#------------------------------------------------------------------------------
#$Date: 2021-06-21 11:01:54 +0300 (Mon, 21 Jun 2021) $
#$Revision: 266596 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/56/36/1563625.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1563625
loop_
_publ_author_name
'Zubkov, Vladimir G.'
'Tarakina, Nadezda V.'
'Leonidov, Ivan I.'
'Tyutyunnik, Alexander P.'
'Surat, Ludmila L.'
'Melkozerova, Marina A.'
'Zabolotskaya, Elena V.'
'Kellerman, Dina G.'
_publ_section_title
;
 Synthesis and crystal structure of Ln2M2+Ge4O12, Ln=rare-earth element or
 Y; M=Ca, Mn, Zn
;
_journal_issue                   5
_journal_name_full               'Journal of Solid State Chemistry'
_journal_page_first              1186
_journal_page_last               1193
_journal_paper_doi               10.1016/j.jssc.2010.03.027
_journal_volume                  183
_journal_year                    2010
_chemical_formula_sum            'Er2 Ge4 Mn O12'
_chemical_formula_weight         871.81
_space_group_IT_number           125
_space_group_name_Hall           '-P 4a 2b'
_space_group_name_H-M_alt        'P 4/n b m :2'
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_H-M   'P 4/n b m :2'
_cell_angle_alpha                90.0
_cell_angle_beta                 90.0
_cell_angle_gamma                90.0
_cell_formula_units_Z            2
_cell_length_a                   9.86945(7)
_cell_length_b                   9.86945
_cell_length_c                   4.96668(5)
_cell_volume                     483.785(6)
_computing_structure_refinement  GSAS
_diffrn_radiation_polarisn_ratio 0.8
_diffrn_radiation_probe          x-ray
_diffrn_radiation_wavelength     1.54056
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  1.00000
_exptl_absorpt_process_details
;   GSAS Absorption/surface roughness correction: function number 0
 No correction is applied.
;
_pd_calc_method                  'Rietveld Refinement'
_pd_instr_location               ' ?'
_pd_meas_2theta_range_inc        0.02
_pd_meas_2theta_range_max        119.98
_pd_meas_2theta_range_min        5.0
_pd_meas_number_of_points        5750
_pd_proc_2theta_range_inc        0.02
_pd_proc_2theta_range_max        119.95344
_pd_proc_2theta_range_min        4.97344
_pd_proc_info_datetime           2010-02-27T12:04:43
_pd_proc_info_excluded_regions   ' ?'
_pd_proc_ls_background_function
;   GSAS Background function number 1 with 36 terms.
 Shifted Chebyshev function of 1st kind
      1:    856.992     2:   -720.786     3:    426.049     4:   -195.652    
      5:    51.9237     6:    4.99954     7:   -17.4578     8:    8.65803    
      9:   0.484581    10:   -10.9937    11:    8.94700    12:    2.45499    
     13:   -9.12581    14:    4.81281    15:   -4.40138    16:   -4.02733    
     17:    8.25532    18:   -9.54116    19:    1.79657    20:    3.67749    
     21:   -9.84802    22:    12.1951    23:   -11.5873    24:    1.29208    
     25:    3.00740    26:   -12.9176    27:    9.49568    28:   -8.74493    
     29:   0.467473    30:    6.56367    31:   -7.02976    32:    3.59680    
     33:  -0.214456    34:   -6.90315    35:    5.51091    36:   -3.35204    
;
_pd_proc_ls_peak_cutoff          0.00100
_pd_proc_ls_profile_function
;
 CW Profile function number 2 with  18 terms
 Profile coefficients for Simpson's rule integration of pseudovoigt function
 C.J. Howard (1982). J. Appl. Cryst.,15,615-620.
 P. Thompson, D.E. Cox & J.B. Hastings (1987). J. Appl. Cryst.,20,79-83.
 #1(GU)   =    6.625 #2(GV)   =  -14.900 #3(GW)   =   26.883
 #4(LX)   =    1.542 #5(LY)   =   10.511 #6(trns) =    0.000
 #7(asym) =   1.4909 #8(shft) =   0.0000 #9(GP)   =    0.000
 #10(stec)=     0.00 #11(ptec)=     0.00 #12(sfec)=     0.00
 #13(L11) =    0.000 #14(L22) =    0.000 #15(L33) =    0.000
 #16(L12) =    0.000 #17(L13) =    0.000 #18(L23) =    0.000
 Peak tails are ignored  where the intensity is below 0.0010 times the peak
   Aniso. broadening axis   0.0   0.0   1.0
;
_pd_proc_ls_prof_R_factor        0.0324
_pd_proc_ls_prof_wR_expected     0.0337
_pd_proc_ls_prof_wR_factor       0.0436
_pd_proc_number_of_points        5750
_pd_spec_mounting                ' ?'
_refine_ls_goodness_of_fit_all   1.30
_refine_ls_matrix_type           full
_refine_ls_number_parameters     52
_refine_ls_number_restraints     0
_refine_ls_R_Fsqd_factor         0.01689
_refine_ls_shift/su_max          0.01
_refine_ls_shift/su_mean         0.00
_reflns_d_resolution_high        0.894
_reflns_d_resolution_low         6.979
_reflns_limit_h_max              11
_reflns_limit_h_min              0
_reflns_limit_k_max              7
_reflns_limit_k_min              0
_reflns_limit_l_max              5
_reflns_limit_l_min              0
_reflns_number_total             203
_cod_data_source_file            ER2MNGE4O12.cif
_cod_data_source_block           ER2MNGE4O12_publ
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_geom_angle_publ_flag' value 'N' was changed to 'n' in
accordance with the built-in table derived from the CIF Core
dictionary named 'cif_core.dic' version 2.4.5 last updated on
2014-11-21 (115 times).

