#------------------------------------------------------------------------------ #$Date: 2011-09-16 18:46:08 +0300 (Fri, 16 Sep 2011) $ #$Revision: 26025 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2012848.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2012848_Fobs loop_ _publ_author_name 'Cox, Philip J.' 'Wardell, James L.' _publ_section_title ; Coordinative N\\rightarrow B bond formation and hydrogen-bonded molecular ladders in 2,5-bis[(N\\rightarrow B)-(2-aminoethoxy)phenylboryl]thiophene ; _journal_issue 8 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first o515 _journal_page_last o517 _journal_volume 58 _journal_year 2002 _space_group_IT_number 60 _symmetry_space_group_name_Hall '-P 2n 2ab' _symmetry_space_group_name_H-M 'P b c n' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 11.4840 _cell_length_b 18.3850 _cell_length_c 9.5090 _exptl_crystal_F_000 800.00 _reflns_d_resolution_high 0.8426 _[local]_cod_data_source_file bm1498IVsup2.hkl _[local]_cod_data_source_block IV #BEGIN Tags that were not found in dictionaries: _shelx_title ' C20H24B2N2O2S Pbcn (Z=4) S in special position' _shelx_refln_list_code 4 _shelx_f_calc_maximum 175.22 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y+1/2, z+1/2' 'x+1/2, -y+1/2, -z' '-x, y, -z+1/2' '-x, -y, -z' 'x-1/2, y-1/2, -z-1/2' '-x-1/2, y-1/2, z' 'x, -y, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 4 0 0 7374.09 6857.83 1058.48 o 6 0 0 3836.64 4226.65 236.18 o 8 0 0 704.80 776.64 134.19 o 10 0 0 2476.34 2363.76 241.51 o 12 0 0 741.59 757.75 349.51 o 1 1 0 1604.72 1208.27 218.55 o 3 1 0 13393.43 15754.84 887.28 o 5 1 0 499.60 442.79 70.68 o 7 1 0 307.38 267.87 60.36 o 9 1 0 221.08 269.95 75.13 o 11 1 0 579.79 643.44 118.52 o 13 1 0 485.25 636.65 224.95 o 0 2 0 30700.73 20191.16 16580.49 o 2 2 0 4124.76 4360.03 136.12 o 4 2 0 5609.79 5365.05 618.90 o 6 2 0 1602.08 1480.17 117.64 o 8 2 0 200.92 175.85 61.25 o 10 2 0 2124.83 2290.75 168.37 o 12 2 0 11.71 58.73 142.08 o 1 3 0 10918.48 12019.55 2045.40 o 3 3 0 605.83 637.88 54.90 o 5 3 0 230.61 229.71 59.82 o 7 3 0 136.55 106.41 53.42 o 9 3 0 2474.61 2567.52 166.72 o 11 3 0 303.93 345.13 120.45 o 13 3 0 323.24 264.23 163.86 o 0 4 0 3795.46 3181.60 206.49 o 2 4 0 23.85 12.16 14.02 o 4 4 0 1593.47 1544.00 102.90 o 6 4 0 2086.04 2008.45 137.29 o 8 4 0 133.82 147.38 61.91 o 10 4 0 2413.30 2371.49 176.44 o 12 4 0 73.53 68.94 80.03 o 1 5 0 14.54 37.72 88.99 o 3 5 0 0.27 17.77 19.99 o 5 5 0 1437.45 1224.84 149.37 o 7 5 0 1480.73 1505.68 124.27 o 9 5 0 2744.25 2795.61 200.15 o 11 5 0 61.67 127.88 85.17 o 13 5 0 433.22 396.87 264.26 o 0 6 0 1244.94 1036.22 178.07 o 2 6 0 23.02 30.85 92.64 o 4 6 0 5765.37 5887.25 448.16 o 6 6 0 802.14 661.59 126.76 o 8 6 0 1.58 35.88 94.80 o 10 6 0 644.08 625.60 174.31 o 12 6 0 83.29 115.60 95.54 o 1 7 0 4106.73 3750.44 219.64 o 3 7 0 606.21 473.20 120.66 o 5 7 0 1892.76 1783.61 159.82 o 7 7 0 67.02 60.16 97.10 o 9 7 0 302.30 263.57 132.17 o 11 7 0 115.69 69.25 95.41 o 0 8 0 7632.37 6368.88 397.82 o 2 8 0 311.31 438.20 77.17 o 4 8 0 3030.16 2846.59 187.81 o 6 8 0 335.65 280.21 92.15 o 8 8 0 216.28 219.55 106.44 o 10 8 0 542.27 694.82 184.09 o 12 8 0 72.15 29.88 79.97 o 1 9 0 6.18 38.99 93.96 o 3 9 0 6450.65 5758.22 321.43 o 5 9 0 50.14 80.90 89.10 o 7 9 0 4201.19 4049.46 326.22 o 9 9 0 1277.96 1232.56 228.46 o 11 9 0 28.25 49.05 96.66 o 0 10 0 1586.07 1619.69 263.32 o 2 10 0 2.28 39.91 93.16 o 4 10 0 4960.63 4757.25 312.29 o 6 10 0 329.74 311.65 113.73 o 8 10 0 667.19 513.67 164.02 o 10 10 0 293.57 220.59 180.30 o 1 11 0 5.28 9.47 140.18 o 3 11 0 