#------------------------------------------------------------------------------
#$Date: 2021-04-26 11:42:13 +0300 (Mon, 26 Apr 2021) $
#$Revision: 264535 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/20/1562099.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1562099
loop_
_publ_author_name
'Li, Cheng-Peng'
'Chen, Jing'
'Guo, Wei'
'Du, Miao'
_publ_section_title
;
 Anion-directed assembly and crystal transformation of Ag(I) coordination
 polymers with a versatile tripyridyltriazole ligand
 3,4-bis(2-pyridyl)-5-(4-pyridyl)-1,2,4-triazole
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              95
_journal_page_last               103
_journal_paper_doi               10.1016/j.jssc.2014.06.038
_journal_volume                  223
_journal_year                    2015
_chemical_formula_sum            'C21 H16 Ag2 F6 N6 O6'
_chemical_formula_weight         778.14
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.398(6)
_cell_angle_beta                 94.772(7)
_cell_angle_gamma                91.577(6)
_cell_formula_units_Z            2
_cell_length_a                   9.711(4)
_cell_length_b                   10.574(4)
_cell_length_c                   12.856(5)
_cell_measurement_reflns_used    3812
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      30.26
_cell_measurement_theta_min      2.55
_cell_volume                     1272.6(9)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0206
_diffrn_reflns_av_sigmaI/netI    0.0375
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            6221
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.99
_exptl_absorpt_coefficient_mu    1.633
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.619680
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            COLORLESS
_exptl_crystal_density_diffrn    2.031
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       BLOCK
_exptl_crystal_F_000             760
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.26
_refine_diff_density_max         0.787
_refine_diff_density_min         -0.811
_refine_diff_density_rms         0.106
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     398
_refine_ls_number_reflns         4463
_refine_ls_number_restraints     48
_refine_ls_restrained_S_all      1.122
_refine_ls_R_factor_all          0.0488
_refine_ls_R_factor_gt           0.0418
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0370P)²+3.7316P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0921
_refine_ls_wR_factor_ref         0.0964
_reflns_number_gt                3847
_reflns_number_total             4463
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2015-223-95.cif
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'MULTI-SCAN' was
changed to 'multi-scan' in accordance with the built-in table derived
from the CIF Core dictionary named 'cif_core.dic' version 2.4.5 last
updated on 2014-11-21.

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

data item '_exptl_crystal_density_meas' value 'NONE' was changed to
'?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               1562099
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
O5 O 0.9284(5) 0.6751(6) 0.5125(5) 0.0914(19) Uani 1 1 d . . .
Ag2 Ag 0.65993(5) 0.68020(4) 0.53314(3) 0.03939(14) Uani 1 1 d . . .
Ag1 Ag 0.62527(4) 0.33530(4) 0.35642(3) 0.03570(13) Uani 1 1 d . . .
F1 F 0.6971(6) 0.7634(6) 0.1915(6) 0.124(2) Uani 1 1 d . . .
F2 F 0.8154(10) 0.6052(6) 0.1270(5) 0.173(4) Uani 1 1 d . . .
F3 F 0.8849(6) 0.7349(7) 0.2678(6) 0.137(3) Uani 1 1 d . . .
F4 F 0.9676(13) -0.0491(8) 0.2077(13) 0.084(5) Uani 0.395(15) 1 d PDU A 1
F5 F 1.0831(12) 0.1268(14) 0.2689(11) 0.068(4) Uani 0.395(15) 1 d PDU A 1
F6 F 0.9691(13) 0.0863(16) 0.1189(7) 0.089(5) Uani 0.395(15) 1 d PDU A 1
F4' F 1.0030(9) -0.0047(10) 0.2887(9) 0.108(4) Uani 0.605(15) 1 d PDU A 2
F5' F 1.0729(10) 0.1592(9) 0.2452(9) 0.079(3) Uani 0.605(15) 1 d PDU A 2
F6' F 0.9689(10) 0.0025(12) 0.1296(7) 0.120(4) Uani 0.605(15) 1 d PDU A 2
O1 O 0.6249(4) 0.6510(5) 0.3432(3) 0.0568(11) Uani 1 1 d . . .
