#------------------------------------------------------------------------------ #$Date: 2016-04-02 22:02:04 +0300 (Sat, 02 Apr 2016) $ #$Revision: 180815 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/01/46/2014694.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2014694_Fobs loop_ _publ_author_name 'Chivers, Tristram' 'Fedorchuck, Chantall' 'Parvez, Masood' _publ_section_title ; An asymmetrically substituted borazine ; _journal_issue 1 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first o47 _journal_page_last o49 _journal_volume 61 _journal_year 2005 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 112.190 _cell_angle_gamma 90.000 _cell_length_a 13.6530 _cell_length_b 13.6370 _cell_length_c 11.8930 _exptl_crystal_F_000 776.00 _reflns_d_resolution_high 0.7697 _cod_data_source_file gg1227IIIsup2.hkl _cod_data_source_block III #BEGIN Tags that were not found in dictionaries: _shelx_title ' Chantall - 1 (KCCD Data)' _shelx_refln_list_code 4 _shelx_f_calc_maximum 77.71 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 4 0 0 131.59 86.03 2.29 o 6 0 0 293.02 336.36 6.87 o 8 0 0 1215.67 1335.96 27.64 o 10 0 0 2354.64 2392.99 60.36 o 12 0 0 1983.08 2159.80 70.17 o 14 0 0 219.84 228.24 7.88 o 16 0 0 131.55 112.47 6.10 o 5 1 0 445.10 456.20 13.13 o 7 1 0 40.46 50.76 0.91 o 9 1 0 249.69 261.15 8.96 o 11 1 0 2502.40 2502.09 55.09 o 13 1 0 2.37 0.89 0.71 o 15 1 0 14.42 13.38 3.44 o 0 2 0 18.69 5.87 0.92 o 4 2 0 0.75 2.95 1.15 o 6 2 0 0.13 -0.10 0.80 o 8 2 0 112.98 115.46 3.28 o 10 2 0 85.80 101.05 2.41 o 12 2 0 66.17 51.93 1.47 o 14 2 0 111.15 110.70 4.61 o 16 2 0 153.90 174.48 8.25 o 3 3 0 646.63 585.13 10.71 o 5 3 0 5526.07 6210.01 325.71 o 7 3 0 1307.72 1488.99 22.30 o 9 3 0 294.96 280.93 4.50 o 11 3 0 75.69 72.87 1.89 o 13 3 0 42.13 42.38 1.50 o 15 3 0 87.69 113.46 4.08 o 0 4 0 809.34 740.61 17.97 o 2 4 0 624.77 619.50 12.45 o 4 4 0 108.92 145.15 2.44 o 6 4 0 1863.71 2054.59 50.51 o 8 4 0 146.92 169.45 3.37 o 10 4 0 76.33 63.80 1.58 o 12 4 0 97.80 85.31 2.07 o 14 4 0 10.38 9.85 1.19 o 1 5 0 40.07 26.48 0.57 o 3 5 0 48.04 45.13 1.01 o 5 5 0 140.84 131.16 2.15 o 7 5 0 12.57 7.37 0.76 o 9 5 0 5.48 12.19 0.66 o 11 5 0 9.01 11.96 0.61 o 13 5 0 141.15 155.20 6.14 o 15 5 0 0.01 0.92 1.03 o 2 6 0 155.92 177.15 3.27 