data item '_geom_bond_publ_flag' value 'N' was changed to 'n' in
accordance with the built-in table derived from the CIF Core
dictionary named 'cif_core.dic' version 2.4.5 last updated on
2014-11-21 (50 times).

Automatic conversion script
Id: cif_fix_values 8369 2020-08-20 11:38:08Z andrius 
;
_cod_original_cell_volume        483.785(10)
_cod_original_sg_symbol_H-M      'P 4/n b m'
_cod_original_formula_sum        'Er2.00 Ge4 Mn1.00 O12'
_cod_database_code               1563625
_gsas_exptl_extinct_corr_t_min   1.00000
_gsas_exptl_extinct_corr_t_max   1.00000
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +x,+y,+z
2 -y+1/2,+x,+z
3 -x+1/2,-y+1/2,+z
4 +y,-x+1/2,+z
5 -x,+y+1/2,+z
6 -y,-x,+z
7 +x+1/2,-y,+z
8 +y+1/2,+x+1/2,+z
-1 -x,-y,-z
-2 +y+1/2,-x,-z
-3 +x+1/2,+y+1/2,-z
-4 -y,+x+1/2,-z
-5 +x,-y+1/2,-z
-6 +y,+x,-z
-7 -x+1/2,+y,-z
-8 -y+1/2,-x+1/2,-z
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_thermal_displace_type
_atom_site_U_iso_or_equiv
_atom_site_symmetry_multiplicity
Mn Mn 0.0 0.0 0.5 0.5 Uiso 0.0215(5) 4
Er Er1 0.0 0.0 0.5 0.5 Uiso 0.0215(5) 4
Er Er2 0.25 0.25 0.5 1.0 Uiso 0.0172(6) 2
Ge GE 0.97848(13) 0.25 0.0 1.0 Uiso 0.0174(5) 8
O O1 0.1307(5) 0.8693(5) 0.8344(14) 1.0 Uiso 0.0120(23) 8
O O2 0.1695(5) 0.0638(5) 0.2571(11) 1.0 Uiso 0.0123(16) 16
loop_
_atom_type_symbol
_atom_type_number_in_cell
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_Cromer_Mann_a1
_atom_type_scat_Cromer_Mann_a2
_atom_type_scat_Cromer_Mann_a3
_atom_type_scat_Cromer_Mann_a4
_atom_type_scat_Cromer_Mann_b1
_atom_type_scat_Cromer_Mann_b2
_atom_type_scat_Cromer_Mann_b3
_atom_type_scat_Cromer_Mann_b4
_atom_type_scat_Cromer_Mann_c
_atom_type_scat_source
Mn 2.0 0.000 0.000 11.2819 5.34090 7.35730 0.34320 3.01930 17.8674 2.24410
83.7543 1.08960 International_Tables_Vol_C
Er 4.0 0.000 0.000 27.6563 2.07356 16.4285 0.22354 14.9779 11.3604 2.98233
105.703 5.92046 International_Tables_Vol_C
Ge 8.0 0.000 0.000 16.0816 2.85090 6.37470 0.25160 3.70680 11.4468 3.68300
54.7625 2.13130 International_Tables_Vol_C
O 24.0 0.000 0.000 3.04850 13.2771 2.28680 5.70110 1.54630 0.32390 0.86700
32.9089 0.25080 International_Tables_Vol_C
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Mn O2 98.05(26) 1_555 . 6_555 n
O2 Mn O2 180.0 1_555 . -1_556 n
O2 Mn O2 81.95(26) 1_555 . -6_556 n
O2 Mn O2 81.95(26) 6_555 . -1_556 n
O2 Mn O2 180.0 6_555 . -6_556 n
O2 Mn O2 98.05(26) -1_556 . -6_556 n
Er2 Er1 Er2 180.0 1_555 . 5_545 n
Er2 Er1 O1 89.9992 1_555 . 1_545 n
Er2 Er1 O1 90.0008 1_555 . -1_566 n
Er2 Er1 O2 40.98(13) 1_555 . 1_555 n
Er2 Er1 O2 139.02(13) 1_555 . 6_555 n
Er2 Er1 O2 139.02(13) 1_555 . -1_556 n
Er2 Er1 O2 40.98(13) 1_555 . -6_556 n
Er2 Er1 O1 90.0008 5_545 . 1_545 n
Er2 Er1 O1 89.9992 5_545 . -1_566 n
Er2 Er1 O2 139.02(13) 5_545 . 1_555 n
Er2 Er1 O2 40.98(13) 5_545 . 6_555 n
Er2 Er1 O2 40.98(13) 5_545 . -1_556 n
Er2 Er1 O2 139.02(13) 5_545 . -6_556 n
O1 Er1 O1 180.0 1_545 . -1_566 n
O1 Er1 O2 97.10(19) 1_545 . 1_555 n
O1 Er1 O2 97.10(19) 1_545 . 6_555 n
O1 Er1 O2 82.90(19) 1_545 . -1_556 n
O1 Er1 O2 82.90(19) 1_545 . -6_556 n
O1 Er1 O2 82.90(19) -1_566 . 1_555 n
O1 Er1 O2 82.90(19) -1_566 . 6_555 n
O1 Er1 O2 97.10(19) -1_566 . -1_556 n
O1 Er1 O2 97.10(19) -1_566 . -6_556 n
O2 Er1 O2 98.05(26) 1_555 . 6_555 n
O2 Er1 O2 180.0 1_555 . -1_556 n
O2 Er1 O2 81.95(26) 1_555 . -6_556 n
O2 Er1 O2 81.95(26) 6_555 . -1_556 n
O2 Er1 O2 180.0 6_555 . -6_556 n
O2 Er1 O2 98.05(26) -1_556 . -6_556 n
Er1 Er2 Er1 90.0 1_555 . 2_555 n
Er1 Er2 Er1 180.0 1_555 . 3_555 n
Er1 Er2 Er1 90.0 1_555 . 4_555 n
Er1 Er2 O2 37.23(13) 1_555 . 1_555 n
Er1 Er2 O2 108.40(11) 1_555 . 2_555 n
Er1 Er2 O2 142.77(13) 1_555 . 3_555 n
Er1 Er2 O2 71.60(11) 1_555 . 4_555 n
Er1 Er2 O2 108.40(11) 1_555 . -5_456 n
