#------------------------------------------------------------------------------
#$Date: 2021-04-26 11:42:13 +0300 (Mon, 26 Apr 2021) $
#$Revision: 264535 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/21/1562100.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1562100
loop_
_publ_author_name
'Li, Cheng-Peng'
'Chen, Jing'
'Guo, Wei'
'Du, Miao'
_publ_section_title
;
 Anion-directed assembly and crystal transformation of Ag(I) coordination
 polymers with a versatile tripyridyltriazole ligand
 3,4-bis(2-pyridyl)-5-(4-pyridyl)-1,2,4-triazole
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              95
_journal_page_last               103
_journal_paper_doi               10.1016/j.jssc.2014.06.038
_journal_volume                  223
_journal_year                    2015
_chemical_formula_sum            'C34 H26 Ag2 N14 O7'
_chemical_formula_weight         958.43
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                103.658(7)
_cell_angle_beta                 92.736(6)
_cell_angle_gamma                91.166(7)
_cell_formula_units_Z            2
_cell_length_a                   10.436(4)
_cell_length_b                   13.084(6)
_cell_length_c                   13.348(5)
_cell_measurement_reflns_used    3344
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      0.00
_cell_measurement_theta_min      0.00
_cell_volume                     1768.1(12)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0172
_diffrn_reflns_av_sigmaI/netI    0.0371
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            9152
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.57
_exptl_absorpt_coefficient_mu    1.180
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.604248
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            COLORLESS
_exptl_crystal_density_diffrn    1.800
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       BLOCK
_exptl_crystal_F_000             956
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.364
_refine_diff_density_min         -0.605
_refine_diff_density_rms         0.074
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     514
_refine_ls_number_reflns         6220
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0477
_refine_ls_R_factor_gt           0.0339
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0304P)²+1.7579P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0736
_refine_ls_wR_factor_ref         0.0810
_reflns_number_gt                4921
_reflns_number_total             6220
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2015-223-95.cif
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'MULTI-SCAN' was
changed to 'multi-scan' in accordance with the built-in table derived
from the CIF Core dictionary named 'cif_core.dic' version 2.4.5 last
updated on 2014-11-21.

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

data item '_exptl_crystal_density_meas' value 'NONE' was changed to
'?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_cell_volume        1768.2(13)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               1562100
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.71870(2) 0.42092(2) 0.33728(2) 0.03902(10) Uani 1 1 d . . .
Ag2 Ag 0.64382(3) 0.58128(2) 0.17721(2) 0.04314(10) Uani 1 1 d . . .
O1 O 0.6602(4) 0.7577(3) 0.1280(3) 0.0701(10) Uani 1 1 d . . .
O2 O 0.6418(3) 0.9256(3) 0.1799(3) 0.0826(12) Uani 1 1 d . . .
O3 O 0.5227(3) 0.8216(3) 0.2390(3) 0.0786(11) Uani 1 1 d . . .
O4 O 0.0752(4) 0.8018(3) 0.2858(3) 0.0915(12) Uani 1 1 d . . .
O5 O 0.0545(4) 0.9668(3) 0.3279(4) 0.0968(13) Uani 1 1 d . . .
O6 O 0.2025(4) 0.9019(4) 0.2309(3) 0.1104(16) Uani 1 1 d . . .
O7 O 0.4135(4) 0.0524(3) 0.2651(3) 0.0989(13) Uani 1 1 d . . .
H7A H 0.3482 0.0106 0.2539 0.148 Uiso 1 1 d R . .
H7B H 0.4860 0.0242 0.2663 0.148 Uiso 1 1 d R . .
N1 N 0.6602(3) 0.3075(2) 0.1726(2) 0.0364(7) Uani 1 1 d . . .
N2 N 0.8219(3) 0.4836(2) 0.1307(2) 0.0293(6) Uani 1 1 d . . .
