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Information card for entry 1549755
Preview
| Coordinates | 1549755.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C15 H6 Al F27 O6 |
|---|---|
| Calculated formula | C15 H6 Al F27 O6 |
| SMILES | [Al](OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)(OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)(OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)[O]=C(OC)OC |
| Title of publication | Facile and systematic access to the least-coordinating WCA [(R<sup>F</sup>O)<sub>3</sub>Al-F-Al(OR<sup>F</sup>)<sub>3</sub>]<sup>-</sup> and its more Lewis-basic brother [F-Al(OR<sup>F</sup>)<sub>3</sub>]<sup>-</sup> (R<sup>F</sup> = C(CF<sub>3</sub>)<sub>3</sub>). |
| Authors of publication | Martens, Arthur; Weis, Philippe; Krummer, Michael Christian; Kreuzer, Marvin; Meierhöfer, Andreas; Meier, Stefan C.; Bohnenberger, Jan; Scherer, Harald; Riddlestone, Ian; Krossing, Ingo |
| Journal of publication | Chemical science |
| Year of publication | 2018 |
| Journal volume | 9 |
| Journal issue | 35 |
| Pages of publication | 7058 - 7068 |
| a | 10.8066 ± 0.0003 Å |
| b | 13.958 ± 0.0004 Å |
| c | 17.2977 ± 0.0005 Å |
| α | 90° |
| β | 90.19 ± 0.002° |
| γ | 90° |
| Cell volume | 2609.15 ± 0.13 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0721 |
| Residual factor for significantly intense reflections | 0.0429 |
| Weighted residual factors for significantly intense reflections | 0.0991 |
| Weighted residual factors for all reflections included in the refinement | 0.1161 |
| Goodness-of-fit parameter for all reflections included in the refinement | 0.931 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 228840 (current) | 2019-11-17 | cif/ Updating files of 1549751, 1549752, 1549753, 1549754, 1549755, 1549756, 1549757, 1549758, 1549759, 1549760 Original log message: Adding full bibliography for 1549751--1549760.cif. |
1549755.cif |
| 209346 | 2018-08-02 | cif/ Adding structures of 1549751, 1549752, 1549753, 1549754, 1549755, 1549756, 1549757, 1549758, 1549759, 1549760 via cif-deposit CGI script. |
1549755.cif |
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Users of the data should acknowledge the original authors of the
structural data.