#------------------------------------------------------------------------------ #$Date: 2016-04-02 22:23:21 +0300 (Sat, 02 Apr 2016) $ #$Revision: 180858 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/01/89/2018999.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2018999_Fobs loop_ _publ_author_name 'Gomes, Ligia R.' 'Low, John Nicolson' 'Rodrigues, Ana S. M. C.' 'Wardell, James L.' 'da Lima, Camillo H.' 'de Souza, Marcus V. N.' _publ_section_title ; Five N'-benzylidene-N-methylpyrazine-2-carbohydrazides ; _journal_coeditor_code SK3484 _journal_issue 5 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first 549 _journal_page_last 555 _journal_volume 69 _journal_year 2013 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 107.887 _cell_angle_gamma 90.000 _cell_length_a 17.5100 _cell_length_b 10.5421 _cell_length_c 14.9638 _exptl_crystal_F_000 1184.00 _reflns_d_resolution_high 0.7700 _cod_data_source_file sk3484IIesup6.hkl _cod_data_source_block IIe #BEGIN Tags that were not found in dictionaries: _shelx_title ' 2011ncs0416 C2/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 555.46 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 4 0 0 22.73 6.30 7.00 o 6 0 0 26465.46 26728.01 218.87 o 8 0 0 3958.78 4257.72 114.36 o 10 0 0 461.95 425.51 29.73 o 12 0 0 1267.85 1411.87 82.99 o 14 0 0 0.78 10.33 9.60 o 16 0 0 361.70 331.83 14.32 o 18 0 0 747.96 745.42 44.44 o 20 0 0 0.60 -3.80 5.22 o 3 1 0 30954.12 32507.01 147.58 o 5 1 0 15.40 19.16 1.66 o 7 1 0 3618.83 3936.06 194.14 o 9 1 0 3725.36 4255.77 138.05 o 11 1 0 105.71 89.80 11.95 o 13 1 0 310.24 296.45 16.25 o 15 1 0 3.81 16.93 10.84 o 17 1 0 37.80 39.93 13.26 o 19 1 0 30.28 48.40 4.93 o 21 1 0 0.00 9.72 23.15 o 0 2 0 3830.43 3387.88 45.38 o 2 2 0 3663.54 3692.33 31.96 o 4 2 0 215.07 238.51 15.87 o 6 2 0 3019.89 3546.56 190.03 o 8 2 0 367.38 358.50 27.87 o 10 2 0 17.46 20.55 4.38 o 12 2 0 1053.61 910.06 40.26 o 14 2 0 528.59 513.22 11.83 o 16 2 0 58.50 39.31 6.57 o 18 2 0 13.45 15.79 6.79 o 20 2 0 25.22 14.52 5.97 o 1 3 0 6923.56 7196.58 42.55 o 3 3 0 788.71 803.21 58.08 o 5 3 0 10441.72 11426.12 435.16 o 7 3 0 4845.73 4741.15 226.75 o 9 3 0 88.27 79.75 6.29 o 11 3 0 64.68 50.07 4.19 o 13 3 0 2405.57 2082.76 57.93 o 15 3 0 338.59 329.58 12.93 o 17 3 0 24.04 26.55 4.02 o 19 3 0 328.01 350.18 10.86 o 21 3 0 10.55 10.06 17.87 o 0 4 