#------------------------------------------------------------------------------ #$Date: 2016-04-02 21:26:34 +0300 (Sat, 02 Apr 2016) $ #$Revision: 180783 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/01/14/2011422.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2011422_Fobs loop_ _publ_author_name 'Ramos Silva, M.' 'Matos Beja, A.' 'Paix\~ao, J. A.' 'Alte da Veiga, L.' 'Sobral, A. J. F. N.' 'd Rocha Gonsalves, A. M.' _publ_section_title ; Benzyl 5-carboxy-4-ethyl-3-methylpyrrole-2-carboxylate ; _journal_issue 10 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first 1263 _journal_page_last 1264 _journal_volume 56 _journal_year 2000 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 98.938 _cell_angle_gamma 90.000 _cell_length_a 22.1953 _cell_length_b 5.2607 _cell_length_c 25.4132 _exptl_crystal_F_000 1216.00 _reflns_d_resolution_high 0.8418 _cod_data_source_file gd1110Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' as1139c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 258.14 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 4 0 0 1428.45 1232.79 13.72 o 6 0 0 21810.12 20760.87 96.03 o 8 0 0 6043.86 6025.11 60.51 o 10 0 0 1158.50 1154.60 17.22 o 12 0 0 11716.55 12054.49 106.70 o 14 0 0 3108.22 2962.79 29.72 o 16 0 0 1620.82 1782.43 25.15 o 18 0 0 7.14 -12.80 49.84 o 20 0 0 110.95 111.27 21.03 o 22 0 0 420.29 381.82 23.93 o 24 0 0 148.65 200.74 25.00 o 26 0 0 2.34 0.00 62.80 o 1 1 0 10544.68 9364.84 61.27 o 3 1 0 3921.95 3392.62 33.69 o 5 1 0 20859.20 19291.98 97.40 o 7 1 0 1339.77 1305.50 17.53 o 9 1 0 3810.63 4213.72 42.37 o 11 1 0 9251.63 9684.93 95.11 o 13 1 0 2.04 -9.15 42.37 o 15 1 0 173.81 177.72 18.44 o 17 1 0 20.84 8.69 48.47 o 19 1 0 0.62 -9.91 51.82 o 21 1 0 336.09 313.23 23.17 o 23 1 0 44.48 43.59 22.56 o 25 1 0 51.79 -32.16 64.32 o 0 2 0 99.28 79.26 17.07 o 2 2 0 5168.07 5152.19 51.82 o 4 2 0 756.30 747.48 17.22 o 6 2 0 1453.69 1436.28 19.81 o 8 2 0 5006.67 5184.50 51.98 o 10 2 0 1566.55 1545.72 21.80 o 12 2 0 12.65 -18.90 43.90 o 14 2 0 31.16 -23.78 47.56 o 16 2 0 188.38 180.77 21.64 o 18 2 0 527.41 533.94 24.39 o 20 2 0 16.05 12.96 22.10 o 22 2 0 8.40 -29.11 58.23 o 24 2 0 90.64 83.07 26.22 o 1 3 0 394.14 383.95 21.19 o 3 3 0 15.75 5.18 49.08 o 5 3 0 309.69 310.48 20.58 o 7 3 0 132.26 170.71 19.97 o 9 3 0 19.68 -9.60 50.15 o 11 3 0 33.45 