N3 N 0.9420(3) 0.5326(2) 0.1351(2) 0.0311(7) Uani 1 1 d . . .
N4 N 0.9645(3) 0.3611(2) 0.0872(2) 0.0287(6) Uani 1 1 d . . .
N5 N 1.4302(3) 0.5405(2) 0.1318(2) 0.0364(7) Uani 1 1 d . . .
N6 N 1.0352(4) 0.2173(3) 0.1468(3) 0.0637(11) Uani 1 1 d . . .
N7 N 0.6999(3) 0.6921(2) 0.3499(2) 0.0394(8) Uani 1 1 d . . .
N8 N 0.5388(3) 0.5123(2) 0.3746(2) 0.0330(7) Uani 1 1 d . . .
N9 N 0.4203(3) 0.4622(2) 0.3631(2) 0.0322(7) Uani 1 1 d . . .
N10 N 0.3993(3) 0.6311(2) 0.4328(2) 0.0286(6) Uani 1 1 d . . .
N11 N -0.0668(3) 0.4584(3) 0.3656(2) 0.0352(7) Uani 1 1 d . . .
N12 N 0.2981(3) 0.7308(2) 0.5763(2) 0.0384(7) Uani 1 1 d . . .
N13 N 0.6092(3) 0.8347(3) 0.1824(3) 0.0519(9) Uani 1 1 d . . .
N14 N 0.1104(4) 0.8907(3) 0.2814(3) 0.0526(9) Uani 1 1 d . . .
C1 C 0.5634(4) 0.2364(3) 0.1641(3) 0.0495(11) Uani 1 1 d . . .
H1 H 0.5119 0.2408 0.2198 0.059 Uiso 1 1 calc R . .
C2 C 0.5367(4) 0.1575(3) 0.0768(4) 0.0530(11) Uani 1 1 d . . .
H2 H 0.4676 0.1106 0.0737 0.064 Uiso 1 1 calc R . .
C3 C 0.6126(4) 0.1486(3) -0.0058(3) 0.0489(11) Uani 1 1 d . . .
H3 H 0.5969 0.0949 -0.0649 0.059 Uiso 1 1 calc R . .
C4 C 0.7132(4) 0.2209(3) 0.0004(3) 0.0391(9) Uani 1 1 d . . .
H4 H 0.7658 0.2172 -0.0546 0.047 Uiso 1 1 calc R . .
C5 C 0.7338(3) 0.2994(3) 0.0910(3) 0.0305(8) Uani 1 1 d . . .
C6 C 0.8368(3) 0.3811(3) 0.1029(2) 0.0279(7) Uani 1 1 d . . .
C7 C 1.0263(3) 0.4593(3) 0.1104(3) 0.0278(8) Uani 1 1 d . . .
C8 C 1.1662(3) 0.4824(3) 0.1129(3) 0.0285(8) Uani 1 1 d . . .
C9 C 1.2083(3) 0.5862(3) 0.1561(3) 0.0339(8) Uani 1 1 d . . .
H9 H 1.1497 0.6379 0.1799 0.041 Uiso 1 1 calc R . .
C10 C 1.3398(3) 0.6111(3) 0.1631(3) 0.0375(9) Uani 1 1 d . . .
H10 H 1.3664 0.6807 0.1910 0.045 Uiso 1 1 calc R . .
C11 C 1.3870(3) 0.4419(3) 0.0875(3) 0.0391(9) Uani 1 1 d . . .
H11 H 1.4470 0.3921 0.0621 0.047 Uiso 1 1 calc R . .
C12 C 1.2588(3) 0.4099(3) 0.0774(3) 0.0382(9) Uani 1 1 d . . .
H12 H 1.2348 0.3402 0.0470 0.046 Uiso 1 1 calc R . .
C13 C 1.0192(3) 0.2581(3) 0.0659(3) 0.0354(9) Uani 1 1 d . . .
C14 C 1.0500(4) 0.2124(3) -0.0334(4) 0.0516(11) Uani 1 1 d . . .