0 6304.19 5873.04 79.51 o 2 4 0 2865.56 3169.08 66.95 o 4 4 0 23858.78 24726.39 207.15 o 8 4 0 269.26 199.87 17.16 o 10 4 0 362.48 320.97 25.98 o 12 4 0 46.48 38.36 7.06 o 14 4 0 2618.18 2534.82 118.33 o 16 4 0 12.56 21.15 5.00 o 18 4 0 10.24 4.61 3.71 o 20 4 0 227.18 263.46 12.11 o 1 5 0 371.44 385.81 17.48 o 3 5 0 5843.50 6845.83 125.78 o 5 5 0 25.34 34.19 2.65 o 7 5 0 485.48 501.80 34.41 o 9 5 0 109.56 65.87 8.82 o 11 5 0 51.02 54.20 6.67 o 13 5 0 566.01 555.70 12.49 o 15 5 0 445.40 408.87 20.06 o 17 5 0 158.84 150.47 9.44 o 19 5 0 31.77 23.12 5.17 o 0 6 0 522.73 535.96 50.65 o 2 6 0 1085.16 1086.65 31.31 o 4 6 0 3062.21 3334.35 182.74 o 6 6 0 3110.79 3271.18 209.35 o 8 6 0 0.00 10.37 3.14 o 10 6 0 82.22 88.23 8.01 o 12 6 0 5852.75 5668.88 186.16 o 14 6 0 1974.63 2007.42 63.99 o 16 6 0 104.95 126.61 16.31 o 18 6 0 56.01 60.63 10.77 o 1 7 0 1382.43 1309.47 71.98 o 3 7 0 13.52 12.77 5.61 o 5 7 0 703.23 768.69 17.69 o 7 7 0 282.16 215.48 14.62 o 9 7 0 31.25 40.75 5.39 o 11 7 0 3.82 2.21 3.60 o 13 7 0 290.95 301.90 11.42 o 15 7 0 568.76 537.91 30.29 o 17 7 0 9.83 7.77 5.19 o 0 8 0 18550.83 17304.35 1667.07 o 2 8 0 1296.91 1286.06 33.19 o 4 8 0 3.62 12.95 9.18 o 6 8 0 280.08 226.13 10.48 o 8 8 0 0.03 0.03 5.17 o 10 8 0 98.61 76.81 11.39 o 12 8 0 44.64 40.64 5.53 o 14 8 0 76.61 71.93 11.65 o 16 8 0 47.12 61.39 8.64 o 1 9 0 3462.72 3624.40 190.28 o 3 9 0 521.18 516.31 11.97 o 5 9 0 33.89 32.42 6.25 o 7 9 0 736.68 528.49 19.35 o 9 9 0 103.25 99.03 14.05 o 11 9 0 182.74 164.35 12.89 o 13 9 0 330.92 290.19 22.16 o 15 9 0 28.27 20.24 9.02 o 0 10 0 3225.88 3701.71 165.29 o 2 10 0 1240.12 1406.95 129.68 o 4 10 0 30.35 27.71 7.53 o 6 10 0 58.30 38.89 15.36 o 8 10 0 390.80 321.68 22.59 o 10 10 0 105.89 96.76 6.70 o 12 10 0 37.93 25.16 7.43 o 14 10 0 79.53 66.24 5.03 o 1 11 0 1.37 15.98 3.24 o 3 11 0 52.67 49.82 7.66 o 5 11 0 41.40 32.56 6.16 o 7 11 0 17.53 17.94 8.40 o 9 11 0 6.81 0.07 4.62 o 11 11 0 55.43 67.36 8.02 o 0 12 0 886.74 1194.49 65.91 o 2 12 0 331.78 343.91 18.58 o 4 12 0 141.73 185.29 18.62 o 6 12 0 184.93 202.20 11.10 o 8 12 0 1.91 11.93 2.80 o 10 12 0 56.58 58.95 3.83 o 1 13 0 781.34 1027.44 61.12 o 3 13 0 89.74 114.98 7.76 o 5 13 0 38.80 69.74 25.97 o -21 1 1 51.80 72.04 11.58 o -19 1 1 476.58 467.86 27.09 o -17 1 1 3.10 15.38 3.82 o -15 1 1 244.74 199.53 9.47 o -13 1 1 822.12 838.05 26.63 o -11 1 1 222.43 189.09 17.28 o -9 1 1 2054.33 2125.61 143.71 o -7 1 1 747.26 730.06 31.56 o -5 1 1 1043.13 1070.51 46.22 o -3 1 1 7030.85 7159.45 49.69 o 3 1 1 5198.41 5213.51 40.71 o 5 1 1 231.47 302.23 20.23 o 7 1 1 5657.92 6641.40 65.91 o 9 1 1 1226.57 1047.01 135.54 o 11 1 1 209.79 195.23 21.12 o 13 1 1 297.38 296.66 10.96 o 15 1 1 632.58 616.94 20.46 o 17 1 1 489.15 502.43 28.99 o 19 1 1 39.91 31.92 10.90 o 21 1 1 115.89 140.42 12.57 o -20 2 1 68.35 89.34 5.74 o -18 2 1 6.97 14.89 17.67 o -16 2 1 7.12 0.32 15.54 o -14 2 1 5.91 4.25 5.24 o -12 2 1 521.01 463.13 38.58 o -10 2 1 1181.16 1017.41 67.09 o -8 2 1 896.01 753.63 42.40 o -6 2 1 544.39 605.94 33.43 o -4 2 1 2721.11 3073.69 76.72 o -2 2 1 3790.23 3537.75 32.85 o 0 2 1 1456.41 1528.08 46.34 o 2 2 1 16031.43 16844.01 208.13 o 4 2 1 2615.39 2762.04 322.02 o 6 2 1 1268.30 1212.41 99.15 o 8 2 1 2001.36 1795.12 97.84 o 10 2 1 1100.60 1056.17 130.82 o 12 2 1 484.93 450.89 12.56 o 14 2 1 20.27 26.08 12.49 o 16 2 1 840.84 784.58 66.77 o 18 2 1 8.71 2.76 10.73 o 20 2 1 32.58 33.42 7.30 o -21 3 1 38.73 63.04 4.16 o -19 3 1 331.01 313.52 17.46 o -17 3 1 3.69 17.68 14.67 o -15 3 1 852.25 711.70 17.45 o -13 3 1 190.85 209.20 9.89 o -11 3 1 283.97 287.82 33.49 o -9 3 1 12.31 15.21 1.98 o -7 3 1 959.63 994.73 42.86 o -5 3 1 1865.06 1848.40 72.32 o -3 3 1 3634.24 3616.35 38.89 o -1 3 1 6104.49 5479.79 35.58 o 1 3 1 12594.70 12430.51 120.66 o 3 3 1 69.53 106.37 7.19 o 5 3 1 323.63 477.22 62.63 o 7 3 1 0.26 10.40 2.85 o 9 3 1 90.33 88.80 12.20 o 11 3 1 6.98 14.52 5.34 o 13 3 1 7759.15 7173.30 186.97 o 15 3 1 349.23 393.30 19.64 o 17 3 1 125.09 120.68 21.84 o 19 3 1 29.87 32.47 8.25 o -20 4 1 41.13 35.03 7.17 o -18 4 1 59.94 65.27 12.21 o -16 4 1 314.42 302.46 12.87 o -14 4 1 73.40 60.99 4.00 o -12 4 1 1.90 13.49 8.28 o -10 4 1 97.67 84.77 10.48 o -8 4 1 1169.76 1043.68 88.15 o -6 4 1 209.25 212.57 33.41 o -4 4 1 69.48 63.27 12.46 o -2 4 1 3.47 10.45 1.53 o 0 4 1 2247.32 2339.00 58.13 o 2 4 1 2350.12 2460.91 40.29 o 4 4 1 2937.91 3582.17 91.68 o 6 4 1 801.35 660.55 62.22 o 8 4 1 3.38 10.67 7.71 o 10 4 1 831.67 808.50 19.88 o 12 4 1 617.30 577.16 16.74 o 14 4 1 685.04 677.53 25.50 o 16 4 1 257.71 240.44 14.71 o 18 4 1 0.54 4.19 6.35 o 20 4 1 92.47 107.40 7.77 o -19 5 1 141.28 126.79 7.35 o -17 5 1 153.84 148.85 14.68 o -15 5 1 236.79 275.90 29.02 o -13 5 1 457.85 