#------------------------------------------------------------------------------ #$Date: 2011-09-16 18:46:08 +0300 (Fri, 16 Sep 2011) $ #$Revision: 26025 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2016117.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2016117_Fobs loop_ _publ_author_name 'Kubicki, Maciej' 'Wagner, Pawe\/l' _publ_section_title ; Two different modes of halogen bonding in two 4-nitroimidazole derivatives ; _journal_coeditor_code SK3142 _journal_issue 8 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first o454 _journal_page_last o457 _journal_volume 63 _journal_year 2007 _space_group_IT_number 62 _symmetry_space_group_name_Hall '-P 2ac 2n' _symmetry_space_group_name_H-M 'P n m a' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 11.6550 _cell_length_b 6.1372 _cell_length_c 8.6994 _exptl_crystal_F_000 328.00 _reflns_d_resolution_high 0.7133 _[local]_cod_data_source_file sk3142IIsup3.hkl _[local]_cod_data_source_block II #BEGIN Tags that were not found in dictionaries: _shelx_title ' pw3 in Pnma' _shelx_refln_list_code 4 _shelx_f_calc_maximum 227.28 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y, z+1/2' '-x, y+1/2, -z' 'x+1/2, -y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, y, -z-1/2' 'x, -y-1/2, z' '-x-1/2, y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 453.47 455.71 5.28 o 4 0 0 928.06 955.76 12.76 o 6 0 0 3759.56 3825.76 146.08 o 8 0 0 892.07 905.31 15.69 o 10 0 0 818.20 794.14 27.36 o 12 0 0 7.10 1.60 8.88 o 14 0 0 151.69 167.30 27.31 o 2 1 0 4451.90 4273.95 25.30 o 4 1 0 474.29 432.21 5.37 o 6 1 0 920.90 1036.64 10.17 o 8 1 0 629.93 586.68 23.30 o 10 1 0 0.76 3.35 5.80 o 12 1 0 392.69 368.97 20.42 o 14 1 0 75.97 55.11 18.18 o 0 2 0 51657.30 48753.38 554.33 o 2 2 0 284.73 272.28 4.35 o 4 2 0 447.09 421.40 8.20 o 6 2 0 2603.92 2675.26 19.12 o 8 2 0 606.95 632.49 13.37 o 10 2 0 688.77 676.50 15.65 o 12 2 0 5.42 6.85 8.29 o 14 2 0 129.05 118.79 18.42 o 2 3 0 2111.06 2103.04 18.25 o 4 3 0 270.33 253.08 5.76 o 6 3 0 316.75 328.50 8.06 o 8 3 0 438.24 451.08 13.38 o 10 3 0 0.36 6.97 5.73 o 12 3 0 307.83 318.76 21.57 o 14 3 0 48.65 28.30 15.81 o 0 4 0 14098.74 14134.01 149.16 o 2 4 0 70.27 67.91 6.09 o 4 4 0 195.80 177.13 11.50 o 6 4 0 1230.21 1290.76 15.60 o 8 4 0 264.10 262.42 13.83 o 10 4 0 447.47 458.35 14.46 o 12 4 0 4.19 10.37 8.40 o 2 5 0 874.65 863.36 15.42 o 4 5 0 123.27 105.99 12.09 o 6 5 0 94.11 98.25 12.28 o 8 5 0 219.67 231.54 14.44 o 10 5 0 0.64 8.66 9.10 o 12 5 0 189.04 175.22 16.54 o 0 6 0 4847.76 4992.71 108.47 o 2 6 0 13.81 19.41 9.17 o 4 6 0 109.43 111.16 11.96 o 6 6 0 533.40 542.46 18.83 o 8 6 0 99.83 91.12 16.52 o 10 6 0 232.65 238.59 15.83 o 2 7 0 394.97 397.83 16.24 o 4 7 0 49.95 50.64 12.08 o 6 7 0 37.89 24.98 9.70 o 8 7 0 85.16 66.02 17.96 o 0 8 0 1893.16 1892.76 50.06 o 2 8 0 6.13 9.76 8.91 o 4 8 0 36.52 36.44 13.01 o 1 0 1 1397.36 1367.18 25.86 o 2 0 1 3544.58 3393.91 43.15 o 3 0 1 873.87 805.59 6.64 o 4 0 1 95.78 98.22 4.21 o 5 0 1 84.11 100.49 4.60 o 6 0 1 559.58 540.24 6.18 o 7 0 1 1182.41 1248.43 8.39 o 8 0 1 266.24 250.12 7.13 o 9 0 1 266.76 263.13 12.36 o 10 0 1 413.17 392.74 18.54 o 11 0 1 8.67 16.90 10.93 o 12 0 1 119.23 119.42 17.59 o 