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Information card for entry 2020487
Preview
| Coordinates | 2020487.cif |
|---|---|
| Structure factors | 2020487.hkl |
| Original IUCr paper | HTML |
| Common name | (PPh4)[V2(PS3'')2(mu-OMe)3] |
|---|---|
| Chemical name | Tetraphenylphosphonium tri-μ-methanolato-κ^6^<i>O</i>:<i>O</i>-bis({tris[2-sulfanidyl-3-(trimethylsilyl)phenyl]phosphane-κ^4^<i>P</i>,<i>S</i>,<i>S</i>',<i>S</i>''}vanadium(IV)) methanol disolvate |
| Formula | C83 H109 O5 P3 S6 Si6 V2 |
| Calculated formula | C83 H101 O5 P3 S6 Si6 V2 |
| Title of publication | A non-oxo methanolate-bridged divanadium(IV) complex with tris(2-sulfanidylphenyl)phosphane ligands: synthesis, structural characterization and magnetic investigation |
| Authors of publication | Wu, Hong-Ming; Chang, Ya-Ho; Su, Chia-Lin; Lee, Gene-Hsiang; Hsu, Hua-Fen |
| Journal of publication | Acta Crystallographica Section C |
| Year of publication | 2016 |
| Journal volume | 72 |
| Journal issue | 5 |
| Pages of publication | 416 - 420 |
| a | 18.474 ± 0.0012 Å |
| b | 25.4633 ± 0.0018 Å |
| c | 19.3663 ± 0.0013 Å |
| α | 90° |
| β | 100.036 ± 0.002° |
| γ | 90° |
| Cell volume | 8970.7 ± 1.1 Å3 |
| Cell temperature | 150 ± 2 K |
| Ambient diffraction temperature | 150 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 15 |
| Hermann-Mauguin space group symbol | C 1 2/c 1 |
| Hall space group symbol | -C 2yc |
| Residual factor for all reflections | 0.1369 |
| Residual factor for significantly intense reflections | 0.0877 |
| Weighted residual factors for significantly intense reflections | 0.1712 |
| Weighted residual factors for all reflections included in the refinement | 0.1912 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.097 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | Yes |
| Revision | Date | Message | Files |
|---|---|---|---|
| 183637 (current) | 2016-06-17 | cif/ Updating files of 2020487 Original log message: Adding full bibliography for 2020487.cif. |
2020487.cif 2020487.hkl |
| 182130 | 2016-04-15 | cif/ hkl/ Adding structures of 2020487 via cif-deposit CGI script. |
2020487.cif 2020487.hkl |
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