#------------------------------------------------------------------------------
#$Date: 2025-08-19 12:35:14 +0300 (Tue, 19 Aug 2025) $
#$Revision: 301801 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/02/16/2021636.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2021636
loop_
_publ_author_name
'Han, Lizhi'
'Jin, Longyi'
'Wang, Enbo'
'Su, Zhongmin'
_publ_section_title
;
 Synthesis and characterization of two isostructural 3d--4f
 coordination compounds based on pyridine-2,6-dicarboxylic acid and
 4,4'-bipyridine
;
_journal_coeditor_code           LF3091
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first
;
;
_journal_paper_doi               10.1107/S2053229619006004
_journal_volume                  75
_journal_year                    2019
_chemical_formula_iupac
'(C10 H10 N2) [Co Eu2 (C7 H3 N O4)6 (C10 H9 N2)2 (H2 O)2], 8H2 O'
_chemical_formula_moiety
'C10 H10 N2 2+, C62 H40 Co Eu2 N10 O26 2-, 16(H2 O)'
_chemical_formula_sum            'C72 H82 Co Eu2 N12 O42'
_chemical_formula_weight         2150.34
_chemical_name_systematic
'4,4'-Bipyridine-1,1'-diium diaquabis(μ₂-pyridine-2,6-dicarboxylato)tetrakis(pyridine-2,6-dicarboxylato)bis[4-(pyridin-4-yl)pyridinium]cobalt(II)dieuropium(III) octahydrate'
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                98.597(2)
_cell_angle_beta                 99.600(2)
_cell_angle_gamma                102.882(2)
_cell_formula_units_Z            1
_cell_length_a                   11.9021(19)
_cell_length_b                   12.680(2)
_cell_length_c                   14.867(2)
_cell_measurement_reflns_used    12178
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.000
_cell_measurement_theta_min      1.679
_cell_volume                     2115.5(6)
_computing_cell_refinement
;
APEX2 (Bruker, 2005)
;
_computing_data_collection
;
APEX2 (Bruker, 2005)
;
_computing_data_reduction
;
SAINT (Bruker, 2006)
;
_computing_molecular_graphics
;
SHELXTL (Sheldrick, 2008)
;
_computing_publication_material
;
SHELXTL (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015b)
;
_computing_structure_solution
;
SHELXT2014 (Sheldrick, 2015a)
;
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker SMART CCD APEXII'
_diffrn_measurement_method       '0.5° ω and 0.5° φ scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0190
_diffrn_reflns_av_unetI/netI     0.0317
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            12178