O2 O 0.7414(5) 0.4784(4) 0.2679(4) 0.0591(11) Uani 1 1 d . . .
O3 O 0.8448(5) 0.2221(5) 0.3416(4) 0.0674(13) Uani 1 1 d . . .
O4 O 0.7316(6) 0.0911(7) 0.1991(6) 0.110(2) Uani 1 1 d . . .
H5A H 0.9993 0.7041 0.5565 0.165 Uiso 1 1 d R . .
H5B H 0.9429 0.6322 0.4495 0.165 Uiso 1 1 d R . .
O6 O 0.0341(5) 0.4964(5) 0.3324(5) 0.0836(16) Uani 1 1 d . . .
H6A H 0.0275 0.4532 0.3799 0.125 Uiso 1 1 d R . .
H6B H -0.0363 0.4893 0.2873 0.125 Uiso 1 1 d R . .
N1 N 0.6619(4) -0.1017(4) 0.5644(3) 0.0343(10) Uani 1 1 d . . .
N2 N 0.6522(4) 0.3780(3) 0.5449(3) 0.0261(8) Uani 1 1 d . . .
N3 N 0.6469(4) 0.5086(3) 0.6000(3) 0.0267(8) Uani 1 1 d . . .
N4 N 0.6756(4) 0.3928(3) 0.7187(3) 0.0248(8) Uani 1 1 d . . .
N5 N 0.5643(4) 0.7201(4) 0.7774(3) 0.0307(9) Uani 1 1 d . . .
N6 N 0.5960(5) 0.3970(4) 0.8855(3) 0.0393(10) Uani 1 1 d . . .
C1 C 0.7574(5) 0.0945(5) 0.5332(4) 0.0370(12) Uani 1 1 d . . .
H1 H 0.8213 0.1345 0.5001 0.044 Uiso 1 1 calc R . .
C2 C 0.7516(6) -0.0393(5) 0.5191(4) 0.0391(12) Uani 1 1 d . . .
H2 H 0.8133 -0.0883 0.4759 0.047 Uiso 1 1 calc R . .
C3 C 0.5729(5) -0.0299(5) 0.6250(4) 0.0352(11) Uani 1 1 d . . .
H3 H 0.5083 -0.0722 0.6558 0.042 Uiso 1 1 calc R . .
C4 C 0.5728(5) 0.1037(5) 0.6438(4) 0.0329(11) Uani 1 1 d . . .
H4 H 0.5100 0.1505 0.6872 0.039 Uiso 1 1 calc R . .
C5 C 0.6667(5) 0.1676(4) 0.5974(4) 0.0264(10) Uani 1 1 d . . .
C6 C 0.6680(5) 0.3118(4) 0.6172(4) 0.0251(10) Uani 1 1 d . . .
C7 C 0.6596(4) 0.5146(4) 0.7032(4) 0.0247(9) Uani 1 1 d . . .
C8 C 0.6632(5) 0.6373(4) 0.7894(4) 0.0268(10) Uani 1 1 d . . .
C9 C 0.7662(5) 0.6635(5) 0.8741(4) 0.0369(12) Uani 1 1 d . . .
H9 H 0.8329 0.6034 0.8793 0.044 Uiso 1 1 calc R . .
C10 C 0.7674(6) 0.7815(5) 0.9508(4) 0.0445(13) Uani 1 1 d . . .
H10 H 0.8353 0.8026 1.0086 0.053 Uiso 1 1 calc R . .
C11 C 0.6668(6) 0.8667(5) 0.9400(4) 0.0455(14) Uani 1 1 d . . .
H11 H 0.6650 0.9462 0.9910 0.055 Uiso 1 1 calc R . .
C12 C 0.5684(6) 0.8336(5) 0.8531(4) 0.0420(13) Uani 1 1 d . . .
H12 H 0.5013 0.8930 0.8465 0.050 Uiso 1 1 calc R . .
C13 C 0.6915(5) 0.3563(4) 0.8198(4) 0.0267(10) Uani 1 1 d . . .
