#------------------------------------------------------------------------------ #$Date: 2019-02-14 05:36:51 +0200 (Thu, 14 Feb 2019) $ #$Revision: 213640 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/02/15/2021507.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2021507 loop_ _publ_author_name 'Losev, Evgeniy A.' 'Boldyreva, Elena' _publ_section_title ; Concomitant cocrystal and salt: no interconversion in the solid state ; _journal_coeditor_code KU3233 _journal_issue 3 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first ; ; _journal_paper_doi 10.1107/S2053229619001372 _journal_volume 75 _journal_year 2019 _chemical_formula_iupac 'C3 H7 N O2 +, C4 H6 O6 -' _chemical_formula_moiety 'C3 H7 N O2 +, C4 H6 O6 -' _chemical_formula_sum 'C7 H13 N O8' _chemical_formula_weight 239.18 _chemical_name_common '\b-Alanine--DL-tartaric acid (1/1)' _chemical_name_systematic '\b-Alaninium DL-tartarate' _space_group_crystal_system monoclinic _space_group_IT_number 14 _space_group_name_Hall '-P 2ybc' _space_group_name_H-M_alt 'P 1 21/c 1' _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _atom_sites_solution_hydrogens geom _audit_creation_method ; Olex2 1.2 (compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506) ; _cell_angle_alpha 90 _cell_angle_beta 103.007(6) _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 4.8828(3) _cell_length_b 9.4372(4) _cell_length_c 21.7258(11) _cell_measurement_reflns_used 3071 _cell_measurement_temperature 275 _cell_measurement_theta_max 28.6060 _cell_measurement_theta_min 1.9380 _cell_volume 975.44(9) _computing_cell_refinement ; CrysAlis PRO (Agilent, 2014) ; _computing_data_collection ; CrysAlis PRO (Agilent, 2014) ; _computing_data_reduction ; CrysAlis PRO (Agilent, 2014) ; _computing_molecular_graphics ; OLEX2 (Dolomanov et al., 2009) ; _computing_publication_material ; OLEX2 (Dolomanov et al., 2009) ; _computing_structure_refinement ; SHELXL2018 (Sheldrick, 2015b) ; _computing_structure_solution ; olex2.solve (Bourhis et al., 2015) ; _diffrn_ambient_temperature 275 _diffrn_detector 'CCD plate' _diffrn_measured_fraction_theta_full 1.000 _diffrn_measured_fraction_theta_max 1.000 _diffrn_measurement_device_type 'STOE IPDS' _diffrn_measurement_method '\w scans' _diffrn_radiation_monochromator graphite _diffrn_radiation_probe x-ray _diffrn_radiation_type MoK\a _diffrn_radiation_wavelength 0.71073 _diffrn_reflns_av_R_equivalents 0.0836 _diffrn_reflns_av_unetI/netI 0.0538 _diffrn_reflns_limit_h_max 5 _diffrn_reflns_limit_h_min -6 _diffrn_reflns_limit_k_max 11 _diffrn_reflns_limit_k_min -11 _diffrn_reflns_limit_l_max 27 _diffrn_reflns_limit_l_min -27 _diffrn_reflns_number 10971 _diffrn_reflns_theta_full 25.242 _diffrn_reflns_theta_max 26.372 _diffrn_reflns_theta_min 1.924 _diffrn_source 'Enhance (Mo) X-ray Source' _exptl_absorpt_coefficient_mu 0.151 _exptl_absorpt_correction_T_max 0.995 _exptl_absorpt_correction_T_min 0.932 _exptl_absorpt_correction_type gaussian _exptl_absorpt_process_details ; (CrysAlis PRO; Agilent, 2014) ; _exptl_crystal_colour colourless _exptl_crystal_density_diffrn 1.629 _exptl_crystal_description block _exptl_crystal_F_000 504 _exptl_crystal_size_max 1 _exptl_crystal_size_mid 0.0951 _exptl_crystal_size_min 0.04 _refine_diff_density_max 0.170 _refine_diff_density_min -0.201 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.017 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 151 _refine_ls_number_reflns 1993 _refine_ls_number_restraints 0 _refine_ls_restrained_S_all 1.017 _refine_ls_R_factor_all 0.0741 _refine_ls_R_factor_gt 0.0422 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0353P)^2^] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.0725 _refine_ls_wR_factor_ref 0.0808 _reflns_number_gt 1439 _reflns_number_total 1993 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file ku3233sup1.cif _cod_data_source_block 275_cocrystal_heating _cod_original_cell_volume 975.43(9) _cod_database_code 2021507 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_estimated_absorpt_t_min 0.864 _shelx_estimated_absorpt_t_max 0.994 _shelx_hkl_file ; 0 0 2 63.8910 1.88084 1 0 0 -2 64.5210 1.81840 1 0 0 2 64.2819 1.74339 2 0 0 3 0.47685 1.18734 1 0 0 3 2.04792 1.14899 2 0 0 -3-0.11769 0.90178 1 0 0 4 16.5919 1.66374 2 0 0 -4 18.2551 1.63584 1 0 0 4 16.4287 1.81838 1 0 0 -5 0.50592 1.18847 1 0 0 5-0.41313 1.30495 2 0 0 5 1.63396 1.62001 1 0 0 6 99.3117 4.01500 1 0 0 -6 99.1052 3.86950 1 0 0 6 95.9801 3.55297 2 0 0 7 0.77490 1.63456 2 0 0 -7 0.98213 1.59502 1 0 0 7-1.42588 1.94610 1 0 0 8 215.937 5.95827 2 0 0 8 223.542 6.63882 1 0 0 -8 226.194 6.61116 1 0 0 -9-0.71108 1.96302 1 0 0 9-1.64986 2.34715 1 0 0 9-1.53374 1.98074 2 0 0 -10 5.28220 2.42270 1 0 0 10 2.83503 2.09503 2 0 0 10 3.89389 2.58073 1 0 0 -11 0.83393 2.40766 1 0 0 11 3.10044 2.24679 2 0 0 11-0.97263 2.65081 1 0 0 12 48.1885 4.11479 2 0 0 -12 58.7024 4.78615 1 0 0 