#------------------------------------------------------------------------------ #$Date: 2016-04-02 22:17:49 +0300 (Sat, 02 Apr 2016) $ #$Revision: 180845 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/01/76/2017614.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2017614_Fobs loop_ _publ_author_name 'Guzei, Ilia A.' 'Spencer, Lara C.' 'Ainooson, Michael K.' 'Darkwa, James' _publ_section_title ; Constructor graph description of the hydrogen-bonding supramolecular assembly in two ionic compounds: 2-(pyrazol-1-yl)ethylammonium chloride and diaquadichloridobis(2-hydroxyethylammonium)cobalt(II) dichloride ; _journal_coeditor_code KU3022 _journal_issue 4 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first m89 _journal_page_last m96 _journal_volume 66 _journal_year 2010 _space_group_IT_number 2 _symmetry_space_group_name_Hall '-P 1' _symmetry_space_group_name_H-M 'P -1' _cell_angle_alpha 83.569 _cell_angle_beta 86.367 _cell_angle_gamma 86.195 _cell_length_a 6.2581 _cell_length_b 6.6527 _cell_length_c 8.3686 _exptl_crystal_F_000 185.00 _reflns_d_resolution_high 0.7699 _cod_data_source_file ku3022IIsup3.hkl _cod_data_source_block II #BEGIN Tags that were not found in dictionaries: _shelx_title ' DARKWA100 IN P-1' _shelx_refln_list_code 4 _shelx_f_calc_maximum 69.28 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 1612.08 1539.89 25.89 o 2 0 0 1421.07 1475.46 31.14 o 3 0 0 853.95 884.01 14.24 o 4 0 0 2165.33 2116.13 25.76 o 5 0 0 306.82 309.80 5.09 o 6 0 0 67.14 67.34 1.67 o 7 0 0 137.82 130.88 2.94 o 8 0 0 81.51 84.50 3.13 o -7 1 0 221.75 213.50 8.66 o -6 1 0 424.40 407.00 7.87 o -5 1 0 43.18 45.82 1.04 o -4 1 0 4014.75 3819.55 50.99 o -3 1 0 1305.03 1308.35 17.97 o -2 1 0 363.88 389.15 4.77 o -1 1 0 1056.27 1038.23 17.77 o 0 1 0 1509.88 1528.87 26.66 o 1 1 0 182.84 212.34 2.68 o 2 1 0 1405.70 1433.47 23.54 o 3 1 0 314.04 322.13 4.01 o 4 1 0 2.12 3.31 0.16 o 5 1 0 270.41 272.80 3.86 o 6 1 0 1057.25 1033.67 19.07 o 7 1 0 147.17 144.58 4.56 o 8 1 0 104.01 100.98 3.55 o -7 2 0 150.01 150.62 3.39 o -6 2 0 7.50 7.88 0.49 o -5 2 0 185.88 183.63 3.22 o -4 2 0 13.61 14.83 1.22 o -3 2 0 5.68 8.32 0.45 o -2 2 0 2003.67 2051.30 31.27 o -1 2 0 190.06 205.83 2.57 o 0 2 0 2710.23 2572.34 59.87 o 1 2 0 297.18 