#------------------------------------------------------------------------------
#$Date: 2019-03-18 09:35:25 +0200 (Mon, 18 Mar 2019) $
#$Revision: 214153 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/54/85/1548585.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1548585
loop_
_publ_author_name
'Omar bin Shawkataly'
'Chin-Ping Goh'
'Abu Tariq'
'Imthyaz Ahmad Khan'
'Hoong-Kun Fun'
'Mohd Mustaqim Rosli'
_publ_section_title
;
 Synthesis, Spectral Characterization and Crystals Structure of some
 Arsane Derivatives of Gold (I) Complexes: A Comparative Density
 Functional Theory Study
;
_journal_name_full               'Plos One'
_journal_page_first              e0119620
_journal_paper_doi               10.1371/journal.pone.0119620
_journal_volume                  10
_journal_year                    2015
_chemical_formula_sum            'C31 H23 As Au Cl3'
_chemical_formula_weight         773.73
_chemical_name_systematic
; 
2.2.5 Chlorido(tris-naphthylarsane)gold(I)
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 96.4610(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.4715(3)
_cell_length_b                   18.0504(5)
_cell_length_c                   16.0002(5)
_cell_measurement_reflns_used    9970
_cell_measurement_temperature    100.0(1)
_cell_measurement_theta_max      37.26
_cell_measurement_theta_min      3.29
_cell_volume                     2718.09(14)
_computing_cell_refinement       'SAINT (Bruker, 2009)'
_computing_data_collection       'APEX2 (Bruker, 2009)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    SHELXTL
_computing_publication_material
;
SHELXTL and PLATON (Spek, 2009)
;
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      100
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Bruker APEX Duo CCD area detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0397
_diffrn_reflns_av_sigmaI/netI    0.0380
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            52853
_diffrn_reflns_theta_full        37.40
_diffrn_reflns_theta_max         37.40
_diffrn_reflns_theta_min         1.71
_diffrn_standards_interval_count .
_diffrn_standards_interval_time  .
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    6.935
_exptl_absorpt_correction_T_max  0.5587
_exptl_absorpt_correction_T_min  0.1326
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.891
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1488
_exptl_crystal_size_max          0.49
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.10
_refine_diff_density_max         3.054
_refine_diff_density_min         -1.136
_refine_diff_density_rms         0.134
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     325
_refine_ls_number_reflns         14091
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0403
_refine_ls_R_factor_gt           0.0287
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0312P)²+0.5462P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0627
_refine_ls_wR_factor_ref         0.0665
_reflns_number_gt                11628
_reflns_number_total             14091
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            pone.0119620.s004.cif
_cod_data_source_block           4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 5376 2017-05-30 11:51:03Z andrius 

2019-03-12
Z value and formula fixed to values more according to usual
chemical conventions.                 miguel
;
_cod_original_formula_sum            'C20.67 H15.33 As0.67 Au0.67 Cl2'
_cod_original_formula_weight         515.82
_cod_original_formula_units_Z            6
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               1548585
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.377673(7) 0.441652(4) 0.827068(4) 0.01799(2) Uani 1 1 d . . .
As1 As 0.429967(19) 0.475261(11) 0.692677(11) 0.01567(4) Uani 1 1 d . . .
Cl1 Cl 0.32651(6) 0.40463(4) 0.95591(3) 0.03237(12) Uani 1 1 d . . .
C1 C 0.7360(2) 0.45247(11) 0.73327(12) 0.0181(3) Uani 1 1 d . . .
C2 C 0.7310(2) 0.49575(12) 0.80739(12) 0.0216(3) Uani 1 1 d . . .
H2A H 0.6477 0.5205 0.8160 0.026 Uiso 1 1 calc R . .
C3 C 0.8479(2) 0.50128(13) 0.86636(13) 0.0246(4) Uani 1 1 d . . .
H3A H 0.8418 0.5284 0.9153 0.030 Uiso 1 1 calc R . .
C4 C 0.9766(2) 0.46637(14) 0.85351(14) 0.0269(4) Uani 1 1 d . . .
H4A H 1.0550 0.4707 0.8938 0.032 Uiso 1 1 calc R . .
C5 C 0.9867(2) 0.42607(13) 0.78178(15) 0.0253(4) Uani 1 1 d . . .
H5A H 1.0726 0.4040 0.7732 0.030 Uiso 1 1 calc R . .
