#------------------------------------------------------------------------------
#$Date: 2021-05-12 11:15:58 +0300 (Wed, 12 May 2021) $
#$Revision: 265135 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/25/1562523.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1562523
loop_
_publ_author_name
'Oliynyk, Anton O.'
'Mar, Arthur'
_publ_section_title
;
 Rare-earth manganese germanides RE2+MnGe2+ (RE=La, Ce) built from
 four-membered rings and stellae quadrangulae of Mn-centred tetrahedra
;
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              60
_journal_page_last               65
_journal_paper_doi               10.1016/j.jssc.2013.07.025
_journal_volume                  206
_journal_year                    2013
_chemical_formula_structural     'La2.12 Mn Ge2.16'
_chemical_formula_sum            'Ge2.16 La2.12 Mn'
_chemical_formula_weight         507.10
_chemical_name_common            'lanthanum manganese germanide (2.12/1/2.16)'
_chemical_name_systematic        'lanthanum manganese germanide (2.12/1/2.16)'
_space_group_IT_number           129
_space_group_name_Hall           '-P 4a 2a'
_space_group_name_H-M_alt        'P 4/n m m :2'
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  '-P 4a 2a'
_symmetry_space_group_name_H-M   'P 4/n m m :2'
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            16
_cell_length_a                   16.0491(4)
_cell_length_b                   16.0491(4)
_cell_length_c                   8.1587(2)
_cell_measurement_reflns_used    8637
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      32.19
_cell_measurement_theta_min      2.50
_cell_volume                     2101.47(9)
_computing_cell_refinement       'Bruker SAINT 7.68A (Bruker, 2009)'
_computing_data_collection       'Bruker SMART 5.054 (Bruker, 1999)'
_computing_data_reduction        'Bruker SAINT 7.68A'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL 6.12'
_computing_structure_refinement  'Bruker SHELXTL 6.12'
_computing_structure_solution    'Bruker SHELXTL 6.12'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker PLATFORM/SMART APEX II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0647
_diffrn_reflns_av_sigmaI/netI    0.0227
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            29480
_diffrn_reflns_theta_full        33.18
_diffrn_reflns_theta_max         33.18
_diffrn_reflns_theta_min         1.79
_exptl_absorpt_coefficient_mu    31.277
_exptl_absorpt_correction_T_max  0.4627
_exptl_absorpt_correction_T_min  0.2334
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL 6.12 (Sheldrick, 2001)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    6.411
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             3445
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.04
_refine_diff_density_max         5.657
_refine_diff_density_min         -5.732
_refine_diff_density_rms         0.322
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.074
_refine_ls_hydrogen_treatment    .
_refine_ls_matrix_type           full
_refine_ls_number_parameters     70
_refine_ls_number_reflns         2227
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.074
_refine_ls_R_factor_all          0.0313
_refine_ls_R_factor_gt           0.0223
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0116P)²+18.2749P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0421
_refine_ls_wR_factor_ref         0.0445
_reflns_number_gt                1880
_reflns_number_total             2227
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            JSSC-2013-206-60.cif
_cod_data_source_block           la2mnge2
_cod_original_sg_symbol_H-M      'P 4/n m m'
_cod_database_code               1562523
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y+1/2, z'
'-y+1/2, x, z'
'y, -x+1/2, z'
'-x, y+1/2, -z'
'x+1/2, -y, -z'
'y+1/2, x+1/2, -z'
'-y, -x, -z'
'-x, -y, -z'
'x-1/2, y-1/2, -z'
'y-1/2, -x, -z'
'-y, x-1/2, -z'
'x, -y-1/2, z'
'-x-1/2, y, z'
'-y-1/2, -x-1/2, z'
'y, x, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
La1 La 0.110269(16) 0.110269(16) 0.69469(4) 0.01027(7) Uani 1 2 d S . .
La2 La 0.2500 0.06483(2) 0.34409(4) 0.00990(7) Uani 1 2 d S . .
La3 La 0.374930(15) 0.625070(15) 0.5000 0.00912(6) Uani 1 2 d S . .
La4 La 0.420518(14) 0.579482(14) 0.0000 0.00904(6) Uani 1 2 d S . .
La5 La 0.2500 0.2500 0.0003(2) 0.0186(4) Uani 0.729(4) 8 d SP . .
La6 La 0.2500 0.2500 0.0628(6) 0.0186(4) Uani 0.279(3) 8 d SP . .
Mn1 Mn 0.2500 0.03398(6) 0.97817(11) 0.01204(17) Uani 1 2 d S . .
Mn2 Mn 0.2500 0.66533(6) 0.86516(11) 0.01008(16) Uani 1 2 d S . .
Ge1 Ge 0.04218(3) 0.04218(3) 0.33255(8) 0.01019(12) Uani 1 2 d S . .
Ge2 Ge 0.11313(3) 0.11313(3) 0.07537(8) 0.00898(11) Uani 1 2 d S . .
Ge3 Ge 0.2500 0.52695(4) 0.70039(8) 0.01048(12) Uani 1 2 d S . .
Ge4 Ge 0.2500 0.61051(4) 0.18301(8) 0.00905(11) Uani 1 2 d S . .
Ge5 Ge 0.2500 0.2500 0.4289(7) 0.0182(4) Uani 0.279(3) 8 d SP . .
Ge6 Ge 0.2500 0.2500 0.5403(3) 0.0182(4) Uani 0.729(4) 8 d SP . .
Ge7 Ge 0.2500 0.2500 0.7196(7) 0.0182(4) Uani 0.279(3) 8 d SP . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge2 La1 Ge3 89.142(13) 1_556 3
Ge2 La1 Ge3 89.142(13) 1_556 2
Ge3 La1 Ge3 178.01(3) 3 2
Ge2 La1 Ge7 85.13(10) 1_556 .
Ge3 La1 Ge7 89.428(11) 3 .
Ge3 La1 Ge7 89.428(11) 2 .
Ge2 La1 Ge1 153.59(2) 1_556 .
Ge3 La1 Ge1 90.991(13) 3 .
Ge3 La1 Ge1 90.991(13) 2 .
Ge7 La1 Ge1 121.28(10) . .
Ge2 La1 Ge6 110.47(4) 1_556 .
Ge3 La1 Ge6 89.831(11) 3 .
Ge3 La1 Ge6 89.831(11) 2 .
Ge7 La1 Ge6 25.34(11) . .
Ge1 La1 Ge6 95.94(4) . .
Ge2 La1 Mn1 47.521(14) 1_556 .
Ge3 La1 Mn1 134.38(2) 3 .
Ge3 La1 Mn1 43.695(19) 2 .
Ge7 La1 Mn1 75.44(7) . .
Ge1 La1 Mn1 133.749(16) . .
Ge6 La1 Mn1 93.07(3) . .
