Crystallography Open Database

Information card for entry 1560038

Preview

Coordinates	1560038.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C48 H58 N4 Si2
Calculated formula	C48 H58 N4 Si2
Title of publication	Boosting homogeneous chemoselective hydrogenation of olefins mediated by a bis(silylenyl)terphenyl-nickel(0) pre-catalyst
Authors of publication	Lücke, Marcel-Philip; Yao, Shenglai; Driess, Matthias
Journal of publication	Chemical Science
Year of publication	2021
Journal volume	12
Journal issue	8
Pages of publication	2909 - 2915
a	25.072 ± 0.0015 Å
b	9.1667 ± 0.0004 Å
c	19.7603 ± 0.0011 Å
α	90°
β	99.889 ± 0.006°
γ	90°
Cell volume	4474 ± 0.4 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	4
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.1185
Residual factor for significantly intense reflections	0.0632
Weighted residual factors for significantly intense reflections	0.1412
Weighted residual factors for all reflections included in the refinement	0.1746
Goodness-of-fit parameter for all reflections included in the refinement	1.023
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
263682 (current)	2021-04-05	cif/ Updating files of 1560037, 1560038, 1560039, 1560040 Original log message: Adding full bibliography for 1560037--1560040.cif.	1560038.cif
260900	2021-01-12	cif/ Adding structures of 1560037, 1560038, 1560039, 1560040 via cif-deposit CGI script.	1560038.cif