H14 H 1.0315 0.2441 -0.0876 0.062 Uiso 1 1 calc R . .
C15 C 1.1100(5) 0.1167(4) -0.0486(6) 0.087(2) Uani 1 1 d . . .
H15 H 1.1344 0.0825 -0.1138 0.104 Uiso 1 1 calc R . .
C16 C 1.1324(5) 0.0737(4) 0.0338(7) 0.101(3) Uani 1 1 d . . .
H16 H 1.1740 0.0103 0.0257 0.121 Uiso 1 1 calc R . .
C17 C 1.0936(6) 0.1243(4) 0.1281(6) 0.097(2) Uani 1 1 d . . .
H17 H 1.1082 0.0927 0.1830 0.117 Uiso 1 1 calc R . .
C18 C 0.7976(4) 0.7636(3) 0.3614(4) 0.0470(10) Uani 1 1 d . . .
H18 H 0.8436 0.7661 0.3040 0.056 Uiso 1 1 calc R . .
C19 C 0.8333(4) 0.8335(3) 0.4543(4) 0.0535(12) Uani 1 1 d . . .
H19 H 0.9046 0.8786 0.4598 0.064 Uiso 1 1 calc R . .
C20 C 0.7609(4) 0.8350(3) 0.5388(4) 0.0519(11) Uani 1 1 d . . .
H20 H 0.7815 0.8820 0.6018 0.062 Uiso 1 1 calc R . .
C21 C 0.6566(4) 0.7646(3) 0.5273(3) 0.0437(10) Uani 1 1 d . . .
H21 H 0.6046 0.7654 0.5821 0.052 Uiso 1 1 calc R . .
C22 C 0.6309(3) 0.6937(3) 0.4336(3) 0.0336(8) Uani 1 1 d . . .
C23 C 0.5255(3) 0.6134(3) 0.4153(3) 0.0303(8) Uani 1 1 d . . .
C24 C 0.3360(3) 0.5351(3) 0.3974(3) 0.0299(8) Uani 1 1 d . . .
C25 C 0.2003(3) 0.5119(3) 0.3898(2) 0.0251(7) Uani 1 1 d . . .
C26 C 0.1531(3) 0.4097(3) 0.3727(3) 0.0431(10) Uani 1 1 d . . .
H26 H 0.2103 0.3554 0.3686 0.052 Uiso 1 1 calc R . .
C27 C 0.0220(4) 0.3859(3) 0.3616(3) 0.0429(10) Uani 1 1 d . . .
H27 H -0.0052 0.3159 0.3509 0.051 Uiso 1 1 calc R . .
C28 C -0.0232(4) 0.5577(3) 0.3797(3) 0.0453(10) Uani 1 1 d . . .
H28 H -0.0829 0.6097 0.3813 0.054 Uiso 1 1 calc R . .
C29 C 0.1060(3) 0.5880(3) 0.3922(3) 0.0413(9) Uani 1 1 d . . .
H29 H 0.1303 0.6586 0.4021 0.050 Uiso 1 1 calc R . .
C30 C 0.3482(3) 0.7310(3) 0.4859(3) 0.0319(8) Uani 1 1 d . . .
C31 C 0.3573(4) 0.8161(3) 0.4425(3) 0.0467(10) Uani 1 1 d . . .
H31 H 0.3935 0.8111 0.3793 0.056 Uiso 1 1 calc R . .
C32 C 0.3096(5) 0.9097(4) 0.4979(4) 0.0663(14) Uani 1 1 d . . .
H32 H 0.3143 0.9701 0.4727 0.080 Uiso 1 1 calc R . .
C33 C 0.2549(5) 0.9125(4) 0.5914(4) 0.0670(14) Uani 1 1 d . . .
H33 H 0.2221 0.9743 0.6297 0.080 Uiso 1 1 calc R . .
