#------------------------------------------------------------------------------
#$Date: 2021-06-14 12:21:27 +0300 (Mon, 14 Jun 2021) $
#$Revision: 266435 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/34/1563404.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1563404
loop_
_publ_author_name
'Puhakainen, Kati'
'Boström, Magnus'
'Groy, Thomas L.'
'Häussermann, Ulrich'
_publ_section_title
;
 A new phase in the system lithium--aluminum: Characterization of
 orthorhombic Li2Al
;
_journal_issue                   11
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              2528
_journal_page_last               2533
_journal_paper_doi               10.1016/j.jssc.2010.08.029
_journal_volume                  183
_journal_year                    2010
_chemical_formula_moiety         '4(Al), 9(Li)'
_chemical_formula_sum            'Al4 Li9'
_chemical_formula_weight         170.38
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 105.19(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   18.916(4)
_cell_length_b                   4.5041(11)
_cell_length_c                   5.4249(14)
_cell_measurement_reflns_used    5681
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      24.85
_cell_measurement_theta_min      2.23
_cell_volume                     446.1(2)
_computing_cell_refinement       'SAINT Version 6.45A (Bruker, 2003)'
_computing_data_collection       'SMART V5.632'
_computing_data_reduction        'SAINT Version 6.45A (Bruker, 2003)'
_computing_molecular_graphics    'SHELXTL Version 6.14 (Sheldrick, 2003b)'
_computing_publication_material  'SHELXTL Version 6.14 (Sheldrick, 2003b)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART APEX'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0197
_diffrn_reflns_av_sigmaI/netI    0.0269
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_k_min       -5
_diffrn_reflns_limit_l_max       6
_diffrn_reflns_limit_l_min       -6
_diffrn_reflns_number            790
_diffrn_reflns_theta_full        24.85
_diffrn_reflns_theta_max         24.85
_diffrn_reflns_theta_min         2.23
_exptl_absorpt_coefficient_mu    0.42
_exptl_absorpt_correction_T_max  0.93
_exptl_absorpt_correction_T_min  0.86
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS Version 2.10 (Sheldrick, 2003a)'
_exptl_crystal_colour            'metallic grey'
_exptl_crystal_density_diffrn    1.269
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             158
_exptl_crystal_size_max          0.367
_exptl_crystal_size_mid          0.253
_exptl_crystal_size_min          0.140
_refine_diff_density_max         0.129
_refine_diff_density_min         -0.160
_refine_diff_density_rms         0.051
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.120
_refine_ls_matrix_type           full
_refine_ls_number_parameters     41
_refine_ls_number_reflns         452
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.120
_refine_ls_R_factor_all          0.0181
_refine_ls_R_factor_gt           0.0170
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0155P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0413
_refine_ls_wR_factor_ref         0.0419
_reflns_number_gt                424
_reflns_number_total             452
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            JSSC-2010-183-2528.cif
_cod_data_source_block           c2m
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the built-in table derived from the
CIF Core dictionary named 'cif_core.dic' version 2.4.5 last updated
on 2014-11-21.

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_sg_symbol_H-M      'C 2/m'
_cod_database_code               1563404
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Al1 Al 0.349703(18) 0.5000 0.78622(6) 0.01579(14) Uani 1 2 d S . .
Al2 Al 0.385380(14) 0.0000 0.06429(5) 0.01656(14) Uani 1 2 d S . .
Li1 Li 0.5000 0.5000 0.0000 0.0263(7) Uani 1 4 d S . .
Li2 Li 0.41440(11) 0.5000 0.3590(4) 0.0186(4) Uani 1 2 d S . .
Li3 Li 0.23302(10) 0.0000 0.8431(4) 0.0301(6) Uani 1 2 d S . .
Li4 Li 0.30810(11) 0.0000 0.4765(4) 0.0215(5) Uani 1 2 d S . .
