#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/01/54/2015486.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2015486_Fobs loop_ _publ_author_name 'Batsanov, Andrei S.' _publ_section_title ; Tetrathiafulvalene revisited ; _journal_coeditor_code GA3012 _journal_issue 8 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first o501 _journal_page_last o504 _journal_volume 62 _journal_year 2006 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90.000 _cell_angle_beta 100.900 _cell_angle_gamma 90.000 _cell_length_a 14.6250 _cell_length_b 3.9090 _cell_length_c 13.8120 _exptl_crystal_F_000 416.00 _reflns_d_resolution_high 0.7332 _[local]_cod_data_source_file ga3012I_90sup4.hkl _[local]_cod_data_source_block I_90 #BEGIN Tags that were not found in dictionaries: _shelx_title ' TTF at 98K in P2(1)/n' _shelx_refln_list_code 4 _shelx_f_calc_maximum 163.48 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 6579.49 6443.33 182.72 o 4 0 0 50.91 64.63 1.38 o 6 0 0 22990.59 22461.10 398.71 o 8 0 0 5580.02 5463.86 98.23 o 10 0 0 1819.51 1817.33 34.10 o 12 0 0 197.40 148.90 5.12 o 14 0 0 1088.77 1079.95 42.51 o 16 0 0 545.37 583.23 13.63 o 18 0 0 2937.72 2896.22 78.77 o 1 1 0 1.02 3.84 1.14 o 2 1 0 25155.86 27631.91 517.23 o 3 1 0 0.18 2.44 0.52 o 4 1 0 345.20 385.29 5.85 o 5 1 0 98.50 106.44 2.06 o 6 1 0 38.49 35.73 1.12 o 7 1 0 35.37 40.94 1.07 o 8 1 0 11226.08 11224.22 168.15 o 9 1 0 3.27 1.36 1.88 o 10 1 0 4434.74 4145.38 53.37 o 11 1 0 54.49 62.88 3.08 o 12 1 0 29.88 33.30 5.25 o 13 1 0 154.71 170.28 6.24 o 14 1 0 910.44 988.12 15.44 o 15 1 0 41.43 43.43 6.40 o 16 1 0 3549.31 3562.28 47.22 o 17 1 0 0.19 -0.74 5.23 o 18 1 0 3.72 10.99 5.72 o 19 1 0 53.46 43.11 8.09 o 0 2 0 8525.30 8713.43 109.97 o 1 2 0 0.00 0.77 0.87 o 2 2 0 1203.59 1155.46 16.77 o 3 2 0 94.40 96.59 2.69 o 4 2 0 269.01 234.18 2.67 o 5 2 0 59.73 61.25 1.31 o 6 2 0 3443.59 3461.87 39.47 o 7 2 0 0.02 0.44 1.44 o 8 2 0 1315.26 1226.35 13.59 o 9 2 0 22.80 28.31 1.47 o 10 2 0 28.74 25.99 2.20 o 11 2 0 68.73 72.97 4.96 o 12 2 0 39.13 47.10 2.80 o 13 2 0 0.27 -1.23 1.84 o 14 2 0 394.79 408.18 9.28 o 15 2 0 142.38 147.65 5.91 o 16 2 0 0.57 -6.34 4.23 o 17 2 0 8.58 10.08 4.07 o 18 2 0 334.14 327.58 10.26 o 1 3 0 0.25 1.67 1.92 o 2 3 0 141.11 141.56 2.44 