12 48.6260 4.62822 1 0 0 13-0.21021 3.06650 1 0 0 -13-4.13842 2.92164 1 0 0 13 0.07443 2.70712 2 0 0 -14 121.895 6.97586 1 0 0 14 117.423 7.02574 1 0 0 14 118.315 6.29605 2 0 0 15 2.82942 3.00755 2 0 0 15-4.82107 3.90054 1 0 0 -15-2.11670 3.41749 1 0 0 -16 258.240 10.5604 1 0 0 16 246.934 10.4738 1 0 0 16 256.163 9.50674 2 0 0 -17 0.62348 3.59280 1 0 0 17 0.74281 3.58918 2 0 0 17 4.46650 4.37195 1 0 0 -18 236.020 10.9787 1 0 0 18 219.141 10.9355 1 0 0 18 235.062 9.98243 2 0 0 19-0.33399 5.01580 1 0 0 19-0.69320 3.90066 2 0 0 -19-1.33747 4.00829 1 0 0 20 42.6004 6.96559 1 0 0 20 41.5206 6.03788 2 0 0 -20 42.3414 6.36228 1 0 0 21-0.54582 5.55516 1 0 0 -21 1.90736 4.67950 1 0 0 21 5.20533 5.23013 2 0 0 22 11.3374 5.25645 2 0 0 -22-4.81468 4.79947 1 0 0 22 5.18869 6.14086 1 0 0 -23 4.31595 5.50735 1 0 0 23-2.67416 6.35231 1 0 0 23-8.11341 5.64867 2 0 0 24 5.36376 6.77674 1 0 0 -24 5.10862 6.59286 1 0 0 24-5.23784 6.42453 2 0 0 -25 4.65227 7.38487 1 0 0 25-4.57905 7.43022 1 0 0 25-1.35410 6.57795 2 0 0 26-1.49576 7.49093 1 0 0 -26 10.4459 9.06534 1 0 0 26 19.8554 8.32411 2 0 0 27-3.66231 7.84736 2 0 0 27 17.7650 8.44162 1 0 0 28 13.8228 9.57740 1 0 0 -28 10.2786 11.5569 1 0 0 28 15.5891 8.68243 2 0 0 -29 31.6644 14.1088 1 0 0 29 3.11564 10.3729 2 0 1 0 0.51457 1.06018 2 0 -1 0-0.00475 0.86585 2 0 1 1 16.9626 1.05926 1 0 -1 -1 17.4393 1.02976 1 0 1 1 18.1116 1.41773 2 0 -1 -1 15.0149 1.29233 2 0 -1 -2 65.0567 2.30960 2 0 -1 2 64.5680 1.86678 1 0 1 -2 62.7269 1.83108 1 0 1 2 64.3468 2.08180 1 0 1 2 64.4120 2.34449 2 0 -1 -2 64.1704 2.07166 1 0 1 3 245.789 4.43522 1 0 -1 3 245.473 4.10584 1 0 -1 -3 255.164 4.49894 1 0 1 -3 249.075 4.11139 1 0 -1 -3 249.075 4.58694 2 0 1 3 240.816 4.57832 2 0 -1 4 6.92661 1.51589 1 0 1 -4 4.82494 1.29871 1 0 1 4 4.40815 1.59712 1 0 -1 -4 5.21717 1.40600 1 0 1 4 4.85181 1.41294 2 0 -1 -4 7.09398 1.73278 2 0 -1 -5 2.63471 1.50803 2 0 -1 -5 0.79692 1.36118 1 0 1 -5-2.67987 1.49873 1 0 1 5 0.75529 1.45536 1 0 1 5-0.53832 1.63967 2 0 -1 5 0.97499 1.47045 1 0 1 -6 179.559 5.08687 1 0 -1 -6 173.487 5.04749 2 0 1 6 178.548 5.15634 1 0 -1 -6 174.721 5.26363 1 0 -1 6 172.127 4.91898 1 0 1 6 176.559 4.98501 2 0 1 7 11.7943 2.23766 2 0 1 -7 8.08815 1.83266 1 0 -1 -7 8.99104 2.27130 1 0 -1 -7 10.1750 2.14969 2 0 -1 7 6.75291 2.04574 1 0 1 7 6.91402 2.16103 1 0 -1 -8 1.61290 2.18265 1 0 1 -8 2.67046 1.82894 1 0 1 8 0.01838 2.05780 1 0 -1 8 1.74572 1.97726 1 0 1 8 0.11418 1.91533 2 0 -1 -8 3.71850 2.15073 2 0 1 -9 17.6522 2.52896 1 0 -1 -9 16.7278 2.64869 1 0 1 9 18.8643 2.81046 1 0 1 9 17.3155 2.65090 2 0 -1 -9 17.1989 2.75572 2 0 -1 9 15.5716 2.43245 1 0 1 10 2.79781 2.12351 2 0 1 -10 3.95588 2.48091 1 0 -1 -10 5.75695 2.39371 2 0 -1 -10 1.40533 2.54361 1 0 1 10 3.70177 2.42556 1 0 -1 10 3.24603 2.52067 1 0 -1 -11 223.769 7.92402 1 0 1 11 223.004 7.33704 2 0 1 11 222.485 8.01719 1 0 -1 11 214.398 7.55365 1 0 1 -11 225.562 7.86394 1 0 -1 12 6.32514 2.74142 2 0 -1 -12 8.39220 3.30733 1 0 1 -12 3.15287 2.78501 1 0 1 12 11.8524 3.25758 1 0 -1 12 10.6728 3.27996 1 0 1 12 7.57463 2.89678 2 0 1 13 247.797 8.54010 2 0 1 -13 266.594 9.32020 1 0 -1 13 249.819 9.10127 1 0 -1 -13 262.497 9.60170 1 0 -1 13 253.970 8.28343 2 0 1 13 254.249 9.25602 1 0 -1 14 64.8759 5.22619 1 0 -1 14 66.7984 4.95168 2 0 -1 -14 62.3973 5.26045 1 0 1 14 65.1351 5.78078 1 0 1 -14 62.8605 5.56647 1 0 1 14 70.8224 5.25623 2 0 1 -15 35.0086 4.73930 1 0 1 15 42.8753 5.20125 1 0 1 15 43.9940 4.76093 2 0 -1 15 36.2519 4.88897 1 0 -1 -15 42.1854 5.11101 1 0 -1 15 41.0202 4.48009 2 0 -1 -16 19.3602 4.78409 1 0 -1 16 20.4346 4.08128 2 0 -1 16 15.5939 4.41998 1 0 1 -16 13.4280 3.79009 1 0 1 16 18.1639 3.85885 1 0 1 16 17.4630 4.15080 2 0 1 17 0.90988 3.43591 2 0 -1 17 11.0306 3.89581 2 0 -1 -17 0.08512 4.34116 1 0 -1 17 7.78594 4.29888 1 0 1 -17 14.9587 4.60519 1 0 1 17 0.29582 3.77478 1 0 1 18 110.334 8.41252 1 0 -1 18 109.954 7.95343 1 0 1 -18 109.936 8.36418 1 0 1 18 117.039 7.48595 2 0 -1 -18 115.010 8.37854 1 0 -1 18 114.063 7.37776 2 0 -1 -19 8.04333 4.27677 1 0 1 19-0.82649 5.10278 1 0 -1 19 2.94850 4.02360 2 0 1 19 7.60628 4.34241 2 0 1 -19 1.65105 4.93737 1 0 -1 19 6.20756 4.33516 1 0 -1 20 113.756 8.07913 2 0 1 20 110.620 8.21178 2 0 -1 20 114.134 9.08435 1 0 1 -20 102.596 8.76637 1 0 -1 -20 104.119 8.73469 1 0 1 20 106.965 9.15913 1 0 1 -21 60.7141 7.67793 1 0 -1 21 65.7315 7.06367 2 0 1 21 57.6992 7.88695 1 0 -1 -21 49.4048 7.68981 1 0 1 21 62.2652 7.18773 2 0 -1 21 54.0916 7.98727 1 0 1 -22 31.0143 6.45011 1 0 -1 -22 39.1432 8.11952 1 0 -1 22 29.8522 7.53631 1 0 1 22 38.9367 7.29713 1 0 1 22 44.1183 6.89987 2 0 -1 22 35.5032 6.27122 2 0 -1 -23 75.8191 9.68329 1 0 -1 23 60.6696 8.81876 1 0 1 23 58.2019 7.65731 2 0 1 -23 61.7258 7.84629 1 0 -1 23 54.4283 7.56632 2 0 1 23 68.1344 8.78403 1 0 -1 24 93.2189 9.80850 1 0 1 24 66.8672 8.37255 2 0 1 -24 88.4124 9.62779 1 0 -1 -24 80.5617 10.4484 1 0 1 24 95.8193 9.96524 1 