1245.06 1042.91 173.31 o 5 11 0 1030.47 1018.22 147.81 o 7 11 0 4859.83 4870.21 362.41 o 9 11 0 7.28 8.58 113.70 o 11 11 0 279.89 344.78 216.91 o 0 12 0 868.79 865.73 233.95 o 2 12 0 0.64 50.55 110.66 o 4 12 0 420.73 364.85 130.55 o 6 12 0 1195.50 1132.42 171.33 o 8 12 0 46.96 149.57 138.25 o 10 12 0 165.82 133.82 136.31 o 1 13 0 23.82 53.04 159.13 o 3 13 0 1012.28 1043.87 185.16 o 5 13 0 1.43 69.14 172.39 o 7 13 0 384.09 416.13 132.74 o 9 13 0 2.33 52.21 125.83 o 0 14 0 47.42 92.82 176.18 o 2 14 0 12.81 36.25 118.47 o 4 14 0 0.26 42.62 148.71 o 6 14 0 250.25 110.50 99.13 o 8 14 0 157.98 98.08 132.67 o 10 14 0 59.54 37.89 159.13 o 1 15 0 15.91 2.84 114.12 o 3 15 0 551.01 490.45 151.20 o 7 15 0 201.37 188.64 112.42 o 9 15 0 0.05 46.41 170.49 o 2 16 0 1482.99 1668.73 246.89 o 4 16 0 694.71 501.54 186.48 o 6 16 0 160.25 170.49 108.52 o 3 17 0 617.31 765.18 199.47 o 5 17 0 88.28 63.28 124.81 o 0 18 0 18.21 59.67 183.75 o 2 18 0 211.13 209.54 151.45 o 4 18 0 131.86 142.93 144.28 o 6 18 0 26.66 26.52 180.91 o 1 19 0 54.38 87.14 192.28 o 3 19 0 161.07 255.18 183.86 o 5 19 0 901.84 1148.94 401.61 o 0 20 0 228.55 237.74 210.28 o 2 20 0 108.14 18.94 189.44 o 1 1 1 691.67 678.38 20.89 o 2 1 1 5384.63 5532.37 192.25 o 3 1 1 200.18 226.25 33.04 o 4 1 1 475.06 453.35 52.96 o 5 1 1 18.91 31.02 47.30 o 6 1 1 17.28 57.68 41.75 o 7 1 1 123.16 127.96 39.90 o 8 1 1 306.40 297.10 48.74 o 9 1 1 8.70 60.12 52.65 o 10 1 1 27.14 33.04 57.45 o 11 1 1 40.54 63.00 64.05 o 12 1 1 4.23 63.46 163.86 o 13 1 1 2.88 2.84 146.81 o 0 2 1 2523.47 2799.71 93.31 o 1 2 1 4548.74 5217.44 244.42 o 2 2 1 4176.15 4111.38 264.31 o 3 2 1 429.57 443.96 32.21 o 4 2 1 548.04 569.36 44.48 o 5 2 1 1318.02 1344.82 67.11 o 6 2 1 942.71 988.91 66.25 o 7 2 1 512.42 521.18 60.44 o 8 2 1 407.14 394.21 55.24 o 9 2 1 0.94 22.71 58.54 o 10 2 1 0.70 13.19 51.64 o 11 2 1 4.59 29.24 63.94 o 12 2 1 42.06 48.11 88.13 o 13 2 1 0.65 1.89 115.56 o 1 3 1 2314.46 2492.81 132.51 o 2 3 1 5528.38 5206.67 219.85 o 3 3 1 30.11 52.44 47.44 o 4 3 1 249.07 245.14 32.17 o 5 3 1 604.73 601.56 52.28 o 6 3 1 16.21 32.35 34.86 o 7 3 1 225.38 186.20 38.36 o 8 3 1 24.69 36.98 41.35 o 9 3 1 183.71 180.51 45.77 o 10 3 1 0.98 75.87 91.01 o 11 3 1 81.30 62.15 69.89 o 12 3 1 25.41 137.32 104.74 o 13 3 1 0.78 14.53 62.17 o 0 4 1 24.54 79.56 107.03 o 1 4 1 10569.99 11619.34 969.55 o 2 4 1 1706.30 1638.32 50.38 o 3 4 1 69.35 63.33 23.48 o 4 4 1 144.81 111.62 42.33 o 5 4 1 172.57 184.54 33.15 o 6 4 1 1068.18 1066.23 69.65 o 7 4 1 3.74 27.08 36.14 o 8 4 1 99.30 83.89 38.67 o 9 4 1 2.76 42.26 62.38 o 10 4 1 39.74 50.06 62.02 o 11 4 1 1.76 51.42 90.64 o 12 4 1 0.49 6.00 61.37 o 13 4 1 174.52 155.21 87.24 o 1 5 1 1331.11 1276.59 75.79 o 2 5 1 22.66 21.00 20.99 o 3 5 1 6282.56 6646.51 284.29 o 4 5 1 454.56 508.03 40.05 o 5 5 1 688.82 709.04 75.36 o 6 5 1 442.44 385.59 71.14 o 7 5 1 238.74 228.42 42.30 o 8 5 1 35.73 39.21 32.05 o 9 5 1 506.41 520.34 80.94 o 10 5 1 2.79 25.86 57.93 o 11 5 1 134.96 116.42 73.55 o 13 5 1 5.30 50.20 134.50 o 0 6 1 3167.21 2663.95 174.79 o 1 6 1 850.80 722.34 54.16 o 2 6 1 468.63 425.97 49.65 o 3 6 1 333.87 265.16 43.14 o 4 6 1 55.35 67.34 30.98 o 5 6 1 117.48 119.34 30.78 o 6 6 1 525.74 458.19 94.19 o 7 6 1 1.69 67.56 117.37 o 8 6 1 96.44 71.61 49.89 o 9 6 1 123.92 103.22 62.79 o 10 6 1 4.91 35.56 96.12 o 11 6 1 72.81 77.24 78.00 o 12 6 1 97.46 75.48 69.19 o 1 7 1 175.52 138.53 54.59 o 2 7 1 303.85 366.96 32.60 o 3 7 1 3324.54 3457.93 152.03 o 4 7 1 38.12 44.65 77.83 o 5 7 1 167.43 167.29 34.53 o 6 7 1 949.59 932.97 107.21 o 7 7 1 378.54 383.09 90.22 o 8 7 1 83.04 