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Information card for entry 1546219
Preview
| Coordinates | 1546219.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C28 H41 N O11 |
|---|---|
| Calculated formula | C28 H41 N O11 |
| SMILES | C1Oc2c(cc3c(c2)CCN2[C@@]4([C@H]3[C@@H](C(=C4)OC)OC(=O)[C@](CC(=O)OC)(CCC(C)(C)O)O)CCC2)O1.O.O |
| Title of publication | Diastereoselective Synthesis of Cephalotaxus Esters via Asymmetric Mukaiyama Aldol Reaction. |
| Authors of publication | Ma, Guo-Zhen; Li, Peng-Fei; Liu, Lu; Li, Wei-Dong Z; Chen, Li |
| Journal of publication | Organic letters |
| Year of publication | 2017 |
| Journal volume | 19 |
| Journal issue | 9 |
| Pages of publication | 2250 - 2253 |
| a | 10.77 ± 0.005 Å |
| b | 15.109 ± 0.007 Å |
| c | 17.72 ± 0.007 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 2883 ± 2 Å3 |
| Cell temperature | 113 ± 2 K |
| Ambient diffraction temperature | 113 ± 2 K |
| Number of distinct elements | 4 |
| Space group number | 19 |
| Hermann-Mauguin space group symbol | P 21 21 21 |
| Hall space group symbol | P 2ac 2ab |
| Residual factor for all reflections | 0.0626 |
| Residual factor for significantly intense reflections | 0.0547 |
| Weighted residual factors for significantly intense reflections | 0.1189 |
| Weighted residual factors for all reflections included in the refinement | 0.1225 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.133 |
| Diffraction radiation wavelength | 0.7107 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 197364 (current) | 2017-06-05 | cif/ Adding structures of 1546219 via cif-deposit CGI script. |
1546219.cif |
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Users of the data should acknowledge the original authors of the
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