C6 C 0.8669(2) 0.41779(12) 0.72047(13) 0.0206(3) Uani 1 1 d . . .
C7 C 0.8751(2) 0.37370(12) 0.64795(13) 0.0239(4) Uani 1 1 d . . .
H7A H 0.9610 0.3515 0.6395 0.029 Uiso 1 1 calc R . .
C8 C 0.7596(2) 0.36311(12) 0.59030(13) 0.0237(4) Uani 1 1 d . . .
H8A H 0.7671 0.3343 0.5428 0.028 Uiso 1 1 calc R . .
C9 C 0.6278(2) 0.39627(12) 0.60296(12) 0.0209(3) Uani 1 1 d . . .
H9A H 0.5487 0.3883 0.5640 0.025 Uiso 1 1 calc R . .
C10 C 0.61582(19) 0.44005(11) 0.67225(11) 0.0179(3) Uani 1 1 d . . .
C11 C 0.2629(2) 0.35576(11) 0.60538(12) 0.0186(3) Uani 1 1 d . . .
C12 C 0.3155(2) 0.30596(12) 0.67035(13) 0.0240(4) Uani 1 1 d . . .
H12A H 0.3818 0.3223 0.7137 0.029 Uiso 1 1 calc R . .
C13 C 0.2692(3) 0.23390(13) 0.66961(15) 0.0299(4) Uani 1 1 d . . .
H13A H 0.3023 0.2024 0.7135 0.036 Uiso 1 1 calc R . .
C14 C 0.1727(3) 0.20703(14) 0.60374(16) 0.0340(5) Uani 1 1 d . . .
H14A H 0.1419 0.1581 0.6042 0.041 Uiso 1 1 calc R . .
C15 C 0.1240(3) 0.25297(13) 0.53867(14) 0.0298(4) Uani 1 1 d . . .
H15A H 0.0626 0.2344 0.4941 0.036 Uiso 1 1 calc R . .
C16 C 0.1656(2) 0.32794(12) 0.53829(12) 0.0221(3) Uani 1 1 d . . .
C17 C 0.1091(2) 0.37661(13) 0.47276(12) 0.0238(4) Uani 1 1 d . . .
H17A H 0.0457 0.3583 0.4290 0.029 Uiso 1 1 calc R . .
C18 C 0.1462(2) 0.44947(12) 0.47319(12) 0.0231(4) Uani 1 1 d . . .
H18A H 0.1078 0.4807 0.4303 0.028 Uiso 1 1 calc R . .
C19 C 0.2437(2) 0.47749(12) 0.53932(11) 0.0203(3) Uani 1 1 d . . .
H19A H 0.2692 0.5273 0.5394 0.024 Uiso 1 1 calc R . .
C20 C 0.3010(2) 0.43227(11) 0.60306(11) 0.0175(3) Uani 1 1 d . . .
C21 C 0.3081(2) 0.62449(11) 0.68331(11) 0.0175(3) Uani 1 1 d . . .
C22 C 0.1867(2) 0.59604(12) 0.71773(11) 0.0199(3) Uani 1 1 d . . .
H22A H 0.1810 0.5456 0.7288 0.024 Uiso 1 1 calc R . .
C23 C 0.0781(2) 0.64219(13) 0.73471(12) 0.0238(4) Uani 1 1 d . . .
H23A H 0.0006 0.6229 0.7583 0.029 Uiso 1 1 calc R . .
C24 C 0.0831(2) 0.71847(13) 0.71674(13) 0.0255(4) Uani 1 1 d . . .
H24A H 0.0092 0.7492 0.7287 0.031 Uiso 1 1 calc R . .
C25 C 0.1968(2) 0.74753(12) 0.68159(13) 0.0249(4) Uani 1 1 d . . .
H25A H 0.1985 0.7978 0.6692 0.030 Uiso 1 1 calc R . .
C26 C 0.3117(2) 0.70175(11) 0.66399(11) 0.0207(3) Uani 1 1 d . . .
C27 C 0.4301(2) 0.73120(12) 0.62832(13) 0.0245(4) Uani 1 1 d . . .
H27A H 0.4322 0.7814 0.6156 0.029 Uiso 1 1 calc R . .
C28 C 0.5415(2) 0.68697(12) 0.61223(13) 0.0243(4) Uani 1 1 d . . .
