#------------------------------------------------------------------------------
#$Date: 2021-04-26 11:42:13 +0300 (Mon, 26 Apr 2021) $
#$Revision: 264535 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/21/1562102.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1562102
loop_
_publ_author_name
'Li, Cheng-Peng'
'Chen, Jing'
'Guo, Wei'
'Du, Miao'
_publ_section_title
;
 Anion-directed assembly and crystal transformation of Ag(I) coordination
 polymers with a versatile tripyridyltriazole ligand
 3,4-bis(2-pyridyl)-5-(4-pyridyl)-1,2,4-triazole
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              95
_journal_page_last               103
_journal_paper_doi               10.1016/j.jssc.2014.06.038
_journal_volume                  223
_journal_year                    2015
_chemical_formula_sum            'C35 H24.5 Ag F3 N12 O3.25 S'
_chemical_formula_weight         862.10
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                105.7840(10)
_cell_angle_beta                 115.9610(10)
_cell_angle_gamma                102.4970(10)
_cell_formula_units_Z            2
_cell_length_a                   12.0568(6)
_cell_length_b                   13.5190(12)
_cell_length_c                   13.6902(7)
_cell_measurement_reflns_used    4733
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      0.00
_cell_measurement_theta_min      0.00
_cell_volume                     1779.6(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0139
_diffrn_reflns_av_sigmaI/netI    0.0291
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            9150
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.70
_exptl_absorpt_coefficient_mu    0.697
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.843577
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            COLORLESS
_exptl_crystal_density_diffrn    1.609
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       BLOCK
_exptl_crystal_F_000             869
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.767
_refine_diff_density_min         -0.496
_refine_diff_density_rms         0.069
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.067
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     505
_refine_ls_number_reflns         6234
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.067
_refine_ls_R_factor_all          0.0391
_refine_ls_R_factor_gt           0.0336
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0372P)²+1.9534P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0870
_refine_ls_wR_factor_ref         0.0916
_reflns_number_gt                5517
_reflns_number_total             6234
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2015-223-95.cif
_cod_data_source_block           5
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'MULTI-SCAN' was
changed to 'multi-scan' in accordance with the built-in table derived
from the CIF Core dictionary named 'cif_core.dic' version 2.4.5 last
updated on 2014-11-21.

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

data item '_exptl_crystal_density_meas' value 'NONE' was changed to
'?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C35 H24.50 Ag F3 N12 O3.25 S'
_cod_database_code               1562102
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.82983(2) 0.61812(2) 0.60594(2) 0.04062(9) Uani 1 1 d . . .
S1 S 0.50913(9) 0.14359(8) 0.23298(8) 0.0483(2) Uani 1 1 d . . .
F1 F 0.5290(3) 0.1292(2) 0.0478(2) 0.0875(8) Uani 1 1 d . . .
F2 F 0.4387(3) 0.2387(3) 0.0868(3) 0.1112(11) Uani 1 1 d . . .
F3 F 0.6492(3) 0.2872(2) 0.1952(3) 0.1126(11) Uani 1 1 d . . .
O1 O 0.3803(3) 0.0560(2) 0.1536(2) 0.0638(7) Uani 1 1 d . . .
O2 O 0.6194(3) 0.1114(4) 0.2773(3) 0.0979(12) Uani 1 1 d . . .
O3 O 0.5155(4) 0.2354(3) 0.3196(3) 0.0957(11) Uani 1 1 d . . .
N1 N 0.7868(3) 0.9423(2) 0.6287(2) 0.0451(6) Uani 1 1 d . . .
N2 N 0.7033(3) 0.7855(2) 0.3355(2) 0.0491(7) Uani 1 1 d . . .
N3 N 0.7530(3) 0.7068(2) 0.3053(2) 0.0496(7) Uani 1 1 d . . .
N4 N 0.8831(2) 0.81081(19) 0.4983(2) 0.0313(5) Uani 1 1 d . . .
N5 N 1.0713(2) 0.5072(2) 0.4034(2) 0.0357(6) Uani 1 1 d . . .
N6 N 1.0038(2) 0.7986(2) 0.6797(2) 0.0341(5) Uani 1 1 d . . .
