#------------------------------------------------------------------------------ #$Date: 2016-04-02 22:10:25 +0300 (Sat, 02 Apr 2016) $ #$Revision: 180826 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/01/57/2015762.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2015762_Fobs loop_ _publ_author_name 'Costa, Marilia S.' 'Boechat, Nubia' 'Wardell, Solange M. S. V.' 'Ferreira, Vitor F.' 'Low, John N.' 'Glidewell, Christopher' _publ_section_title ; Three ethyl 5-amino-1-aryl-1H-imidazole-4-carboxylates: hydrogen-bonded supramolecular structures in one, two and three dimensions ; _journal_coeditor_code SK3077 _journal_issue 1 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first o33 _journal_page_last o37 _journal_volume 63 _journal_year 2007 _space_group_IT_number 9 _symmetry_space_group_name_Hall 'C -2yc' _symmetry_space_group_name_H-M 'C 1 c 1' _cell_angle_alpha 90.000 _cell_angle_beta 98.810 _cell_angle_gamma 90.000 _cell_length_a 7.9045 _cell_length_b 12.9950 _cell_length_c 11.7737 _exptl_crystal_F_000 552.00 _reflns_d_resolution_high 0.7711 _cod_data_source_file sk3077IIIsup4.hkl _cod_data_source_block III #BEGIN Tags that were not found in dictionaries: _shelx_title ' 0122' _shelx_refln_list_code 4 _shelx_f_calc_maximum 190.72 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' 'x, -y, z+1/2' 'x+1/2, y+1/2, z' 'x+1/2, -y+1/2, z+1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 644.90 612.33 14.46 o 4 0 0 1602.43 1470.11 31.79 o 6 0 0 796.78 831.19 28.92 o 8 0 0 67.26 65.11 9.92 o 10 0 0 60.77 71.69 37.68 o 1 1 0 8378.99 7213.54 120.25 o 3 1 0 3438.33 3288.87 50.76 o 5 1 0 1711.44 1750.21 28.58 o 7 1 0 212.60 236.79 12.06 o 9 1 0 88.66 63.69 10.41 o 2 2 0 6643.18 6189.72 83.15 o 4 2 0 134.71 128.92 4.13 o 6 2 0 500.98 514.00 11.00 o 8 2 0 201.55 196.59 9.95 o 10 2 0 180.39 166.13 25.12 o 1 3 0 4413.96 3941.38 44.46 o 3 3 0 1681.95 1634.34 34.05 o 5 3 0 217.76 228.42 6.82 o 7 3 0 138.13 148.70 6.50 o 9 3 0 54.34 50.68 23.36 o 0 4 0 468.25 437.30 8.61 o 2 4 0 1844.74 1694.64 22.62 o 4 4 0 971.26 962.03 18.68 o 6 4 0 398.57 406.13 10.31 o 8 4 0 53.15 50.75 5.18 o 1 5 0 433.03 400.96 6.88 o 3 5 0 146.88 153.16 4.14 o 5 5 0 195.07 171.31 6.42 o 7 5 0 175.82 181.27 9.24 o 9 5 0 76.71 46.90 16.54 o 0 6 0 2853.85 2860.75 47.34 o 2 6 0 515.71 540.09 8.96 o 4 6 0 611.86 588.34 12.96 o 6 6 0 130.04 136.84 8.20 o 8 6 0 143.49 