Crystallography Open Database

Information card for entry 1563983

Preview

Coordinates	1563983.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C50 H59 N5 Rh2
Calculated formula	C50 H59 N5 Rh2
SMILES	[Rh]1234(N(C(=CC(=[N]1c1c(cccc1C)C)C)C)c1c(cccc1C)C)[NH]=[C]12[C]3([CH]2[Rh]356(N(C(=CC(=[N]3c3c(cccc3C)C)C)C)c3c(cccc3C)C)[CH]=2[CH]5=[C]16C)=[CH2]4
Title of publication	Reactivity of Rhodium(II) amido/Rhodium(I) aminyl complexes
Authors of publication	Zhang, Nan; Zhu, Di; Herbert, David E.; van Leest, Nicolaas P.; de Bruin, Bas; Budzelaar, Peter H.M.
Journal of publication	Inorganica Chimica Acta
Year of publication	2018
Journal volume	482
Pages of publication	709 - 716
a	7.2577 ± 0.0003 Å
b	21.6424 ± 0.0009 Å
c	27.4338 ± 0.001 Å
α	90°
β	90°
γ	90°
Cell volume	4309.1 ± 0.3 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	4
Space group number	19
Hermann-Mauguin space group symbol	P 21 21 21
Hall space group symbol	P 2ac 2ab
Residual factor for all reflections	0.0538
Residual factor for significantly intense reflections	0.0418
Weighted residual factors for significantly intense reflections	0.082
Weighted residual factors for all reflections included in the refinement	0.0862
Goodness-of-fit parameter for all reflections included in the refinement	1.123
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
267294 (current)	2021-07-06	cif/ Adding structures of 1563981, 1563982, 1563983, 1563984, 1563985, 1563986 via cif-deposit CGI script.	1563983.cif