#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/01/35/2013561.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2013561_Fobs loop_ _publ_author_name 'Narasimhamurthy, T.' 'Benny, J. C. N.' 'Pandiarajan, K.' 'Rathore, Ravindranath S.' _publ_section_title ; Herring-bone \p--\p interactions in trans-2,6-diphenyl-2,3,5,6-tetrahydrothiapyran-4-one ; _journal_issue 11 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first o620 _journal_page_last o621 _journal_volume 59 _journal_year 2003 _space_group_IT_number 2 _symmetry_space_group_name_Hall '-P 1' _symmetry_space_group_name_H-M 'P -1' _cell_angle_alpha 102.020 _cell_angle_beta 94.390 _cell_angle_gamma 106.390 _cell_length_a 5.9090 _cell_length_b 9.7060 _cell_length_c 13.1840 _exptl_crystal_F_000 283.97 _reflns_d_resolution_high 0.7953 _[local]_cod_data_source_file de1222Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title '2,6-Diphenylthiapyran-4-one Space Group P1bar' _shelx_refln_list_code 4 _shelx_f_calc_maximum 94.84 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 4002.36 4469.01 653.03 o 2 0 0 67.70 78.27 11.45 o 3 0 0 398.27 397.86 40.77 o 4 0 0 40.06 34.10 0.39 o 5 0 0 4.27 7.11 1.20 o 6 0 0 15.82 15.18 0.21 o -6 1 0 0.65 1.18 0.21 o -5 1 0 1.65 2.62 0.07 o -4 1 0 237.54 213.13 7.08 o -3 1 0 166.02 173.49 17.30 o -2 1 0 68.65 64.63 8.30 o -1 1 0 2.47 3.20 0.34 o 0 1 0 748.98 607.52 116.92 o 1 1 0 449.16 415.49 68.94 o 2 1 0 151.21 183.23 30.87 o 3 1 0 358.67 370.50 37.12 o 4 1 0 3.28 3.91 0.07 o 5 1 0 23.60 24.99 2.44 o 6 1 0 7.34 8.10 0.34 o -7 2 0 3.45 5.88 0.19 o -6 2 0 0.03 0.45 0.13 o -5 2 0 12.97 11.57 0.77 o -4 2 0 64.99 53.96 0.76 o -3 2 0 6.58 4.95 1.04 o -2 2 0 579.14 709.78 17.63 o -1 2 0 532.86 606.78 29.73 o 0 2 0 84.87 94.51 5.58 o 1 2 0 303.13 305.66 25.53 o 2 2 0 43.07 105.50 64.14 o 3 2 0 57.85 52.92 4.11 o 4 2 0 0.65 1.79 0.05 o 5 2 0 71.28 70.69 6.28 o 6 2 0 17.10 18.74 0.30 o -7 3 0 3.04 4.22 0.12 o -6 3 0 41.81 42.06 1.72 o -5 3 0 95.53 86.95 3.81 o -4 3 0 90.73 73.28 4.75 o -3 3 0 186.38 237.04 9.19 o -2 3 0 1763.89 2181.18 120.42 o -1 3 0 116.66 129.30 6.57 o 0 3 0 137.35 127.28 4.25 o 1 3 0 163.76 153.37 6.58 o 2 3 0 