Ge2 La1 Mn1 47.522(14) 1_556 4
Ge3 La1 Mn1 43.694(19) 3 4
Ge3 La1 Mn1 134.38(2) 2 4
Ge7 La1 Mn1 75.44(7) . 4
Ge1 La1 Mn1 133.748(16) . 4
Ge6 La1 Mn1 93.07(3) . 4
Mn1 La1 Mn1 90.69(3) . 4
Ge2 La1 Ge1 94.873(18) 1_556 9_556
Ge3 La1 Ge1 90.572(11) 3 9_556
Ge3 La1 Ge1 90.572(11) 2 9_556
Ge7 La1 Ge1 179.99(11) . 9_556
Ge1 La1 Ge1 58.71(2) . 9_556
Ge6 La1 Ge1 154.66(4) . 9_556
Mn1 La1 Ge1 104.567(17) . 9_556
Mn1 La1 Ge1 104.567(17) 4 9_556
Ge2 La1 La2 139.944(9) 1_556 .
Ge3 La1 La2 125.138(15) 3 .
Ge3 La1 La2 56.086(13) 2 .
Ge7 La1 La2 76.19(8) . .
Ge1 La1 La2 56.636(10) . .
Ge6 La1 La2 56.42(3) . .
Mn1 La1 La2 93.114(13) . .
Mn1 La1 La2 149.397(17) 4 .
Ge1 La1 La2 103.804(12) 9_556 .
Ge2 La1 La2 139.944(9) 1_556 4
Ge3 La1 La2 56.087(13) 3 4
Ge3 La1 La2 125.138(15) 2 4
Ge7 La1 La2 76.19(8) . 4
Ge1 La1 La2 56.636(10) . 4
Ge6 La1 La2 56.42(3) . 4
Mn1 La1 La2 149.397(17) . 4
Mn1 La1 La2 93.114(13) 4 4
Ge1 La1 La2 103.804(12) 9_556 4
La2 La1 La2 69.059(11) . 4
Ge2 La1 La4 52.058(11) 1_556 10_556
Ge3 La1 La4 62.712(12) 3 10_556
Ge3 La1 La4 116.828(14) 2 10_556
Ge7 La1 La4 126.14(9) . 10_556
Ge1 La1 La4 105.315(13) . 10_556
Ge6 La1 La4 144.94(2) . 10_556
Mn1 La1 La4 91.943(13) . 10_556
Mn1 La1 La4 52.169(13) 4 10_556
Ge1 La1 La4 53.871(10) 9_556 10_556
La2 La1 La4 157.638(11) . 10_556
La2 La1 La4 114.144(7) 4 10_556
Mn1 La2 Ge5 112.53(11) 1_554 .
Mn1 La2 Ge4 55.55(2) 1_554 2
Ge5 La2 Ge4 168.08(11) . 2
Mn1 La2 Ge2 50.470(13) 1_554 3
Ge5 La2 Ge2 85.38(8) . 3
Ge4 La2 Ge2 85.960(14) 2 3
Mn1 La2 Ge2 50.470(13) 1_554 .
Ge5 La2 Ge2 85.38(8) . .
Ge4 La2 Ge2 85.959(14) 2 .
Ge2 La2 Ge2 86.74(2) 3 .
Mn1 La2 Ge3 143.71(2) 1_554 2
Ge5 La2 Ge3 103.76(11) . 2
Ge4 La2 Ge3 88.159(18) 2 2
Ge2 La2 Ge3 136.127(12) 3 2
Ge2 La2 Ge3 136.127(12) . 2
Mn1 La2 Ge1 87.398(13) 1_554 3
Ge5 La2 Ge1 96.422(9) . 3
Ge4 La2 Ge1 83.684(10) 2 3
Ge2 La2 Ge1 47.517(15) 3 3
Ge2 La2 Ge1 133.584(18) . 3
Ge3 La2 Ge1 88.628(12) 2 3
Mn1 La2 Ge1 87.398(13) 1_554 .
Ge5 La2 Ge1 96.422(9) . .
Ge4 La2 Ge1 83.684(10) 2 .
Ge2 La2 Ge1 133.584(18) 3 .
Ge2 La2 Ge1 47.516(15) . .
Ge3 La2 Ge1 88.629(12) 2 .
Ge1 La2 Ge1 167.152(18) 3 .
Mn1 La2 Ge6 127.72(4) 1_554 .
Ge5 La2 Ge6 15.19(11) . .
Ge4 La2 Ge6 176.73(4) 2 .
Ge2 La2 Ge6 96.41(3) 3 .
Ge2 La2 Ge6 96.41(3) . .
Ge3 La2 Ge6 88.57(4) 2 .
Ge1 La2 Ge6 96.238(10) 3 .
Ge1 La2 Ge6 96.238(10) . .
Mn1 La2 La1 142.504(6) 1_554 .
Ge5 La2 La1 68.49(8) . .
Ge4 La2 La1 120.312(12) 2 .
Ge2 La2 La1 153.712(15) 3 .
Ge2 La2 La1 93.771(10) . .
Ge3 La2 La1 53.175(9) 2 .
Ge1 La2 La1 130.096(15) 3 .
Ge1 La2 La1 56.071(12) . .
Ge6 La2 La1 57.38(2) . .
Mn1 La2 La1 142.504(6) 1_554 3
Ge5 La2 La1 68.49(8) . 3
Ge4 La2 La1 120.312(12) 2 3
Ge2 La2 La1 93.771(10) 3 3
Ge2 La2 La1 153.712(15) . 3
Ge3 La2 La1 53.175(9) 2 3
Ge1 La2 La1 56.070(12) 3 3
Ge1 La2 La1 130.097(15) . 3
Ge6 La2 La1 57.38(2) . 3
La1 La2 La1 74.447(12) . 3
Mn1 La2 La6 61.74(6) 1_554 .
Ge5 La2 La6 50.79(13) . .
Ge4 La2 La6 117.29(6) 2 .
Ge2 La2 La6 52.36(3) 3 .
Ge2 La2 La6 52.36(3) . .
Ge3 La2 La6 154.55(6) 2 .
Ge1 La2 La6 93.933(12) 3 .
Ge1 La2 La6 93.932(12) . .
Ge6 La2 La6 65.98(7) . .
La1 La2 La6 108.42(5) . .
La1 La2 La6 108.42(5) 3 .
Ge3 La3 Ge3 168.47(2) 12_666 .
Ge3 La3 Ge4 89.078(13) 12_666 12_666
Ge3 La3 Ge4 86.525(15) . 12_666
Ge3 La3 Ge4 86.524(15) 12_666 .
Ge3 La3 Ge4 89.078(13) . .
Ge4 La3 Ge4 135.11(2) 12_666 .
Ge3 La3 Ge1 93.876(17) 12_666 10_666
Ge3 La3 Ge1 96.065(15) . 10_666
Ge4 La3 Ge1 82.053(14) 12_666 10_666
Ge4 La3 Ge1 142.800(16) . 10_666
Ge3 La3 Ge1 96.065(15) 12_666 2
Ge3 La3 Ge1 93.875(17) . 2
Ge4 La3 Ge1 142.800(16) 12_666 2
Ge4 La3 Ge1 82.053(14) . 2
Ge1 La3 Ge1 60.88(2) 10_666 2
Ge3 La3 Mn2 127.534(18) 12_666 .
Ge3 La3 Mn2 44.564(18) . .
Ge4 La3 Mn2 44.543(15) 12_666 .
