#------------------------------------------------------------------------------ #$Date: 2016-04-02 21:35:28 +0300 (Sat, 02 Apr 2016) $ #$Revision: 180791 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/01/22/2012288.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2012288_Fobs loop_ _publ_author_name 'Toscano, Rub\'en A.' 'Hern\'andez-Ortega, Sim\'on' 'Ortiz, Benjam\'in' 'S\'anchez-Obreg\'on, Rub\'en' 'Walls, Fernando' 'Yuste, Francisco' _publ_section_title ; Diethyl 2-[cyano(toluene-4-sulfinyl)methylene]propanedioate and its Diels--Alder adduct with cyclopentadiene ; _journal_issue 11 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first 1313 _journal_page_last 1315 _journal_volume 57 _journal_year 2001 _space_group_IT_number 9 _symmetry_space_group_name_Hall 'C -2yc' _symmetry_space_group_name_H-M 'C 1 c 1' _cell_angle_alpha 90.000 _cell_angle_beta 95.980 _cell_angle_gamma 90.000 _cell_length_a 8.4580 _cell_length_b 15.1370 _cell_length_c 15.9300 _exptl_crystal_F_000 848.00 _reflns_d_resolution_high 0.7697 _cod_data_source_file bj1028IIsup3.hkl _cod_data_source_block II #BEGIN Tags that were not found in dictionaries: _shelx_title ' Compound (2)' _shelx_refln_list_code 4 _shelx_f_calc_maximum 205.01 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' 'x, -y, z+1/2' 'x+1/2, y+1/2, z' 'x+1/2, -y+1/2, z+1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 0 0 -20 83.81 53.25 111.83 o 2 0 -20 11.66 -55.38 104.38 o 1 1 -20 12.29 9.59 107.57 o 3 1 -20 1.47 9.59 101.18 o 0 2 -20 6.33 19.17 104.38 o 2 2 -20 31.05 62.84 99.05 o 1 3 -20 12.78 -34.08 109.70 o 3 3 -20 1.65 -48.99 100.12 o 0 4 -20 15.07 22.37 104.38 o 2 4 -20 36.59 40.47 109.70 o 1 5 -20 14.26 -17.04 117.16 o 1 1 -19 72.80 58.58 94.79 o 3 1 -19 45.72 34.08 93.73 o 5 1 -19 40.18 58.58 100.12 o 0 2 -19 64.20 -56.45 102.25 o 2 2 -19 2.76 23.43 101.18 o 4 2 -19 27.56 36.21 90.53 o 1 3 -19 3.19 29.82 82.01 o 3 3 -19 41.07 67.10 99.05 o 5 3 -19 24.30 -23.43 93.73 o 0 4 -19 1.85 79.88 93.73 o 2 4 -19 90.97 31.95 96.92 o 4 4 -19 19.51 -9.59 91.59 o 1 5 -19 8.12 -3.20 95.86 o 3 5 -19 14.33 139.52 92.66 o 0 6 -19 13.30 44.73 109.70 o 2 6 -19 25.27 -34.08 101.18 o 1 7 -19 2.26 44.73 105.44 o 0 0 -18 280.73 179.99 95.86 o 2 0 -18 12.75 -13.85 90.53 o 4 0 -18 23.00 7.46 85.20 o 6 0 -18 42.03 27.69 94.79 o 1 1 -18 23.44 19.17 99.05 o 3 1 -18 5.70 51.12 90.53 o 5 