12.50 19.97 o 13 3 0 1119.52 1151.86 26.98 o 15 3 0 859.29 842.44 26.52 o 17 3 0 13.59 21.80 56.09 o 19 3 0 10.23 48.32 56.85 o 21 3 0 68.01 30.48 63.26 o 0 4 0 197.31 223.45 25.45 o 2 4 0 0.72 -32.47 64.93 o 4 4 0 1116.30 1147.28 28.81 o 6 4 0 41.66 26.37 62.49 o 8 4 0 4.58 34.60 61.27 o 10 4 0 238.48 224.98 25.30 o 12 4 0 298.74 252.41 25.61 o 14 4 0 58.00 19.51 61.58 o 16 4 0 63.79 -10.52 63.10 o 18 4 0 38.80 34.60 64.63 o 20 4 0 63.34 64.02 27.44 o 1 5 0 1.73 49.69 72.55 o 3 5 0 4.52 -37.95 75.91 o 5 5 0 66.71 -7.93 74.38 o 7 5 0 40.22 49.08 28.05 o 9 5 0 2.58 -17.22 69.66 o 11 5 0 5.62 -25.45 66.46 o 13 5 0 49.53 -35.90 71.79 o 15 5 0 41.10 55.48 29.42 o 0 6 0 59.45 51.21 85.05 o 2 6 0 25.71 37.80 35.21 o 4 6 0 0.98 -42.14 84.29 o 6 6 0 45.20 26.67 81.24 o -25 1 1 48.12 59.90 25.61 o -23 1 1 1.21 0.00 57.01 o -21 1 1 3.05 23.63 53.50 o -19 1 1 293.62 241.74 21.95 o -17 1 1 743.25 748.85 23.02 o -15 1 1 179.51 220.56 17.99 o -13 1 1 1543.97 1408.84 21.49 o -11 1 1 581.38 561.98 16.92 o -9 1 1 10574.42 10781.61 90.84 o -7 1 1 3288.55 2967.97 29.42 o -5 1 1 200.35 194.49 14.78 o -3 1 1 1647.69 1576.51 16.16 o -1 1 1 7357.42 6788.60 55.02 o 1 1 1 17119.09 16013.82 75.45 o 3 1 1 27055.75 24278.02 97.25 o 5 1 1 4441.21 4428.79 43.75 o 7 1 1 605.39 613.50 16.00 o 9 1 1 2457.53 2477.02 25.15 o 11 1 1 86.79 85.97 15.24 o 13 1 1 3752.54 3700.67 37.50 o 15 1 1 927.71 867.13 21.64 o 17 1 1 1817.96 1875.86 28.35 o 19 1 1 772.47 735.44 24.54 o 21 1 1 1.52 20.88 52.28 o 23 1 1 4.82 -11.28 22.56 o 25 1 1 264.33 314.75 27.74 o -24 2 1 0.00 -29.87 59.75 o -22 2 1 65.32 53.81 23.02 o -20 2 1 4.31 1.68 52.89 o -18 2 1 1088.21 951.42 26.52 o -16 2 1 322.07 313.99 22.25 o -14 2 1 322.60 310.94 19.97 o -12 2 1 466.92 433.49 19.36 o -10 2 1 0.57 -21.03 42.07 o -8 2 1 62.26 73.16 15.70 o -6 2 1 3255.75 3297.66 32.31 o -4 2 1 1435.88 1344.06 18.75 o -2 2 1 2908.34 2897.86 27.44 o 0 2 1 1444.25 1375.06 17.53 o 2 2 1 305.44 225.74 17.07 o 4 2 1 219.24 198.76 16.16 o 6 2 1 7281.24 7219.34 73.62 o 8 2 1 2662.32 2558.57 26.52 o 10 2 1 4086.40 3928.84 38.41 o 12 2 1 278.71 251.65 18.60 o 14 2 1 89.11 78.04 19.05 o 16 2 1 1498.91 1494.50 27.89 o 18 2 1 1781.57 1722.22 29.57 o 20 2 1 166.17 159.43 23.17 o 22 2 1 190.93 179.86 23.78 o 24 2 1 9.30 10.21 62.80 o -21 3 1 0.33 22.71 61.73 o -19 3 1 35.31 51.98 23.32 o -17 3 1 67.35 -29.34 58.68 o -15 3 1 1135.29 1187.07 27.74 o -13 3 1 2.01 0.00 55.94 o -11 3 1 7.34 -3.51 51.06 o -9 3 1 15.86 -24.24 49.99 o -7 3 1 28.61 22.25 49.23 o -5 3 1 969.15 1010.56 22.56 o -3 3 1 107.53 41.31 51.21 o -1 3 1 4.37 11.74 50.76 o 1 3 1 1875.81 1938.21 25.30 o 3 3 1 134.50 122.70 19.81 o 5 3 1 773.51 686.97 21.80 o 7 3 1 596.22 687.43 22.10 o 9 3 1 14.74 -25.00 49.99 o 11 3 1 139.93 132.15 20.42 o 13 3 1 151.02 169.19 21.95 o 15 3 1 1560.53 1582.45 29.72 o 17 3 1 190.34 204.25 23.63 o 19 3 1 1.23 -11.81 23.63 o 21 3 1 48.61 66.46 25.61 o -20 4 1 4.05 -33.91 67.83 o -18 4 1 49.12 59.44 26.83 o -16 4 1 31.28 29.87 61.43 o -14 4 1 298.11 340.05 25.45 o -12 4 1 248.07 250.13 25.15 o -10 4 1 27.16 32.62 24.08 o -8 4 1 1443.78 1387.20 30.48 o -6 4 1 397.78 316.58 26.67 o -4 4 1 274.85 316.89 25.61 o -2 4 1 706.97 773.70 28.35 o 0 4 1 0.62 -0.67 58.99 o 2 4 1 1.47 -28.35 61.73 o 4 4 1 146.62 37.65 62.34 o 6 4 1 23.56 38.11 25.15 o 8 4 1 59.06 -31.09 62.19 o 10 4 1 86.32 83.68 24.54 o 12 4 1 331.74 266.13 25.61 o 14 4 1 45.93 32.77 60.51 o 16 4 1 39.16 55.79 24.54 o 18 4 1 5.86 56.09 60.97 o -15 5 1 5.46 -35.06 70.11 o -13 5 1 3.76 -14.40 28.81 o -11 5 1 0.14 63.71 26.52 o -9 5 1 5.70 61.88 64.32 o -7 5 1 40.33 37.80 68.59 o -5 5 1 4.48 -1.52 71.49 o -3 5 1 709.38 827.35 32.77 o -1 5 1 11.06 -4.57 74.53 o 1 5 1 159.55 225.59 30.03 o 3 5 1 182.02 235.04 29.87 o 5 5 1 49.89 7.93 72.40 o 7 5 1 122.65 70.42 28.35 o 9 5 1 57.91 8.69 67.83 o 11 5 1 13.27 -34.60 69.20 o 13 5 1 55.27 48.32 66.76 o 15 5 1 21.23 -35.90 71.79 o -6 6 1 4.07 -41.99 83.98 o -4 6 1 6.35 -3.96 84.90 o -2 6 1 0.00 -41.99 83.98 o 0 6 1 12.18 7.85 58.09 o 2 6 1 10.23 -43.44 86.88 o 4 6 1 13.19 -17.53 35.06 o 6 6 1 59.84 52.59 34.90 o -26 0 2 15.83 22.41 24.69 o -24 0 2 1.67 42.22 54.87 o -22 0 2 65.23 52.89 21.19 o -20 0 2 0.59 12.04 20.42 o -18 0 2 397.02 442.94 21.64 o -16 0 2 2647.33 2866.46 28.35 o -14 0 2 1347.87 1461.89 21.95 o -12 0 2 8893.48 9582.50 95.42 o -10 0 2 1002.14 1031.90 16.92 o -8 0 2 2409.46 2222.78 21.95 o -6 0 2 4326.54 3866.05 38.41 o -4 0 2 240.67 253.63 12.50 o 4 0 2 62851.26 58950.35 135.50 o 6 0 2 39369.18 38903.58 132.61 o 8 0 2 98.49 58.99 14.33 o 10 0 2 2342.34 2318.65 23.63 o 12 0 2 3831.21 4374.38 43.14 o 14 0 2 513.04 585.61 18.90 o 16 0 2 655.34 663.95 21.19 o 18 0 2 3.55 11.89 