#------------------------------------------------------------------------------ #$Date: 2011-09-16 18:46:08 +0300 (Fri, 16 Sep 2011) $ #$Revision: 26025 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2012849.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2012849_Fobs loop_ _publ_author_name 'Hallam, Matthew J.' 'Kilner, Colin A.' 'Halcrow, Malcolm A.' _publ_section_title ; Bis[\m-3{5}-(2-pyridyl)pyrazolido]bis[(acetonitrile)copper(II)] diperchlorate ; _journal_issue 8 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first m445 _journal_page_last m446 _journal_volume 58 _journal_year 2002 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 124.194 _cell_angle_gamma 90.000 _cell_length_a 7.9977 _cell_length_b 15.9230 _cell_length_c 12.1212 _exptl_crystal_F_000 700.00 _reflns_d_resolution_high 0.7697 _[local]_cod_data_source_file bm1502Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' mjh6 blue crystals' _shelx_refln_list_code 4 _shelx_f_calc_maximum 204.73 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 7818.53 7215.68 534.29 o 2 0 0 1380.18 1331.35 54.95 o 3 0 0 720.60 686.52 26.62 o 4 0 0 7085.36 7079.76 248.08 o 5 0 0 2178.71 2234.68 95.88 o 6 0 0 24.51 17.75 8.09 o 7 0 0 0.02 3.56 8.32 o 8 0 0 0.50 -8.80 8.80 o 1 1 0 658.02 617.78 149.23 o 2 1 0 402.75 400.93 11.43 o 3 1 0 872.56 915.84 24.14 o 4 1 0 1063.34 1157.27 31.50 o 5 1 0 735.29 761.16 21.65 o 6 1 0 125.42 129.50 6.46 o 7 1 0 84.58 79.57 8.77 o 8 1 0 53.48 39.86 11.45 o 1 2 0 7661.05 7423.48 213.14 o 2 2 0 48.65 30.70 2.23 o 3 2 0 3031.32 2889.55 66.57 o 4 2 0 2623.93 2731.76 73.60 o 5 2 0 2037.61 2146.72 55.55 o 6 2 0 339.75 347.90 9.83 o 7 2 0 4.65 7.96 6.04 o 8 2 0 2.14 -5.73 8.24 o 1 3 0 1471.31 1502.33 44.37 o 2 3 0 1866.67 1862.11 48.16 o 3 3 0 1144.38 1273.61 37.78 o 4 3 0 3.62 10.48 3.26 o 5 3 0 1602.93 1778.84 48.54 o 6 3 0 68.28 68.12 4.28 o 7 3 0 2.21 -4.49 4.49 o 8 3 0 22.04 10.60 8.84 o 0 4 0 6361.16 6416.55 281.83 o 1 4 0 28287.38 27497.62 873.81 o 2 4 0 5108.93 4494.12 111.74 o 3 4 0 2629.66 2379.89 47.54 o 4 4 0 17.98 17.95 1.89 o 5 4 0 61.25 57.95 3.28 o 6 4 0 163.92 178.88 6.57 o 7 4 0 14.37 28.58 3.78 o 8 4 0 17.29 17.17 8.47 o 1 5 0 8826.39 8565.70 265.89 o 2 5 0 294.76 263.02 7.70 o 3 5 0 1879.96 1845.05 45.69 o 4 5 0 2217.82 2251.96 47.99 o 5 5 0 110.08 105.56 4.75 o 6 5 0 