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_min         1.679
_exptl_absorpt_coefficient_mu    1.763
_exptl_absorpt_correction_T_max  0.700
_exptl_absorpt_correction_T_min  0.660
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(SADABS; Krause et al.,  2015)
;
_exptl_crystal_colour            pink
_exptl_crystal_density_diffrn    1.688
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1087
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.180
_refine_diff_density_max         1.014
_refine_diff_density_min         -0.667
_refine_ls_extinction_coef       0.0086(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.081
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     584
_refine_ls_number_reflns         7429
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.081
_refine_ls_R_factor_all          0.0278
_refine_ls_R_factor_gt           0.0259
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0405P)²+2.0276P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0741
_refine_ls_wR_factor_ref         0.0754
_reflns_number_gt                7015
_reflns_number_total             7429
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            lf3091sup1.cif
_cod_data_source_block           Eu
_cod_original_cell_volume        2115.6(6)
_cod_database_code               2021636
_cod_database_fobs_code          2021636
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.677
_shelx_estimated_absorpt_t_max   0.719
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
Eu Eu1 0.57553(2) 0.30582(2) 0.71494(2) 0.02178(8) Uani d 1
Co Co1 1.0000 0.5000 1.0000 0.02301(13) Uani d 1
O O1 0.6945(3) 0.5793(2) 0.5598(2) 0.0502(7) Uani d 1
O O2 0.6592(2) 0.47912(18) 0.66888(16) 0.0345(5) Uani d 1
O O3 0.4547(2) 0.13712(18) 0.61421(15) 0.0335(5) Uani d 1
O O4 0.3641(2) 0.0320(2) 0.47651(16) 0.0442(6) Uani d 1
O O5 0.4683(2) 0.21669(19) 0.82287(16) 0.0325(5) Uani d 1
O O6 0.4449(3) 0.1014(2) 0.9216(2) 0.0550(7) Uani d 1
O O7 0.7466(2) 0.26312(19) 0.66363(16) 0.0353(5) Uani d 1
O O8 0.8858(2) 0.1705(2) 0.66152(19) 0.0469(6) Uani d 1
O O9 0.3869(2) 0.3530(2) 0.68415(16) 0.0359(5) Uani d 1
O O10 0.2612(2) 0.4520(3) 0.7183(2) 0.0544(7) Uani d 1
O O11 0.74032(18) 0.39302(18) 0.84981(15) 0.0310(5) Uani d 1
O O12 0.83304(19) 0.52922(19) 0.97045(15) 0.0323(5) Uani d 1
O O13 0.95625(19) 0.35526(18) 0.89841(15) 0.0315(5) Uani d 1
H H13A 0.9899 0.3437 0.8531 0.038 Uiso d 1