H28A H 0.6178 0.7072 0.5882 0.029 Uiso 1 1 calc R . .
C29 C 0.5407(2) 0.61047(12) 0.63212(12) 0.0213(3) Uani 1 1 d . . .
H29A H 0.6170 0.5807 0.6219 0.026 Uiso 1 1 calc R . .
C30 C 0.4270(2) 0.58011(11) 0.66654(11) 0.0176(3) Uani 1 1 d . . .
Cl2 Cl 0.41474(8) 0.68807(5) 0.89283(4) 0.04398(16) Uani 1 1 d . . .
Cl3 Cl 0.17457(9) 0.64130(6) 0.97850(6) 0.0562(2) Uani 1 1 d . . .
C31 C 0.3286(3) 0.61361(15) 0.93599(16) 0.0311(4) Uani 1 1 d . . .
H31A H 0.3038 0.5769 0.8926 0.037 Uiso 1 1 calc R . .
H31B H 0.3933 0.5906 0.9797 0.037 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Cl1 Au1 As1 177.895(19) . .
C10 As1 C30 106.03(8) . .
C10 As1 C20 104.68(8) . .
C30 As1 C20 103.81(8) . .
C10 As1 Au1 111.16(5) . .
C30 As1 Au1 116.87(5) . .
C20 As1 Au1 113.26(6) . .
C6 C1 C2 118.14(18) . .
C6 C1 C10 118.14(17) . .
C2 C1 C10 123.70(17) . .
C3 C2 C1 120.74(19) . .
C3 C2 H2A 119.6 . .
C1 C2 H2A 119.6 . .
C2 C3 C4 120.7(2) . .
C2 C3 H3A 119.6 . .
C4 C3 H3A 119.6 . .
C5 C4 C3 120.18(19) . .
C5 C4 H4A 119.9 . .
C3 C4 H4A 119.9 . .
C4 C5 C6 120.5(2) . .
C4 C5 H5A 119.7 . .
C6 C5 H5A 119.7 . .
C7 C6 C5 120.75(19) . .
C7 C6 C1 119.58(19) . .
C5 C6 C1 119.64(19) . .
C8 C7 C6 121.29(19) . .
C8 C7 H7A 119.4 . .
C6 C7 H7A 119.4 . .
C7 C8 C9 119.76(19) . .
C7 C8 H8A 120.1 . .
C9 C8 H8A 120.1 . .
C10 C9 C8 120.71(19) . .
C10 C9 H9A 119.6 . .
C8 C9 H9A 119.6 . .
C9 C10 C1 120.51(17) . .
C9 C10 As1 118.95(14) . .
C1 C10 As1 120.17(13) . .
C12 C11 C16 118.15(19) . .
C12 C11 C20 124.18(18) . .
C16 C11 C20 117.68(18) . .
C13 C12 C11 120.5(2) . .
C13 C12 H12A 119.7 . .
C11 C12 H12A 119.7 . .
C12 C13 C14 121.0(2) . .
C12 C13 H13A 119.5 . .
C14 C13 H13A 119.5 . .
C15 C14 C13 119.8(2) . .
C15 C14 H14A 120.1 . .
C13 C14 H14A 120.1 . .
C14 C15 C16 120.9(2) . .
C14 C15 H15A 119.5 . .
C16 C15 H15A 119.5 . .
C15 C16 C17 120.85(19) . .
C15 C16 C11 119.5(2) . .
C17 C16 C11 119.64(19) . .
C18 C17 C16 121.08(18) . .
C18 C17 H17A 119.5 . .
C16 C17 H17A 119.5 . .
C17 C18 C19 119.67(19) . .
C17 C18 H18A 120.2 . .
C19 C18 H18A 120.2 . .
C20 C19 C18 120.88(19) . .
C20 C19 H19A 119.6 . .
C18 C19 H19A 119.6 . .
C19 C20 C11 121.04(17) . .
C19 C20 As1 118.42(14) . .
C11 C20 As1 120.50(14) . .
C22 C21 C26 118.34(18) . .
C22 C21 C30 123.80(18) . .
C26 C21 C30 117.86(17) . .
C23 C22 C21 120.81(19) . .
C23 C22 H22A 119.6 . .
C21 C22 H22A 119.6 . .
C22 C23 C24 120.6(2) . .
