Crystallography Open Database
- COD Home
- Accessing COD Data
- Add Your Data
- Documentation
Information card for entry 1567137
Preview
| Coordinates | 1567137.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Chemical name | Ge9{Si(SiMe3)}3Rh(Me2IMe)*hex |
|---|---|
| Formula | C40 H107 Ge9 N2 Rh Si12 |
| Calculated formula | C40 H107 Ge9 N2 Rh Si12 |
| Title of publication | Zintl cluster supported low coordinate Rh(i) centers for catalytic H/D exchange between H2 and D2 |
| Authors of publication | Townrow, Oliver P. E.; Duckett, Simon B.; Weller, Andrew S.; Goicoechea, Jose M. |
| Journal of publication | Chemical Science |
| Year of publication | 2022 |
| a | 16.3622 ± 0.0003 Å |
| b | 19.8996 ± 0.0003 Å |
| c | 25.9438 ± 0.0004 Å |
| α | 68.56 ± 0.001° |
| β | 79.856 ± 0.001° |
| γ | 82.113 ± 0.001° |
| Cell volume | 7715.4 ± 0.2 Å3 |
| Cell temperature | 150 ± 2 K |
| Ambient diffraction temperature | 150 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0593 |
| Residual factor for significantly intense reflections | 0.0544 |
| Weighted residual factors for significantly intense reflections | 0.1641 |
| Weighted residual factors for all reflections included in the refinement | 0.1728 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.048 |
| Diffraction radiation wavelength | 1.54184 Å |
| Diffraction radiation type | CuKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 276054 (current) | 2022-06-16 | cif/ Adding structures of 1567135, 1567136, 1567137, 1567138, 1567139 via cif-deposit CGI script. |
1567137.cif |
All data in the COD and the database itself are dedicated to the
public domain and licensed under the
CC0
License
.
Users of the data should acknowledge the original authors of the
structural data.