Er1 Er2 O2 37.23(13) 1_555 . -6_556 n
Er1 Er2 O2 71.60(11) 1_555 . -7_546 n
Er1 Er2 O2 142.77(13) 1_555 . -8_556 n
Er1 Er2 Er1 90.0 2_555 . 3_555 n
Er1 Er2 Er1 180.0 2_555 . 4_555 n
Er1 Er2 O2 71.60(11) 2_555 . 1_555 n
Er1 Er2 O2 37.23(13) 2_555 . 2_555 n
Er1 Er2 O2 108.40(11) 2_555 . 3_555 n
Er1 Er2 O2 142.77(13) 2_555 . 4_555 n
Er1 Er2 O2 142.77(13) 2_555 . -5_456 n
Er1 Er2 O2 108.40(11) 2_555 . -6_556 n
Er1 Er2 O2 37.23(13) 2_555 . -7_546 n
Er1 Er2 O2 71.60(11) 2_555 . -8_556 n
Er1 Er2 Er1 90.0 3_555 . 4_555 n
Er1 Er2 O2 142.77(13) 3_555 . 1_555 n
Er1 Er2 O2 71.60(11) 3_555 . 2_555 n
Er1 Er2 O2 37.23(13) 3_555 . 3_555 n
Er1 Er2 O2 108.40(11) 3_555 . 4_555 n
Er1 Er2 O2 71.60(11) 3_555 . -5_456 n
Er1 Er2 O2 142.77(13) 3_555 . -6_556 n
Er1 Er2 O2 108.40(11) 3_555 . -7_546 n
Er1 Er2 O2 37.23(13) 3_555 . -8_556 n
Er1 Er2 O2 108.40(11) 4_555 . 1_555 n
Er1 Er2 O2 142.77(13) 4_555 . 2_555 n
Er1 Er2 O2 71.60(11) 4_555 . 3_555 n
Er1 Er2 O2 37.23(13) 4_555 . 4_555 n
Er1 Er2 O2 37.23(13) 4_555 . -5_456 n
Er1 Er2 O2 71.60(11) 4_555 . -6_556 n
Er1 Er2 O2 142.77(13) 4_555 . -7_546 n
Er1 Er2 O2 108.40(11) 4_555 . -8_556 n
O2 Er2 O2 74.55(12) 1_555 . 2_555 n
O2 Er2 O2 117.86(26) 1_555 . 3_555 n
O2 Er2 O2 74.55(12) 1_555 . 4_555 n
O2 Er2 O2 140.27(23) 1_555 . -5_456 n
O2 Er2 O2 74.46(26) 1_555 . -6_556 n
O2 Er2 O2 76.33(23) 1_555 . -7_546 n
O2 Er2 O2 143.19(22) 1_555 . -8_556 n
O2 Er2 O2 74.55(12) 2_555 . 3_555 n
O2 Er2 O2 117.86(26) 2_555 . 4_555 n
O2 Er2 O2 143.19(22) 2_555 . -5_456 n
O2 Er2 O2 140.27(23) 2_555 . -6_556 n
O2 Er2 O2 74.46(26) 2_555 . -7_546 n
O2 Er2 O2 76.33(23) 2_555 . -8_556 n
O2 Er2 O2 74.55(12) 3_555 . 4_555 n
O2 Er2 O2 76.33(23) 3_555 . -5_456 n
O2 Er2 O2 143.19(22) 3_555 . -6_556 n
O2 Er2 O2 140.27(23) 3_555 . -7_546 n
O2 Er2 O2 74.46(26) 3_555 . -8_556 n
O2 Er2 O2 74.46(26) 4_555 . -5_456 n
O2 Er2 O2 76.33(23) 4_555 . -6_556 n
O2 Er2 O2 143.19(22) 4_555 . -7_546 n
O2 Er2 O2 140.27(23) 4_555 . -8_556 n
O2 Er2 O2 74.55(12) -5_456 . -6_556 n
O2 Er2 O2 117.86(26) -5_456 . -7_546 n
O2 Er2 O2 74.55(12) -5_456 . -8_556 n
O2 Er2 O2 74.55(12) -6_556 . -7_546 n
O2 Er2 O2 117.86(26) -6_556 . -8_556 n
O2 Er2 O2 74.55(12) -7_546 . -8_556 n
O1 GE O1 106.2(5) 4_554 . -1_666 n
O1 GE O2 109.29(34) 4_554 . 4_655 n
O1 GE O2 104.82(28) 4_554 . -6_655 n
O1 GE O2 104.83(28) -1_666 . 4_655 n
O1 GE O2 109.29(34) -1_666 . -6_655 n
O2 GE O2 121.5(4) 4_655 . -6_655 n
Er1 O1 GE 109.73(23) 1_565 . 2_556 n
Er1 O1 GE 109.72(23) 1_565 . 5_656 n
GE O1 GE 125.2(4) 2_556 . 5_656 n
Mn O2 Er1 0.0 1_555 . 1_555 n
Mn O2 Er2 101.80(20) 1_555 . 1_555 n
Mn O2 GE 129.01(29) 1_555 . 2_545 n
Er1 O2 Er2 101.80(20) 1_555 . 1_555 n
Er1 O2 GE 129.01(29) 1_555 . 2_545 n
Er2 O2 GE 127.58(29) 1_555 . 2_545 n
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Mn O1 2.467(7) . 1_545 n
Mn O1 2.467(7) . -1_566 n
Mn O2 2.157(5) . 1_555 n
Mn O2 2.157(5) . 6_555 n
Mn O2 2.157(5) . -1_556 n
Mn O2 2.157(5) . -6_556 n
Er1 Er2 3.489380(30) . 1_555 n
Er1 Er2 3.489380(30) . 5_545 n
Er1 GE 3.50713(8) . 1_455 n
Er1 GE 3.50713(8) . 1_456 n
Er1 GE 3.50713(8) . 2_545 n
Er1 GE 3.50713(8) . 2_546 n
Er1 GE 3.50713(8) . 5_645 n
Er1 GE 3.50713(8) . 5_646 n
Er1 GE 3.50713(8) . 6_565 n
Er1 GE 3.50713(8) . 6_566 n
Er1 O1 2.467(7) . 1_545 n
Er1 O1 2.467(7) . -1_566 n
Er1 O2 2.157(5) . 1_555 n
Er1 O2 2.157(5) . 6_555 n
Er1 O2 2.157(5) . -1_556 n
Er1 O2 2.157(5) . -6_556 n
Er2 Er1 3.489380(30) . 1_555 n
Er2 Er1 3.489380(30) . 2_555 n
Er2 Er1 3.489380(30) . 3_555 n
Er2 Er1 3.489380(30) . 4_555 n
Er2 O2 2.338(5) . 1_555 n
Er2 O2 2.338(5) . 2_555 n
Er2 O2 2.338(5) . 3_555 n
Er2 O2 2.338(5) . 4_555 n
Er2 O2 2.338(5) . -5_556 n
Er2 O2 2.338(5) . -6_556 n
Er2 O2 2.338(5) . -7_556 n
Er2 O2 2.338(5) . -8_556 n
GE Er1 3.50713(8) . 1_654 n