298.98 3.68 o 2 2 0 4421.15 4074.34 78.56 o 3 2 0 594.16 572.99 7.00 o 4 2 0 330.44 351.00 4.41 o 5 2 0 54.21 53.99 1.16 o 6 2 0 414.31 415.32 7.98 o 7 2 0 214.15 223.31 6.57 o -7 3 0 9.16 8.83 0.58 o -6 3 0 830.35 837.78 15.71 o -5 3 0 329.77 340.36 5.66 o -4 3 0 720.82 715.10 11.30 o -3 3 0 34.25 33.97 0.63 o -2 3 0 2529.93 2435.74 35.19 o -1 3 0 1175.38 1188.38 15.86 o 0 3 0 161.00 163.09 2.26 o 1 3 0 65.90 76.21 1.04 o 2 3 0 237.41 215.62 2.73 o 3 3 0 375.02 381.12 6.66 o 4 3 0 40.55 44.85 0.99 o 5 3 0 78.48 78.17 1.58 o 6 3 0 81.44 83.48 2.02 o 7 3 0 4.64 5.40 0.69 o -6 4 0 381.19 397.10 7.85 o -5 4 0 390.76 373.22 10.05 o -4 4 0 125.65 125.14 2.32 o -3 4 0 83.10 86.84 1.67 o -2 4 0 168.89 171.94 2.91 o -1 4 0 361.19 375.37 4.69 o 0 4 0 592.20 608.18 7.43 o 1 4 0 452.88 457.25 5.64 o 2 4 0 127.12 134.52 1.96 o 3 4 0 27.96 32.83 0.82 o 4 4 0 656.75 637.07 10.13 o 5 4 0 1200.44 1141.32 45.54 o 6 4 0 15.59 15.93 1.03 o 7 4 0 46.83 47.58 2.07 o -6 5 0 9.87 12.15 1.62 o -5 5 0 34.11 31.99 1.08 o -4 5 0 484.38 489.61 7.99 o -3 5 0 640.59 623.50 9.92 o -2 5 0 28.29 27.13 0.60 o -1 5 0 2.74 3.59 0.24 o 0 5 0 888.70 880.94 11.77 o 1 5 0 2179.75 2115.51 28.28 o 2 5 0 237.37 240.76 4.04 o 3 5 0 13.69 15.76 0.62 o 4 5 0 318.92 322.87 5.39 o 5 5 0 367.67 357.50 9.01 o 6 5 0 52.02 51.82 1.54 o -5 6 0 45.33 49.03 1.72 o -4 6 0 104.93 102.70 2.94 o -3 6 0 847.06 825.80 13.11 o -2 6 0 185.68 190.76 4.28 o -1 6 0 5.47 5.21 0.27 o 0 6 0 266.39 273.34 3.90 o 1 6 0 202.16 207.29 3.59 o 2 6 0 21.72 21.47 0.67 o 3 6 0 286.25 286.91 5.74 o 4 6 0 243.62 241.29 4.96 o 5 6 0 1.22 1.71 0.32 o 6 6 0 21.36 21.57 0.92 o -4 7 0 80.78 81.85 2.12 o -3 7 0 13.40 12.27 0.56 o -2 7 0 0.74 1.75 0.65 o -1 7 0 253.52 260.58 4.47 o 0 7 0 144.45 148.00 2.74 o 1 7 0 76.85 77.88 1.66 o 2 7 0 2.69 3.78 0.75 o 3 7 0 517.98 525.49 10.15 o 4 7 0 180.33 176.48 3.87 o 5 7 0 25.45 25.61 1.38 o -1 8 0 332.40 327.47 10.81 o 0 8 0 141.07 146.50 2.82 o 1 8 0 2.11 2.46 0.37 o 2 8 0 21.21 23.36 0.95 o 3 8 0 39.31 40.66 1.35 o -3 -8 1 33.80 37.51 1.31 o -2 -8 1 750.69 766.12 12.36 o -1 -8 1 36.76 38.30 1.10 o 0 -8 1 201.53 212.36 3.85 o 1 -8 1 46.72 47.85 1.60 o 2 -8 1 349.67 389.94 10.97 o -4 -7 1 98.15 89.61 2.28 o -3 -7 1 84.43 86.60 1.87 o -2 -7 1 501.95 