13 0 1 275.31 306.85 20.58 o 14 0 1 0.35 8.83 9.77 o 15 0 1 2.07 7.49 10.56 o 0 1 1 426.01 416.93 3.72 o 1 1 1 575.35 550.93 3.73 o 2 1 1 3279.89 3109.40 21.26 o 3 1 1 220.77 216.13 3.06 o 4 1 1 2556.17 2461.18 16.17 o 5 1 1 1479.36 1473.75 8.65 o 6 1 1 103.42 111.64 3.87 o 7 1 1 57.33 59.06 4.55 o 8 1 1 6.27 6.77 3.52 o 9 1 1 272.04 269.66 9.08 o 10 1 1 972.20 1040.36 14.80 o 11 1 1 2.86 1.48 6.55 o 12 1 1 1.19 7.14 5.92 o 13 1 1 6.84 7.40 7.34 o 14 1 1 121.52 128.82 13.50 o 15 1 1 32.95 44.80 11.58 o 1 2 1 773.06 851.31 5.95 o 2 2 1 2506.91 2443.51 10.90 o 3 2 1 467.78 422.24 5.02 o 4 2 1 85.48 81.74 3.21 o 5 2 1 43.37 44.52 3.30 o 6 2 1 464.03 466.07 5.73 o 7 2 1 863.66 891.19 9.45 o 8 2 1 238.25 239.28 6.35 o 9 2 1 212.87 204.15 7.36 o 10 2 1 365.72 349.42 9.69 o 11 2 1 7.39 10.27 6.23 o 12 2 1 102.57 98.00 11.84 o 13 2 1 236.68 272.79 14.97 o 14 2 1 0.38 7.91 7.38 o 0 3 1 74.10 77.02 4.22 o 1 3 1 68.66 77.89 3.12 o 2 3 1 1202.39 1205.07 6.46 o 3 3 1 129.44 131.50 3.70 o 4 3 1 976.32 970.02 6.10 o 5 3 1 845.88 857.14 7.31 o 6 3 1 68.04 68.75 4.98 o 7 3 1 36.86 45.36 5.27 o 8 3 1 2.07 6.97 3.88 o 9 3 1 193.45 201.54 7.76 o 10 3 1 670.08 722.97 10.94 o 11 3 1 2.03 6.36 4.48 o 12 3 1 0.54 9.02 6.53 o 13 3 1 5.75 6.47 6.97 o 14 3 1 91.23 78.97 14.03 o 1 4 1 222.39 246.99 4.88 o 2 4 1 1004.44 1008.35 6.77 o 3 4 1 191.44 186.11 5.24 o 4 4 1 47.75 48.98 5.34 o 5 4 1 16.96 18.93 5.37 o 6 4 1 231.62 236.52 7.57 o 7 4 1 458.40 460.41 8.86 o 8 4 1 161.78 161.14 9.38 o 9 4 1 114.27 114.91 7.31 o 10 4 1 255.00 256.25 9.71 o 11 4 1 4.80 7.11 4.48 o 12 4 1 62.44 62.82 8.01 o 13 4 1 152.75 155.42 10.97 o 0 5 1 73.23 74.70 8.52 o 1 5 1 12.50 16.50 4.36 o 2 5 1 368.92 391.29 7.22 o 3 5 1 37.43 36.31 5.22 o 4 5 1 395.79 395.25 9.26 o 5 5 1 362.74 361.52 10.88 o 6 5 1 45.36 41.93 6.93 o 7 5 1 20.59 17.05 5.38 o 8 5 1 0.37 8.00 5.69 o 9 5 1 99.79 105.13 9.96 o 10 5 1 364.75 401.81 12.73 o 11 5 1 1.63 8.45 5.59 o 12 5 1 0.01 7.82 6.36 o 1 6 1 83.09 77.72 6.19 o 2 6 1 358.10 369.19 9.19 o 3 6 1 89.51 93.61 8.40 o 4 6 1 17.57 20.24 6.51 o 5 6 1 10.92 13.02 6.16 o 6 6 1 84.96 83.66 8.62 o 7 6 1 217.58 226.79 10.95 o 8 6 1 86.60 90.46 10.82 o 9 6 1 45.57 48.32 8.85 o 10 6 1 156.00 139.89 11.27 o 11 6 1 3.53 9.89 16.49 o 0 7 1 51.46 40.24 10.83 o 1 7 1 11.07 10.29 5.01 o 2 7 1 124.83 130.19 9.16 o 3 7 1 7.84 11.48 5.16 o 4 7 1 162.22 153.36 10.25 o 5 7 1 144.05 137.45 10.32 o 6 7 1 19.72 19.66 6.75 o 7 7 1 13.09 8.85 5.38 o 8 7 1 1.92 8.87 8.12 o 1 8 1 52.09 33.99 10.24 o 2 8 1 131.67 130.49 11.42 o 3 8 1 31.77 26.78 7.02 o 4 8 1 3.83 10.22 10.28 o 0 0 2 31.99 29.16 3.91 o 1 0 2 103.64 102.26 3.08 o 2 0 2 915.33 889.59 6.64 o 3 0 2 427.66 435.02 5.01 o 4 0 2 8.47 5.71 2.61 o 5 0 2 1408.49 1346.11 9.48 o 6 0 2 512.45 568.77 7.43 o 7 0 2 102.74 110.34 6.10 o 8 0 2 520.51 528.80 9.63 o 9 0 2 386.00 369.87 10.78 o 10 0 2 16.32 7.17 7.08 o 11 0 2 1226.86 1265.03 25.59 o 12 0 2 0.02 8.58 9.66 o 13 0 2 5.39 12.39 12.15 o 14 0 2 0.85 8.57 10.55 o 15 0 2 3.97 8.49 11.42 o 1 1 2 2214.84 2028.41 9.81 o 2 1 2 79.09 81.93 2.34 o 3 1 2 6249.61 6367.71 26.97 o 4 1 2 4.08 5.46 1.91 o 5 1 2 268.80 292.46 4.37 o 6 1 2 373.30 412.87 5.19 o 7 1 2 1554.63 1570.17 9.86 