#------------------------------------------------------------------------------ #$Date: 2016-04-02 21:28:50 +0300 (Sat, 02 Apr 2016) $ #$Revision: 180785 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/01/16/2011667.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2011667_Fobs loop_ _publ_author_name 'Paix\~ao, J. A.' 'Matos Beja, A.' 'Ramos Silva, M.' 'Alte da Veiga, L.' 'Serra, A. C.' _publ_section_title ; 2,4-Dibromo-3-methoxy-6-nitrobenzaldeyde: effect of substituents on ring geometry ; _journal_issue 12 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first 1501 _journal_page_last 1502 _journal_volume 56 _journal_year 2000 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90.000 _cell_angle_beta 95.847 _cell_angle_gamma 90.000 _cell_length_a 4.3048 _cell_length_b 18.1080 _cell_length_c 13.3152 _exptl_crystal_F_000 648.00 _reflns_d_resolution_high 0.7705 _cod_data_source_file sk1420Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' ACS53' _shelx_refln_list_code 4 _shelx_f_calc_maximum 252.64 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 173.65 246.87 8.97 o 4 0 0 1818.69 2037.78 24.95 o 1 1 0 548.25 684.40 7.39 o 2 1 0 10350.49 10439.58 68.63 o 3 1 0 724.00 761.95 15.07 o 4 1 0 25.74 -38.49 55.99 o 5 1 0 0.68 -30.99 75.91 o 1 2 0 8937.64 9254.33 51.08 o 2 2 0 137.01 213.35 9.26 o 3 2 0 76.36 61.97 12.59 o 4 2 0 0.38 48.31 51.87 o 5 2 0 280.80 295.86 25.23 o 1 3 0 9.56 -9.31 20.49 o 2 3 0 54.19 66.60 8.18 o 3 3 0 1.18 11.06 38.32 o 4 3 0 498.97 581.00 19.13 o 5 3 0 2.52 32.11 24.38 o 0 4 0 5627.29 5246.15 48.65 o 1 4 0 3370.53 3222.81 31.83 o 2 4 0 36.48 55.76 9.37 o 3 4 0 53.94 -15.80 41.65 o 4 4 0 2.08 -18.29 54.41 o 5 4 0 182.28 -56.84 76.08 o 1 5 0 2932.22 2726.36 26.81 o 2 5 0 6523.99 6372.81 62.31 o 3 5 0 1829.60 1902.16 19.25 o 4 5 0 3.23 -14.79 56.78 o 5 5 0 11.28 61.24 75.74 o 0 6 0 63824.92 56434.88 174.57 o 1 6 0 132.49 137.77 9.93 o 2 6 0 58.89 66.26 11.74 o 3 6 0 4.86 21.00 46.28 o 4 6 0 887.87 951.59 23.08 o 5 6 0 4.85 14.28 26.64 o 1 7 0 2609.25 2766.21 27.15 o 2 7 0 11558.06 10826.14 99.17 o 3 7 0 15.34 17.84 16.14 o 4 7 0 36.14 -14.45 64.12 o 5 7 0 43.69 70.55 28.11 o 0 8 0 1745.65 1654.61 16.48 o 1 8 0 1758.51 1734.70 17.55 o 2 8 0 253.18 256.97 14.73 o 3 8 0 3.51 7.22 54.24 o 4 8 0 54.38 -9.76 69.93 o 5 8 0 24.32 10.72 85.85 o 1 9 0 23.83 27.15 