Ge4 La3 Mn2 108.689(13) . .
Ge1 La3 Mn2 100.413(15) 10_666 .
Ge1 La3 Mn2 134.843(19) 2 .
Ge3 La3 Mn2 44.562(18) 12_666 12_666
Ge3 La3 Mn2 127.535(18) . 12_666
Ge4 La3 Mn2 108.690(13) 12_666 12_666
Ge4 La3 Mn2 44.543(15) . 12_666
Ge1 La3 Mn2 134.843(19) 10_666 12_666
Ge1 La3 Mn2 100.413(15) 2 12_666
Mn2 La3 Mn2 118.17(3) . 12_666
Ge3 La3 La2 127.902(12) 12_666 2
Ge3 La3 La2 54.833(13) . 2
Ge4 La3 La2 141.135(11) 12_666 2
Ge4 La3 La2 50.735(12) . 2
Ge1 La3 La2 103.944(13) 10_666 2
Ge1 La3 La2 55.247(11) 2 2
Mn2 La3 La2 97.086(12) . 2
Mn2 La3 La2 94.172(11) 12_666 2
Ge3 La3 La2 54.833(13) 12_666 11_666
Ge3 La3 La2 127.902(12) . 11_666
Ge4 La3 La2 50.735(12) 12_666 11_666
Ge4 La3 La2 141.135(11) . 11_666
Ge1 La3 La2 55.247(11) 10_666 11_666
Ge1 La3 La2 103.944(13) 2 11_666
Mn2 La3 La2 94.172(11) . 11_666
Mn2 La3 La2 97.086(12) 12_666 11_666
La2 La3 La2 157.995(11) 2 11_666
Ge3 La3 La3 121.327(12) 12_666 11_566
Ge3 La3 La3 48.546(10) . 11_566
Ge4 La3 La3 94.086(12) 12_666 11_566
Ge4 La3 La3 52.327(8) . 11_566
Ge1 La3 La3 144.610(11) 10_666 11_566
Ge1 La3 La3 113.829(11) 2 11_566
Mn2 La3 La3 56.667(8) . 11_566
Mn2 La3 La3 79.800(15) 12_666 11_566
La2 La3 La3 58.738(5) 2 11_566
La2 La3 La3 142.079(6) 11_666 11_566
Ge3 La3 La3 48.546(10) 12_666 12_666
Ge3 La3 La3 121.328(12) . 12_666
Ge4 La3 La3 52.327(8) 12_666 12_666
Ge4 La3 La3 94.086(12) . 12_666
Ge1 La3 La3 113.829(11) 10_666 12_666
Ge1 La3 La3 144.611(11) 2 12_666
Mn2 La3 La3 79.799(15) . 12_666
Mn2 La3 La3 56.667(8) 12_666 12_666
La2 La3 La3 142.079(6) 2 12_666
La2 La3 La3 58.738(5) 11_666 12_666
La3 La3 La3 90.0 11_566 12_666
Ge4 La4 Ge4 87.15(2) . 12_665
Ge4 La4 Ge2 154.462(15) . 10_665
Ge4 La4 Ge2 85.131(13) 12_665 10_665
Ge4 La4 Ge2 85.131(13) . 2
Ge4 La4 Ge2 154.463(15) 12_665 2
Ge2 La4 Ge2 111.314(16) 10_665 2
Ge4 La4 Mn2 50.533(19) . 1_554
Ge4 La4 Mn2 48.755(18) 12_665 1_554
Ge2 La4 Mn2 132.547(16) 10_665 1_554
Ge2 La4 Mn2 109.400(16) 2 1_554
Ge4 La4 Mn2 48.755(18) . 12_666
Ge4 La4 Mn2 50.534(19) 12_665 12_666
Ge2 La4 Mn2 109.400(16) 10_665 12_666
Ge2 La4 Mn2 132.547(17) 2 12_666
Mn2 La4 Mn2 53.32(3) 1_554 12_666
Ge4 La4 Mn1 108.83(2) . 11_666
Ge4 La4 Mn1 52.569(19) 12_665 11_666
Ge2 La4 Mn1 48.339(16) 10_665 11_666
Ge2 La4 Mn1 152.454(19) 2 11_666
Mn2 La4 Mn1 97.55(2) 1_554 11_666
Mn2 La4 Mn1 61.12(2) 12_666 11_666
Ge4 La4 Mn1 52.569(19) . 2_554
Ge4 La4 Mn1 108.83(2) 12_665 2_554
Ge2 La4 Mn1 152.454(19) 10_665 2_554
Ge2 La4 Mn1 48.339(16) 2 2_554
Mn2 La4 Mn1 61.12(2) 1_554 2_554
Mn2 La4 Mn1 97.55(2) 12_666 2_554
Mn1 La4 Mn1 157.31(3) 11_666 2_554
Ge4 La4 Ge1 154.702(14) . 10_665
Ge4 La4 Ge1 82.277(13) 12_665 10_665
Ge2 La4 Ge1 47.179(15) 10_665 10_665
Ge2 La4 Ge1 94.608(14) 2 10_665
Mn2 La4 Ge1 106.736(17) 1_554 10_665
Mn2 La4 Ge1 131.416(17) 12_666 10_665
Mn1 La4 Ge1 82.629(19) 11_666 10_665
Mn1 La4 Ge1 109.710(19) 2_554 10_665
Ge4 La4 Ge1 82.277(13) . 2
Ge4 La4 Ge1 154.702(14) 12_665 2
Ge2 La4 Ge1 94.608(14) 10_665 2
Ge2 La4 Ge1 47.179(15) 2 2
Mn2 La4 Ge1 131.416(17) 1_554 2
Mn2 La4 Ge1 106.736(17) 12_666 2
Mn1 La4 Ge1 109.710(19) 11_666 2
Mn1 La4 Ge1 82.629(19) 2_554 2
Ge1 La4 Ge1 115.824(15) 10_665 2
Ge4 La4 La4 136.426(12) . 9_665
Ge4 La4 La4 136.425(12) 12_665 9_665
Ge2 La4 La4 55.657(8) 10_665 9_665
Ge2 La4 La4 55.657(8) 2 9_665
Mn2 La4 La4 153.340(16) 1_554 9_665
Mn2 La4 La4 153.340(16) 12_666 9_665
Mn1 La4 La4 101.343(15) 11_666 9_665
Mn1 La4 La4 101.343(15) 2_554 9_665
Ge1 La4 La4 57.912(7) 10_665 9_665
Ge1 La4 La4 57.912(7) 2 9_665
Ge4 La4 La1 108.073(11) . 2_554
Ge4 La4 La1 110.425(11) 12_665 2_554
Ge2 La4 La1 97.432(12) 10_665 2_554
Ge2 La4 La1 50.008(12) 2 2_554
Mn2 La4 La1 90.458(16) 1_554 2_554
Mn2 La4 La1 143.628(17) 12_666 2_554
Mn1 La4 La1 137.849(17) 11_666 2_554
Mn1 La4 La1 55.778(16) 2_554 2_554
Ge1 La4 La1 55.554(12) 10_665 2_554
Ge1 La4 La1 94.719(12) 2 2_554
La4 La4 La1 62.938(5) 9_665 2_554
La6 La5 Ge7 180.000(2) . 1_554
La6 La5 Ge2 78.84(3) . 2
Ge7 La5 Ge2 101.16(3) 1_554 2
La6 La5 Ge2 78.84(3) . 4
Ge7 La5 Ge2 101.16(3) 1_554 4
Ge2 La5 Ge2 87.853(13) 2 4
La6 La5 Ge2 78.84(3) . 3
Ge7 La5 Ge2 101.16(3) 1_554 3
Ge2 La5 Ge2 87.853(13) 2 3
Ge2 La5 Ge2 157.68(7) 4 3
La6 La5 Ge2 78.84(3) . .