o 4 6 0 688.87 678.16 10.69 o 6 6 0 87.12 95.73 4.06 o 8 6 0 348.31 349.52 6.39 o 10 6 0 77.96 80.50 1.60 o 12 6 0 14.43 11.94 0.83 o 14 6 0 0.01 -0.92 0.92 o 1 7 0 2221.02 2408.88 51.06 o 3 7 0 1674.76 1547.54 35.59 o 5 7 0 875.69 898.36 31.07 o 7 7 0 42.96 35.16 1.31 o 9 7 0 85.20 69.84 1.30 o 11 7 0 25.55 18.74 0.63 o 13 7 0 4.25 4.30 0.89 o 15 7 0 1.63 2.68 2.50 o 0 8 0 490.69 606.95 14.18 o 2 8 0 1.58 0.45 0.62 o 4 8 0 216.73 228.64 3.96 o 6 8 0 4.34 5.77 1.35 o 8 8 0 275.79 276.79 9.53 o 10 8 0 86.70 80.95 3.87 o 12 8 0 0.80 -1.57 1.57 o 14 8 0 4.10 4.25 2.00 o 1 9 0 7.17 5.47 0.80 o 3 9 0 263.94 286.74 5.33 o 5 9 0 3341.83 3241.12 129.98 o 7 9 0 3608.55 3829.93 218.57 o 9 9 0 22.96 25.61 4.03 o 11 9 0 59.02 58.53 3.94 o 13 9 0 23.42 19.12 2.37 o 0 10 0 545.55 480.44 11.32 o 2 10 0 697.59 730.30 16.27 o 4 10 0 361.06 394.18 6.84 o 6 10 0 2423.94 2325.19 52.03 o 8 10 0 17.86 19.97 1.49 o 10 10 0 20.97 23.29 1.83 o 12 10 0 0.15 0.61 1.34 o 1 11 0 170.57 147.25 2.56 o 3 11 0 1439.57 1466.74 26.76 o 5 11 0 287.51 298.64 6.72 o 7 11 0 2.20 4.02 1.07 o 9 11 0 533.78 535.67 15.17 o 11 11 0 0.26 3.80 2.70 o 0 12 0 13.79 52.57 2.06 o 2 12 0 649.66 543.28 19.18 o 4 12 0 4.03 3.04 1.76 o 6 12 0 705.57 758.18 17.01 o 8 12 0 57.69 50.79 2.21 o 10 12 0 31.41 33.12 2.13 o 12 12 0 125.33 148.92 6.36 o 1 13 0 572.75 535.41 10.74 o 3 13 0 125.37 108.77 2.53 o 5 13 0 258.94 249.78 6.42 o 7 13 0 34.99 31.62 1.63 o 9 13 0 27.61 23.59 1.76 o 11 13 0 48.69 55.68 3.05 o 0 14 0 57.71 65.59 3.78 o 2 14 0 46.42 43.31 2.34 o 4 14 0 2.47 3.21 0.87 o 6 14 0 8.26 8.07 2.13 o 8 14 0 1.05 -0.21 1.92 o 10 14 0 5.90 2.91 2.31 o 1 15 0 0.17 0.87 0.92 o 3 15 0 0.06 0.84 0.95 o 5 15 0 18.74 22.35 1.92 o 7 15 0 53.77 47.69 8.20 o 0 16 0 24.20 11.78 2.02 o 2 16 0 6.47 5.91 1.24 o 4 16 0 20.07 29.43 5.41 o 6 16 0 4.01 1.74 3.35 o 1 17 0 2.70 3.62 1.19 o 3 17 0 73.74 86.96 5.21 o -15 1 1 153.81 166.35 5.05 o -13 1 1 71.55 65.33 5.09 o -11 1 1 375.61 369.52 6.43 o -9 1 1 122.28 121.53 2.11 o -7 1 1 506.03 522.34 7.85 o -5 1 1 3376.73 3417.69 67.08 o -3 1 1 664.41 571.64 15.72 o -1 1 1 21.15 -0.14 0.14 o 1 1 1 176.15 124.33 7.29 o 3 1 1 2923.53 2797.22 41.96 o 5 1 1 363.69 359.01 4.80 o 7 1 1 54.49 48.19 0.87 o 9 1 1 1152.30 1177.66 15.54 o 11 1 1 12.28 11.45 0.80 