N7 N 1.1704(3) 0.7124(2) 0.9918(3) 0.0464(7) Uani 1 1 d . . .
N8 N 0.9611(2) 0.4194(2) 0.8292(2) 0.0375(6) Uani 1 1 d . . .
N9 N 0.8242(2) 0.3769(2) 0.7530(2) 0.0376(6) Uani 1 1 d . . .
N10 N 0.8940(2) 0.55869(19) 0.8452(2) 0.0297(5) Uani 1 1 d . . .
N11 N 0.3787(2) 0.4090(2) 0.5342(2) 0.0384(6) Uani 1 1 d . . .
N12 N 0.8549(2) 0.70666(19) 0.8002(2) 0.0329(5) Uani 1 1 d . . .
C1 C 0.7615(4) 1.0205(3) 0.6900(4) 0.0567(9) Uani 1 1 d . . .
H1 H 0.7792 1.0267 0.7652 0.068 Uiso 1 1 calc R . .
C2 C 0.7111(5) 1.0918(3) 0.6480(4) 0.0668(11) Uani 1 1 d . . .
H2 H 0.6973 1.1460 0.6947 0.080 Uiso 1 1 calc R . .
C3 C 0.6814(5) 1.0820(4) 0.5363(4) 0.0716(13) Uani 1 1 d . . .
H3 H 0.6468 1.1293 0.5057 0.086 Uiso 1 1 calc R . .
C4 C 0.7038(4) 1.0007(3) 0.4697(4) 0.0557(9) Uani 1 1 d . . .
H4 H 0.6832 0.9911 0.3930 0.067 Uiso 1 1 calc R . .
C5 C 0.7574(3) 0.9344(3) 0.5198(3) 0.0374(7) Uani 1 1 d . . .
C6 C 0.7808(3) 0.8460(2) 0.4503(3) 0.0364(7) Uani 1 1 d . . .
C7 C 0.8602(3) 0.7227(2) 0.4032(3) 0.0356(7) Uani 1 1 d . . .
C8 C 0.9378(3) 0.6524(2) 0.4066(2) 0.0327(6) Uani 1 1 d . . .
C9 C 0.8692(3) 0.5401(3) 0.3285(3) 0.0391(7) Uani 1 1 d . . .
H9 H 0.7771 0.5116 0.2754 0.047 Uiso 1 1 calc R . .
C10 C 0.9388(3) 0.4717(3) 0.3303(3) 0.0384(7) Uani 1 1 d . . .
H10 H 0.8912 0.3966 0.2779 0.046 Uiso 1 1 calc R . .
C11 C 1.1376(3) 0.6162(3) 0.4779(3) 0.0366(7) Uani 1 1 d . . .
H11 H 1.2298 0.6428 0.5290 0.044 Uiso 1 1 calc R . .
C12 C 1.0755(3) 0.6905(2) 0.4823(3) 0.0362(7) Uani 1 1 d . . .
H12 H 1.1253 0.7652 0.5353 0.043 Uiso 1 1 calc R . .
C13 C 0.9944(3) 0.8616(2) 0.6197(2) 0.0291(6) Uani 1 1 d . . .
C14 C 1.0835(3) 0.9689(3) 0.6649(3) 0.0411(7) Uani 1 1 d . . .
H14 H 1.0722 1.0094 0.6186 0.049 Uiso 1 1 calc R . .
C15 C 1.1901(3) 1.0142(3) 0.7812(3) 0.0479(8) Uani 1 1 d . . .
H15 H 1.2527 1.0864 0.8150 0.058 Uiso 1 1 calc R . .
C16 C 1.2028(3) 0.9516(3) 0.8467(3) 0.0446(8) Uani 1 1 d . . .
H16 H 1.2736 0.9806 0.9255 0.054 Uiso 1 1 calc R . .
C17 C 1.1085(3) 0.8454(3) 0.7931(3) 0.0399(7) Uani 1 1 d . . .
H17 H 1.1174 0.8034 0.8378 0.048 Uiso 1 1 calc R . .
C18 C 1.2987(3) 0.7830(3) 1.0669(3) 0.0555(9) Uani 1 1 d . . .