Ge7 La5 Ge2 101.16(3) 1_554 .
Ge2 La5 Ge2 157.68(7) 2 .
Ge2 La5 Ge2 87.853(13) 4 .
Ge2 La5 Ge2 87.853(13) 3 .
La6 La5 Mn1 92.97(3) . 4_554
Ge7 La5 Mn1 87.03(3) 1_554 4_554
Ge2 La5 Mn1 134.656(11) 2 4_554
Ge2 La5 Mn1 46.941(6) 4 4_554
Ge2 La5 Mn1 134.656(11) 3 4_554
Ge2 La5 Mn1 46.940(6) . 4_554
La6 La5 Mn1 92.97(3) . 1_554
Ge7 La5 Mn1 87.03(3) 1_554 1_554
Ge2 La5 Mn1 134.656(11) 2 1_554
Ge2 La5 Mn1 134.656(11) 4 1_554
Ge2 La5 Mn1 46.941(6) 3 1_554
Ge2 La5 Mn1 46.940(6) . 1_554
Mn1 La5 Mn1 89.846(4) 4_554 1_554
La6 La5 Mn1 92.97(3) . 3_554
Ge7 La5 Mn1 87.03(3) 1_554 3_554
Ge2 La5 Mn1 46.941(6) 2 3_554
Ge2 La5 Mn1 134.656(11) 4 3_554
Ge2 La5 Mn1 46.941(6) 3 3_554
Ge2 La5 Mn1 134.656(11) . 3_554
Mn1 La5 Mn1 174.05(7) 4_554 3_554
Mn1 La5 Mn1 89.846(4) 1_554 3_554
La6 La5 Mn1 92.97(3) . 2_554
Ge7 La5 Mn1 87.03(3) 1_554 2_554
Ge2 La5 Mn1 46.941(6) 2 2_554
Ge2 La5 Mn1 46.941(6) 4 2_554
Ge2 La5 Mn1 134.656(11) 3 2_554
Ge2 La5 Mn1 134.656(11) . 2_554
Mn1 La5 Mn1 89.846(4) 4_554 2_554
Mn1 La5 Mn1 174.05(7) 1_554 2_554
Mn1 La5 Mn1 89.846(4) 3_554 2_554
La6 La5 Ge5 0.000(1) . .
Ge7 La5 Ge5 180.0 1_554 .
Ge2 La5 Ge5 78.84(3) 2 .
Ge2 La5 Ge5 78.84(3) 4 .
Ge2 La5 Ge5 78.84(3) 3 .
Ge2 La5 Ge5 78.84(3) . .
Mn1 La5 Ge5 92.97(3) 4_554 .
Mn1 La5 Ge5 92.97(3) 1_554 .
Mn1 La5 Ge5 92.97(3) 3_554 .
Mn1 La5 Ge5 92.97(3) 2_554 .
La6 La5 La1 128.17(2) . 1_554
Ge7 La5 La1 51.83(2) 1_554 1_554
Ge2 La5 La1 152.99(5) 2 1_554
Ge2 La5 La1 96.869(18) 4 1_554
Ge2 La5 La1 96.869(18) 3 1_554
Ge2 La5 La1 49.329(17) . 1_554
Mn1 La5 La1 54.039(17) 4_554 1_554
Mn1 La5 La1 54.039(17) 1_554 1_554
Mn1 La5 La1 121.54(4) 3_554 1_554
Mn1 La5 La1 121.54(4) 2_554 1_554
Ge5 La5 La1 128.17(2) . 1_554
La5 La6 Ge7 0.000(1) . 1_554
La5 La6 Ge5 180.000(2) . .
Ge7 La6 Ge5 180.0 1_554 .
La5 La6 Ge2 91.89(9) . 2
Ge7 La6 Ge2 91.89(9) 1_554 2
Ge5 La6 Ge2 88.11(9) . 2
La5 La6 Ge2 91.89(9) . 4
Ge7 La6 Ge2 91.89(9) 1_554 4
Ge5 La6 Ge2 88.11(9) . 4
Ge2 La6 Ge2 89.938(6) 2 4
La5 La6 Ge2 91.89(9) . 3
Ge7 La6 Ge2 91.89(9) 1_554 3
Ge5 La6 Ge2 88.11(9) . 3
Ge2 La6 Ge2 89.938(6) 2 3
Ge2 La6 Ge2 176.22(18) 4 3
La5 La6 Ge2 91.89(9) . .
Ge7 La6 Ge2 91.89(9) 1_554 .
Ge5 La6 Ge2 88.11(9) . .
Ge2 La6 Ge2 176.22(18) 2 .
Ge2 La6 Ge2 89.938(6) 4 .
Ge2 La6 Ge2 89.938(6) 3 .
