#------------------------------------------------------------------------------ #$Date: 2011-09-16 18:46:08 +0300 (Fri, 16 Sep 2011) $ #$Revision: 26025 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2011197.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2011197_Fobs loop_ _publ_author_name 'Yilmaz, Veysel T.' 'Karadag, Ahmet' 'Th\"one, Carsten' 'Herbst-Irmer, Regine' _publ_section_title ; trans-Bis(diethanolamine)bis(isothiocyanato)nickel(II) ; _journal_issue 8 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first 948 _journal_page_last 949 _journal_volume 56 _journal_year 2000 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90.000 _cell_angle_beta 100.119 _cell_angle_gamma 90.000 _cell_length_a 6.8157 _cell_length_b 8.3508 _cell_length_c 14.7254 _exptl_crystal_F_000 404.00 _reflns_d_resolution_high 0.7696 _[local]_cod_data_source_file bm1413Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' yilni in P2(1)/n' _shelx_refln_list_code 4 _shelx_f_calc_maximum 110.28 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 2604.35 2722.82 35.19 o 6 0 0 995.00 983.78 44.31 o 1 1 0 1260.06 1314.82 14.95 o 2 1 0 4841.82 4914.15 35.40 o 3 1 0 5222.97 5364.76 41.34 o 5 1 0 15.36 18.55 16.85 o 6 1 0 218.08 239.03 22.15 o 7 1 0 819.45 861.04 32.75 o 0 2 0 3258.51 3290.34 24.70 o 1 2 0 5774.24 5837.09 33.60 o 2 2 0 2582.96 2689.75 27.24 o 3 2 0 2866.33 2939.69 33.18 o 5 2 0 353.53 322.13 21.52 o 6 2 0 8.39 34.98 18.44 o 7 2 0 3.58 -10.71 21.20 o 1 3 0 1750.63 1633.46 22.90 o 2 3 0 0.21 2.44 12.72 o 3 3 0 98.54 131.76 15.05 o 5 3 0 1428.72 1488.34 35.51 o 6 3 0 28.32 15.90 19.19 o 7 3 0 44.51 37.74 20.99 o 0 4 0 2.95 5.41 13.57 o 1 4 0 53.40 53.21 13.67 o 2 4 0 3201.78 3189.96 36.89 o 3 4 0 54.02 58.51 15.79 o 5 4 0 12.09 24.59 18.97 o 6 4 0 1244.96 1172.15 35.51 o 7 4 0 3.85 3.71 22.15 o 1 5 0 799.94 789.06 23.21 o 2 5 0 35.47 28.94 16.22 o 3 5 0 1747.11 1753.45 34.87 o 5 5 0 745.77 738.18 29.79 o 6 5 0 1.34 -12.08 20.25 o 7 5 0 75.38 94.45 24.59 o 0 6 0 2170.68 2096.36 51.30 o 1 6 0 46.55 78.76 27.45 o 2 6 0 501.13 472.12 35.09 o 3 6 0 162.22 120.73 32.12 o 5 6 0 79.25 80.14 32.44 o 6 6 0 114.60 130.59 23.53 o 7 6 0 2.44 1.70 23.53 o 1 7 0 482.45 517.81 36.36 o 2 7 0 7.22 1.17 27.98 o 3 7 0 69.01 91.27 30.10 o 5 7 0 129.99 120.10 34.98 o 6 7 0 0.56 9.54 34.24 o 0 8 0 212.40 