510.91 8.37 o -1 -7 1 66.08 70.06 1.62 o 0 -7 1 19.27 17.82 0.64 o 1 -7 1 73.16 69.82 1.95 o 2 -7 1 38.09 39.74 1.37 o 3 -7 1 99.33 100.59 2.09 o 4 -7 1 334.96 349.98 6.01 o -5 -6 1 82.87 87.15 2.21 o -4 -6 1 308.38 302.37 5.17 o -3 -6 1 221.21 217.81 3.82 o -2 -6 1 9.13 9.51 0.44 o -1 -6 1 103.68 105.29 2.03 o 0 -6 1 1495.00 1441.97 22.40 o 1 -6 1 642.07 664.11 9.04 o 2 -6 1 25.32 25.76 0.74 o 3 -6 1 4.69 4.98 0.45 o 4 -6 1 605.81 604.36 11.44 o 5 -6 1 214.66 226.67 4.12 o -6 -5 1 137.22 133.85 3.60 o -5 -5 1 0.29 0.66 0.79 o -4 -5 1 1396.62 1308.08 37.42 o -3 -5 1 893.03 875.23 13.80 o -2 -5 1 20.85 19.36 0.59 o -1 -5 1 23.58 23.15 0.64 o 0 -5 1 1160.23 1145.72 15.28 o 1 -5 1 410.35 402.29 5.54 o 2 -5 1 3.26 3.76 0.39 o 3 -5 1 145.74 150.39 2.72 o 4 -5 1 196.98 193.48 3.45 o 5 -5 1 12.54 14.73 1.24 o 6 -5 1 198.07 195.28 4.27 o -7 -4 1 261.76 268.93 5.56 o -6 -4 1 4.62 4.92 0.43 o -5 -4 1 18.71 15.71 0.58 o -4 -4 1 376.07 382.44 7.39 o -3 -4 1 173.74 175.42 3.03 o -2 -4 1 31.22 26.77 0.67 o -1 -4 1 257.52 250.35 3.49 o 0 -4 1 9.31 8.84 0.40 o 1 -4 1 34.37 34.79 0.64 o 2 -4 1 505.20 524.94 8.32 o 3 -4 1 1078.39 1072.07 16.72 o 4 -4 1 4.58 4.89 0.42 o 5 -4 1 101.58 100.47 3.14 o 6 -4 1 145.74 146.06 3.63 o -7 -3 1 3.34 3.07 0.58 o -6 -3 1 178.03 176.05 7.28 o -5 -3 1 361.54 365.25 6.00 o -4 -3 1 21.48 20.91 0.60 o -3 -3 1 354.77 385.40 6.18 o -2 -3 1 739.18 707.28 14.52 o -1 -3 1 2078.67 2062.76 29.57 o 0 -3 1 11.15 12.08 0.27 o 1 -3 1 54.05 54.67 0.88 o 2 -3 1 478.01 493.57 6.66 o 3 -3 1 212.05 211.92 3.54 o 4 -3 1 7.97 8.39 0.39 o 5 -3 1 105.02 104.78 2.05 o 6 -3 1 59.79 57.65 1.37 o 7 -3 1 9.33 10.01 0.64 o -7 -2 1 152.36 152.16 4.77 o -6 -2 1 232.99 226.55 4.59 o -5 -2 1 1118.42 1149.54 17.95 o -4 -2 1 68.90 62.48 1.03 o -3 -2 1 30.42 34.66 0.55 o -2 -2 1 1485.93 1535.16 23.99 o -1 -2 1 508.12 517.87 8.09 o 0 -2 1 59.02 58.22 2.11 o 1 -2 1 1218.95 1250.94 20.82 o 2 -2 1 450.91 469.90 6.33 o 4 -2 1 289.31 291.55 4.80 o 5 -2 1 1065.92 1034.16 19.36 o 6 -2 1 353.69 351.49 5.89 o 7 -2 1 16.60 16.77 0.79 o -8 -1 1 54.52 59.82 2.49 o -7 -1 1 65.93 69.99 2.60 o -6 -1 1 408.16 419.66 11.39 o -5 -1 1 193.79 192.22 2.80 o -4 -1 1 219.50 225.14 2.90 o -3 -1 1 1845.87 1873.02 22.72 o -2 -1 1 993.98 1043.83 12.69 o 0 -1 1 1327.39 1250.98 35.40 o 1 -1 1 4695.31 4067.42 170.09 o 2 -1 1 3470.89 3140.43 80.76 o 3 -1 1 311.03 338.61 4.79 o 4 -1 1 12.37 13.09 0.50 o 5 -1 1 545.14 540.76 8.66 o 6 -1 1 529.20 518.66 8.42 o 7 -1 1 48.24 44.06 1.35 o -8 0 1 51.08 50.07 2.17 o -7 0 1 767.87 759.21 20.13 o -6 0 1 356.41 351.39 6.82 o -5 0 1 55.43 56.01 1.67 o -4 0 1 68.35 72.41 1.07 o -3 0 1 2080.43 2039.56 24.81 o -2 0 1 1976.52 1968.74 41.51 o -1 0 1 1648.35 1473.06 45.24 o 0 0 1 334.31 349.12 5.38 o 1 0 1 432.02 475.18 6.53 o 2 0 1 1031.66 1025.02 20.20 o 3 0 1 339.25 337.42 4.18 o 4 0 1 580.65 584.77 7.19 o 5 0 1 112.87 108.52 2.68 o 6 0 1 6.91 7.61 0.51 o 7 0 1 386.36 377.52 7.42 o 8 0 1 726.54 739.45 19.81 o -7 1 1 232.53 239.20 4.95 o -6 1 1 153.53 158.12 3.35 o -5 1 1 103.46 106.62 2.32 o -4 1 1 294.85 299.12 4.30 o -3 1 1 110.39 113.72 1.72 o -2 1 1 8.58 9.24 0.23 o 0 1 1 1087.19 1138.97 19.73 o 1 1 1 88.75 71.83 0.93 o 2 1 1 1392.59 1391.60 23.42 o 3 1 1 665.62 653.64 7.95 o 4 1 1 3170.18 2931.28 35.60 o 5 1 1 0.44 0.64 0.12 o 6 1 1 442.92 440.96 8.43 o 7 1 1 160.11 162.70 5.03 o 8 1 1 296.26 281.01 8.21 o -7 2 1 7.39 7.02 0.50 o -6 2 1 5.99 5.87 0.43 o -5 2 1 233.59 238.22 4.76 o -4 2 1 841.60 869.07 10.62 o -3 2 1 13.83 13.99 0.31 o -2 2 1 1112.34 1208.72 14.71 o -1 2 1 58.35 64.06 0.88 o 1 2 1 289.25 289.33 3.59 o 2 2 1 671.46 752.32 9.14 o 3 2 1 195.69 179.65 2.32 o 4 2 1 192.49 189.44 2.48 o 5 2 1 19.72 19.48 0.60 o 6 2 1 289.14 288.00 8.05 o 7 2 1 44.37 41.75 1.85 o 8 2 1 44.21 45.14 2.07 o -7 3 1 19.04 18.44 1.17 o -6 3 1 116.34 117.57 8.32 o -5 3 1 50.61 51.23 1.64 o -4 3 1 1013.49 1010.65 15.77 o -3 3 1 373.74 370.04 4.64 o -2 3 1 139.63 141.70 1.98 o -1 3 1 713.85 787.52 9.57 o 0 3 1 19.88 23.03 1.21 o 1 3 1 89.42 78.53 1.09 o 2 3 1 2693.17 2581.56 37.37 o 3 3 1 349.26 389.23 4.85 o 4 3 1 403.51 405.50 5.08 o 5 3 1 379.24 386.89 7.42 o 6 3 1 1979.95 2020.31 36.93 o 7 3 1 94.65 94.57 3.28 o -6 4 1 218.11 222.47 5.56 o -5 4 1 379.31 382.89 7.47 o -4 4 1 0.60 1.00 0.20 o -3 4 1 73.47 78.31 1.28 o -2 4 1 2945.74 2881.73 45.15 o -1 4 1 872.32 877.09 10.67 o 0 4 1 671.43 705.55 8.61 o 1 4 1 425.91 451.02 5.57 o 2 4 1 4583.18 4332.52 52.42 o 3 4 1 716.92 732.82 9.44 o 4 4 1 4.86 5.38 0.30 o 5 4 1 89.69 89.77 2.08 o 6 4 1 