12.81 o 2 9 0 17.85 33.69 44.93 o 3 9 0 6.56 12.98 56.33 o 4 9 0 100.20 102.38 24.33 o 5 9 0 8.99 -1.58 90.08 o 0 10 0 1209.73 1156.58 16.25 o 1 10 0 238.68 193.99 14.39 o 2 10 0 349.45 329.05 17.78 o 3 10 0 2.10 -15.41 59.77 o 4 10 0 3.96 70.83 76.76 o 5 10 0 49.35 -89.12 99.39 o 1 11 0 788.79 704.15 17.61 o 2 11 0 1773.60 1699.26 23.37 o 3 11 0 1343.06 1296.04 25.45 o 4 11 0 1.34 -47.24 77.32 o 0 12 0 11336.32 11196.16 106.50 o 1 12 0 600.47 551.93 19.25 o 2 12 0 113.69 108.82 19.70 o 3 12 0 17.73 32.00 65.92 o 4 12 0 435.75 498.14 30.25 o 1 13 0 215.06 261.94 20.04 o 2 13 0 3608.69 3504.39 35.05 o 3 13 0 1.05 17.50 24.21 o 4 13 0 8.11 -28.56 30.42 o 0 14 0 2253.89 2445.68 27.66 o 1 14 0 1075.82 1275.33 24.83 o 2 14 0 86.18 43.80 66.37 o 3 14 0 55.71 22.29 82.18 o 4 14 0 47.03 108.48 32.34 o 1 15 0 158.08 125.69 22.80 o 2 15 0 80.21 2.93 73.20 o 3 15 0 10.89 -59.04 87.82 o 4 15 0 1.39 58.92 99.05 o 0 16 0 608.34 605.55 25.17 o 1 16 0 315.59 284.69 24.61 o 2 16 0 72.91 -21.96 77.61 o 3 16 0 1.49 -37.25 90.70 o 4 16 0 19.84 -10.61 108.87 o 1 17 0 5.02 -20.77 74.61 o 2 17 0 239.96 297.16 29.29 o 3 17 0 304.61 297.72 33.69 o 0 18 0 1746.48 1869.59 30.37 o 1 18 0 330.32 296.20 30.03 o 2 18 0 4.53 -46.11 92.22 o 3 18 0 2.61 -56.55 108.20 o 1 19 0 54.16 51.53 31.55 o 2 19 0 850.59 1013.67 34.82 o 3 19 0 0.14 -35.84 107.46 o 0 20 0 428.80 556.90 31.83 o 1 20 0 51.30 172.37 33.07 o 2 20 0 7.16 -34.54 34.54 o 1 21 0 14.71 85.34 34.43 o 2 21 0 4.00 18.34 36.69 o 0 22 0 0.37 -107.07 107.07 o 1 22 0 85.11 -12.08 101.37 o 1 23 0 23.52 88.61 109.27 o -5 0 1 0.37 -33.98 72.02 o -3 0 1 735.39 677.96 13.26 o -1 0 1 16176.52 16495.14 62.14 o 1 0 1 29503.95 30460.16 80.26 o 3 0 1 3281.31 3428.20 34.60 o 5 0 1 275.02 313.87 25.57 o -5 1 1 50.77 12.08 70.78 o -4 1 1 753.42 693.77 18.79 o -3 1 1 1792.90 1687.57 16.82 o -2 1 1 1327.95 1308.69 13.32 o -1 1 1 48.79 62.03 5.76 o 1 1 1 39528.38 39984.38 92.96 o 2 1 1 6.75 -2.65 23.54 o 3 1 1 302.76 362.01 13.32 o 4 1 1 96.38 109.16 17.50 o 5 1 1 120.58 154.25 24.72 o -5 2 1 26.50 33.53 23.71 o -4 2 1 726.21 603.12 18.68 o -3 2 1 798.57 740.22 14.39 o -2 2 1 722.57 657.93 9.82 o -1 2 1 2581.69 2555.91 25.68 o 1 2 1 4093.64 4176.32 35.73 o 2 2 1 3666.42 3880.79 38.66 o 3 2 1 929.33 954.97 14.84 o 4 2 1 4.19 -5.36 52.32 o 5 2 1 4.17 -23.54 24.44 o -5 3 1 150.04 153.12 