o 13 1 1 309.10 323.99 6.95 o 15 1 1 2.08 0.42 1.21 o -16 2 1 2.06 2.39 1.26 o -14 2 1 13.91 12.68 1.21 o -12 2 1 247.35 257.18 13.06 o -10 2 1 218.63 194.35 3.17 o -8 2 1 3223.72 3315.65 57.99 o -6 2 1 4317.36 4221.06 140.41 o -4 2 1 1659.65 1592.25 47.44 o -2 2 1 252.25 244.10 6.83 o 0 2 1 1903.59 922.05 63.25 o 2 2 1 348.96 333.47 17.28 o 4 2 1 1200.77 1176.55 15.73 o 6 2 1 476.04 465.90 6.39 o 8 2 1 2.23 0.25 0.44 o 10 2 1 467.70 437.58 6.43 o 12 2 1 29.07 27.28 1.03 o 14 2 1 10.44 12.33 3.00 o -15 3 1 48.44 54.53 2.21 o -13 3 1 2.56 2.00 1.72 o -11 3 1 160.59 152.29 3.55 o -9 3 1 698.51 753.37 12.24 o -7 3 1 1601.65 1898.20 28.42 o -5 3 1 1034.44 1089.52 18.47 o -3 3 1 1738.07 1698.46 31.43 o 1 3 1 736.08 720.78 14.47 o 3 3 1 1663.41 1617.41 29.57 o 5 3 1 358.52 416.16 6.03 o 7 3 1 2342.55 2431.80 32.70 o 9 3 1 108.84 92.37 1.79 o 11 3 1 93.79 92.02 1.91 o 13 3 1 9.90 15.51 1.22 o 15 3 1 1.27 2.33 1.72 o -16 4 1 13.74 16.19 1.43 o -14 4 1 0.32 1.54 1.24 o -12 4 1 122.64 113.04 7.47 o -10 4 1 520.17 496.54 9.27 o -8 4 1 23.94 36.83 1.54 o -6 4 1 144.81 142.88 5.22 o -4 4 1 592.27 562.96 9.96 o 0 4 1 2.48 2.52 0.23 o 2 4 1 431.14 433.13 9.86 o 4 4 1 511.53 541.06 14.85 o 6 4 1 635.07 653.93 8.59 o 8 4 1 757.32 765.93 10.61 o 10 4 1 287.37 264.75 4.35 o 12 4 1 26.77 31.26 1.12 o 14 4 1 5.44 9.60 2.27 o -15 5 1 3.87 1.92 1.63 o -13 5 1 11.70 6.27 1.12 o -11 5 1 372.13 355.54 8.02 o -9 5 1 681.10 712.94 12.92 o -7 5 1 60.07 62.70 2.38 o -5 5 1 1418.17 1214.67 23.24 o -3 5 1 4983.99 5147.61 240.99 o -1 5 1 2792.05 2885.46 121.27 o 1 5 1 1.10 0.70 0.24 o 3 5 1 56.91 52.85 1.25 o 5 5 1 253.92 282.44 12.31 o 7 5 1 411.37 436.00 6.02 o 9 5 1 6.52 1.82 0.73 o 11 5 1 447.43 421.84 8.56 o 13 5 1 247.41 251.13 8.72 o 15 5 1 40.94 38.89 2.46 o -14 6 1 43.68 31.99 1.63 o -12 6 1 899.60 930.51 34.17 o -10 6 1 53.70 41.11 1.27 o -8 6 1 18.36 15.34 0.73 o -6 6 1 691.00 770.28 14.11 o -4 6 1 0.38 2.11 0.69 o -2 6 1 861.53 955.93 15.83 o 2 6 1 467.30 487.13 8.47 o 4 6 1 224.01 245.97 7.79 o 6 6 1 76.20 98.49 2.93 o 8 6 1 325.05 351.04 6.09 o 10 6 1 1612.79 1638.81 41.85 o 12 6 1 1.72 -0.07 0.69 o 14 6 1 8.24 6.07 1.02 o -15 7 1 23.89 21.66 3.23 o -13 7 1 78.18 70.32 2.52 o -11 7 1 116.94 98.91 3.94 o -9 7 1 4.87 5.71 0.60 o -7 7 1 6.08 4.82 