H H13B 0.8896 0.3660 0.8777 0.038 Uiso d 1
N N1 0.5417(2) 0.3032(2) 0.54226(17) 0.0259(5) Uani d 1
N N2 0.5487(2) 0.4631(2) 0.83064(17) 0.0230(5) Uani d 1
N N3 0.6513(2) 0.1541(2) 0.77982(17) 0.0272(5) Uani d 1
N N4 1.0615(2) 0.5999(2) 0.90470(18) 0.0302(6) Uani d 1
N N5 1.2794(3) 0.9073(2) 0.5876(2) 0.0413(7) Uani d 1
H H5 1.3062 0.9448 0.5487 0.050 Uiso calc 1
C C1 0.5891(3) 0.3930(3) 0.5108(2) 0.0307(7) Uani d 1
C C2 0.5778(3) 0.3927(3) 0.4167(3) 0.0443(9) Uani d 1
H H2 0.6121 0.4555 0.3960 0.053 Uiso calc 1
C C3 0.5153(4) 0.2984(4) 0.3542(3) 0.0500(10) Uani d 1
H H3 0.5068 0.2967 0.2906 0.060 Uiso calc 1
C C4 0.4647(3) 0.2055(3) 0.3869(2) 0.0425(9) Uani d 1
H H4 0.4212 0.1410 0.3460 0.051 Uiso calc 1
C C5 0.4810(3) 0.2119(3) 0.4819(2) 0.0294(7) Uani d 1
C C6 0.6542(3) 0.4933(3) 0.5856(2) 0.0344(7) Uani d 1
C C7 0.4290(3) 0.1189(3) 0.5269(2) 0.0299(7) Uani d 1
C C8 0.7458(3) 0.1265(3) 0.7556(2) 0.0339(7) Uani d 1
C C9 0.7943(4) 0.0496(4) 0.7941(3) 0.0519(10) Uani d 1
H H9 0.8612 0.0329 0.7776 0.062 Uiso calc 1
C C10 0.7412(5) -0.0016(4) 0.8572(4) 0.0678(14) Uani d 1
H H10 0.7712 -0.0548 0.8828 0.081 Uiso calc 1
C C11 0.6441(4) 0.0261(3) 0.8824(3) 0.0520(10) Uani d 1
H H11 0.6082 -0.0070 0.9256 0.062 Uiso calc 1
C C12 0.6007(3) 0.1048(3) 0.8417(2) 0.0324(7) Uani d 1
C C13 0.7972(3) 0.1904(3) 0.6874(2) 0.0311(7) Uani d 1
C C14 0.4960(3) 0.1436(3) 0.8649(2) 0.0331(7) Uani d 1
C C15 0.6355(3) 0.5186(2) 0.9027(2) 0.0261(6) Uani d 1
C C16 0.6241(3) 0.6057(3) 0.9645(3) 0.0439(9) Uani d 1
H H16 0.6857 0.6432 1.0140 0.053 Uiso calc 1
C C17 0.5193(4) 0.6365(4) 0.9519(3) 0.0595(12) Uani d 1
H H17 0.5092 0.6949 0.9929 0.071 Uiso calc 1
C C18 0.4297(3) 0.5795(3) 0.8775(3) 0.0483(10) Uani d 1
H H18 0.3585 0.5992 0.8675 0.058 Uiso calc 1
C C19 0.4475(3) 0.4928(3) 0.8182(2) 0.0301(7) Uani d 1
C C20 0.7449(3) 0.4775(2) 0.9083(2) 0.0248(6) Uani d 1
C C21 0.3570(3) 0.4266(3) 0.7335(2) 0.0333(7) Uani d 1
C C22 1.1605(3) 0.6816(3) 0.9309(2) 0.0332(7) Uani d 1
H H22 1.2000 0.6968 0.9927 0.040 Uiso calc 1
C C23 1.2067(3) 0.7441(3) 0.8719(2) 0.0346(7) Uani d 1
H H23 1.2756 0.8002 0.8936 0.042 Uiso calc 1
C C24 1.1493(3) 0.7228(3) 0.7789(2) 0.0312(7) Uani d 1
C C25 1.0457(3) 0.6388(3) 0.7512(2) 0.0369(8) Uani d 1
H H25 1.0043 0.6219 0.6898 0.044 Uiso calc 1
C C26 1.0055(3) 0.5812(3) 0.8158(2) 0.0361(8) Uani d 1
H H26 0.9355 0.5262 0.7966 0.043 Uiso calc 1