H18 H 1.3192 0.8588 1.0867 0.067 Uiso 1 1 calc R . .
C19 C 1.4014(3) 0.7488(4) 1.1160(3) 0.0614(11) Uani 1 1 d . . .
H19 H 1.4890 0.8005 1.1694 0.074 Uiso 1 1 calc R . .
C20 C 1.3727(4) 0.6378(4) 1.0853(4) 0.0685(12) Uani 1 1 d . . .
H20 H 1.4407 0.6125 1.1162 0.082 Uiso 1 1 calc R . .
C21 C 1.2412(3) 0.5633(3) 1.0074(4) 0.0539(9) Uani 1 1 d . . .
H21 H 1.2192 0.4869 0.9838 0.065 Uiso 1 1 calc R . .
C22 C 1.1434(3) 0.6047(3) 0.9656(3) 0.0354(7) Uani 1 1 d . . .
C23 C 1.0019(3) 0.5280(2) 0.8832(3) 0.0316(6) Uani 1 1 d . . .
C24 C 0.7853(3) 0.4603(2) 0.7625(2) 0.0309(6) Uani 1 1 d . . .
C25 C 0.6458(3) 0.4464(2) 0.6892(2) 0.0306(6) Uani 1 1 d . . .
C26 C 0.5669(3) 0.3582(3) 0.5768(3) 0.0427(8) Uani 1 1 d . . .
H26 H 0.6024 0.3096 0.5512 0.051 Uiso 1 1 calc R . .
C27 C 0.4372(3) 0.3425(3) 0.5039(3) 0.0470(8) Uani 1 1 d . . .
H27 H 0.3865 0.2826 0.4291 0.056 Uiso 1 1 calc R . .
C28 C 0.4547(3) 0.4936(3) 0.6424(3) 0.0415(7) Uani 1 1 d . . .
H28 H 0.4168 0.5410 0.6657 0.050 Uiso 1 1 calc R . .
C29 C 0.5858(3) 0.5150(3) 0.7216(3) 0.0395(7) Uani 1 1 d . . .
H29 H 0.6340 0.5749 0.7963 0.047 Uiso 1 1 calc R . .
C30 C 0.8910(3) 0.6679(2) 0.8831(2) 0.0291(6) Uani 1 1 d . . .
C31 C 0.9202(3) 0.7217(3) 0.9980(3) 0.0389(7) Uani 1 1 d . . .
H31 H 0.9460 0.6906 1.0530 0.047 Uiso 1 1 calc R . .
C32 C 0.9092(3) 0.8240(3) 1.0272(3) 0.0480(8) Uani 1 1 d . . .
H32 H 0.9283 0.8639 1.1036 0.058 Uiso 1 1 calc R . .
C33 C 0.8699(3) 0.8661(3) 0.9430(3) 0.0476(8) Uani 1 1 d . . .
H33 H 0.8603 0.9340 0.9609 0.057 Uiso 1 1 calc R . .
C34 C 0.8447(3) 0.8064(3) 0.8310(3) 0.0399(7) Uani 1 1 d . . .
H34 H 0.8197 0.8361 0.7746 0.048 Uiso 1 1 calc R . .
C35 C 0.5336(4) 0.2026(3) 0.1373(4) 0.0554(9) Uani 1 1 d . . .
O4 O 0.357(2) 0.3796(17) 0.9575(14) 0.132(7) Uani 0.25 1 d P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N11 Ag1 N5 125.42(9) 2_666 2_766
N11 Ag1 N6 115.31(9) 2_666 .
N5 Ag1 N6 105.44(8) 2_766 .
N11 Ag1 N12 106.30(9) 2_666 .
N5 Ag1 N12 114.41(8) 2_766 .
N6 Ag1 N12 81.65(8) . .
O2 S1 O1 116.6(2) . .
O2 S1 O3 114.6(2) . .
O1 S1 O3 114.78(19) . .
O2 S1 C35 102.5(2) . .
O1 S1 C35 102.92(16) . .
O3 S1 C35 102.5(2) . .
C1 N1 C5 116.4(3) . .
C6 N2 N3 107.7(2) . .
C7 N3 N2 107.9(2) . .