o 3 3 0 0.68 1.61 0.88 o 4 3 0 126.40 113.12 2.16 o 5 3 0 85.31 86.29 3.04 o 6 3 0 352.89 356.61 5.01 o 7 3 0 60.56 63.96 2.96 o 8 3 0 2.61 0.32 1.27 o 9 3 0 53.66 53.83 4.07 o 10 3 0 123.37 125.38 4.24 o 11 3 0 155.26 162.58 9.09 o 12 3 0 598.63 637.74 12.13 o 13 3 0 398.13 404.94 9.00 o 14 3 0 202.46 225.71 6.48 o 15 3 0 192.49 179.66 9.05 o 16 3 0 134.11 127.80 9.06 o 0 4 0 615.47 651.18 11.82 o 1 4 0 2.48 0.81 2.58 o 2 4 0 700.46 699.63 8.19 o 3 4 0 39.45 38.96 2.41 o 4 4 0 1964.15 1896.36 21.25 o 5 4 0 30.77 27.33 3.42 o 6 4 0 110.33 118.76 3.94 o 7 4 0 24.95 23.82 2.02 o 8 4 0 15.77 20.96 3.68 o 9 4 0 44.88 43.96 3.28 o 10 4 0 873.68 869.98 12.28 o 11 4 0 29.28 23.98 3.92 o 12 4 0 68.12 76.43 3.79 o 1 5 0 0.14 -3.20 2.55 o 2 5 0 1153.98 1161.91 17.66 o 3 5 0 5.68 1.01 3.31 o 4 5 0 701.17 677.89 10.25 o 5 5 0 14.19 12.81 2.64 o 6 5 0 808.28 824.40 14.76 o -19 0 1 838.60 851.11 21.88 o -17 0 1 632.52 652.48 15.21 o -15 0 1 37.62 29.87 2.70 o -13 0 1 345.90 345.45 9.08 o -11 0 1 284.42 269.95 6.98 o -9 0 1 3.93 4.46 1.49 o -7 0 1 48.54 59.37 3.62 o -5 0 1 122.50 133.14 3.93 o -3 0 1 11.08 19.25 1.65 o -1 0 1 0.25 6.28 0.61 o 1 0 1 2.33 17.16 1.61 o 3 0 1 66.67 69.24 1.54 o 5 0 1 619.26 620.69 10.13 o 7 0 1 868.62 879.98 15.57 o 9 0 1 350.16 354.25 8.06 o 11 0 1 558.29 535.67 11.73 o 13 0 1 290.23 297.68 11.79 o 15 0 1 91.55 89.28 4.47 o 17 0 1 80.91 88.53 7.04 o 19 0 1 10.28 11.06 4.42 o -19 1 1 0.54 -1.59 6.88 o -18 1 1 379.43 389.33 8.95 o -17 1 1 447.51 446.61 9.58 o -16 1 1 430.46 467.87 8.49 o -15 1 1 280.94 295.54 7.65 o -14 1 1 927.13 917.45 12.12 o -13 1 1 152.41 163.36 4.41 o -12 1 1 3.11 5.76 2.22 o -11 1 1 721.94 704.69 9.29 o -10 1 1 733.85 678.82 10.24 o -9 1 1 694.65 654.57 7.61 o -8 1 1 1245.94 1195.69 12.01 o -7 1 1 489.24 486.45 5.24 o -6 1 1 3656.58 3897.24 37.42 o -5 1 1 157.94 157.21 2.17 o -4 1 1 247.68 330.04 5.58 o -3 1 1 36.45 38.97 1.54 o -2 1 1 373.45 410.93 4.59 o -1 1 1 119.74 128.20 2.01 o 0 1 1 6542.25 7051.18 129.14 o 1 1 1 0.05 3.18 0.62 o 2 1 1 3621.81 3828.75 42.28 o 3 1 1 36.45 39.71 1.66 o 4 1 1 1266.85 1233.65 16.05 o 5 1 1 33.01 41.51 1.25 o 6 1 1 343.37 311.53 4.23 o 7 1 1 63.04 62.53 1.51 o 8 1 1 147.25 146.51 2.57 o 9 1 1 91.15 91.78 3.04 o 10 1 1 2095.09 1980.73 26.33 o 11 