59.13 70.03 o 9 7 1 289.18 288.04 80.51 o 10 7 1 181.32 184.83 70.97 o 11 7 1 37.89 62.24 78.71 o 12 7 1 14.00 5.68 74.17 o 0 8 1 30.48 73.43 99.08 o 1 8 1 337.91 300.86 63.64 o 2 8 1 1259.43 1339.90 71.97 o 3 8 1 17.27 46.64 31.19 o 4 8 1 720.31 713.31 83.32 o 5 8 1 0.43 45.37 58.32 o 6 8 1 493.38 451.39 75.34 o 7 8 1 54.92 73.04 76.52 o 8 8 1 8.47 57.64 77.34 o 9 8 1 111.63 115.60 66.42 o 10 8 1 0.12 39.82 75.23 o 11 8 1 63.09 74.43 92.24 o 12 8 1 61.63 56.13 66.67 o 1 9 1 110.73 68.94 68.61 o 2 9 1 180.69 198.02 31.07 o 3 9 1 113.03 64.32 33.73 o 4 9 1 326.53 248.39 72.68 o 5 9 1 144.73 96.54 59.14 o 6 9 1 390.67 400.94 80.51 o 7 9 1 892.83 937.53 128.75 o 8 9 1 0.50 60.32 97.93 o 9 9 1 247.58 291.75 79.62 o 10 9 1 85.60 63.12 94.81 o 11 9 1 157.07 128.07 80.49 o 12 9 1 127.73 77.99 119.99 o 0 10 1 5.93 16.10 135.45 o 1 10 1 589.85 526.74 85.18 o 2 10 1 52.02 37.65 21.86 o 3 10 1 91.76 84.83 42.95 o 4 10 1 667.25 616.72 94.93 o 5 10 1 48.34 63.91 60.56 o 6 10 1 310.19 304.35 77.68 o 7 10 1 284.00 285.91 84.34 o 8 10 1 193.22 199.45 84.96 o 9 10 1 80.11 67.20 90.88 o 10 10 1 344.10 321.57 95.17 o 11 10 1 32.66 48.31 171.44 o 1 11 1 517.77 458.81 91.06 o 2 11 1 578.58 617.75 69.84 o 3 11 1 238.14 212.04 43.76 o 4 11 1 235.80 239.11 73.98 o 5 11 1 51.68 40.72 65.55 o 6 11 1 437.56 433.97 76.18 o 7 11 1 1306.13 1229.73 132.40 o 8 11 1 451.28 336.82 96.11 o 9 11 1 141.75 156.95 95.35 o 10 11 1 64.68 117.30 106.10 o 11 11 1 417.92 501.86 160.49 o 0 12 1 30.21 28.42 151.55 o 1 12 1 548.32 503.61 90.17 o 2 12 1 557.16 577.60 76.52 o 3 12 1 179.37 167.15 44.60 o 4 12 1 148.95 167.47 85.36 o 5 12 1 3.06 20.83 81.71 o 6 12 1 215.36 265.80 72.95 o 7 12 1 254.92 267.39 92.19 o 8 12 1 191.42 122.05 89.95 o 9 12 1 2.59 44.26 95.20 o 10 12 1 620.60 758.08 161.76 o 1 13 1 720.44 636.50 101.41 o 2 13 1 3.76 35.56 50.62 o 3 13 1 387.83 408.36 56.02 o 4 13 1 1.41 16.72 84.72 o 5 13 1 49.01 46.65 69.15 o 6 13 1 10.25 28.68 63.79 o 7 13 1 332.31 344.78 88.94 o 8 13 1 14.86 45.46 175.23 o 9 13 1 57.97 81.12 91.68 o 10 13 1 1.41 68.68 98.71 o 0 14 1 2061.96 2033.54 243.10 o 1 14 1 235.38 167.22 92.33 o 2 14 1 778.13 791.44 90.95 o 3 14 1 9.74 57.14 83.16 o 4 14 1 211.01 205.98 81.15 o 5 14 1 286.82 297.14 78.50 o 6 14 1 0.12 46.83 131.07 o 7 14 1 3.94 63.03 109.70 o 8 14 1 35.97 51.37 111.29 o 9 14 1 120.13 151.88 108.06 o 10 14 1 286.38 133.55 171.44 o 1 15 1 1038.68 910.47 129.13 o 2 15 1 6.72 70.22 98.62 o 3 15 1 502.31 591.42 105.81 o 4 15 1 33.27 64.96 93.14 o 5 15 1 4.40 36.00 82.17 o 6 15 1 61.93 82.50 81.37 o 7 15 1 330.14 442.41 96.56 o 8 15 1 12.82 63.27 86.96 o 9 15 1 26.94 48.31 150.60 o 0 16 1 1320.22 1382.56 232.40 o 1 16 1 6.76 32.12 104.04 o 2 16 1 74.46 158.59 147.80 o 3 16 1 2.25 47.06 109.68 o 4 16 1 715.61 790.39 142.63 o 5 16 1 2.32 24.47 99.38 o 6 16 1 11.44 88.21 82.42 o 7 16 1 0.38 8.52 166.70 o 8 16 1 22.94 24.46 108.16 o 9 16 1 44.05 75.77 150.60 o 1 17 1 599.76 497.12 116.40 o 2 17 1 64.36 46.58 101.41 o 3 17 1 184.54 203.90 101.99 o 4 17 1 65.37 87.93 94.25 o 5 17 1 0.22 54.48 109.44 o 6 17 1 26.49 65.48 103.57 o 7 17 1 162.64 220.77 120.34 o 8 17 1 0.73 4.74 139.24 o 0 18 1 224.89 224.80 130.86 o 1 18 1 39.54 66.20 128.51 o 2 18 1 76.42 103.92 96.52 o 3 18 1 194.10 209.57 93.09 o 4 18 1 95.94 89.86 93.53 o 5 18 1 41.10 65.66 84.13 o 6 18 1 161.01 350.46 267.11 o 7 18 1 0.36 28.42 158.18 o 1 19 1 12.90 84.14 108.11 o 2 19 1 0.89 26.52 185.65 o 3 19 1 129.29 228.57 114.57 o 4 19 1 59.40 24.23 120.86 o 5 19 1 145.48 128.82 192.28 o 0 20 1 263.58 425.05 208.23 o 1 20 1 0.18 50.03 122.22 o 3 