259.29 279.67 27.72 o 3 3 0 31.26 29.96 0.68 o 4 3 0 181.04 110.60 57.21 o 5 3 0 8.59 9.61 4.93 o 6 3 0 0.08 0.95 0.07 o -7 4 0 4.13 4.59 0.08 o -6 4 0 32.48 33.95 2.00 o -5 4 0 43.29 37.95 0.76 o -4 4 0 6.15 6.66 0.10 o -3 4 0 73.66 84.04 6.05 o -2 4 0 489.90 578.14 36.69 o -1 4 0 0.46 1.30 0.29 o 0 4 0 879.45 909.29 69.64 o 1 4 0 50.08 40.83 1.44 o 2 4 0 11.29 13.43 0.50 o 3 4 0 90.63 97.45 2.22 o 4 4 0 41.98 36.95 2.03 o 5 4 0 1.77 2.00 0.14 o -7 5 0 19.68 18.06 0.88 o -6 5 0 12.92 14.09 0.66 o -5 5 0 0.01 0.97 0.13 o -4 5 0 76.88 40.96 32.75 o -3 5 0 0.90 1.22 0.05 o -2 5 0 178.60 194.45 10.69 o -1 5 0 0.82 2.64 0.22 o 0 5 0 32.22 27.08 2.32 o 1 5 0 491.74 499.14 9.70 o 2 5 0 29.44 31.52 1.10 o 3 5 0 11.63 16.00 0.34 o 4 5 0 43.17 41.66 2.45 o 5 5 0 1.91 3.44 0.07 o -6 6 0 24.71 28.28 0.78 o -5 6 0 46.88 43.31 9.54 o -4 6 0 83.74 86.55 1.10 o -3 6 0 138.26 146.16 2.07 o -2 6 0 333.41 346.21 4.51 o -1 6 0 83.24 97.51 7.64 o 0 6 0 211.68 219.87 1.16 o 1 6 0 11.10 9.98 0.22 o 2 6 0 173.19 169.71 3.18 o 3 6 0 3.42 7.59 4.39 o 4 6 0 2.67 3.86 0.08 o -6 7 0 42.70 45.10 2.31 o -5 7 0 0.30 0.76 0.08 o -4 7 0 74.37 75.78 2.37 o -3 7 0 2.83 3.75 0.17 o -2 7 0 263.98 261.22 3.63 o -1 7 0 173.59 169.01 0.87 o 0 7 0 3.37 5.73 0.09 o 1 7 0 72.31 71.13 2.10 o 2 7 0 111.40 109.01 3.57 o 3 7 0 5.21 4.48 0.09 o 4 7 0 3.58 3.89 0.17 o -6 8 0 2.31 3.03 0.08 o -5 8 0 10.44 13.31 0.19 o -4 8 0 102.38 102.22 0.61 o -3 8 0 15.20 14.88 0.21 o -2 8 0 38.60 37.32 0.83 o -1 8 0 120.19 119.83 1.94 o 0 8 0 0.25 1.38 0.10 o 1 8 0 0.47 1.16 0.06 o 2 8 0 65.76 63.87 0.54 o 3 8 0 10.72 11.76 0.32 o -6 9 0 27.00 22.72 0.29 o -5 9 0 0.92 1.00 0.06 o -4 9 0 16.56 16.99 0.28 o -3 9 0 16.56 15.63 2.51 o -2 9 0 48.30 46.35 0.41 o -1 9 0 0.06 1.23 0.27 o 0 9 0 99.19 99.80 3.12 o 1 9 0 6.86 6.39 0.10 o 2 9 0 4.09 3.42 0.11 o -5 10 0 1.95 2.85 0.07 o -4 10 0 32.43 34.30 0.30 o -3 10 0 75.76 77.88 0.48 o -2 10 0 58.53 58.29 0.43 o -1 10 0 0.73 1.64 0.06 o 0 10 0 34.15 31.75 0.97 o 1 10 0 1.53 2.59 0.07 o -4 11 0 45.30 48.06 0.28 o -3 11 0 1.92 2.70 0.07 o -2 11 0 18.23 18.21 0.49 o -1 11 0 4.22 5.29 0.25 o 0 11 0 18.30 16.51 0.17 o 0 -11 1 5.23 5.54 0.12 o 1 -11 