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Information card for entry 2018899
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| Coordinates | 2018899.cif |
|---|---|
| Structure factors | 2018899.hkl |
| Original IUCr paper | HTML |
| Chemical name | Tricarbonyl[9-(triphenylphosphonio)fluorenylidene]ruthenium |
|---|---|
| Formula | C34 H21 O3 P Ru |
| Calculated formula | C34 H21 O3 P Ru |
| SMILES | [Ru]12(C#[O])(C#[O])(C#[O])C3([P+](c4ccccc4)(c4c1cccc4)c1c2cccc1)c1ccccc1c1c3cccc1 |
| Title of publication | Two complexes derived from the reaction of <i>M</i>~3~(CO)~12~ clusters (<i>M</i> = Ru, Os) with the 9-(triphenylphosphonio)fluorenide ylide: tricarbonyl[9-(triphenylphosphonio)fluorenylidene]ruthenium and nonacarbonyl-μ~3~-fluorenylidene-μ~2~-hydrido-<i>triangulo</i>-triosmium(III) |
| Authors of publication | Arce, Alejandro; De Sanctis, Ysaura; Galarza, Esperanza; Garland, María Teresa; Baggio, Ricardo |
| Journal of publication | Acta Crystallographica Section C |
| Year of publication | 2013 |
| Journal volume | 69 |
| Journal issue | 4 |
| Pages of publication | 363 - 366 |
| a | 10.029 ± 0.007 Å |
| b | 15.242 ± 0.005 Å |
| c | 17.922 ± 0.005 Å |
| α | 90° |
| β | 93.5 ± 0.05° |
| γ | 90° |
| Cell volume | 2734 ± 2 Å3 |
| Cell temperature | 295 ± 2 K |
| Ambient diffraction temperature | 295 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/n 1 |
| Hall space group symbol | -P 2yn |
| Residual factor for all reflections | 0.1144 |
| Residual factor for significantly intense reflections | 0.0647 |
| Weighted residual factors for significantly intense reflections | 0.0709 |
| Weighted residual factors for all reflections included in the refinement | 0.0807 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.054 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | Yes |
| Revision | Date | Message | Files |
|---|---|---|---|
| 180857 (current) | 2016-04-02 | cif/2/01/ (antanas@echidna) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 2/01/88. |
2018899.cif 2018899.hkl |
| 176760 | 2016-02-20 | cif/2/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 2/01. |
2018899.cif 2018899.hkl |
| 88055 | 2013-08-28 | cod/cif/ (saulius@koala.ibt.lt) Adding the _cod_database_fobs_code links for those COD CIFs that have their Fobs deposited recently. |
2018899.cif 2018899.hkl |
| 88054 | 2013-08-28 | cod/hkl/ (saulius@koala.ibt.lt) Adding Fobs files for the recently deposited IUCr coordinate data. |
2018899.cif 2018899.hkl |
| 85342 | 2013-05-07 | cif/ Adding structures of 2018899, 2018900 via cif-deposit CGI script. |
2018899.cif |
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Users of the data should acknowledge the original authors of the
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