20 1 101.77 104.19 187.54 o 0 0 2 2954.51 2837.62 74.78 o 1 0 2 7679.15 8537.37 243.58 o 2 0 2 24431.50 26622.44 1126.50 o 3 0 2 6370.50 6559.54 309.27 o 4 0 2 16.23 34.35 56.82 o 5 0 2 55.98 94.48 65.01 o 6 0 2 3080.33 2964.70 172.18 o 7 0 2 112.55 73.00 64.04 o 8 0 2 37.49 55.88 135.45 o 9 0 2 86.27 87.70 69.08 o 10 0 2 289.33 360.94 82.75 o 11 0 2 127.46 145.36 105.39 o 12 0 2 519.66 663.12 164.39 o 1 1 2 6773.17 7181.39 312.94 o 2 1 2 2693.18 2719.23 60.40 o 3 1 2 9784.82 9763.38 387.41 o 4 1 2 1256.02 1163.71 70.39 o 5 1 2 344.32 348.24 51.25 o 6 1 2 14.89 42.74 54.29 o 7 1 2 1381.36 1275.02 92.16 o 8 1 2 1.15 27.27 54.54 o 9 1 2 55.82 70.33 47.99 o 10 1 2 171.44 206.42 53.86 o 11 1 2 464.49 510.40 90.41 o 12 1 2 27.02 37.85 69.82 o 0 2 2 15006.18 16002.47 436.16 o 1 2 2 15806.75 16599.57 852.97 o 2 2 2 6734.13 7335.12 209.72 o 3 2 2 672.59 642.98 42.17 o 4 2 2 2.53 16.78 52.09 o 5 2 2 12.57 44.73 51.13 o 6 2 2 403.20 340.13 64.92 o 7 2 2 400.82 424.69 56.05 o 8 2 2 438.72 440.85 58.30 o 9 2 2 4.91 46.06 67.53 o 10 2 2 820.18 801.29 103.23 o 11 2 2 259.20 288.11 88.29 o 12 2 2 260.80 281.52 93.67 o 13 2 2 63.15 53.04 122.19 o 1 3 2 236.28 225.24 22.27 o 2 3 2 332.56 340.38 27.31 o 3 3 2 8611.71 9570.05 252.29 o 4 3 2 605.88 522.03 54.03 o 5 3 2 253.22 275.49 36.76 o 6 3 2 107.32 102.15 30.46 o 7 3 2 5297.97 5504.18 181.32 o 8 3 2 236.07 224.22 44.03 o 9 3 2 113.62 130.65 46.16 o 10 3 2 22.97 72.81 70.91 o 11 3 2 963.93 1120.47 113.82 o 12 3 2 4.49 24.63 148.71 o 13 3 2 347.37 449.91 231.11 o 0 4 2 4703.54 5297.06 226.54 o 1 4 2 918.51 847.55 41.77 o 2 4 2 2433.58 2680.62 85.38 o 3 4 2 984.11 950.43 55.90 o 4 4 2 5850.02 5824.02 125.14 o 5 4 2 0.39 37.86 50.99 o 6 4 2 1005.08 953.86 80.08 o 7 4 2 163.92 182.27 35.68 o 8 4 2 851.13 816.16 66.59 o 9 4 2 45.40 75.20 68.68 o 10 4 2 1000.85 961.86 111.91 o 11 4 2 70.29 61.11 57.34 o 12 4 2 188.27 187.29 80.18 o 13 4 2 21.12 20.84 134.50 o 1 5 2 546.64 469.76 40.43 o 2 5 2 494.37 525.84 38.52 o 3 5 2 7425.25 7971.69 420.84 o 4 5 2 1469.37 1410.66 85.90 o 5 5 2 1814.30 1866.53 86.92 o 6 5 2 57.78 28.89 44.48 o 7 5 2 5020.93 5039.70 181.48 o 8 5 2 426.93 433.65 80.15 o 9 5 2 5.07 28.91 56.85 o 10 5 2 589.87 586.28 95.38 o 11 5 2 1073.99 1164.01 129.48 o 12 5 2 9.89 33.78 63.96 o 13 5 2 192.92 163.86 169.55 o 0 6 2 4784.39 4280.39 301.68 o 1 6 2 217.33 205.12 45.16 o 2 6 2 48.32 78.33 32.87 o 3 6 2 266.59 266.99 29.10 o 4 6 2 1357.99 1311.44 73.51 o 5 6 2 34.99 51.40 58.62 o 6 6 2 1133.17 1116.24 105.49 o 7 6 2 38.26 56.24 50.26 o 8 6 2 308.69 326.19 74.08 o 9 6 2 49.60 59.47 48.47 o 10 6 2 1125.39 1199.28 120.44 o 11 6 2 21.33 45.80 81.28 o 12 6 2 2.46 51.22 94.62 o 1 7 2 79.78 56.02 50.35 o 2 7 2 391.53 410.80 54.89 o 3 7 2 4969.36 5452.97 258.48 o 4 7 2 387.50 426.03 49.51 o 5 7 2 97.81 125.95 43.25 o 6 7 2 23.39 35.59 57.92 o 7 7 2 3735.83 3818.80 191.65 o 8 7 2 685.71 709.19 92.08 o 9 7 2 73.60 67.28 61.59 o 10 7 2 134.67 183.61 94.03 o 11 7 2 185.28 209.15 82.68 o 12 7 2 125.08 96.06 80.39 o 0 8 2 1329.46 1127.49 146.86 o 1 8 2 12.30 23.60 55.03 o 2 8 2 1347.43 1309.46 90.31 o 3 8 2 593.92 578.11 64.10 o 4 8 2 2205.47 2130.23 109.35 o 5 8 2 83.15 90.14 32.65 o 6 8 2 686.40 660.25 69.11 o 7 8 2 71.19 80.58 87.67 o 8 8 2 208.86 160.20 65.51 o 9 8 2 55.19 81.77 96.33 o 10 8 2 71.52 84.73 73.49 o 11 8 2 148.59 98.83 71.81 o 12 8 2 13.71 9.01 108.50 o 1 9 2 1335.33 1338.20 93.86 o 2 9 2 4.00 39.13 47.74 o 3 9 2 529.91 525.20 65.77 o 4 9 2 0.19 26.36 59.40 o 5 9 2 436.42 391.01 96.71 o 6 9 2 78.48 43.06 21.45 o 7 9 2 239.48 235.62 81.88 o 8 9 2 551.03 