C C27 1.3021(4) 0.9539(3) 0.6772(3) 0.0474(10) Uani d 1
H H27 1.3461 1.0267 0.6969 0.057 Uiso calc 1
C C28 1.2614(4) 0.8957(3) 0.7405(3) 0.0459(9) Uani d 1
H H28 1.2780 0.9290 0.8030 0.055 Uiso calc 1
C C29 1.1954(3) 0.7869(3) 0.7119(2) 0.0330(7) Uani d 1
C C30 1.1734(4) 0.7413(3) 0.6181(3) 0.0453(9) Uani d 1
H H30 1.1298 0.6686 0.5962 0.054 Uiso calc 1
C C31 1.2164(4) 0.8044(3) 0.5573(3) 0.0490(10) Uani d 1
H H31 1.2008 0.7740 0.4942 0.059 Uiso calc 1
N N6 0.8356(3) 0.7843(2) 0.5813(2) 0.0407(7) Uani d 1
H H6 0.7956 0.7307 0.6013 0.049 Uiso calc 1
C C32 0.9168(3) 0.8635(3) 0.6418(3) 0.0438(9) Uani d 1
H H32 0.9292 0.8605 0.7047 0.053 Uiso calc 1
C C33 0.9831(3) 0.9502(3) 0.6120(2) 0.0383(8) Uani d 1
H H33 1.0397 1.0057 0.6547 0.046 Uiso calc 1
C C34 0.9651(3) 0.9541(2) 0.5175(2) 0.0285(7) Uani d 1
C C35 0.8770(3) 0.8697(3) 0.4575(3) 0.0400(8) Uani d 1
H H35 0.8608 0.8706 0.3943 0.048 Uiso calc 1
C C36 0.8140(3) 0.7853(3) 0.4910(3) 0.0447(9) Uani d 1
H H36 0.7562 0.7288 0.4504 0.054 Uiso calc 1
O O14 0.8869(3) 0.4359(2) 0.5899(2) 0.0582(8) Uani d 1
H H14A 0.8292 0.3859 0.5956 0.070 Uiso d 1
H H14B 0.8666 0.4613 0.5417 0.070 Uiso d 1
O O16 0.8988(4) 0.7793(3) 0.9531(3) 0.0811(11) Uani d 1
H H16A 0.8818 0.7118 0.9578 0.097 Uiso d 1
H H16B 0.8628 0.8135 0.9874 0.097 Uiso d 1
O O17 0.0819(3) 0.3147(4) 0.7676(3) 0.0899(13) Uani d 1
H H17A 0.0260 0.2773 0.7233 0.108 Uiso d 1
H H17B 0.1271 0.3627 0.7468 0.108 Uiso d 1
O O18 1.0249(3) 0.9265(3) 0.8572(3) 0.0814(11) Uani d 1
H H18A 0.9947 0.8887 0.8939 0.098 Uiso d 1
H H18B 1.0821 0.9786 0.8890 0.098 Uiso d 1
O O19 0.7689(3) 0.7136(3) 0.7568(2) 0.0783(11) Uani d 1
H H19A 0.7458 0.6437 0.7425 0.118 Uiso d 1
H H19B 0.7940 0.7274 0.8154 0.118 Uiso d 1
O O20 0.2155(3) 0.1689(3) 0.7752(3) 0.0884(12) Uani d 1
H H20A 0.2807 0.1986 0.7622 0.106 Uiso d 1
H H20B 0.1694 0.2111 0.7701 0.106 Uiso d 1
O O15 1.1020(3) 0.4336(3) 0.5513(2) 0.0731(10) Uani d 1
H H15A 1.1494 0.4673 0.6019 0.088 Uiso d 1
H H15B 1.0356 0.4064 0.5636 0.088 Uiso d 1
O O21 0.2206(3) 0.1115(4) 0.9370(3) 0.1004(14) Uani d 1
H H21A 0.2906 0.1043 0.9439 0.121 Uiso d 1
H H21B 0.2037 0.1308 0.8851 0.121 Uiso d 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
O3 Eu1 O7 . . 88.73(8)
O3 Eu1 O9 . . 79.51(8)
O7 Eu1 O9 . . 151.08(8)
O3 Eu1 O2 . . 127.13(7)
O7 Eu1 O2 . . 79.96(8)
O9 Eu1 O2 . . 86.24(8)
O3 Eu1 O5 . . 78.31(8)
O7 Eu1 O5 . . 126.47(8)
O9 Eu1 O5 . . 77.10(8)
O2 Eu1 O5 . . 146.61(8)