427.47 23.60 o -11 5 1 2980.13 2796.33 151.55 o -9 5 1 319.77 263.84 21.46 o -7 5 1 3655.34 3910.97 346.88 o -5 5 1 8197.26 8968.71 231.02 o -3 5 1 1115.67 1122.12 41.50 o -1 5 1 1198.44 1364.05 55.55 o 1 5 1 3206.14 3037.84 122.26 o 3 5 1 510.73 542.60 36.61 o 5 5 1 311.12 329.44 20.87 o 7 5 1 3113.49 3328.86 470.08 o 9 5 1 103.37 109.55 9.82 o 11 5 1 2173.58 2046.94 55.80 o 13 5 1 2298.29 2243.10 44.46 o 15 5 1 89.86 105.71 12.07 o 17 5 1 0.01 8.92 5.92 o 19 5 1 46.31 60.94 8.66 o -18 6 1 90.44 121.69 6.14 o -16 6 1 12.93 20.02 9.46 o -14 6 1 1.29 2.54 3.84 o -12 6 1 1026.61 958.97 48.51 o -10 6 1 13.57 17.84 2.03 o -8 6 1 545.17 511.31 50.03 o -6 6 1 353.41 386.54 25.28 o -4 6 1 576.99 631.94 34.71 o -2 6 1 711.59 789.64 30.16 o 0 6 1 0.16 11.99 9.01 o 2 6 1 274.13 274.88 13.78 o 4 6 1 140.79 208.43 12.43 o 6 6 1 291.17 248.90 18.51 o 8 6 1 24.73 18.93 4.93 o 10 6 1 600.75 552.17 15.99 o 12 6 1 1302.45 1268.42 61.22 o 14 6 1 174.41 195.28 10.74 o 16 6 1 3.93 15.10 5.85 o 18 6 1 6.43 7.00 10.45 o -17 7 1 17.66 50.25 12.16 o -15 7 1 625.06 660.56 36.10 o -13 7 1 53.46 53.06 6.66 o -11 7 1 4.37 16.17 8.50 o -9 7 1 142.59 123.61 8.81 o -7 7 1 798.67 859.24 43.35 o -5 7 1 43.75 45.54 3.32 o -3 7 1 392.86 378.25 23.98 o -1 7 1 15.53 17.22 2.29 o 1 7 1 1890.68 1904.65 127.13 o 3 7 1 72.12 58.68 4.49 o 5 7 1 318.71 324.87 13.58 o 7 7 1 0.18 18.40 2.25 o 9 7 1 421.28 338.26 18.78 o 11 7 1 266.23 280.00 11.04 o 13 7 1 30.27 28.68 6.34 o 15 7 1 626.04 700.60 24.23 o 17 7 1 150.89 166.06 11.43 o -16 8 1 40.77 37.79 9.20 o -14 8 1 111.97 115.00 8.80 o -12 8 1 7.99 15.64 10.00 o -10 8 1 418.82 373.85 13.03 o -8 8 1 37.16 38.66 3.58 o -6 8 1 1461.29 1370.38 37.38 o -4 8 1 22.98 29.67 2.80 o -2 8 1 609.89 587.40 14.77 o 0 8 1 2328.67 2331.04 70.17 o 2 8 1 419.68 429.89 18.07 o 4 8 1 153.64 150.33 9.32 o 6 8 1 209.59 181.76 11.69 o 8 8 1 16.20 10.75 6.55 o 10 8 1 27.84 12.16 6.40 o 12 8 1 60.13 72.34 6.75 o 14 8 1 0.39 1.71 3.86 o 16 8 1 1.09 -4.09 4.09 o -15 9 1 142.97 169.75 9.20 o -13 9 1 88.98 52.67 4.15 o -11 9 1 6.61 20.35 4.66 o -9 9 1 1468.70 1031.66 107.17 o -7 9 1 17.59 22.91 5.98 o -5 9 1 320.19 331.12 12.38 o -3 9 1 1515.72 1497.24 64.97 o -1 9 1 58.04 47.37 5.04 o 1 9 1 6433.37 6352.39 441.25 o 3 9 1 847.38 849.72 35.16 o 5 9 1 70.45 81.75 4.73 o 7 9 1 248.89 190.07 15.65 o 9 9 1 29.32 58.98 12.49 