352.11 335.00 12.52 o 7 5 0 372.59 333.93 18.41 o 8 5 0 92.09 104.35 12.64 o 0 6 0 1004.61 860.93 41.67 o 1 6 0 2189.07 2074.24 68.83 o 2 6 0 8979.37 8906.97 259.80 o 3 6 0 1797.67 1654.44 44.14 o 4 6 0 3212.18 3218.75 92.23 o 5 6 0 2.04 6.14 3.55 o 6 6 0 100.31 85.88 4.91 o 7 6 0 30.12 34.70 8.71 o 8 6 0 0.13 -0.82 9.15 o 1 7 0 521.24 476.19 13.68 o 2 7 0 870.02 970.68 27.19 o 3 7 0 4555.36 4653.62 129.02 o 4 7 0 1823.20 1814.03 49.07 o 5 7 0 38.12 22.03 4.46 o 6 7 0 197.32 186.21 7.59 o 7 7 0 352.29 344.96 19.15 o 8 7 0 26.96 19.85 14.93 o 0 8 0 5205.25 4766.52 219.47 o 1 8 0 1157.21 1003.04 26.09 o 2 8 0 3128.58 3218.96 94.55 o 3 8 0 2920.33 3105.85 114.83 o 4 8 0 2635.20 2785.78 86.26 o 5 8 0 20.22 22.76 3.92 o 6 8 0 1.01 -1.28 3.74 o 7 8 0 0.24 -0.35 8.89 o 1 9 0 340.79 331.74 10.92 o 2 9 0 79.31 91.68 4.43 o 3 9 0 464.38 434.58 19.38 o 4 9 0 452.26 447.02 16.27 o 5 9 0 623.66 670.26 21.01 o 6 9 0 287.81 296.63 12.11 o 7 9 0 84.55 69.64 16.49 o 0 10 0 645.33 608.97 24.47 o 1 10 0 3110.39 3096.77 85.97 o 2 10 0 2812.80 2974.81 85.30 o 3 10 0 2713.38 2767.16 75.15 o 4 10 0 115.03 126.81 8.08 o 5 10 0 86.32 90.26 6.62 o 6 10 0 378.54 352.86 26.67 o 7 10 0 5.06 -3.51 9.69 o 1 11 0 51.83 45.23 5.19 o 2 11 0 1358.82 1366.41 41.80 o 3 11 0 1293.93 1326.52 36.07 o 4 11 0 168.97 160.31 7.49 o 5 11 0 153.38 144.82 9.95 o 6 11 0 335.03 296.63 16.67 o 7 11 0 263.87 228.63 39.37 o 0 12 0 66.85 61.72 6.89 o 1 12 0 540.80 594.04 25.48 o 2 12 0 1664.21 1846.87 54.42 o 3 12 0 835.61 885.69 25.40 o 4 12 0 2.16 11.01 4.43 o 5 12 0 423.81 377.67 21.77 o 6 12 0 201.82 148.48 52.42 o 1 13 0 11.91 14.76 4.98 o 2 13 0 840.75 981.33 28.40 o 3 13 0 959.02 1062.20 41.29 o 4 13 0 36.39 43.16 6.27 o 5 13 0 107.82 94.20 17.75 o 6 13 0 280.41 269.85 17.68 o 0 14 0 1706.16 1790.33 103.93 o 1 14 0 423.15 451.64 15.83 o 2 14 0 203.35 203.35 9.94 o 3 14 0 16.71 14.95 8.11 o 4 14 0 176.32 178.94 15.02 o 5 14 0 32.79 15.35 9.59 o 6 14 0 56.82 37.18 17.95 o 1 15 0 561.41 557.47 25.35 o 2 15 0 539.29 536.93 18.64 o 3 15 0 31.32 32.97 7.72 o 4 15 0 110.50 92.32 10.31 o 5 15 0 281.13 262.17 19.80 o 0 16 0 0.90 11.45 6.24 o 1 16 0 0.70 -4.74 5.07 o 2 16 0 36.01 25.12 6.34 o 3 16 0 40.98 32.04 7.90 o 4 16 0 30.40 18.41 8.72 o 5 16 0 4.24 7.48 12.74 o 1 17 0 642.70 636.10 29.73 o 2 17 0 144.67 126.26 7.64 o 3 17 0 2.00 6.13 