C34 C 0.2504(4) 0.8220(3) 0.6257(3) 0.0518(11) Uani 1 1 d . . .
H34 H 0.2117 0.8240 0.6874 0.062 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N8 Ag1 N11 135.19(11) . 1_655
N8 Ag1 N1 102.36(10) . .
N11 Ag1 N1 114.08(10) 1_655 .
N8 Ag1 N12 105.51(10) . 2_666
N11 Ag1 N12 99.14(11) 1_655 2_666
N1 Ag1 N12 91.16(11) . 2_666
N5 Ag2 N2 129.86(11) 1_455 .
N5 Ag2 N7 117.93(10) 1_455 .
N2 Ag2 N7 105.56(10) . .
N5 Ag2 O1 99.09(12) 1_455 .
N2 Ag2 O1 111.00(11) . .
N7 Ag2 O1 82.01(11) . .
N13 O1 Ag2 118.7(3) . .
H7A O7 H7B 116.1 . .
C1 N1 C5 117.4(3) . .
C1 N1 Ag1 119.4(3) . .
C5 N1 Ag1 122.3(2) . .
C6 N2 N3 107.7(3) . .
C6 N2 Ag2 131.6(2) . .
N3 N2 Ag2 120.5(2) . .
C7 N3 N2 108.0(3) . .
C6 N4 C7 105.1(3) . .
C6 N4 C13 125.3(3) . .
C7 N4 C13 129.1(3) . .
C11 N5 C10 116.0(3) . .
C11 N5 Ag2 122.3(2) . 1_655
C10 N5 Ag2 120.9(2) . 1_655
C13 N6 C17 114.7(5) . .
C18 N7 C22 116.9(3) . .
C18 N7 Ag2 118.7(3) . .
C22 N7 Ag2 124.0(2) . .
C23 N8 N9 108.9(3) . .
C23 N8 Ag1 129.9(2) . .
N9 N8 Ag1 121.1(2) . .
C24 N9 N8 106.9(3) . .
C23 N10 C24 105.8(3) . .
C23 N10 C30 125.3(3) . .
C24 N10 C30 128.7(3) . .
C27 N11 C28 116.1(3) . .
C27 N11 Ag1 124.2(3) . 1_455
C28 N11 Ag1 119.5(2) . 1_455
C34 N12 C30 115.4(3) . .
C34 N12 Ag1 116.8(3) . 2_666
C30 N12 Ag1 127.8(2) . 2_666
O2 N13 O3 118.9(4) . .
O2 N13 O1 120.9(4) . .
O3 N13 O1 120.2(4) . .
O5 N14 O6 120.6(5) . .
O5 N14 O4 119.9(4) . .
O6 N14 O4 119.5(5) . .
N1 C1 C2 123.1(4) . .
N1 C1 H1 118.4 . .
C2 C1 H1 118.4 . .
C3 C2 C1 119.4(4) . .
C3 C2 H2 120.3 . .
C1 C2 H2 120.3 . .
C2 C3 C4 118.9(4) . .
C2 C3 H3 120.6 . .
C4 C3 H3 120.6 . .
C3 C4 C5 118.4(4) . .
C3 C4 H4 120.8 . .
C5 C4 H4 120.8 . .
N1 C5 C4 122.7(3) . .
N1 C5 C6 115.4(3) . .
C4 C5 C6 121.8(3) . .
N2 C6 N4 109.6(3) . .
N2 C6 C5 125.7(3) . .
N4 C6 C5 124.7(3) . .
N3 C7 N4 109.6(3) . .
N3 C7 C8 123.1(3) . .
N4 C7 C8 127.2(3) . .
C12 C8 C9 117.4(3) . .
C12 C8 C7 125.8(3) . .
C9 C8 C7 116.8(3) . .
C8 C9 C10 118.9(3) . .
C8 C9 H9 120.5 . .
C10 C9 H9 120.5 . .
N5 C10 C9 123.9(3) . .