La5 La6 Mn1 78.73(8) . 4_554
Ge7 La6 Mn1 78.73(8) 1_554 4_554
Ge5 La6 Mn1 101.27(8) . 4_554
Ge2 La6 Mn1 134.39(3) 2 4_554
Ge2 La6 Mn1 46.633(10) 4 4_554
Ge2 La6 Mn1 134.39(3) 3 4_554
Ge2 La6 Mn1 46.633(10) . 4_554
La5 La6 Mn1 78.73(8) . 1_554
Ge7 La6 Mn1 78.73(8) 1_554 1_554
Ge5 La6 Mn1 101.27(8) . 1_554
Ge2 La6 Mn1 134.39(3) 2 1_554
Ge2 La6 Mn1 134.39(3) 4 1_554
Ge2 La6 Mn1 46.633(10) 3 1_554
Ge2 La6 Mn1 46.633(10) . 1_554
Mn1 La6 Mn1 87.81(3) 4_554 1_554
La5 La6 Mn1 78.73(8) . 2_554
Ge7 La6 Mn1 78.73(8) 1_554 2_554
Ge5 La6 Mn1 101.27(8) . 2_554
Ge2 La6 Mn1 46.633(10) 2 2_554
Ge2 La6 Mn1 46.633(10) 4 2_554
Ge2 La6 Mn1 134.39(3) 3 2_554
Ge2 La6 Mn1 134.39(3) . 2_554
Mn1 La6 Mn1 87.81(3) 4_554 2_554
Mn1 La6 Mn1 157.47(16) 1_554 2_554
La5 La6 Mn1 78.73(8) . 3_554
Ge7 La6 Mn1 78.73(8) 1_554 3_554
Ge5 La6 Mn1 101.27(8) . 3_554
Ge2 La6 Mn1 46.633(10) 2 3_554
Ge2 La6 Mn1 134.39(3) 4 3_554
Ge2 La6 Mn1 46.633(10) 3 3_554
Ge2 La6 Mn1 134.39(3) . 3_554
Mn1 La6 Mn1 157.47(16) 4_554 3_554
Mn1 La6 Mn1 87.81(3) 1_554 3_554
Mn1 La6 Mn1 87.81(3) 2_554 3_554
La5 La6 La2 127.68(6) . 2
Ge7 La6 La2 127.68(6) 1_554 2
Ge5 La6 La2 52.32(6) . 2
Ge2 La6 La2 54.58(4) 2 2
Ge2 La6 La2 54.58(4) 4 2
Ge2 La6 La2 122.63(10) 3 2
Ge2 La6 La2 122.63(10) . 2
Mn1 La6 La2 96.86(4) 4_554 2
Mn1 La6 La2 153.59(14) 1_554 2
Mn1 La6 La2 48.94(3) 2_554 2
Mn1 La6 La2 96.86(4) 3_554 2
Ge3 Mn1 Ge2 117.59(3) 2 3_556
Ge3 Mn1 Ge2 117.59(3) 2 1_556
Ge2 Mn1 Ge2 111.44(4) 3_556 1_556
Ge3 Mn1 Ge4 102.44(4) 2 2_556
Ge2 Mn1 Ge4 102.31(3) 3_556 2_556
Ge2 Mn1 Ge4 102.31(3) 1_556 2_556
Ge3 Mn1 La2 166.07(4) 2 1_556
Ge2 Mn1 La2 68.13(2) 3_556 1_556
Ge2 Mn1 La2 68.13(2) 1_556 1_556
Ge4 Mn1 La2 63.64(2) 2_556 1_556
Ge3 Mn1 La4 80.24(2) 2 2_556
Ge2 Mn1 La4 159.24(4) 3_556 2_556
Ge2 Mn1 La4 63.977(15) 1_556 2_556
Ge4 Mn1 La4 61.289(17) 2_556 2_556
La2 Mn1 La4 92.13(2) 1_556 2_556
Ge3 Mn1 La4 80.24(2) 2 12_656
Ge2 Mn1 La4 63.977(15) 3_556 12_656
Ge2 Mn1 La4 159.24(4) 1_556 12_656
Ge4 Mn1 La4 61.289(17) 2_556 12_656
La2 Mn1 La4 92.13(2) 1_556 12_656
La4 Mn1 La4 112.47(3) 2_556 12_656
Ge3 Mn1 La1 61.61(2) 2 .
Ge2 Mn1 La1 124.62(4) 3_556 .
Ge2 Mn1 La1 59.521(18) 1_556 .
Ge4 Mn1 La1 132.89(2) 2_556 .
La2 Mn1 La1 127.15(2) 1_556 .
La4 Mn1 La1 72.054(10) 2_556 .
La4 Mn1 La1 140.69(3) 12_656 .
Ge3 Mn1 La1 61.61(2) 2 3
Ge2 Mn1 La1 59.521(18) 3_556 3
Ge2 Mn1 La1 124.62(4) 1_556 3
Ge4 Mn1 La1 132.89(2) 2_556 3
La2 Mn1 La1 127.15(2) 1_556 3
La4 Mn1 La1 140.69(3) 2_556 3
La4 Mn1 La1 72.053(10) 12_656 3
La1 Mn1 La1 81.19(2) . 3
Ge3 Mn1 La5 116.32(5) 2 1_556
Ge2 Mn1 La5 60.49(2) 3_556 1_556
Ge2 Mn1 La5 60.49(2) 1_556 1_556
Ge4 Mn1 La5 141.25(5) 2_556 1_556
La2 Mn1 La5 77.61(4) 1_556 1_556
La4 Mn1 La5 123.341(16) 2_556 1_556
La4 Mn1 La5 123.341(16) 12_656 1_556
La1 Mn1 La5 71.34(3) . 1_556
La1 Mn1 La5 71.34(3) 3 1_556
Ge3 Mn1 La6 124.61(9) 2 1_556
Ge2 Mn1 La6 58.21(3) 3_556 1_556
Ge2 Mn1 La6 58.21(3) 1_556 1_556
Ge4 Mn1 La6 132.95(8) 2_556 1_556
La2 Mn1 La6 69.32(8) 1_556 1_556
La4 Mn1 La6 122.14(2) 2_556 1_556
La4 Mn1 La6 122.14(2) 12_656 1_556
La1 Mn1 La6 77.45(6) . 1_556
La1 Mn1 La6 77.45(6) 3 1_556
La5 Mn1 La6 8.29(7) 1_556 1_556
Ge3 Mn2 Ge4 111.23(2) . 12_666
Ge3 Mn2 Ge4 111.23(2) . 11_566
Ge4 Mn2 Ge4 115.43(4) 12_666 11_566
Ge3 Mn2 Mn2 148.81(2) . 2_565
Ge4 Mn2 Mn2 59.129(18) 12_666 2_565
Ge4 Mn2 Mn2 59.129(18) 11_566 2_565
Ge3 Mn2 Ge4 102.44(4) . 1_556
Ge4 Mn2 Ge4 107.78(2) 12_666 1_556
Ge4 Mn2 Ge4 107.78(2) 11_566 1_556
Mn2 Mn2 Ge4 108.74(2) 2_565 1_556
Ge3 Mn2 Mn2 141.99(2) . 12_667
Ge4 Mn2 Mn2 58.66(3) 12_666 12_667
Ge4 Mn2 Mn2 105.45(2) 11_566 12_667
Mn2 Mn2 Mn2 62.281(19) 2_565 12_667
Ge4 Mn2 Mn2 55.68(3) 1_556 12_667
Ge3 Mn2 Mn2 141.99(2) . 11_567
Ge4 Mn2 Mn2 105.45(2) 12_666 11_567
Ge4 Mn2 Mn2 58.66(3) 11_566 11_567
Mn2 Mn2 Mn2 62.281(19) 2_565 11_567
Ge4 Mn2 Mn2 55.68(3) 1_556 11_567
Mn2 Mn2 Mn2 55.44(4) 12_667 11_567
Ge3 Mn2 La4 79.22(2) . 11_566
Ge4 Mn2 La4 167.96(4) 12_666 11_566
Ge4 Mn2 La4 63.682(10) 11_566 11_566
Mn2 Mn2 La4 115.039(15) 2_565 11_566
Ge4 Mn2 La4 62.870(16) 1_556 11_566
Mn2 Mn2 La4 109.47(4) 12_667 11_566
Mn2 Mn2 La4 63.340(16) 11_567 11_566
Ge3 Mn2 La4 79.22(2) . 1_556
Ge4 Mn2 La4 63.682(10) 12_666 1_556
Ge4 Mn2 La4 167.96(4) 11_566 1_556
Mn2 Mn2 La4 115.039(15) 2_565 1_556
Ge4 Mn2 La4 62.870(16) 1_556 1_556
Mn2 Mn2 La4 63.340(16) 12_667 1_556
Mn2 Mn2 La4 109.47(4) 11_567 1_556
La4 Mn2 La4 114.41(3) 11_566 1_556
Ge3 Mn2 La3 54.949(18) . .