1 4.32 4.37 0.12 o 2 -11 1 9.46 11.35 0.21 o 3 -11 1 24.86 24.65 0.34 o 4 -11 1 10.60 12.78 0.23 o -1 -10 1 14.71 15.09 0.27 o 0 -10 1 15.25 14.99 0.27 o 1 -10 1 2.57 2.88 0.10 o 2 -10 1 180.44 177.52 1.07 o 3 -10 1 38.71 37.96 0.49 o 4 -10 1 0.75 1.24 0.09 o 5 -10 1 14.94 14.18 0.25 o -2 -9 1 19.03 19.10 0.32 o -1 -9 1 47.76 41.74 0.52 o 0 -9 1 6.16 6.59 0.14 o 1 -9 1 7.73 7.77 0.15 o 2 -9 1 2.63 4.62 0.12 o 3 -9 1 26.44 20.12 0.33 o 4 -9 1 6.41 8.22 0.16 o 5 -9 1 15.87 15.42 0.30 o 6 -9 1 6.79 7.27 0.13 o -3 -8 1 24.79 21.54 0.32 o -2 -8 1 21.94 20.14 0.38 o -1 -8 1 28.86 35.87 0.51 o 0 -8 1 121.15 118.67 0.90 o 1 -8 1 21.72 25.36 0.42 o 2 -8 1 3.40 3.93 0.11 o 3 -8 1 69.13 70.54 0.70 o 4 -8 1 18.05 21.96 0.40 o 5 -8 1 8.69 7.68 0.15 o 6 -8 1 0.86 1.49 0.09 o -4 -7 1 0.13 0.92 0.07 o -3 -7 1 79.80 69.31 0.66 o -2 -7 1 16.00 17.15 0.37 o -1 -7 1 54.35 49.93 0.58 o 0 -7 1 209.85 205.61 1.11 o 1 -7 1 8.92 8.75 0.20 o 2 -7 1 27.09 27.43 0.40 o 3 -7 1 223.86 206.11 1.13 o 4 -7 1 8.41 7.23 0.15 o 5 -7 1 1.79 2.73 0.10 o 6 -7 1 19.44 19.40 0.34 o -4 -6 1 0.34 0.72 0.07 o -3 -6 1 4.79 5.89 0.13 o -2 -6 1 15.62 16.97 0.35 o -1 -6 1 9.14 8.29 0.18 o 0 -6 1 69.48 61.69 0.55 o 1 -6 1 55.00 48.41 0.46 o 2 -6 1 220.99 233.18 1.04 o 3 -6 1 0.62 0.82 0.05 o 4 -6 1 6.81 11.66 0.25 o 5 -6 1 24.89 21.69 0.42 o 6 -6 1 41.02 43.57 0.54 o -5 -5 1 29.89 24.76 0.33 o -4 -5 1 1.12 2.10 0.10 o -3 -5 1 4.06 8.71 5.46 o -2 -5 1 188.09 180.67 1.02 o -1 -5 1 26.55 26.26 0.37 o 0 -5 1 9.14 14.81 0.23 o 1 -5 1 141.67 130.29 0.67 o 2 -5 1 35.29 36.87 0.37 o 3 -5 1 19.43 17.05 0.29 o 4 -5 1 2.71 4.21 0.10 o 5 -5 1 195.92 190.38 1.17 o 6 -5 1 0.39 1.26 0.08 o 7 -5 1 14.31 17.25 0.26 o -5 -4 1 57.85 52.45 0.54 o -4 -4 1 45.92 40.49 0.54 o -3 -4 1 479.68 460.90 1.70 o -2 -4 1 142.19 159.95 0.92 o -1 -4 1 210.19 221.32 0.93 o 0 -4 1 202.67 192.37 0.72 o 1 -4 1 28.97 27.19 0.27 o 2 -4 1 443.13 475.87 5.65 o 3 -4 1 125.21 143.95 0.76 o 4 -4 1 206.89 188.27 1.02 o 5 -4 1 44.03 45.58 0.57 o 6 -4 1 0.01 1.02 0.13 o 7 -4 1 37.32 36.07 0.38 o -6 -3 1 5.52 13.15 0.24 o -5 -3 1 11.97 9.92 0.21 o -4 -3 1 88.08 91.06 0.79 o -3 -3 1 0.53 0.98 0.05 o -2 -3 1 319.54 372.05 