N5 C10 H10 118.0 . .
C9 C10 H10 118.0 . .
N5 C11 C12 124.1(4) . .
N5 C11 H11 117.9 . .
C12 C11 H11 117.9 . .
C11 C12 C8 119.6(4) . .
C11 C12 H12 120.2 . .
C8 C12 H12 120.2 . .
N6 C13 C14 126.4(4) . .
N6 C13 N4 114.8(3) . .
C14 C13 N4 118.9(4) . .
C13 C14 C15 116.7(5) . .
C13 C14 H14 121.7 . .
C15 C14 H14 121.7 . .
C16 C15 C14 118.7(6) . .
C16 C15 H15 120.6 . .
C14 C15 H15 120.6 . .
C15 C16 C17 119.5(5) . .
C15 C16 H16 120.3 . .
C17 C16 H16 120.3 . .
N6 C17 C16 124.0(6) . .
N6 C17 H17 118.0 . .
C16 C17 H17 118.0 . .
N7 C18 C19 123.5(4) . .
N7 C18 H18 118.2 . .
C19 C18 H18 118.2 . .
C20 C19 C18 118.8(4) . .
C20 C19 H19 120.6 . .
C18 C19 H19 120.6 . .
C19 C20 C21 118.5(4) . .
C19 C20 H20 120.8 . .
C21 C20 H20 120.8 . .
C22 C21 C20 119.3(4) . .
C22 C21 H21 120.3 . .
C20 C21 H21 120.3 . .
N7 C22 C21 122.8(3) . .
N7 C22 C23 114.0(3) . .
C21 C22 C23 123.2(3) . .
N8 C23 N10 109.0(3) . .
N8 C23 C22 124.6(3) . .
N10 C23 C22 126.4(3) . .
N9 C24 N10 109.4(3) . .
N9 C24 C25 122.2(3) . .
N10 C24 C25 128.3(3) . .
C26 C25 C29 114.8(3) . .
C26 C25 C24 121.0(3) . .
C29 C25 C24 124.1(3) . .
C25 C26 C27 121.5(4) . .
C25 C26 H26 119.3 . .
C27 C26 H26 119.3 . .
N11 C27 C26 123.4(4) . .
N11 C27 H27 118.3 . .
C26 C27 H27 118.3 . .
N11 C28 C29 124.0(4) . .
N11 C28 H28 118.0 . .
C29 C28 H28 118.0 . .
C28 C29 C25 120.1(4) . .
C28 C29 H29 119.9 . .
C25 C29 H29 119.9 . .
N12 C30 C31 125.9(3) . .
N12 C30 N10 114.9(3) . .
C31 C30 N10 119.2(3) . .
C30 C31 C32 116.6(4) . .
C30 C31 H31 121.7 . .
C32 C31 H31 121.7 . .
C31 C32 C33 119.4(4) . .
C31 C32 H32 120.3 . .
C33 C32 H32 120.3 . .
C34 C33 C32 118.3(4) . .
C34 C33 H33 120.9 . .
C32 C33 H33 120.9 . .
N12 C34 C33 124.4(4) . .
N12 C34 H34 117.8 . .
C33 C34 H34 117.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N8 2.259(3) .
Ag1 N11 2.276(3) 1_655
Ag1 N1 2.387(3) .
Ag1 N12 2.527(3) 2_666
Ag2 N5 2.301(3) 1_455
Ag2 N2 2.304(3) .
Ag2 N7 2.452(3) .
Ag2 O1 2.549(3) .
O1 N13 1.241(5) .
O2 N13 1.239(5) .
O3 N13 1.239(5) .
O4 N14 1.228(5) .
O5 N14 1.218(5) .
O6 N14 1.226(5) .
O7 H7A 0.8500 .
O7 H7B 0.8502 .
N1 C1 1.341(5) .
N1 C5 1.348(4) .
N2 C6 1.318(4) .
N2 N3 1.388(4) .