Li5 Li 0.45656(12) 0.0000 0.6745(4) 0.0266(5) Uani 1 2 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Al Al 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Al2 Al1 Al2 113.29(3) 1_566 1_556
Al2 Al1 Li1 71.779(18) 1_566 1_556
Al2 Al1 Li1 71.779(19) 1_556 1_556
Al2 Al1 Li4 176.91(3) 1_566 .
Al2 Al1 Li4 69.71(4) 1_556 .
Li1 Al1 Li4 110.32(4) 1_556 .
Li4 Al1 Li4 107.27(7) . 1_565
Al2 Al1 Li3 73.07(2) 1_566 7_557
Li1 Al1 Li3 113.36(5) 1_556 7_557
Li4 Al1 Li3 107.66(5) . 7_557
Al2 Al1 Li2 110.62(3) 1_566 .
Al2 Al1 Li2 110.62(2) 1_556 .
Li1 Al1 Li2 74.48(5) 1_556 .
Li4 Al1 Li2 68.28(4) . .
Li3 Al1 Li2 172.16(6) 7_557 .
Al2 Al1 Li4 110.08(3) 1_566 7_556
Li1 Al1 Li4 176.01(4) 1_556 7_556
Li4 Al1 Li4 67.67(5) . 7_556
Li3 Al1 Li4 70.63(6) 7_557 7_556
Li2 Al1 Li4 101.53(7) . 7_556
Al2 Al1 Li2 56.700(14) 1_566 1_556
Li1 Al1 Li2 58.43(5) 1_556 1_556
Li4 Al1 Li2 126.25(3) . 1_556
Li3 Al1 Li2 54.92(6) 7_557 1_556
Li2 Al1 Li2 132.92(8) . 1_556
Li4 Al1 Li2 125.56(7) 7_556 1_556
Al2 Al1 Li5 128.18(4) 1_566 .
Al2 Al1 Li5 55.81(4) 1_556 .
Li1 Al1 Li5 56.52(4) 1_556 .
Li4 Al1 Li5 53.82(7) . .
Li4 Al1 Li5 123.18(4) 1_565 .
Li3 Al1 Li5 128.75(4) 7_557 .
Li2 Al1 Li5 54.90(4) . .
Li4 Al1 Li5 121.30(5) 7_556 .
Li2 Al1 Li5 95.11(6) 1_556 .
Li5 Al1 Li5 89.87(6) . 1_565
Al2 Al1 Li3 127.38(3) 1_566 .
Al2 Al1 Li3 55.96(3) 1_556 .
Li1 Al1 Li3 127.74(3) 1_556 .
Li4 Al1 Li3 53.35(6) . .
Li4 Al1 Li3 121.87(4) 1_565 .
Li3 Al1 Li3 54.33(4) 7_557 .
Li2 Al1 Li3 121.40(4) . .
Li4 Al1 Li3 54.21(4) 7_556 .
Li2 Al1 Li3 90.26(5) 1_556 .
Li5 Al1 Li3 90.50(3) . .
Li5 Al1 Li3 174.56(7) 1_565 .
Al1 Al2 Al1 113.29(3) 1_544 1_554
Al1 Al2 Li2 176.43(4) 1_544 .
Al1 Al2 Li2 67.76(4) 1_554 .
Li2 Al2 Li2 110.98(7) . 1_545
Al1 Al2 Li5 71.07(3) 1_544 1_554
Li2 Al2 Li5 112.38(5) . 1_554
Al1 Al2 Li3 71.55(3) 1_544 1_554
Li2 Al2 Li3 105.99(5) . 1_554
Li5 Al2 Li3 108.69(7) 1_554 1_554
Al1 Al2 Li5 109.99(3) 1_544 5_656
Li2 Al2 Li5 72.33(5) . 5_656
Li5 Al2 Li5 74.61(8) 1_554 5_656
Li3 Al2 Li5 176.70(5) 1_554 5_656
Al1 Al2 Li4 108.68(2) 1_544 .