1.27 o -1 -3 1 145.03 173.16 0.71 o 0 -3 1 969.02 967.09 6.47 o 1 -3 1 1966.36 1893.86 9.34 o 2 -3 1 309.43 281.62 0.83 o 3 -3 1 24.12 17.94 0.26 o 4 -3 1 58.57 57.41 0.55 o 5 -3 1 0.04 0.89 0.07 o 6 -3 1 3.10 2.87 0.11 o 7 -3 1 19.78 18.80 0.28 o -6 -2 1 14.46 14.53 0.27 o -5 -2 1 5.21 14.01 0.35 o -4 -2 1 7.33 7.52 0.16 o -3 -2 1 6.38 4.44 0.09 o -2 -2 1 214.09 283.62 0.99 o -1 -2 1 37.79 39.67 0.29 o 0 -2 1 49.17 46.83 0.23 o 1 -2 1 862.53 798.06 4.95 o 2 -2 1 114.32 103.28 0.46 o 3 -2 1 474.19 501.22 6.18 o 4 -2 1 32.49 29.76 0.39 o 5 -2 1 265.82 270.29 1.37 o 6 -2 1 8.50 6.81 0.14 o 7 -2 1 18.43 16.82 0.25 o -6 -1 1 3.93 4.68 0.12 o -5 -1 1 113.47 100.74 0.84 o -4 -1 1 52.06 53.70 0.56 o -3 -1 1 0.43 0.95 0.05 o -2 -1 1 290.80 327.82 0.96 o -1 -1 1 2224.23 2247.71 9.54 o 0 -1 1 869.20 804.98 3.94 o 1 -1 1 4071.13 3477.88 10.69 o 2 -1 1 931.06 993.38 6.83 o 3 -1 1 72.30 59.17 0.45 o 4 -1 1 36.41 38.94 0.46 o 5 -1 1 199.37 198.55 1.18 o 6 -1 1 15.79 16.13 0.33 o -6 0 1 0.05 1.03 0.08 o -5 0 1 121.71 108.58 0.88 o -4 0 1 203.45 188.74 1.02 o -3 0 1 110.54 124.14 0.70 o -2 0 1 537.04 551.52 5.50 o -1 0 1 1893.14 1653.04 7.27 o 0 0 1 101.70 101.83 1.20 o 1 0 1 183.98 222.28 2.29 o 2 0 1 136.85 163.79 0.60 o 3 0 1 438.00 474.71 6.21 o 4 0 1 10.68 11.89 0.26 o 5 0 1 41.60 44.52 0.56 o 6 0 1 8.14 9.01 0.18 o -7 1 1 0.14 0.66 0.09 o -6 1 1 0.12 0.92 0.12 o -5 1 1 19.07 15.98 0.35 o -4 1 1 96.13 86.03 0.67 o -3 1 1 4.85 6.76 0.15 o -2 1 1 546.07 535.24 5.31 o -1 1 1 141.92 128.84 0.40 o 0 1 1 137.79 133.58 1.69 o 1 1 1 145.67 137.23 2.07 o 2 1 1 9.17 6.63 0.14 o 3 1 1 66.54 65.83 0.52 o 4 1 1 41.92 49.79 0.55 o 5 1 1 23.63 22.94 0.41 o 6 1 1 0.85 1.72 0.09 o -7 2 1 5.26 6.18 0.12 o -6 2 1 69.59 66.66 0.69 o -5 2 1 51.87 46.16 0.57 o -4 2 1 61.50 59.03 0.57 o -3 2 1 1419.93 1458.88 11.47 o -2 2 1 84.64 91.52 0.48 o -1 2 1 11.51 12.93 0.15 o 0 2 1 1810.95 1779.63 8.70 o 1 2 1 1187.89 1068.69 7.18 o 2 2 1 9.84 12.53 0.20 o 3 2 1 287.07 299.25 1.21 o 4 2 1 132.85 135.06 0.94 o 5 2 1 8.58 9.91 0.22 o 6 2 1 5.66 14.15 5.26 o -7 3 1 19.03 21.37 0.29 o -6 3 1 96.59 91.10 0.81 o -5 3 1 39.19 34.49 0.50 o -4 3 1 76.08 47.40 0.55 o -3 3 