GE Er1 3.50713(8) . 1_655 n
GE Er1 3.50713(8) . 4_654 n
GE Er1 3.50713(8) . 4_655 n
GE O1 1.7956(31) . 4_554 n
GE O1 1.7956(31) . -1_666 n
GE O2 1.723(5) . 4_655 n
GE O2 1.723(5) . -6_655 n
O1 Mn 2.467(7) . 1_565 n
O1 Er1 2.467(7) . 1_565 n
O1 GE 1.7956(31) . 2_556 n
O1 GE 1.7956(31) . 5_656 n
O2 Mn 2.157(5) . 1_555 n
O2 Er1 2.157(5) . 1_555 n
O2 Er2 2.338(5) . 1_555 n
O2 GE 1.723(5) . 2_545 n
loop_
_pd_meas_counts_total
_pd_proc_ls_weight
_pd_proc_intensity_bkg_calc
_pd_calc_intensity_total
2249.0 0.000445 2237.93262 2237.93188
2192.0 0.000456 2232.24927 2232.24878
2194.0 0.000456 2227.15576 2227.15552
2224.0 0.000450 2222.60449 2222.60425
2208.0 0.000453 2218.55103 2218.55078
2143.0 0.000467 2214.95288 2214.95288
2219.0 0.000451 2211.77100 2211.77100
2264.0 0.000442 2208.96777 2208.96753
2194.0 0.000456 2206.50806 2206.50806
2235.0 0.000447 2204.35938 2204.35962
2261.0 0.000442 2202.49072 2202.49097
2205.0 0.000454 2200.87354 2200.87354
2141.0 0.000467 2199.47998 2199.48022
2148.0 0.000466 2198.28564 2198.28589
2203.0 0.000454 2197.26685 2197.26685
2222.0 0.000450 2196.40112 2196.40137
2272.0 0.000440 2195.66846 2195.66870
2175.0 0.000460 2195.04956 2195.04980
2212.0 0.000452 2194.52686 2194.52710
2237.0 0.000447 2194.08423 2194.08447
2214.0 0.000452 2193.70630 2193.70654
2272.0 0.000440 2193.37915 2193.37939
2259.0 0.000443 2193.09009 2193.09033
2169.0 0.000461 2192.82715 2192.82739
2223.0 0.000450 2192.57959 2192.57983
2211.0 0.000452 2192.33765 2192.33789
2228.0 0.000449 2192.09229 2192.09229
2209.0 0.000453 2191.83496 2191.83521
2153.0 0.000464 2191.55908 2191.55908
2093.0 0.000478 2191.25732 2191.25732
2151.0 0.000465 2190.92407 2190.92432
2176.0 0.000460 2190.55396 2190.55396
2238.0 0.000447 2190.14233 2190.14233
2200.0 0.000455 2189.68530 2189.68530
2214.0 0.000452 2189.17896 2189.17896
2138.0 0.000468 2188.62061 2188.62061
2150.0 0.000465 2188.00732 2188.00732
2271.0 0.000440 2187.33716 2187.33716
2186.0 0.000457 2186.60864 2186.60864
2181.0 0.000459 2185.81982 2185.81982
2174.0 0.000460 2184.97046 2184.97046
2179.0 0.000459 2184.05908 2184.05908
2227.0 0.000449 2183.08594 2183.08594
2242.0 0.000446 2182.05103 2182.05103
2182.0 0.000458 2180.95410 2180.95386
2165.0 0.000462 2179.79565 2179.79565
2122.0 0.000471 2178.57642 2178.57642
2136.0 0.000468 2177.29736 2177.29736
2163.0 0.000462 2175.95923 2175.95898
2187.0 0.000457 2174.56299 2174.56299
2249.0 0.000445 2173.11060 2173.11060
2185.0 0.000458 2171.60327 2171.60303
2129.0 0.000470 2170.04224 2170.04224
2094.0 0.000478 2168.42920 2168.42920
2154.0 0.000464 2166.76636 2166.76611
2130.0 0.000469 2165.05518 2165.05493
2113.0 0.000473 2163.29761 2163.29736
2097.0 0.000477 2161.49561 2161.49536
2127.0 0.000470 2159.65112 2159.65088
2095.0 0.000477 2157.76636 2157.76611
2171.0 0.000461 2155.84302 2155.84277
2175.0 0.000460 2153.88330 2153.88330
2090.0 0.000478 2151.88965 2151.88965
2167.0 0.000461 2149.86377 2149.86377
2179.0 0.000459 2147.80811 2147.80786
2153.0 0.000464 2145.72437 2145.72412
2161.0 0.000463 2143.61450 2143.61450
2114.0 0.000473 2141.48120 2141.48120
2025.0 0.000494 2139.32593 2139.32593
2145.0 0.000466 2137.15088 2137.15088
2126.0 0.000470 2134.95801 2134.95801
2032.0 0.000492 2132.74927 2132.74927
2132.0 0.000469 2130.52637 2130.52637
2111.0 0.000474 2128.29150 2128.29126
2071.0 0.000483 2126.04614 2126.04614
2161.0 0.000463 2123.79224 2123.79224
2070.0 0.000483 2121.53149 2121.53149
2101.0 0.000476 2119.26538 2119.26538
2128.0 0.000470 2116.99585 2116.99585
2122.0 0.000471 2114.72412 2114.72412
2121.0 0.000471 2112.45190 2112.45190
2168.0 0.000461 2110.18066 2110.18066
2151.0 0.000465 2107.91162 2107.91162
2140.0 0.000467 2105.64624 2105.64624
2118.0 0.000472 2103.38574 2103.38574