215.60 33.28 o 1 8 0 29.59 22.15 27.67 o 2 8 0 166.59 151.37 34.45 o 3 8 0 27.40 28.09 28.83 o 5 8 0 16.72 17.60 33.39 o 1 9 0 319.75 272.31 38.90 o 2 9 0 7.88 17.60 30.42 o 3 9 0 119.03 171.51 39.22 o 0 10 0 198.29 243.16 39.96 o 1 10 0 16.21 7.95 42.29 o 2 10 0 330.13 329.55 43.35 o 3 10 0 2.86 17.91 37.10 o -7 0 1 1282.97 1276.13 52.58 o -5 0 1 136.29 175.85 26.61 o -3 0 1 2552.99 2374.93 39.43 o -1 0 1 5790.74 5545.17 33.39 o 1 0 1 8776.44 8760.36 44.31 o 3 0 1 731.85 742.85 25.76 o 5 0 1 1515.12 1456.12 46.64 o 7 0 1 118.52 154.87 30.95 o -7 1 1 115.87 148.61 22.26 o -6 1 1 633.37 635.58 26.92 o -5 1 1 9.41 15.48 16.54 o -3 1 1 49.38 32.97 11.98 o -2 1 1 422.27 428.88 14.20 o -1 1 1 474.34 440.22 11.55 o 1 1 1 146.68 165.15 10.60 o 2 1 1 3344.61 3387.01 28.73 o 3 1 1 0.78 2.76 12.08 o 5 1 1 151.93 155.08 21.41 o 6 1 1 311.42 311.22 22.37 o 7 1 1 6.63 0.74 20.78 o -7 2 1 193.85 198.33 23.64 o -6 2 1 80.44 66.25 19.29 o -5 2 1 239.89 229.49 20.25 o -3 2 1 939.50 964.81 21.52 o -2 2 1 1659.68 1670.88 22.47 o -1 2 1 1477.79 1499.58 20.03 o 0 2 1 262.30 261.08 9.54 o 1 2 1 65.06 60.63 12.30 o 2 2 1 928.96 1023.64 19.29 o 3 2 1 2007.30 1986.23 28.62 o 5 2 1 71.33 7.00 32.12 o 6 2 1 324.08 345.24 23.85 o 7 2 1 340.91 359.98 27.03 o -7 3 1 0.17 -16.11 21.20 o -6 3 1 4.71 -16.32 18.13 o -5 3 1 68.74 56.60 19.82 o -3 3 1 467.99 466.82 18.23 o -2 3 1 1077.12 1118.93 21.73 o -1 3 1 18.72 24.80 11.87 o 0 3 1 740.42 747.94 12.19 o 1 3 1 268.47 271.68 14.42 o 2 3 1 3.42 5.72 12.83 o 3 3 1 77.68 66.78 14.10 o 5 3 1 18.13 31.38 19.29 o 6 3 1 552.88 530.21 27.56 o 7 3 1 10.04 16.54 22.37 o -7 4 1 20.37 20.88 22.90 o -6 4 1 0.12 15.58 19.61 o -5 4 1 1778.43 1819.70 39.22 o -3 4 1 335.39 328.28 19.50 o -2 4 1 505.37 515.37 19.40 o -1 4 1 2260.27 2206.71 29.57 o 0 4 1 177.92 184.86 11.02 o 1 4 1 156.36 171.61 15.69 o 2 4 1 10.06 18.13 13.57 o 3 4 1 1590.21 1595.40 30.63 o 5 4 1 240.12 247.19 22.15 o 6 4 1 398.91 433.22 26.71 o 7 4 1 448.07 432.90 28.83 o -7 5 1 251.65 280.90 27.45 o -6 5 1 759.07 751.33 32.22 o -5 5 1 148.06 155.50 22.15 o -3 5 1 78.71 70.60 18.13 o -2 5 1 1367.09 1369.52 30.00 o -1 5 1 93.38 80.45 15.69 o 0 5 1 1024.80 994.07 17.38 o 1 5 1 41.22 22.05 14.84 o 2 5 1 1830.82 1836.24 33.50 o 3 5 1 2.71 -15.26 17.49 o 5 5 1 16.87 -12.61 20.56 o 6 5 1 326.23 338.03 26.92 o 7 5 1 52.66 