0.37 o -5 7 1 24.69 33.35 0.84 o -3 7 1 89.74 90.04 1.62 o -1 7 1 797.73 949.02 16.64 o 1 7 1 132.40 141.19 2.40 o 3 7 1 91.14 69.42 1.70 o 5 7 1 35.42 30.02 0.94 o 7 7 1 4.44 4.21 0.85 o 9 7 1 46.06 33.83 1.41 o 11 7 1 394.96 377.49 9.19 o 13 7 1 0.01 0.23 0.66 o -14 8 1 1.68 -0.11 2.06 o -12 8 1 95.65 88.38 3.01 o -10 8 1 4.45 5.44 0.37 o -8 8 1 138.79 141.40 2.81 o -6 8 1 421.59 438.83 8.89 o -4 8 1 9.39 8.37 0.41 o -2 8 1 10.58 28.25 0.80 o 0 8 1 1545.74 1744.05 30.67 o 2 8 1 765.81 837.67 15.92 o 4 8 1 810.13 753.29 39.58 o 6 8 1 100.10 82.64 2.75 o 8 8 1 98.54 103.68 8.89 o 10 8 1 29.88 29.31 1.63 o 12 8 1 47.01 34.19 2.41 o 14 8 1 202.04 217.34 14.35 o -13 9 1 7.51 8.38 4.29 o -11 9 1 147.24 152.84 7.86 o -9 9 1 41.03 47.13 4.33 o -7 9 1 1200.41 1137.20 29.73 o -5 9 1 2500.56 2347.47 105.67 o -3 9 1 693.59 680.66 11.57 o -1 9 1 5.19 9.91 1.72 o 1 9 1 361.21 365.55 12.60 o 3 9 1 606.47 561.12 9.45 o 5 9 1 1363.15 1312.34 28.02 o 7 9 1 82.35 71.81 1.99 o 9 9 1 332.20 346.84 8.34 o 11 9 1 8.64 4.09 1.44 o 13 9 1 15.75 13.84 2.34 o -12 10 1 3.60 4.32 1.97 o -10 10 1 0.00 -0.43 2.64 o -8 10 1 212.84 195.50 4.82 o -6 10 1 1292.69 1377.20 33.75 o -4 10 1 80.35 76.22 1.63 o -2 10 1 207.00 247.64 4.03 o 0 10 1 41.02 63.07 2.38 o 2 10 1 227.52 236.16 4.90 o 4 10 1 503.32 512.06 10.66 o 6 10 1 216.84 211.43 4.82 o 8 10 1 228.25 226.38 5.86 o 10 10 1 228.95 232.26 6.52 o 12 10 1 207.30 221.77 9.97 o -13 11 1 4.39 -0.31 1.51 o -11 11 1 2.53 4.90 1.43 o -9 11 1 33.64 33.50 3.74 o -7 11 1 184.06 185.94 4.24 o -5 11 1 382.19 387.85 14.94 o -3 11 1 46.49 59.62 1.29 o -1 11 1 305.40 346.21 5.57 o 1 11 1 37.06 33.15 0.81 o 3 11 1 97.38 93.40 2.36 o 5 11 1 394.06 403.99 9.12 o 7 11 1 195.62 187.18 5.07 o 9 11 1 150.55 147.17 5.01 o 11 11 1 54.01 49.21 4.67 o -12 12 1 19.40 19.41 2.33 o -10 12 1 7.98 8.28 1.57 o -8 12 1 227.47 240.21 8.69 o -6 12 1 414.75 416.85 8.16 o -4 12 1 5.92 4.24 0.47 o -2 12 1 180.77 181.95 7.45 o 0 12 1 33.49 47.92 1.07 o 2 12 1 56.57 56.11 2.59 o 4 12 1 27.97 28.21 1.32 o 6 12 1 0.79 0.00 1.42 o 8 12 1 2.02 -0.39 1.63 o 10 12 1 0.84 0.56 1.41 o -11 13 1 9.17 6.19 2.98 o -9 13 1 158.81 162.26 6.41 o -7 13 1 75.99 69.60 2.58 o -5 13 1 151.69 141.63 3.47 o -3 13 1 78.82 73.62 1.65 o -1 13 1 3.02 2.21 0.59 o 1 13 1 