Li2 Al2 Li4 67.87(4) . .
Li5 Al2 Li4 179.47(5) 1_554 .
Li3 Al2 Li4 70.78(6) 1_554 .
Li5 Al2 Li4 105.93(7) 5_656 .
Al1 Al2 Li4 56.647(14) 1_544 1_554
Al1 Al2 Li4 56.647(13) 1_554 1_554
Li2 Al2 Li4 124.24(4) . 1_554
Li5 Al2 Li4 54.47(7) 1_554 1_554
Li3 Al2 Li4 54.22(6) 1_554 1_554
Li5 Al2 Li4 129.08(7) 5_656 1_554
Li4 Al2 Li4 125.00(7) . 1_554
Al1 Al2 Li1 127.07(2) 1_544 .
Al1 Al2 Li1 55.249(19) 1_554 .
Li2 Al2 Li1 56.44(4) . .
Li2 Al2 Li1 127.17(5) 1_545 .
Li5 Al2 Li1 56.16(3) 1_554 .
Li3 Al2 Li1 126.80(2) 1_554 .
Li5 Al2 Li1 54.84(2) 5_656 .
Li4 Al2 Li1 124.12(3) . .
Li4 Al2 Li1 92.16(3) 1_554 .
Li1 Al2 Li1 89.182(19) . 1_545
Al1 Al2 Li5 123.323(13) 1_544 .
Al1 Al2 Li5 123.323(14) 1_554 .
Li2 Al2 Li5 55.57(4) . .
Li5 Al2 Li5 128.51(8) 1_554 .
Li3 Al2 Li5 122.80(6) 1_554 .
Li5 Al2 Li5 53.90(7) 5_656 .
Li4 Al2 Li5 52.02(7) . .
Li4 Al2 Li5 177.02(4) 1_554 .
Li1 Al2 Li5 89.96(3) . .
Al1 Li1 Al1 180.000(6) 1_554 5_666
Al1 Li1 Li2 65.22(5) 1_554 .
Al1 Li1 Li2 114.78(5) 5_666 .
Li2 Li1 Li2 180.0 . 5_665
Al1 Li1 Li5 69.09(5) 1_554 1_554
Al1 Li1 Li5 110.91(5) 5_666 1_554
Li2 Li1 Li5 107.55(5) . 1_554
Li2 Li1 Li5 72.45(5) 5_665 1_554
Li5 Li1 Li5 180.0 1_554 5_666
Li5 Li1 Li5 104.58(8) 1_554 1_564
Li5 Li1 Li5 75.42(8) 5_666 1_564
Al1 Li1 Al2 52.972(11) 1_554 .
Al1 Li1 Al2 127.028(11) 5_666 .
Li2 Li1 Al2 53.31(2) . .
Li2 Li1 Al2 126.69(2) 5_665 .
Li5 Li1 Al2 54.45(4) 1_554 .
Li5 Li1 Al2 125.55(4) 5_666 .
Li5 Li1 Al2 121.96(5) 1_564 .
Li5 Li1 Al2 58.04(5) 5_656 .
Al2 Li1 Al2 180.0 . 5_665
Al2 Li1 Al2 89.182(19) . 1_565
Al2 Li1 Al2 90.818(19) 5_665 1_565
Li3 Li2 Al2 74.71(5) 7_556 .
Al2 Li2 Al2 110.98(7) . 1_565
Li3 Li2 Li5 110.05(6) 7_556 1_565
Al2 Li2 Li5 175.24(8) . 1_565
Al2 Li2 Li5 71.21(4) 1_565 1_565
Li5 Li2 Li5 106.28(9) 1_565 .
Li3 Li2 Li1 115.64(9) 7_556 .
Al2 Li2 Li1 70.25(4) . .
Li5 Li2 Li1 107.18(6) 1_565 .
Li3 Li2 Al1 73.63(7) 7_556 .
Al2 Li2 Al1 114.00(5) . .