0 -1 24 74.8047 8.39258 2 0 1 -25 13.4708 7.29055 1 0 -1 25 17.9203 7.62571 1 0 1 25 30.0769 7.41072 2 0 -1 25 26.8757 7.09948 2 0 -1 -25 21.0576 7.90323 1 0 1 25 34.7528 7.74270 1 0 1 -26 5.53193 7.85202 1 0 1 26-13.1642 7.86960 2 0 -1 -26-8.35368 8.11338 1 0 1 26-5.53683 6.82803 1 0 -1 26-9.38867 7.28579 2 0 -1 26-2.21334 8.39036 1 0 -1 27 4.57814 7.79900 2 0 1 27-2.37304 8.71507 2 0 1 -27 16.5391 9.24273 1 0 -1 -27 12.6947 10.1650 1 0 -1 27-2.42743 10.4616 1 0 1 27-3.20718 8.29290 1 0 1 -28 10.1551 9.47575 1 0 1 28-13.5582 10.1044 1 0 -1 -28 4.74836 11.8918 1 0 1 28 26.6948 10.0289 2 0 -1 28-15.8233 9.72496 2 0 -1 28 14.5965 12.1834 1 0 -1 29 24.6342 10.8598 2 0 1 29 19.2033 10.5319 2 0 -1 29 14.5551 12.2721 1 0 1 29-0.08961 9.69678 1 0 1 -29 2.65683 10.2391 1 0 2 0 316.031 5.71297 2 0 -2 0 312.640 5.63350 2 0 -2 0 299.947 3.87559 1 0 2 0 304.418 3.96630 1 0 -2 -1 3.93107 1.56360 2 0 2 1 0.50481 0.98295 1 0 2 1 2.68817 1.58070 2 0 -2 1-1.22835 1.57241 2 0 -2 -1 3.22206 0.96446 1 0 -2 1 2.53273 0.91513 1 0 -2 1 1.64730 0.85752 1 0 2 2 2640.69 16.9691 2 0 2 2 2575.63 13.5988 1 0 2 -2 2643.84 12.2170 1 0 -2 -2 2606.24 16.8538 2 0 -2 -2 2587.04 13.5116 1 0 -2 2 2663.82 12.0480 1 0 2 3 160.541 4.68555 2 0 2 3 153.779 3.87764 1 0 -2 3 152.691 3.42565 1 0 -2 -3 163.970 3.98588 1 0 2 -3 157.869 3.49517 1 0 -2 -3 151.877 4.54227 2 0 -2 4 186.657 4.22526 1 0 -2 -4 200.299 4.82624 1 0 2 4 193.582 5.32684 2 0 2 -4 193.709 4.27940 1 0 -2 -4 190.664 5.22544 2 0 2 4 193.313 4.82284 1 0 2 -5 199.938 4.82854 1 0 -2 5 200.164 4.86734 1 0 2 5 206.625 5.80319 2 0 -2 -5 213.673 5.81384 2 0 2 5 208.860 5.40664 1 0 -2 -5 208.119 5.34857 1 0 2 6 21.6765 2.54701 1 0 -2 -6 22.5223 2.56273 1 0 -2 -6 22.3638 2.46765 2 0 2 -6 19.1605 2.14920 1 0 2 6 17.9237 2.46840 2 0 -2 6 18.2290 2.15062 1 0 -2 -7 356.604 8.22402 2 0 -2 7 350.381 7.48884 1 0 2 7 357.776 8.08634 1 0 2 7 343.423 8.07071 2 0 2 -7 361.560 7.57958 1 0 -2 -7 351.696 8.03300 1 0 2 -8 138.875 5.25833 1 0 -2 -8 141.419 5.71174 2 0 2 8 142.020 5.64982 1 0 -2 8 144.516 5.33269 1 0 2 8 134.323 5.54853 2 0 -2 -8 134.542 5.58023 1 0 -2 -9 311.370 8.59976 1 0 2 9 289.787 8.14267 2 0 2 -9 289.032 7.83752 1 0 -2 -9 296.523 8.29198 2 0 2 9 288.857 8.30152 1 0 -2 9 309.453 8.08465 1 0 -2 10 22.8815 3.20956 1 0 2 10 20.4685 3.22512 2 0 2 10 20.0903 3.34101 1 0 -2 -10 22.2829 3.17756 2 0 -2 -10 18.7579 3.39328 1 0 2 -10 20.4936 3.01978 1 0 2 11 1059.52 16.4152 2 0 -2 11 1049.26 16.2582 1 0 2 11 1074.08 17.1866 1 0 -2 -11 1064.94 16.6020 2 0 -2 -11 1086.53 17.3119 1 0 2 -11 1028.25 16.0788 1 0 2 12 51.9145 4.49519 2 0 -2 -12 46.7335 4.45457 1 0 2 12 44.8482 4.69303 1 0 -2 12 50.8147 4.35118 1 0 -2 -12 61.5715 5.07435 2 0 2 -12 42.6112 4.41896 1 0 2 -13 115.020 6.54693 1 0 2 13 106.127 6.17560 2 0 2 13 110.844 6.75364 1 0 -2 -13 114.626 6.90567 1 0 -2 -13 118.301 6.51414 2 0 -2 13 105.336 6.32984 1 0 -2 14 12.4115 3.42567 1 0 2 14 11.4637 3.54206 2 0 2 -14 14.2038 3.48613 1 0 -2 -14 18.1293 4.14973 2 0 -2 -14 12.5393 3.58258 1 0 2 14 13.4013 3.28484 1 0 -2 -15 4.22906 3.91844 1 0 2 15 3.79042 3.91689 1 0 2 15-0.23032 2.96851 2 0 2 -15 1.39521 3.44014 1 0 -2 15 2.58589 3.64211 1 0 -2 16 34.1929 4.68388 1 0 2 16 36.2847 4.95228 1 0 2 16 40.3117 4.94112 2 0 -2 -16 33.5724 5.39962 1 0 2 -16 32.2254 5.06002 1 0 2 17 10.5274 4.41446 2 0 -2 -17 6.64594 3.64514 1 0 2 -17 4.95636 4.19614 1 0 -2 17 3.86489 3.89865 2 0 -2 17 6.25426 4.40707 1 0 2 17 4.44325 4.37580 1 0 2 18 109.602 8.20749 1 0 2 18 108.537 7.62442 2 0 -2 -18 110.078 8.49960 1 0 -2 18 100.371 7.03449 2 0 -2 18 114.405 8.28794 1 0 2 -18 119.702 8.27095 1 0 -2 19 2.12649 3.99933 2 0 -2 19-3.78270 4.00389 1 0 -2 -19-5.09944 5.34218 1 0 2 19 1.95727 4.86328 1 0 2 -19 0.28084 4.99434 1 0 2 19 0.42352 4.65532 2 0 2 -20 12.1195 4.96023 1 0 -2 20 10.8995 5.79480 1 0 2 20 5.19693 6.02015 1 0 -2 20 10.7736 4.67038 2 0 -2 -20 3.83969 4.90274 1 0 2 20 5.80258 4.64881 2 0 -2 21 39.2862 6.29708 2 0 -2 21 22.4617 6.66393 1 0 -2 -21 34.1867 6.76279 1 0 2 21 22.3716 6.23419 2 0 2 21 33.6372 7.08057 1 0 2 -21 25.7554 6.42202 1 0 -2 22-5.46977 5.40687 2 0 2 -22-7.34838 6.67883 1 0 -2 22 7.08145 5.44188 1 0 2 22 5.85533 5.24101 1 0 -2 -22-6.98318 7.30949 1 0 2 22 3.78280 5.92548 2 0 -2 23-1.52016 6.14045 1 0 2 23 7.51288 6.98603 1 0 -2 23 6.27173 5.60570 2 0 2 23 17.1980 6.72384 2 0 -2 -23 7.98269 7.67730 1 0 2 -23 9.26817 7.35280 1 0 2 -24 25.9654 7.80543 1 0 -2 24 12.9836 6.28092 2 0 2 24 23.0592 7.05975 2 0 2 24 13.1165 8.33028 1 0 -2 24 15.0084 7.96981 1 0 -2 -24 24.1921 7.91724 1 0 -2 25 21.1752 7.24413 2 0 -2 -25 19.5288 7.47409 1 0 -2 25 20.5310 9.27334 1 0 2 25-1.23734 9.66662 1 0 2 25-1.65891 7.18262 2 0 2 -25 13.4222 6.99458 1 0 -2 26-4.61209 7.78933 1 0 -2 26-9.49128 7.36795 2 0 2 26-6.01071 9.56545 1 0 -2 -26-1.36663 9.20728 1 0 2 26-6.58887 7.44196 2 0 2 -26-3.10213 7.47398 1 0 -2 27 1.34435 8.26314 2 0 2 -27-3.43183 8.90774 