51.94 23.11 o -7 6 1 249.80 292.45 28.51 o -6 6 1 0.01 13.67 21.41 o -5 6 1 40.29 21.31 38.27 o -3 6 1 1469.91 1402.91 50.77 o -2 6 1 155.01 157.30 30.63 o -1 6 1 92.38 80.77 27.67 o 0 6 1 216.99 210.94 20.56 o 1 6 1 2693.09 2710.52 58.30 o 2 6 1 486.38 494.38 37.21 o 3 6 1 1.70 -20.99 28.20 o 5 6 1 1023.10 980.50 50.77 o 6 6 1 3.16 4.88 21.84 o 7 6 1 33.43 19.19 26.61 o -6 7 1 362.51 292.14 43.04 o -5 7 1 165.98 186.67 37.21 o -3 7 1 52.97 39.54 26.71 o -2 7 1 901.15 890.93 42.93 o -1 7 1 65.38 39.86 29.57 o 0 7 1 174.89 174.26 23.11 o 1 7 1 0.65 -6.89 28.62 o 2 7 1 356.10 378.74 34.56 o 3 7 1 0.01 -9.01 25.65 o 5 7 1 0.11 -3.82 30.74 o 6 7 1 4.34 12.30 37.52 o -5 8 1 96.66 108.12 38.90 o -3 8 1 100.09 133.03 34.03 o -2 8 1 343.10 284.08 35.72 o -1 8 1 123.36 91.80 30.21 o 0 8 1 618.01 603.78 29.57 o 1 8 1 543.24 590.10 41.55 o 2 8 1 616.76 557.56 41.87 o 3 8 1 65.73 57.98 31.69 o 5 8 1 132.38 73.78 41.23 o -3 9 1 32.75 37.21 35.83 o -2 9 1 67.06 71.44 35.09 o -1 9 1 314.67 325.21 39.22 o 0 9 1 379.76 382.77 28.73 o 1 9 1 33.95 48.12 32.65 o 2 9 1 445.55 485.90 44.84 o 3 9 1 12.08 18.13 33.50 o -3 10 1 20.35 5.72 37.74 o -2 10 1 1.77 9.01 33.92 o -1 10 1 701.08 864.64 51.94 o 0 10 1 28.70 20.67 24.27 o 1 10 1 2.32 0.32 32.22 o 2 10 1 6.07 -29.89 32.65 o 3 10 1 508.51 567.95 57.77 o -6 0 2 1602.49 1453.36 51.09 o -2 0 2 1629.24 1645.65 29.15 o 2 0 2 12160.69 11957.53 73.25 o 6 0 2 579.49 549.40 36.99 o -7 1 2 199.54 184.23 23.21 o -6 1 2 172.05 162.29 21.52 o -5 1 2 1184.28 1106.21 31.38 o -3 1 2 315.12 358.92 17.17 o -2 1 2 1325.16 1359.87 19.72 o -1 1 2 3215.54 3297.02 23.21 o 0 1 2 1.27 9.01 6.25 o 1 1 2 2097.57 2143.11 21.41 o 2 1 2 8.12 11.13 11.24 o 3 1 2 2363.58 2394.75 30.21 o 5 1 2 447.17 397.82 28.20 o 6 1 2 5.23 6.78 17.60 o 7 1 2 168.29 168.22 26.08 o -7 2 2 23.29 18.34 21.52 o -6 2 2 36.43 18.76 19.40 o -5 2 2 23.72 23.21 17.49 o -3 2 2 835.08 881.49 20.78 o -2 2 2 1022.98 1017.49 18.97 o -1 2 2 3207.87 3382.46 27.24 o 0 2 2 2417.53 2457.82 16.75 o 1 2 2 1936.68 1977.85 22.68 o 2 2 2 69.37 46.00 12.08 o 3 2 2 17.60 39.01 13.14 o 5 2 2 233.57 239.56 21.62 o 6 2 2 356.67 350.65 23.74 o 7 2 2 51.20 56.50 23.43 o -7 3 2 620.93 678.08 32.01 o -6 3 2 25.94 28.20 18.66 o -5 3 2 28.15 38.27 18.76 o -3 3 2 2194.32 2107.81 30.95 o -2 3 2 0.33 4.35 12.40 o -1 3 2 674.36 688.58 