1 1 153.49 147.38 3.42 o 12 1 1 206.07 226.93 4.59 o 13 1 1 486.83 481.31 12.91 o 14 1 1 3.47 -0.64 4.51 o 15 1 1 358.41 360.40 16.85 o 16 1 1 732.93 738.94 13.73 o 17 1 1 517.16 539.98 11.02 o 18 1 1 284.92 286.74 9.39 o 19 1 1 520.68 513.79 13.54 o -18 2 1 466.73 470.67 10.66 o -17 2 1 308.04 311.59 28.01 o -16 2 1 2136.39 2125.42 38.60 o -15 2 1 77.83 77.04 6.92 o -14 2 1 723.62 802.42 17.84 o -13 2 1 129.56 130.59 5.26 o -12 2 1 1494.30 1445.52 23.43 o -11 2 1 52.56 42.45 3.92 o -10 2 1 1018.75 986.52 12.46 o -9 2 1 0.38 -0.35 1.44 o -8 2 1 3329.64 3280.70 34.61 o -7 2 1 7.60 8.69 1.29 o -6 2 1 948.06 852.29 12.99 o -5 2 1 43.75 45.64 1.24 o -4 2 1 1368.60 1304.67 16.10 o -3 2 1 6.37 4.24 0.57 o -2 2 1 220.70 215.03 3.50 o -1 2 1 2.75 0.74 1.31 o 0 2 1 6.34 6.11 1.47 o 1 2 1 0.13 0.02 1.02 o 2 2 1 10519.41 10860.82 111.76 o 3 2 1 55.45 54.83 1.53 o 4 2 1 1685.34 1840.64 31.81 o 5 2 1 186.02 185.69 2.57 o 6 2 1 38.31 27.21 2.82 o 7 2 1 212.58 209.52 4.19 o 8 2 1 5868.73 5683.02 64.89 o 9 2 1 198.24 184.63 3.83 o 10 2 1 1441.70 1425.17 19.60 o 11 2 1 298.90 302.60 13.31 o 12 2 1 517.16 521.91 12.28 o 13 2 1 144.27 151.44 9.66 o 14 2 1 571.07 581.73 11.31 o 15 2 1 63.21 61.39 3.75 o 16 2 1 321.52 325.36 7.95 o 17 2 1 43.87 39.08 5.46 o -16 3 1 115.81 117.76 5.36 o -15 3 1 122.62 115.49 7.87 o -14 3 1 3500.47 3376.08 52.28 o -13 3 1 173.25 167.20 5.76 o -12 3 1 335.48 351.52 8.59 o -11 3 1 160.40 161.13 9.05 o -10 3 1 337.73 329.89 6.26 o -9 3 1 114.82 119.90 3.36 o -8 3 1 3421.95 3411.27 36.28 o -7 3 1 92.51 92.18 2.37 o -6 3 1 3678.35 3589.57 41.21 o -5 3 1 46.83 45.93 2.13 o -4 3 1 0.04 1.29 1.47 o -3 3 1 15.67 12.76 1.48 o -2 3 1 52.01 48.53 2.75 o -1 3 1 0.78 3.11 1.14 o 0 3 1 3481.71 3368.59 34.33 o 1 3 1 5.65 8.07 1.16 o 2 3 1 485.18 534.23 6.16 o 3 3 1 3.54 4.90 0.94 o 4 3 1 1984.94 1936.47 23.63 o 5 3 1 1.46 1.31 1.87 o 6 3 1 481.00 485.90 8.35 o 7 3 1 1.64 0.86 1.88 o 8 3 1 358.20 367.65 7.53 o 9 3 1 4.02 2.51 1.61 o 10 3 1 2874.98 2885.76 43.23 o 11 3 1 43.84 38.98 2.90 o 12 3 1 80.92 85.33 5.23 o 13 3 1 88.83 91.86 4.15 o 14 3 1 116.02 117.92 9.16 o 15 3 1 96.77 88.11 5.46 o -13 4 1 1.20 -6.48 4.54 o -12 4 1 558.45 519.00 9.63 o -11 4 1 1.10 7.32 2.48 o -10 4 1 118.87 116.38 7.79 o -9 4 1 0.30 2.34 2.79 