o 8 1 2 60.62 56.25 5.22 o 9 1 2 545.51 518.49 8.42 o 10 1 2 27.92 22.30 5.23 o 11 1 2 1.61 11.20 8.35 o 12 1 2 2.31 3.38 6.75 o 13 1 2 185.69 181.62 14.26 o 14 1 2 0.63 4.67 6.91 o 15 1 2 12.57 13.27 12.39 o 0 2 2 9.55 15.12 3.38 o 1 2 2 13.33 18.15 2.47 o 2 2 2 552.20 541.91 4.66 o 3 2 2 192.86 182.43 3.75 o 4 2 2 11.71 7.92 2.33 o 5 2 2 1148.58 1137.39 6.67 o 6 2 2 344.36 377.14 5.95 o 7 2 2 77.55 75.81 5.04 o 8 2 2 392.82 405.93 7.18 o 9 2 2 286.84 264.94 6.92 o 10 2 2 13.94 11.35 5.21 o 11 2 2 1038.16 1039.04 13.74 o 12 2 2 0.01 8.54 6.30 o 13 2 2 4.82 6.36 8.95 o 14 2 2 0.68 9.53 8.27 o 1 3 2 784.54 746.96 5.43 o 2 3 2 14.26 19.51 3.16 o 3 3 2 2599.90 2547.77 13.91 o 4 3 2 4.53 9.33 3.37 o 5 3 2 101.43 88.26 5.39 o 6 3 2 248.53 267.59 6.43 o 7 3 2 915.18 927.41 8.67 o 8 3 2 39.51 36.71 5.10 o 9 3 2 405.10 402.05 7.65 o 10 3 2 22.35 19.40 4.75 o 11 3 2 0.05 5.22 4.21 o 12 3 2 1.10 8.65 6.30 o 13 3 2 140.12 131.76 12.32 o 14 3 2 0.20 6.47 8.68 o 0 4 2 0.93 5.43 3.38 o 1 4 2 3.60 6.41 2.61 o 2 4 2 171.57 172.29 5.13 o 3 4 2 39.53 41.87 4.94 o 4 4 2 2.09 6.84 3.16 o 5 4 2 620.04 630.40 9.61 o 6 4 2 148.55 149.94 7.19 o 7 4 2 46.29 46.16 6.14 o 8 4 2 224.22 223.48 7.98 o 9 4 2 164.77 145.86 8.04 o 10 4 2 8.28 8.23 4.36 o 11 4 2 666.51 677.27 11.39 o 12 4 2 0.01 12.31 5.36 o 13 4 2 2.88 12.53 7.77 o 1 5 2 308.69 308.75 6.40 o 2 5 2 8.30 8.53 3.20 o 3 5 2 974.41 991.56 9.30 o 4 5 2 3.75 8.59 5.27 o 5 5 2 25.84 24.87 5.86 o 6 5 2 135.02 138.35 8.82 o 7 5 2 441.88 453.48 10.72 o 8 5 2 17.20 11.76 5.06 o 9 5 2 235.29 242.31 10.76 o 10 5 2 13.08 14.80 6.42 o 11 5 2 1.26 9.59 5.80 o 12 5 2 0.36 8.92 7.57 o 0 6 2 0.08 8.87 5.61 o 1 6 2 5.72 8.10 4.13 o 2 6 2 48.58 39.92 7.03 o 3 6 2 9.97 11.20 5.76 o 4 6 2 0.21 4.95 3.74 o 5 6 2 266.55 272.22 10.54 o 6 6 2 61.16 51.19 7.27 o 7 6 2 23.45 19.88 5.71 o 8 6 2 122.67 106.01 9.60 o 9 6 2 104.13 90.81 10.83 o 10 6 2 4.07 8.82 7.23 o 11 6 2 353.63 363.36 31.41 o 1 7 2 124.61 131.24 9.24 o 2 7 2 6.60 7.53 5.07 o 3 7 2 349.21 378.21 13.11 o 4 7 2 2.68 8.95 6.07 o 5 7 2 5.70 14.16 7.09 o 6 7 2 75.57 67.32 8.78 o 7 7 2 175.81 180.58 10.26 o 8 7 2 5.86 6.07 10.27 o 0 8 2 1.39 7.70 10.81 o 1 8 2 1.27 9.91 6.97 o 2 8 2 16.27 11.48 5.99 o 3 8 2 4.23 10.83 6.69 o 4 8 2 0.76 8.74 14.55 o 1 0 3 99.50 108.35 3.53 o 2 0 3 622.55 580.55 5.09 o 3 0 3 765.61 757.05 5.76 o 4 0 3 2.21 3.81 2.88 o 5 0 3 220.22 228.00 5.71 o 6 0 3 0.79 3.16 2.75 o 7 0 3 95.39 89.38 6.11 o 8 0 3 121.16 118.78 8.31 o 9 0 3 620.70 652.19 12.65 o 10 0 3 753.01 715.28 15.63 o 11 0 3 1.45 4.65 7.30 o 12 0 3 26.72 26.55 10.47 o 13 0 3 480.90 480.33 32.53 o 14 0 3 66.06 80.80 20.00 o 15 0 3 6.45 6.68 11.92 o 0 1 3 2222.00 2239.06 14.00 o 1 1 3 1072.79 1111.76 4.99 o 2 1 3 0.76 4.10 1.49 o 3 1 3 599.93 614.57 4.64 o 4 1 3 315.15 356.10 3.78 o 5 1 3 54.51 47.74 3.27 o 6 1 3 512.04 479.37 6.16 o 7 1 3 186.66 188.62 6.18 o 8 1 3 207.68 208.03 7.00 o 9 1 3 233.83 230.16 7.80 o 10 1 3 263.51 259.59 7.59 o 11 1 3 1.10 7.61 5.82 o 12 1 3 7.38 11.83 7.31 o 13 1 3 19.60 10.99 7.41 o 14 1 3 67.53 77.73 13.61 o 15 1 3 63.46 64.04 27.45 o 1 2 3 40.91 38.83 3.08 o 2 2 3 432.36 424.87 4.44 o 3 2 3 459.97 459.55 5.76 o 4 2 3 2.95 5.61 2.37 o 5 2 3 