17.60 o 0 3 2 845.64 887.32 13.25 o 1 3 2 648.71 658.79 18.02 o 2 3 2 74.31 65.93 13.89 o 3 3 2 684.24 611.83 20.88 o 5 3 2 214.66 180.31 22.15 o 6 3 2 1.94 -0.53 18.76 o 7 3 2 474.49 432.80 29.47 o -7 4 2 31.07 30.74 21.94 o -6 4 2 219.96 219.74 23.43 o -5 4 2 13.48 12.30 18.97 o -3 4 2 1083.08 1036.04 26.18 o -2 4 2 418.90 423.15 18.44 o -1 4 2 859.89 889.97 21.84 o 0 4 2 4369.71 4438.00 28.20 o 1 4 2 1061.90 1101.97 23.32 o 2 4 2 3.14 5.30 14.10 o 3 4 2 38.26 51.62 16.32 o 5 4 2 38.20 40.70 19.82 o 6 4 2 141.69 117.87 22.26 o 7 4 2 0.37 -12.72 21.62 o -7 5 2 68.33 76.32 25.86 o -6 5 2 271.88 319.38 25.55 o -5 5 2 461.79 431.53 26.50 o -3 5 2 1616.26 1633.88 34.45 o -2 5 2 352.09 317.26 19.82 o -1 5 2 621.40 635.58 21.31 o 0 5 2 151.77 145.11 11.87 o 1 5 2 1289.58 1258.22 28.09 o 2 5 2 53.46 62.86 17.49 o 3 5 2 593.07 573.35 25.44 o 5 5 2 498.83 551.09 27.56 o 6 5 2 16.09 21.20 20.56 o 7 5 2 123.17 104.94 26.50 o -7 6 2 2.10 3.82 33.60 o -6 6 2 400.91 495.23 42.61 o -5 6 2 2.21 7.63 27.24 o -3 6 2 0.02 5.19 27.35 o -2 6 2 1632.12 1695.68 50.14 o -1 6 2 486.49 444.99 33.71 o 0 6 2 14.63 13.14 18.23 o 1 6 2 104.60 111.41 27.88 o 2 6 2 2183.44 2284.72 55.97 o 3 6 2 401.53 366.55 35.62 o 5 6 2 62.00 69.54 32.01 o 6 6 2 387.94 420.82 30.74 o 7 6 2 33.72 41.66 27.88 o -6 7 2 10.22 12.83 30.42 o -5 7 2 530.36 551.52 49.93 o -3 7 2 57.56 82.68 27.35 o -2 7 2 164.80 147.55 31.59 o -1 7 2 1026.27 1039.86 45.69 o 0 7 2 27.02 16.11 20.25 o 1 7 2 452.71 465.55 37.10 o 2 7 2 1.80 -9.43 27.77 o 3 7 2 87.69 111.19 31.48 o 5 7 2 398.85 336.13 53.74 o 6 7 2 3.57 -13.46 35.40 o -5 8 2 1.80 -1.59 35.40 o -3 8 2 3.70 30.85 28.83 o -2 8 2 498.59 473.40 40.07 o -1 8 2 370.29 391.67 37.63 o 0 8 2 77.16 65.40 20.25 o 1 8 2 410.33 450.92 40.17 o 2 8 2 474.32 446.68 41.02 o 3 8 2 368.86 324.25 37.95 o 5 8 2 81.85 109.39 36.57 o -3 9 2 503.96 517.28 47.81 o -2 9 2 3.24 16.96 30.00 o -1 9 2 5.74 29.36 29.26 o 0 9 2 116.71 128.68 22.58 o 1 9 2 507.44 517.70 45.26 o 2 9 2 1.31 15.37 30.42 o 3 9 2 234.15 228.64 40.49 o -3 10 2 63.21 57.77 38.27 o -2 10 2 21.59 38.48 34.34 o -1 10 2 11.19 22.47 35.93 o 0 10 2 827.34 857.75 38.05 o 1 10 2 37.32 30.74 33.60 o 2 10 2 4.42 10.71 35.72 o 3 10 2 29.34 46.32 38.58 o -7 0 3 470.98 429.94 37.52 o -5 0 3 1861.67 1714.12 48.23 o -3 0 3 12.51 9.65 17.28 o -1 0 3 1651.82 1691.97 