1 -18 8.97 0.00 79.88 o 0 2 -18 25.10 60.71 90.53 o 2 2 -18 49.89 68.16 100.12 o 4 2 -18 13.41 9.59 86.27 o 6 2 -18 3.38 93.73 82.01 o 1 3 -18 44.34 141.65 93.73 o 3 3 -18 13.09 12.78 88.40 o 5 3 -18 88.72 76.68 92.66 o 0 4 -18 31.41 -10.65 101.18 o 2 4 -18 28.19 57.51 90.53 o 4 4 -18 10.30 53.25 89.46 o 1 5 -18 46.30 41.54 99.05 o 3 5 -18 52.49 70.29 91.59 o 5 5 -18 48.01 80.94 86.27 o 0 6 -18 22.03 36.21 95.86 o 2 6 -18 12.41 38.34 91.59 o 4 6 -18 8.54 -23.43 86.27 o 1 7 -18 33.89 104.38 99.05 o 3 7 -18 19.95 23.43 91.59 o 0 8 -18 1.29 6.39 104.38 o 2 8 -18 59.28 118.22 94.79 o 4 8 -18 23.00 57.51 83.07 o 1 9 -18 32.04 50.06 99.05 o 3 9 -18 39.97 -27.69 94.79 o 1 1 -17 60.85 87.33 96.92 o 3 1 -17 21.75 -39.41 87.33 o 5 1 -17 189.44 268.39 82.01 o 7 1 -17 27.34 22.37 87.33 o 0 2 -17 19.54 28.76 92.66 o 2 2 -17 17.16 15.98 92.66 o 4 2 -17 49.60 75.62 84.14 o 6 2 -17 14.78 -11.72 83.07 o 1 3 -17 181.11 251.35 99.05 o 3 3 -17 4.33 22.37 77.75 o 5 3 -17 24.34 108.64 77.75 o 0 4 -17 116.55 161.89 89.46 o 2 4 -17 102.21 23.43 87.33 o 4 4 -17 44.79 84.14 85.20 o 6 4 -17 0.39 -6.39 82.01 o 1 5 -17 3.48 19.17 88.40 o 3 5 -17 7.26 67.10 78.81 o 5 5 -17 29.54 56.45 74.55 o 0 6 -17 67.25 120.35 93.73 o 2 6 -17 28.80 68.16 85.20 o 4 6 -17 42.27 28.76 86.27 o 6 6 -17 98.34 156.56 87.33 o 1 7 -17 19.55 11.72 88.40 o 3 7 -17 20.55 30.89 88.40 o 5 7 -17 8.92 128.87 87.33 o 0 8 -17 20.17 -86.27 92.66 o 2 8 -17 95.20 88.40 91.59 o 4 8 -17 24.36 -11.72 89.46 o 1 9 -17 46.64 77.75 91.59 o 3 9 -17 50.40 -39.41 96.92 o 0 10 -17 36.05 2.13 93.73 o 2 10 -17 55.49 56.45 99.05 o 1 11 -17 25.55 110.77 95.86 o 0 0 -16 408.42 297.15 101.18 o 2 0 -16 88.79 58.58 84.14 o 4 0 -16 191.05 143.78 83.07 o 6 0 -16 110.64 160.82 79.88 o 1 1 -16 25.26 -26.63 91.59 o 3 1 -16 14.72 -4.26 80.94 o 5 1 -16 22.93 9.59 75.62 o 7 1 -16 21.41 1.07 78.81 o 0 2 -16 94.38 119.29 86.27 o 2 2 -16 179.92 149.11 91.59 o 4 2 -16 61.11 44.73 87.33 o 6 2 -16 98.16 69.23 73.49 o 1 3 -16 103.01 46.86 91.59 o 3 3 -16 28.44 -1.07 63.90 o 5 3 -16 62.65 118.22 76.68 o 7 3 -16 67.08 -38.34 78.81 o 0 4 -16 109.73 99.05 92.66 o 2 4 -16 93.21 63.90 84.14 o 4 4 -16 5.86 14.91 73.49 o 6 4 -16 35.42 142.72 70.29 o 1 5 -16 157.05 181.06 88.40 o 3 5 -16 42.48 64.97 69.23 o 5 5 -16 21.52 91.59 67.10 o 7 5 -16 44.94 7.46 82.01 o 0 6 -16 40.74 23.43 84.14 o 2 6 -16 13.32 -10.65 88.40 o 4 6 -16 16.91 -17.04 75.62 o 6 6 -16 11.80 -18.11 67.10 o 1 7 -16 76.78 80.94 88.40 o 3 7 -16 94.35 53.25 78.81 o 5 7 -16 107.94 99.05 73.49 o 0 8 -16 5.29 9.59 76.68 o 2 8 -16 48.25 38.34 94.79 o 4 8 -16 39.67 85.20 76.68 o 6 8 -16 37.63 38.34 75.62 o 1 9 -16 101.54 112.90 90.53 o 3 9 -16 16.55 22.37 82.01 o 5 9 -16 20.86 51.12 78.81 o 0 10 -16 71.38 55.38 95.86 o 2 10 -16 123.81 63.90 94.79 o 4 10 -16 4.50 -64.97 82.01 o 1 11 -16 76.76 2.13 103.31 o 3 11 -16 29.11 -4.26 86.27 o 0 12 -16 35.25 3.20 100.12 o 2 12 -16 37.91 62.84 101.18 o 1 1 -15 348.71 292.89 92.66 o 3 1 -15 171.91 154.43 85.20 o 5 1 -15 168.01 208.75 77.75 o 7 1 -15 26.42 -9.59 69.23 o 0 2 -15 172.31 142.72 85.20 o 2 2 -15 30.66 31.95 77.75 o 4 2 -15 81.83 10.65 72.42 o 6 2 -15 14.00 14.91 48.99 o 8 2 -15 10.86 -31.95 72.42 o 1 3 -15 22.97 -33.02 82.01 o 3 3 -15 33.47 35.15 76.68 o 5 3 -15 68.29 71.36 76.68 o 7 3 -15 145.37 172.54 76.68 o 0 4 -15 184.49 237.51 94.79 o 2 4 -15 0.64 -56.45 86.27 o 4 4 -15 78.55 55.38 74.55 o 6 4 -15 135.32 107.57 70.29 o 8 4 -15 36.89 8.52 74.55 o 1 5 -15 67.64 85.20 63.90 o 3 5 -15 12.87 -9.59 82.01 o 5 5 -15 14.30 80.94 68.16 o 7 5 -15 43.53 44.73 73.49 o 0 6 -15 213.66 154.43 92.66 o 2 6 -15 70.04 121.42 83.07 o 4 6 -15 85.35 28.76 75.62 o 6 6 -15 51.35 22.37 70.29 o 1 7 -15 15.74 33.02 85.20 o 3 7 -15 2.87 4.26 75.62 o 5 7 -15 17.93 10.65 70.29 o 7 7 -15 6.79 -17.04 66.03 o 0 8 -15 28.69 50.06 77.75 o 2 8 -15 204.02 297.15 92.66 o 4 8 -15 41.58 14.91 72.42 o 6 8 -15 17.36 53.25 74.55 o 1 9 -15 44.43 91.59 86.27 o 3 9 -15 66.78 47.93 80.94 o 5 9 -15 17.98 34.08 70.29 o 0 10 -15 83.61 57.51 87.33 o 2 10 -15 88.00 79.88 101.18 o 4 10 -15 13.88 -14.91 83.07 o 1 11 -15 9.93 -46.86 87.33 o 3 11 -15 6.73 24.50 75.62 o 5 11 -15 10.55 10.65 72.42 o 0 12 -15 19.52 21.30 90.53 o 2 12 -15 2.65 1.07 90.53 o 4 12 -15 15.01 -79.88 83.07 o 1 13 -15 62.77 53.25 89.46 o 0 0 -14 265.82 285.44 104.38 o 2 0 -14 134.29 67.10 88.40 o 4 0 -14 22.09 41.54 71.36 o 6 0 -14 86.18 47.93 68.16 o 8 0 -14 49.14 76.68 71.36 o 1 1 -14 256.26 279.04 96.92 o 3 1 -14 404.55 330.17 85.20 o 5 1 -14 53.31 41.54 69.23 o 7 1 -14 15.08 48.99 64.97 o 0 2 -14 587.89 593.24 105.44 o 2 2 -14 366.48 550.63 97.99 o 4 2 -14 31.52 26.63 72.42 o 6 2 -14 90.87 45.80 62.84 o 8 2 -14 12.41 39.41 73.49 o 1 3 -14 676.98 606.02 102.25 o 3 3 -14 528.08 632.64 92.66 o 5 3 -14 33.80 101.18 