166.04 171.24 4.88 o 6 2 3 1.07 5.87 2.77 o 7 2 3 60.16 51.98 4.83 o 8 2 3 98.32 97.60 5.83 o 9 2 3 524.01 533.94 7.93 o 10 2 3 630.77 622.26 10.19 o 11 2 3 1.77 7.17 4.43 o 12 2 3 23.23 34.81 10.78 o 13 2 3 416.30 423.95 15.94 o 14 2 3 58.96 64.99 12.10 o 0 3 3 1023.04 969.84 9.31 o 1 3 3 651.46 645.32 5.48 o 2 3 3 1.33 5.75 2.69 o 3 3 3 321.60 315.70 5.33 o 4 3 3 119.08 135.73 5.60 o 5 3 3 62.91 60.43 5.36 o 6 3 3 310.24 298.38 6.40 o 7 3 3 119.55 119.01 5.52 o 8 3 3 151.80 143.88 6.34 o 9 3 3 160.30 160.52 6.69 o 10 3 3 194.46 193.38 7.73 o 11 3 3 1.67 7.75 4.68 o 12 3 3 3.74 8.97 6.69 o 13 3 3 15.13 15.92 8.18 o 14 3 3 49.56 39.95 22.20 o 1 4 3 17.42 19.91 3.94 o 2 4 3 184.35 182.12 5.14 o 3 4 3 240.42 241.20 5.88 o 4 4 3 3.56 5.36 3.16 o 5 4 3 67.00 61.62 6.70 o 6 4 3 1.83 9.29 4.66 o 7 4 3 24.60 24.07 5.59 o 8 4 3 56.45 51.73 6.77 o 9 4 3 331.03 335.32 9.06 o 10 4 3 407.92 408.31 10.41 o 11 4 3 1.74 6.68 4.86 o 12 4 3 15.29 15.82 6.84 o 13 4 3 274.66 266.05 22.73 o 0 5 3 359.91 349.20 8.35 o 1 5 3 254.67 243.14 5.94 o 2 5 3 2.08 7.95 3.30 o 3 5 3 107.08 108.41 5.60 o 4 5 3 32.69 32.34 5.16 o 5 5 3 26.80 23.48 5.35 o 6 5 3 140.99 143.87 7.90 o 7 5 3 68.02 68.03 7.68 o 8 5 3 91.58 89.29 8.45 o 9 5 3 69.76 72.77 9.25 o 10 5 3 109.02 117.13 10.38 o 11 5 3 1.52 6.81 5.21 o 12 5 3 0.71 9.05 12.86 o 1 6 3 8.16 9.89 4.29 o 2 6 3 60.09 56.67 6.67 o 3 6 3 134.71 132.86 8.15 o 4 6 3 1.82 7.68 4.17 o 5 6 3 18.95 20.43 5.67 o 6 6 3 1.08 8.19 4.92 o 7 6 3 5.28 11.98 5.32 o 8 6 3 24.18 24.92 6.55 o 9 6 3 170.33 159.47 10.54 o 10 6 3 231.99 213.31 16.81 o 11 6 3 1.65 8.91 11.94 o 0 7 3 117.87 116.56 14.83 o 1 7 3 87.71 85.54 8.16 o 2 7 3 1.16 8.40 6.42 o 3 7 3 33.26 33.94 7.51 o 4 7 3 14.61 14.59 6.24 o 5 7 3 4.80 10.15 6.08 o 6 7 3 50.84 52.54 8.45 o 7 7 3 33.83 33.65 9.61 o 8 7 3 48.45 43.45 17.68 o 1 8 3 0.63 8.85 7.38 o 2 8 3 14.73 16.83 8.32 o 3 8 3 55.76 53.20 20.74 o 0 0 4 8916.46 9290.55 121.36 o 1 0 4 33.98 31.12 4.40 o 2 0 4 181.07 176.09 4.52 o 3 0 4 907.97 941.61 8.78 o 4 0 4 1653.56 1581.00 10.72 o 5 0 4 1.51 3.33 3.80 o 6 0 4 1198.92 1165.67 10.93 o 7 0 4 174.89 185.83 8.56 o 8 0 4 371.75 375.94 10.02 o 9 0 4 5.82 3.14 4.01 o 10 0 4 682.04 678.30 13.35 o 11 0 4 43.15 47.49 11.04 o 12 0 4 9.14 17.63 11.12 o 13 0 4 22.12 12.83 9.96 o 14 0 4 35.66 28.35 13.03 o 15 0 4 14.16 11.55 19.81 o 2 1 4 294.73 309.00 4.05 o 3 1 4 1.00 6.51 1.94 o 4 1 4 406.00 430.45 4.31 o 5 1 4 37.55 56.24 4.11 o 6 1 4 1.02 5.51 2.89 o 7 1 4 18.99 14.32 3.87 o 8 1 4 338.07 327.48 7.37 o 9 1 4 85.46 73.84 6.76 o 10 1 4 4.89 7.03 4.40 o 11 1 4 70.20 75.92 7.42 o 12 1 4 172.22 153.61 13.50 o 13 1 4 5.47 12.23 7.34 o 14 1 4 64.97 52.39 14.05 o 0 2 4 5967.59 5957.52 44.70 o 1 2 4 9.95 13.49 2.66 o 2 2 4 123.73 118.61 3.80 o 3 2 4 569.88 601.48 5.11 o 4 2 4 1200.05 1107.17 6.71 o 5 2 4 0.01 4.89 2.34 o 6 2 4 958.32 934.32 8.58 o 7 2 4 141.15 136.94 5.70 o 8 2 4 299.00 297.50 6.58 o 9 2 4 2.59 6.28 3.57 o 10 2 4 576.98 579.51 10.18 o 11 2 4 34.27 32.99 7.13 o 12 2 4 7.95 12.00 6.53 o 13 2 4 19.25 15.44 9.40 o 14 2 4 29.38 27.57 13.17 o 1 3 4 68.37 73.65 4.35 o 2 3 4 225.49 229.86 5.19 o 3 3 4 7.87 10.14 2.94 o 4 3 4 261.69 272.69 6.14 o 5 3 4 32.82 31.58 4.72 