Crystallography Open Database

Information card for entry 1568965

Preview

Coordinates	1568965.cif
Original IUCr paper	HTML

Structure parameters

Chemical name	(<i>N</i>-Benzoyl-<i>N</i>-phenylhydroxylaminato)carbonyl(triphenylarsine)rhodium(I)
Formula	C32 H25 As N O3 Rh
Calculated formula	C32 H25 As N O3 Rh
SMILES	[Rh]1(ON(C(=[O]1)c1ccccc1)c1ccccc1)([As](c1ccccc1)(c1ccccc1)c1ccccc1)C#[O]
Title of publication	(N-Benzoyl-N-phenylhydroxylaminato)carbonyl(triphenylarsine)rhodium(I)
Authors of publication	Motente, Mokete A.; Venter, Johan; Brink, Alice
Journal of publication	IUCrData
Year of publication	2023
Journal volume	8
Journal issue	4
Pages of publication	x230355
a	9.5178 ± 0.0017 Å
b	10.1995 ± 0.0019 Å
c	14.589 ± 0.002 Å
α	81.516 ± 0.006°
β	83.142 ± 0.006°
γ	72.351 ± 0.007°
Cell volume	1330.6 ± 0.4 Å³
Cell temperature	100 K
Ambient diffraction temperature	100 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0355
Residual factor for significantly intense reflections	0.0299
Weighted residual factors for significantly intense reflections	0.0707
Weighted residual factors for all reflections included in the refinement	0.0739
Goodness-of-fit parameter for all reflections included in the refinement	1.067
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
300370 (current)	2025-07-05	Updating bibliography information from the data sent by Robert McMeeking. cod/ (saulius@pterodaktilis)	1568965.cif
282852	2023-04-26	cif/ Adding structures of 1568965 via cif-deposit CGI script.	1568965.cif