2177.0 0.000459 2101.13135 2101.13135
2166.0 0.000462 2098.88428 2098.88428
2165.0 0.000462 2096.64551 2096.64551
2134.0 0.000469 2094.41626 2094.41626
2050.0 0.000488 2092.19751 2092.19751
2077.0 0.000481 2089.98999 2089.98999
2125.0 0.000471 2087.79492 2087.79492
2083.0 0.000480 2085.61279 2085.61279
2186.0 0.000457 2083.44458 2083.44458
2094.0 0.000478 2081.29102 2081.29102
2125.0 0.000471 2079.15259 2079.15283
2086.0 0.000479 2077.03003 2077.03027
2133.0 0.000469 2074.92407 2074.92407
2049.0 0.000488 2072.83521 2072.83521
2006.0 0.000499 2070.76343 2070.76367
2101.0 0.000476 2068.70996 2068.70996
2116.0 0.000473 2066.67456 2066.67456
2083.0 0.000480 2064.65771 2064.65771
2007.0 0.000498 2062.65967 2062.65991
1998.0 0.000501 2060.68091 2060.68115
2046.0 0.000489 2058.72168 2058.72168
2143.0 0.000467 2056.78174 2056.78198
2040.0 0.000490 2054.86157 2054.86182
2028.0 0.000493 2052.96118 2052.96143
2133.0 0.000469 2051.08057 2051.08081
2050.0 0.000488 2049.21997 2049.22021
2161.0 0.000463 2047.37927 2047.37939
2097.0 0.000477 2045.55835 2045.55847
1981.0 0.000505 2043.75720 2043.75732
2140.0 0.000467 2041.97571 2041.97595
2059.0 0.000486 2040.21411 2040.21423
2031.0 0.000492 2038.47168 2038.47192
2078.0 0.000481 2036.74890 2036.74902
2020.0 0.000495 2035.04492 2035.04517
1970.0 0.000508 2033.35999 2033.36023
2084.0 0.000480 2031.69397 2031.69409
2105.0 0.000475 2030.04614 2030.04626
2044.0 0.000489 2028.41675 2028.41687
2028.0 0.000493 2026.80518 2026.80542
1991.0 0.000502 2025.21143 2025.21155
2045.0 0.000489 2023.63477 2023.63501
1968.0 0.000508 2022.07532 2022.07544
2021.0 0.000495 2020.53259 2020.53271
1936.0 0.000517 2019.00623 2019.00635
2000.0 0.000500 2017.49597 2017.49609
2003.0 0.000499 2016.00122 2016.00146
2046.0 0.000489 2014.52197 2014.52222
2074.0 0.000482 2013.05762 2013.05774
2005.0 0.000499 2011.60779 2011.60803
2019.0 0.000495 2010.17236 2010.17249
1969.0 0.000508 2008.75061 2008.75073
2018.0 0.000496 2007.34241 2007.34253
1980.0 0.000505 2005.94714 2005.94739
2048.0 0.000488 2004.56470 2004.56482
1977.0 0.000506 2003.19458 2003.19470
1980.0 0.000505 2001.83630 2001.83643
1980.0 0.000505 2000.48962 2000.48975
1989.0 0.000503 1999.15405 1999.15417
1993.0 0.000502 1997.82922 1997.82935
1992.0 0.000502 1996.51489 1996.51501
2002.0 0.000500 1995.21045 1995.21057
2009.0 0.000498 1993.91589 1993.91602
1934.0 0.000517 1992.63049 1992.63062
2066.0 0.000484 1991.35413 1991.35425
1950.0 0.000513 1990.08618 1990.08630
2044.0 0.000489 1988.82654 1988.82666
1982.0 0.000505 1987.57495 1987.57507
1910.0 0.000524 1986.33069 1986.33081
1895.0 0.000528 1985.09387 1985.09399
1928.0 0.000519 1983.86389 1983.86389
2020.0 0.000495 1982.64038 1982.64050
1969.0 0.000508 1981.42334 1981.42346
1989.0 0.000503 1980.21228 1980.21240
1966.0 0.000509 1979.00696 1979.00708
1949.0 0.000513 1977.80701 1977.80713
2038.0 0.000491 1976.61243 1976.61243
2009.0 0.000498 1975.42249 1975.42261
1943.0 0.000515 1974.23730 1974.23730
1988.0 0.000503 1973.05664 1973.05664
1933.0 0.000517 1971.87988 1971.88000
1923.0 0.000520 1970.70740 1970.70740
1944.0 0.000514 1969.53845 1969.53857
1954.0 0.000512 1968.37305 1968.37317
1981.0 0.000505 1967.21106 1967.21118
2013.0 0.000497 1966.05225 1966.05225
1931.0 0.000518 1964.89636 1964.89636
1983.0 0.000504 1963.74329 1963.74329
1957.0 0.000511 1962.59290 1962.59290
1963.0 0.000509 1961.44482 1961.44495
2067.0 0.000484 1960.29932 1960.29932
1902.0 0.000526 1959.15588 1959.15588
1906.0 0.000525 1958.01440 1958.01453
1950.0 0.000513 1956.87524 1956.87524
1873.0 0.000534 1955.73767 1955.73767
1956.0 0.000511 1954.60205 1954.60205
2006.0 0.000499 1953.46802 1953.46802
1947.0 0.000514 1952.33557 1952.33557
1986.0 0.000504 1951.20471 1951.20471
1929.0 0.000518 1950.07520 1950.07520