Ge4 Mn2 La3 60.340(17) 12_666 .
Ge4 Mn2 La3 115.74(3) 11_566 .
Mn2 Mn2 La3 100.201(15) 2_565 .
Ge4 Mn2 La3 135.75(2) 1_556 .
Mn2 Mn2 La3 116.21(3) 12_667 .
Mn2 Mn2 La3 162.36(3) 11_567 .
La4 Mn2 La3 131.52(3) 11_566 .
La4 Mn2 La3 74.873(11) 1_556 .
Ge3 Mn2 La3 54.949(18) . 11_566
Ge4 Mn2 La3 115.74(3) 12_666 11_566
Ge4 Mn2 La3 60.340(17) 11_566 11_566
Mn2 Mn2 La3 100.201(15) 2_565 11_566
Ge4 Mn2 La3 135.75(2) 1_556 11_566
Mn2 Mn2 La3 162.36(3) 12_667 11_566
Mn2 Mn2 La3 116.21(3) 11_567 11_566
La4 Mn2 La3 74.873(11) 11_566 11_566
La4 Mn2 La3 131.52(3) 1_556 11_566
La3 Mn2 La3 66.667(17) . 11_566
Ge2 Ge1 La3 120.411(10) . 10_556
Ge2 Ge1 La3 120.411(10) . 2
La3 Ge1 La3 119.11(2) 10_556 2
Ge2 Ge1 La1 114.89(3) . .
La3 Ge1 La1 76.531(12) 10_556 .
La3 Ge1 La1 76.531(12) 2 .
Ge2 Ge1 La2 63.118(16) . .
La3 Ge1 La2 139.00(2) 10_556 .
La3 Ge1 La2 71.045(8) 2 .
La1 Ge1 La2 67.293(13) . .
Ge2 Ge1 La2 63.117(16) . 4
La3 Ge1 La2 71.046(8) 10_556 4
La3 Ge1 La2 139.00(2) 2 4
La1 Ge1 La2 67.294(13) . 4
La2 Ge1 La2 77.523(18) . 4
Ge2 Ge1 La4 62.473(16) . 10
La3 Ge1 La4 77.968(8) 10_556 10
La3 Ge1 La4 135.034(19) 2 10
La1 Ge1 La4 146.995(9) . 10
La2 Ge1 La4 125.08(2) . 10
La2 Ge1 La4 84.809(11) 4 10
Ge2 Ge1 La4 62.473(16) . 2
La3 Ge1 La4 135.034(19) 10_556 2
La3 Ge1 La4 77.968(8) 2 2
La1 Ge1 La4 146.995(9) . 2
La2 Ge1 La4 84.809(11) . 2
La2 Ge1 La4 125.08(2) 4 2
La4 Ge1 La4 64.177(15) 10 2
Ge2 Ge1 La1 123.83(3) . 9_556
La3 Ge1 La1 74.717(12) 10_556 9_556
La3 Ge1 La1 74.717(12) 2 9_556
La1 Ge1 La1 121.29(2) . 9_556
La2 Ge1 La1 141.210(9) . 9_556
La2 Ge1 La1 141.210(9) 4 9_556
La4 Ge1 La1 70.576(13) 10 9_556
La4 Ge1 La1 70.576(13) 2 9_556
Ge1 Ge2 Mn1 112.75(2) . 1_554
Ge1 Ge2 Mn1 112.75(2) . 4_554
Mn1 Ge2 Mn1 134.48(5) 1_554 4_554
Ge1 Ge2 La1 141.30(3) . 1_554
Mn1 Ge2 La1 72.96(2) 1_554 1_554
Mn1 Ge2 La1 72.96(2) 4_554 1_554
Ge1 Ge2 La6 129.39(9) . .
Mn1 Ge2 La6 75.16(4) 1_554 .
Mn1 Ge2 La6 75.16(4) 4_554 .
La1 Ge2 La6 89.31(9) 1_554 .
Ge1 Ge2 La5 138.66(4) . .
Mn1 Ge2 La5 72.57(2) 1_554 .
Mn1 Ge2 La5 72.57(2) 4_554 .
La1 Ge2 La5 80.04(4) 1_554 .
La6 Ge2 La5 9.27(8) . .
Ge1 Ge2 La4 70.348(17) . 10
Mn1 Ge2 La4 131.35(3) 1_554 10
Mn1 Ge2 La4 67.68(2) 4_554 10
La1 Ge2 La4 77.934(14) 1_554 10
La6 Ge2 La4 142.77(3) . 10
La5 Ge2 La4 138.64(2) . 10
Ge1 Ge2 La4 70.348(17) . 2
Mn1 Ge2 La4 67.68(2) 1_554 2
Mn1 Ge2 La4 131.35(3) 4_554 2
La1 Ge2 La4 77.934(14) 1_554 2
La6 Ge2 La4 142.77(3) . 2
La5 Ge2 La4 138.64(2) . 2
La4 Ge2 La4 68.687(16) 10 2
Ge1 Ge2 La2 69.366(16) . 4
Mn1 Ge2 La2 137.12(3) 1_554 4
Mn1 Ge2 La2 61.40(2) 4_554 4
La1 Ge2 La2 133.771(13) 1_554 4
La6 Ge2 La2 73.05(7) . 4
La5 Ge2 La2 79.88(3) . 4
La4 Ge2 La2 90.775(11) 10 4
La4 Ge2 La2 139.00(2) 2 4
Ge1 Ge2 La2 69.366(16) . .
Mn1 Ge2 La2 61.40(2) 1_554 .
Mn1 Ge2 La2 137.12(3) 4_554 .
La1 Ge2 La2 133.771(13) 1_554 .
La6 Ge2 La2 73.05(7) . .
La5 Ge2 La2 79.88(3) . .
La4 Ge2 La2 139.00(2) 10 .
La4 Ge2 La2 90.775(11) 2 .
La2 Ge2 La2 82.128(19) 4 .
Mn1 Ge3 Mn2 82.16(4) 2 .
Mn1 Ge3 La3 134.559(15) 2 .
Mn2 Ge3 La3 80.49(2) . .