O3 Eu1 O11 . . 147.25(8)
O7 Eu1 O11 . . 76.01(8)
O9 Eu1 O11 . . 126.21(8)
O2 Eu1 O11 . . 79.09(8)
O5 Eu1 O11 . . 87.66(8)
O3 Eu1 N1 . . 63.25(7)
O7 Eu1 N1 . . 73.61(8)
O9 Eu1 N1 . . 77.50(8)
O2 Eu1 N1 . . 63.99(8)
O5 Eu1 N1 . . 136.95(8)
O11 Eu1 N1 . . 135.30(8)
O3 Eu1 N2 . . 137.93(8)
O7 Eu1 N2 . . 133.32(8)
O9 Eu1 N2 . . 63.53(8)
O2 Eu1 N2 . . 72.08(8)
O5 Eu1 N2 . . 74.60(8)
O11 Eu1 N2 . . 62.69(7)
N1 Eu1 N2 . . 122.17(8)
O3 Eu1 N3 . . 75.68(8)
O7 Eu1 N3 . . 63.42(8)
O9 Eu1 N3 . . 136.29(8)
O2 Eu1 N3 . . 137.25(8)
O5 Eu1 N3 . . 63.06(8)
O11 Eu1 N3 . . 71.59(8)
N1 Eu1 N3 . . 120.10(8)
N2 Eu1 N3 . . 117.61(8)
O12 Co1 O12 . 2_767 180.00(13)
O12 Co1 O13 . . 94.28(9)
O12 Co1 O13 2_767 . 85.72(9)
O12 Co1 O13 . 2_767 85.72(9)
O12 Co1 O13 2_767 2_767 94.28(9)
O13 Co1 O13 . 2_767 180.00(12)
O12 Co1 N4 . 2_767 88.52(10)
O12 Co1 N4 2_767 2_767 91.48(10)
O13 Co1 N4 . 2_767 87.96(10)
O13 Co1 N4 2_767 2_767 92.04(10)
O12 Co1 N4 . . 91.48(10)
O12 Co1 N4 2_767 . 88.52(10)
O13 Co1 N4 . . 92.04(10)
O13 Co1 N4 2_767 . 87.96(10)
N4 Co1 N4 2_767 . 180.0
C6 O2 Eu1 . . 125.3(2)
C7 O3 Eu1 . . 126.45(19)
C14 O5 Eu1 . . 125.8(2)
C13 O7 Eu1 . . 126.3(2)
C21 O9 Eu1 . . 125.7(2)
C20 O11 Eu1 . . 124.86(19)
C20 O12 Co1 . . 129.6(2)
Co1 O13 H13A . . 126.1
Co1 O13 H13B . . 91.3
H13A O13 H13B . . 108.6
C5 N1 C1 . . 119.5(3)
C5 N1 Eu1 . . 120.50(19)
C1 N1 Eu1 . . 119.9(2)
C19 N2 C15 . . 119.2(3)
C19 N2 Eu1 . . 119.5(2)
C15 N2 Eu1 . . 121.20(19)
C12 N3 C8 . . 119.2(3)
C12 N3 Eu1 . . 120.5(2)
C8 N3 Eu1 . . 120.2(2)
C26 N4 C22 . . 116.8(3)
C26 N4 Co1 . . 121.8(2)
C22 N4 Co1 . . 121.3(2)
C31 N5 C27 . . 121.2(3)
C31 N5 H5 . . 119.4
C27 N5 H5 . . 119.4
N1 C1 C2 . . 121.5(3)
N1 C1 C6 . . 115.1(3)
C2 C1 C6 . . 123.4(3)
C3 C2 C1 . . 119.1(3)
C3 C2 H2 . . 120.5
C1 C2 H2 . . 120.4
C2 C3 C4 . . 119.4(3)
C2 C3 H3 . . 120.3
C4 C3 H3 . . 120.3
C5 C4 C3 . . 118.1(3)
C5 C4 H4 . . 121.0
C3 C4 H4 . . 121.0
N1 C5 C4 . . 122.4(3)
N1 C5 C7 . . 113.8(3)
C4 C5 C7 . . 123.7(3)
O1 C6 O2 . . 127.1(3)
O1 C6 C1 . . 117.3(3)
O2 C6 C1 . . 115.6(3)
O4 C7 O3 . . 125.2(3)
O4 C7 C5 . . 119.0(3)
O3 C7 C5 . . 115.8(3)
N3 C8 C9 . . 121.9(3)
N3 C8 C13 . . 114.3(3)
C9 C8 C13 . . 123.8(3)
C10 C9 C8 . . 118.6(4)
C10 C9 H9 . . 120.7
C8 C9 H9 . . 120.7
C11 C10 C9 . . 119.9(4)
C11 C10 H10 . . 120.1
C9 C10 H10 . . 120.1
C10 C11 C12 . . 118.4(4)
C10 C11 H11 . . 120.8
C12 C11 H11 . . 120.8
N3 C12 C11 . . 121.9(3)
N3 C12 C14 . . 114.6(3)
C11 C12 C14 . . 123.4(3)