24.78 o -4 3 1 0.22 -13.15 17.72 o -3 3 1 675.82 589.52 14.39 o -2 3 1 72.22 96.46 9.37 o -1 3 1 9654.05 9629.26 70.32 o 0 3 1 697.48 688.08 30.62 o 1 3 1 3296.61 3183.81 31.78 o 2 3 1 225.33 250.14 9.09 o 3 3 1 898.36 866.08 15.13 o 4 3 1 42.04 60.50 17.72 o 5 3 1 47.29 -1.35 71.85 o -5 4 1 35.72 11.91 24.78 o -4 4 1 416.91 351.17 19.75 o -3 4 1 1819.29 1638.64 18.17 o -2 4 1 1949.74 1917.28 18.06 o -1 4 1 3010.57 2981.75 31.32 o 0 4 1 1407.47 1436.94 89.77 o 1 4 1 4924.73 4612.15 46.00 o 2 4 1 3184.44 3212.48 32.90 o 3 4 1 377.03 352.75 14.79 o 4 4 1 12.97 31.55 18.12 o 5 4 1 0.15 -44.31 73.99 o -5 5 1 41.43 -20.26 77.78 o -4 5 1 337.89 317.70 19.64 o -3 5 1 545.03 551.99 16.14 o -2 5 1 2780.28 2643.90 26.53 o -1 5 1 134.39 143.81 11.01 o 0 5 1 10350.24 9697.35 351.96 o 1 5 1 8552.82 8137.09 63.78 o 2 5 1 226.74 263.24 10.44 o 3 5 1 225.12 287.28 15.24 o 4 5 1 380.68 424.15 19.98 o 5 5 1 40.80 -24.33 26.19 o -5 6 1 58.64 77.15 80.54 o -4 6 1 60.34 78.51 20.26 o -3 6 1 985.89 929.58 18.96 o -2 6 1 429.72 417.10 13.66 o -1 6 1 11918.71 11482.94 92.73 o 0 6 1 491.31 430.66 33.22 o 1 6 1 8852.41 8280.56 70.95 o 2 6 1 194.54 150.36 11.12 o 3 6 1 3638.34 3762.78 38.49 o 4 6 1 0.76 -16.65 20.09 o 5 6 1 46.91 -56.89 80.09 o -5 7 1 103.45 84.32 85.34 o -4 7 1 151.43 143.42 21.67 o -3 7 1 1733.64 1683.28 22.75 o -2 7 1 815.75 845.99 16.14 o -1 7 1 8933.07 9146.81 89.91 o 0 7 1 3988.75 3872.98 206.83 o 1 7 1 13158.00 11952.41 91.26 o 2 7 1 106.48 107.46 12.30 o 3 7 1 116.43 133.48 16.93 o 4 7 1 33.44 47.75 63.33 o 5 7 1 98.73 17.55 83.48 o -5 8 1 3.03 10.95 88.61 o -4 8 1 228.80 154.82 23.93 o -3 8 1 188.53 53.22 58.81 o -2 8 1 157.96 199.91 16.25 o -1 8 1 4217.82 4168.81 42.39 o 0 8 1 667.42 549.24 62.06 o 1 8 1 780.54 730.85 13.32 o 2 8 1 5954.44 6148.52 61.29 o 3 8 1 592.52 573.10 18.96 o 4 8 1 14.28 12.02 67.95 o 5 8 1 2.18 -29.07 29.07 o -5 9 1 200.70 61.58 96.12 o -4 9 1 2.53 47.47 74.39 o -3 9 1 214.14 167.35 20.09 o -2 9 1 105.48 116.66 17.55 o -1 9 1 10359.05 10593.83 95.84 o 0 9 1 177.72 163.79 20.91 o 1 9 1 796.14 783.17 14.51 o 2 9 1 56.21 28.62 45.15 o 3 9 1 43.33 -58.47 58.47 o 4 9 1 70.36 53.45 72.92 o 5 9 1 6.35 11.34 30.48 o -5 10 1 11.55 -11.80 34.88 o -4 10 1 156.96 77.10 27.09 o -3 10 1 920.94 802.98 24.66 o -2 10 1 902.75 910.89 21.56 o -1 10 1 2123.60 2125.55 21.22 o 0 10 1 7.53 -24.18 29.97 o 1 10 1 1947.95 1800.73 19.42 o 2 10 1 1056.34 992.45 18.91 o 3 10 1 38.85 46.62 58.47 o 4 10 1 18.47 59.04 73.65 o -4 11 1 157.92 184.22 28.73 o -3 11 1 146.17 68.58 71.40 o -2 11 1 931.96 837.35 23.20 o -1 11 1 102.10 -54.30 54.30 o 0 11 1 4179.73 4112.96 90.84 o 1 11 1 4399.30 4322.72 43.97 o 2 11 1 1.65 39.06 52.09 o 3 11 1 120.80 114.91 21.84 o 4 11 1 300.06 323.18 28.73 o -4 12 1 26.88 90.08 90.08 o -3 12 1 663.52 657.19 27.77 o -2 12 1 759.66 782.38 23.93 o -1 12 1 3621.37 3643.91 37.14 o 0 12 1 157.06 196.27 27.01 o 1 12 1 2029.44 2021.53 23.99 o 2 12 1 122.49 51.47 60.17 o 3 12 1 837.80 899.72 26.13 o 4 12 1 2.35 -9.54 84.60 o -4 13 1 4.77 -11.12 94.03 o -3 13 1 727.67 712.73 29.24 o -2 13 1 58.50 88.89 23.25 o -1 13 1 882.24 841.25 24.38 o 0 13 1 746.62 783.83 123.49 o 1 13 1 4831.95 4938.60 50.46 o 2 13 1 1.23 45.27 63.55 o 3 13 1 220.23 262.45 24.83 o 4 13 1 52.86 40.13 91.38 o -4 14 1 159.05 131.00 33.75 o -3 14 1 47.25 69.37 86.18 o -2 14 1 21.34 46.45 75.29 o -1 14 1 2356.49 2418.03 29.24 o 0 14 1 2228.79 2132.47 67.31 o 1 14 1 48.20 48.88 21.62 o 2 14 1 421.43 517.00 24.10 o 3 14 1 286.71 275.26 27.77 o 4 14 1 30.25 18.00 32.28 o -4 15 1 2.18 -28.45 105.66 o -3 15 1 9.40 32.79 29.91 o -2 15 1 54.24 8.01 80.09 o -1 15 1 723.97 673.00 26.24 o 0 15 1 24.40 46.83 19.54 o 1 15 1 55.29 -1.58 69.31 o 2 15 1 7.48 -24.10 24.10 o 3 15 1 1.02 -23.03 84.66 o 4 15 1 25.42 -37.87 101.25 o -4 16 1 20.26 -44.70 109.72 o -3 16 1 138.17 47.58 95.89 o -2 16 1 152.44 133.76 28.84 o -1 16 1 476.65 432.79 25.62 o 0 16 1 221.24 194.15 20.15 o 1 16 1 786.90 833.63 25.85 o 2 16 1 84.64 -23.37 77.32 o 3 16 1 8.93 90.08 90.08 o 4 16 1 2.24 42.67 36.40 o -3 17 1 50.95 -2.20 102.50 o -2 17 1 157.07 88.22 91.32 o -1 17 1 46.94 63.10 78.51 o 0 17 1 608.87 595.58 55.09 o 1 17 1 609.47 675.59 26.36 o 2 17 1 42.56 -62.20 86.35 o 3 17 1 3.52 58.25 96.17 o -3 18 1 60.29 -72.47 111.98 o -2 18 1 291.74 62.14 100.29 o -1 18 1 852.87 892.55 32.34 o 0 18 1 55.05 68.13 18.94 o 1 18 1 164.45 150.98 26.81 o 2 18 1 58.24 -27.09 92.96 o 3 18 1 210.89 234.68 35.16 o -3 19 1 116.17 215.94 38.77 o -2 19 1 9.08 77.83 101.03 o -1 19 1 283.53 283.16 32.40 o 0 19 1 0.06 -34.74 34.74 o 1 19 1 400.47 457.85 29.63 o 2 19 1 41.11 76.87 98.09 o 3 19 1 72.33 86.18 106.56 o -2 20 1 7.29 -2.09 103.68 o -1 20 1 338.45 334.13 