o 6 3 4 0.30 7.52 3.45 o 7 3 4 12.51 12.79 4.54 o 8 3 4 252.83 252.99 7.41 o 9 3 4 66.49 60.65 6.91 o 10 3 4 2.04 6.61 4.12 o 11 3 4 48.30 44.99 9.42 o 12 3 4 125.56 127.04 11.05 o 13 3 4 4.32 8.65 9.39 o 0 4 4 2650.35 2692.34 26.60 o 1 4 4 4.39 8.25 3.23 o 2 4 4 56.33 52.53 4.42 o 3 4 4 241.71 249.12 6.54 o 4 4 4 596.87 576.04 7.48 o 5 4 4 0.05 6.07 3.15 o 6 4 4 568.92 580.23 9.24 o 7 4 4 79.72 74.76 6.93 o 8 4 4 177.55 169.55 8.00 o 9 4 4 0.47 7.83 5.29 o 10 4 4 361.83 368.97 12.04 o 11 4 4 18.28 20.25 7.02 o 12 4 4 6.26 10.27 9.59 o 13 4 4 12.17 7.43 15.44 o 1 5 4 23.91 18.91 3.98 o 2 5 4 133.00 123.84 5.95 o 3 5 4 11.13 15.42 4.48 o 4 5 4 132.08 128.51 7.73 o 5 5 4 22.01 20.94 4.87 o 6 5 4 1.09 7.85 4.38 o 7 5 4 3.36 7.91 4.14 o 8 5 4 142.45 140.93 8.01 o 9 5 4 48.14 52.19 8.97 o 10 5 4 0.32 6.49 5.61 o 11 5 4 28.34 25.58 8.49 o 0 6 4 1120.65 1147.94 13.21 o 1 6 4 7.06 8.47 3.52 o 2 6 4 21.20 25.82 5.96 o 3 6 4 112.71 107.01 7.30 o 4 6 4 246.62 248.84 9.30 o 5 6 4 0.40 6.80 4.42 o 6 6 4 281.41 285.90 10.48 o 7 6 4 39.99 36.05 7.25 o 8 6 4 89.27 86.13 10.72 o 9 6 4 0.10 3.99 10.79 o 1 7 4 8.78 10.43 5.49 o 2 7 4 58.74 62.92 8.45 o 3 7 4 13.66 16.34 6.66 o 4 7 4 54.27 49.16 8.30 o 5 7 4 15.22 12.68 5.93 o 6 7 4 0.28 11.59 8.91 o 7 7 4 0.67 7.75 16.31 o 0 8 4 438.54 479.12 37.37 o 1 8 4 6.46 5.18 8.34 o 2 8 4 5.02 9.42 12.18 o 1 0 5 121.07 129.64 5.37 o 2 0 5 2787.39 3055.96 26.06 o 3 0 5 921.45 984.80 8.90 o 4 0 5 7.23 5.34 3.40 o 5 0 5 241.19 239.43 8.41 o 6 0 5 256.34 261.09 8.39 o 7 0 5 292.03 291.44 9.99 o 8 0 5 705.74 699.39 14.24 o 9 0 5 224.79 213.50 10.54 o 10 0 5 0.60 5.29 6.30 o 11 0 5 19.99 18.28 12.01 o 12 0 5 22.57 20.93 12.03 o 13 0 5 158.29 153.46 25.80 o 14 0 5 6.35 6.92 20.52 o 0 1 5 851.04 852.91 8.47 o 1 1 5 13.80 8.15 2.25 o 2 1 5 123.06 118.46 4.15 o 3 1 5 85.73 83.35 4.35 o 4 1 5 1114.33 1180.45 8.28 o 5 1 5 1244.65 1279.24 9.52 o 6 1 5 550.63 570.11 8.24 o 7 1 5 373.63 359.37 8.89 o 8 1 5 143.79 141.61 6.89 o 9 1 5 0.04 6.05 3.70 o 10 1 5 575.16 574.98 11.03 o 11 1 5 132.03 142.32 8.98 o 12 1 5 119.38 109.59 11.87 o 13 1 5 163.97 179.00 20.65 o 14 1 5 92.65 84.48 18.65 o 1 2 5 59.90 72.55 4.63 o 2 2 5 2199.40 2379.65 12.29 o 3 2 5 733.16 750.80 7.14 o 4 2 5 9.13 9.03 3.17 o 5 2 5 195.17 185.36 6.21 o 6 2 5 213.31 220.27 6.58 o 7 2 5 267.15 258.25 6.92 o 8 2 5 605.69 622.67 10.13 o 9 2 5 181.65 181.24 8.03 o 10 2 5 0.49 5.36 4.92 o 11 2 5 17.88 22.67 6.69 o 12 2 5 19.36 10.34 6.43 o 13 2 5 138.35 142.14 16.74 o 14 2 5 6.19 13.27 12.36 o 0 3 5 542.98 539.17 10.58 o 1 3 5 6.34 10.64 3.69 o 2 3 5 77.24 72.34 5.52 o 3 3 5 46.83 46.84 5.20 o 4 3 5 706.65 726.31 10.16 o 5 3 5 763.96 786.74 9.54 o 6 3 5 368.65 362.87 8.55 o 7 3 5 242.46 234.28 7.30 o 8 3 5 107.63 96.65 7.17 o 9 3 5 0.04 6.35 4.15 o 10 3 5 426.44 430.16 10.35 o 11 3 5 99.39 103.88 9.35 o 12 3 5 89.20 83.71 11.26 o 13 3 5 127.40 136.49 20.70 o 1 4 5 11.09 14.30 3.54 o 2 4 5 1206.34 1255.92 8.90 o 3 4 5 386.06 380.65 7.38 o 4 4 5 8.27 12.01 4.78 o 5 4 5 110.23 101.39 8.14 o 6 4 5 115.56 106.72 8.06 o 7 4 5 190.02 190.68 9.44 o 8 4 5 392.94 399.90 11.30 o 9 4 5 102.80 99.52 9.20 o 10 4 5 0.14 6.48 5.60 o 11 4 5 11.13 14.86 7.32 o 12 4 5 11.12 8.69 