C14 C 0.7990(6) 0.2819(6) 0.8395(4) 0.0426(13) Uani 1 1 d . . .
H14 H 0.8641 0.2570 0.7902 0.051 Uiso 1 1 calc R . .
C15 C 0.8070(7) 0.2452(7) 0.9358(5) 0.0553(16) Uani 1 1 d . . .
H15 H 0.8775 0.1936 0.9523 0.066 Uiso 1 1 calc R . .
C16 C 0.7094(7) 0.2858(6) 1.0067(5) 0.0550(16) Uani 1 1 d . . .
H16 H 0.7120 0.2621 1.0718 0.066 Uiso 1 1 calc R . .
C17 C 0.6084(7) 0.3620(6) 0.9789(5) 0.0524(16) Uani 1 1 d . . .
H17 H 0.5441 0.3914 1.0281 0.063 Uiso 1 1 calc R . .
C18 C 0.7050(6) 0.5913(6) 0.2814(4) 0.0406(13) Uani 1 1 d . . .
C19 C 0.7725(7) 0.6703(7) 0.2139(6) 0.0622(18) Uani 1 1 d . . .
C20 C 0.8334(6) 0.1355(6) 0.2584(5) 0.0486(14) Uani 1 1 d . A .
C21 C 0.9671(6) 0.0748(5) 0.2230(5) 0.0618(18) Uani 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
H5A O5 H5B 116.9 . .
N3 Ag2 N1 147.28(14) . 1_565
N3 Ag2 O1 119.23(15) . .
N1 Ag2 O1 92.51(16) 1_565 .
N3 Ag2 Ag1 68.37(10) . 2_666
N1 Ag2 Ag1 93.08(11) 1_565 2_666
O1 Ag2 Ag1 113.07(10) . 2_666
N2 Ag1 N5 135.16(14) . 2_666
N2 Ag1 O2 119.55(15) . .
N5 Ag1 O2 94.44(16) 2_666 .
N2 Ag1 O3 91.44(14) . .
N5 Ag1 O3 122.99(15) 2_666 .
O2 Ag1 O3 83.17(17) . .
N2 Ag1 Ag2 65.48(10) . 2_666
N5 Ag1 Ag2 69.69(10) 2_666 2_666
O2 Ag1 Ag2 138.42(11) . 2_666
O3 Ag1 Ag2 138.01(13) . 2_666
C18 O1 Ag2 122.2(4) . .
C18 O2 Ag1 118.4(4) . .
C20 O3 Ag1 108.2(4) . .
H6A O6 H6B 115.1 . .
C2 N1 C3 117.6(4) . .
C2 N1 Ag2 119.9(3) . 1_545
C3 N1 Ag2 122.5(3) . 1_545
C6 N2 N3 106.9(4) . .
C6 N2 Ag1 137.6(3) . .
N3 N2 Ag1 115.5(3) . .
C7 N3 N2 107.5(4) . .
C7 N3 Ag2 124.0(3) . .
N2 N3 Ag2 127.3(3) . .
C7 N4 C6 104.8(4) . .
C7 N4 C13 127.7(4) . .
C6 N4 C13 127.4(4) . .
C12 N5 C8 116.5(4) . .
C12 N5 Ag1 119.8(3) . 2_666
C8 N5 Ag1 123.3(3) . 2_666
C13 N6 C17 115.8(5) . .
C5 C1 C2 118.6(5) . .
C5 C1 H1 120.7 . .
C2 C1 H1 120.7 . .
N1 C2 C1 123.2(5) . .
N1 C2 H2 118.4 . .
C1 C2 H2 118.4 . .
N1 C3 C4 122.8(5) . .
N1 C3 H3 118.6 . .
C4 C3 H3 118.6 . .
C3 C4 C5 119.3(5) . .
C3 C4 H4 120.4 . .
C5 C4 H4 120.4 . .
C1 C5 C4 118.5(4) . .
C1 C5 C6 121.6(4) . .
C4 C5 C6 119.8(4) . .
N2 C6 N4 110.8(4) . .
N2 C6 C5 126.7(4) . .
N4 C6 C5 122.4(4) . .