469.52 84.30 o 9 9 2 235.10 213.24 81.57 o 10 9 2 7.84 50.76 114.24 o 11 9 2 69.26 111.37 121.49 o 12 9 2 87.10 123.13 161.97 o 0 10 2 608.42 456.48 109.35 o 1 10 2 8.96 18.18 67.86 o 2 10 2 84.23 87.47 40.83 o 3 10 2 433.56 493.90 67.23 o 4 10 2 533.59 493.49 64.42 o 5 10 2 434.18 495.32 87.04 o 6 10 2 639.47 663.31 98.44 o 7 10 2 172.46 109.92 82.57 o 8 10 2 157.00 192.38 85.92 o 9 10 2 26.33 45.59 75.75 o 10 10 2 94.46 149.52 108.80 o 11 10 2 17.53 63.50 120.86 o 1 11 2 19.81 2.84 135.45 o 2 11 2 90.13 80.78 59.86 o 3 11 2 347.37 358.17 59.29 o 4 11 2 36.57 52.32 36.14 o 5 11 2 1080.99 1064.13 116.38 o 6 11 2 743.99 727.44 103.53 o 7 11 2 43.36 68.16 68.44 o 8 11 2 379.61 341.53 89.92 o 9 11 2 138.88 144.21 100.66 o 10 11 2 0.30 19.31 109.73 o 11 11 2 36.20 73.88 173.34 o 0 12 2 638.95 735.44 153.84 o 1 12 2 8.32 42.58 76.18 o 2 12 2 95.73 103.52 62.00 o 3 12 2 982.00 998.04 95.61 o 4 12 2 531.06 521.57 69.73 o 5 12 2 0.07 64.32 77.01 o 6 12 2 253.47 266.65 73.11 o 7 12 2 161.16 173.80 72.88 o 8 12 2 23.54 29.12 102.91 o 9 12 2 22.61 43.48 82.95 o 10 12 2 328.01 350.72 131.38 o 1 13 2 7.69 93.77 161.02 o 2 13 2 10.97 22.61 75.82 o 3 13 2 72.02 45.16 49.39 o 4 13 2 181.77 146.58 74.83 o 5 13 2 6.42 67.21 100.80 o 6 13 2 222.02 220.20 73.54 o 7 13 2 661.27 669.81 108.80 o 8 13 2 59.36 58.25 142.43 o 9 13 2 208.29 251.85 95.21 o 10 13 2 46.59 61.57 133.55 o 0 14 2 756.44 916.78 167.97 o 1 14 2 347.66 339.64 106.14 o 2 14 2 218.85 192.01 66.52 o 3 14 2 399.19 442.24 76.84 o 4 14 2 305.43 335.72 89.34 o 5 14 2 653.92 590.90 103.50 o 6 14 2 157.71 140.33 68.51 o 7 14 2 19.46 32.41 89.34 o 8 14 2 2.98 44.49 108.30 o 9 14 2 3.38 7.44 98.29 o 1 15 2 38.09 77.20 93.34 o 2 15 2 346.64 346.86 80.48 o 3 15 2 349.21 368.88 102.64 o 4 15 2 3.12 50.30 94.03 o 5 15 2 3.22 61.09 126.77 o 6 15 2 133.72 122.42 78.76 o 7 15 2 59.80 86.03 73.25 o 8 15 2 0.49 25.14 96.69 o 9 15 2 15.96 46.41 132.61 o 0 16 2 1786.17 1812.74 251.61 o 1 16 2 78.44 71.08 71.19 o 2 16 2 373.43 396.67 101.81 o 3 16 2 295.52 210.34 97.80 o 4 16 2 521.00 494.22 110.46 o 5 16 2 18.13 27.32 85.13 o 6 16 2 9.06 15.15 96.94 o 7 16 2 1.32 53.06 125.83 o 8 16 2 11.21 29.36 133.55 o 1 17 2 200.20 209.66 98.52 o 2 17 2 1.05 60.63 105.89 o 3 17 2 47.66 36.07 104.49 o 4 17 2 222.35 207.65 90.94 o 5 17 2 25.56 31.52 85.93 o 6 17 2 6.16 38.78 88.97 o 0 18 2 989.55 1078.25 235.51 o 1 18 2 20.78 85.24 135.79 o 2 18 2 20.83 97.56 179.02 o 3 18 2 3.65 79.08 138.83 o 4 18 2 33.54 20.83 95.04 o 5 18 2 1.63 152.50 224.48 o 1 19 2 0.02 13.26 154.39 o 3 19 2 1.55 2.84 118.04 o 4 19 2 80.57 81.46 180.91 o 5 19 2 25.58 140.18 190.38 o 6 19 2 19.20 25.57 156.29 o 0 20 2 1.89 17.05 154.39 o 1 20 2 5.34 32.12 112.81 o 2 20 2 0.09 0.95 142.08 o 4 20 2 81.08 82.41 177.12 o 1 1 3 1046.94 1015.96 27.58 o 2 1 3 1796.29 1798.05 56.92 o 3 1 3 288.08 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22.56 19.99 55.98 o 3 10 3 2.81 27.80 48.09 o 4 10 3 329.72 321.32 44.24 o 5 10 3 31.74 25.02 20.70 o 6 10 3 278.17 287.67 67.93 o 7 10 3 42.95 56.08 60.00 o 8 10 3 409.73 407.45 90.22 o 9 10 3 10.00 67.85 99.10 o 10 10 3 542.20 587.71 140.39 o 11 10 3 3.96 86.19 159.13 o 1 11 3 0.75 12.31 169.55 o 2 11 3 4.05 34.96 81.71 o 3 11 3 208.37 181.33 44.56 o 4 11 3 125.84 121.20 41.19 o 5 11 3 829.77 782.50 94.63 o 6 11 3 1297.10 1433.93 121.47 o 7 11 3 102.37 119.55 62.61 o 8 11 3 145.76 114.76 82.05 o 9 11 3 522.48 697.12 121.60 o 10 11 3 39.56 34.10 205.54 o 0 12 3 3516.85 3449.05 276.18 o 1 12 3 325.80 278.27 66.26 o 2 12 3 55.04 74.51 66.68 o 3 12 3 112.28 54.52 55.90 o 4 