Mn1 Ge3 La3 134.559(15) 2 11_566
Mn2 Ge3 La3 80.49(2) . 11_566
La3 Ge3 La3 82.908(19) . 11_566
Mn1 Ge3 La1 74.69(2) 2 4
Mn2 Ge3 La1 127.374(17) . 4
La3 Ge3 La1 145.95(2) . 4
La3 Ge3 La1 83.337(11) 11_566 4
Mn1 Ge3 La1 74.69(2) 2 2
Mn2 Ge3 La1 127.373(17) . 2
La3 Ge3 La1 83.338(11) . 2
La3 Ge3 La1 145.95(2) 11_566 2
La1 Ge3 La1 91.03(2) 4 2
Mn1 Ge3 La2 129.79(3) 2 2
Mn2 Ge3 La2 148.06(3) . 2
La3 Ge3 La2 75.729(14) . 2
La3 Ge3 La2 75.729(14) 11_566 2
La1 Ge3 La2 70.739(14) 4 2
La1 Ge3 La2 70.739(14) 2 2
Mn2 Ge4 Mn2 61.75(4) 12_666 11_566
Mn2 Ge4 Mn2 65.66(3) 12_666 1_554
Mn2 Ge4 Mn2 65.66(3) 11_566 1_554
Mn2 Ge4 Mn1 126.80(3) 12_666 2_554
Mn2 Ge4 Mn1 126.80(3) 11_566 2_554
Mn2 Ge4 Mn1 72.96(3) 1_554 2_554
Mn2 Ge4 La2 145.97(2) 12_666 2
Mn2 Ge4 La2 145.97(2) 11_566 2
Mn2 Ge4 La2 133.77(3) 1_554 2
Mn1 Ge4 La2 60.81(2) 2_554 2
Mn2 Ge4 La4 120.53(3) 12_666 11_565
Mn2 Ge4 La4 67.563(19) 11_566 11_565
Mn2 Ge4 La4 66.596(13) 1_554 11_565
Mn1 Ge4 La4 66.142(12) 2_554 11_565
La2 Ge4 La4 93.281(14) 2 11_565
Mn2 Ge4 La4 67.563(19) 12_666 .
Mn2 Ge4 La4 120.53(3) 11_566 .
Mn2 Ge4 La4 66.596(13) 1_554 .
Mn1 Ge4 La4 66.141(12) 2_554 .
La2 Ge4 La4 93.280(14) 2 .
La4 Ge4 La4 120.19(2) 11_565 .
Mn2 Ge4 La3 75.12(2) 12_666 .
Mn2 Ge4 La3 111.74(3) 11_566 .
Mn2 Ge4 La3 136.354(15) 1_554 .
Mn1 Ge4 La3 121.25(2) 2_554 .
La2 Ge4 La3 74.395(14) 2 .
La4 Ge4 La3 156.043(17) 11_565 .
La4 Ge4 La3 81.622(6) . .
Mn2 Ge4 La3 111.74(3) 12_666 11_566
Mn2 Ge4 La3 75.12(2) 11_566 11_566
Mn2 Ge4 La3 136.354(15) 1_554 11_566
Mn1 Ge4 La3 121.24(2) 2_554 11_566
La2 Ge4 La3 74.395(14) 2 11_566
La4 Ge4 La3 81.622(6) 11_565 11_566
La4 Ge4 La3 156.043(17) . 11_566
La3 Ge4 La3 75.345(15) . 11_566
Ge6 Ge5 Ge7 0.000(1) . .
Ge6 Ge5 La6 180.000(1) . .
Ge7 Ge5 La6 180.000(1) . .
Ge6 Ge5 La2 103.11(11) . 4
Ge7 Ge5 La2 103.11(11) . 4
La6 Ge5 La2 76.89(11) . 4
Ge6 Ge5 La2 103.11(11) . 3
Ge7 Ge5 La2 103.11(11) . 3
La6 Ge5 La2 76.89(11) . 3
La2 Ge5 La2 153.8(2) 4 3
Ge6 Ge5 La2 103.11(11) . 2
Ge7 Ge5 La2 103.11(11) . 2
La6 Ge5 La2 76.89(11) . 2
La2 Ge5 La2 87.05(5) 4 2
La2 Ge5 La2 87.05(5) 3 2
Ge6 Ge5 La2 103.11(11) . .
Ge7 Ge5 La2 103.11(11) . .
La6 Ge5 La2 76.89(11) . .
La2 Ge5 La2 87.05(5) 4 .
La2 Ge5 La2 87.05(5) 3 .
La2 Ge5 La2 153.8(2) 2 .
Ge6 Ge5 La5 180.000(1) . .
Ge7 Ge5 La5 180.000(1) . .
La6 Ge5 La5 0.0 . .
La2 Ge5 La5 76.89(11) 4 .
La2 Ge5 La5 76.89(11) 3 .
La2 Ge5 La5 76.89(11) 2 .
La2 Ge5 La5 76.89(11) . .
Ge5 Ge6 Ge7 180.000(2) . .
Ge5 Ge6 La2 61.69(3) . 4
Ge7 Ge6 La2 118.31(3) . 4
Ge5 Ge6 La2 61.69(3) . .
Ge7 Ge6 La2 118.31(3) . .
La2 Ge6 La2 77.01(3) 4 .
Ge5 Ge6 La2 61.69(3) . 3
Ge7 Ge6 La2 118.31(3) . 3
La2 Ge6 La2 123.39(7) 4 3
La2 Ge6 La2 77.01(3) . 3
Ge5 Ge6 La2 61.69(3) . 2
Ge7 Ge6 La2 118.31(3) . 2
La2 Ge6 La2 77.01(3) 4 2
La2 Ge6 La2 123.39(7) . 2
La2 Ge6 La2 77.01(3) 3 2
Ge5 Ge6 La1 111.67(3) . .
Ge7 Ge6 La1 68.33(3) . .
La2 Ge6 La1 66.203(6) 4 .
La2 Ge6 La1 66.203(6) . .
La2 Ge6 La1 138.907(11) 3 .
La2 Ge6 La1 138.907(11) 2 .
Ge5 Ge6 La1 111.67(4) . 2
Ge7 Ge6 La1 68.33(3) . 2
La2 Ge6 La1 138.907(11) 4 2
La2 Ge6 La1 138.907(11) . 2
La2 Ge6 La1 66.203(6) 3 2
La2 Ge6 La1 66.203(6) 2 2
La1 Ge6 La1 136.67(7) . 2
Ge5 Ge6 La1 111.67(3) . 4
Ge7 Ge6 La1 68.33(3) . 4
La2 Ge6 La1 66.203(6) 4 4
La2 Ge6 La1 138.907(11) . 4
La2 Ge6 La1 138.907(11) 3 4
La2 Ge6 La1 66.203(6) 2 4
La1 Ge6 La1 82.17(2) . 4
La1 Ge6 La1 82.17(2) 2 4
Ge5 Ge6 La1 111.67(4) . 3
Ge7 Ge6 La1 68.33(3) . 3
La2 Ge6 La1 138.907(11) 4 3
La2 Ge6 La1 66.203(6) . 3
La2 Ge6 La1 66.203(6) 3 3
La2 Ge6 La1 138.907(11) 2 3
La1 Ge6 La1 82.17(2) . 3
La1 Ge6 La1 82.17(2) 2 3
La1 Ge6 La1 136.67(7) 4 3
Ge6 Ge7 La5 180.000(1) . 1_556
Ge6 Ge7 Ge5 0.000(1) . .
La5 Ge7 Ge5 180.000(1) 1_556 .
Ge6 Ge7 La6 180.000(1) . 1_556
La5 Ge7 La6 0.0 1_556 1_556
Ge5 Ge7 La6 180.000(1) . 1_556
Ge6 Ge7 La1 86.33(10) . .
La5 Ge7 La1 93.67(10) 1_556 .
Ge5 Ge7 La1 86.33(10) . .
La6 Ge7 La1 93.67(10) 1_556 .