C7 N4 C6 104.9(2) . .
C7 N4 C13 128.1(2) . .
C6 N4 C13 126.8(2) . .
C10 N5 C11 116.9(2) . .
C10 N5 Ag1 118.78(19) . 2_766
C11 N5 Ag1 124.28(19) . 2_766
C13 N6 C17 116.2(3) . .
C13 N6 Ag1 123.81(18) . .
C17 N6 Ag1 119.5(2) . .
C22 N7 C18 117.3(3) . .
C23 N8 N9 107.8(2) . .
C24 N9 N8 107.9(2) . .
C23 N10 C24 104.7(2) . .
C23 N10 C30 129.0(2) . .
C24 N10 C30 126.2(2) . .
C28 N11 C27 116.2(3) . .
C28 N11 Ag1 124.9(2) . 2_666
C27 N11 Ag1 118.5(2) . 2_666
C30 N12 C34 116.6(3) . .
C30 N12 Ag1 123.78(18) . .
C34 N12 Ag1 119.3(2) . .
N1 C1 C2 123.6(4) . .
N1 C1 H1 118.2 . .
C2 C1 H1 118.2 . .
C3 C2 C1 119.0(3) . .
C3 C2 H2 120.5 . .
C1 C2 H2 120.5 . .
C2 C3 C4 118.8(4) . .
C2 C3 H3 120.6 . .
C4 C3 H3 120.6 . .
C5 C4 C3 118.3(4) . .
C5 C4 H4 120.9 . .
C3 C4 H4 120.9 . .
N1 C5 C4 123.9(3) . .
N1 C5 C6 116.6(3) . .
C4 C5 C6 119.5(3) . .
N2 C6 N4 110.0(3) . .
N2 C6 C5 124.9(3) . .
N4 C6 C5 124.9(3) . .
N3 C7 N4 109.6(3) . .
N3 C7 C8 123.4(3) . .
N4 C7 C8 127.0(3) . .
C12 C8 C9 117.7(3) . .
C12 C8 C7 124.4(3) . .
C9 C8 C7 117.9(3) . .
C10 C9 C8 119.3(3) . .
C10 C9 H9 120.3 . .
C8 C9 H9 120.3 . .
N5 C10 C9 123.5(3) . .
N5 C10 H10 118.2 . .
C9 C10 H10 118.2 . .
N5 C11 C12 123.3(3) . .
N5 C11 H11 118.4 . .
C12 C11 H11 118.4 . .
C11 C12 C8 119.2(3) . .
C11 C12 H12 120.4 . .
C8 C12 H12 120.4 . .
N6 C13 C14 124.8(3) . .
N6 C13 N4 115.8(2) . .
C14 C13 N4 119.4(3) . .
C13 C14 C15 117.7(3) . .
C13 C14 H14 121.2 . .
C15 C14 H14 121.2 . .
C16 C15 C14 119.3(3) . .
C16 C15 H15 120.4 . .
C14 C15 H15 120.4 . .
C17 C16 C15 118.5(3) . .
C17 C16 H16 120.8 . .
C15 C16 H16 120.8 . .
N6 C17 C16 123.7(3) . .
N6 C17 H17 118.2 . .
C16 C17 H17 118.2 . .
N7 C18 C19 123.2(4) . .
N7 C18 H18 118.4 . .
C19 C18 H18 118.4 . .
C20 C19 C18 118.8(3) . .
C20 C19 H19 120.6 . .
C18 C19 H19 120.6 . .
C19 C20 C21 119.2(3) . .
C19 C20 H20 120.4 . .
C21 C20 H20 120.4 . .
C22 C21 C20 118.4(4) . .
C22 C21 H21 120.8 . .
C20 C21 H21 120.8 . .
N7 C22 C21 123.1(3) . .
N7 C22 C23 116.8(3) . .
C21 C22 C23 120.1(3) . .
N8 C23 N10 109.8(2) . .
N8 C23 C22 124.3(3) . .
N10 C23 C22 125.8(3) . .
N9 C24 N10 109.8(2) . .
N9 C24 C25 122.9(3) . .
N10 C24 C25 127.3(2) . .
C26 C25 C29 116.8(3) . .