70.29 o 7 3 -14 64.34 -17.04 69.23 o 0 4 -14 66.80 143.78 88.40 o 2 4 -14 224.76 238.57 87.33 o 4 4 -14 57.32 23.43 66.03 o 6 4 -14 42.95 39.41 60.71 o 8 4 -14 58.85 104.38 66.03 o 1 5 -14 128.22 146.98 86.27 o 3 5 -14 137.41 186.39 78.81 o 5 5 -14 99.16 116.09 70.29 o 7 5 -14 81.02 85.20 70.29 o 0 6 -14 12.88 -7.46 85.20 o 2 6 -14 207.28 258.81 85.20 o 4 6 -14 66.55 85.20 66.03 o 6 6 -14 24.03 29.82 61.77 o 8 6 -14 11.20 10.65 71.36 o 1 7 -14 77.04 25.56 83.07 o 3 7 -14 188.09 262.00 80.94 o 5 7 -14 33.30 14.91 68.16 o 7 7 -14 6.18 50.06 63.90 o 0 8 -14 283.74 269.46 91.59 o 2 8 -14 163.05 128.87 78.81 o 4 8 -14 21.28 2.13 71.36 o 6 8 -14 21.37 -42.60 67.10 o 1 9 -14 88.52 157.63 80.94 o 3 9 -14 9.41 -19.17 70.29 o 5 9 -14 35.98 47.93 64.97 o 7 9 -14 55.95 31.95 75.62 o 0 10 -14 28.57 42.60 82.01 o 2 10 -14 191.17 183.19 87.33 o 4 10 -14 80.01 158.69 78.81 o 6 10 -14 11.43 29.82 73.49 o 1 11 -14 44.70 38.34 85.20 o 3 11 -14 10.91 14.91 77.75 o 5 11 -14 17.54 13.85 80.94 o 0 12 -14 315.44 453.71 102.25 o 2 12 -14 81.78 54.32 90.53 o 4 12 -14 24.65 102.25 80.94 o 1 13 -14 5.20 -20.24 80.94 o 3 13 -14 10.08 -66.03 77.75 o 0 14 -14 18.60 11.72 94.79 o 2 14 -14 34.31 -41.54 94.79 o 1 1 -13 243.71 151.24 104.38 o 3 1 -13 1134.48 952.16 111.83 o 5 1 -13 120.29 93.73 64.97 o 7 1 -13 30.95 12.78 61.77 o 9 1 -13 85.87 109.70 75.62 o 0 2 -13 249.92 304.61 108.64 o 2 2 -13 67.93 51.12 90.53 o 4 2 -13 86.76 36.21 72.42 o 6 2 -13 14.17 5.33 54.32 o 8 2 -13 13.36 -30.89 60.71 o 1 3 -13 54.34 83.07 92.66 o 3 3 -13 133.12 184.25 77.75 o 5 3 -13 82.30 41.54 64.97 o 7 3 -13 169.47 182.12 66.03 o 9 3 -13 3.05 35.15 66.03 o 0 4 -13 462.43 361.05 95.86 o 2 4 -13 330.49 288.63 91.59 o 4 4 -13 51.82 91.59 72.42 o 6 4 -13 81.63 97.99 56.45 o 8 4 -13 4.17 -21.30 71.36 o 1 5 -13 255.87 275.85 91.59 o 3 5 -13 408.98 423.89 82.01 o 5 5 -13 4.99 26.63 66.03 o 7 5 -13 10.14 38.34 61.77 o 0 6 -13 187.18 224.73 88.40 o 2 6 -13 38.43 -8.52 76.68 o 4 6 -13 89.38 59.64 62.84 o 6 6 -13 78.83 56.45 66.03 o 8 6 -13 128.30 142.72 83.07 o 1 7 -13 61.92 27.69 78.81 o 3 7 -13 18.84 13.85 66.03 o 5 7 -13 194.49 148.04 72.42 o 7 7 -13 17.92 6.39 57.51 o 0 8 -13 234.63 296.09 87.33 o 2 8 -13 793.42 950.03 104.38 o 4 8 -13 40.56 19.17 67.10 o 6 8 -13 44.05 80.94 61.77 o 1 9 -13 94.36 43.67 79.88 o 3 9 -13 165.32 57.51 67.10 o 5 9 -13 72.62 44.73 69.23 o 7 9 -13 19.81 