N3 C7 1.310(4) .
N4 C6 1.379(4) .
N4 C7 1.386(4) .
N4 C13 1.446(5) .
N5 C11 1.344(5) .
N5 C10 1.345(5) .
N5 Ag2 2.301(3) 1_655
N6 C13 1.317(5) .
N6 C17 1.348(7) .
N7 C18 1.348(5) .
N7 C22 1.354(5) .
N8 C23 1.319(4) .
N8 N9 1.373(4) .
N9 C24 1.326(4) .
N10 C23 1.364(4) .
N10 C24 1.377(4) .
N10 C30 1.457(4) .
N11 C27 1.333(5) .
N11 C28 1.336(5) .
N11 Ag1 2.276(3) 1_455
N12 C34 1.338(5) .
N12 C30 1.339(5) .
N12 Ag1 2.527(3) 2_666
C1 C2 1.375(6) .
C1 H1 0.9300 .
C2 C3 1.372(6) .
C2 H2 0.9300 .
C3 C4 1.385(5) .
C3 H3 0.9300 .
C4 C5 1.393(5) .
C4 H4 0.9300 .
C5 C6 1.477(5) .
C7 C8 1.483(4) .
C8 C12 1.388(5) .
C8 C9 1.397(5) .
C9 C10 1.398(5) .
C9 H9 0.9300 .
C10 H10 0.9300 .
C11 C12 1.385(5) .
C11 H11 0.9300 .
C12 H12 0.9300 .
C13 C14 1.375(5) .
C14 C15 1.388(7) .
C14 H14 0.9300 .
C15 C16 1.361(9) .
C15 H15 0.9300 .
C16 C17 1.362(9) .
C16 H16 0.9300 .
C17 H17 0.9300 .
C18 C19 1.385(6) .
C18 H18 0.9300 .
C19 C20 1.383(6) .
C19 H19 0.9300 .
C20 C21 1.390(6) .
C20 H20 0.9300 .
C21 C22 1.382(5) .
C21 H21 0.9300 .
C22 C23 1.475(5) .
C24 C25 1.436(5) .
C25 C26 1.379(5) .
C25 C29 1.411(5) .
C26 C27 1.390(5) .
C26 H26 0.9300 .
C27 H27 0.9300 .
C28 C29 1.388(5) .
C28 H28 0.9300 .
C29 H29 0.9300 .
C30 C31 1.374(5) .
C31 C32 1.388(6) .
C31 H31 0.9300 .
C32 C33 1.391(7) .
C32 H32 0.9300 .
C33 C34 1.367(6) .
C33 H33 0.9300 .
C34 H34 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
N5 Ag2 O1 N13 72.0(3) 1_455 . . .
N2 Ag2 O1 N13 -148.8(3) . . . .
N7 Ag2 O1 N13 -45.1(3) . . . .
N8 Ag1 N1 C1 -62.5(3) . . . .
N11 Ag1 N1 C1 144.2(3) 1_655 . . .
N12 Ag1 N1 C1 43.7(3) 2_666 . . .
N8 Ag1 N1 C5 128.9(3) . . . .
N11 Ag1 N1 C5 -24.4(3) 1_655 . . .
N12 Ag1 N1 C5 -124.9(3) 2_666 . . .
N5 Ag2 N2 C6 -26.9(4) 1_455 . . .
N7 Ag2 N2 C6 123.1(3) . . . .
O1 Ag2 N2 C6 -149.6(3) . . . .
N5 Ag2 N2 N3 157.2(2) 1_455 . . .
N7 Ag2 N2 N3 -52.8(2) . . . .
O1 Ag2 N2 N3 34.5(3) . . . .
C6 N2 N3 C7 -0.2(4) . . . .
Ag2 N2 N3 C7 176.5(2) . . . .
N5 Ag2 N7 C18 -142.9(3) 1_455 . . .
N2 Ag2 N7 C18 62.9(3) . . . .