o -8 4 1 87.58 95.12 3.59 o -7 4 1 0.33 1.95 1.56 o -6 4 1 1205.76 1235.62 15.99 o -5 4 1 0.70 -0.85 1.90 o -4 4 1 980.30 999.88 12.05 o -3 4 1 6.15 5.53 2.15 o -2 4 1 66.64 67.71 3.29 o -1 4 1 4.72 4.05 2.13 o 0 4 1 347.92 337.75 5.12 o 1 4 1 1.49 1.56 1.52 o 2 4 1 2789.15 2746.60 29.93 o 3 4 1 18.96 22.88 1.79 o 4 4 1 466.70 471.31 6.66 o 5 4 1 8.46 11.47 3.54 o 6 4 1 14.42 13.88 1.83 o 7 4 1 7.12 -0.94 1.49 o 8 4 1 1751.54 1764.57 22.12 o 9 4 1 44.65 40.64 2.84 o 10 4 1 467.35 482.66 11.51 o 11 4 1 33.92 33.58 4.18 o 12 4 1 77.77 65.71 3.73 o -6 5 1 436.85 434.34 8.47 o -5 5 1 3.41 -2.67 3.02 o -4 5 1 265.78 266.43 7.04 o -3 5 1 3.26 -2.58 2.05 o -2 5 1 242.31 232.03 5.88 o -1 5 1 1.47 -1.33 5.67 o 0 5 1 217.47 219.69 6.86 o 1 5 1 2.33 3.18 2.64 o 2 5 1 68.17 74.60 3.19 o 3 5 1 0.05 -3.22 2.45 o 4 5 1 49.67 49.80 2.61 o 5 5 1 2.39 -5.48 3.66 o 6 5 1 3.68 3.39 4.14 o -18 0 2 82.50 71.54 4.38 o -16 0 2 27.46 30.10 2.79 o -14 0 2 3554.10 3532.73 65.47 o -12 0 2 1453.94 1526.57 29.42 o -10 0 2 245.62 275.10 7.26 o -8 0 2 5879.16 5819.07 104.56 o -6 0 2 9179.92 9139.90 165.78 o -4 0 2 3366.88 3209.23 48.81 o -2 0 2 5510.27 5700.73 87.56 o 0 0 2 6915.88 7360.32 279.77 o 2 0 2 14030.75 14493.86 481.56 o 4 0 2 5277.45 5072.76 77.07 o 6 0 2 256.47 242.97 4.34 o 8 0 2 2884.93 3065.83 51.79 o 10 0 2 12995.49 12759.86 228.05 o 12 0 2 2904.40 2769.07 51.61 o 14 0 2 97.53 78.09 6.74 o 16 0 2 3460.59 3448.26 91.95 o 18 0 2 2001.08 2029.15 57.47 o -19 1 2 5.06 5.66 3.72 o -18 1 2 90.62 94.34 7.93 o -17 1 2 11.86 10.39 3.57 o -16 1 2 441.09 449.98 8.30 o -15 1 2 14.03 15.69 2.70 o -14 1 2 7.65 14.36 1.60 o -13 1 2 53.76 52.43 2.72 o -12 1 2 2608.24 2595.45 30.63 o -11 1 2 15.15 16.86 1.40 o -10 1 2 371.75 381.51 5.79 o -9 1 2 3.91 5.92 1.18 o -8 1 2 27.17 52.22 3.57 o -7 1 2 8.02 6.45 1.14 o -6 1 2 12131.96 11934.56 148.18 o -5 1 2 102.41 117.69 1.80 o -4 1 2 8476.96 8321.33 173.49 o -3 1 2 19.52 22.92 1.15 o -2 1 2 56.30 66.52 1.81 o -1 1 2 46.92 53.22 1.28 o 0 1 2 24530.58 27616.02 413.96 o 1 1 2 10.12 12.72 0.89 o 2 1 2 13830.75 14852.12 171.46 o 3 1 2 2.42 4.31 0.92 o 4 1 2 423.47 447.60 6.24 o 5 1 2 54.55 59.84 2.99 o 6 1 2 933.57 1011.96 12.12 o 7 1 2 0.08 0.69 1.16 o 8 1 2 3903.85 3772.47 43.24 o 9 1 2 1.48 0.42 0.79 o 10 