N3 C7 N4 110.0(4) . .
N3 C7 C8 124.3(4) . .
N4 C7 C8 125.6(4) . .
N5 C8 C9 123.7(4) . .
N5 C8 C7 115.7(4) . .
C9 C8 C7 120.6(4) . .
C10 C9 C8 118.3(5) . .
C10 C9 H9 120.9 . .
C8 C9 H9 120.9 . .
C11 C10 C9 118.8(5) . .
C11 C10 H10 120.6 . .
C9 C10 H10 120.6 . .
C10 C11 C12 119.4(5) . .
C10 C11 H11 120.3 . .
C12 C11 H11 120.3 . .
N5 C12 C11 123.3(5) . .
N5 C12 H12 118.3 . .
C11 C12 H12 118.3 . .
N6 C13 C14 125.3(5) . .
N6 C13 N4 115.2(4) . .
C14 C13 N4 119.5(4) . .
C13 C14 C15 117.4(5) . .
C13 C14 H14 121.3 . .
C15 C14 H14 121.3 . .
C16 C15 C14 119.1(5) . .
C16 C15 H15 120.4 . .
C14 C15 H15 120.4 . .
C17 C16 C15 118.1(5) . .
C17 C16 H16 120.9 . .
C15 C16 H16 120.9 . .
N6 C17 C16 124.3(5) . .
N6 C17 H17 117.9 . .
C16 C17 H17 117.9 . .
O2 C18 O1 129.9(6) . .
O2 C18 C19 115.0(5) . .
O1 C18 C19 115.1(6) . .
F2 C19 F1 108.1(8) . .
F2 C19 F3 103.5(7) . .
F1 C19 F3 103.1(7) . .
F2 C19 C18 116.1(6) . .
F1 C19 C18 114.4(6) . .
F3 C19 C18 110.3(6) . .
O4 C20 O3 129.6(7) . .
O4 C20 C21 114.8(6) . .
O3 C20 C21 115.6(6) . .
F6' C21 F5 116.0(10) . .
F6' C21 F4 59.5(6) . .
F5 C21 F4 110.0(8) . .
F6' C21 F5' 110.1(7) . .
F4 C21 F5' 128.1(9) . .
F6' C21 F4' 104.0(7) . .
F5 C21 F4' 78.0(8) . .
F4 C21 F4' 46.9(6) . .
F5' C21 F4' 101.1(7) . .
F5 C21 F6 103.7(8) . .
F4 C21 F6 100.6(7) . .
F5' C21 F6 85.4(8) . .
F4' C21 F6 142.7(8) . .
F6' C21 C20 119.5(7) . .
F5 C21 C20 120.5(8) . .
F4 C21 C20 115.2(7) . .
F5' C21 C20 112.9(7) . .
F4' C21 C20 107.0(6) . .
F6 C21 C20 103.8(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
O5 H5A 0.8512 .
O5 H5B 0.8494 .
Ag2 N3 2.198(4) .
Ag2 N1 2.239(4) 1_565
Ag2 O1 2.378(4) .
Ag2 Ag1 3.2341(12) 2_666
Ag1 N2 2.343(4) .
Ag1 N5 2.367(4) 2_666
Ag1 O2 2.415(4) .
Ag1 O3 2.471(4) .
Ag1 Ag2 3.2341(12) 2_666
F1 C19 1.317(8) .
F2 C19 1.267(8) .
F3 C19 1.318(9) .
F4 C21 1.276(8) .
F5 C21 1.270(9) .
F6 C21 1.375(8) .
F4' C21 1.364(8) .
F5' C21 1.307(8) .
F6' C21 1.255(7) .
O1 C18 1.230(7) .
O2 C18 1.229(7) .
O3 C20 1.218(7) .
O4 C20 1.204(8) .
O6 H6A 0.8538 .
O6 H6B 0.8477 .
N1 C2 1.334(7) .
N1 C3 1.335(6) .
N1 Ag2 2.239(4) 1_545
N2 C6 1.298(6) .
N2 N3 1.391(5) .
N3 C7 1.308(6) .
N4 C7 1.362(6) .