59.64 76.68 o 0 10 -13 202.52 187.45 87.33 o 2 10 -13 162.23 306.74 89.46 o 4 10 -13 253.76 233.25 78.81 o 6 10 -13 24.47 35.15 64.97 o 1 11 -13 89.25 123.55 89.46 o 3 11 -13 7.57 48.99 71.36 o 5 11 -13 104.54 119.29 75.62 o 0 12 -13 17.47 42.60 86.27 o 2 12 -13 26.81 70.29 80.94 o 4 12 -13 18.00 55.38 75.62 o 1 13 -13 63.79 170.41 91.59 o 3 13 -13 50.52 56.45 77.75 o 5 13 -13 2.87 -44.73 72.42 o 0 14 -13 110.40 138.46 93.73 o 2 14 -13 46.79 46.86 87.33 o 4 14 -13 11.02 42.60 82.01 o 1 15 -13 33.65 18.11 89.46 o 0 0 -12 798.18 733.82 117.16 o 2 0 -12 527.77 633.71 104.38 o 4 0 -12 339.18 328.04 78.81 o 6 0 -12 54.78 91.59 62.84 o 8 0 -12 141.86 93.73 72.42 o 1 1 -12 294.13 440.93 106.51 o 3 1 -12 248.56 164.02 92.66 o 5 1 -12 167.92 151.24 71.36 o 7 1 -12 76.15 67.10 64.97 o 9 1 -12 6.89 15.98 66.03 o 0 2 -12 1215.58 1135.35 111.83 o 2 2 -12 578.77 600.69 104.38 o 4 2 -12 346.44 482.47 86.27 o 6 2 -12 119.82 207.69 64.97 o 8 2 -12 31.84 58.58 68.16 o 1 3 -12 4.22 -8.52 89.46 o 3 3 -12 774.14 862.70 99.05 o 5 3 -12 344.60 295.02 74.55 o 7 3 -12 36.42 20.24 66.03 o 9 3 -12 58.01 45.80 75.62 o 0 4 -12 680.06 689.09 111.83 o 2 4 -12 591.37 613.47 103.31 o 4 4 -12 58.47 39.41 68.16 o 6 4 -12 141.68 169.34 57.51 o 8 4 -12 15.59 24.50 64.97 o 1 5 -12 222.65 190.65 89.46 o 3 5 -12 746.69 668.86 94.79 o 5 5 -12 218.40 221.53 70.29 o 7 5 -12 36.78 30.89 60.71 o 9 5 -12 25.75 -6.39 70.29 o 0 6 -12 156.40 136.33 95.86 o 2 6 -12 95.65 118.22 85.20 o 4 6 -12 2.69 37.28 61.77 o 6 6 -12 222.91 292.89 67.10 o 8 6 -12 27.09 23.43 61.77 o 1 7 -12 317.85 510.16 92.66 o 3 7 -12 1179.97 1170.50 104.38 o 5 7 -12 61.65 116.09 60.71 o 7 7 -12 147.77 259.87 73.49 o 0 8 -12 184.41 160.82 82.01 o 2 8 -12 346.30 242.83 79.88 o 4 8 -12 96.47 126.74 68.16 o 6 8 -12 1.62 -37.28 63.90 o 8 8 -12 91.91 125.68 70.29 o 1 9 -12 498.02 619.86 90.53 o 3 9 -12 9.03 61.77 64.97 o 5 9 -12 64.96 68.16 69.23 o 7 9 -12 71.89 106.51 71.36 o 0 10 -12 186.73 188.52 80.94 o 2 10 -12 513.00 581.52 90.53 o 4 10 -12 161.94 165.08 70.29 o 6 10 -12 7.57 -23.43 61.77 o 1 11 -12 19.70 36.21 74.55 o 3 11 -12 100.48 38.34 75.62 o 5 11 -12 30.99 21.30 62.84 o 7 11 -12 7.47 13.85 70.29 o 0 12 -12 188.15 149.11 84.14 o 2 12 -12 165.98 215.14 85.20 o 4 12 -12 104.17 139.52 72.42 o 6 12 -12 9.68 -20.24 71.36 o 1 13 -12 37.64 34.08 78.81 o 3 13 -12 9.60 9.59 62.84 o 5 13 -12 20.36 83.07 