Li5 Li2 Al1 67.94(5) 1_565 .
Li1 Li2 Al1 170.74(9) . .
Li3 Li2 Al1 59.29(7) 7_556 1_554
Al2 Li2 Al1 55.54(4) . 1_554
Li5 Li2 Al1 126.75(4) 1_565 1_554
Li1 Li2 Al1 56.35(4) . 1_554
Al1 Li2 Al1 132.92(8) . 1_554
Li3 Li2 Li4 56.42(6) 7_556 1_565
Al2 Li2 Li4 131.12(9) . 1_565
Al2 Li2 Li4 59.67(4) 1_565 1_565
Li5 Li2 Li4 53.64(7) 1_565 1_565
Li5 Li2 Li4 122.40(8) . 1_565
Li1 Li2 Li4 129.71(5) . 1_565
Al1 Li2 Li4 54.47(5) . 1_565
Al1 Li2 Li4 95.66(7) 1_554 1_565
Li4 Li2 Li4 89.72(8) 1_565 .
Li3 Li2 Li2 175.44(12) 7_556 5_666
Al2 Li2 Li2 107.63(6) . 5_666
Li5 Li2 Li2 67.61(6) 1_565 5_666
Li1 Li2 Li2 68.92(7) . 5_666
Al1 Li2 Li2 101.82(9) . 5_666
Al1 Li2 Li2 125.27(10) 1_554 5_666
Li4 Li2 Li2 121.08(8) 1_565 5_666
Li3 Li2 Li5 131.42(6) 7_556 5_666
Al2 Li2 Li5 123.91(8) . 5_666
Al2 Li2 Li5 56.88(4) 1_565 5_666
Li5 Li2 Li5 53.32(7) 1_565 5_666
Li5 Li2 Li5 118.36(7) . 5_666
Li1 Li2 Li5 53.86(5) . 5_666
Al1 Li2 Li5 120.63(7) . 5_666
Al1 Li2 Li5 92.78(7) 1_554 5_666
Li4 Li2 Li5 92.44(3) 1_565 5_666
Li4 Li2 Li5 171.05(11) . 5_666
Li2 Li2 Li5 50.75(5) 5_666 5_666
Li2 Li3 Li4 112.39(11) 7_556 .
Li2 Li3 Li3 107.09(8) 7_556 7_557
Li4 Li3 Li3 111.30(8) . 7_557
Li2 Li3 Li3 107.09(9) 7_556 7_547
Li3 Li3 Li3 107.39(13) 7_557 7_547
Li2 Li3 Al2 178.66(9) 7_556 1_556
Li4 Li3 Al2 68.95(7) . 1_556
Li3 Li3 Al2 72.19(8) 7_557 1_556
Li2 Li3 Li4 70.35(6) 7_556 7_546
Li4 Li3 Li4 70.42(6) . 7_546
Li3 Li3 Li4 177.41(10) 7_557 7_546
Li3 Li3 Li4 73.37(6) 7_547 7_546
Al2 Li3 Li4 110.36(5) 1_556 7_546
Li4 Li3 Li4 105.77(8) 7_546 7_556
Li2 Li3 Al1 65.79(7) 7_556 7_557
Li4 Li3 Al1 178.18(10) . 7_557
Li3 Li3 Al1 69.62(7) 7_557 7_557
Al2 Li3 Al1 112.87(7) 1_556 7_557
Li4 Li3 Al1 108.61(5) 7_546 7_557
Li2 Li3 Al1 128.14(5) 7_556 .
Li4 Li3 Al1 55.28(4) . .
Li3 Li3 Al1 56.05(5) 7_557 .
Li3 Li3 Al1 124.56(10) 7_547 .
Al2 Li3 Al1 52.49(3) 1_556 .
Li4 Li3 Al1 125.70(6) 7_546 .
Li4 Li3 Al1 57.96(4) 7_556 .