49.54 o 20 0 2 281.80 229.55 22.25 o 22 0 2 107.35 40.39 57.01 o 24 0 2 62.86 90.39 24.54 o -25 1 2 2.26 74.08 24.54 o -23 1 2 9.57 -27.89 55.79 o -21 1 2 173.78 179.55 21.80 o -19 1 2 119.60 108.07 20.88 o -17 1 2 47.32 45.42 19.05 o -15 1 2 1261.43 1309.46 22.86 o -13 1 2 66.46 35.36 41.00 o -11 1 2 89.36 154.56 15.39 o -9 1 2 375.53 410.63 15.24 o -7 1 2 16954.28 16489.08 100.45 o -5 1 2 23075.67 21553.47 101.97 o -3 1 2 3970.35 3866.50 40.09 o -1 1 2 1600.75 1614.46 16.77 o 1 1 2 134.82 155.47 13.72 o 3 1 2 468.97 523.72 15.09 o 5 1 2 2802.89 2796.04 28.96 o 7 1 2 508.60 454.37 15.39 o 9 1 2 63.79 28.50 38.26 o 11 1 2 576.63 624.17 17.68 o 13 1 2 44.57 24.69 16.92 o 15 1 2 1.64 -13.26 46.49 o 17 1 2 9.68 -10.21 20.42 o 19 1 2 0.81 1.52 50.30 o 21 1 2 2.14 -27.21 54.41 o 23 1 2 0.97 -28.88 57.77 o 25 1 2 0.07 -33.15 66.30 o -24 2 2 1.14 0.00 62.34 o -22 2 2 9.93 -1.68 22.56 o -20 2 2 185.78 170.71 23.02 o -18 2 2 174.84 127.58 22.41 o -16 2 2 278.55 281.68 21.49 o -14 2 2 360.85 404.22 19.97 o -12 2 2 236.99 247.23 18.14 o -10 2 2 23.06 -5.49 15.85 o -8 2 2 44.42 61.27 15.70 o -6 2 2 1416.87 1479.11 19.81 o -4 2 2 1576.65 1444.81 18.90 o -2 2 2 5342.56 5235.56 51.67 o 0 2 2 860.67 818.72 12.93 o 2 2 2 307.48 258.66 16.61 o 4 2 2 4847.66 5063.63 50.60 o 6 2 2 5476.23 5173.98 51.67 o 8 2 2 174.21 131.08 16.31 o 10 2 2 1475.42 1465.85 22.10 o 12 2 2 196.47 215.37 18.14 o 14 2 2 1526.26 1557.91 25.15 o 16 2 2 1647.14 1605.92 28.35 o 18 2 2 2.69 -10.75 21.49 o 20 2 2 352.43 306.06 24.54 o 22 2 2 38.02 30.94 23.32 o 24 2 2 14.50 18.44 61.27 o -23 3 2 5.24 45.88 62.34 o -21 3 2 5.48 -24.54 61.43 o -19 3 2 48.11 36.12 23.17 o -17 3 2 167.53 183.97 23.02 o -15 3 2 33.65 -28.88 57.77 o -13 3 2 103.48 152.73 21.64 o -11 3 2 591.45 603.29 22.41 o -9 3 2 127.90 160.81 19.97 o -7 3 2 9.19 -24.54 49.08 o -5 3 2 755.60 709.07 21.64 o -3 3 2 3311.35 3218.10 32.77 o -1 3 2 36.56 44.66 49.69 o 1 3 2 707.40 706.02 21.95 o 3 3 2 8.41 11.58 19.36 o 5 3 2 24.53 50.45 19.51 o 7 3 2 161.70 134.59 19.97 o 9 3 2 842.68 759.06 23.47 o 11 3 2 165.98 -4.73 54.11 o 13 3 2 724.74 674.62 24.69 o 15 3 2 86.96 33.53 57.92 o 17 3 2 588.73 564.27 26.52 o 19 3 2 189.23 138.09 24.39 o 21 3 2 12.28 -27.13 62.80 o -20 4 2 5.23 -2.13 63.10 o -18 4 2 132.34 139.31 27.13 o -16 4 2 14.39 50.76 62.65 o -14 4 2 331.07 347.07 26.06 