289.60 292.73 6.62 o 7 4 1 169.17 178.33 5.51 o -6 5 1 862.84 878.45 22.86 o -5 5 1 320.65 323.89 6.46 o -4 5 1 270.68 262.58 8.74 o -3 5 1 18.47 18.00 0.58 o -2 5 1 1371.61 1344.78 17.91 o -1 5 1 600.79 596.00 8.09 o 0 5 1 152.18 163.06 2.39 o 1 5 1 229.74 239.61 3.41 o 2 5 1 34.39 32.74 0.81 o 3 5 1 146.12 144.35 4.29 o 4 5 1 632.14 637.72 12.00 o 5 5 1 159.60 161.95 3.48 o 6 5 1 22.11 21.08 0.84 o -5 6 1 34.79 34.97 1.70 o -4 6 1 188.73 180.49 3.84 o -3 6 1 239.11 237.59 4.12 o -2 6 1 38.97 39.85 0.82 o -1 6 1 0.81 0.97 0.15 o 0 6 1 870.39 897.13 12.08 o 1 6 1 242.94 243.45 4.14 o 2 6 1 212.19 208.80 3.62 o 3 6 1 16.24 12.82 0.58 o 4 6 1 669.59 669.64 12.68 o 5 6 1 483.07 479.24 9.31 o 6 6 1 33.98 32.86 1.18 o -4 7 1 450.78 472.48 13.14 o -3 7 1 246.27 251.02 7.31 o -2 7 1 121.77 117.99 3.76 o -1 7 1 66.23 70.49 1.51 o 0 7 1 299.77 298.51 5.04 o 1 7 1 514.42 541.01 16.66 o 2 7 1 17.29 19.87 1.51 o 3 7 1 5.21 5.64 0.44 o 4 7 1 46.10 44.48 1.36 o 5 7 1 30.63 31.46 1.27 o 0 8 1 31.69 33.11 1.64 o 1 8 1 15.12 15.47 1.11 o 2 8 1 120.83 117.51 4.03 o 3 8 1 314.89 316.03 9.32 o -2 -8 2 28.33 29.49 0.95 o -1 -8 2 87.58 91.06 1.98 o 0 -8 2 103.96 106.88 2.79 o 1 -8 2 49.99 51.57 1.71 o -4 -7 2 83.76 81.18 1.83 o -3 -7 2 265.41 271.00 4.76 o -2 -7 2 232.90 233.45 4.15 o -1 -7 2 7.60 9.02 0.99 o 0 -7 2 2.17 2.90 0.31 o 1 -7 2 441.12 426.65 8.82 o 2 -7 2 950.63 973.08 19.23 o 3 -7 2 12.27 11.26 0.56 o -5 -6 2 4.68 4.53 0.40 o -4 -6 2 51.40 51.06 1.42 o -3 -6 2 270.66 259.43 4.47 o -2 -6 2 1319.06 1240.82 22.79 o -1 -6 2 134.00 138.67 2.57 o 0 -6 2 34.76 33.97 0.87 o 1 -6 2 241.88 238.58 4.39 o 2 -6 2 485.09 486.05 9.83 o 3 -6 2 62.67 62.59 1.43 o 4 -6 2 40.56 39.91 1.09 o 5 -6 2 31.74 32.01 1.01 o -6 -5 2 443.36 430.14 13.64 o -5 -5 2 111.52 98.49 2.01 o -4 -5 2 1.91 2.01 0.25 o -3 -5 2 128.32 126.94 4.33 o -2 -5 2 181.78 171.51 3.01 o -1 -5 2 119.52 116.63 2.13 o 0 -5 2 384.89 375.00 6.09 o 1 -5 2 17.49 17.71 0.93 o 2 -5 2 177.27 164.61 4.77 o 3 -5 2 193.17 196.42 3.45 o 4 -5 2 1092.81 1070.26 16.83 o 5 -5 2 43.42 42.58 1.16 o 6 -5 2 174.26 176.40 3.77 o -7 -4 2 39.89 41.30 1.37 o -6 -4 2 0.57 0.84 0.42 o -5 -4 2 28.72 29.52 0.85 o -4 -4 2 819.17 796.92 12.60 o -3 -4 2 72.63 65.52 1.34 o -2 -4 2 905.28 907.71 14.16 