7.03 o 4 17 0 543.37 507.60 26.53 o 0 18 0 75.60 108.57 15.76 o 1 18 0 157.60 159.51 14.42 o 2 18 0 137.92 127.72 11.11 o 3 18 0 3.71 1.79 13.46 o 4 18 0 109.06 98.27 14.73 o 1 19 0 2.82 -7.30 8.01 o 2 19 0 1.00 8.08 9.97 o 3 19 0 313.61 267.89 22.91 o 0 20 0 14.36 2.32 13.28 o 1 20 0 55.41 62.22 13.03 o 2 20 0 9.01 8.59 8.90 o -8 1 1 834.02 847.09 54.23 o -7 1 1 34.79 34.70 5.26 o -6 1 1 2.99 7.45 2.29 o -5 1 1 502.37 475.66 16.98 o -4 1 1 3596.97 3641.32 83.88 o -3 1 1 103.34 114.98 3.81 o -2 1 1 4502.15 4370.69 111.61 o -1 1 1 2399.90 45.75 361.87 o 1 1 1 42.95 49.95 5.09 o 2 1 1 4321.48 3947.12 108.57 o 3 1 1 3772.89 3601.69 82.06 o 4 1 1 1139.74 1127.26 24.18 o 5 1 1 1813.76 1906.48 49.89 o 6 1 1 2543.81 2640.39 105.26 o 7 1 1 71.64 81.72 11.06 o 8 1 1 85.05 53.26 27.79 o -8 2 1 26.34 24.41 9.40 o -7 2 1 344.80 376.50 14.10 o -6 2 1 562.94 552.51 16.49 o -5 2 1 8.14 13.84 2.74 o -4 2 1 428.85 442.23 12.40 o -3 2 1 11652.58 11496.92 286.15 o -2 2 1 5537.90 5455.79 155.24 o -1 2 1 5459.21 4980.03 277.09 o 0 2 1 1199.75 1035.00 188.49 o 2 2 1 2731.52 2570.66 63.90 o 3 2 1 6.93 24.19 2.83 o 4 2 1 1348.31 1456.72 38.51 o 5 2 1 6.56 19.02 3.19 o 6 2 1 501.19 535.22 17.93 o 7 2 1 35.10 35.90 8.99 o 8 2 1 246.13 230.28 18.43 o -8 3 1 135.19 127.15 10.57 o -7 3 1 358.10 361.83 11.26 o -6 3 1 1205.10 1281.08 37.43 o -5 3 1 2387.12 2464.49 70.30 o -4 3 1 67.62 66.71 2.65 o -3 3 1 237.37 297.41 7.30 o -2 3 1 62.45 63.27 2.78 o -1 3 1 2.88 18.24 2.45 o 0 3 1 21604.38 21266.55 1266.04 o 1 3 1 41912.35 38215.82 3040.48 o 2 3 1 1513.42 1420.70 35.21 o 3 3 1 2370.80 2313.58 70.74 o 4 3 1 5485.34 5589.49 184.10 o 5 3 1 5123.86 5444.45 137.54 o 6 3 1 181.77 191.58 7.77 o 7 3 1 222.76 233.72 15.02 o 8 3 1 196.58 170.32 14.87 o -8 4 1 7.14 7.95 4.40 o -7 4 1 1.07 2.89 3.84 o -6 4 1 50.15 69.57 6.42 o -5 4 1 493.17 480.57 14.32 o -4 4 1 155.11 103.93 3.50 o -3 4 1 1272.86 1189.86 32.14 o -2 4 1 455.58 471.98 12.62 o -1 4 1 2.78 9.05 2.30 o 0 4 1 36.05 45.75 2.92 o 1 4 1 10187.15 10542.43 296.84 o 2 4 1 2173.53 2405.05 58.63 o 3 4 1 91.06 107.86 3.48 o 4 4 1 82.84 94.29 5.72 o 5 4 1 619.79 599.28 14.01 o 6 4 1 441.19 451.24 14.44 o 7 4 1 20.59 21.60 7.27 o 8 4 1 9.39 13.04 7.96 o -8 5 1 118.45 115.57 9.14 o -7 5 1 865.40 833.51 30.47 o -6 5 1 1020.56 1121.40 33.58 o -5 5 1 263.78 288.74 8.39 o -4 5 1 