o 11 9 1 442.99 399.31 19.64 o 13 9 1 325.87 265.04 12.00 o 15 9 1 183.28 195.39 15.11 o -14 10 1 34.35 29.67 6.64 o -12 10 1 9.79 17.64 4.26 o -10 10 1 309.94 257.63 14.63 o -8 10 1 858.32 721.06 55.58 o -6 10 1 1.42 10.40 5.30 o -4 10 1 804.53 846.28 69.06 o -2 10 1 2639.26 2713.52 240.56 o 0 10 1 29.01 32.37 9.85 o 2 10 1 28.72 24.70 7.99 o 4 10 1 34.50 17.47 7.95 o 6 10 1 232.96 172.14 7.68 o 8 10 1 3.84 8.23 3.01 o 10 10 1 7.78 4.19 3.49 o 12 10 1 3.32 2.04 4.86 o 14 10 1 504.56 635.35 64.85 o -13 11 1 92.28 88.76 5.85 o -11 11 1 0.77 0.97 8.70 o -9 11 1 29.35 30.80 6.23 o -7 11 1 18.50 13.86 7.94 o -5 11 1 4.37 11.51 3.91 o -3 11 1 0.91 -1.71 3.70 o -1 11 1 2.14 8.86 8.43 o 1 11 1 123.01 110.27 24.58 o 3 11 1 851.66 958.05 132.70 o 5 11 1 38.31 32.38 10.02 o 7 11 1 395.57 395.90 27.45 o 9 11 1 26.46 25.37 6.28 o 11 11 1 81.73 77.23 4.50 o -10 12 1 36.30 84.32 14.25 o -8 12 1 266.34 275.20 15.72 o -6 12 1 216.94 293.45 10.90 o -4 12 1 0.86 4.94 4.66 o -2 12 1 82.97 105.22 23.31 o 0 12 1 44.96 43.30 11.71 o 2 12 1 33.47 26.32 12.31 o 4 12 1 11.12 19.99 6.29 o 6 12 1 15.64 31.06 7.91 o 8 12 1 5.46 0.25 3.57 o -7 13 1 43.78 68.07 6.31 o -5 13 1 276.50 430.92 51.44 o -3 13 1 56.26 77.48 8.66 o -1 13 1 140.81 206.57 11.61 o 1 13 1 133.72 194.52 18.55 o 3 13 1 172.70 175.28 26.09 o 5 13 1 261.14 281.81 26.49 o -22 0 2 236.79 220.31 13.05 o -20 0 2 469.36 493.35 49.85 o -18 0 2 3.32 19.27 6.63 o -16 0 2 320.91 327.74 34.69 o -14 0 2 317.90 318.50 13.22 o -12 0 2 9388.14 8373.68 369.57 o -10 0 2 545.45 609.40 44.88 o -8 0 2 11285.53 11777.00 130.63 o -6 0 2 0.15 8.17 1.48 o -4 0 2 18012.11 18688.77 102.16 o -2 0 2 6688.75 6561.48 88.52 o 2 0 2 8555.07 8131.26 74.60 o 4 0 2 10697.42 11191.55 107.96 o 6 0 2 2885.46 3093.19 69.49 o 8 0 2 26748.59 30323.44 1980.10 o 10 0 2 538.99 575.35 44.25 o 12 0 2 186.29 160.91 12.91 o 14 0 2 70.71 88.06 9.20 o 16 0 2 478.80 498.84 31.28 o 18 0 2 418.60 391.35 35.92 o 20 0 2 248.97 214.54 15.06 o -21 1 2 463.13 554.08 24.63 o -19 1 2 239.44 195.28 16.51 o -17 1 2 4.42 4.05 8.50 o -15 1 2 32.30 21.91 5.43 o -13 1 2 1181.40 1096.02 44.37 o -11 1 2 1028.95 1048.74 60.91 o -9 1 2 322.39 361.56 18.69 o -7 1 2 314.02 300.87 12.25 o -5 1 2 1984.14 2266.01 23.77 o -3 1 2 460.88 627.11 21.55 o -1 1 2 3545.24 3351.77 28.00 o 1 1 2 1461.30 1717.21 22.41 o 3 1 2 52.23 83.16 9.65 