Al1 Li3 Al1 125.67(4) 7_557 .
Al1 Li3 Al1 88.61(5) . 1_545
Li2 Li3 Li4 121.84(10) 7_556 1_556
Li4 Li3 Li4 125.76(11) . 1_556
Li3 Li3 Li4 53.73(7) 7_557 1_556
Al2 Li3 Li4 56.82(6) 1_556 1_556
Li4 Li3 Li4 127.09(4) 7_546 1_556
Al1 Li3 Li4 56.05(5) 7_557 1_556
Al1 Li3 Li4 88.93(6) . 1_556
Li3 Li4 Li5 113.02(12) . .
Li3 Li4 Al1 71.37(5) . .
Li5 Li4 Al1 70.44(6) . .
Al1 Li4 Al1 107.27(7) . 1_545
Li3 Li4 Li3 109.58(6) . 7_546
Li5 Li4 Li3 109.32(6) . 7_546
Al1 Li4 Li3 178.98(7) . 7_546
Al1 Li4 Li3 73.48(4) 1_545 7_546
Li3 Li4 Li3 105.77(8) 7_546 7_556
Li3 Li4 Al1 72.45(7) . 7_556
Li5 Li4 Al1 174.53(11) . 7_556
Al1 Li4 Al1 112.33(5) . 7_556
Li3 Li4 Al1 67.83(5) 7_546 7_556
Li3 Li4 Al2 178.17(10) . .
Li5 Li4 Al2 68.81(8) . .
Al1 Li4 Al2 109.59(5) . .
Li3 Li4 Al2 69.45(5) 7_546 .
Al1 Li4 Al2 105.72(7) 7_556 .
Li3 Li4 Al2 56.83(6) . 1_556
Li5 Li4 Al2 56.18(7) . 1_556
Al1 Li4 Al2 53.64(3) . 1_556
Li3 Li4 Al2 127.12(4) 7_546 1_556
Al1 Li4 Al2 129.28(7) 7_556 1_556
Al2 Li4 Al2 125.00(7) . 1_556
Li3 Li4 Li2 128.36(6) . .
Li5 Li4 Li2 56.09(6) . .
Al1 Li4 Li2 57.26(4) . .
Al1 Li4 Li2 126.52(9) 1_545 .
Li3 Li4 Li2 121.76(8) 7_546 .
Li3 Li4 Li2 53.23(5) 7_556 .
Al1 Li4 Li2 120.91(7) 7_556 .
Al2 Li4 Li2 52.46(5) . .
Al2 Li4 Li2 93.02(7) 1_556 .
Li2 Li4 Li2 89.72(8) . 1_545
Li3 Li4 Li4 56.17(6) . 7_546
Li5 Li4 Li4 128.68(8) . 7_546
Al1 Li4 Li4 127.54(10) . 7_546
Al1 Li4 Li4 58.47(4) 1_545 7_546
Li3 Li4 Li4 53.41(6) 7_546 7_546
Li3 Li4 Li4 121.68(10) 7_556 7_546
Al1 Li4 Li4 53.86(6) 7_556 7_546
Al2 Li4 Li4 122.84(7) . 7_546
Al2 Li4 Li4 93.77(8) 1_556 7_546
Li2 Li4 Li4 173.20(13) . 7_546
Li2 Li4 Li4 90.06(3) 1_545 7_546
Li4 Li5 Al2 69.34(8) . 1_556
Li4 Li5 Li5 117.19(15) . 5_656
Al2 Li5 Li5 173.47(14) 1_556 5_656
Li4 Li5 Li2 70.27(7) . 1_545
Al2 Li5 Li2 110.18(6) 1_556 1_545
Li5 Li5 Li2 73.33(7) 5_656 1_545
Li2 Li5 Li2 106.28(9) 1_545 .