75.62 o 0 14 -12 19.94 63.90 85.20 o 2 14 -12 106.50 89.46 87.33 o 4 14 -12 39.69 160.82 86.27 o 1 15 -12 37.16 57.51 89.46 o 3 15 -12 5.37 -30.89 83.07 o 1 1 -11 72.25 36.21 94.79 o 3 1 -11 864.99 701.87 96.92 o 5 1 -11 223.45 237.51 66.03 o 7 1 -11 30.18 112.90 59.64 o 9 1 -11 40.16 53.25 60.71 o 0 2 -11 420.91 364.25 95.86 o 2 2 -11 121.78 112.90 87.33 o 4 2 -11 116.18 124.61 71.36 o 6 2 -11 93.69 100.12 62.84 o 8 2 -11 42.00 87.33 62.84 o 1 3 -11 114.64 109.70 88.40 o 3 3 -11 149.36 97.99 79.88 o 5 3 -11 242.73 254.55 70.29 o 7 3 -11 210.54 88.40 50.06 o 9 3 -11 9.19 -38.34 67.10 o 0 4 -11 625.70 470.76 97.99 o 2 4 -11 811.32 932.99 101.18 o 4 4 -11 760.88 745.54 91.59 o 6 4 -11 400.81 291.83 73.49 o 8 4 -11 13.19 0.00 63.90 o 1 5 -11 476.75 582.59 101.18 o 3 5 -11 1208.57 1137.48 106.51 o 5 5 -11 541.27 592.17 76.68 o 7 5 -11 90.99 88.40 56.45 o 9 5 -11 8.68 -2.13 66.03 o 0 6 -11 512.22 434.54 97.99 o 2 6 -11 1437.85 1509.19 112.90 o 4 6 -11 391.49 488.86 79.88 o 6 6 -11 121.87 110.77 66.03 o 8 6 -11 79.04 89.46 60.71 o 1 7 -11 5.55 64.97 86.27 o 3 7 -11 193.84 275.85 76.68 o 5 7 -11 5.38 -1.07 59.64 o 7 7 -11 6.63 29.82 58.58 o 9 7 -11 18.83 38.34 70.29 o 0 8 -11 601.49 470.76 95.86 o 2 8 -11 389.55 447.32 88.40 o 4 8 -11 12.02 -18.11 69.23 o 6 8 -11 218.98 206.62 68.16 o 8 8 -11 33.59 36.21 71.36 o 1 9 -11 302.90 216.21 89.46 o 3 9 -11 26.71 -34.08 64.97 o 5 9 -11 15.23 54.32 61.77 o 7 9 -11 70.14 26.63 62.84 o 0 10 -11 102.46 95.86 78.81 o 2 10 -11 34.90 3.20 78.81 o 4 10 -11 15.00 7.46 70.29 o 6 10 -11 51.46 2.13 58.58 o 8 10 -11 22.72 -7.46 70.29 o 1 11 -11 390.91 383.42 80.94 o 3 11 -11 11.67 39.41 67.10 o 5 11 -11 96.22 82.01 68.16 o 7 11 -11 55.29 86.27 71.36 o 0 12 -11 22.38 -1.07 77.75 o 2 12 -11 0.67 5.33 74.55 o 4 12 -11 62.84 7.46 68.16 o 6 12 -11 33.55 37.28 70.29 o 1 13 -11 113.72 131.00 82.01 o 3 13 -11 52.64 70.29 63.90 o 5 13 -11 39.37 38.34 63.90 o 0 14 -11 136.10 26.63 78.81 o 2 14 -11 31.51 33.02 67.10 o 4 14 -11 24.44 93.73 70.29 o 1 15 -11 50.97 61.77 87.33 o 3 15 -11 50.89 61.77 75.62 o 0 16 -11 22.85 -27.69 86.27 o 2 16 -11 20.98 13.85 86.27 o 0 0 -10 485.27 363.18 90.53 o 2 0 -10 914.78 1102.33 101.18 o 4 0 -10 1919.90 2072.60 112.90 o 6 0 -10 267.49 157.63 60.71 o 8 0 -10 147.14 67.10 57.51 o 10 0 -10 75.39 52.19 77.75 o 1 1 -10 419.03 580.46 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