33.24 o 0 20 1 13.57 59.58 30.31 o 1 20 1 10.58 71.96 87.48 o 2 20 1 122.11 52.72 109.04 o -2 21 1 33.24 40.19 36.69 o -1 21 1 171.46 140.31 35.44 o 0 21 1 1.50 -52.56 69.56 o 1 21 1 81.96 77.61 33.86 o 2 21 1 15.72 -18.74 110.17 o -1 22 1 49.52 19.53 112.09 o 0 22 1 13.01 -51.73 77.01 o 1 22 1 50.06 8.47 108.65 o -1 23 1 50.82 -23.14 123.66 o 0 23 1 118.13 118.99 34.69 o 1 23 1 79.96 150.24 40.92 o -4 0 2 91.38 125.52 17.50 o -2 0 2 124.89 150.36 8.92 o 0 0 2 902.80 1034.38 34.68 o 2 0 2 5298.94 5638.92 55.09 o 4 0 2 269.33 311.10 18.51 o -5 1 2 53.17 61.18 70.16 o -4 1 2 10.64 29.24 17.10 o -3 1 2 4396.12 4318.49 43.06 o -2 1 2 603.81 585.51 9.31 o -1 1 2 1580.79 1957.70 19.47 o 0 1 2 1166.83 1226.44 84.15 o 1 1 2 42955.77 42672.99 102.83 o 2 1 2 4147.46 4627.67 45.38 o 3 1 2 166.05 217.18 12.92 o 4 1 2 181.03 166.16 18.00 o 5 1 2 50.38 -19.02 73.26 o -5 2 2 57.11 -47.69 72.24 o -4 2 2 9.01 19.08 16.88 o -3 2 2 298.39 269.50 13.04 o -2 2 2 11037.01 10838.44 78.17 o -1 2 2 5833.49 6560.53 55.03 o 0 2 2 413.04 423.51 32.68 o 1 2 2 435.16 413.77 6.49 o 2 2 2 2552.36 2512.62 25.40 o 3 2 2 1303.04 1397.98 16.09 o 4 2 2 49.15 72.92 17.89 o 5 2 2 5.26 -6.32 72.92 o -5 3 2 1.84 -72.75 72.75 o -4 3 2 1899.19 1651.90 22.29 o -3 3 2 4.46 -2.88 13.49 o -2 3 2 2286.85 2310.34 22.52 o -1 3 2 159.04 129.08 9.54 o 0 3 2 26659.78 24913.61 1609.71 o 1 3 2 11.89 -15.46 18.34 o 2 3 2 3701.44 3842.25 37.87 o 3 3 2 4.92 -3.22 13.32 o 4 3 2 484.89 601.83 19.53 o 5 3 2 4.24 23.65 71.91 o -5 4 2 45.89 19.70 25.23 o -4 4 2 74.23 82.29 18.91 o -3 4 2 406.97 341.92 15.63 o -2 4 2 11053.72 11122.79 101.03 o -1 4 2 6243.49 6742.39 60.62 o 0 4 2 1761.14 1754.97 12.06 o 1 4 2 4586.99 4564.12 45.32 o 2 4 2 5181.82 5023.43 52.04 o 3 4 2 1451.16 1505.04 17.89 o 4 4 2 93.04 15.69 58.13 o 5 4 2 21.66 -75.40 75.40 o -5 5 2 87.39 47.01 78.40 o -4 5 2 14.35 -7.51 58.87 o -3 5 2 1836.84 1686.10 20.94 o -2 5 2 17.79 39.06 40.58 o -1 5 2 30.81 37.36 10.78 o 0 5 2 2157.20 1915.70 116.30 o 1 5 2 3455.84 3364.65 33.41 o 2 5 2 1360.60 1495.00 15.18 o 3 5 2 174.30 183.32 14.79 o 4 5 2 97.72 101.93 19.42 o 5 5 2 51.46 -81.78 81.78 o -5 6 2 46.64 32.79 27.43 o -4 6 2 380.77 381.03 22.46 o -3 6 2 1.55 -38.38 52.60 o -2 6 2 48.46 37.53 44.76 o -1 6 2 359.31 348.29 12.42 o 0 6 2 4773.52 4504.95 236.32 o 1 6 2 1.27 -27.66 27.66 o 2 6 2 147.69 142.91 