1 0 2 27 13.4705 10.5576 1 0 2 27 1.75979 8.27316 2 0 -2 -27-10.1056 10.8772 1 0 -2 27-2.87323 9.12694 1 0 2 -28-0.64241 10.4403 1 0 2 28 19.1632 10.8728 1 0 -2 28 6.10133 9.35343 2 0 -2 -28-11.5939 12.2751 1 0 2 28 2.94098 9.20133 2 0 -2 28-10.2063 11.2399 1 0 -2 29 47.5318 13.4338 1 0 -2 29 5.09570 9.25382 2 0 2 -29 36.9494 12.4469 1 0 2 29 0.35799 9.45562 2 0 -3 0-0.80748 1.91328 2 0 3 0 0.41435 1.77681 2 0 3 0-0.68653 1.08852 1 0 -3 0 0.81365 1.00817 1 0 -3 1 88.4204 2.70442 1 0 3 1 90.6687 4.13852 2 0 3 1 88.7334 2.93441 1 0 -3 -1 91.6241 2.85793 1 0 -3 -1 88.9389 4.01611 2 0 -3 1 89.2327 4.06293 2 0 3 2 264.381 6.61673 2 0 3 2 273.364 5.20856 1 0 -3 -2 261.321 6.67223 2 0 -3 -2 271.576 5.03783 1 0 -3 2 261.633 4.64400 1 0 -3 2 255.354 6.38100 2 0 -3 -3 2.51826 2.09300 2 0 3 3 1.25636 1.31478 1 0 3 3-0.76976 2.09144 2 0 3 -3 0.10143 1.06920 1 0 -3 3 1.38367 1.12940 1 0 -3 -3 1.93158 1.38083 1 0 3 4 192.392 6.04441 2 0 -3 4 187.830 4.40809 1 0 3 -4 186.996 4.46647 1 0 -3 -4 188.099 6.09118 2 0 3 4 185.910 5.04443 1 0 -3 -4 194.912 5.10266 1 0 3 5 111.348 4.33973 1 0 -3 -5 109.248 4.24786 1 0 3 5 107.160 4.77901 2 0 3 -5 109.880 3.82669 1 0 -3 5 111.046 3.80235 1 0 -3 -5 114.739 5.12587 2 0 -3 -6-0.75969 1.85653 2 0 3 6-1.73489 2.27739 2 0 -3 6 1.45942 1.59775 1 0 3 6 2.76147 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47.5545 2.93976 2 1 2 -2 1885.23 16.8034 1 -1 -2 2 1905.53 16.9190 1 -1 2 2 1960.73 10.4793 1 -1 2 2 1875.54 14.3591 2 1 -2 -2 1910.60 10.7107 1 1 -2 -2 1917.34 14.4874 2 1 -2 -1 42.6062 2.34962 2 -1 2 1 44.5034 1.62032 1 -1 2 1 43.8375 1.66289 1 -1 2 1 43.3170 2.36250 2 1 2 -1 39.3406 2.96708 1 -1 -2 1 44.3069 2.94308 1 1 -2 0 646.417 7.27197 2 -1 2 0 630.509 5.39414 1 -1 -2 0 637.660 9.39810 2 -1 -2 0 626.900 9.79071 1 -1 2 0 626.141 7.14691 2 1 -2 0 659.492 5.60646 1 1 2 0 642.157 9.97084 1 1 2 1 22.9620 2.73094 1 1 -2 1 22.2643 1.41296 1 -1 -2 -1 22.0920 2.45078 2 -1 2 -1 22.9360 1.60375 2 -1 -2 -1 24.2201 2.65524 1 1 -2 1 23.5776 1.61621 2 -1 2 -1 21.7409 1.30354 1 1 2 2 111.370 4.23330 2 -1 -2 -2 108.741 4.38396 1 1 -2 2 109.248 2.71400 2 -1 -2 -2 103.654 4.00936 2 1 -2 2 109.121 2.92129 1 -1 2 -2 110.868 2.79560 2 1 2 2 113.946 4.66252 1 -1 2 -2 110.559 2.85006 1 1 2 3 705.152 9.99177 2 1 -2 3 705.522 7.87415 1 -1 -2 -3 705.299 9.86206 2 1 2 3 712.402 11.3175 1 -1 2 -3 722.395 7.82759 1 -1 -2 -3 749.417 11.3575 1 1 -2 3 725.830 6.45161 2 1 -2 4 131.182 3.92952 1 1 -2 4 133.151 2.97262 2 1 2 4 134.368 4.68308 2 -1 -2 -4 134.239 4.66486 2 -1 2 -4 133.881 3.90784 1 1 2 4 132.239 5.25336 1 -1 -2 -4 142.348 5.40793 1 -1 -2 -5 1230.28 13.6855 2 -1 -2 -5 1247.24 15.7081 1 1 2 5 1171.24 13.4152 2 1 -2 5 1224.75 12.5025 1 1 2 5 1210.87 15.7359 1 -1 2 -5 1186.63 12.2623 1 -1 2 -6 19.4333 2.31095 1 1 2 6 13.8411 2.31302 2 1 -2 6 17.4296 2.25827 1 -1 -2 -6 17.6755 3.01026 1 1 2 6 18.6404 2.75969 1 -1 -2 -6 18.8666 2.49366 2 1 2 7 183.318 5.94331 2 -1 -2 -7 174.649 5.82610 2 -1 -2 -7 166.974 6.71829 1 1 2 7 177.349 6.92068 1 1 -2 7 167.396 5.65776 1 -1 2 -7 173.192 5.70669 1 -1 2 -8 41.7915 3.47600 1 -1 -2 -8 41.2952 4.17393 1 1 2 8 35.1582 3.63372 1 1 -2 8 40.4432 3.40843 1 1 2 8 37.9003 3.35179 2 -1 -2 -8 40.5844 3.42185 2 -1 -2 -9 8.92922 2.54930 2 1 -2 9 12.3183 2.68948 1 -1 -2 -9 9.37778 3.03775 1 1 2 9 9.19437 2.98417 1 -1 2 -9 10.8919 2.69708 1 1 2 9 8.51595 2.52494 2 -1 -2 -10 11.4725 3.07116 1 1 -2 10 14.7361 3.03903 1 -1 2 -10 16.8639 3.11397 1 1 2 10 10.3420 3.35393 1 -1 -2 -10 12.4247 2.84241 2 1 2 10 17.2802 3.01429 2 -1 -2 -11 5.81948 2.70574 2 1 -2 11 7.37382 2.99802 1 1 -2 11 9.67806 2.23850 2 -1 2 -11 12.2641 3.00911 1 1 2 11 12.5590 3.69444 1 1 2 11 5.80415 2.71017 2 -1 -2 -11 10.1825 3.63256 1 -1 2 -12 11.5945 3.48348 1 -1 -2 -12 8.05099 3.00814 2 1 -2 12 10.1908 2.40512 2 1 2 12 10.1042 3.67017 1 1 2 12 11.1913 3.06620 2 -1 -2 -12 9.77998 3.72580 1 1 -2 12 8.32908 3.26403 1 -1 -2 -13 6.65756 3.12735 2 -1 -2 -13 5.43413 3.83806 1 -1 2 -13 13.7487 3.59702 1 1 -2 13 11.0079 2.54149 2 1 2 13 11.8516 3.22924 2 1 2 13 11.2877 3.88571 1 1 -2 13 8.19311 3.53734 1 -1 -2 -14 112.548 6.58329 2 1 2 14 108.171 7.59165 1 1 2 14 126.096 6.71162 2 1 -2 14 112.159 5.47819 2 -1 -2 -14 107.422 7.30453 1 1 -2 14 108.613 6.95505 1 -1 2 -14 104.496 6.95071 1 -1 -2 -15 12.2814 3.93310 1 1 2 15 9.30612 4.75948 1 -1 -2 -15 8.47910 3.62535 2 1 -2 15 7.30776 3.63323 1 1 2 15 6.72758 3.44860 2 -1 2 -15 13.2096 4.42024 1 1 -2 15 5.98939 2.89659 2 -1 2 -16 15.4002 4.29933 1 1 -2 16 25.4072 5.26452 1 1 2 16 21.9493 5.53365 1 1 2 16 13.8371 4.16072 2 1 -2 16 20.6497 3.60761 2 -1 -2 -16 24.7621 4.76569 1 -1 -2 -17 44.5930 6.10885 1 1 -2 17 44.2894 4.56535 2 1 2 17 46.1179 6.96356 1 1 -2 17 54.2848 6.11966 1 1 2 17 37.6881 5.28430 2 -1 2 -17 45.9251 6.17222 1 -1 -2 -18 58.1756 7.59361 1 1 -2 18 49.8326 5.01149 2 1 2 18 59.5207 7.73864 1 1 2 18 56.8259 6.22097 2 1 -2 18 54.5649 6.96002 1 -1 2 -18 54.2946 7.12540 1 1 2 19 17.9380 5.03186 2 -1 2 -19 13.7675 5.63728 1 -1 -2 -19 20.1655 6.71194 1 1 -2 19 16.7748 5.90573 1 1 2 19 19.7133 6.69376 1 1 -2 19 19.9355 4.44121 2 1 -2 20-7.50481 4.29488 2 -1 -2 -20-1.58474 6.05842 1 1 2 20 7.14348 4.90959 2 1 2 20-6.06134 5.35422 1 -1 2 -20 5.64246 5.03193 1 1 -2 20 2.91278 5.24282 1 1 2 21 7.87052 6.65278 1 1 2 21 17.2810 5.79618 2 1 -2 21 16.7853 5.11938 2 1 -2 21 7.59228 6.66814 1 -1 2 -21 15.0343 6.78427 1 -1 -2 -21 14.2180 6.40273 1 -1 2 -22 4.40833 7.16788 1 -1 -2 -22 11.2370 8.20140 1 1 -2 22-2.26593 6.68526 1 1 -2 22 2.47844 4.84399 2 1 2 22 9.05618 5.74706 2 1 2 22 11.6170 8.23824 1 1 2 23 25.5916 7.90672 1 1 -2 23 11.9755 5.26716 2 -1 2 -23 9.48687 7.54821 1 -1 -2 -23 12.8181 7.11251 1 1 2 23 6.20263 6.23052 2 1 -2 23 7.43534 6.57881 1 1 2 24-2.60946 9.14056 1 -1 2 -24-1.35929 7.44966 1 -1 -2 -24 3.99567 9.35129 1 1 2 24-8.08497 7.15941 2 1 -2 24 3.78189 5.83369 2 1 -2 24 6.34666 7.13850 1 1 2 25-3.07315 9.06726 1 -1 -2 -25-8.74878 8.88168 1 1 2 25-5.11763 7.19962 2 1 -2 25-1.63717 6.25316 2 -1 2 -25 0.07203 8.41644 1 1 -2 25 26.3726 10.0017 1 1 -2 26-0.76896 10.5912 1 1 -2 26 8.15493 7.04166 2 -1 -2 -26 7.80987 10.8221 1 1 2 26-9.65532 9.92088 1 1 2 26 17.5449 8.25645 2 -1 2 -26 18.6639 10.6246 1 -1 2 -27-7.72787 11.5733 1 1 2 27-2.54591 12.9089 1 1 -2 27-3.33244 12.0591 1 1 2 27 15.7388 9.63976 2 1 -2 27 3.62044 7.92025 2 -1 -2 -27 2.85533 11.3963 1 -1 -3 29 12.3978 11.6758 2 -1 3 29-8.33148 10.3856 2 1 3 -29 11.1655 13.0248 1 1 -3 -29 7.78148 10.7013 1 -1 3 29 30.5229 14.0525 1 -1 -3 29-11.4923 11.0824 1 1 3 -28 10.7534 8.97751 1 -1 3 28-8.89862 10.4713 2 -1 -3 28 0.28038 10.8052 2 -1 -3 28 13.3783 11.2814 1 1 -3 -28 15.9920 9.61397 1 -1 3 27-6.87756 10.5544 1 -1 3 27 12.6913 8.72030 2 1 3 -27 16.2530 10.5563 1 -1 -3 27 5.29777 9.67048 2 -1 -3 27 8.72159 8.04612 1 1 -3 -27 0.07771 8.01515 1 1 3 -26 9.57813 7.58976 1 -1 -3 26-0.19244 8.52471 2 -1 3 26 8.57260 9.40790 1 -1 -3 26-8.05853 8.98785 1 -1 3 26 22.3558 8.60960 2 1 -3 -26 11.2570 7.75304 1 -1 -3 25 3.20264 8.15572 1 1 3 -25 3.29306 8.47693 1 -1 3 25 14.2649 8.21253 2 -1 -3 25 6.45048 7.98384 2 1 -3 -25 5.00663 7.49145 1 -1 3 25 0.63208 7.80315 1 -1 -3 24 7.74607 6.32600 1 -1 3 24-5.10672 7.88154 2 1 -3 -24-3.67628 7.39954 1 -1 3 24 14.7325 6.90026 1 1 3 -24 11.1823 7.54145 1 -1 -3 24 14.9720 7.35599 2 1 3 -23 1.09769 5.57618 1 -1 3 23 7.55159 7.22190 2 1 -3 -23 0.61827 7.08535 1 -1 -3 23 1.64933 7.08339 1 -1 -3 23-2.85535 6.82961 2 -1 3 23 1.24156 5.79485 1 -1 -3 22 13.6423 6.72519 1 1 -3 -22 17.2715 6.83284 1 -1 3 22 11.5477 5.61897 1 -1 3 22 22.2804 6.13846 2 1 3 -22 10.9767 5.64730 1 -1 3 21 17.3065 6.61945 2 1 3 -21 10.4946 5.67176 1 -1 -3 21 4.33285 5.86023 1 1 -3 -21 5.57106 5.10034 1 -1 3 21 8.69904 5.14949 1 -1 -3 20 6.51893 4.90881 1 -1 3 20-8.02403 5.63411 2 1 3 -20 5.79775 5.13307 1 1 -3 -20 1.33246 4.87718 1 -1 3 20 1.33310 4.36928 1 1 -3 -19 45.1392 6.92082 1 -1 3 19 45.5426 6.12263 1 1 3 -19 38.9164 5.76565 1 -1 -3 19 38.0442 6.05412 1 -1 3 19 29.4067 6.40067 2 -1 3 18 112.225 7.95668 1 -1 -3 18 112.518 8.27235 1 1 3 -18 101.987 7.95751 1 1 -3 -18 111.048 8.21963 1 -1 3 18 93.2007 7.56956 2 -1 -3 17 36.5418 5.71277 1 1 -3 -17 43.3157 5.75995 1 -1 3 17 48.3752 5.59987 1 1 3 -17 47.9822 6.21749 1 -1 3 17 41.6765 6.34869 2 1 3 -16 21.1678 4.60199 1 -1 -3 16 19.6433 4.78178 1 -1 3 16 26.4243 5.30215 2 1 -3 -16 20.7228 4.78194 1 -1 3 16 19.0340 4.05857 1 -1 -3 15 200.290 9.22680 1 1 3 -15 191.714 8.99611 1 -1 3 15 204.996 9.68870 2 -1 3 15 193.541 8.80962 1 1 -3 -15 183.459 8.67863 1 -1 -3 14 2.29451 3.20834 1 1 -3 -14 3.91739 3.48069 1 1 -3 -14 5.52907 3.78949 2 -1 3 14 3.43294 2.88462 1 -1 3 14 7.30541 3.76832 2 1 3 -14 5.89397 3.09578 1 1 3 -13 45.4094 4.85260 1 -1 3 13 39.4460 4.98035 2 1 -3 -13 44.1469 4.72712 1 1 -3 -13 43.7300 5.09332 2 -1 3 13 41.7608 4.37262 1 -1 -3 13 44.7641 4.87531 1 -1 3 12 42.5903 4.24192 1 -1 3 12 48.7399 5.24319 2 1 3 -12 40.8533 4.60900 1 1 -3 -12 53.9576 4.58782 1 1 -3 -12 47.4016 4.96907 2 -1 -3 12 47.9565 4.55300 1 1 -3 -11 47.5250 4.91582 2 -1 3 11 42.9288 4.24742 2 -1 3 11 46.7497 4.15526 1 -1 -3 11 44.3441 4.37496 1 1 -3 -11 46.7839 4.12143 1 1 3 -11 47.8754 4.61163 1 1 -3 -10 36.7596 4.45060 2 1 3 -10 37.2437 3.76412 1 -1 3 10 31.6943 4.19255 2 -1 -3 10 36.1670 3.73489 1 1 -3 -10 35.0310 3.57582 1 -1 3 10 35.6423 3.62813 1 1 -3 -9 9.19977 2.55119 1 -1 3 9 4.18216 3.00112 2 -1 -3 9 2.86307 2.52174 1 1 3 -9 4.68764 2.34814 1 1 -3 -9 8.29764 3.09760 2 -1 3 9 7.64335 2.41478 1 1 -3 -8 126.222 6.07833 2 -1 3 8 116.957 5.85642 2 1 -3 -8 117.822 4.96212 1 1 3 -8 121.855 5.72484 1 -1 -3 8 115.880 5.31803 1 -1 3 8 110.425 4.86210 1 -1 3 7 110.178 5.60182 2 1 -3 -7 106.664 5.46317 2 -1 -3 7 100.350 4.93771 1 1 -3 -7 108.408 4.46539 1 -1 3 7 99.9715 4.30438 1 1 3 -7 112.876 5.34858 1 -1 3 6 98.5836 5.12568 2 -1 -3 6 96.3358 4.71048 