Crystallography Open Database

Information card for entry 1565351

Preview

Coordinates	1565351.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C50 H40 Br6 O2 P2 Pt2 Sn
Calculated formula	C50 H40 Br6 O2 P2 Pt2 Sn
SMILES	[Pt]([Sn]([Pt](Br)(Br)C#[O])(Br)Br)(Br)(Br)C#[O].[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
Title of publication	Reactions of [Pt6(CO)6(SnX2)2(SnX3)4]4– (X = Cl, Br) with Acids: Syntheses and molecular structures of [Pt12(CO)10(SnCl)2(SnCl2)4{Cl2Sn(μ-OH)SnCl2}2]2– And [Pt7(CO)6(SnBr2)4{Br2Sn(μ-OH)SnBr2}{Br2Sn(μ-Br)SnBr2}]2– Platinum carbonyl clusters decorated by Sn(II)-Fragments
Authors of publication	Berti, Beatrice; Bortoluzzi, Marco; Cesari, Cristiana; Femoni, Cristina; Iapalucci, Maria Carmela; Zacchini, Stefano
Journal of publication	Inorganica Chimica Acta
Year of publication	2020
Journal volume	503
Pages of publication	119432
a	22.1246 ± 0.0016 Å
b	13.9666 ± 0.001 Å
c	18.0304 ± 0.0014 Å
α	90°
β	110.363 ± 0.002°
γ	90°
Cell volume	5223.3 ± 0.7 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	7
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0546
Residual factor for significantly intense reflections	0.043
Weighted residual factors for significantly intense reflections	0.1009
Weighted residual factors for all reflections included in the refinement	0.107
Goodness-of-fit parameter for all reflections included in the refinement	1.058
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
270824 (current)	2021-11-23	cif/ Adding structures of 1565347, 1565348, 1565349, 1565350, 1565351 via cif-deposit CGI script.	1565351.cif