O1 Ag2 N7 C18 -46.8(3) . . . .
N5 Ag2 N7 C22 30.4(3) 1_455 . . .
N2 Ag2 N7 C22 -123.9(3) . . . .
O1 Ag2 N7 C22 126.4(3) . . . .
N11 Ag1 N8 C23 6.6(4) 1_655 . . .
N1 Ag1 N8 C23 -137.8(3) . . . .
N12 Ag1 N8 C23 127.4(3) 2_666 . . .
N11 Ag1 N8 N9 -168.2(2) 1_655 . . .
N1 Ag1 N8 N9 47.4(3) . . . .
N12 Ag1 N8 N9 -47.3(3) 2_666 . . .
C23 N8 N9 C24 0.0(4) . . . .
Ag1 N8 N9 C24 175.8(2) . . . .
Ag2 O1 N13 O2 160.4(3) . . . .
Ag2 O1 N13 O3 -20.9(5) . . . .
C5 N1 C1 C2 -0.2(6) . . . .
Ag1 N1 C1 C2 -169.4(3) . . . .
N1 C1 C2 C3 1.1(7) . . . .
C1 C2 C3 C4 -1.2(7) . . . .
C2 C3 C4 C5 0.6(6) . . . .
C1 N1 C5 C4 -0.5(5) . . . .
Ag1 N1 C5 C4 168.4(3) . . . .
C1 N1 C5 C6 178.3(3) . . . .
Ag1 N1 C5 C6 -12.8(4) . . . .
C3 C4 C5 N1 0.3(6) . . . .
C3 C4 C5 C6 -178.4(3) . . . .
N3 N2 C6 N4 -0.8(4) . . . .
Ag2 N2 C6 N4 -177.2(2) . . . .
N3 N2 C6 C5 178.6(3) . . . .
Ag2 N2 C6 C5 2.3(5) . . . .
C7 N4 C6 N2 1.5(4) . . . .
C13 N4 C6 N2 173.6(3) . . . .
C7 N4 C6 C5 -177.9(3) . . . .
C13 N4 C6 C5 -5.9(5) . . . .
N1 C5 C6 N2 -52.2(5) . . . .
C4 C5 C6 N2 126.7(4) . . . .
N1 C5 C6 N4 127.2(4) . . . .
C4 C5 C6 N4 -54.0(5) . . . .
N2 N3 C7 N4 1.2(4) . . . .
N2 N3 C7 C8 -176.2(3) . . . .
C6 N4 C7 N3 -1.7(4) . . . .
C13 N4 C7 N3 -173.4(3) . . . .
C6 N4 C7 C8 175.6(3) . . . .
C13 N4 C7 C8 4.0(6) . . . .
N3 C7 C8 C12 -172.7(3) . . . .
N4 C7 C8 C12 10.3(6) . . . .
N3 C7 C8 C9 8.2(5) . . . .
N4 C7 C8 C9 -168.8(3) . . . .
C12 C8 C9 C10 -1.1(5) . . . .
C7 C8 C9 C10 178.0(3) . . . .
C11 N5 C10 C9 3.0(5) . . . .
Ag2 N5 C10 C9 -167.0(3) 1_655 . . .
C8 C9 C10 N5 -1.0(6) . . . .
C10 N5 C11 C12 -3.0(6) . . . .
Ag2 N5 C11 C12 166.8(3) 1_655 . . .
N5 C11 C12 C8 1.1(6) . . . .
C9 C8 C12 C11 1.1(5) . . . .
C7 C8 C12 C11 -178.0(3) . . . .
C17 N6 C13 C14 3.5(7) . . . .
C17 N6 C13 N4 -176.0(4) . . . .
C6 N4 C13 N6 -76.4(4) . . . .
C7 N4 C13 N6 93.7(4) . . . .
C6 N4 C13 C14 103.9(4) . . . .
C7 N4 C13 C14 -86.0(5) . . . .