1957.0 0.000511 1948.94714 1948.94714
1951.0 0.000513 1947.82056 1947.82056
1928.0 0.000519 1946.69507 1946.69507
1895.0 0.000528 1945.57104 1945.57104
1914.0 0.000522 1944.44812 1944.44812
1977.0 0.000506 1943.32654 1943.32654
1963.0 0.000509 1942.20605 1942.20605
1966.0 0.000509 1941.08679 1941.08679
1979.0 0.000505 1939.96863 1939.96863
1865.0 0.000536 1938.85156 1938.85156
1917.0 0.000522 1937.73584 1937.73584
1948.0 0.000513 1936.62122 1936.62122
1972.0 0.000507 1935.50793 1935.50793
1904.0 0.000525 1934.39575 1934.39575
1868.0 0.000535 1933.28479 1933.28479
1887.0 0.000530 1932.17517 1932.17517
1869.0 0.000535 1931.06677 1931.06677
1891.0 0.000529 1929.95984 1929.95984
1970.0 0.000508 1928.85425 1928.85425
1941.0 0.000515 1927.75000 1927.74988
1907.0 0.000524 1926.64722 1926.64722
1935.0 0.000517 1925.54590 1925.54590
1838.0 0.000544 1924.44641 1924.44641
1949.0 0.000513 1923.34827 1923.34814
1935.0 0.000517 1922.25183 1922.25183
1994.0 0.000502 1921.15710 1921.15710
1950.0 0.000513 1920.06409 1920.06409
1966.0 0.000509 1918.97302 1918.97302
1896.0 0.000527 1917.88379 1917.88379
1911.0 0.000523 1916.79651 1916.79651
1938.0 0.000516 1915.71118 1915.71118
1895.0 0.000528 1914.62793 1914.62781
1926.0 0.000519 1913.54675 1913.54675
1903.0 0.000525 1912.46777 1912.46777
1871.0 0.000534 1911.39099 1911.39099
1918.0 0.000521 1910.31653 1910.31653
1920.0 0.000521 1909.24438 1909.24438
1958.0 0.000511 1908.17456 1908.17456
1824.0 0.000548 1907.10718 1907.10718
1961.0 0.000510 1906.04248 1906.04248
1847.0 0.000541 1904.98010 1904.98010
1918.0 0.000521 1903.92041 1903.92041
1928.0 0.000519 1902.86328 1902.86328
1860.0 0.000538 1901.80884 1901.80884
1918.0 0.000521 1900.75720 1900.75720
1881.0 0.000532 1899.70825 1899.70825
1873.0 0.000534 1898.66211 1898.66211
1918.0 0.000521 1897.61877 1897.61877
1932.0 0.000518 1896.57813 1896.57813
1864.0 0.000536 1895.54065 1895.54065
1916.0 0.000522 1894.50586 1894.50586
1879.0 0.000532 1893.47412 1893.47412
1905.0 0.000525 1892.44507 1892.44519
1936.0 0.000517 1891.41931 1891.41931
1881.0 0.000532 1890.39624 1890.39624
1917.0 0.000522 1889.37622 1889.37634
1891.0 0.000529 1888.35913 1888.35913
1820.0 0.000549 1887.34497 1887.34497
1899.0 0.000527 1886.33374 1886.33386
1844.0 0.000542 1885.32544 1885.32556
1925.0 0.000519 1884.32007 1884.32019
1933.0 0.000517 1883.31763 1883.31775
1862.0 0.000537 1882.31799 1882.31812
1844.0 0.000542 1881.32141 1881.32141
1918.0 0.000521 1880.32739 1880.32751
1845.0 0.000542 1879.33630 1879.33643
1919.0 0.000521 1878.34778 1878.34778
1904.0 0.000525 1877.36194 1877.36194
1856.0 0.000539 1876.37878 1876.37891
1843.0 0.000543 1875.39819 1875.39832
1818.0 0.000550 1874.42017 1874.42029
1864.0 0.000536 1873.44446 1873.44458
1923.0 0.000520 1872.47131 1872.47144
1910.0 0.000524 1871.50024 1871.50037
1877.0 0.000533 1870.53149 1870.53162
1862.0 0.000537 1869.56494 1869.56506
1882.0 0.000531 1868.60034 1868.60046
1821.0 0.000549 1867.63782 1867.63794
1979.0 0.000505 1866.67700 1866.67712
1908.0 0.000524 1865.71790 1865.71802
1849.0 0.000541 1864.76062 1864.76074
1786.0 0.000560 1863.80469 1863.80481
1866.0 0.000536 1862.85034 1862.85059
1835.0 0.000545 1861.89722 1861.89734
1842.0 0.000543 1860.94543 1860.94556
1930.0 0.000518 1859.99451 1859.99463
1942.0 0.000515 1859.04456 1859.04468
1926.0 0.000519 1858.09546 1858.09558
1827.0 0.000547 1857.14685 1857.14697
1895.0 0.000528 1856.19885 1856.19910
1901.0 0.000526 1855.25122 1855.25146
1894.0 0.000528 1854.30371 1854.30383
1913.0 0.000523 1853.35632 1853.35657
1907.0 0.000524 1852.40881 1852.40906
1884.0 0.000531 1851.46118 1851.46143
1855.0 0.000539 1850.51294 1850.51318
1860.0 0.000538 1849.56409 1849.56433
1900.0 0.000526 1848.61462 1848.61487