1 1 3 -6 95.2189 4.83153 1 1 -3 -6 99.1652 5.14433 2 1 -3 -6 99.0301 3.91783 1 -1 3 6 99.2633 3.92984 1 -1 3 5 102.331 4.76416 2 1 -3 -5 109.735 3.72552 1 -1 -3 5 114.184 4.85594 1 -1 3 5 109.698 3.74925 1 1 -3 -5 116.890 5.19576 2 -1 -3 5 110.239 5.02216 1 -1 3 4 217.334 4.52612 1 1 -3 -4 211.752 4.44836 1 -1 3 4 217.026 6.48320 2 -1 -3 4 217.330 6.39900 1 1 -3 -4 229.584 6.61993 2 -1 -3 4 222.082 6.68254 1 -1 3 3 120.266 4.80776 2 1 -3 -3 117.944 4.66437 2 -1 -3 3 122.195 5.03396 1 -1 3 3 120.225 2.95074 1 -1 -3 3 125.372 4.94060 1 1 -3 -3 119.795 2.95044 1 -1 -3 2 209.006 6.25178 1 1 3 -2 207.927 6.32728 1 1 -3 -2 209.560 3.13529 1 -1 3 2 209.815 3.07372 1 1 -3 -2 206.401 5.78350 2 -1 3 2 206.311 5.80487 2 -1 3 1 401.739 7.52713 2 -1 -3 1 394.477 8.43020 1 -1 -3 1 401.790 8.78738 2 1 -3 -1 411.151 7.62202 2 1 3 -1 405.693 8.59641 1 -1 3 0 71.0146 3.33985 2 -1 -3 0 66.5220 3.95684 2 -1 -3 0 68.3741 3.96338 1 1 3 0 67.2102 4.00941 1 1 -3 0 64.9886 3.20118 2 1 3 1 34.8516 3.05176 1 -1 -3 -1 33.9975 3.28803 2 -1 -3 -1 37.9586 3.17974 1 -1 3 -1 36.3128 2.50509 2 1 -3 1 36.2025 2.50694 2 -1 3 -2 124.714 2.40975 1 1 3 2 124.449 5.15106 2 -1 -3 -2 127.331 5.25103 2 -1 3 -2 122.541 4.01568 2 -1 -3 -2 126.456 5.19724 1 1 -3 2 124.187 2.49144 1 1 3 2 130.386 5.35069 1 1 -3 2 134.334 4.07309 2 -1 3 -3 33.7284 1.74488 1 -1 -3 -3 30.4309 2.95788 2 1 3 3 33.1012 3.29304 1 -1 -3 -3 33.2334 3.11595 1 1 3 3 32.8342 3.10749 2 1 -3 3 34.2072 2.27839 2 1 -3 3 33.6494 1.75560 1 1 3 4 25.2283 3.15499 2 1 -3 4 29.1896 1.96542 1 1 3 4 27.3753 3.03025 1 -1 -3 -4 28.4960 3.24198 1 1 -3 4 26.5803 2.11406 2 -1 3 -4 30.0688 1.98381 1 -1 -3 -4 28.8328 2.98564 2 -1 3 -5 243.794 5.42189 1 1 3 5 258.715 7.55259 2 1 -3 5 255.830 5.54567 1 -1 -3 -5 259.488 7.73465 1 -1 -3 -5 254.082 7.41235 2 1 3 5 251.168 7.92236 1 1 -3 5 248.488 5.40812 2 1 3 6 225.238 7.24789 2 1 -3 6 228.182 5.78490 1 -1 -3 -6 210.997 7.46179 1 -1 3 -6 237.557 5.89304 1 -1 -3 -6 226.981 7.23929 2 1 3 6 236.325 7.89636 1 1 3 7 8.65817 2.77119 2 1 3 7 7.19481 2.86599 1 -1 3 -7 5.38707 1.95523 1 -1 -3 -7 6.67807 2.73069 2 1 -3 7 4.38472 1.87325 1 -1 -3 -7 6.81370 2.91350 1 1 3 8 21.0778 3.25787 2 1 3 8 26.8921 3.71164 1 -1 3 -8 22.4154 2.77578 1 -1 -3 -8 20.4987 3.65571 1 -1 -3 -8 21.2768 3.30114 2 1 -3 8 21.1103 2.72289 1 1 3 9 13.3436 3.13276 2 -1 -3 -9 17.6815 3.60185 1 -1 -3 -9 9.34202 3.01197 2 -1 3 -9 11.8873 2.65814 1 1 3 9 14.6201 3.43288 1 1 -3 9 14.3879 2.73164 1 1 3 10 20.0162 3.57184 2 1 3 10 22.4826 4.00721 1 -1 -3 -10 17.8853 3.56465 1 -1 -3 -10 24.2442 3.53453 2 1 -3 10 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7.45700 1 -6 -5 7-4.60263 9.33835 2 -6 -5 7 3.28181 12.6817 1 -6 -5 7-7.20604 13.3183 1 -6 5 6 12.3871 6.80184 1 -6 5 6 6.64687 6.14930 2 -6 5 6-6.92988 7.60202 1 -6 -5 6-15.5237 10.3066 2 -6 -5 6 13.2076 12.7840 1 -6 -5 6 8.63233 13.0041 1 -6 5 5 7.60490 7.07292 1 -6 5 5-6.23710 8.08214 1 -6 5 5 4.87029 5.48040 2 -6 -5 5 20.3634 9.78381 2 -6 -5 5 4.38072 13.8253 1 -6 -5 5-5.08576 12.4906 1 -6 5 4 2.20363 7.27889 1 -6 5 4-1.33955 7.29470 1 -6 5 4 4.47355 4.24031 2 -6 -5 4-3.18994 9.39189 2 -6 -5 4-15.5305 12.7718 1 -6 -5 4 16.8219 13.4794 1 -6 5 3-6.29173 7.05864 1 -6 -5 3-4.71753 9.07807 2 -6 5 3 0.32846 2.37386 2 -6 -5 3-1.62496 12.7258 1 -6 5 3-10.6483 7.42194 1 -6 5 2 6.39509 7.55645 1 -6 -5 2 22.2529 13.3519 1 -6 -5 2-16.2186 10.1162 2 -6 5 2 9.82069 7.13380 1 6 5 -1 14.0994 12.9928 1 -6 5 1-1.58257 7.00105 1 -6 -5 1-6.23132 11.0174 1 -6 -5 1-8.89539 9.47327 2 -6 5 1-2.52927 7.46991 1 -6 5 0 7.53746 7.71507 1 -6 -5 0 1.27263 9.89193 1 -6 -5 0 23.4047 9.33133 2 -6 5 0 10.0710 7.48641 1 -6 -5 -1 6.06565 11.3220 1 6 5 1-17.2046 12.6215 1 -6 -5 -1 2.97053 8.55361 2 -6 5 -1-5.99074 7.44606 1 -6 5 -1-1.76197 7.61843 1 -6 -5 -2-4.85262 6.82118 2 -6 5 -2 1.68597 6.41896 1 -6 5 -2-9.10006 6.54944 1 -6 6 10 7.01175 4.37178 1 -6 6 10 11.7283 5.85349 2 -6 -6 10 15.6186 7.90527 2 -6 6 10 16.9518 5.14292 1 -6 6 9-2.71592 5.61997 1 -6 6 9 4.33836 6.91554 2 -6 6 9-7.97721 6.63657 1 -6 -6 9 4.42166 9.28182 2 -6 6 8 31.5925 7.12412 1 -6 6 8 24.7753 7.88965 2 -6 6 8 38.2599 7.46617 1 -6 -6 8 24.8393 11.2491 2 -6 6 7-0.07826 6.30999 1 -6 6 7 4.40716 6.82955 1 -6 6 7 9.06422 6.94347 2 -6 -6 7-8.38239 11.8362 2 -6 -6 7 16.5932 11.4025 1 -6 -6 7 11.7107 10.9658 1 -6 6 6 9.33935 6.29322 1 -6 6 6 2.44224 6.51792 1 -6 6 6-2.30368 6.58618 2 -6 -6 6 14.2585 10.9610 2 -6 -6 6-1.24848 11.4804 1 -6 -6 6-1.30721 11.4251 1 -6 6 5 10.5277 6.35541 1 -6 6 5 0.23037 6.43940 1 -6 6 5 7.56393 5.55399 2 -6 -6 5 0.77890 9.84962 2 -6 -6 5 18.0334 11.8269 1 -6 -6 5 19.7850 11.7271 1 -6 6 4 18.2770 6.20812 1 -6 6 4 19.9057 6.44132 1 -6 6 4 14.5736 4.27698 2 -6 6 3-7.37487 5.23551 1 -6 6 3-5.19361 5.34631 1 -6 -6 3-10.9439 8.21139 2 -6 6 2 18.3826 4.31062 1 -6 6 2 14.0009 4.16293 1 0 0 0 0.00 0.00 0 TITL 275_II in P2(1)/c REM P2(1)/c (#14 in standard setting) CELL 