8.63 o 0 5 5 341.40 345.09 9.64 o 1 5 5 3.49 8.91 3.26 o 2 5 5 39.99 38.62 5.26 o 3 5 5 25.34 28.02 5.57 o 4 5 5 393.60 410.34 10.52 o 5 5 5 387.41 400.55 11.97 o 6 5 5 190.95 185.36 10.64 o 7 5 5 133.38 122.33 9.59 o 8 5 5 65.47 42.73 8.67 o 9 5 5 0.04 9.58 6.11 o 10 5 5 246.77 236.67 11.28 o 1 6 5 1.74 8.23 3.91 o 2 6 5 565.21 580.19 8.69 o 3 6 5 158.35 163.36 8.56 o 4 6 5 3.10 7.38 4.52 o 5 6 5 54.07 47.61 9.07 o 6 6 5 43.75 35.93 7.88 o 7 6 5 105.45 104.44 10.56 o 8 6 5 205.28 199.86 16.97 o 9 6 5 44.04 27.56 13.48 o 0 7 5 171.46 154.78 13.70 o 1 7 5 0.67 7.33 5.28 o 2 7 5 17.12 18.46 6.57 o 3 7 5 12.19 17.60 7.80 o 4 7 5 190.01 170.22 14.94 o 5 7 5 177.30 168.40 14.97 o 6 7 5 76.66 67.06 25.91 o 0 0 6 66.08 46.63 8.25 o 1 0 6 85.29 74.71 6.13 o 2 0 6 208.52 219.14 7.76 o 3 0 6 50.86 51.98 6.30 o 4 0 6 156.75 150.24 9.47 o 5 0 6 364.42 356.61 10.50 o 6 0 6 142.69 129.73 8.68 o 7 0 6 21.34 20.95 7.71 o 8 0 6 233.63 228.49 13.75 o 9 0 6 199.77 221.96 14.84 o 10 0 6 2.92 9.02 8.86 o 11 0 6 50.52 36.90 13.35 o 12 0 6 0.14 7.83 10.74 o 13 0 6 3.55 4.06 11.09 o 1 1 6 684.90 648.75 7.02 o 2 1 6 0.17 6.25 2.87 o 3 1 6 1264.02 1210.18 8.97 o 4 1 6 24.29 29.18 4.77 o 5 1 6 0.48 9.27 4.33 o 6 1 6 515.25 517.48 9.75 o 7 1 6 1548.55 1549.34 14.39 o 8 1 6 32.49 22.85 6.61 o 9 1 6 3.56 8.52 5.80 o 10 1 6 19.40 14.57 6.63 o 11 1 6 126.57 139.46 11.23 o 12 1 6 72.20 97.48 14.92 o 13 1 6 205.56 188.28 30.52 o 0 2 6 36.67 41.83 8.76 o 1 2 6 70.68 66.28 6.60 o 2 2 6 161.11 171.41 7.50 o 3 2 6 40.66 40.58 4.88 o 4 2 6 116.11 118.10 6.53 o 5 2 6 315.80 317.36 8.80 o 6 2 6 114.63 108.76 8.03 o 7 2 6 15.44 13.13 4.26 o 8 2 6 196.41 178.78 9.39 o 9 2 6 169.97 175.87 10.37 o 10 2 6 2.37 5.91 5.79 o 11 2 6 42.90 37.10 9.16 o 12 2 6 0.13 12.77 7.82 o 13 2 6 3.05 8.20 10.84 o 1 3 6 412.26 398.31 10.82 o 2 3 6 0.82 10.09 6.30 o 3 3 6 892.17 847.22 10.75 o 4 3 6 17.70 22.13 5.48 o 5 3 6 0.03 5.70 3.45 o 6 3 6 406.72 409.59 9.25 o 7 3 6 1111.15 1098.80 11.85 o 8 3 6 23.06 15.96 5.45 o 9 3 6 3.10 8.87 5.56 o 10 3 6 13.75 22.31 8.60 o 11 3 6 96.30 107.93 11.00 o 12 3 6 59.36 57.27 14.22 o 13 3 6 154.81 143.69 32.35 o 0 4 6 13.21 18.09 8.19 o 1 4 6 44.59 46.37 6.31 o 2 4 6 86.94 83.79 5.99 o 3 4 6 23.62 23.67 5.32 o 4 4 6 70.14 73.49 6.64 o 5 4 6 218.70 215.23 8.54 o 6 4 6 68.55 65.99 7.37 o 7 4 6 5.07 6.37 4.88 o 8 4 6 134.23 126.89 9.39 o 9 4 6 108.00 116.93 10.00 o 10 4 6 1.44 9.16 5.48 o 11 4 6 26.10 25.49 9.27 o 1 5 6 167.52 165.29 8.37 o 2 5 6 0.42 5.46 4.14 o 3 5 6 486.55 496.49 9.81 o 4 5 6 9.11 15.63 5.47 o 5 5 6 0.08 7.71 5.30 o 6 5 6 259.84 249.56 11.57 o 7 5 6 607.51 627.05 12.40 o 8 5 6 10.40 13.67 5.82 o 9 5 6 3.44 8.38 6.17 o 10 5 6 8.93 11.55 13.02 o 0 6 6 4.25 7.36 6.65 o 1 6 6 18.81 20.29 6.15 o 2 6 6 43.71 40.92 7.41 o 3 6 6 14.36 9.03 4.93 o 4 6 6 41.03 43.45 8.04 o 5 6 6 120.54 120.81 9.78 o 6 6 6 34.87 29.86 7.48 o 7 6 6 0.28 6.24 11.37 o 8 6 6 82.55 87.44 26.99 o 1 7 6 48.57 57.48 11.82 o 2 7 6 0.01 10.49 9.19 o 3 7 6 214.61 216.19 34.83 o 1 0 7 40.35 28.53 6.24 o 2 0 7 197.51 193.86 8.55 o 3 0 7 1379.18 1372.85 12.84 o 4 0 7 24.93 17.91 6.85 o 5 0 7 47.63 46.26 10.62 o 6 0 7 49.46 33.98 7.68 o 7 0 7 3.86 2.97 6.43 o 8 0 7 31.01 