Crystallography Open Database

Information card for entry 1518855

Preview

Coordinates	1518855.cif

Structure parameters

Formula	C32 H84 N12 O15 Pt2 Rh2
Calculated formula	C32 H84 N12 O15 Pt2 Rh2
SMILES	[Pt]([Rh]1234[O]=C(C)N[Rh]4([Pt](NC(=O)C(C)(C)C)(NC(=O)C(C)(C)C)([NH3])[NH3])([O]=C(N2)C)([O]=C(N3)C)NC(=[O]1)C)(NC(=O)C(C)(C)C)(NC(=O)C(C)(C)C)([NH3])[NH3].OC.O.O.OC.OC.O.O.OC
Title of publication	Acetamidate-bridged paddlewheel dirhodium complex sandwiched by mononuclear platinum complexes with axial metal-metal bonds affording neutral heterometallic one-dimensional alignments
Authors of publication	Kazuhiro Uemura; Tomofumi Yamada; Toru Kanbara; Masahiro Ebihara
Journal of publication	Inorganica Chimica Acta
Year of publication	2015
Journal volume	424
Pages of publication	194 - 201
a	27.041 ± 0.005 Å
b	11.654 ± 0.002 Å
c	22.017 ± 0.004 Å
α	90°
β	126.38 ± 0.0015°
γ	90°
Cell volume	5586.1 ± 1.7 Å³
Cell temperature	123 ± 2 K
Ambient diffraction temperature	123 ± 2 K
Number of distinct elements	6
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.0333
Residual factor for significantly intense reflections	0.0303
Weighted residual factors for significantly intense reflections	0.0679
Weighted residual factors for all reflections included in the refinement	0.0701
Goodness-of-fit parameter for all reflections included in the refinement	1.116
Diffraction radiation wavelength	0.7107 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176729 (current)	2016-02-18	cif/ (antanas@echidna.ibt.lt) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 1.	1518855.cif
133936	2015-03-15	cif/ Adding structures of 1518855 via cif-deposit CGI script.	1518855.cif