344.71 362.84 9.12 o 3 13 1 28.56 33.43 0.99 o 5 13 1 7.55 6.99 1.81 o 7 13 1 237.99 210.19 7.57 o 9 13 1 8.12 6.36 1.47 o -10 14 1 13.66 12.74 2.17 o -8 14 1 116.28 115.24 4.60 o -6 14 1 55.82 46.15 2.33 o -4 14 1 40.85 39.47 3.60 o -2 14 1 142.55 127.74 16.52 o 0 14 1 38.06 34.11 6.00 o 2 14 1 4.21 3.31 0.57 o 4 14 1 1.29 0.91 0.97 o 6 14 1 0.84 -1.26 1.57 o 8 14 1 15.83 7.33 1.68 o -9 15 1 1.87 -1.93 2.30 o -7 15 1 470.42 528.92 20.56 o -5 15 1 193.91 231.52 12.47 o -3 15 1 4.86 3.27 0.92 o -1 15 1 216.66 218.89 7.84 o 1 15 1 3.27 0.90 0.95 o 3 15 1 154.79 167.20 9.92 o 5 15 1 371.33 451.72 20.44 o 7 15 1 18.91 19.80 2.23 o -6 16 1 401.85 449.71 38.64 o -4 16 1 10.28 6.41 3.21 o -2 16 1 14.29 16.09 1.47 o 0 16 1 8.78 4.31 1.05 o 2 16 1 20.44 15.49 1.47 o 4 16 1 286.23 320.09 14.38 o 6 16 1 95.47 87.05 4.32 o -3 17 1 147.15 144.79 6.85 o -1 17 1 15.58 17.87 1.74 o 1 17 1 0.85 0.23 1.10 o 3 17 1 0.04 0.76 1.82 o -16 0 2 191.77 195.20 9.53 o -14 0 2 597.35 638.99 21.31 o -10 0 2 424.95 406.90 9.07 o -8 0 2 197.82 222.42 4.63 o -6 0 2 2607.03 2482.46 63.71 o -4 0 2 2359.01 2397.21 58.25 o 4 0 2 1983.16 2077.12 37.81 o 6 0 2 723.55 730.57 12.92 o 8 0 2 45.54 31.40 0.96 o 12 0 2 10.44 15.31 1.42 o 14 0 2 202.62 199.23 9.81 o -17 1 2 1.91 2.34 1.42 o -15 1 2 61.32 74.19 2.62 o -13 1 2 565.06 560.87 12.45 o -11 1 2 2.27 3.47 0.82 o -9 1 2 1.13 0.97 0.99 o -7 1 2 631.37 560.74 20.37 o -5 1 2 387.45 399.44 6.27 o 3 1 2 1065.74 1016.13 13.06 o 5 1 2 190.18 216.19 2.83 o 7 1 2 146.61 152.46 1.97 o 9 1 2 2749.55 2824.36 58.38 o 11 1 2 143.55 144.98 2.77 o 13 1 2 0.26 -0.10 0.89 o 15 1 2 31.52 31.81 2.05 o -16 2 2 0.21 0.97 1.29 o -14 2 2 42.34 44.56 2.34 o -12 2 2 186.07 205.85 4.35 o -10 2 2 1016.74 972.73 16.05 o -8 2 2 42.83 53.37 1.67 o -6 2 2 1188.47 1358.50 20.71 o -4 2 2 3617.75 3418.80 258.45 o -2 2 2 1505.08 1429.37 25.52 o 2 2 2 281.04 320.42 4.57 o 4 2 2 4815.01 5380.33 129.14 o 6 2 2 1.18 0.07 0.36 o 8 2 2 681.42 731.39 10.06 o 10 2 2 315.92 312.87 4.76 o 12 2 2 43.79 45.93 1.70 o 14 2 2 121.95 139.13 4.59 o -15 3 2 179.54 176.80 6.55 o -13 3 2 119.85 127.65 5.68 o -11 3 2 695.06 625.74 14.94 o -9 3 2 257.73 214.44 3.61 o -7 3 2 2947.18 3170.87 65.08 o -5 3 2 3069.52 3188.92 81.63 o -3 3 2 1775.01 1671.31 29.29 o -1 3 2 89.13 