1 2 306.97 297.62 5.17 o 11 1 2 20.48 20.33 2.26 o 12 1 2 2294.06 2124.60 83.97 o 13 1 2 0.00 1.48 2.24 o 14 1 2 1.28 0.09 2.06 o 15 1 2 122.98 140.87 4.86 o 16 1 2 317.14 294.79 7.25 o 17 1 2 14.59 19.12 2.98 o 18 1 2 2154.22 2176.31 38.58 o -18 2 2 152.19 142.40 4.62 o -17 2 2 11.53 8.65 6.87 o -16 2 2 589.37 599.08 11.85 o -15 2 2 332.52 330.97 7.74 o -14 2 2 1791.22 1813.52 32.63 o -13 2 2 190.71 188.26 6.56 o -12 2 2 1137.61 1099.70 15.78 o -11 2 2 3.58 6.55 1.71 o -10 2 2 105.35 76.81 2.29 o -9 2 2 54.22 53.31 2.23 o -8 2 2 1231.55 1234.77 12.62 o -7 2 2 126.44 136.01 3.14 o -6 2 2 915.83 919.17 11.24 o -5 2 2 18.46 18.31 1.01 o -4 2 2 1156.63 1215.11 12.20 o -3 2 2 37.49 38.59 1.50 o -2 2 2 124.22 111.47 1.69 o -1 2 2 2.59 1.38 1.19 o 0 2 2 19.33 23.65 0.82 o 1 2 2 56.49 55.32 1.11 o 2 2 2 3403.16 3401.96 35.57 o 3 2 2 14.53 14.25 0.87 o 4 2 2 2522.72 2454.80 33.86 o 5 2 2 69.68 72.50 1.81 o 6 2 2 727.55 712.97 10.08 o 7 2 2 204.40 213.47 4.75 o 8 2 2 783.82 738.76 12.43 o 9 2 2 29.50 33.31 3.45 o 10 2 2 2197.81 2128.66 35.70 o 11 2 2 63.12 74.07 4.21 o 12 2 2 793.60 818.37 14.48 o 13 2 2 446.22 461.00 9.73 o 14 2 2 0.34 -2.56 7.90 o 15 2 2 143.89 150.36 8.86 o 16 2 2 461.91 487.51 10.81 o 17 2 2 12.07 20.10 3.94 o -16 3 2 27.36 29.10 4.31 o -15 3 2 10.11 6.84 7.16 o -14 3 2 186.78 175.29 5.45 o -13 3 2 164.43 151.14 4.95 o -12 3 2 180.63 193.73 5.57 o -11 3 2 54.82 49.51 4.51 o -10 3 2 857.69 879.90 13.10 o -9 3 2 21.94 19.08 1.66 o -8 3 2 1470.14 1417.22 15.96 o -7 3 2 94.98 92.72 2.91 o -6 3 2 1312.78 1323.11 17.25 o -5 3 2 135.98 137.20 2.91 o -4 3 2 1512.64 1472.60 14.91 o -3 3 2 34.52 36.57 2.61 o -2 3 2 1804.47 1761.14 23.69 o -1 3 2 15.86 14.93 1.51 o 0 3 2 601.44 608.74 7.38 o 1 3 2 7.80 11.03 1.17 o 2 3 2 290.52 278.91 4.05 o 3 3 2 7.37 4.00 1.11 o 4 3 2 402.08 402.44 6.45 o 5 3 2 118.13 122.16 2.98 o 6 3 2 51.56 45.82 2.14 o 7 3 2 0.32 0.39 1.48 o 8 3 2 93.50 91.37 3.09 o 9 3 2 5.08 8.29 1.54 o 10 3 2 3.20 1.41 2.86 o 11 3 2 29.56 21.99 2.66 o 12 3 2 8.00 19.01 9.98 o 13 3 2 0.38 3.15 2.20 o 14 3 2 77.84 81.17 5.19 o 15 3 2 276.89 284.84 15.58 o -13 4 2 194.78 199.51 7.65 o -12 4 2 74.31 72.86 4.04 o -11 4 2 51.59 58.37 3.88 o -10 4 2 823.02 827.17 14.52 o -9 4 2 102.21 103.02 4.32 o -8 4 2 14.39 