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Information card for entry 1574536
Preview
| Coordinates | 1574536.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C38 H27 F3 N2 O3 P Pt |
|---|---|
| Calculated formula | C38 H27 F3 N2 O3 P Pt |
| SMILES | [Pt]12([O]=P(c3ccccc3)(c3ccccc3)c3ccccc3c3n1c1c(n3)cccc1)[n]1cc(ccc1c1c2cc(OC)cc1)C(F)(F)F |
| Title of publication | Building metal-induced inherent chirality: chiral stability/phosphorescence enhancement via a ring expansion strategy of Pt(ii) complexes |
| Authors of publication | Shi, Yingshuang; Tang, Ke; Zhang, Jincheng; Hu, Ping; Wang, Bi-Qin; Zhao, Ke-Qing; Zhou, Yuqiao; Xiang, Haifeng; Song, Jintong |
| Journal of publication | Chemical Science |
| Year of publication | 2025 |
| Journal volume | 16 |
| Journal issue | 21 |
| Pages of publication | 9135 - 9142 |
| a | 11.7209 ± 0.0003 Å |
| b | 12.2296 ± 0.0003 Å |
| c | 12.3631 ± 0.0003 Å |
| α | 80.842 ± 0.001° |
| β | 74.977 ± 0.001° |
| γ | 72.509 ± 0.001° |
| Cell volume | 1626.08 ± 0.07 Å3 |
| Cell temperature | 173 ± 2 K |
| Ambient diffraction temperature | 173 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0472 |
| Residual factor for significantly intense reflections | 0.0412 |
| Weighted residual factors for significantly intense reflections | 0.0919 |
| Weighted residual factors for all reflections included in the refinement | 0.0953 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.119 |
| Diffraction radiation wavelength | 1.54178 Å |
| Diffraction radiation type | CuKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 301209 (current) | 2025-07-10 | cif/1: Fixing Z values and formulae |
1574536.cif |
| 300667 | 2025-07-06 | cif/ Updating files of 1574533, 1574534, 1574535, 1574536, 1574537, 1574538, 1574539 Original log message: Adding full bibliography for 1574533--1574539.cif. |
1574536.cif |
| 299438 | 2025-04-29 | cif/ Adding structures of 1574533, 1574534, 1574535, 1574536, 1574537, 1574538, 1574539 via cif-deposit CGI script. |
1574536.cif |
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Users of the data should acknowledge the original authors of the
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