131.71 10.67 o 1 7 0 1356.03 1498.80 19.20 o 3 7 0 255.08 265.50 6.41 o 5 7 0 287.40 295.61 9.99 o 7 7 0 67.60 73.20 11.92 o 9 7 0 49.88 59.76 14.42 o 0 8 0 1192.09 1326.28 25.32 o 2 8 0 351.81 349.78 6.82 o 4 8 0 161.28 162.42 5.60 o 6 8 0 65.89 79.90 8.46 o 8 8 0 19.06 25.32 12.82 o 1 9 0 592.92 599.46 10.40 o 3 9 0 958.26 990.04 16.64 o 5 9 0 316.86 330.27 10.64 o 7 9 0 26.74 12.85 8.57 o 0 10 0 46.87 63.98 6.13 o 2 10 0 1193.64 1188.13 19.39 o 4 10 0 88.60 76.19 5.04 o 6 10 0 267.91 295.04 14.62 o 8 10 0 86.24 57.46 21.77 o 1 11 0 179.69 187.23 6.60 o 3 11 0 630.46 646.30 13.64 o 5 11 0 169.91 175.60 9.79 o 7 11 0 40.21 40.82 12.29 o 0 12 0 8.42 -2.37 4.88 o 2 12 0 195.78 202.46 7.66 o 4 12 0 19.27 10.96 5.16 o 6 12 0 145.27 137.75 16.36 o 1 13 0 848.89 905.70 22.12 o 3 13 0 35.35 32.70 8.38 o 5 13 0 33.80 20.30 11.21 o 0 14 0 1057.73 1052.59 41.45 o 2 14 0 133.29 130.08 10.43 o 4 14 0 130.57 123.17 16.72 o 1 15 0 460.62 480.04 24.88 o 3 15 0 14.73 18.08 13.80 o 0 16 0 1.04 1.64 16.89 o 2 16 0 30.45 22.98 9.60 o -9 1 1 18.10 5.99 13.19 o -7 1 1 354.56 374.02 12.67 o -5 1 1 35.26 39.75 4.05 o -3 1 1 2398.91 2292.99 36.77 o -1 1 1 146.98 134.88 3.78 o 1 1 1 1045.01 986.16 22.75 o 3 1 1 459.94 467.66 11.04 o 5 1 1 2105.21 2185.86 32.39 o 7 1 1 23.88 20.51 4.04 o 9 1 1 146.59 157.93 19.72 o -10 2 1 15.79 -11.03 27.57 o -8 2 1 348.38 347.98 14.60 o -6 2 1 143.84 135.90 7.06 o -4 2 1 224.60 239.79 6.17 o -2 2 1 36372.37 32183.63 388.09 o 0 2 1 9466.20 8393.94 220.12 o 2 2 1 867.06 781.84 11.76 o 4 2 1 647.14 658.50 15.16 o 6 2 1 14.10 10.16 2.79 o 8 2 1 179.54 178.04 8.00 o -9 3 1 51.19 43.25 17.46 o -7 3 1 45.16 48.50 5.24 o -5 3 1 122.77 133.31 5.27 o -3 3 1 5905.68 5561.64 75.25 o -1 3 1 4994.26 4304.27 59.57 o 1 3 1 1576.43 1443.09 17.84 o 3 3 1 3587.90 3439.27 48.03 o 5 3 1 305.40 328.34 7.59 o 7 3 1 18.91 12.66 4.15 o 9 3 1 362.26 335.96 32.95 o -8 4 1 71.61 72.10 6.69 o -6 4 1 514.93 501.34 18.72 o -4 4 1 1159.93 1215.42 20.74 o -2 4 1 1632.09 1713.65 25.65 o 0 4 1 3123.24 2855.44 32.05 o 2 4 1 746.83 738.05 10.30 o 4 4 1 523.12 508.26 10.73 o 6 4 1 718.48 735.21 14.70 o 8 4 1 54.97 48.36 7.14 o -9 5 1 60.95 71.73 17.03 o -7 5 1 57.51 57.07 4.48 o -5 5 1 387.80 385.95 8.58 o -3 5 1 2912.62 2947.83 37.91 o -1 5 1 2879.20 2760.02 33.75 o 1 5 1 1252.67 1237.62 15.73 o 3 5 1 483.58 562.63 9.80 o 5 5 1 422.38 455.83 11.54 o 7 5 1 4.18 