N4 C6 1.366(6) .
N4 C13 1.442(6) .
N5 C12 1.342(6) .
N5 C8 1.342(6) .
N5 Ag1 2.367(4) 2_666
N6 C13 1.316(6) .
N6 C17 1.339(7) .
C1 C5 1.377(7) .
C1 C2 1.380(7) .
C1 H1 0.9300 .
C2 H2 0.9300 .
C3 C4 1.373(7) .
C3 H3 0.9300 .
C4 C5 1.379(7) .
C4 H4 0.9300 .
C5 C6 1.481(6) .
C7 C8 1.480(6) .
C8 C9 1.384(7) .
C9 C10 1.384(7) .
C9 H9 0.9300 .
C10 C11 1.368(8) .
C10 H10 0.9300 .
C11 C12 1.376(8) .
C11 H11 0.9300 .
C12 H12 0.9300 .
C13 C14 1.369(7) .
C14 C15 1.383(8) .
C14 H14 0.9300 .
C15 C16 1.373(9) .
C15 H15 0.9300 .
C16 C17 1.366(8) .
C16 H16 0.9300 .
C17 H17 0.9300 .
C18 C19 1.518(9) .
C20 C21 1.517(8) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
N3 Ag2 O1 C18 -65.8(5) . . . .
N1 Ag2 O1 C18 122.5(5) 1_565 . . .
Ag1 Ag2 O1 C18 -143.0(4) 2_666 . . .
N2 Ag1 O2 C18 -66.9(5) . . . .
N5 Ag1 O2 C18 82.6(4) 2_666 . . .
O3 Ag1 O2 C18 -154.6(5) . . . .
Ag2 Ag1 O2 C18 18.6(5) 2_666 . . .
N2 Ag1 O3 C20 147.6(4) . . . .
N5 Ag1 O3 C20 -1.9(5) 2_666 . . .
O2 Ag1 O3 C20 -92.8(5) . . . .
Ag2 Ag1 O3 C20 94.0(4) 2_666 . . .
N5 Ag1 N2 C6 85.9(5) 2_666 . . .
O2 Ag1 N2 C6 -140.0(4) . . . .
O3 Ag1 N2 C6 -57.1(5) . . . .
Ag2 Ag1 N2 C6 86.6(5) 2_666 . . .
N5 Ag1 N2 N3 -91.8(3) 2_666 . . .
O2 Ag1 N2 N3 42.4(3) . . . .
O3 Ag1 N2 N3 125.3(3) . . . .
Ag2 Ag1 N2 N3 -91.0(3) 2_666 . . .
C6 N2 N3 C7 -0.1(5) . . . .
Ag1 N2 N3 C7 178.3(3) . . . .
C6 N2 N3 Ag2 167.8(3) . . . .
Ag1 N2 N3 Ag2 -13.9(4) . . . .
N1 Ag2 N3 C7 -13.0(5) 1_565 . . .
O1 Ag2 N3 C7 -177.5(3) . . . .
Ag1 Ag2 N3 C7 -72.4(3) 2_666 . . .
N1 Ag2 N3 N2 -179.1(3) 1_565 . . .
O1 Ag2 N3 N2 16.5(4) . . . .
Ag1 Ag2 N3 N2 121.6(4) 2_666 . . .
C3 N1 C2 C1 0.9(8) . . . .
Ag2 N1 C2 C1 178.9(4) 1_545 . . .
C5 C1 C2 N1 0.2(9) . . . .
C2 N1 C3 C4 -1.5(8) . . . .
Ag2 N1 C3 C4 -179.4(4) 1_545 . . .
N1 C3 C4 C5 0.9(8) . . . .
C2 C1 C5 C4 -0.8(8) . . . .
C2 C1 C5 C6 179.3(5) . . . .
C3 C4 C5 C1 0.3(7) . . . .
C3 C4 C5 C6 -179.8(5) . . . .
N3 N2 C6 N4 -0.9(5) . . . .
Ag1 N2 C6 N4 -178.7(3) . . . .
N3 N2 C6 C5 174.2(4) . . . .