C22 C23 H23A 119.7 . .
C24 C23 H23A 119.7 . .
C25 C24 C23 120.17(19) . .
C25 C24 H24A 119.9 . .
C23 C24 H24A 119.9 . .
C24 C25 C26 120.8(2) . .
C24 C25 H25A 119.6 . .
C26 C25 H25A 119.6 . .
C27 C26 C25 121.35(19) . .
C27 C26 C21 119.46(18) . .
C25 C26 C21 119.19(19) . .
C28 C27 C26 121.2(2) . .
C28 C27 H27A 119.4 . .
C26 C27 H27A 119.4 . .
C27 C28 C29 120.1(2) . .
C27 C28 H28A 120.0 . .
C29 C28 H28A 120.0 . .
C30 C29 C28 120.13(19) . .
C30 C29 H29A 119.9 . .
C28 C29 H29A 119.9 . .
C29 C30 C21 121.26(18) . .
C29 C30 As1 118.81(15) . .
C21 C30 As1 119.93(14) . .
Cl3 C31 Cl2 112.28(15) . .
Cl3 C31 H31A 109.1 . .
Cl2 C31 H31A 109.1 . .
Cl3 C31 H31B 109.1 . .
Cl2 C31 H31B 109.1 . .
H31A C31 H31B 107.9 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 Cl1 2.2707(5) .
Au1 As1 2.34024(19) .
As1 C10 1.9336(18) .
As1 C30 1.938(2) .
As1 C20 1.9382(19) .
C1 C6 1.424(3) .
C1 C2 1.425(3) .
C1 C10 1.432(3) .
C2 C3 1.375(3) .
C2 H2A 0.9300 .
C3 C4 1.408(3) .
C3 H3A 0.9300 .
C4 C5 1.371(3) .
C4 H4A 0.9300 .
C5 C6 1.422(3) .
C5 H5A 0.9300 .
C6 C7 1.416(3) .
C7 C8 1.363(3) .
C7 H7A 0.9300 .
C8 C9 1.419(3) .
C8 H8A 0.9300 .
C9 C10 1.377(3) .
C9 H9A 0.9300 .
C11 C12 1.421(3) .
C11 C16 1.425(3) .
C11 C20 1.429(3) .
C12 C13 1.372(3) .
C12 H12A 0.9300 .
C13 C14 1.402(4) .
C13 H13A 0.9300 .
C14 C15 1.370(4) .
C14 H14A 0.9300 .
C15 C16 1.410(3) .
C15 H15A 0.9300 .
C16 C17 1.425(3) .
C17 C18 1.361(3) .
C17 H17A 0.9300 .
C18 C19 1.417(3) .
C18 H18A 0.9300 .
C19 C20 1.370(3) .
C19 H19A 0.9300 .
C21 C22 1.425(3) .
C21 C26 1.430(3) .
C21 C30 1.431(3) .
C22 C23 1.374(3) .
C22 H22A 0.9300 .
C23 C24 1.408(3) .
C23 H23A 0.9300 .
C24 C25 1.374(3) .
C24 H24A 0.9300 .
C25 C26 1.420(3) .
C25 H25A 0.9300 .
C26 C27 1.418(3) .
C27 C28 1.371(3) .
C27 H27A 0.9300 .
C28 C29 1.417(3) .
C28 H28A 0.9300 .
C29 C30 1.377(3) .
C29 H29A 0.9300 .
Cl2 C31 1.754(3) .
Cl3 C31 1.751(3) .
C31 H31A 0.9700 .
C31 H31B 0.9700 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
C31 H31B Cl1 0.9700 2.7400 3.535(3) 140.00 3_667 yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
Cl1 Au1 As1 C10 -68.4(4) . . . .
Cl1 Au1 As1 C30 169.7(4) . . . .
Cl1 Au1 As1 C20 49.1(4) . . . .
C6 C1 C2 C3 -2.6(3) . . . .
C10 C1 C2 C3 175.5(2) . . . .
C1 C2 C3 C4 2.2(3) . . . .
C2 C3 C4 C5 -0.2(3) . . . .
C3 C4 C5 C6 -1.3(3) . . . .
C4 C5 C6 C7 -177.4(2) . . . .
C4 C5 C6 C1 0.8(3) . . . .
C2 C1 C6 C7 179.28(19) . . . .