O8 C13 O7 . . 125.6(3)
O8 C13 C8 . . 118.6(3)
O7 C13 C8 . . 115.8(3)
O6 C14 O5 . . 126.1(3)
O6 C14 C12 . . 118.1(3)
O5 C14 C12 . . 115.8(3)
N2 C15 C16 . . 122.2(3)
N2 C15 C20 . . 113.9(3)
C16 C15 C20 . . 124.0(3)
C15 C16 C17 . . 118.7(3)
C15 C16 H16 . . 120.6
C17 C16 H16 . . 120.6
C16 C17 C18 . . 119.2(3)
C16 C17 H17 . . 120.4
C18 C17 H17 . . 120.4
C17 C18 C19 . . 118.9(3)
C17 C18 H18 . . 120.6
C19 C18 H18 . . 120.6
N2 C19 C18 . . 121.8(3)
N2 C19 C21 . . 114.8(3)
C18 C19 C21 . . 123.4(3)
O12 C20 O11 . . 125.2(3)
O12 C20 C15 . . 117.9(3)
O11 C20 C15 . . 116.9(3)
O10 C21 O9 . . 126.4(3)
O10 C21 C19 . . 117.2(3)
O9 C21 C19 . . 116.4(3)
N4 C22 C23 . . 123.7(3)
N4 C22 H22 . . 118.1
C23 C22 H22 . . 118.1
C22 C23 C24 . . 119.2(3)
C22 C23 H23 . . 120.4
C24 C23 H23 . . 120.4
C25 C24 C23 . . 117.5(3)
C25 C24 C29 . . 120.8(3)
C23 C24 C29 . . 121.6(3)
C26 C25 C24 . . 119.0(3)
C26 C25 H25 . . 120.5
C24 C25 H25 . . 120.5
N4 C26 C25 . . 123.7(3)
N4 C26 H26 . . 118.1
C25 C26 H26 . . 118.1
N5 C27 C28 . . 120.5(3)
N5 C27 H27 . . 119.7
C28 C27 H27 . . 119.7
C27 C28 C29 . . 120.3(3)
C27 C28 H28 . . 119.9
C29 C28 H28 . . 119.9
C30 C29 C28 . . 117.5(3)
C30 C29 C24 . . 121.2(3)
C28 C29 C24 . . 121.2(3)
C31 C30 C29 . . 119.6(3)
C31 C30 H30 . . 120.2
C29 C30 H30 . . 120.2
N5 C31 C30 . . 120.9(3)
N5 C31 H31 . . 119.6
C30 C31 H31 . . 119.6
C32 N6 C36 . . 122.0(3)
C32 N6 H6 . . 119.0
C36 N6 H6 . . 119.0
N6 C32 C33 . . 120.4(3)
N6 C32 H32 . . 119.8
C33 C32 H32 . . 119.8
C32 C33 C34 . . 119.8(3)
C32 C33 H33 . . 120.1
C34 C33 H33 . . 120.1
C35 C34 C33 . . 117.2(3)
C35 C34 C34 . 2_776 121.4(4)
C33 C34 C34 . 2_776 121.4(4)
C36 C35 C34 . . 120.5(3)
C36 C35 H35 . . 119.7
C34 C35 H35 . . 119.7
N6 C36 C35 . . 120.1(3)
N6 C36 H36 . . 120.0
C35 C36 H36 . . 120.0
H14A O14 H14B . . 109.0
H16A O16 H16B . . 108.4
H17A O17 H17B . . 108.8
H18A O18 H18B . . 108.7
H19A O19 H19B . . 104.5
H20A O20 H20B . . 109.7
H15A O15 H15B . . 108.4
H21A O21 H21B . . 107.9
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Eu1 O3 . 2.416(2) ?
Eu1 O7 . 2.431(2) ?
Eu1 O9 . 2.438(2) ?
Eu1 O2 . 2.448(2) ?
Eu1 O5 . 2.462(2) ?
Eu1 O11 . 2.480(2) ?
Eu1 N1 . 2.526(2) ?
Eu1 N2 . 2.546(2) ?
Eu1 N3 . 2.546(3) ?
Co1 O12 . 2.089(2) ?
Co1 O12 2_767 2.089(2) ?
Co1 O13 . 2.098(2) ?
Co1 O13 2_767 2.098(2) ?
Co1 N4 2_767 2.148(3) ?
Co1 N4 . 2.149(3) ?
O1 C6 . 1.233(4) ?
O2 C6 . 1.271(4) ?
O3 C7 . 1.256(4) ?
O4 C7 . 1.246(4) ?
O5 C14 . 1.264(4) ?