11.18 5.13 o 9 5 1 181.13 192.31 16.41 o -8 6 1 6.50 -0.73 9.52 o -6 6 1 626.25 627.44 13.30 o -4 6 1 438.57 441.62 9.08 o -2 6 1 800.30 886.56 13.11 o 0 6 1 389.26 434.18 7.44 o 2 6 1 54.56 51.82 2.50 o 4 6 1 206.38 214.39 6.51 o 6 6 1 197.70 214.17 9.14 o 8 6 1 120.57 84.02 9.42 o -9 7 1 14.98 46.12 27.57 o -7 7 1 227.37 235.05 12.74 o -5 7 1 1341.56 1372.84 27.55 o -3 7 1 1035.12 1096.85 16.83 o -1 7 1 435.99 441.98 7.55 o 1 7 1 806.22 840.21 12.24 o 3 7 1 19.99 21.30 2.34 o 5 7 1 551.80 552.50 15.08 o 7 7 1 360.45 380.66 15.84 o 9 7 1 16.36 21.31 15.01 o -8 8 1 35.69 10.65 15.04 o -6 8 1 27.19 23.50 6.16 o -4 8 1 491.62 470.53 10.97 o -2 8 1 345.35 361.03 7.61 o 0 8 1 12.77 13.17 2.49 o 2 8 1 264.97 258.97 5.92 o 4 8 1 259.41 256.79 7.52 o 6 8 1 113.24 107.95 8.52 o 8 8 1 59.91 49.13 11.14 o -7 9 1 125.91 91.27 15.45 o -5 9 1 571.15 585.60 13.60 o -3 9 1 315.55 349.42 9.15 o -1 9 1 320.22 273.21 6.73 o 1 9 1 523.58 541.55 9.87 o 3 9 1 1596.20 1586.11 25.53 o 5 9 1 76.83 68.37 5.37 o 7 9 1 47.88 39.73 8.83 o -8 10 1 17.98 8.24 14.57 o -6 10 1 88.92 83.72 9.56 o -4 10 1 387.32 400.75 11.18 o -2 10 1 864.26 867.73 15.28 o 0 10 1 100.71 110.86 4.97 o 2 10 1 207.15 190.56 6.00 o 4 10 1 576.73 598.35 14.67 o 6 10 1 20.91 20.76 8.08 o 8 10 1 106.73 102.88 18.20 o -7 11 1 9.06 20.77 13.10 o -5 11 1 245.94 260.63 11.16 o -3 11 1 56.53 45.72 4.17 o -1 11 1 1022.25 1052.62 18.95 o 1 11 1 421.47 422.29 10.32 o 3 11 1 70.71 69.81 4.86 o 5 11 1 61.24 44.20 6.66 o 7 11 1 38.60 21.09 15.14 o -6 12 1 79.65 82.98 17.59 o -4 12 1 6.89 -4.58 7.74 o -2 12 1 789.81 796.04 16.58 o 0 12 1 573.00 582.39 13.41 o 2 12 1 358.77 363.33 9.91 o 4 12 1 436.49 449.83 17.82 o 6 12 1 534.24 611.25 30.12 o -5 13 1 58.42 60.69 14.41 o -3 13 1 13.28 7.47 6.01 o -1 13 1 56.48 52.21 6.65 o 1 13 1 151.75 139.88 7.81 o 3 13 1 250.64 224.83 10.05 o 5 13 1 25.74 8.56 13.21 o -4 14 1 22.80 33.72 11.26 o -2 14 1 109.34 98.58 11.14 o 0 14 1 27.85 17.78 7.62 o 2 14 1 134.08 140.00 10.01 o 4 14 1 101.96 104.05 13.03 o -3 15 1 369.67 344.50 20.33 o -1 15 1 28.53 11.58 9.25 o 1 15 1 321.55 338.24 20.96 o 3 15 1 6.34 22.87 13.42 o -2 16 1 137.34 145.05 25.09 o 0 16 1 26.47 17.68 9.26 o 2 16 1 12.11 24.94 14.32 o -10 0 2 31.90 53.31 41.36 o -8 0 2 163.28 164.24 14.05 o -6 0 2 788.99 843.14 46.28 o -4 0 2 364.18 364.61 12.88 o -2 0 2 34831.58 31660.26 1113.85 o 2 0 2 5407.23 4901.02 88.35 