C26 C25 C24 117.5(3) . .
C29 C25 C24 125.7(3) . .
C27 C26 C25 120.0(3) . .
C27 C26 H26 120.0 . .
C25 C26 H26 120.0 . .
N11 C27 C26 123.6(3) . .
N11 C27 H27 118.2 . .
C26 C27 H27 118.2 . .
N11 C28 C29 123.9(3) . .
N11 C28 H28 118.0 . .
C29 C28 H28 118.0 . .
C28 C29 C25 119.5(3) . .
C28 C29 H29 120.3 . .
C25 C29 H29 120.3 . .
N12 C30 C31 125.3(3) . .
N12 C30 N10 115.1(2) . .
C31 C30 N10 119.5(3) . .
C30 C31 C32 116.8(3) . .
C30 C31 H31 121.6 . .
C32 C31 H31 121.6 . .
C33 C32 C31 119.5(3) . .
C33 C32 H32 120.2 . .
C31 C32 H32 120.2 . .
C32 C33 C34 119.2(3) . .
C32 C33 H33 120.4 . .
C34 C33 H33 120.4 . .
N12 C34 C33 122.5(3) . .
N12 C34 H34 118.7 . .
C33 C34 H34 118.7 . .
F3 C35 F1 107.1(3) . .
F3 C35 F2 107.4(4) . .
F1 C35 F2 105.5(4) . .
F3 C35 S1 112.4(3) . .
F1 C35 S1 112.5(3) . .
F2 C35 S1 111.6(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N11 2.265(2) 2_666
Ag1 N5 2.280(2) 2_766
Ag1 N6 2.442(2) .
Ag1 N12 2.450(2) .
S1 O2 1.419(3) .
S1 O1 1.422(3) .
S1 O3 1.425(3) .
S1 C35 1.801(4) .
F1 C35 1.321(5) .
F2 C35 1.326(5) .
F3 C35 1.314(4) .
N1 C1 1.340(4) .
N1 C5 1.340(4) .
N2 C6 1.303(4) .
N2 N3 1.384(4) .
N3 C7 1.311(4) .
N4 C7 1.375(4) .
N4 C6 1.377(4) .
N4 C13 1.436(3) .
N5 C10 1.338(4) .
N5 C11 1.345(4) .
N5 Ag1 2.280(2) 2_766
N6 C13 1.325(4) .
N6 C17 1.345(4) .
N7 C22 1.328(4) .
N7 C18 1.340(4) .
N8 C23 1.312(4) .
N8 N9 1.378(3) .
N9 C24 1.309(4) .
N10 C23 1.376(4) .
N10 C24 1.377(4) .
N10 C30 1.440(3) .
N11 C28 1.333(4) .
N11 C27 1.344(4) .
N11 Ag1 2.265(2) 2_666
N12 C30 1.319(4) .
N12 C34 1.348(4) .
C1 C2 1.370(5) .
C1 H1 0.9300 .
C2 C3 1.370(6) .
C2 H2 0.9300 .
C3 C4 1.383(5) .
C3 H3 0.9300 .
C4 C5 1.374(5) .
C4 H4 0.9300 .
C5 C6 1.474(4) .
C7 C8 1.467(4) .
C8 C12 1.389(4) .
C8 C9 1.389(4) .
C9 C10 1.376(4) .
C9 H9 0.9300 .
C10 H10 0.9300 .
C11 C12 1.380(4) .
C11 H11 0.9300 .
C12 H12 0.9300 .
C13 C14 1.377(4) .
C14 C15 1.378(5) .
C14 H14 0.9300 .
C15 C16 1.377(5) .
C15 H15 0.9300 .
C16 C17 1.372(5) .
C16 H16 0.9300 .
C17 H17 0.9300 .
C18 C19 1.375(5) .
C18 H18 0.9300 .
C19 C20 1.360(6) .
C19 H19 0.9300 .
C20 C21 1.382(5) .
C20 H20 0.9300 .
C21 C22 1.379(4) .
C21 H21 0.9300 .
C22 C23 1.474(4) .
C24 C25 1.467(4) .
C25 C26 1.387(4) .
C25 C29 1.388(4) .