0.71073 4.882772 9.437163 21.725772 90.0000 103.0066 90.0000 ZERR 4.00 0.000301 0.000413 0.001115 0.0000 0.0056 0.0000 LATT 1 SYMM -x, y+1/2,-z+1/2 SFAC C H N O UNIT 28.00 52.00 4.00 32.00 TREF HKLF 4 END ; _shelx_hkl_checksum 1179 _shelx_res_file ; TITL 275_II in P2(1)/c 275_ii.res created by SHELXL-2018/3 at 16:24:32 on 31-Aug-2018 REM P2(1)/c (#14 in standard setting) CELL 0.71073 4.882772 9.437163 21.725772 90 103.0066 90 ZERR 4 0.000301 0.000413 0.001115 0 0.0056 0 LATT 1 SYMM -X,0.5+Y,0.5-Z SFAC C H N O UNIT 28 52 4 32 EQIV $1 1-X,1-Y,-Z EQIV $2 1+X,+Y,+Z EQIV $3 2-X,0.5+Y,0.5-Z EQIV $4 -1+X,1.5-Y,-0.5+Z EQIV $5 1-X,0.5+Y,0.5-Z L.S. 10 PLAN 20 SIZE 0.04 0.0951 1 TEMP 1.85 HTAB O4 O3_$1 HTAB O3 O4_$2 HTAB O6 O8_$3 HTAB O1 O7_$4 HTAB N1 O7 HTAB N1 O8_$5 HTAB N1 O2_$1 CONF BOND $H BOND fmap 2 acta SHEL 40 0.8 TWIN -1 0 0 0 -1 0 2 0 1 2 REM REM REM WGHT 0.035300 BASF 0.22655 FVAR 0.45518 O4 4 0.284172 0.646722 0.001114 11.00000 0.02283 0.03480 = 0.03622 0.01053 0.00104 -0.00572 AFIX 147 H4 2 0.368553 0.582812 0.023059 11.00000 -1.20000 AFIX 0 O3 4 0.726823 0.617159 -0.066844 11.00000 0.01862 0.02735 = 0.03314 -0.00284 -0.00053 0.00632 AFIX 147 H3 2 0.890789 0.627686 -0.047852 11.00000 -1.20000 AFIX 0 O6 4 0.872624 0.872839 0.052580 11.00000 0.03757 0.03164 = 0.02659 -0.00003 -0.00882 -0.00727 AFIX 147 H6 2 0.994955 0.876905 0.085297 11.00000 -1.20000 AFIX 0 O1 4 0.174830 0.862248 -0.117993 11.00000 0.03704 0.03810 = 0.02982 -0.00743 -0.01115 0.01863 AFIX 147 H1 2 0.038649 0.862376 -0.148017 11.00000 -1.20000 AFIX 0 C4 1 0.718025 0.760501 0.053709 11.00000 0.02423 0.02683 = 0.02430 -0.00386 0.00822 0.00364 C3 1 0.473278 0.757651 -0.003223 11.00000 0.02097 0.02385 = 0.02260 0.00226 0.00232 0.00031 AFIX 13 H3A 2 0.371627 0.847515 -0.004429 11.00000 -1.20000 AFIX 0 O5 4 0.760090 0.668720 0.093127 11.00000 0.03746 0.04199 = 0.02705 0.01033 -0.00083 -0.00243 O7 4 0.730606 0.583948 0.300722 11.00000 0.02255 0.02757 = 0.03007 0.00202 -0.00261 -0.00770 O8 4 0.708455 0.380730 0.351327 11.00000 0.03592 0.02860 = 0.03649 0.00859 -0.01258 -0.00096 O2 4 0.287844 0.664942 -0.163376 11.00000 0.03040 0.02966 = 0.02576 -0.00794 -0.00245 0.00271 C2 1 0.576808 0.744970 -0.064641 11.00000 0.02097 0.01941 = 0.02255 -0.00039 0.00195 -0.00008 AFIX 13 H2 2 0.701937 0.824913 -0.067146 11.00000 -1.20000 AFIX 0 C5 1 0.613080 0.469163 0.308989 11.00000 0.02148 0.02087 = 0.02127 -0.00342 0.00328 0.00330 C1 1 0.329701 0.750622 -0.121252 11.00000 0.01964 0.02106 = 0.02089 0.00317 0.00214 -0.00061 C6 1 0.335322 0.434330 0.264499 11.00000 0.02283 0.02201 = 0.02226 0.00047 0.00164 -0.00353 AFIX 23 H6A 2 0.361551 0.352228 0.239585 11.00000 -1.20000 H6B 2 0.201322 0.408478 0.289442 11.00000 -1.20000 AFIX 0 N1 3 0.392052 0.587611 0.175595 11.00000 0.04027 0.02633 = 0.02723 0.00475 0.01143 0.00918 AFIX 137 H1A 2 0.387386 0.516556 0.148443 11.00000 -1.50000 H1B 2 0.567901 0.600810 0.197236 11.00000 -1.50000 H1C 2 0.329544 0.666349 0.154516 11.00000 -1.50000 AFIX 0 C7 1 0.210646 0.552756 0.219980 11.00000 0.01999 0.02928 = 0.02376 0.00005 0.00047 -0.00022 AFIX 23 H7A 2 0.026143 0.524607 0.196103 11.00000 -1.20000 H7B 2 0.188093 0.636387 0.244322 11.00000 -1.20000 AFIX 0 HKLF 4 REM 275_II in P2(1)/c REM wR2 = 0.0808, GooF = S = 1.017, Restrained GooF = 1.017 for all data REM R1 = 0.0422 for 1439 Fo > 4sig(Fo) and 0.0741 for all 1993 data REM 151 parameters refined using 0 restraints END WGHT 0.0353 0.0000 REM Highest difference peak 0.170, deepest hole -0.201, 1-sigma level 0.047 Q1 1 0.8506 0.4022 0.3731 11.00000 0.05 0.17 Q2 1 0.5958 0.7492 0.0213 11.00000 0.05 0.17 Q3 1 0.1623 0.6331 -0.1973 11.00000 0.05 0.16 Q4 1 0.1779 0.6960 0.0803 11.00000 0.05 0.16 Q5 1 0.7820 0.5739 -0.0133 11.00000 0.05 0.16 Q6 1 0.2736 0.5207 0.3272 11.00000 0.05 0.16 Q7 1 -0.0613 0.9027 -0.1762 11.00000 0.05 0.16 Q8 1 0.2994 0.3534 0.2666 11.00000 0.05 0.16 Q9 1 0.2950 0.6565 -0.0424 11.00000 0.05 0.15 Q10 1 0.4195 0.7100 -0.0106 11.00000 0.05 0.15 Q11 1 0.3652 0.7074 0.2834 11.00000 0.05 0.15 Q12 1 0.4444 0.4562 0.2933 11.00000 0.05 0.15 Q13 1 0.5360 0.7650 -0.0368 11.00000 0.05 0.15 Q14 1 0.7280 0.6163 -0.1107 11.00000 0.05 0.15 Q15 1 0.6603 0.5815 0.0690 11.00000 0.05 0.15 Q16 1 0.3059 0.6446 -0.1205 11.00000 0.05 0.14 Q17 1 0.3730 0.2804 0.2064 11.00000 0.05 0.14 Q18 1 0.3562 0.2861 0.2494 11.00000 0.05 0.14 Q19 1 -0.0470 0.4433 0.1802 11.00000 0.05 0.14 Q20 1 0.2311 0.6939 -0.2190 11.00000 0.05 0.14 ; _shelx_res_checksum 80883 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy O O4 0.2842(3) 0.64672(15) 0.00111(8) 0.0322(4) Uani d 1 H H4 0.368553 0.582812 0.023059 0.039 Uiso calc 1 O O3 0.7268(3) 0.61716(15) -0.06684(8) 0.0274(4) Uani d 1 H H3 0.890789 0.627686 -0.047852 0.033 Uiso calc 1 O O6 0.8726(4) 0.87284(16) 0.05258(8) 0.0345(5) Uani d 1 H H6 0.994955 0.876905 0.085297 0.041 Uiso calc 1 O O1 0.1748(4) 0.86225(16) -0.11799(8) 0.0379(5) Uani