1875.0 0.000533 1847.66418 1847.66443
1794.0 0.000557 1846.71265 1846.71289
1885.0 0.000531 1845.75977 1845.76001
1868.0 0.000535 1844.80554 1844.80579
1899.0 0.000527 1843.84949 1843.84973
1873.0 0.000534 1842.89160 1842.89185
1840.0 0.000543 1841.93188 1841.93213
1883.0 0.000531 1840.96973 1840.96997
1856.0 0.000539 1840.00537 1840.00562
1804.0 0.000554 1839.03821 1839.03845
1894.0 0.000528 1838.06836 1838.06860
1797.0 0.000556 1837.09558 1837.09583
1894.0 0.000528 1836.11951 1836.11975
1831.0 0.000546 1835.14026 1835.14050
1889.0 0.000529 1834.15710 1834.15747
1852.0 0.000540 1833.17053 1833.17078
1746.0 0.000573 1832.17969 1832.17993
1880.0 0.000532 1831.18481 1831.18506
1880.0 0.000532 1830.18542 1830.18567
1882.0 0.000531 1829.18140 1829.18164
1837.0 0.000544 1828.17273 1828.17297
1816.0 0.000551 1827.15894 1827.15918
1824.0 0.000548 1826.14001 1826.14026
1926.0 0.000519 1825.11560 1825.11584
1876.0 0.000533 1824.08557 1824.08582
1890.0 0.000529 1823.04980 1823.05005
1843.0 0.000543 1822.00793 1822.00818
1844.0 0.000542 1820.95972 1820.95996
1761.0 0.000568 1819.90527 1819.90564
1834.0 0.000545 1818.84412 1818.84436
1815.0 0.000551 1817.77625 1817.77649
1869.0 0.000535 1816.70117 1816.70142
1748.0 0.000572 1815.61902 1815.61938
1787.0 0.000560 1814.52930 1814.52966
1777.0 0.000563 1813.43213 1813.43250
1762.0 0.000568 1812.32703 1812.32727
1829.0 0.000547 1811.21399 1811.21423
1789.0 0.000559 1810.09277 1810.09302
1807.0 0.000553 1808.96313 1808.96338
1754.0 0.000570 1807.82495 1807.82532
1760.0 0.000568 1806.67810 1806.67834
1776.0 0.000563 1805.52209 1805.52246
1828.0 0.000547 1804.35730 1804.35754
1747.0 0.000572 1803.18298 1803.18335
1805.0 0.000554 1801.99951 1801.99976
1789.0 0.000559 1800.80615 1803.77039
1752.0 0.000571 1799.60315 1802.67407
1811.0 0.000552 1798.39038 1801.57373
1817.0 0.000550 1797.16724 1800.46948
1743.0 0.000574 1795.93408 1799.36194
1827.0 0.000547 1794.69031 1798.25122
1798.0 0.000556 1793.43616 1797.13782
1780.0 0.000562 1792.17126 1796.02209
1778.0 0.000562 1790.89551 1794.90491
1724.0 0.000580 1789.60876 1793.78674
1734.0 0.000577 1788.31104 1792.66821
1690.0 0.000592 1787.00208 1791.55042
1705.0 0.000587 1785.68164 1790.43408
1752.0 0.000571 1784.34973 1789.32019
1727.0 0.000579 1783.00647 1788.21008
1802.0 0.000555 1781.65125 1787.10498
1783.0 0.000561 1780.28442 1786.00671
1735.0 0.000576 1778.90552 1784.91675
1700.0 0.000588 1777.51477 1783.83728
1784.0 0.000561 1776.11182 1782.77039
1775.0 0.000563 1774.69678 1781.71899
1796.0 0.000557 1773.26941 1780.68555
1718.0 0.000582 1771.82971 1779.67395
1773.0 0.000564 1770.37769 1778.68811
1741.0 0.000574 1768.91296 1777.73242
1748.0 0.000572 1767.43579 1776.81238
1802.0 0.000555 1765.94617 1775.93396
1773.0 0.000564 1764.44373 1775.10474
1741.0 0.000574 1762.92883 1774.33289
1658.0 0.000603 1761.40088 1773.62830
1781.0 0.000561 1759.86023 1773.00330
1800.0 0.000556 1758.30701 1772.47217
1756.0 0.000569 1756.74072 1772.05139
1785.0 0.000560 1755.16162 1771.76184
1729.0 0.000578 1753.56970 1771.62878
1743.0 0.000574 1751.96497 1771.68298
1712.0 0.000584 1750.34717 1771.96204
1697.0 0.000589 1748.71667 1772.51404
1635.0 0.000612 1747.07324 1773.39856
1742.0 0.000574 1745.41687 1774.69177
1805.0 0.000554 1743.74780 1776.49280
1753.0 0.000570 1742.06580 1778.93250
1861.0 0.000537 1740.37109 1782.19470
1835.0 0.000545 1738.66370 1786.56641
1863.0 0.000537 1736.94336 1792.57776
1877.0 0.000533 1735.21069 1801.37415
1958.0 0.000511 1733.46521 1815.58643
2058.0 0.000486 1731.70728 1841.08655
2073.0 0.000482 1729.93677 1889.86865
2352.0 0.000425 1728.15381 1983.62622
2514.0 0.000398 1726.35864 2156.14624
2732.0 0.000366 1724.55115 2450.80176
3077.0 0.0003250 1722.73157 2908.46802