26.50 o 1 0 3 3.55 -2.65 16.75 o 3 0 3 11458.01 10960.92 89.89 o 5 0 3 715.44 613.00 48.55 o 7 0 3 849.52 847.05 48.12 o -7 1 3 45.92 33.39 21.09 o -6 1 3 54.18 58.62 19.08 o -5 1 3 568.80 580.77 23.53 o -3 1 3 53.00 43.35 12.40 o -2 1 3 6.81 14.63 11.24 o -1 1 3 6588.84 6447.02 34.13 o 0 1 3 6436.10 6435.36 23.00 o 1 1 3 3450.97 3473.72 27.77 o 2 1 3 477.87 474.88 15.90 o 3 1 3 509.23 553.85 18.66 o 5 1 3 706.56 698.12 28.62 o 6 1 3 443.19 458.03 26.50 o 7 1 3 148.97 136.21 23.64 o -7 2 3 411.11 431.00 26.71 o -6 2 3 26.31 36.57 17.49 o -5 2 3 241.66 282.38 21.62 o -3 2 3 1470.65 1456.33 25.44 o -2 2 3 1282.60 1332.63 21.62 o -1 2 3 2744.54 2724.73 26.08 o 0 2 3 2617.95 2743.91 19.61 o 1 2 3 1880.42 1942.34 23.64 o 2 2 3 3128.25 3175.33 32.65 o 3 2 3 214.16 210.52 15.90 o 5 2 3 1434.53 1483.36 36.78 o 6 2 3 672.64 680.10 28.73 o 7 2 3 196.86 201.93 24.70 o -7 3 3 150.70 150.31 24.49 o -6 3 3 1306.14 1298.82 36.36 o -5 3 3 263.07 255.99 22.15 o -3 3 3 386.12 397.39 18.23 o -2 3 3 2498.67 2429.09 30.53 o -1 3 3 48.84 58.30 12.83 o 0 3 3 1964.61 1995.55 18.13 o 1 3 3 202.23 205.32 14.95 o 2 3 3 2307.08 2254.62 30.85 o 3 3 3 7.15 3.07 13.46 o 5 3 3 73.26 46.96 21.31 o 6 3 3 269.11 230.34 23.43 o 7 3 3 8.01 -14.31 21.41 o -7 4 3 98.83 115.12 22.68 o -6 4 3 102.66 94.45 20.46 o -5 4 3 125.25 101.34 26.29 o -3 4 3 2941.52 2925.81 39.11 o -2 4 3 388.39 386.69 18.23 o -1 4 3 371.32 364.32 17.70 o 0 4 3 3.52 -7.95 9.86 o 1 4 3 1506.68 1449.76 26.39 o 2 4 3 420.28 417.64 19.93 o 3 4 3 59.00 70.60 17.49 o 5 4 3 1035.24 1084.91 35.51 o 6 4 3 39.56 38.05 21.41 o 7 4 3 22.55 43.88 22.26 o -7 5 3 164.79 152.85 25.76 o -6 5 3 91.33 78.23 23.43 o -5 5 3 281.72 250.27 23.96 o -3 5 3 0.59 11.77 18.23 o -2 5 3 2191.80 2183.70 35.72 o -1 5 3 44.59 59.04 16.22 o 0 5 3 204.57 193.66 12.51 o 1 5 3 64.66 75.90 16.75 o 2 5 3 609.74 646.49 24.17 o 3 5 3 64.97 73.78 19.29 o 5 5 3 1.04 -21.09 21.52 o 6 5 3 280.25 304.75 27.14 o 7 5 3 7.11 -17.28 24.91 o -7 6 3 80.80 107.27 38.48 o -6 6 3 2.88 6.15 28.73 o -5 6 3 1035.43 1033.82 50.88 o -3 6 3 2.03 -9.22 27.45 o -2 6 3 0.37 11.98 27.03 o -1 6 3 910.49 963.22 40.39 o 0 6 3 339.05 319.80 22.37 o 1 6 3 693.22 615.22 36.68 o 2 6 3 27.77 23.21 30.10 o 3 6 3 491.66 472.12 37.84 o 5 6 3 105.52 130.06 34.87 o 6 6 3 35.69 20.14 22.68 o -6 7 3 129.42 76.43 36.99 o -5 7 3 