o -12 4 2 183.63 231.07 25.00 o -10 4 2 204.25 177.88 24.69 o -8 4 2 236.81 255.46 25.30 o -6 4 2 558.58 465.19 26.98 o -4 4 2 16.18 60.36 60.66 o -2 4 2 357.00 383.95 26.98 o 0 4 2 6.94 22.08 22.31 o 2 4 2 34.83 -27.44 64.93 o 4 4 2 155.29 137.03 25.00 o 6 4 2 0.17 2.59 24.69 o 8 4 2 727.72 779.95 27.89 o 10 4 2 0.95 27.44 58.84 o 12 4 2 67.58 -30.18 60.36 o 14 4 2 106.89 107.61 24.84 o 16 4 2 2.13 24.39 24.39 o 18 4 2 79.74 64.32 66.91 o -15 5 2 6.34 33.69 28.66 o -13 5 2 52.34 45.88 69.66 o -11 5 2 253.40 234.73 28.50 o -9 5 2 66.90 -12.04 68.29 o -7 5 2 40.64 -21.34 71.64 o -5 5 2 0.00 35.06 71.49 o -3 5 2 43.31 -38.64 77.28 o -1 5 2 70.33 73.01 74.38 o 1 5 2 203.71 234.12 29.87 o 3 5 2 155.82 218.12 30.03 o 5 5 2 88.51 48.17 72.40 o 7 5 2 1.11 11.58 68.59 o 9 5 2 218.75 187.17 29.11 o 11 5 2 82.67 45.88 71.64 o 13 5 2 120.38 98.62 29.57 o 15 5 2 11.12 18.60 73.62 o -6 6 2 11.56 10.21 81.85 o -4 6 2 0.09 -43.36 86.73 o -2 6 2 146.58 158.52 35.67 o 0 6 2 299.73 312.54 25.38 o 2 6 2 166.94 231.68 35.67 o 4 6 2 58.62 35.82 34.30 o 6 6 2 4.22 34.45 34.14 o -25 1 3 103.13 111.27 25.45 o -23 1 3 17.79 3.51 57.62 o -21 1 3 106.03 94.35 21.80 o -19 1 3 334.72 338.99 22.56 o -17 1 3 194.03 182.91 19.21 o -15 1 3 655.09 746.41 20.58 o -13 1 3 76.22 12.65 41.76 o -11 1 3 19.17 -6.10 38.41 o -9 1 3 74.37 48.01 14.02 o -7 1 3 504.95 529.06 15.70 o -5 1 3 1874.31 1779.99 17.83 o -3 1 3 20434.32 19002.83 89.62 o -1 1 3 9515.95 9371.09 64.17 o 1 1 3 20087.87 19490.43 87.64 o 3 1 3 4916.14 4490.67 46.18 o 5 1 3 11452.45 10924.89 81.70 o 7 1 3 1293.59 1115.28 17.22 o 9 1 3 1231.11 1219.08 18.60 o 11 1 3 3416.16 3422.80 34.45 o 13 1 3 1152.35 1145.00 21.19 o 15 1 3 984.23 972.00 22.41 o 17 1 3 262.14 254.09 21.34 o 19 1 3 133.78 38.87 22.25 o 21 1 3 448.65 420.53 24.69 o 23 1 3 13.33 -12.12 24.24 o 25 1 3 0.04 -31.02 62.04 o -24 2 3 0.01 53.65 58.99 o -22 2 3 110.95 117.37 23.63 o -20 2 3 117.11 52.59 57.77 o -18 2 3 369.27 377.40 22.71 o -16 2 3 552.94 556.34 22.56 o -14 2 3 394.94 406.66 20.27 o -12 2 3 23.24 13.41 17.22 o -10 2 3 49.15 34.60 42.68 o -8 2 3 927.42 926.27 18.60 o -6 2 3 15.20 32.47 39.63 o -4 2 3 1284.88 1184.78 18.29 o -2 2 3 4260.25 4546.61 44.96 o 0 2 3 256.95 220.77 11.75 o 2 2 3 322.88 333.50 16.61 o 4 2 3 118.95 128.49 15.39 o 6 2 3 3.36 -20.42 40.85 o 8 2 3 745.97 674.17 18.29 