1 871.28 998.02 9.75 o -2 3 1 625.28 818.18 7.48 o -1 3 1 64.32 73.10 0.42 o 0 3 1 19.35 18.97 0.22 o 1 3 1 121.79 105.59 0.54 o 2 3 1 1.23 2.91 0.06 o 3 3 1 138.08 136.35 0.88 o 4 3 1 58.14 56.28 0.63 o 5 3 1 43.91 42.32 0.52 o -7 4 1 29.65 30.46 0.35 o -6 4 1 3.65 4.77 0.13 o -5 4 1 33.77 28.96 0.47 o -4 4 1 24.24 19.94 0.36 o -3 4 1 299.77 381.32 1.34 o -2 4 1 312.47 406.50 1.23 o -1 4 1 454.84 536.80 6.33 o 0 4 1 5.31 7.79 0.17 o 1 4 1 28.62 31.21 0.34 o 2 4 1 65.86 66.83 0.58 o 3 4 1 79.74 80.40 0.72 o 4 4 1 26.62 27.79 0.44 o 5 4 1 23.13 23.17 0.35 o -7 5 1 2.59 3.24 0.09 o -6 5 1 0.11 0.71 0.13 o -5 5 1 113.20 123.19 0.96 o -4 5 1 57.99 61.88 0.64 o -3 5 1 33.61 38.27 0.44 o -2 5 1 66.03 82.99 0.61 o -1 5 1 112.49 114.10 0.71 o 0 5 1 330.49 403.90 1.39 o 1 5 1 316.25 330.66 1.27 o 2 5 1 222.38 228.78 1.17 o 3 5 1 88.04 85.54 0.77 o 4 5 1 0.06 1.46 0.09 o 5 5 1 11.12 13.04 0.22 o -6 6 1 58.58 68.22 0.67 o -5 6 1 2.84 3.92 0.12 o -4 6 1 2.69 2.50 0.09 o -3 6 1 0.41 1.83 0.07 o -2 6 1 143.88 144.93 0.86 o -1 6 1 13.45 12.79 0.26 o 0 6 1 107.47 103.18 0.74 o 1 6 1 570.31 586.61 1.88 o 2 6 1 88.47 88.44 0.78 o 3 6 1 2.07 3.15 0.11 o 4 6 1 17.56 17.38 0.31 o -6 7 1 12.63 13.70 0.25 o -5 7 1 15.82 18.12 0.36 o -4 7 1 0.37 0.75 0.14 o -3 7 1 349.60 349.83 1.54 o -2 7 1 34.66 39.48 0.50 o -1 7 1 18.52 18.97 0.35 o 0 7 1 3.86 5.58 0.12 o 1 7 1 276.35 287.97 1.41 o 2 7 1 5.86 7.71 0.16 o 3 7 1 1.16 2.26 0.10 o -6 8 1 60.18 62.24 0.52 o -5 8 1 0.94 1.17 0.08 o -4 8 1 6.73 11.25 0.24 o -3 8 1 159.65 155.68 1.07 o -2 8 1 0.11 1.34 0.08 o -1 8 1 73.32 68.58 0.69 o 0 8 1 0.36 1.16 0.08 o 1 8 1 0.35 1.10 0.09 o 2 8 1 4.38 5.51 0.13 o 3 8 1 0.09 0.84 0.11 o -5 9 1 69.15 70.13 0.59 o -4 9 1 2.48 2.95 0.10 o -2 9 1 16.04 16.99 0.36 o -1 9 1 95.39 92.57 0.80 o 0 9 1 1.29 2.01 0.10 o 1 9 1 5.27 4.94 0.13 o 2 9 1 21.04 22.76 0.31 o -5 10 1 39.83 40.15 0.37 o -4 10 1 13.10 13.32 0.23 o -3 10 1 0.70 1.21 0.09 o -2 10 1 2.37 3.95 0.11 o -1 10 1 56.93 58.86 0.58 o 0 10 1 12.64 12.13 0.22 o 1 10 1 7.56 8.30 0.17 o -3 11 1 11.88 11.59 0.22 o -2 11 1 0.78 1.65 0.08 o -1 11 1 16.54 15.45 0.24 o 0 -11 2 29.34 25.73 0.32 o 1 -11 2 14.64 15.51 0.28 