o -1 -4 2 13.12 11.66 0.40 o 0 -4 2 2638.69 2489.30 45.17 o 1 -4 2 303.35 306.05 4.24 o 2 -4 2 399.87 403.08 6.44 o 3 -4 2 12.51 12.15 0.56 o 4 -4 2 572.67 568.12 9.13 o 5 -4 2 98.92 96.75 1.98 o 6 -4 2 5.62 6.62 0.45 o -7 -3 2 201.09 197.53 7.84 o -6 -3 2 452.62 444.29 8.62 o -5 -3 2 2.25 3.74 0.37 o -4 -3 2 1713.05 1612.16 25.01 o -3 -3 2 632.74 631.86 9.94 o -2 -3 2 19.56 17.61 0.49 o -1 -3 2 150.09 146.70 1.90 o 0 -3 2 941.80 941.03 11.67 o 1 -3 2 552.94 549.30 7.84 o 2 -3 2 363.31 357.71 4.89 o 3 -3 2 176.93 186.60 4.22 o 4 -3 2 0.35 1.35 0.52 o 5 -3 2 35.74 32.26 0.88 o 6 -3 2 881.67 866.41 13.82 o 7 -3 2 381.28 390.93 7.85 o -7 -2 2 182.10 183.68 5.62 o -6 -2 2 86.76 81.13 1.97 o -5 -2 2 315.14 304.30 5.06 o -4 -2 2 145.63 150.83 2.64 o -3 -2 2 334.47 356.05 4.84 o -2 -2 2 2786.18 2638.45 62.22 o -1 -2 2 1465.67 1467.61 21.96 o 0 -2 2 372.28 389.95 4.77 o 1 -2 2 32.23 33.07 0.51 o 2 -2 2 4777.96 4293.53 53.29 o 3 -2 2 2531.36 2415.44 53.05 o 4 -2 2 55.89 53.24 1.15 o 5 -2 2 0.74 1.78 0.39 o 6 -2 2 848.20 798.01 12.73 o 7 -2 2 206.52 206.28 3.79 o -7 -1 2 3.66 3.60 0.58 o -6 -1 2 1389.31 1384.84 25.45 o -5 -1 2 1134.68 1135.00 17.72 o -4 -1 2 213.79 214.74 3.55 o -3 -1 2 60.01 63.30 1.00 o -2 -1 2 4116.78 3640.28 58.85 o -1 -1 2 4799.26 4325.53 109.46 o 1 -1 2 91.45 88.20 1.26 o 2 -1 2 2948.16 2725.37 60.06 o 3 -1 2 497.53 495.70 9.39 o 4 -1 2 83.97 81.34 1.56 o 5 -1 2 422.63 421.92 6.86 o 6 -1 2 35.23 32.68 0.90 o 7 -1 2 0.28 0.99 0.26 o -7 0 2 77.70 78.78 2.81 o -6 0 2 367.96 377.96 7.29 o -5 0 2 656.61 676.06 11.29 o -4 0 2 49.69 48.98 1.39 o -3 0 2 68.08 65.75 0.94 o -2 0 2 389.58 411.43 6.76 o -1 0 2 127.05 140.55 1.76 o 0 0 2 392.20 413.86 7.66 o 1 0 2 1270.11 1316.13 20.35 o 2 0 2 285.17 316.58 6.06 o 3 0 2 400.31 418.47 6.32 o 4 0 2 1095.95 1136.75 15.14 o 5 0 2 1173.40 1146.28 22.19 o 6 0 2 1.52 1.35 0.26 o 7 0 2 38.68 34.96 1.14 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1.30 o -2 -3 9 9.24 8.48 0.69 o -1 -3 9 181.65 188.28 4.14 o 0 -3 9 419.34 424.91 8.33 o 1 -3 9 15.62 15.74 1.06 o 2 -3 9 10.53 9.75 0.45 o 3 -3 9 176.91 169.22 5.30 o -3 -2 9 6.92 6.41 0.50 o -2 -2 9 45.59 45.35 2.07 o -1 -2 9 154.58 166.20 5.35 o 0 -2 9 559.59 649.65 18.97 o 2 -2 9 13.95 16.85 0.61 o 3 -2 9 86.35 