12 3 797.98 846.03 73.65 o 5 12 3 0.01 42.10 76.20 o 6 12 3 10.69 58.43 79.58 o 7 12 3 2.57 36.58 81.19 o 8 12 3 243.05 253.72 87.62 o 9 12 3 76.69 69.83 91.08 o 10 12 3 221.28 155.34 227.32 o 1 13 3 714.86 821.44 97.33 o 2 13 3 34.57 18.94 118.40 o 3 13 3 324.97 364.41 70.38 o 4 13 3 225.07 312.06 69.81 o 5 13 3 17.76 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260.54 o 1 2 4 401.24 372.76 27.04 o 2 2 4 127.51 149.71 27.65 o 3 2 4 279.54 306.10 39.99 o 4 2 4 5120.20 5076.56 85.70 o 5 2 4 11.54 16.78 29.84 o 6 2 4 916.10 844.44 75.73 o 7 2 4 53.66 84.21 48.44 o 8 2 4 7.90 62.12 56.42 o 9 2 4 229.54 198.83 58.82 o 10 2 4 1101.30 1166.85 139.90 o 11 2 4 0.31 62.47 137.36 o 12 2 4 5.26 8.52 155.34 o 1 3 4 440.51 365.66 29.84 o 2 3 4 910.08 916.06 31.63 o 3 3 4 1535.11 1513.89 46.04 o 4 3 4 134.36 126.44 21.74 o 5 3 4 441.57 343.51 47.05 o 6 3 4 1231.54 1284.96 88.72 o 7 3 4 1448.93 1304.14 101.05 o 8 3 4 74.78 82.59 49.96 o 9 3 4 115.29 58.21 52.42 o 10 3 4 104.42 118.54 84.85 o 11 3 4 362.66 423.79 124.90 o 12 3 4 199.58 200.83 119.99 o 0 4 4 2514.64 2557.42 106.97 o 1 4 4 2915.82 3032.33 79.69 o 2 4 4 405.55 371.18 29.29 o 3 4 4 643.80 586.33 39.86 o 4 4 4 46.71 26.25 33.33 o 5 4 4 279.60 301.33 43.96 o 6 4 4 1134.87 1185.74 92.32 o 7 4 4 114.95 114.27 47.50 o 8 4 4 536.87 473.01 76.74 o 9 4 4 225.11 203.57 63.37 o 10 4 4 1335.21 1412.03 145.31 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284.60 349.96 161.75 o 0 8 4 4421.98 4443.65 178.44 o 1 8 4 172.07 178.40 37.08 o 2 8 4 24.91 50.98 36.30 o 3 8 4 33.70 45.47 36.93 o 4 8 4 937.45 955.80 59.81 o 5 8 4 425.62 425.15 59.51 o 6 8 4 307.58 352.18 56.47 o 7 8 4 367.18 366.02 61.22 o 8 8 4 50.97 59.20 64.30 o 9 8 4 6.93 41.80 91.93 o 10 8 4 136.78 151.33 93.30 o 1 9 4 289.80 294.51 44.80 o 2 9 4 220.76 202.46 37.25 o 3 9 4 1756.92 1833.98 86.64 o 4 9 4 13.05 44.22 24.31 o 5 9 4 72.65 111.23 44.40 o 6 9 4 41.14 55.73 46.43 o 7 9 4 131.91 144.43 62.68 o 8 9 4 226.69 214.72 74.06 o 9 9 4 34.92 79.20 147.67 o 10 9 4 24.36 50.20 137.34 o 0 10 4 2440.04 2416.03 167.07 o 1 10 4 821.14 792.76 68.99 o 2 10 4 39.52 70.37 42.17 o 3 10 4 52.08 78.66 35.71 o 4 10 4 128.68 158.30 36.10 o 5 10 4 97.23 105.39 48.52 o 6 10 4 176.87 195.33 62.54 o 7 10 4 502.18 390.44 78.40 o 8 10 4 155.20 185.45 101.84 o 9 10 4 11.99 63.11 137.02 o 10 10 4 163.82 341.93 187.54 o 1 11 4 0.46 44.30 59.29 o 2 11 4 30.97 42.26 45.03 o 3 11 4 1152.05 1158.82 80.29 o 4 11 4 29.36 39.91 54.81 o 5 11 4 7.45 21.16 56.61 o 6 11 4 5.10 42.84 79.76 o 7 11 4 305.66 360.62 79.24 o 8 11 4 13.69 42.15 93.80 o 9 11 4 1.91 9.47 197.01 o 0 12 4 2039.32 1962.31 152.57 o 1 12 4 5.48 22.38 92.59 o 2 12 4 85.96 58.07 46.42 o 3 12 4 26.93 51.34 83.58 o 4 12 4 169.90 171.87 61.62 o 5 12 4 56.42 60.27 51.34 o 6 12 4 19.87 75.21 93.80 o 7 12 4 0.94 10.49 62.46 o 8 12 4 254.22 385.72 99.80 o 1 13 4 0.04 80.85 89.08 o 2 13 4 565.16 593.45 69.56 o 3 13 4 189.84 212.39 55.47 o 4 13 4 103.78 101.44 53.74 o 5 13 4 25.48 60.34 89.13 o 6 13 4 48.95 82.43 70.08 o 7 13 4 305.23 335.56 93.55 o 8 13 4 23.96 39.32 88.52 o 9 13 4 51.89 76.72 183.75 o 0 14 4 34.63 52.67 103.28 o 1 14 4 647.47 636.77 80.78 o 2 14 4 75.97 146.73 51.40 o 3 14 4 836.05 796.12 89.76 o 4 14 4 167.80 159.09 69.19 o 5 14 4 160.04 187.54 74.17 o 6 14 4 66.14 96.94 77.71 o 7 14 4 12.36 42.51 73.94 o 8 14 4 3.00 26.52 98.51 o 1 15 4 272.24 268.91 66.73 o 2 15 4 5.28 62.09 100.99 o 3 15 4 0.43 67.64 79.73 o 4 15 4 456.98 482.90 103.47 o 6 15 4 283.15 187.79 81.98 o 7 15 4 56.68 77.67 141.13 o 8 15 4 43.80 15.15 99.45 o 0 16 4 2.24 32.22 