07490(18) 0.0298(11) Uani 1 1 d . . . . .
H26A H 0.5854 -0.1673 -0.0346 0.045 Uiso 1 1 calc R U . . .
H26B H 0.5986 -0.3220 -0.0681 0.045 Uiso 1 1 calc R U . . .
H26C H 0.5218 -0.2622 -0.0824 0.045 Uiso 1 1 calc R U . . .
C27 C 0.5709(2) -0.2615(5) -0.19271(18) 0.0345(12) Uani 1 1 d . . . . .
H27A H 0.5322 -0.3302 -0.1981 0.052 Uiso 1 1 calc R U . . .
H27B H 0.6138 -0.3195 -0.1794 0.052 Uiso 1 1 calc R U . . .
H27C H 0.5651 -0.2097 -0.2358 0.052 Uiso 1 1 calc R U . . .
C28 C 0.5094(2) -0.0433(5) -0.16314(19) 0.0300(11) Uani 1 1 d . . . . .
H28A H 0.4681 -0.1065 -0.1741 0.045 Uiso 1 1 calc R U . . .
H28B H 0.5100 0.0108 -0.2039 0.045 Uiso 1 1 calc R U . . .
H28C H 0.5091 0.0298 -0.1279 0.045 Uiso 1 1 calc R U . . .
C29 C 0.6177(2) 0.3519(4) -0.08663(17) 0.0233(10) Uani 1 1 d . . . . .
H29 H 0.6350 0.3214 -0.1216 0.028 Uiso 1 1 calc R U . . .
C30 C 0.6652(2) 0.3949(4) -0.02512(17) 0.0226(9) Uani 1 1 d . . . . .
H30 H 0.7126 0.3881 -0.0203 0.027 Uiso 1 1 calc R U . . .
C31 C 0.6460(2) 0.4523(5) 0.03544(18) 0.0287(11) Uani 1 1 d . . . . .
H31A H 0.6005 0.5023 0.0185 0.034 Uiso 1 1 calc R U . . .
H31B H 0.6800 0.5293 0.0598 0.034 Uiso 1 1 calc R U . . .
C32 C 0.6432(2) 0.3274(5) 0.08559(18) 0.0306(11) Uani 1 1 d . . . . .
H32A H 0.6895 0.3157 0.1198 0.037 Uiso 1 1 calc R U . . .
H32B H 0.6113 0.3587 0.1098 0.037 Uiso 1 1 calc R U . . .
C33 C 0.6201(2) 0.1762(5) 0.05176(18) 0.0271(10) Uani 1 1 d . . . . .
H33 H 0.6455 0.0896 0.0727 0.032 Uiso 1 1 calc R U . . .
C34 C 0.5651(2) 0.1531(5) -0.00702(18) 0.0268(10) Uani 1 1 d . . . . .
H34 H 0.5561 0.0528 -0.0239 0.032 Uiso 1 1 calc R U . . .
C35 C 0.5182(2) 0.2781(5) -0.04607(18) 0.0285(11) Uani 1 1 d . . . . .
H35A H 0.5158 0.3581 -0.0137 0.034 Uiso 1 1 calc R U . . .
H35B H 0.4713 0.2365 -0.0667 0.034 Uiso 1 1 calc R U . . .
C36 C 0.5410(2) 0.3498(5) -0.10229(17) 0.0253(10) Uani 1 1 d . . . . .
H36A H 0.5199 0.2931 -0.1450 0.030 Uiso 1 1 calc R U . . .
H36B H 0.5236 0.4548 -0.1098 0.030 Uiso 1 1 calc R U . . .
Ge1 Ge 0.76774(2) 0.10382(5) 0.03483(2) 0.02088(11) Uani 1 1 d . . . . .
N1 N 0.80689(17) 0.0609(4) 0.13498(14) 0.0230(8) Uani 1 1 d . . . . .
N2 N 0.84587(17) 0.2387(4) 0.08553(14) 0.0234(8) Uani 1 1 d . . . . .