C26 C27 1.365(4) .
C26 H26 0.9300 .
C27 H27 0.9300 .
C28 C29 1.374(4) .
C28 H28 0.9300 .
C29 H29 0.9300 .
C30 C31 1.381(4) .
C31 C32 1.385(4) .
C31 H31 0.9300 .
C32 C33 1.368(5) .
C32 H32 0.9300 .
C33 C34 1.381(5) .
C33 H33 0.9300 .
C34 H34 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C6 N2 N3 C7 -0.4(4) . . . .
N11 Ag1 N6 C13 -22.6(2) 2_666 . . .
N5 Ag1 N6 C13 120.1(2) 2_766 . . .
N12 Ag1 N6 C13 -126.8(2) . . . .
N11 Ag1 N6 C17 148.6(2) 2_666 . . .
N5 Ag1 N6 C17 -68.7(2) 2_766 . . .
N12 Ag1 N6 C17 44.4(2) . . . .
C23 N8 N9 C24 0.0(3) . . . .
N11 Ag1 N12 C30 126.2(2) 2_666 . . .
N5 Ag1 N12 C30 -16.6(2) 2_766 . . .
N6 Ag1 N12 C30 -119.8(2) . . . .
N11 Ag1 N12 C34 -60.6(2) 2_666 . . .
N5 Ag1 N12 C34 156.7(2) 2_766 . . .
N6 Ag1 N12 C34 53.4(2) . . . .
C5 N1 C1 C2 -1.4(6) . . . .
N1 C1 C2 C3 1.6(7) . . . .
C1 C2 C3 C4 -0.3(7) . . . .
C2 C3 C4 C5 -1.1(7) . . . .
C1 N1 C5 C4 -0.2(5) . . . .
C1 N1 C5 C6 -178.0(3) . . . .
C3 C4 C5 N1 1.4(6) . . . .
C3 C4 C5 C6 179.2(4) . . . .
N3 N2 C6 N4 0.8(4) . . . .
N3 N2 C6 C5 -175.6(3) . . . .
C7 N4 C6 N2 -0.8(4) . . . .
C13 N4 C6 N2 174.8(3) . . . .
C7 N4 C6 C5 175.5(3) . . . .
C13 N4 C6 C5 -8.8(5) . . . .
N1 C5 C6 N2 141.4(3) . . . .
C4 C5 C6 N2 -36.6(5) . . . .
N1 C5 C6 N4 -34.5(5) . . . .
C4 C5 C6 N4 147.6(3) . . . .
N2 N3 C7 N4 -0.1(4) . . . .
N2 N3 C7 C8 178.0(3) . . . .
C6 N4 C7 N3 0.6(4) . . . .
C13 N4 C7 N3 -175.0(3) . . . .
C6 N4 C7 C8 -177.5(3) . . . .
C13 N4 C7 C8 7.0(5) . . . .
N3 C7 C8 C12 146.7(3) . . . .
N4 C7 C8 C12 -35.5(5) . . . .
N3 C7 C8 C9 -32.9(5) . . . .
N4 C7 C8 C9 144.9(3) . . . .
C12 C8 C9 C10 1.0(5) . . . .
C7 C8 C9 C10 -179.3(3) . . . .
C11 N5 C10 C9 -0.2(5) . . . .
Ag1 N5 C10 C9 -179.9(2) 2_766 . . .
C8 C9 C10 N5 -0.6(5) . . . .
C10 N5 C11 C12 0.5(5) . . . .
Ag1 N5 C11 C12 -179.8(2) 2_766 . . .
N5 C11 C12 C8 0.0(5) . . . .
C9 C8 C12 C11 -0.8(4) . . . .
C7 C8 C12 C11 179.6(3) . . . .
C17 N6 C13 C14 0.5(4) . . . .
Ag1 N6 C13 C14 172.0(2) . . . .
C17 N6 C13 N4 179.5(2) . . . .
Ag1 N6 C13 N4 -9.1(3) . . . .
C7 N4 C13 N6 -66.7(4) . . . .
C6 N4 C13 N6 118.7(3) . . . .
C7 N4 C13 C14 112.3(3) . . . .
C6 N4 C13 C14 -62.3(4) . . . .