C10 C1 C6 C7 1.1(3) . . . .
C2 C1 C6 C5 1.1(3) . . . .
C10 C1 C6 C5 -177.06(18) . . . .
C5 C6 C7 C8 177.5(2) . . . .
C1 C6 C7 C8 -0.6(3) . . . .
C6 C7 C8 C9 -0.4(3) . . . .
C7 C8 C9 C10 1.0(3) . . . .
C8 C9 C10 C1 -0.5(3) . . . .
C8 C9 C10 As1 -173.54(15) . . . .
C6 C1 C10 C9 -0.6(3) . . . .
C2 C1 C10 C9 -178.60(19) . . . .
C6 C1 C10 As1 172.37(14) . . . .
C2 C1 C10 As1 -5.6(3) . . . .
C30 As1 C10 C9 -107.57(16) . . . .
C20 As1 C10 C9 1.82(17) . . . .
Au1 As1 C10 C9 124.45(14) . . . .
C30 As1 C10 C1 79.37(16) . . . .
C20 As1 C10 C1 -171.24(15) . . . .
Au1 As1 C10 C1 -48.61(16) . . . .
C16 C11 C12 C13 -2.4(3) . . . .
C20 C11 C12 C13 177.4(2) . . . .
C11 C12 C13 C14 2.0(4) . . . .
C12 C13 C14 C15 0.3(4) . . . .
C13 C14 C15 C16 -2.2(4) . . . .
C14 C15 C16 C17 -176.7(2) . . . .
C14 C15 C16 C11 1.8(3) . . . .
C12 C11 C16 C15 0.5(3) . . . .
C20 C11 C16 C15 -179.26(19) . . . .
C12 C11 C16 C17 179.03(19) . . . .
C20 C11 C16 C17 -0.7(3) . . . .
C15 C16 C17 C18 178.4(2) . . . .
C11 C16 C17 C18 -0.1(3) . . . .
C16 C17 C18 C19 0.6(3) . . . .
C17 C18 C19 C20 -0.2(3) . . . .
C18 C19 C20 C11 -0.7(3) . . . .
C18 C19 C20 As1 -178.51(15) . . . .
C12 C11 C20 C19 -178.57(19) . . . .
C16 C11 C20 C19 1.2(3) . . . .
C12 C11 C20 As1 -0.9(3) . . . .
C16 C11 C20 As1 178.89(14) . . . .
C10 As1 C20 C19 -106.46(16) . . . .
C30 As1 C20 C19 4.53(17) . . . .
Au1 As1 C20 C19 132.29(14) . . . .
C10 As1 C20 C11 75.77(16) . . . .
C30 As1 C20 C11 -173.24(15) . . . .
Au1 As1 C20 C11 -45.48(16) . . . .
C26 C21 C22 C23 -2.3(3) . . . .
C30 C21 C22 C23 177.97(18) . . . .
C21 C22 C23 C24 1.4(3) . . . .
C22 C23 C24 C25 0.3(3) . . . .
C23 C24 C25 C26 -1.0(3) . . . .
C24 C25 C26 C27 -179.51(19) . . . .
C24 C25 C26 C21 0.0(3) . . . .
C22 C21 C26 C27 -178.90(17) . . . .
C30 C21 C26 C27 0.9(3) . . . .
C22 C21 C26 C25 1.6(3) . . . .
C30 C21 C26 C25 -178.65(17) . . . .
C25 C26 C27 C28 179.3(2) . . . .
C21 C26 C27 C28 -0.2(3) . . . .
C26 C27 C28 C29 -0.7(3) . . . .
C27 C28 C29 C30 0.9(3) . . . .
C28 C29 C30 C21 -0.2(3) . . . .
C28 C29 C30 As1 179.93(15) . . . .
C22 C21 C30 C29 179.10(18) . . . .
C26 C21 C30 C29 -0.7(3) . . . .
C22 C21 C30 As1 -1.1(2) . . . .
C26 C21 C30 As1 179.17(13) . . . .
C10 As1 C30 C29 6.09(17) . . . .
C20 As1 C30 C29 -103.91(16) . . . .
Au1 As1 C30 C29 130.60(13) . . . .
C10 As1 C30 C21 -173.74(14) . . . .
C20 As1 C30 C21 76.26(15) . . . .
Au1 As1 C30 C21 -49.23(16) . . . .