3419.0 0.0002925 1720.89978 3543.08252
4034.0 0.0002479 1719.05615 4309.81738
4747.0 0.0002107 1717.20056 5087.20410
5340.0 0.0001873 1715.33313 5697.10547
5680.0 0.0001761 1713.45410 5948.16846
5745.0 0.0001741 1711.56360 5722.59473
5320.0 0.0001880 1709.66162 5088.65576
4435.0 0.0002255 1707.74829 4260.02051
3466.0 0.0002885 1705.82385 3451.49463
2893.0 0.0003457 1703.88843 2797.94556
2497.0 0.000400 1701.94202 2343.27148
2202.0 0.000454 1699.98511 2064.99438
1928.0 0.000519 1698.01746 1911.52722
1812.0 0.000552 1696.03955 1832.24268
1782.0 0.000561 1694.05127 1791.26660
1781.0 0.000561 1692.05286 1768.15833
1762.0 0.000568 1690.04468 1753.06299
1707.0 0.000586 1688.02673 1741.77319
1714.0 0.000583 1685.99927 1732.58679
1733.0 0.000577 1683.96240 1724.77527
1690.0 0.000592 1681.91638 1717.96716
1658.0 0.000603 1679.86145 1711.93201
1668.0 0.000600 1677.79773 1706.50732
1707.0 0.000586 1675.72546 1701.57202
1663.0 0.000601 1673.64490 1697.03333
1597.0 0.000626 1671.55603 1692.81885
1725.0 0.000580 1669.45947 1688.87207
1654.0 0.000605 1667.35510 1685.14771
1610.0 0.000621 1665.24341 1681.60962
1684.0 0.000594 1663.12427 1678.22827
1613.0 0.000620 1660.99829 1674.98010
1620.0 0.000617 1658.86548 1671.84509
1661.0 0.000602 1656.72607 1668.80725
1650.0 0.000606 1654.58057 1665.85315
1579.0 0.000633 1652.42883 1662.97107
1619.0 0.000618 1650.27148 1660.15198
1624.0 0.000616 1648.10864 1657.38745
1586.0 0.000631 1645.94031 1654.67078
1622.0 0.000617 1643.76721 1651.99646
1686.0 0.000593 1641.58911 1649.35901
1563.0 0.000640 1639.40674 1646.75464
1576.0 0.000635 1637.22009 1644.17920
1570.0 0.000637 1635.02954 1641.63013
1654.0 0.000605 1632.83521 1639.10413
1610.0 0.000621 1630.63770 1636.59912
1608.0 0.000622 1628.43677 1634.11304
1597.0 0.000626 1626.23315 1631.64392
1619.0 0.000618 1624.02710 1629.19080
1580.0 0.000633 1621.81860 1626.75159
1593.0 0.000628 1619.60828 1624.32581
1580.0 0.000633 1617.39612 1621.91187
1583.0 0.000632 1615.18262 1619.50928
1650.0 0.000606 1612.96814 1617.11719
1540.0 0.000649 1610.75269 1614.73499
1609.0 0.000622 1608.53674 1612.36206
1657.0 0.000604 1606.32068 1609.99817
1576.0 0.000635 1604.10449 1607.64258
1600.0 0.000625 1601.88892 1605.29529
1596.0 0.000627 1599.67383 1602.95581
1582.0 0.000632 1597.45984 1600.62402
1601.0 0.000625 1595.24695 1598.29956
1649.0 0.000606 1593.03577 1593.03589
1627.0 0.000615 1590.82642 1590.82642
1535.0 0.000651 1588.61926 1588.61926
1637.0 0.000611 1586.41455 1586.41455
1517.0 0.000659 1584.21265 1584.21265
1509.0 0.000663 1582.01379 1582.01379
1565.0 0.000639 1579.81836 1579.81836
1635.0 0.000612 1577.62646 1577.62646
1512.0 0.000661 1575.43884 1575.43884
1577.0 0.000634 1573.25525 1573.25525
1658.0 0.000603 1571.07642 1571.07642
1555.0 0.000643 1568.90247 1568.90247
1531.0 0.000653 1566.73352 1566.73352
1525.0 0.000656 1564.57043 1564.57043
1479.0 0.000676 1562.41284 1562.41272
1565.0 0.000639 1560.26147 1560.26147
1590.0 0.000629 1558.11646 1558.11633
1523.0 0.000657 1555.97815 1555.97815
1555.0 0.000643 1553.84668 1553.84668
1587.0 0.000630 1551.72266 1551.72266
1503.0 0.000665 1549.60620 1549.60608
1568.0 0.000638 1547.49744 1547.49744
1554.0 0.000644 1545.39697 1545.39697
1531.0 0.000653 1543.30493 1543.30493
1534.0 0.000652 1541.22144 1541.22144
1527.0 0.000655 1539.14722 1539.14722
1534.0 0.000652 1537.08203 1537.08203
1499.0 0.000667 1535.02661 1535.02661
1537.0 0.000651 1532.98083 1532.98083
1487.0 0.000672 1530.94531 1530.94531
1534.0 0.000652 1528.92004 1528.92004
1576.0 0.000635 1526.90564 1526.90564
1505.0 0.000664 1524.90198 1524.90186
1459.0 0.000685 1522.90942 1522.90942
1545.0 0.000647 1520.92847 1520.92847
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460.0 . . .