N3 N 0.82090(17) -0.0413(4) 0.00481(14) 0.0220(8) Uani 1 1 d . . . . .
Ni1 Ni 0.65930(3) 0.15450(6) -0.02992(2) 0.02050(14) Uani 1 1 d . . . . .
P1 P 0.65481(6) -0.02479(12) -0.10590(5) 0.0204(3) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C4 C3 111.4(4) . . ?
N1 C4 C1 112.0(3) . . ?
C3 C4 C1 109.6(3) . . ?
N1 C4 C2 105.6(3) . . ?
C3 C4 C2 108.6(3) . . ?
C1 C4 C2 109.7(4) . . ?
N1 C5 N2 108.7(3) . . ?
N1 C5 C6 125.7(4) . . ?
N2 C5 C6 125.5(4) . . ?
N1 C5 Ge1 54.90(18) . . ?
N2 C5 Ge1 54.54(19) . . ?
C6 C5 Ge1 168.9(3) . . ?
C11 C6 C7 118.5(4) . . ?
C11 C6 C5 122.9(4) . . ?
C7 C6 C5 118.6(4) . . ?
C8 C7 C6 121.0(4) . . ?
C9 C8 C7 119.7(4) . . ?
C10 C9 C8 120.0(4) . . ?
C9 C10 C11 120.7(4) . . ?
C6 C11 C10 120.1(4) . . ?
N2 C12 C14 111.2(3) . . ?
N2 C12 C13 111.5(3) . . ?
C14 C12 C13 110.8(3) . . ?
N2 C12 C15 105.3(3) . . ?
C14 C12 C15 108.8(4) . . ?
C13 C12 C15 109.0(3) . . ?
C17 C16 N3 110.1(4) . . ?
C16 C17 C18 106.6(4) . . ?
C19 C18 C17 107.6(4) . . ?
C18 C19 N3 108.6(4) . . ?
C18 C19 C20 129.5(4) . . ?
N3 C19 C20 121.7(4) . . ?
C19 C20 P1 119.1(3) . . ?
C24 C21 C22 108.4(3) . . ?
C24 C21 C23 107.8(3) . . ?
C22 C21 C23 107.6(3) . . ?
C24 C21 P1 110.2(3) . . ?
C22 C21 P1 116.3(3) . . ?
C23 C21 P1 106.3(2) . . ?
C28 C25 C26 108.0(3) . . ?
C28 C25 C27 108.1(3) . . ?
C26 C25 C27 106.9(3) . . ?
C28 C25 P1 111.1(3) . . ?
C26 C25 P1 106.0(2) . . ?
C27 C25 P1 116.3(3) . . ?
C30 C29 C36 125.2(4) . . ?
C30 C29 Ni1 71.2(2) . . ?
C36 C29 Ni1 108.3(3) . . ?
C29 C30 C31 124.1(4) . . ?
C29 C30 Ni1 70.8(2) . . ?
C31 C30 Ni1 110.2(3) . . ?
C30 C31 C32 113.6(3) . . ?
C33 C32 C31 113.3(3) . . ?
C34 C33 C32 125.7(4) . . ?
C34 C33 Ni1 72.1(2) . . ?
C32 C33 Ni1 108.0(3) . . ?
C33 C34 C35 124.0(4) . . ?
C33 C34 Ni1 70.0(2) . . ?
C35 C34 Ni1 109.8(3) . . ?
C34 C35 C36 114.3(3) . . ?
C29 C36 C35 113.7(3) . . ?
N3 Ge1 N2 97.21(14) . . ?
N3 Ge1 N1 97.74(13) . . ?
N2 Ge1 N1 65.50(12) . . ?
N3 Ge1 Ni1 119.91(9) . . ?
N2 Ge1 Ni1 131.85(10) . . ?
N1 Ge1 Ni1 130.04(10) . . ?