Ag1 N2 C6 C5 -3.6(8) . . . .
C7 N4 C6 N2 1.5(5) . . . .
C13 N4 C6 N2 179.3(4) . . . .
C7 N4 C6 C5 -173.8(4) . . . .
C13 N4 C6 C5 3.9(7) . . . .
C1 C5 C6 N2 57.7(7) . . . .
C4 C5 C6 N2 -122.3(5) . . . .
C1 C5 C6 N4 -127.8(5) . . . .
C4 C5 C6 N4 52.3(6) . . . .
N2 N3 C7 N4 1.0(5) . . . .
Ag2 N3 C7 N4 -167.3(3) . . . .
N2 N3 C7 C8 178.1(4) . . . .
Ag2 N3 C7 C8 9.7(6) . . . .
C6 N4 C7 N3 -1.6(5) . . . .
C13 N4 C7 N3 -179.3(4) . . . .
C6 N4 C7 C8 -178.6(4) . . . .
C13 N4 C7 C8 3.7(7) . . . .
C12 N5 C8 C9 -0.1(7) . . . .
Ag1 N5 C8 C9 -172.9(4) 2_666 . . .
C12 N5 C8 C7 -178.1(4) . . . .
Ag1 N5 C8 C7 9.1(6) 2_666 . . .
N3 C7 C8 N5 47.7(6) . . . .
N4 C7 C8 N5 -135.7(5) . . . .
N3 C7 C8 C9 -130.4(5) . . . .
N4 C7 C8 C9 46.2(7) . . . .
N5 C8 C9 C10 0.1(8) . . . .
C7 C8 C9 C10 178.0(5) . . . .
C8 C9 C10 C11 0.3(8) . . . .
C9 C10 C11 C12 -0.7(9) . . . .
C8 N5 C12 C11 -0.3(8) . . . .
Ag1 N5 C12 C11 172.8(4) 2_666 . . .
C10 C11 C12 N5 0.7(9) . . . .
C17 N6 C13 C14 0.5(8) . . . .
C17 N6 C13 N4 179.0(5) . . . .
C7 N4 C13 N6 52.6(6) . . . .
C6 N4 C13 N6 -124.6(5) . . . .
C7 N4 C13 C14 -128.8(5) . . . .
C6 N4 C13 C14 54.0(7) . . . .
N6 C13 C14 C15 0.8(9) . . . .
N4 C13 C14 C15 -177.6(5) . . . .
C13 C14 C15 C16 -0.8(10) . . . .
C14 C15 C16 C17 -0.4(11) . . . .
C13 N6 C17 C16 -1.9(9) . . . .
C15 C16 C17 N6 1.9(11) . . . .
Ag1 O2 C18 O1 8.2(8) . . . .
Ag1 O2 C18 C19 -173.9(4) . . . .
Ag2 O1 C18 O2 57.9(8) . . . .
Ag2 O1 C18 C19 -120.0(5) . . . .
O2 C18 C19 F2 25.1(10) . . . .
O1 C18 C19 F2 -156.7(8) . . . .
O2 C18 C19 F1 152.1(7) . . . .
O1 C18 C19 F1 -29.7(9) . . . .
O2 C18 C19 F3 -92.2(7) . . . .
O1 C18 C19 F3 86.0(7) . . . .
Ag1 O3 C20 O4 -12.3(10) . . . .
Ag1 O3 C20 C21 167.1(4) . . . .
O4 C20 C21 F6' 12.2(12) . . . .
O3 C20 C21 F6' -167.3(9) . . . .
O4 C20 C21 F5 168.7(10) . . . .
O3 C20 C21 F5 -10.8(12) . . . .
O4 C20 C21 F4 -55.6(11) . . . .
O3 C20 C21 F4 124.9(10) . . . .
O4 C20 C21 F5' 144.2(9) . . . .
O3 C20 C21 F5' -35.3(10) . . . .
O4 C20 C21 F4' -105.4(8) . . . .
O3 C20 C21 F4' 75.1(8) . . . .
O4 C20 C21 F6 53.4(10) . . . .
O3 C20 C21 F6 -126.1(8) . . . .