o 4 0 2 340.92 349.97 10.32 o 6 0 2 747.61 775.46 21.39 o 8 0 2 597.72 655.85 27.35 o -9 1 2 126.39 124.41 14.59 o -7 1 2 266.90 272.21 9.47 o -5 1 2 801.32 845.87 18.85 o -3 1 2 685.91 582.01 11.01 o 1 1 2 1645.56 1512.31 28.82 o 3 1 2 352.32 342.74 6.34 o 5 1 2 0.66 3.22 2.06 o 7 1 2 171.05 185.08 7.91 o 9 1 2 105.51 94.59 15.40 o -10 2 2 20.68 3.96 14.92 o -8 2 2 136.96 135.02 8.78 o -6 2 2 521.33 543.63 16.34 o -4 2 2 857.39 873.49 19.10 o -2 2 2 15247.68 14085.06 277.06 o 0 2 2 433.91 392.13 5.96 o 2 2 2 2948.65 2748.90 33.66 o 4 2 2 550.15 539.59 9.83 o 6 2 2 50.32 45.63 3.47 o 8 2 2 226.11 206.70 8.11 o -9 3 2 1.28 -6.22 12.55 o -7 3 2 25.55 23.94 4.43 o -5 3 2 7.96 5.46 3.35 o -3 3 2 579.91 554.88 9.47 o -1 3 2 3538.43 3222.34 36.77 o 1 3 2 751.68 725.55 16.51 o 3 3 2 1672.41 1657.54 48.89 o 5 3 2 59.98 58.85 3.47 o 7 3 2 299.55 302.88 9.46 o 9 3 2 198.24 170.84 16.44 o -8 4 2 72.09 72.38 7.06 o -6 4 2 511.08 523.87 15.25 o -4 4 2 3349.82 3181.11 48.68 o -2 4 2 523.58 485.27 8.32 o 0 4 2 6.66 -0.01 1.32 o 2 4 2 216.52 229.79 4.48 o 4 4 2 1349.95 1448.93 24.25 o 6 4 2 33.96 32.11 5.36 o 8 4 2 3.09 -2.17 6.15 o -9 5 2 102.01 94.09 16.55 o -7 5 2 415.33 427.01 14.35 o -5 5 2 2040.21 2047.00 32.62 o -3 5 2 544.23 495.08 9.42 o -1 5 2 806.39 817.60 12.90 o 1 5 2 1433.95 1486.59 18.27 o 3 5 2 681.65 727.65 11.58 o 5 5 2 757.37 802.36 17.37 o 7 5 2 240.30 228.00 10.49 o 9 5 2 0.22 0.04 10.37 o -8 6 2 67.56 60.45 12.20 o -6 6 2 2.70 1.86 2.89 o -4 6 2 449.92 450.98 12.03 o -2 6 2 377.81 445.99 8.50 o 0 6 2 2587.46 2527.50 29.53 o 2 6 2 2260.34 2354.26 31.49 o 4 6 2 698.39 742.62 14.55 o 6 6 2 19.70 13.77 5.52 o 8 6 2 87.31 70.99 9.92 o -9 7 2 1.42 11.76 14.95 o -7 7 2 97.32 98.89 5.95 o -5 7 2 732.69 779.76 16.76 o -3 7 2 123.20 137.63 5.15 o -1 7 2 1267.56 1333.14 17.87 o 1 7 2 128.82 125.81 3.97 o 3 7 2 220.65 210.71 8.01 o 5 7 2 8.12 6.39 4.27 o 7 7 2 63.53 57.92 8.39 o -8 8 2 172.89 151.18 18.13 o -6 8 2 388.13 410.13 11.39 o -4 8 2 1242.77 1278.76 22.21 o -2 8 2 349.05 356.13 8.04 o 0 8 2 256.33 238.76 5.87 o 2 8 2 503.46 494.11 8.80 o 4 8 2 527.80 570.19 12.54 o 6 8 2 192.56 184.77 10.90 o 8 8 2 120.56 114.53 15.47 o -7 9 2 136.51 146.90 15.74 o -5 9 2 715.38 690.25 17.54 o -3 9 2 490.11 515.28 11.53 o -1 9 2 304.91 318.34 7.36 o 1 9 2 512.01 569.33 10.58 o 3 9 2 611.23 607.39 12.59 o 5 9 2 155.16 137.66 8.13 o 7 9 2 46.89 32.20 