750.71 831.79 18.82 o -3 5 1 673.41 672.80 16.82 o -2 5 1 489.94 523.61 15.57 o -1 5 1 94.89 115.35 5.36 o 0 5 1 69.75 50.34 4.46 o 1 5 1 15359.86 15330.21 391.38 o 2 5 1 740.15 699.06 19.17 o 3 5 1 806.12 740.42 17.17 o 4 5 1 4828.70 4872.43 119.93 o 5 5 1 2919.66 3107.61 76.43 o 6 5 1 383.55 389.18 15.61 o 7 5 1 641.09 630.98 38.11 o -8 6 1 6.14 -8.63 8.63 o -7 6 1 113.75 116.68 9.67 o -6 6 1 407.06 407.50 19.09 o -5 6 1 1498.94 1534.26 34.87 o -4 6 1 2059.79 2066.68 60.37 o -3 6 1 351.80 352.36 11.26 o -2 6 1 47.09 41.23 4.01 o -1 6 1 1541.54 1308.05 37.34 o 0 6 1 13.60 4.68 2.76 o 1 6 1 3.77 4.74 1.96 o 2 6 1 1272.61 1308.24 36.28 o 3 6 1 10.22 0.88 2.96 o 4 6 1 64.50 68.07 3.84 o 5 6 1 172.73 181.33 8.40 o 6 6 1 64.98 81.59 13.60 o 7 6 1 9.07 10.69 6.08 o -8 7 1 466.63 452.67 29.52 o -7 7 1 437.37 438.99 23.33 o -6 7 1 328.55 330.62 15.00 o -5 7 1 3.80 5.43 4.04 o -4 7 1 754.19 737.35 23.44 o -3 7 1 16.34 18.38 2.67 o -2 7 1 37.55 25.87 5.90 o -1 7 1 1733.20 1667.22 49.06 o 0 7 1 515.36 502.53 16.25 o 1 7 1 1241.32 1226.18 28.72 o 2 7 1 16436.97 16481.25 410.83 o 3 7 1 1810.60 1798.29 52.59 o 4 7 1 1028.93 1070.14 30.01 o 5 7 1 5.95 9.08 6.43 o 6 7 1 623.03 720.41 48.89 o 7 7 1 419.66 429.25 27.62 o -8 8 1 10.83 11.23 6.75 o -7 8 1 220.38 232.27 14.40 o -6 8 1 715.65 712.66 22.20 o -5 8 1 46.85 41.14 4.34 o -4 8 1 116.64 113.22 7.08 o -3 8 1 834.16 801.28 22.38 o -2 8 1 2845.70 2644.63 69.50 o -1 8 1 2001.17 1914.81 54.15 o 0 8 1 497.47 442.92 15.29 o 1 8 1 645.75 652.24 29.28 o 2 8 1 1852.57 1920.08 52.59 o 3 8 1 184.33 206.72 8.60 o 4 8 1 979.81 987.87 28.17 o 5 8 1 454.14 445.87 15.41 o 6 8 1 54.79 43.10 5.63 o 7 8 1 107.72 114.12 12.78 o -8 9 1 192.81 192.29 13.70 o -7 9 1 221.33 232.80 14.40 o -6 9 1 397.17 395.90 29.21 o -5 9 1 107.48 107.47 6.59 o -4 9 1 0.50 -2.74 3.49 o -3 9 1 346.60 353.71 14.18 o -2 9 1 722.78 709.57 21.20 o -1 9 1 13.56 17.47 4.09 o 0 9 1 381.46 419.92 16.68 o 1 9 1 451.35 493.34 14.38 o 2 9 1 4498.86 4811.58 130.70 o 3 9 1 2556.09 2661.64 70.31 o 4 9 1 883.31 907.18 25.77 o 5 9 1 317.15 332.87 14.06 o 6 9 1 433.28 430.17 21.50 o 7 9 1 138.34 120.11 12.41 o -7 10 1 418.62 394.03 29.49 o -6 10 1 348.06 330.41 25.88 o -5 10 1 579.76 519.78 16.91 o -4 10 1 44.50 42.82 5.62 o -3 10 1 4708.83 4822.77 133.32 o -2 10 1 3189.95 3310.39 78.13 o -1 10 1 950.87 