5.71 16.64 31.80 o -3 7 3 14.17 5.51 27.67 o -2 7 3 138.51 156.99 30.00 o -1 7 3 1.27 26.08 29.04 o 0 7 3 705.24 750.59 29.68 o 1 7 3 78.33 58.41 28.41 o 2 7 3 413.72 362.41 34.87 o 3 7 3 2.85 -2.23 26.92 o 5 7 3 25.48 27.14 32.44 o 6 7 3 75.71 75.79 36.15 o -5 8 3 112.99 79.29 36.36 o -3 8 3 268.80 283.87 36.57 o -2 8 3 40.31 32.12 30.95 o -1 8 3 274.82 275.60 34.24 o 0 8 3 108.22 123.07 21.52 o 1 8 3 171.46 131.65 32.44 o 2 8 3 3.61 16.54 30.00 o 3 8 3 436.13 413.93 43.78 o 5 8 3 159.03 245.39 38.69 o -3 9 3 13.50 86.71 33.39 o -2 9 3 158.63 152.75 35.72 o -1 9 3 50.68 71.55 34.45 o 0 9 3 275.84 296.16 26.82 o 1 9 3 35.60 14.52 38.37 o 2 9 3 202.90 193.98 36.99 o 3 9 3 1.32 -33.71 35.51 o -3 10 3 391.48 368.77 51.52 o -2 10 3 0.33 -20.14 34.66 o -1 10 3 4.83 -21.41 34.45 o 0 10 3 4.31 -7.95 24.91 o 1 10 3 421.75 414.57 49.40 o 2 10 3 14.59 -15.90 34.45 o -6 0 4 210.78 249.63 30.10 o -2 0 4 142.51 142.68 17.81 o 0 0 4 7069.71 7137.61 36.46 o 2 0 4 62.94 58.09 17.60 o 6 0 4 228.72 222.18 30.95 o -7 1 4 623.09 637.27 29.36 o -6 1 4 3.86 5.51 18.55 o -5 1 4 310.28 336.34 21.20 o -3 1 4 1768.00 1812.07 26.92 o -2 1 4 96.97 99.53 12.19 o -1 1 4 890.83 803.80 23.53 o 0 1 4 2501.62 2638.23 17.49 o 1 1 4 64.89 50.56 11.98 o 2 1 4 4.94 1.91 12.19 o 3 1 4 2793.50 2718.79 34.77 o 5 1 4 332.06 381.60 25.44 o 6 1 4 201.75 192.07 22.37 o 7 1 4 91.85 68.37 23.85 o -7 2 4 100.09 102.93 23.21 o -6 2 4 193.36 207.23 21.31 o -5 2 4 241.49 264.15 21.20 o -3 2 4 3.68 -12.72 13.04 o -2 2 4 917.22 922.62 20.25 o -1 2 4 2177.60 2233.63 25.44 o 0 2 4 1749.39 1793.94 16.32 o 1 2 4 3163.72 3260.45 31.06 o 2 2 4 2966.18 2981.56 33.39 o 3 2 4 488.56 503.71 20.46 o 5 2 4 72.00 62.33 23.11 o 6 2 4 668.20 675.96 29.47 o 7 2 4 0.08 9.75 24.59 o -7 3 4 106.18 118.30 23.43 o -6 3 4 306.11 290.02 23.64 o -5 3 4 1514.30 1434.39 39.43 o -3 3 4 2.49 0.64 13.78 o -2 3 4 177.62 174.48 15.16 o -1 3 4 8601.48 8600.51 51.52 o 0 3 4 2652.10 2730.98 21.94 o 1 3 4 1926.29 1920.29 27.67 o 2 3 4 213.04 248.25 16.32 o 3 3 4 212.31 224.51 19.93 o 5 3 4 445.91 355.74 37.95 o 6 3 4 0.01 -8.80 19.08 o 7 3 4 595.96 596.25 32.65 o -7 4 4 69.44 39.43 23.11 o -6 4 4 421.54 385.95 26.92 o -5 4 4 80.98 81.20 20.56 o -3 4 4 522.17 542.93 22.79 o -2 4 4 3955.61 3850.34 41.34 o -1 4 4 252.28 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