8.76 o -8 10 2 19.15 22.45 12.85 o -6 10 2 9.03 9.91 4.71 o -4 10 2 1052.23 1071.56 22.35 o -2 10 2 346.08 350.65 8.76 o 0 10 2 228.30 235.22 7.01 o 2 10 2 338.40 342.50 8.25 o 4 10 2 683.43 677.35 16.13 o 6 10 2 323.46 345.27 16.80 o -7 11 2 43.28 43.61 15.77 o -5 11 2 139.81 118.75 8.77 o -3 11 2 285.20 288.72 9.10 o -1 11 2 4.94 4.81 3.65 o 1 11 2 419.08 429.99 10.30 o 3 11 2 259.01 267.31 8.97 o 5 11 2 211.13 212.49 10.64 o 7 11 2 27.84 -8.81 14.19 o -6 12 2 16.58 8.52 11.24 o -4 12 2 31.11 19.59 7.66 o -2 12 2 122.57 105.57 6.18 o 0 12 2 935.32 987.28 19.63 o 2 12 2 5.38 -2.28 4.11 o 4 12 2 140.96 124.81 11.62 o 6 12 2 159.14 158.96 16.60 o -5 13 2 12.96 18.66 11.68 o -3 13 2 38.53 37.04 7.52 o -1 13 2 402.18 426.19 15.15 o 1 13 2 16.00 14.58 4.97 o 3 13 2 50.20 59.74 7.67 o 5 13 2 148.14 138.98 15.96 o -4 14 2 22.03 24.07 11.76 o -2 14 2 494.44 504.57 20.03 o 0 14 2 8.45 3.42 6.03 o 2 14 2 3.06 11.53 5.81 o 4 14 2 52.33 33.78 14.73 o -3 15 2 81.99 70.46 12.59 o -1 15 2 21.61 22.53 8.12 o 1 15 2 251.27 264.19 15.64 o 3 15 2 30.65 9.53 13.10 o -2 16 2 37.97 20.43 10.24 o 0 16 2 24.43 18.39 12.06 o 2 16 2 285.95 289.63 25.06 o -9 1 3 18.23 9.47 7.96 o -7 1 3 1.84 4.02 4.04 o -5 1 3 212.42 203.72 6.71 o -3 1 3 1629.12 1481.38 25.02 o -1 1 3 3412.29 3342.07 59.46 o 1 1 3 167.17 154.66 3.51 o 3 1 3 403.22 389.89 7.09 o 5 1 3 58.95 57.04 3.26 o 7 1 3 826.76 899.85 18.21 o 9 1 3 21.89 37.27 16.21 o -10 2 3 137.58 135.00 20.15 o -8 2 3 314.93 335.03 14.36 o -6 2 3 21.75 20.39 4.59 o -4 2 3 3872.44 3966.04 67.01 o -2 2 3 1742.25 1665.63 25.09 o 0 2 3 1970.95 1800.04 22.80 o 2 2 3 3687.20 3380.11 42.77 o 4 2 3 1092.10 1124.22 16.48 o 6 2 3 222.54 215.67 6.27 o 8 2 3 294.27 296.57 10.98 o -9 3 3 117.47 94.71 14.63 o -7 3 3 199.12 200.64 9.52 o -5 3 3 482.85 477.84 12.91 o -3 3 3 2518.77 2513.85 36.28 o -1 3 3 3184.66 2962.70 38.94 o 1 3 3 2568.94 2392.37 27.93 o 3 3 3 4000.29 4019.85 48.67 o 5 3 3 635.27 674.39 13.36 o 7 3 3 165.03 178.71 7.65 o 9 3 3 92.89 85.74 12.57 o -8 4 3 170.47 165.83 11.91 o -6 4 3 193.80 187.58 8.47 o -4 4 3 5121.60 5504.76 84.91 o -2 4 3 517.11 535.65 9.98 o 0 4 3 1405.93 1357.29 17.44 o 2 4 3 743.91 800.14 11.49 o 4 4 3 1048.58 1097.96 20.28 o 6 4 3 179.34 193.65 8.07 o 8 4 3 76.69 70.21 7.88 o -9 5 3 105.19 92.48 16.43 o -7 5 3 138.61 117.38 9.16 o -5 5 3 439.87 468.08 14.93 o -3 5 3 207.58 234.95 6.36 o -1 5 3 907.22 