Li4 Li5 Li1 110.12(6) . 1_556
Al2 Li5 Li1 69.39(5) 1_556 1_556
Li5 Li5 Li1 107.03(7) 5_656 1_556
Li2 Li5 Li1 179.15(8) 1_545 1_556
Li2 Li5 Li1 74.57(4) . 1_556
Li1 Li5 Li1 104.58(8) 1_556 1_546
Li4 Li5 Al2 174.74(11) . 5_656
Al2 Li5 Al2 105.39(8) 1_556 5_656
Li5 Li5 Al2 68.08(9) 5_656 5_656
Li2 Li5 Al2 112.43(6) 1_545 5_656
Li1 Li5 Al2 67.12(5) 1_556 5_656
Li4 Li5 Al1 55.74(4) . 1_545
Al2 Li5 Al1 53.12(4) 1_556 1_545
Li5 Li5 Al1 129.72(6) 5_656 1_545
Li2 Li5 Al1 57.16(4) 1_545 1_545
Li2 Li5 Al1 126.01(8) . 1_545
Li1 Li5 Al1 122.36(7) 1_556 1_545
Li1 Li5 Al1 54.39(3) 1_546 1_545
Al2 Li5 Al1 121.41(5) 5_656 1_545
Al1 Li5 Al1 89.87(6) 1_545 .
Li4 Li5 Al2 59.16(8) . .
Al2 Li5 Al2 128.51(8) 1_556 .
Li5 Li5 Al2 58.02(8) 5_656 .
Li2 Li5 Al2 53.21(4) 1_545 .
Li2 Li5 Al2 53.22(4) . .
Li1 Li5 Al2 127.64(4) 1_556 .
Al2 Li5 Al2 126.10(7) 5_656 .
Al1 Li5 Al2 94.59(6) 1_545 .
Li4 Li5 Li2 131.70(7) . 5_666
Al2 Li5 Li2 122.88(7) 1_556 5_666
Li5 Li5 Li2 53.35(6) 5_656 5_666
Li2 Li5 Li2 126.68(7) 1_545 5_666
Li2 Li5 Li2 61.64(7) . 5_666
Li1 Li5 Li2 53.68(4) 1_556 5_666
Li1 Li5 Li2 117.90(9) 1_546 5_666
Al2 Li5 Li2 50.79(5) 5_656 5_666
Al1 Li5 Li2 171.55(10) 1_545 5_666
Al1 Li5 Li2 92.44(3) . 5_666
Al2 Li5 Li2 93.33(7) . 5_666
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Al1 Al2 2.6962(6) 1_566
Al1 Li1 2.7748(9) 1_556
Al1 Li4 2.7966(13) .
Al1 Li3 2.853(2) 7_557
Al1 Li2 2.891(2) .
Al1 Li4 2.952(2) 7_556
Al1 Li2 3.027(2) 1_556
Al1 Li5 3.1884(16) .
Al1 Li5 3.1884(17) 1_565
Al1 Li3 3.2243(14) .
Al2 Li2 2.7330(12) .
Al2 Li5 2.788(2) 1_554
Al2 Li3 2.817(2) 1_554
Al2 Li5 2.954(2) 5_656
Al2 Li4 2.975(2) .
Al2 Li4 3.140(2) 1_554
Al2 Li1 3.2079(5) .
Al2 Li5 3.231(3) .
Li1 Al1 2.7748(8) 5_666
Li1 Li2 2.840(2) .
Li1 Li5 2.8467(15) 1_554
Li2 Li3 2.716(3) 7_556
Li2 Li5 2.8147(17) 1_565
Li2 Li4 3.193(2) 1_565
Li2 Li2 3.199(4) 5_666
Li2 Li5 3.361(3) 5_666
Li3 Li4 2.730(3) .
Li3 Li3 2.794(2) 7_557
Li3 Li4 2.8242(16) 7_546
Li3 Li4 3.357(3) 1_556
Li4 Li5 2.731(4) .
Li4 Li4 3.203(3) 7_546
Li5 Li5 2.814(4) 5_656