87.73 o 1 16 4 135.83 109.93 58.65 o 2 16 4 34.97 61.20 80.36 o 3 16 4 14.68 44.72 74.86 o 4 16 4 178.36 173.99 80.35 o 5 16 4 4.05 63.66 91.58 o 6 16 4 8.19 46.86 94.05 o 1 17 4 27.87 74.25 70.97 o 2 17 4 20.98 43.05 87.21 o 3 17 4 57.23 72.46 65.30 o 4 17 4 245.27 165.34 71.39 o 5 17 4 10.09 62.53 76.97 o 6 17 4 2.28 12.31 125.03 o 1 18 4 97.30 41.23 99.08 o 2 18 4 5.81 55.88 209.33 o 3 18 4 309.72 311.32 97.76 o 4 18 4 25.24 54.10 76.22 o 2 19 4 11.75 7.58 143.03 o 3 19 4 6.53 18.84 111.42 o 1 20 4 14.58 27.47 119.35 o 1 1 5 15.10 19.71 11.93 o 2 1 5 875.05 862.40 44.23 o 3 1 5 0.03 19.09 11.40 o 4 1 5 144.13 110.22 29.40 o 5 1 5 194.59 166.55 25.28 o 6 1 5 40.65 28.95 21.99 o 7 1 5 126.69 159.17 43.68 o 8 1 5 24.67 72.82 82.56 o 9 1 5 8.08 42.79 121.28 o 10 1 5 8.72 0.95 151.55 o 11 1 5 23.91 52.19 125.11 o 12 1 5 0.79 97.56 172.39 o 0 2 5 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37.59 o 2 5 5 196.77 191.22 28.97 o 3 5 5 190.60 199.48 26.52 o 4 5 5 41.10 28.09 19.24 o 5 5 5 93.04 97.36 30.67 o 6 5 5 115.16 123.17 40.72 o 7 5 5 483.03 505.35 77.08 o 8 5 5 6.96 20.55 62.74 o 9 5 5 0.02 64.85 106.50 o 10 5 5 156.21 126.77 99.44 o 11 5 5 77.12 96.76 104.42 o 0 6 5 11.70 31.14 45.49 o 1 6 5 832.48 853.90 54.43 o 2 6 5 398.29 367.63 38.48 o 3 6 5 1671.02 1651.10 76.31 o 4 6 5 108.73 129.02 37.84 o 5 6 5 968.67 966.49 68.74 o 6 6 5 71.27 116.79 55.07 o 7 6 5 421.43 451.19 86.83 o 8 6 5 3.63 89.04 222.59 o 9 6 5 5.74 54.35 85.71 o 10 6 5 376.87 317.55 101.54 o 1 7 5 1725.28 1718.15 70.88 o 2 7 5 113.13 144.18 35.86 o 3 7 5 110.49 123.22 34.16 o 4 7 5 198.41 180.09 45.00 o 5 7 5 121.82 111.32 44.92 o 6 7 5 535.55 503.12 65.46 o 7 7 5 134.66 159.56 66.83 o 8 7 5 33.36 85.59 65.37 o 9 7 5 62.23 96.75 143.32 o 10 7 5 168.94 122.17 151.97 o 0 8 5 941.22 900.64 77.27 o 1 8 5 406.73 414.82 43.66 o 2 8 5 20.90 40.73 48.49 o 3 8 5 257.95 281.36 47.41 o 4 8 5 804.60 735.03 71.59 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244.14 262.08 138.17 o 8 9 7 85.54 2.84 155.34 o 0 10 7 60.14 130.87 83.91 o 1 10 7 45.21 45.88 46.51 o 2 10 7 32.69 72.20 56.49 o 3 10 7 2.44 24.35 53.58 o 4 10 7 512.68 627.96 84.66 o 5 10 7 86.94 105.74 82.66 o 6 10 7 302.52 213.30 95.37 o 7 10 7 11.31 18.28 60.73 o 1 11 7 31.18 46.18 53.76 o 2 11 7 77.39 106.23 58.71 o 3 11 7 431.48 481.58 78.79 o 4 11 7 2.37 41.18 65.60 o 5 11 7 69.58 111.67 73.83 o 6 11 7 7.66 8.52 138.29 o 7 11 7 408.01 459.39 220.69 o 0 12 7 429.05 474.80 109.75 o 1 12 7 47.82 68.51 56.54 o 2 12 7 72.75 129.49 68.00 o 3 12 7 14.28 63.49 74.37 o 4 12 7 164.81 182.26 68.65 o 5 12 7 76.36 76.51 68.38 o 6 12 7 102.14 159.56 126.73 o 1 13 7 13.34 58.54 69.22 o 2 13 7 69.66 68.38 62.81 o 3 13 7 151.37 137.00 77.13 o 4 13 7 45.85 87.87 68.55 o 5 13 7 667.97 752.57 164.07 o 6 13 7 0.31 43.57 138.29 o 1 14 7 32.39 47.28 74.66 o 2 14 7 230.64 304.69 80.14 o 3 14 7 106.61 110.69 65.25 o 4 14 7 100.68 115.49 77.35 o 5 14 7 8.62 20.84 112.72 o 6 14 7 357.90 646.93 287.00 o 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2 8 225.05 239.56 132.34 o 9 2 8 190.04 151.52 129.18 o 1 3 8 367.01 348.50 61.36 o 2 3 8 14.36 33.29 68.64 o 3 3 8 60.00 72.25 67.13 o 4 3 8 31.68 39.89 59.43 o 5 3 8 1535.74 1715.83 136.16 o 6 3 8 448.05 411.20 86.06 o 7 3 8 7.52 22.11 82.87 o 8 3 8 41.61 50.04 86.40 o 0 4 8 1976.35 1879.78 153.91 o 1 4 8 533.60 530.21 60.36 o 2 4 8 91.76 73.95 56.20 o 3 4 8 901.14 834.24 93.24 o 4 4 8 2393.72 2494.68 150.94 o 5 4 8 9.34 83.28 123.62 o 6 4 8 46.11 109.48 84.52 o 7 4 8 0.94 39.42 73.36 o 8 4 8 96.26 113.08 88.15 o 1 5 8 741.02 781.21 