o 10 2 3 913.10 873.53 20.12 o 12 2 3 1122.81 1127.01 22.56 o 14 2 3 492.43 535.16 21.34 o 16 2 3 2.73 -8.08 53.35 o 18 2 3 269.00 286.10 23.17 o 20 2 3 16.38 -29.57 59.14 o 22 2 3 8.11 39.17 58.23 o 24 2 3 2.36 -30.79 61.58 o -23 3 3 0.14 -32.92 65.85 o -21 3 3 9.34 15.09 59.60 o -19 3 3 13.71 -29.65 59.29 o -17 3 3 145.74 132.61 22.71 o -15 3 3 1521.41 1498.62 29.11 o -13 3 3 859.78 897.62 25.00 o -11 3 3 1.30 49.69 49.69 o -9 3 3 11.25 37.95 48.78 o -7 3 3 21.24 26.98 19.05 o -5 3 3 1398.67 1592.21 24.08 o -3 3 3 650.67 620.21 20.88 o -1 3 3 75.24 -5.94 48.93 o 1 3 3 1201.67 1280.81 23.47 o 3 3 3 1492.96 1543.13 23.93 o 5 3 3 288.50 316.58 20.42 o 7 3 3 949.47 1045.31 23.47 o 9 3 3 26.14 49.69 20.12 o 11 3 3 71.32 -10.82 21.64 o 13 3 3 192.93 214.61 22.56 o 15 3 3 460.82 457.27 25.00 o 17 3 3 812.59 815.16 27.28 o 19 3 3 0.22 46.18 57.31 o 21 3 3 31.15 -33.46 66.91 o -20 4 3 4.98 -31.09 65.24 o -18 4 3 105.94 88.10 27.44 o -16 4 3 34.85 40.85 24.84 o -14 4 3 250.89 289.76 25.30 o -12 4 3 166.87 141.91 24.69 o -10 4 3 174.08 118.58 25.00 o -8 4 3 35.33 24.69 24.54 o -6 4 3 15.53 1.22 59.75 o -4 4 3 7.92 -30.56 61.12 o -2 4 3 4.54 -31.78 63.56 o 0 4 3 100.14 -18.40 44.40 o 2 4 3 540.85 579.82 26.67 o 4 4 3 404.95 419.01 26.67 o 6 4 3 333.37 368.10 26.52 o 8 4 3 110.94 104.26 25.15 o 10 4 3 1.86 -7.32 60.97 o 12 4 3 48.15 58.07 24.24 o 14 4 3 439.92 446.29 26.98 o 16 4 3 55.81 10.82 61.88 o 18 4 3 0.02 1.98 65.85 o -15 5 3 23.60 21.19 28.66 o -13 5 3 0.01 -15.24 67.52 o -11 5 3 3.20 -34.37 68.74 o -9 5 3 5.82 -34.98 69.96 o -7 5 3 23.77 -6.55 67.98 o -5 5 3 101.04 68.90 28.35 o -3 5 3 57.22 -35.06 70.11 o -1 5 3 51.42 -10.82 71.94 o 1 5 3 209.52 269.33 29.72 o 3 5 3 3.47 -35.36 70.72 o 5 5 3 56.22 12.96 71.94 o 7 5 3 21.67 28.50 66.91 o 9 5 3 0.43 64.93 69.50 o 11 5 3 21.89 59.14 66.46 o 13 5 3 104.62 82.46 29.72 o 15 5 3 0.12 0.00 71.03 o -6 6 3 37.13 -42.30 84.59 o -4 6 3 11.92 -42.37 84.75 o -2 6 3 5.28 -23.93 82.16 o 0 6 3 10.75 -19.05 38.11 o 2 6 3 12.69 -37.95 85.66 o 4 6 3 1.25 30.48 81.24 o 6 6 3 0.20 10.36 80.33 o -26 0 4 78.83 -8.23 62.80 o -24 0 4 14.97 45.88 22.25 o -22 0 4 17.09 -9.30 21.64 o -20 0 4 1067.23 1030.68 26.22 o -18 0 4 234.81 226.96 20.73 o -16 0 4 1120.97 1065.59 22.25 o -14 0 4 4893.28 4921.42 49.99 o -12 0 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