974.78 30.12 o 0 10 1 536.06 562.17 15.45 o 1 10 1 275.63 290.57 8.86 o 2 10 1 1029.86 1024.55 24.72 o 3 10 1 6.05 6.93 6.40 o 4 10 1 24.51 30.80 4.91 o 5 10 1 29.46 30.77 6.32 o 6 10 1 6.17 5.86 7.41 o 7 10 1 304.94 214.93 22.51 o -7 11 1 189.24 172.55 15.17 o -6 11 1 218.16 215.43 27.84 o -5 11 1 461.79 449.29 20.88 o -4 11 1 3.20 -2.84 4.70 o -3 11 1 180.06 215.87 8.00 o -2 11 1 3.98 0.68 3.56 o -1 11 1 191.72 180.33 7.91 o 0 11 1 736.35 735.17 22.53 o 1 11 1 1614.11 1594.26 89.88 o 2 11 1 13.67 4.38 3.29 o 3 11 1 3291.53 3292.07 124.52 o 4 11 1 249.18 270.88 14.46 o 5 11 1 382.92 396.01 23.98 o 6 11 1 2.83 6.11 7.37 o -7 12 1 19.42 12.04 8.93 o -6 12 1 143.06 119.94 10.70 o -5 12 1 776.32 758.60 32.58 o -4 12 1 760.15 795.34 29.90 o -3 12 1 602.90 651.24 22.92 o -2 12 1 2209.70 2468.24 76.57 o -1 12 1 2153.03 2120.63 63.72 o 0 12 1 1686.87 1668.46 55.84 o 1 12 1 53.14 42.97 5.28 o 2 12 1 1.28 7.44 2.47 o 3 12 1 1335.18 1417.80 38.84 o 4 12 1 549.40 552.19 19.95 o 5 12 1 92.24 71.23 9.16 o 6 12 1 33.92 10.80 7.50 o -7 13 1 68.92 52.94 13.96 o -6 13 1 4.24 -5.72 7.98 o -5 13 1 3.79 6.63 7.02 o -4 13 1 173.45 167.94 8.92 o -3 13 1 119.29 123.75 6.18 o -2 13 1 416.91 425.31 15.89 o -1 13 1 348.82 359.21 12.95 o 0 13 1 27.00 26.21 4.91 o 1 13 1 45.58 64.54 5.98 o 2 13 1 98.35 109.21 5.26 o 3 13 1 1247.53 1219.92 34.62 o 4 13 1 51.10 27.13 16.34 o 5 13 1 4.18 10.71 6.66 o 6 13 1 75.11 52.53 14.70 o -6 14 1 129.75 131.62 20.44 o -5 14 1 414.73 414.15 67.96 o -4 14 1 1526.67 1566.47 76.43 o -3 14 1 708.09 759.33 26.01 o -2 14 1 3181.36 3371.67 99.74 o -1 14 1 2059.37 2145.44 85.54 o 0 14 1 1236.11 1349.61 47.69 o 1 14 1 564.28 594.20 21.49 o 2 14 1 21.37 27.34 5.90 o 3 14 1 379.41 401.92 14.86 o 4 14 1 80.41 80.53 8.78 o 5 14 1 93.84 66.40 10.98 o -6 15 1 0.56 -9.56 11.16 o -5 15 1 62.19 70.42 15.84 o -4 15 1 106.78 118.56 11.11 o -3 15 1 587.37 588.55 22.10 o -2 15 1 583.92 612.49 22.95 o -1 15 1 419.73 413.94 17.60 o 0 15 1 10.78 5.04 4.40 o 1 15 1 100.31 94.49 8.67 o 2 15 1 864.77 949.09 29.02 o 3 15 1 46.83 50.62 6.78 o 4 15 1 157.95 120.18 12.88 o 5 15 1 5.50 -0.01 8.16 o -5 16 1 140.18 130.99 14.18 o -4 16 1 300.78 261.91 24.08 o -3 16 1 1247.97 1206.07 87.84 o -2 16 1 924.62 877.25 35.60 o -1 16 1 421.03 401.24 20.72 o 0 16 1 150.97 169.63 9.67 o 1 16 1 769.69 856.00 30.32 o 2 16 1 