o 5 1 2 4971.21 5468.79 72.69 o 7 1 2 559.27 589.89 40.70 o 9 1 2 2273.18 2626.69 195.29 o 11 1 2 185.14 129.84 12.94 o 13 1 2 47.94 46.83 8.88 o 15 1 2 594.88 573.85 17.40 o 17 1 2 549.46 523.21 29.48 o 19 1 2 52.91 48.09 20.35 o -22 2 2 12.39 31.49 12.75 o -20 2 2 11.16 5.39 11.62 o -18 2 2 310.32 309.48 17.80 o -16 2 2 526.17 527.34 15.71 o -14 2 2 570.87 519.05 14.76 o -12 2 2 1749.41 1526.22 32.64 o -10 2 2 0.06 -2.12 2.12 o -8 2 2 951.28 940.72 35.36 o -6 2 2 4602.71 4723.54 113.06 o -4 2 2 2607.43 2835.53 85.99 o -2 2 2 1753.17 2027.44 89.12 o 0 2 2 31.11 25.36 0.90 o 4 2 2 8.89 18.07 5.28 o 6 2 2 3.17 12.16 3.65 o 8 2 2 2338.32 2200.60 139.73 o 10 2 2 283.07 220.68 13.98 o 12 2 2 1296.87 1326.70 32.66 o 14 2 2 7.29 22.45 8.58 o 16 2 2 328.78 346.49 18.88 o 18 2 2 156.45 150.35 27.14 o 20 2 2 16.80 52.23 29.52 o -21 3 2 454.27 556.09 39.22 o -19 3 2 92.85 97.51 4.80 o -17 3 2 474.52 504.65 17.93 o -15 3 2 2907.87 2799.73 61.03 o -13 3 2 113.20 89.69 7.15 o -11 3 2 1209.77 992.64 52.21 o -9 3 2 24.81 26.39 3.52 o -7 3 2 4275.52 4467.88 219.28 o -5 3 2 380.14 412.36 15.35 o -3 3 2 317.08 483.82 21.84 o -1 3 2 5.84 16.90 3.56 o 1 3 2 19.61 12.22 1.40 o 3 3 2 4616.76 4985.85 43.94 o 5 3 2 328.56 355.54 20.88 o 7 3 2 3480.89 3725.70 239.66 o 9 3 2 4.84 5.97 1.83 o 11 3 2 2564.48 2458.94 86.12 o 13 3 2 1562.13 1429.05 57.50 o 15 3 2 236.88 242.77 20.57 o 17 3 2 327.73 416.72 26.10 o 19 3 2 205.69 223.10 10.41 o -20 4 2 74.47 109.51 27.08 o -18 4 2 2365.87 2284.37 157.70 o -16 4 2 2339.37 2229.28 185.45 o -14 4 2 1510.69 1403.40 42.43 o -12 4 2 1201.08 1157.52 28.56 o -10 4 2 37.92 42.66 7.46 o -8 4 2 43.98 58.26 6.76 o -6 4 2 10895.22 10626.88 1160.14 o -4 4 2 159.36 195.52 8.04 o -2 4 2 269.80 271.46 7.97 o 0 4 2 1585.88 1764.46 119.46 o 2 4 2 7116.52 7517.61 69.65 o 4 4 2 4053.06 4816.80 90.59 o 6 4 2 192.92 186.85 14.62 o 8 4 2 326.91 348.62 20.30 o 10 4 2 5850.82 5915.90 151.90 o 12 4 2 6087.62 5795.42 108.38 o 14 4 2 3976.81 3773.47 229.85 o 16 4 2 21.88 23.34 4.83 o 18 4 2 111.82 142.03 9.62 o -19 5 2 2.23 15.08 4.26 o -17 5 2 147.06 120.77 6.75 o -15 5 2 2720.69 2606.74 214.92 o -13 5 2 1126.98 1073.52 58.55 o -11 5 2 214.82 171.06 9.43 o -9 5 2 897.22 959.27 35.13 o -7 5 2 5.20 3.84 6.41 o -5 5 2 40.21 30.46 4.24 o -3 5 2 230.31 265.23 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