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Information card for entry 1567399
Preview
| Coordinates | 1567399.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C48 H65 Mn N7 O3 Si2 |
|---|---|
| Calculated formula | C48 H65 Mn N7 O3 Si2 |
| Title of publication | A bis(silylene)pyridine pincer ligand can stabilize mononuclear manganese(0) complexes: facile access to isolable analogues of the elusive d7-Mn(CO)5 radical |
| Authors of publication | Kalra, Shweta; Pividori, Daniel; Fehn, Dominik; Dai, Chenshu; Dong, Shicheng; Yao, Shenglai; Zhu, Jun; Meyer, Karsten; Driess, Matthias |
| Journal of publication | Chemical Science |
| Year of publication | 2022 |
| Journal volume | 13 |
| Journal issue | 29 |
| Pages of publication | 8634 - 8641 |
| a | 10.1252 ± 0.0003 Å |
| b | 18.0882 ± 0.0005 Å |
| c | 13.3966 ± 0.0005 Å |
| α | 90° |
| β | 103.606 ± 0.003° |
| γ | 90° |
| Cell volume | 2384.69 ± 0.13 Å3 |
| Cell temperature | 150.01 ± 0.1 K |
| Ambient diffraction temperature | 150.01 ± 0.1 K |
| Number of distinct elements | 6 |
| Space group number | 4 |
| Hermann-Mauguin space group symbol | P 1 21 1 |
| Hall space group symbol | P 2yb |
| Residual factor for all reflections | 0.0605 |
| Residual factor for significantly intense reflections | 0.0511 |
| Weighted residual factors for significantly intense reflections | 0.1279 |
| Weighted residual factors for all reflections included in the refinement | 0.1399 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.05 |
| Diffraction radiation wavelength | 1.54184 Å |
| Diffraction radiation type | CuKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 277001 (current) | 2022-07-30 | cif/ Adding structures of 1567398, 1567399, 1567400, 1567401 via cif-deposit CGI script. |
1567399.cif |
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Users of the data should acknowledge the original authors of the
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