N3 Ge1 C5 102.39(13) . . ?
N2 Ge1 C5 33.10(12) . . ?
N1 Ge1 C5 32.73(12) . . ?
Ni1 Ge1 C5 137.68(10) . . ?
C5 N1 C4 131.9(3) . . ?
C5 N1 Ge1 92.4(2) . . ?
C4 N1 Ge1 135.4(3) . . ?
C5 N2 C12 130.3(3) . . ?
C5 N2 Ge1 92.4(3) . . ?
C12 N2 Ge1 136.4(2) . . ?
C16 N3 C19 107.2(3) . . ?
C16 N3 Ge1 128.2(3) . . ?
C19 N3 Ge1 123.7(3) . . ?
C33 Ni1 C29 100.51(16) . . ?
C33 Ni1 C30 84.40(15) . . ?
C29 Ni1 C30 38.04(13) . . ?
C33 Ni1 C34 37.90(14) . . ?
C29 Ni1 C34 84.22(16) . . ?
C30 Ni1 C34 92.11(16) . . ?
C33 Ni1 P1 134.40(12) . . ?
C29 Ni1 P1 105.96(10) . . ?
C30 Ni1 P1 137.27(10) . . ?
C34 Ni1 P1 108.97(11) . . ?
C33 Ni1 Ge1 95.77(11) . . ?
C29 Ni1 Ge1 129.74(11) . . ?
C30 Ni1 Ge1 98.13(11) . . ?
C34 Ni1 Ge1 131.25(10) . . ?
P1 Ni1 Ge1 95.00(4) . . ?
C20 P1 C21 101.72(19) . . ?
C20 P1 C25 98.39(18) . . ?
C21 P1 C25 108.60(17) . . ?
C20 P1 Ni1 112.41(12) . . ?
C21 P1 Ni1 115.46(13) . . ?
C25 P1 Ni1 117.81(14) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C4 1.533(5) . ?
C2 C4 1.535(5) . ?
C3 C4 1.529(5) . ?
C4 N1 1.474(5) . ?
C5 N1 1.330(5) . ?
C5 N2 1.344(4) . ?
C5 C6 1.495(5) . ?
C5 Ge1 2.458(4) . ?
C6 C11 1.391(5) . ?
C6 C7 1.393(5) . ?
C7 C8 1.389(5) . ?
C8 C9 1.380(6) . ?
C9 C10 1.374(6) . ?
C10 C11 1.392(5) . ?
C12 N2 1.492(5) . ?
C12 C14 1.526(5) . ?
C12 C13 1.534(5) . ?
C12 C15 1.539(5) . ?
C16 C17 1.365(5) . ?
C16 N3 1.373(5) . ?
C17 C18 1.413(6) . ?
C18 C19 1.376(5) . ?
C19 N3 1.383(4) . ?
C19 C20 1.491(5) . ?
C20 P1 1.869(4) . ?
C21 C24 1.539(5) . ?
C21 C22 1.541(5) . ?
C21 C23 1.544(5) . ?
C21 P1 1.899(4) . ?
C25 C28 1.537(5) . ?
C25 C26 1.543(5) . ?
C25 C27 1.545(5) . ?
C25 P1 1.900(4) . ?
C29 C30 1.387(5) . ?
C29 C36 1.503(5) . ?
C29 Ni1 2.126(4) . ?
C30 C31 1.528(5) . ?
C30 Ni1 2.131(4) . ?
C31 C32 1.536(5) . ?
C32 C33 1.515(5) . ?
C33 C34 1.385(5) . ?
C33 Ni1 2.119(4) . ?
C34 C35 1.517(5) . ?
C34 Ni1 2.145(4) . ?
C35 C36 1.536(5) . ?
Ge1 N3 1.921(3) . ?
Ge1 N2 2.004(3) . ?
Ge1 N1 2.013(3) . ?
Ge1 Ni1 2.2439(7) . ?
Ni1 P1 2.2224(11) . ?