23.38 11.53 o 9 0 7 401.28 393.87 22.69 o 10 0 7 0.13 11.28 9.77 o 11 0 7 54.17 36.21 14.16 o 12 0 7 13.70 11.47 12.81 o 13 0 7 241.09 219.86 31.25 o 0 1 7 1191.20 1278.69 13.42 o 1 1 7 1216.79 1204.65 8.97 o 2 1 7 206.74 191.57 6.20 o 3 1 7 31.47 31.44 5.42 o 4 1 7 140.41 126.51 6.75 o 5 1 7 306.95 315.04 8.20 o 6 1 7 224.53 234.40 9.62 o 7 1 7 20.42 22.08 6.39 o 8 1 7 14.00 8.77 6.68 o 9 1 7 72.15 66.54 12.67 o 10 1 7 104.14 113.88 13.39 o 11 1 7 57.72 48.64 11.50 o 12 1 7 32.70 26.83 11.79 o 13 1 7 19.66 10.85 14.80 o 1 2 7 40.04 30.23 6.68 o 2 2 7 145.75 134.92 6.79 o 3 2 7 1141.80 1131.33 11.17 o 4 2 7 21.75 19.76 6.45 o 5 2 7 42.64 36.05 7.41 o 6 2 7 47.91 45.18 8.32 o 7 2 7 3.35 7.85 5.52 o 8 2 7 24.91 21.36 7.94 o 9 2 7 345.09 341.61 13.58 o 10 2 7 0.00 11.25 7.51 o 11 2 7 46.08 41.47 11.12 o 12 2 7 12.04 10.50 8.79 o 0 3 7 848.89 907.57 18.67 o 1 3 7 858.42 875.42 12.98 o 2 3 7 138.92 127.27 9.32 o 3 3 7 22.51 16.45 6.23 o 4 3 7 85.38 77.78 8.26 o 5 3 7 213.40 227.23 13.41 o 6 3 7 158.83 165.30 10.94 o 7 3 7 19.26 19.10 7.50 o 8 3 7 11.82 8.72 7.14 o 9 3 7 52.38 49.65 11.45 o 10 3 7 79.70 68.48 12.27 o 11 3 7 41.49 38.45 14.39 o 12 3 7 24.27 26.06 18.00 o 1 4 7 35.64 30.16 6.47 o 2 4 7 77.86 73.41 8.20 o 3 4 7 698.67 713.56 17.43 o 4 4 7 15.37 12.26 6.10 o 5 4 7 31.47 31.34 7.25 o 6 4 7 38.41 30.48 7.48 o 7 4 7 1.49 6.36 6.14 o 8 4 7 13.95 17.50 7.43 o 9 4 7 223.82 216.73 13.30 o 10 4 7 0.23 7.02 8.51 o 11 4 7 28.78 17.20 15.61 o 0 5 7 457.72 457.54 15.87 o 1 5 7 477.35 476.37 12.46 o 2 5 7 81.23 73.27 9.58 o 3 5 7 11.44 14.75 6.25 o 4 5 7 52.10 47.13 8.04 o 5 5 7 103.96 99.74 11.31 o 6 5 7 82.60 70.66 8.91 o 7 5 7 15.39 12.22 7.34 o 8 5 7 10.53 8.01 9.02 o 1 6 7 22.74 16.44 6.85 o 2 6 7 35.63 32.76 7.41 o 3 6 7 343.24 343.38 13.69 o 4 6 7 10.56 11.08 7.40 o 5 6 7 20.03 13.10 14.15 o 0 0 8 78.37 91.68 12.76 o 1 0 8 79.27 72.75 8.17 o 2 0 8 87.96 88.70 8.24 o 3 0 8 0.79 6.36 5.11 o 4 0 8 933.49 929.77 14.23 o 5 0 8 23.97 24.45 9.32 o 6 0 8 192.14 207.26 12.91 o 7 0 8 41.41 47.08 16.79 o 8 0 8 57.11 29.54 14.55 o 9 0 8 14.18 17.23 11.30 o 10 0 8 322.58 305.48 22.11 o 11 0 8 48.13 49.19 17.94 o 12 0 8 1.23 15.47 20.39 o 1 1 8 453.28 428.24 7.48 o 2 1 8 0.53 5.63 3.39 o 3 1 8 69.23 69.92 7.54 o 4 1 8 21.04 24.09 6.43 o 5 1 8 98.52 82.26 8.24 o 6 1 8 51.00 46.14 8.42 o 7 1 8 4.81 5.32 5.58 o 8 1 8 213.86 208.91 15.54 o 9 1 8 0.72 7.59 6.82 o 10 1 8 11.38 15.36 8.63 o 11 1 8 16.00 18.67 12.76 o 12 1 8 18.89 16.15 17.97 o 0 2 8 68.59 70.72 10.37 o 1 2 8 68.54 65.41 7.15 o 2 2 8 71.47 77.34 8.00 o 3 2 8 1.03 7.63 4.51 o 4 2 8 785.17 773.40 14.56 o 5 2 8 20.51 25.43 8.13 o 6 2 8 167.12 177.75 12.06 o 7 2 8 34.82 34.83 8.64 o 8 2 8 51.44 42.14 9.14 o 9 2 8 11.90 17.37 7.67 o 10 2 8 278.43 270.87 14.77 o 11 2 8 42.65 39.73 15.95 o 1 3 8 315.68 314.15 12.63 o 2 3 8 0.90 5.41 5.52 o 3 3 8 55.76 59.86 9.75 o 4 3 8 12.75 16.11 7.88 o 5 3 8 73.66 65.65 11.16 o 6 3 8 35.16 27.53 9.03 o 7 3 8 2.15 7.94 6.70 o 8 3 8 161.85 165.37 11.97 o 9 3 8 0.44 7.43 6.66 o 10 3 8 7.36 3.34 9.19 o 0 4 8 35.79 32.29 14.44 o 1 4 8 42.51 36.84 7.81 o 2 4 8 38.86 44.49 8.98 o 3 4 8 1.02 4.54 4.78 o 4 4 8 471.15 474.60 14.62 o 5 4 8 16.26 11.89 7.22 o 6 4 