17.95 3.63 o -7 4 2 32.40 27.57 3.16 o -6 4 2 92.01 89.56 2.82 o -5 4 2 3.34 -0.50 2.54 o -4 4 2 557.14 564.36 6.98 o -3 4 2 4.20 3.53 1.59 o -2 4 2 83.55 90.55 3.76 o -1 4 2 0.77 2.37 1.39 o 0 4 2 912.86 943.40 12.54 o 1 4 2 7.75 7.98 2.66 o 2 4 2 43.20 35.60 2.95 o 3 4 2 0.08 -0.98 1.80 o 4 4 2 3.67 4.27 2.35 o 5 4 2 54.30 51.89 2.17 o 6 4 2 1111.75 1107.84 14.59 o 7 4 2 140.02 133.99 5.91 o 8 4 2 228.25 241.06 4.99 o 9 4 2 74.55 75.45 3.72 o 10 4 2 103.68 108.82 3.66 o 11 4 2 95.55 88.94 4.84 o 12 4 2 166.09 157.53 9.41 o -6 5 2 386.96 372.09 9.07 o -5 5 2 25.70 21.34 3.98 o -4 5 2 6.46 13.55 3.75 o -3 5 2 11.39 20.29 5.92 o -2 5 2 1059.65 1091.27 16.69 o -1 5 2 1.64 4.50 2.19 o 0 5 2 28.23 25.34 2.39 o 1 5 2 0.11 -4.43 4.28 o 2 5 2 41.73 57.54 5.55 o 3 5 2 11.25 8.34 3.57 o 4 5 2 820.53 785.31 12.71 o 5 5 2 18.63 16.82 3.84 o 6 5 2 240.27 253.98 5.72 o -19 0 3 141.35 143.29 7.40 o -17 0 3 835.82 840.48 15.14 o -15 0 3 276.18 290.55 6.70 o -13 0 3 319.75 334.39 6.87 o -11 0 3 1450.28 1426.19 22.37 o -9 0 3 363.67 363.17 9.09 o -7 0 3 146.94 151.87 2.99 o -5 0 3 574.80 546.08 8.25 o -3 0 3 0.30 4.82 1.28 o -1 0 3 2.34 8.14 0.56 o 1 0 3 81.56 92.83 1.65 o 3 0 3 20.91 31.73 1.45 o 5 0 3 186.35 199.88 3.27 o 7 0 3 211.75 211.20 4.12 o 9 0 3 963.99 944.67 14.89 o 11 0 3 114.39 110.38 10.77 o 13 0 3 206.92 211.93 14.91 o 15 0 3 1178.08 1228.45 36.11 o 17 0 3 907.63 935.26 29.34 o -19 1 3 442.17 448.67 14.87 o -18 1 3 559.38 558.69 11.63 o -17 1 3 195.54 196.41 5.12 o -16 1 3 49.44 45.65 2.09 o -15 1 3 5.05 4.09 2.18 o -14 1 3 581.75 619.42 7.99 o -13 1 3 201.47 204.32 4.40 o -12 1 3 264.38 226.23 4.03 o -11 1 3 0.13 -2.01 2.49 o -10 1 3 658.34 627.43 8.31 o -9 1 3 167.03 164.00 4.29 o -8 1 3 1011.02 1011.40 15.47 o -7 1 3 2.59 2.84 1.09 o -6 1 3 588.26 642.11 7.12 o -5 1 3 138.47 143.14 1.95 o -4 1 3 1698.79 1593.60 24.16 o -3 1 3 144.48 148.10 2.18 o -2 1 3 71.97 61.81 1.36 o -1 1 3 21.84 23.29 1.04 o 0 1 3 6296.31 6711.68 71.13 o 1 1 3 37.55 42.76 0.69 o 2 1 3 1951.78 2073.71 20.11 o 3 1 3 1.03 4.11 1.00 o 4 1 3 4638.00 4809.58 79.47 o 5 1 3 238.05 239.86 3.95 o 6 1 3 581.67 575.53 8.18 o 7 1 3 989.69 975.45 11.88 o 8 1 3 71.24 79.73 3.14 o 9 1 3 112.03 113.08 2.63 o 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