N6 C13 C14 C15 -0.2(5) . . . .
N4 C13 C14 C15 -179.1(3) . . . .
C13 C14 C15 C16 -0.3(5) . . . .
C14 C15 C16 C17 0.3(5) . . . .
C13 N6 C17 C16 -0.4(4) . . . .
Ag1 N6 C17 C16 -172.3(2) . . . .
C15 C16 C17 N6 0.0(5) . . . .
C22 N7 C18 C19 0.5(6) . . . .
N7 C18 C19 C20 1.6(6) . . . .
C18 C19 C20 C21 -1.1(7) . . . .
C19 C20 C21 C22 -1.2(6) . . . .
C18 N7 C22 C21 -3.1(5) . . . .
C18 N7 C22 C23 179.8(3) . . . .
C20 C21 C22 N7 3.5(6) . . . .
C20 C21 C22 C23 -179.5(3) . . . .
N9 N8 C23 N10 0.6(3) . . . .
N9 N8 C23 C22 -175.4(3) . . . .
C24 N10 C23 N8 -1.0(3) . . . .
C30 N10 C23 N8 177.8(3) . . . .
C24 N10 C23 C22 175.0(3) . . . .
C30 N10 C23 C22 -6.3(5) . . . .
N7 C22 C23 N8 165.3(3) . . . .
C21 C22 C23 N8 -12.0(5) . . . .
N7 C22 C23 N10 -10.1(4) . . . .
C21 C22 C23 N10 172.7(3) . . . .
N8 N9 C24 N10 -0.6(3) . . . .
N8 N9 C24 C25 176.6(3) . . . .
C23 N10 C24 N9 1.0(3) . . . .
C30 N10 C24 N9 -177.8(3) . . . .
C23 N10 C24 C25 -176.1(3) . . . .
C30 N10 C24 C25 5.1(5) . . . .
N9 C24 C25 C26 -28.2(4) . . . .
N10 C24 C25 C26 148.6(3) . . . .
N9 C24 C25 C29 152.8(3) . . . .
N10 C24 C25 C29 -30.4(5) . . . .
C29 C25 C26 C27 0.4(5) . . . .
C24 C25 C26 C27 -178.8(3) . . . .
C28 N11 C27 C26 -0.3(5) . . . .
Ag1 N11 C27 C26 173.2(3) 2_666 . . .
C25 C26 C27 N11 0.1(6) . . . .
C27 N11 C28 C29 0.0(5) . . . .
Ag1 N11 C28 C29 -173.1(3) 2_666 . . .
N11 C28 C29 C25 0.5(5) . . . .
C26 C25 C29 C28 -0.7(5) . . . .
C24 C25 C29 C28 178.4(3) . . . .
C34 N12 C30 C31 -0.8(4) . . . .
Ag1 N12 C30 C31 172.5(2) . . . .
C34 N12 C30 N10 176.9(2) . . . .
Ag1 N12 C30 N10 -9.7(3) . . . .
C23 N10 C30 N12 114.6(3) . . . .
C24 N10 C30 N12 -66.9(4) . . . .
C23 N10 C30 C31 -67.5(4) . . . .
C24 N10 C30 C31 110.9(3) . . . .
N12 C30 C31 C32 0.7(5) . . . .
N10 C30 C31 C32 -176.9(3) . . . .
C30 C31 C32 C33 0.4(5) . . . .
C31 C32 C33 C34 -1.3(5) . . . .
C30 N12 C34 C33 -0.1(4) . . . .
Ag1 N12 C34 C33 -173.8(2) . . . .
C32 C33 C34 N12 1.2(5) . . . .
O2 S1 C35 F3 -59.0(4) . . . .
O1 S1 C35 F3 179.6(3) . . . .
O3 S1 C35 F3 60.1(4) . . . .
O2 S1 C35 F1 61.9(3) . . . .
O1 S1 C35 F1 -59.5(3) . . . .
O3 S1 C35 F1 -178.9(3) . . . .
O2 S1 C35 F2 -179.8(3) . . . .
O1 S1 C35 F2 58.8(3) . . . .
O3 S1 C35 F2 -60.6(3) . . . .