941.06 14.19 o 1 5 3 5036.57 4969.22 84.28 o 3 5 3 486.78 484.12 9.23 o 5 5 3 1027.02 1107.24 22.09 o 7 5 3 354.44 358.70 13.25 o 9 5 3 10.64 -11.99 13.42 o -8 6 3 90.28 87.73 9.37 o -6 6 3 1646.73 1733.03 36.01 o -4 6 3 61.14 61.53 4.55 o -2 6 3 984.11 1031.88 15.55 o 0 6 3 797.16 793.24 11.75 o 2 6 3 142.74 136.48 3.87 o 4 6 3 329.27 353.64 11.35 o 6 6 3 201.54 212.09 9.40 o 8 6 3 69.66 66.50 10.99 o -9 7 3 90.58 79.64 18.14 o -7 7 3 2116.81 2284.56 50.24 o -5 7 3 721.16 760.74 17.58 o -3 7 3 1207.63 1211.77 19.84 o -1 7 3 1537.97 1686.21 21.94 o 1 7 3 982.83 1113.43 17.36 o 3 7 3 463.30 498.80 10.02 o 5 7 3 225.18 223.22 8.78 o 7 7 3 123.26 108.29 10.38 o -8 8 3 141.01 139.21 18.42 o -6 8 3 952.04 1002.19 24.56 o -4 8 3 343.83 356.49 9.73 o -2 8 3 95.71 108.81 4.42 o 0 8 3 924.95 980.19 15.78 o 2 8 3 150.68 159.67 5.17 o 4 8 3 159.16 139.96 6.20 o 6 8 3 117.13 121.88 8.93 o 8 8 3 17.96 18.81 12.04 o -7 9 3 134.96 118.12 20.48 o -5 9 3 28.01 22.42 4.62 o -3 9 3 617.66 676.74 14.40 o -1 9 3 833.28 851.59 14.61 o 1 9 3 152.80 164.69 6.16 o 3 9 3 742.91 796.05 14.19 o 5 9 3 24.35 19.88 6.39 o 7 9 3 127.96 127.05 14.41 o -8 10 3 44.61 17.78 16.29 o -6 10 3 22.30 18.44 7.16 o -4 10 3 256.06 246.67 10.23 o -2 10 3 77.23 60.33 4.22 o 0 10 3 34.04 36.45 3.85 o 2 10 3 1301.82 1419.69 30.16 o 4 10 3 852.60 920.91 19.72 o 6 10 3 0.50 -7.23 7.27 o -7 11 3 23.34 25.26 13.60 o -5 11 3 172.87 178.06 11.43 o -3 11 3 610.95 594.99 14.67 o -1 11 3 80.18 71.31 5.52 o 1 11 3 1321.73 1390.09 24.19 o 3 11 3 239.77 229.32 8.19 o 5 11 3 425.90 478.68 19.56 o 7 11 3 20.58 11.86 16.38 o -6 12 3 0.81 -6.02 11.59 o -4 12 3 29.59 31.44 6.69 o -2 12 3 50.10 37.74 4.99 o 0 12 3 602.44 593.12 14.43 o 2 12 3 313.19 328.61 12.90 o 4 12 3 401.09 421.42 16.05 o 6 12 3 226.17 265.37 22.47 o -5 13 3 72.12 61.19 14.96 o -3 13 3 76.09 77.74 8.94 o -1 13 3 82.41 61.53 7.17 o 1 13 3 137.60 127.75 7.88 o 3 13 3 27.75 3.53 6.76 o 5 13 3 28.98 3.02 13.83 o -4 14 3 45.51 47.80 8.44 o -2 14 3 107.00 82.47 9.75 o 0 14 3 349.27 324.47 14.62 o 2 14 3 109.64 96.45 11.22 o 4 14 3 215.55 212.84 18.74 o -3 15 3 48.98 60.76 10.63 o -1 15 3 53.36 54.62 11.92 o 1 15 3 25.56 13.32 9.61 o 3 15 3 310.36 358.53 25.93 o -2 16 3 19.85 25.97 9.90 o 0 16 3 30.04 44.52 10.51 o 2 16 3 7.70 7.40 16.98 o -10 0 4 246.67 266.53 45.95 o -8 0 4 403.04 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