8 107.30 95.31 10.67 o 7 4 8 21.93 19.93 8.35 o 8 4 8 35.83 25.59 13.22 o 9 4 8 6.66 13.22 15.84 o 1 5 8 180.26 176.71 11.66 o 2 5 8 1.77 9.68 5.97 o 3 5 8 39.37 27.14 7.30 o 4 5 8 4.12 10.72 7.19 o 5 5 8 44.35 39.44 9.99 o 6 5 8 18.18 19.03 20.60 o 0 6 8 7.61 14.59 14.00 o 1 6 8 19.61 23.03 11.48 o 2 6 8 14.31 18.03 11.17 o 3 6 8 0.58 13.47 16.10 o 1 0 9 265.94 263.50 9.98 o 2 0 9 395.62 422.42 12.47 o 3 0 9 174.25 187.43 10.79 o 4 0 9 114.76 117.62 11.16 o 5 0 9 22.49 14.12 7.33 o 6 0 9 171.57 149.01 19.97 o 7 0 9 85.64 78.84 16.64 o 8 0 9 321.51 323.17 25.08 o 9 0 9 18.13 20.70 13.14 o 10 0 9 1.45 2.32 10.23 o 0 1 9 249.64 259.68 11.09 o 1 1 9 195.02 186.36 7.70 o 2 1 9 3.21 8.76 4.73 o 3 1 9 5.45 11.67 5.39 o 4 1 9 99.04 108.25 8.45 o 5 1 9 132.05 141.52 9.78 o 6 1 9 648.17 689.99 13.93 o 7 1 9 29.01 30.98 8.28 o 8 1 9 0.05 6.53 7.29 o 9 1 9 4.70 8.85 7.13 o 10 1 9 82.32 59.53 14.93 o 1 2 9 236.28 233.06 10.30 o 2 2 9 330.73 361.28 11.29 o 3 2 9 156.90 171.03 11.40 o 4 2 9 101.36 107.63 11.47 o 5 2 9 18.59 11.37 5.93 o 6 2 9 147.83 141.05 12.32 o 7 2 9 75.09 63.69 10.42 o 8 2 9 276.49 280.01 14.47 o 9 2 9 15.74 14.43 15.33 o 0 3 9 176.86 160.22 13.45 o 1 3 9 147.21 139.25 10.53 o 2 3 9 3.66 6.79 5.52 o 3 3 9 3.93 9.57 6.03 o 4 3 9 79.43 81.58 11.43 o 5 3 9 101.23 107.68 12.79 o 6 3 9 487.07 518.14 16.24 o 7 3 9 23.45 25.55 8.43 o 8 3 9 0.14 6.72 8.34 o 1 4 9 164.44 167.91 12.07 o 2 4 9 200.80 201.04 11.37 o 3 4 9 110.17 92.97 11.90 o 4 4 9 70.16 58.95 9.72 o 5 4 9 11.76 14.29 7.98 o 6 4 9 98.12 69.42 17.13 o 0 5 9 84.41 68.24 16.28 o 1 5 9 92.30 85.64 11.25 o 2 5 9 3.15 8.04 7.02 o 3 5 9 2.31 8.35 10.00 o 4 5 9 47.62 38.71 21.72 o 0 0 10 42.59 33.11 13.19 o 1 0 10 177.80 175.34 12.25 o 2 0 10 54.33 49.99 10.19 o 3 0 10 6.63 16.33 9.21 o 4 0 10 160.25 161.10 15.47 o 5 0 10 44.47 44.18 12.71 o 6 0 10 0.06 8.51 11.35 o 7 0 10 0.88 8.09 11.48 o 8 0 10 18.34 16.23 14.60 o 1 1 10 150.92 144.24 9.29 o 2 1 10 61.18 57.28 9.40 o 3 1 10 707.21 741.46 12.82 o 4 1 10 80.27 83.51 11.04 o 5 1 10 51.44 48.13 9.75 o 6 1 10 53.27 62.13 11.63 o 7 1 10 206.39 224.48 16.74 o 8 1 10 0.02 14.07 15.34 o 0 2 10 38.88 39.93 9.82 o 1 2 10 152.57 155.34 9.57 o 2 2 10 45.32 38.36 9.19 o 3 2 10 5.69 6.84 6.61 o 4 2 10 137.63 140.47 11.78 o 5 2 10 36.44 37.90 9.23 o 6 2 10 0.06 4.83 6.36 o 7 2 10 0.55 7.35 8.80 o 1 3 10 110.86 105.10 10.44 o 2 3 10 47.27 38.59 9.42 o 3 3 10 538.21 581.71 14.83 o 4 3 10 59.70 53.55 9.67 o 5 3 10 42.77 43.57 10.51 o 6 3 10 40.37 27.87 12.03 o 0 4 10 28.77 8.10 11.83 o 1 4 10 99.98 101.54 17.40 o 2 4 10 27.23 12.96 9.83 o 3 4 10 3.85 5.85 10.38 o 4 4 10 89.09 56.28 24.84 o 1 0 11 91.64 76.71 18.75 o 2 0 11 12.21 10.71 8.98 o 3 0 11 284.47 269.30 14.43 o 4 0 11 6.61 9.45 12.05 o 5 0 11 38.03 33.98 16.66 o 6 0 11 6.56 6.85 11.70 o 0 1 11 61.67 60.82 11.52 o 1 1 11 301.56 296.53 11.68 o 2 1 11 0.26 7.23 5.73 o 3 1 11 10.43 8.77 6.27 o 4 1 11 30.47 23.44 9.06 o 5 1 11 355.97 375.48 16.39 o 1 2 11 81.27 74.57 12.65 o 2 2 11 10.59 12.35 8.25 o 3 2 11 246.95 238.19 14.81 o 4 2 11 5.64 11.67 10.13 o 0 3 11 51.63 35.38 16.74 o 1 3 11 227.25 234.37 29.18 o 2 3 11 0.68 8.37 10.49 o 3 3 11 7.05 7.52 13.73 o 2 0 12 2.05 12.09 18.29 o