N6 C13 C14 C15 -3.7(6) . . . .
N4 C13 C14 C15 175.9(4) . . . .
C13 C14 C15 C16 1.0(7) . . . .
C14 C15 C16 C17 1.2(9) . . . .
C13 N6 C17 C16 -0.9(8) . . . .
C15 C16 C17 N6 -1.4(10) . . . .
C22 N7 C18 C19 3.1(6) . . . .
Ag2 N7 C18 C19 176.8(3) . . . .
N7 C18 C19 C20 -3.9(6) . . . .
C18 C19 C20 C21 1.2(6) . . . .
C19 C20 C21 C22 2.0(6) . . . .
C18 N7 C22 C21 0.4(5) . . . .
Ag2 N7 C22 C21 -172.9(3) . . . .
C18 N7 C22 C23 180.0(3) . . . .
Ag2 N7 C22 C23 6.6(4) . . . .
C20 C21 C22 N7 -2.9(6) . . . .
C20 C21 C22 C23 177.6(4) . . . .
N9 N8 C23 N10 1.1(4) . . . .
Ag1 N8 C23 N10 -174.2(2) . . . .
N9 N8 C23 C22 -176.3(3) . . . .
Ag1 N8 C23 C22 8.5(5) . . . .
C24 N10 C23 N8 -1.7(4) . . . .
C30 N10 C23 N8 173.8(3) . . . .
C24 N10 C23 C22 175.6(3) . . . .
C30 N10 C23 C22 -8.9(5) . . . .
N7 C22 C23 N8 51.4(5) . . . .
C21 C22 C23 N8 -129.1(4) . . . .
N7 C22 C23 N10 -125.5(4) . . . .
C21 C22 C23 N10 54.1(5) . . . .
N8 N9 C24 N10 -1.1(4) . . . .
N8 N9 C24 C25 175.2(3) . . . .
C23 N10 C24 N9 1.7(4) . . . .
C30 N10 C24 N9 -173.6(3) . . . .
C23 N10 C24 C25 -174.3(3) . . . .
C30 N10 C24 C25 10.4(6) . . . .
N9 C24 C25 C26 17.8(5) . . . .
N10 C24 C25 C26 -166.6(4) . . . .
N9 C24 C25 C29 -158.0(3) . . . .
N10 C24 C25 C29 17.5(6) . . . .
C29 C25 C26 C27 -1.6(5) . . . .
C24 C25 C26 C27 -177.7(4) . . . .
C28 N11 C27 C26 0.9(6) . . . .
Ag1 N11 C27 C26 175.8(3) 1_455 . . .
C25 C26 C27 N11 0.6(6) . . . .
C27 N11 C28 C29 -1.3(6) . . . .
Ag1 N11 C28 C29 -176.5(3) 1_455 . . .
N11 C28 C29 C25 0.3(6) . . . .
C26 C25 C29 C28 1.1(5) . . . .
C24 C25 C29 C28 177.2(4) . . . .
C34 N12 C30 C31 1.8(6) . . . .
Ag1 N12 C30 C31 -178.8(3) 2_666 . . .
C34 N12 C30 N10 -179.8(3) . . . .
Ag1 N12 C30 N10 -0.4(4) 2_666 . . .
C23 N10 C30 N12 -113.7(4) . . . .
C24 N10 C30 N12 60.8(5) . . . .
C23 N10 C30 C31 64.8(5) . . . .
C24 N10 C30 C31 -120.7(4) . . . .
N12 C30 C31 C32 -0.2(6) . . . .
N10 C30 C31 C32 -178.5(4) . . . .
C30 C31 C32 C33 -0.9(7) . . . .
C31 C32 C33 C34 0.2(8) . . . .
C30 N12 C34 C33 -2.5(6) . . . .
Ag1 N12 C34 C33 178.0(4) 2_666 . . .
C32 C33 C34 N12 1.6(8) . . . .