Ge6 Ge7 La1 86.33(10) . 2
La5 Ge7 La1 93.67(10) 1_556 2
Ge5 Ge7 La1 86.33(10) . 2
La6 Ge7 La1 93.67(10) 1_556 2
La1 Ge7 La1 172.7(2) . 2
Ge6 Ge7 La1 86.33(10) . 4
La5 Ge7 La1 93.67(10) 1_556 4
Ge5 Ge7 La1 86.33(10) . 4
La6 Ge7 La1 93.67(10) 1_556 4
La1 Ge7 La1 89.765(13) . 4
La1 Ge7 La1 89.765(13) 2 4
Ge6 Ge7 La1 86.33(10) . 3
La5 Ge7 La1 93.67(10) 1_556 3
Ge5 Ge7 La1 86.33(10) . 3
La6 Ge7 La1 93.67(10) 1_556 3
La1 Ge7 La1 89.765(13) . 3
La1 Ge7 La1 89.765(13) 2 3
La1 Ge7 La1 172.7(2) 4 3
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
La1 Ge2 3.1065(7) 1_556
La1 Ge3 3.1435(5) 3
La1 Ge3 3.1435(5) 2
La1 Ge7 3.1780(5) .
La1 Ge1 3.3344(7) .
La1 Ge6 3.4126(9) .
La1 Mn1 3.4463(8) .
La1 Mn1 3.4463(8) 4
La1 Ge1 3.4673(7) 9_556
La1 La2 3.7072(4) .
La1 La2 3.7072(4) 4
La1 La4 3.9652(3) 10_556
La2 Mn1 3.0262(10) 1_554
La2 Ge5 3.0513(14) .
La2 Ge4 3.1057(7) 2
La2 Ge2 3.1988(5) 3
La2 Ge2 3.1989(5) .
La2 Ge3 3.2590(7) 2
La2 Ge1 3.3564(5) 3
La2 Ge1 3.3564(5) .
La2 Ge6 3.3754(11) .
La2 La1 3.7072(4) 3
La2 La6 3.755(3) .
La3 Ge3 3.0286(5) 12_666
La3 Ge3 3.0287(5) .
La3 Ge4 3.2807(5) 12_666
La3 Ge4 3.2807(5) .
La3 Ge1 3.2926(4) 10_666
La3 Ge1 3.2926(4) 2
La3 Mn2 3.6487(8) .
La3 Mn2 3.6487(8) 12_666
La3 La2 3.8636(3) 2
La3 La2 3.8636(3) 11_666
La3 La3 4.0100(5) 11_566
La3 La3 4.0100(5) 12_666
La4 Ge4 3.1570(4) .
La4 Ge4 3.1570(4) 12_665
La4 Ge2 3.1977(5) 10_665
La4 Ge2 3.1977(5) 2
La4 Mn2 3.2554(6) 1_554
La4 Mn2 3.2554(6) 12_666
La4 Mn1 3.2920(6) 11_666
La4 Mn1 3.2920(6) 2_554
La4 Ge1 3.3959(6) 10_665
La4 Ge1 3.3959(6) 2
La4 La4 3.6080(6) 9_665
La4 La1 3.9652(3) 2_554
La5 La6 0.510(4) .
La5 Ge7 2.290(6) 1_554
La5 Ge2 3.1664(7) 2
La5 Ge2 3.1664(7) 4
La5 Ge2 3.1664(7) 3
La5 Ge2 3.1664(7) .
La5 Mn1 3.4716(10) 4_554
La5 Mn1 3.4716(10) 1_554
La5 Mn1 3.4716(10) 3_554
La5 Mn1 3.4716(10) 2_554
La5 Ge5 3.498(6) .
La5 La1 4.0340(12) 1_554
La6 Ge7 2.800(7) 1_554
La6 Ge5 2.987(8) .
La6 Ge2 3.1083(6) 2
La6 Ge2 3.1082(6) 4
La6 Ge2 3.1082(6) 3
La6 Ge2 3.1083(6) .
La6 Mn1 3.5350(14) 4_554
La6 Mn1 3.5350(14) 1_554
La6 Mn1 3.5350(14) 2_554
La6 Mn1 3.5350(14) 3_554
La6 La2 3.755(3) 2
Mn1 Ge3 2.4683(11) 2
Mn1 Ge2 2.6585(6) 3_556
Mn1 Ge2 2.6585(6) 1_556
Mn1 Ge4 2.8584(12) 2_556
Mn1 La2 3.0261(10) 1_556
Mn1 La4 3.2920(6) 2_556
Mn1 La4 3.2920(6) 12_656
Mn1 La1 3.4463(8) 3
Mn1 La5 3.4715(10) 1_556
Mn1 La6 3.5350(14) 1_556
Mn2 Ge3 2.5960(11) .
Mn2 Ge4 2.6482(7) 12_666
Mn2 Ge4 2.6482(7) 11_566
Mn2 Mn2 2.7177(18) 2_565
Mn2 Ge4 2.7385(11) 1_556
Mn2 Mn2 2.9213(16) 12_667
Mn2 Mn2 2.9213(16) 11_567
Mn2 La4 3.2555(6) 11_566
Mn2 La4 3.2555(6) 1_556
Mn2 La3 3.6487(8) 11_566
Ge1 Ge2 2.6449(9) .
Ge1 La3 3.2926(4) 10_556
Ge1 La3 3.2926(4) 2
Ge1 La2 3.3564(5) 4
Ge1 La4 3.3959(6) 10
Ge1 La4 3.3959(6) 2
Ge1 La1 3.4673(7) 9_556
Ge2 Mn1 2.6585(6) 1_554
Ge2 Mn1 2.6585(6) 4_554
Ge2 La1 3.1065(7) 1_554
Ge2 La4 3.1977(5) 10
Ge2 La4 3.1977(5) 2
Ge2 La2 3.1989(5) 4
Ge3 Mn1 2.4683(11) 2
Ge3 La3 3.0287(5) 11_566
Ge3 La1 3.1435(5) 4
Ge3 La1 3.1435(5) 2
Ge3 La2 3.2589(7) 2
Ge4 Mn2 2.6482(7) 12_666
Ge4 Mn2 2.6482(7) 11_566
Ge4 Mn2 2.7385(11) 1_554
Ge4 Mn1 2.8584(12) 2_554
Ge4 La2 3.1058(7) 2
Ge4 La4 3.1570(4) 11_565
Ge4 La3 3.2807(5) 11_566
Ge5 Ge6 0.908(6) .
Ge5 Ge7 2.372(8) .
Ge5 La2 3.0513(14) 4
Ge5 La2 3.0513(14) 3
Ge5 La2 3.0513(14) 2
Ge6 Ge7 1.463(6) .
Ge6 La2 3.3754(11) 4
Ge6 La2 3.3754(11) 3
Ge6 La2 3.3754(11) 2
Ge6 La1 3.4126(9) 2
Ge6 La1 3.4126(9) 4
Ge6 La1 3.4126(9) 3
Ge7 La5 2.290(6) 1_556
Ge7 La6 2.800(7) 1_556
Ge7 La1 3.1780(5) 2
Ge7 La1 3.1780(5) 4
Ge7 La1 3.1780(5) 3