72.08 o 2 5 8 137.87 136.33 52.09 o 3 5 8 304.20 358.64 73.37 o 4 5 8 24.06 30.75 77.34 o 5 5 8 105.28 99.23 69.79 o 6 5 8 333.47 289.50 91.82 o 7 5 8 204.72 194.83 83.82 o 8 5 8 26.57 25.34 111.66 o 0 6 8 964.35 866.28 117.41 o 1 6 8 985.21 943.79 85.82 o 2 6 8 87.63 110.98 66.51 o 3 6 8 542.67 508.85 76.12 o 4 6 8 301.53 325.30 74.46 o 5 6 8 23.92 34.47 84.08 o 6 6 8 91.29 117.17 60.56 o 7 6 8 0.75 36.25 82.15 o 8 6 8 129.27 174.34 125.31 o 1 7 8 269.22 238.43 56.82 o 2 7 8 194.66 195.52 57.89 o 3 7 8 133.98 165.33 77.70 o 4 7 8 510.74 519.27 97.53 o 5 7 8 170.93 224.19 78.61 o 6 7 8 56.12 71.17 71.13 o 7 7 8 148.74 184.27 93.28 o 8 7 8 50.69 68.20 156.29 o 0 8 8 118.26 106.05 75.54 o 1 8 8 680.71 618.05 79.95 o 2 8 8 808.70 911.77 90.64 o 3 8 8 72.84 150.77 86.58 o 4 8 8 0.30 92.82 179.97 o 5 8 8 0.61 33.78 88.55 o 6 8 8 30.91 60.75 66.50 o 7 8 8 0.78 41.61 83.86 o 8 8 8 35.86 143.97 179.02 o 1 9 8 537.31 579.88 89.88 o 2 9 8 43.16 39.71 52.46 o 3 9 8 0.53 28.34 114.57 o 4 9 8 101.92 110.59 72.12 o 5 9 8 32.23 68.21 75.04 o 6 9 8 78.91 87.72 75.08 o 7 9 8 25.29 49.99 81.57 o 0 10 8 59.18 64.05 67.68 o 1 10 8 16.88 42.15 63.86 o 2 10 8 230.21 191.57 60.55 o 3 10 8 195.58 150.17 63.76 o 4 10 8 24.52 39.22 62.93 o 5 10 8 75.56 66.97 71.99 o 6 10 8 15.02 61.99 111.04 o 1 11 8 424.38 407.78 84.74 o 2 11 8 0.49 15.10 55.72 o 3 11 8 35.71 64.10 58.84 o 4 11 8 98.78 126.52 78.19 o 5 11 8 2.81 21.64 72.46 o 6 11 8 119.00 93.38 115.61 o 0 12 8 0.21 43.42 116.60 o 1 12 8 6.75 8.57 110.12 o 2 12 8 628.93 812.50 127.62 o 3 12 8 13.49 1.89 142.08 o 4 12 8 7.88 53.99 179.97 o 5 12 8 64.25 59.34 80.06 o 1 13 8 44.53 87.82 75.68 o 2 13 8 97.05 134.86 78.89 o 3 13 8 167.76 255.45 96.12 o 4 13 8 34.53 59.99 92.58 o 0 14 8 13.13 32.20 163.86 o 1 14 8 3.29 62.73 92.41 o 2 14 8 210.49 217.22 80.34 o 1 15 8 7.85 13.26 159.13 o 2 15 8 23.59 8.52 161.02 o 2 1 9 1.07 9.47 215.01 o 3 1 9 33.14 46.40 48.20 o 4 1 9 68.65 68.31 52.45 o 5 1 9 3.58 38.96 66.73 o 6 1 9 11.18 37.70 103.47 o 7 1 9 2.55 59.67 171.44 o 8 1 9 37.35 35.18 84.86 o 0 2 9 231.91 130.99 121.71 o 1 2 9 34.19 77.79 95.71 o 2 2 9 142.92 188.76 69.82 o 3 2 9 124.60 108.93 51.72 o 4 2 9 47.15 48.47 52.21 o 5 2 9 32.45 25.02 62.32 o 6 2 9 1.50 39.09 86.21 o 7 2 9 34.53 22.36 93.88 o 8 2 9 8.38 24.63 113.66 o 1 3 9 67.36 137.21 94.48 o 2 3 9 76.19 111.63 65.35 o 3 3 9 223.01 203.70 77.66 o 4 3 9 30.91 69.95 81.05 o 5 3 9 58.35 62.38 66.50 o 6 3 9 363.06 277.66 83.16 o 7 3 9 1.38 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113.82 59.50 o 2 9 9 13.82 70.61 129.60 o 3 9 9 146.29 138.26 75.30 o 4 9 9 20.54 34.98 77.69 o 5 9 9 28.69 50.20 158.18 o 6 9 9 50.82 59.83 85.42 o 0 10 9 0.84 7.58 112.72 o 1 10 9 7.27 32.20 137.34 o 2 10 9 498.55 579.37 110.36 o 3 10 9 106.07 54.44 78.74 o 4 10 9 22.92 67.25 163.86 o 5 10 9 9.55 54.94 139.24 o 1 11 9 142.85 177.08 70.24 o 2 11 9 60.55 39.49 61.05 o 3 11 9 61.34 70.07 91.55 o 4 11 9 8.15 24.92 112.78 o 1 12 9 2.39 3.79 161.97 o 2 12 9 144.71 109.05 113.10 o 3 12 9 9.95 53.78 106.70 o 1 13 9 49.15 114.61 170.49 o 0 0 10 39.79 96.61 197.96 o 1 0 10 176.31 211.22 244.37 o 2 0 10 191.88 165.76 251.00 o 3 0 10 337.37 274.68 217.85 o 4 0 10 112.34 159.13 178.07 o 1 1 10 21.83 40.73 190.38 o 2 1 10 221.90 152.38 110.50 o 3 1 10 561.28 662.01 134.62 o 4 1 10 57.62 73.88 198.91 o 0 2 10 1.60 78.62 205.54 o 1 2 10 89.24 115.62 106.11 o 2 2 10 471.85 583.11 158.75 o 3 2 10 194.67 213.16 114.24 o 4 2 10 56.88 2.84 179.97 o 1 3 10 156.13 172.10 149.44 o 2 3 10 171.57 171.37 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