85.81 2.09 o -3 -1 9 50.44 60.96 1.88 o -2 -1 9 48.42 50.66 1.46 o -1 -1 9 101.20 102.39 2.43 o 0 -1 9 22.97 24.94 0.67 o 1 -1 9 2.33 3.38 0.24 o 2 -1 9 207.38 218.97 4.63 o 3 -1 9 172.92 181.54 4.05 o 4 -1 9 58.39 62.68 1.76 o -4 0 9 0.79 1.35 0.40 o -3 0 9 0.35 0.32 0.22 o -2 0 9 280.54 280.11 5.96 o -1 0 9 268.44 272.65 4.62 o 0 0 9 91.44 86.02 1.69 o 1 0 9 63.19 66.94 1.39 o 2 0 9 436.79 430.13 8.75 o 3 0 9 401.98 409.46 8.39 o 4 0 9 4.04 3.72 0.42 o -4 1 9 11.53 11.91 1.17 o -3 1 9 31.79 32.48 1.20 o -2 1 9 238.13 239.43 4.17 o -1 1 9 313.18 322.18 5.42 o 0 1 9 89.74 92.00 1.81 o 1 1 9 161.13 161.46 2.90 o 2 1 9 51.52 52.26 1.44 o 3 1 9 6.29 6.84 0.48 o 4 1 9 202.96 201.22 5.67 o -3 2 9 390.45 387.15 6.54 o -2 2 9 102.84 101.96 2.07 o -1 2 9 2.96 3.72 0.32 o 0 2 9 354.98 345.04 5.80 o 1 2 9 936.07 919.63 14.60 o 2 2 9 30.89 28.16 0.82 o 3 2 9 76.87 80.54 2.17 o 4 2 9 199.31 197.83 6.62 o -3 3 9 767.50 782.26 12.66 o -2 3 9 45.03 43.44 1.37 o -1 3 9 84.51 84.49 1.81 o 0 3 9 63.85 61.22 1.41 o 1 3 9 674.96 652.30 10.55 o 2 3 9 287.60 273.07 4.72 o 3 3 9 17.47 15.88 0.63 o 4 3 9 45.15 44.53 1.52 o -2 4 9 103.21 98.21 2.39 o -1 4 9 151.70 144.17 2.81 o 0 4 9 62.62 59.19 1.43 o 1 4 9 11.28 11.56 0.54 o 2 4 9 4.21 3.95 0.37 o 3 4 9 456.58 451.40 7.55 o 4 4 9 115.94 114.81 3.02 o -1 5 9 486.86 479.21 8.05 o 0 5 9 199.98 201.21 3.75 o 1 5 9 253.56 251.61 4.51 o 2 5 9 26.61 27.32 0.90 o -1 -2 10 0.64 0.75 0.29 o -2 -1 10 31.95 34.26 1.18 o -1 -1 10 407.87 451.90 9.22 o 0 -1 10 377.47 428.56 8.70 o 1 -1 10 195.40 215.39 3.73 o 2 -1 10 82.91 80.88 1.99 o -2 0 10 81.63 83.58 2.21 o -1 0 10 301.43 313.65 6.60 o 0 0 10 279.42 293.09 4.98 o 1 0 10 26.49 27.71 0.77 o 2 0 10 65.63 67.54 1.79 o 3 0 10 92.97 96.53 2.45 o -2 1 10 276.95 283.61 6.13 o -1 1 10 76.68 78.65 1.70 o 0 1 10 8.45 8.65 0.44 o 1 1 10 255.97 255.75 5.56 o 2 1 10 543.50 547.26 11.38 o 3 1 10 38.91 39.25 1.54 o -2 2 10 661.52 670.30 10.92 o -1 2 10 61.65 60.92 1.44 o 0 2 10 49.63 48.74 1.32 o 1 2 10 62.77 62.44 1.44 o 2 2 10 477.41 459.87 7.60 o 3 2 10 128.37 132.79 3.28 o -1 3 10 49.44 47.40 1.24 o 0 3 10 64.47 62.73 1.52 o 1 3 10 154.65 151.03 2.89 o 2 3 10 2.24 2.77 0.33 o 3 3 10 0.73 1.37 0.35 o 0 4 10 276.08 273.52 4.86 o 1 4 10 196.65 194.14 3.62 o