364.72 351.61 20.37 o 3 16 1 35.24 48.21 9.83 o 4 16 1 1.20 -4.61 21.37 o 5 16 1 7.07 -9.48 12.87 o -5 17 1 15.49 14.79 11.43 o -4 17 1 17.41 35.86 9.12 o -3 17 1 86.81 101.71 31.13 o -2 17 1 172.99 185.06 10.86 o -1 17 1 214.20 219.04 16.74 o 0 17 1 211.45 222.52 14.72 o 1 17 1 208.41 213.46 11.40 o 2 17 1 7.44 2.77 4.61 o 3 17 1 7.47 0.58 8.53 o 4 17 1 118.90 93.00 15.34 o -4 18 1 218.79 210.76 18.27 o -3 18 1 352.39 338.55 23.04 o -2 18 1 37.06 36.78 8.23 o -1 18 1 768.22 804.50 62.86 o 0 18 1 429.34 453.58 22.15 o 1 18 1 144.49 154.60 9.14 o 2 18 1 35.71 43.45 8.59 o 3 18 1 1.39 -0.30 10.08 o -3 19 1 36.81 27.96 10.97 o -2 19 1 171.00 149.77 14.37 o -1 19 1 3.47 9.31 6.54 o 0 19 1 20.80 39.00 11.03 o 1 19 1 15.82 3.70 8.76 o 2 19 1 268.42 248.14 37.91 o -2 20 1 23.13 6.52 8.97 o -1 20 1 719.15 721.53 39.95 o 0 20 1 824.36 764.31 45.00 o 1 20 1 18.43 12.78 11.87 o -9 0 2 727.84 747.58 57.46 o -8 0 2 344.57 327.11 62.90 o -7 0 2 355.54 355.48 19.25 o -6 0 2 4234.44 4818.04 344.26 o -5 0 2 9951.54 10517.59 335.81 o -4 0 2 10071.44 10863.92 344.52 o -3 0 2 4614.50 4487.44 157.85 o -2 0 2 19578.95 18519.51 879.36 o -1 0 2 18598.57 13080.48 6005.69 o 0 0 2 191.08 166.71 6.72 o 1 0 2 1373.56 1323.99 56.40 o 2 0 2 1528.16 1627.32 60.90 o 3 0 2 692.82 760.03 38.77 o 4 0 2 1939.93 2032.92 72.25 o 5 0 2 2806.79 3007.29 119.66 o 6 0 2 1501.15 1574.15 152.53 o 7 0 2 61.00 104.17 18.15 o -9 1 2 92.93 96.72 31.33 o -8 1 2 23.73 25.79 6.38 o -7 1 2 24.95 25.46 4.66 o -6 1 2 412.85 442.15 13.83 o -5 1 2 968.37 1124.46 28.73 o -4 1 2 86.97 141.23 5.71 o -3 1 2 1433.21 1397.40 31.41 o -2 1 2 11445.20 10991.71 295.38 o -1 1 2 341.13 327.97 9.45 o 0 1 2 3686.55 3476.39 107.07 o 1 1 2 262.12 246.65 8.95 o 2 1 2 352.66 332.92 8.84 o 3 1 2 78.01 80.87 3.04 o 4 1 2 233.74 224.63 8.76 o 5 1 2 241.93 247.12 7.52 o 6 1 2 8.81 18.86 3.65 o 7 1 2 17.83 25.27 9.24 o -9 2 2 255.78 268.23 32.21 o -8 2 2 501.29 520.02 57.38 o -7 2 2 1107.20 1127.84 28.70 o -6 2 2 1264.34 1329.43 33.00 o -5 2 2 3500.44 3741.90 89.47 o -4 2 2 7146.44 7259.05 168.75 o -3 2 2 2190.23 1916.02 49.25 o -2 2 2 1202.52 1101.49 29.00 o -1 2 2 141.38 145.52 3.71 o 0 2 2 5458.45 4947.33 143.66 o 1 2 2 757.42 605.82 14.46 o 2 2 2 503.64 472.99 12.51 o 3 2 2 2.53 7.00 2.18 o 4 2 2 178.05 190.12 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