d 1 H H1 0.038649 0.862376 -0.148017 0.046 Uiso calc 1 C C4 0.7180(5) 0.7605(2) 0.05371(11) 0.0247(5) Uani d 1 C C3 0.4733(5) 0.7577(2) -0.00322(11) 0.0229(5) Uani d 1 H H3A 0.371627 0.847515 -0.004429 0.027 Uiso calc 1 O O5 0.7601(4) 0.66872(17) 0.09313(8) 0.0368(5) Uani d 1 O O7 0.7306(3) 0.58395(15) 0.30072(7) 0.0281(4) Uani d 1 O O8 0.7085(4) 0.38073(15) 0.35133(8) 0.0369(5) Uani d 1 O O2 0.2878(4) 0.66494(15) -0.16338(8) 0.0300(4) Uani d 1 C C2 0.5768(5) 0.7450(2) -0.06464(10) 0.0214(5) Uani d 1 H H2 0.701937 0.824913 -0.067146 0.026 Uiso calc 1 C C5 0.6131(5) 0.4692(2) 0.30899(10) 0.0215(5) Uani d 1 C C1 0.3297(5) 0.7506(2) -0.12125(10) 0.0209(5) Uani d 1 C C6 0.3353(5) 0.4343(2) 0.26450(10) 0.0229(5) Uani d 1 H H6A 0.361551 0.352228 0.239585 0.027 Uiso calc 1 H H6B 0.201322 0.408478 0.289442 0.027 Uiso calc 1 N N1 0.3921(5) 0.58761(19) 0.17559(9) 0.0307(5) Uani d 1 H H1A 0.387386 0.516556 0.148443 0.046 Uiso calc 1 H H1B 0.567901 0.600810 0.197236 0.046 Uiso calc 1 H H1C 0.329544 0.666349 0.154516 0.046 Uiso calc 1 C C7 0.2106(5) 0.5528(2) 0.21998(11) 0.0250(6) Uani d 1 H H7A 0.026143 0.524607 0.196103 0.030 Uiso calc 1 H H7B 0.188093 0.636387 0.244322 0.030 Uiso calc 1 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 O4 0.0228(10) 0.0348(9) 0.0362(10) -0.0057(8) 0.0010(9) 0.0105(7) O3 0.0186(9) 0.0274(8) 0.0331(10) 0.0063(7) -0.0005(8) -0.0028(7) O6 0.0376(12) 0.0316(8) 0.0266(10) -0.0073(9) -0.0088(9) 0.0000(7) O1 0.0370(12) 0.0381(9) 0.0298(11) 0.0186(9) -0.0112(9) -0.0074(8) C4 0.0242(14) 0.0268(12) 0.0243(13) 0.0036(11) 0.0082(11) -0.0039(11) C3 0.0210(13) 0.0239(11) 0.0226(13) 0.0003(10) 0.0023(12) 0.0023(10) O5 0.0375(12) 0.0420(9) 0.0271(10) -0.0024(9) -0.0008(9) 0.0103(8) O7 0.0225(9) 0.0276(8) 0.0301(10) -0.0077(7) -0.0026(8) 0.0020(7) O8 0.0359(12) 0.0286(8) 0.0365(11) -0.0010(8) -0.0126(9) 0.0086(8) O2 0.0304(10) 0.0297(8) 0.0258(10) 0.0027(8) -0.0025(8) -0.0079(7) C2 0.0210(13) 0.0194(11) 0.0226(13) -0.0001(10) 0.0020(11) -0.0004(9) C5 0.0215(13) 0.0209(10) 0.0213(12) 0.0033(11) 0.0033(11) -0.0034(9) C1 0.0196(13) 0.0211(11) 0.0209(12) -0.0006(10) 0.0021(11) 0.0032(10) C6 0.0228(13) 0.0220(11) 0.0223(12) -0.0035(10) 0.0016(11) 0.0005(9) N1 0.0403(13) 0.0263(9) 0.0272(11) 0.0092(10) 0.0114(11) 0.0048(8) C7 0.0200(13) 0.0293(12) 0.0238(13) -0.0002(10) 0.0005(11) 0.0000(10) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _exptl_crystal_face_index_h _exptl_crystal_face_index_k _exptl_crystal_face_index_l _exptl_crystal_face_perp_dist 1 -1 -4 0.0320 -4 -3 4 0.0100 2 -2 -1 0.2800 4 3 -4 0.0300 -2 2 1 0.2270 -1 1 4 0.0240 loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle C3 O4 H4 109.5 C2 O3 H3 109.5 C4 O6 H6 109.5 C1 O1 H1 109.5 O6 C4 C3 110.64(19) O5 C4 O6 126.3(2) O5 C4 C3 123.1(2) O4 C3 C4 111.47(18) O4 C3 H3A 108.0 O4 C3 C2 110.39(18) C4 C3 H3A 108.0 C4 C3 C2 110.97(18) C2 C3 H3A 108.0 O3 C2 C3 111.69(17) O3 C2 H2 108.7 O3 C2 C1 108.97(17) C3 C2 H2 108.7 C1 C2 C3 110.16(18) C1 C2 H2 108.7 O7 C5 C6 117.90(19) O8 C5 O7 125.0(2) O8 C5 C6 117.14(19) O1 C1 C2 110.38(18) O2 C1 O1 125.5(2) O2 C1 C2 124.1(2) C5 C6 H6A 108.5 C5 C6 H6B 108.5 H6A C6 H6B 107.5 C7 C6 C5 114.93(18) C7 C6 H6A 108.5 C7 C6 H6B 108.5 H1A N1 H1B 109.5 H1A N1 H1C 109.5 H1B N1 H1C 109.5 C7 N1 H1A 109.5 C7 N1 H1B 109.5 C7 N1 H1C 109.5 C6 C7 H7A 109.3 C6 C7 H7B 109.3 N1 C7 C6 111.44(18) N1 C7 H7A 109.3 N1 C7 H7B 109.3 H7A C7 H7B 108.0 loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance O4 H4 0.8200 O4 C3 1.413(3) O3 H3 0.8200 O3 C2 1.418(2) O6 H6 0.8200 O6 C4 1.305(3) O1 H1 0.8200 O1 C1 1.308(3) C4 C3 1.514(3) C4 O5 1.203(3) C3 H3A 0.9800 C3 C2 1.534(3) O7 C5 1.258(3) O8 C5 1.252(2) O2 C1 1.204(2) C2 H2 0.9800 C2 C1 1.518(3) C5 C6 1.514(3) C6 H6A 0.9700 C6 H6B 0.9700 C6 C7 1.513(3) N1 H1A 0.8900 N1 H1B 0.8900 N1 H1C 0.8900 N1 C7 1.486(3) C7 H7A 0.9700 C7 H7B 0.9700 loop_ _geom_hbond_atom_site_label_D _geom_hbond_atom_site_label_H _geom_hbond_atom_site_label_A _geom_hbond_site_symmetry_A _geom_hbond_distance_DH _geom_hbond_distance_HA _geom_hbond_distance_DA _geom_hbond_angle_DHA _geom_hbond_publ_flag O4 H4 O3 3_665 0.82 2.21 2.877(2) 138.7 yes O3 H3 O4 1_655 0.82 1.98 2.803(2) 177.3 yes O6 H6 O8 2_755 0.82 1.76 2.574(2) 171.8 yes O1 H1 O7 4_475 0.82 1.73 2.521(2) 160.5 yes N1 H1A O2 3_665 0.89 2.31 2.895(2) 123.5 yes N1 H1B O7 . 0.89 2.22 2.846(2) 127.5 yes N1 H1C O8 2_655 0.89 2.03 2.847(2) 151.5 yes loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion O4 C3 C2 O3 -62.2(2) O4 C3 C2 C1 59.1(2) O3 C2 C1 O1 175.20(19) O3 C2 C1 O2 -6.0(3) O6 C4 C3 O4 -172.62(19) O6 C4 C3 C2 63.9(2) C4 C3 C2 O3 61.9(2) C4 C3 C2 C1 -176.82(17) C3 C2 C1 O1 52.3(2) C3 C2 C1 O2 -128.9(2) O5 C4 C3 O4 8.5(3) O5 C4 C3 C2 -115.0(2) O7 C5 C6 C7 -7.9(3) O8 C5 C6 C7 172.2(2) C5 C6 C7 N1 64.2(2) loop_ _twin_individual_id _twin_individual_mass_fraction_refined 1 0.7734(11) 2 0.2266(11) _cod_database_fobs_code 2021507