11.23 o 3 6 2 76.01 108.54 15.58 o 4 6 2 205.44 212.44 21.96 o 5 6 2 0.85 22.75 77.72 o -5 7 2 154.64 31.72 86.41 o -4 7 2 13.20 -69.65 69.65 o -3 7 2 1105.42 1174.47 23.03 o -2 7 2 788.28 758.39 18.17 o -1 7 2 3963.48 4549.84 45.72 o 0 7 2 997.17 902.18 8.80 o 1 7 2 4711.29 4242.86 43.35 o 2 7 2 472.41 505.14 13.38 o 3 7 2 354.13 373.18 17.55 o 4 7 2 340.02 352.53 23.03 o 5 7 2 7.82 -11.68 85.56 o -5 8 2 345.40 348.69 31.66 o -4 8 2 84.15 -28.67 75.91 o -3 8 2 118.36 -9.82 63.16 o -2 8 2 3451.29 3374.81 34.71 o -1 8 2 1725.19 1778.55 18.29 o 0 8 2 35.65 44.55 7.80 o 1 8 2 24.93 30.25 33.53 o 2 8 2 2173.73 2166.64 22.86 o 3 8 2 1907.94 1945.34 22.69 o 4 8 2 0.43 -11.74 67.45 o 5 8 2 0.63 -27.94 87.37 o -5 9 2 36.42 -95.55 95.55 o -4 9 2 636.06 571.46 28.50 o -3 9 2 10.39 20.38 63.89 o -2 9 2 1002.48 1003.68 20.66 o -1 9 2 98.59 139.69 14.11 o 0 9 2 11737.71 11436.27 227.96 o 1 9 2 419.57 369.97 13.32 o 2 9 2 775.88 774.76 17.16 o 3 9 2 60.33 44.31 54.69 o 4 9 2 54.93 37.70 72.70 o 5 9 2 8.65 26.08 93.52 o -5 10 2 44.73 54.47 35.73 o -4 10 2 127.40 114.46 28.28 o -3 10 2 9.85 -27.54 67.45 o -2 10 2 4403.23 4333.79 42.22 o -1 10 2 1265.63 1209.80 19.13 o 0 10 2 1614.68 1657.60 52.52 o 1 10 2 602.30 583.43 14.73 o 2 10 2 3406.76 3171.34 30.65 o 3 10 2 386.11 432.22 21.28 o 4 10 2 54.08 63.21 76.14 o -4 11 2 101.40 86.86 29.41 o -3 11 2 631.79 579.42 26.58 o -2 11 2 20.45 2.48 20.71 o -1 11 2 477.79 531.33 18.29 o 0 11 2 4965.85 4727.38 33.44 o 1 11 2 1027.94 1055.21 18.23 o 2 11 2 86.17 134.50 17.61 o 3 11 2 77.10 36.63 63.16 o 4 11 2 23.97 -4.52 79.41 o -4 12 2 3.58 -14.05 30.82 o -3 12 2 4.41 -76.25 76.25 o -2 12 2 13.07 6.60 22.35 o -1 12 2 551.32 582.30 20.49 o 0 12 2 662.56 644.80 12.83 o 1 12 2 64.61 -34.32 51.14 o 2 12 2 195.67 196.53 19.58 o 3 12 2 14.66 53.90 22.41 o 4 12 2 90.94 44.59 85.17 o -4 13 2 20.13 -55.82 98.43 o -3 13 2 219.82 234.96 28.67 o -2 13 2 411.20 477.94 25.34 o -1 13 2 196.94 202.40 21.11 o 0 13 2 154.47 158.14 13.41 o 1 13 2 769.27 722.21 20.43 o 2 13 2 698.45 675.99 21.67 o 3 13 2 22.53 58.36 72.07 o 4 13 2 41.91 -91.77 91.77 o -4 14 2 34.84 38.44 35.61 o -3 14 2 77.60 65.25 30.70 o -2 14 2 694.97 702.46 26.53 o -1 14 2 896.07 1009.50 25.17 o 0 14 2 33.62 0.62 43.82 o 1 14 2 226.49 152.62 20.43 o 2 14 2 882.08 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