O6 C14 . 1.236(4) ?
O7 C13 . 1.270(4) ?
O8 C13 . 1.244(4) ?
O9 C21 . 1.252(4) ?
O10 C21 . 1.247(4) ?
O11 C20 . 1.259(4) ?
O12 C20 . 1.255(4) ?
O13 H13A . 0.8501 ?/c/coeditors/2019_CVs
O13 H13B . 0.8497 ?
N1 C5 . 1.330(4) ?
N1 C1 . 1.339(4) ?
N2 C19 . 1.332(4) ?
N2 C15 . 1.338(4) ?
N3 C12 . 1.337(4) ?
N3 C8 . 1.339(4) ?
N4 C26 . 1.337(4) ?
N4 C22 . 1.340(4) ?
N5 C31 . 1.319(5) ?
N5 C27 . 1.332(5) ?
N5 H5 . 0.8600 ?
C1 C2 . 1.382(5) ?
C1 C6 . 1.518(5) ?
C2 C3 . 1.374(6) ?
C2 H2 . 0.9300 ?
C3 C4 . 1.393(5) ?
C3 H3 . 0.9300 ?
C4 C5 . 1.380(5) ?
C4 H4 . 0.9300 ?
C5 C7 . 1.507(4) ?
C8 C9 . 1.384(5) ?
C8 C13 . 1.513(5) ?
C9 C10 . 1.378(6) ?
C9 H9 . 0.9300 ?
C10 C11 . 1.373(6) ?
C10 H10 . 0.9300 ?
C11 C12 . 1.390(5) ?
C11 H11 . 0.9300 ?
C12 C14 . 1.511(5) ?
C15 C16 . 1.375(5) ?
C15 C20 . 1.501(4) ?
C16 C17 . 1.379(6) ?
C16 H16 . 0.9300 ?
C17 C18 . 1.381(6) ?
C17 H17 . 0.9300 ?
C18 C19 . 1.382(5) ?
C18 H18 . 0.9300 ?
C19 C21 . 1.509(5) ?
C22 C23 . 1.370(5) ?
C22 H22 . 0.9300 ?
C23 C24 . 1.393(5) ?
C23 H23 . 0.9300 ?
C24 C25 . 1.392(5) ?
C24 C29 . 1.477(4) ?
C25 C26 . 1.376(5) ?
C25 H25 . 0.9300 ?
C26 H26 . 0.9300 ?
C27 C28 . 1.366(5) ?
C27 H27 . 0.9300 ?
C28 C29 . 1.389(5) ?
C28 H28 . 0.9300 ?
C29 C30 . 1.384(5) ?
C30 C31 . 1.382(5) ?
C30 H30 . 0.9300 ?
C31 H31 . 0.9300 ?
N6 C32 . 1.326(5) ?
N6 C36 . 1.327(5) ?
N6 H6 . 0.8600 ?
C32 C33 . 1.380(5) ?
C32 H32 . 0.9300 ?
C33 C34 . 1.395(5) ?
C33 H33 . 0.9300 ?
C34 C35 . 1.394(5) ?
C34 C34 2_776 1.486(6) ?
C35 C36 . 1.371(5) ?
C35 H35 . 0.9300 ?
C36 H36 . 0.9300 ?
O14 H14A . 0.8499 ?
O14 H14B . 0.8498 ?
O16 H16A . 0.8498 ?
O16 H16B . 0.8501 ?
O17 H17A . 0.8500 ?
O17 H17B . 0.8500 ?
O18 H18A . 0.8503 ?
O18 H18B . 0.8499 ?
O19 H19A . 0.8499 ?
O19 H19B . 0.8503 ?
O20 H20A . 0.8499 ?
O20 H20B . 0.8499 ?
O15 H15A . 0.8500 ?
O15 H15B . 0.8500 ?
O21 H21A . 0.8499 ?
O21 H21B . 0.8500 ?
loop_
_cod_related_entry_id
_cod_related_entry_database
_cod_related_entry_code
1 PubChem 168308076