o 2 -11 2 0.04 1.15 0.09 o 3 -11 2 4.73 5.58 0.12 o 4 -11 2 2.04 4.17 0.11 o -1 -10 2 2.09 2.56 0.09 o 0 -10 2 5.21 4.57 0.13 o 1 -10 2 17.62 16.96 0.34 o 2 -10 2 0.03 1.06 0.17 o 3 -10 2 31.46 34.06 0.47 o 4 -10 2 6.47 8.74 0.17 o 5 -10 2 3.08 3.68 0.11 o -2 -9 2 8.50 17.87 0.33 o -1 -9 2 9.19 9.51 0.19 o 0 -9 2 0.19 0.79 0.13 o 1 -9 2 98.19 93.29 0.80 o 2 -9 2 310.16 305.00 1.46 o 3 -9 2 7.81 8.21 0.17 o 4 -9 2 0.84 1.14 0.08 o 5 -9 2 8.84 10.48 0.20 o 6 -9 2 15.65 17.51 0.25 o -3 -8 2 5.11 6.19 0.13 o -2 -8 2 16.13 17.11 0.30 o -1 -8 2 139.03 134.47 0.97 o 0 -8 2 0.04 0.62 0.11 o 1 -8 2 4.48 7.87 0.17 o 2 -8 2 147.64 140.56 0.96 o 3 -8 2 6.13 7.05 0.16 o 4 -8 2 3.84 4.68 0.12 o 5 -8 2 22.74 21.77 0.39 o 6 -8 2 10.82 13.31 0.23 o -4 -7 2 5.65 7.12 0.14 o -3 -7 2 0.03 0.75 0.11 o -2 -7 2 60.48 62.02 0.66 o -1 -7 2 9.16 8.99 0.18 o 0 -7 2 80.96 70.17 0.64 o 1 -7 2 2.51 3.19 0.09 o 2 -7 2 10.35 13.75 0.29 o 3 -7 2 0.73 1.70 0.07 o 4 -7 2 14.65 13.72 0.27 o 6 -7 2 18.47 19.34 0.34 o -4 -6 2 4.28 4.29 0.12 o -3 -6 2 7.07 7.65 0.15 o -2 -6 2 65.84 66.21 0.66 o -1 -6 2 56.96 61.63 0.59 o 0 -6 2 395.76 375.01 1.34 o 1 -6 2 211.52 208.90 0.96 o 2 -6 2 32.44 38.19 0.42 o 3 -6 2 3.89 2.57 0.07 o 4 -6 2 4.27 4.16 0.11 o 5 -6 2 100.09 58.17 0.65 o 6 -6 2 21.74 25.30 0.42 o -5 -5 2 4.03 3.50 0.11 o -4 -5 2 49.83 45.04 0.56 o -3 -5 2 72.50 76.24 0.73 o -2 -5 2 22.80 22.02 0.36 o -1 -5 2 68.48 81.73 0.64 o 0 -5 2 1.61 4.03 0.08 o 1 -5 2 335.25 324.53 1.07 o 2 -5 2 31.62 33.46 0.36 o 3 -5 2 431.97 403.58 6.65 o 4 -5 2 114.81 105.76 0.80 o 5 -5 2 94.01 87.43 0.80 o 6 -5 2 34.07 38.01 0.51 o 7 -5 2 3.04 4.25 0.11 o -5 -4 2 5.22 6.74 0.14 o -4 -4 2 92.86 87.28 0.78 o -3 -4 2 16.71 18.25 0.34 o -2 -4 2 0.10 0.67 0.05 o -1 -4 2 37.83 32.72 0.36 o 0 -4 2 295.11 266.97 0.85 o 1 -4 2 44.21 47.18 0.35 o 2 -4 2 73.51 70.40 0.46 o 3 -4 2 529.38 442.23 1.35 o 4 -4 2 0.08 0.59 0.10 o 5 -4 2 0.47 2.33 0.10 o 6 -4 2 74.89 77.52 0.73 o 7 -4 2 4.29 4.88 0.11 o -6 -3 2 5.11 5.13 0.11 o -5 -3 2 21.16 19.63 0.36 o -4 -3 2 112.31 110.31 0.86 o -3 -3 2 0.19 0.67 0.05 o -2 -3 2 143.21 198.60 0.93 o -1 -3 2 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