87.06 1.61 o 1 3 2 2746.95 2524.80 54.10 o 3 3 2 1691.65 1979.43 34.48 o 5 3 2 6038.67 6691.74 284.44 o 7 3 2 174.79 150.59 4.70 o 9 3 2 35.12 32.23 0.77 o 11 3 2 120.41 120.79 2.47 o 13 3 2 27.34 28.49 1.48 o 15 3 2 80.70 83.95 4.94 o -16 4 2 2.10 2.51 1.53 o -14 4 2 504.21 581.81 17.43 o -12 4 2 326.79 329.74 11.18 o -10 4 2 142.48 143.48 2.71 o -8 4 2 31.90 26.68 0.78 o -6 4 2 3847.89 4115.66 80.48 o -4 4 2 622.43 585.69 9.66 o -2 4 2 49.60 35.98 0.78 o 0 4 2 174.70 171.91 2.99 o 2 4 2 790.91 652.75 12.81 o 4 4 2 5995.03 6136.48 254.37 o 6 4 2 7.22 12.83 0.50 o 8 4 2 93.35 86.72 1.55 o 10 4 2 490.43 517.87 9.62 o 12 4 2 68.50 71.66 2.51 o 14 4 2 0.80 2.23 1.20 o -15 5 2 185.65 210.90 8.89 o -13 5 2 16.10 14.21 1.31 o -11 5 2 291.99 294.36 6.90 o -9 5 2 5.61 3.57 0.78 o -7 5 2 38.81 50.78 0.94 o -5 5 2 15.27 13.40 0.46 o -1 5 2 735.86 631.87 11.07 o 1 5 2 979.66 935.78 16.90 o 3 5 2 58.06 42.56 2.22 o 5 5 2 3.75 6.12 1.65 o 7 5 2 348.07 367.23 5.35 o 9 5 2 13.05 20.40 0.68 o 11 5 2 14.59 11.36 0.96 o 13 5 2 32.03 31.79 3.02 o -16 6 2 0.77 -1.22 2.59 o -14 6 2 13.32 11.46 2.22 o -12 6 2 22.73 20.64 1.72 o -10 6 2 0.02 -0.20 0.50 o -8 6 2 156.99 131.77 2.17 o -6 6 2 0.66 0.88 0.55 o -4 6 2 132.26 140.90 3.44 o -2 6 2 640.43 678.46 12.33 o 0 6 2 384.52 459.96 8.43 o 2 6 2 275.53 261.01 4.52 o 4 6 2 186.89 160.63 3.09 o 6 6 2 344.96 347.49 6.41 o 8 6 2 29.88 29.38 0.67 o 10 6 2 25.24 23.30 3.25 o 12 6 2 12.29 9.37 2.73 o 14 6 2 3.96 2.69 1.91 o -15 7 2 27.15 25.30 2.00 o -13 7 2 11.78 11.33 0.95 o -11 7 2 394.23 349.27 8.43 o -9 7 2 613.83 612.84 12.00 o -7 7 2 481.33 497.20 9.32 o -5 7 2 240.48 220.00 3.99 o -3 7 2 1215.44 1283.22 21.48 o -1 7 2 265.81 298.74 5.54 o 1 7 2 1440.87 1253.62 20.70 o 3 7 2 388.19 401.12 8.48 o 5 7 2 210.56 233.29 4.21 o 7 7 2 77.69 80.70 2.80 o 9 7 2 444.51 427.35 12.35 o 11 7 2 186.89 178.19 5.90 o 13 7 2 66.77 62.62 6.19 o -14 8 2 0.16 1.75 1.28 o -12 8 2 47.23 34.79 1.83 o -10 8 2 52.77 55.00 2.34 o -8 8 2 1434.77 1379.93 33.50 o -6 8 2 198.64 182.02 3.24 o -4 8 2 78.89 105.56 1.75 o -2 8 2 64.59 79.28 1.44 o 0 8 2 241.19 263.07 4.38 o 2 8 2 1219.19 1105.62 21.05 o 4 8 2 267.09 256.39 5.18 o 6 8 2 212.63 225.94 4.65 o 8 8 2 33.28 31.73 1.46 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