#------------------------------------------------------------------------------ #$Date: 2019-06-15 07:17:17 +0300 (Sat, 15 Jun 2019) $ #$Revision: 216003 $ #$URL: file:///home/coder/svn-repositories/cod/cif/2/02/16/2021671.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2021671 loop_ _publ_author_name 'Nicholls, Daniel' 'Elleman, Carole' 'Shankland, Norman' 'Shankland, Kenneth' _publ_section_title ; A new crystalline form of \a\b-D-lactose prepared by oven drying a concentrated aqueous solution of D-lactose ; _journal_coeditor_code KY3180 _journal_issue 7 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first ; ; _journal_paper_doi 10.1107/S2053229619008210 _journal_volume 75 _journal_year 2019 _chemical_absolute_configuration rm _chemical_formula_iupac 'C12 H22 O11' _chemical_formula_moiety 'C12 H22 O11' _chemical_formula_sum 'C12 H22 O11' _chemical_formula_weight 342.29 _chemical_name_common ; \a\b-D-Lactose ; _chemical_name_systematic ; \a\b-D-Lactose ; _space_group_crystal_system monoclinic _space_group_IT_number 4 _space_group_name_Hall 'P 2yb' _space_group_name_H-M_alt 'P 1 21 1' _symmetry_space_group_name_Hall 'P 2yb' _symmetry_space_group_name_H-M 'P 1 21 1' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary dual _audit_creation_method ; Olex2 1.2 (compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506) ; _cell_angle_alpha 90 _cell_angle_beta 106.200(5) _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 5.0044(3) _cell_length_b 38.6364(14) _cell_length_c 7.6007(4) _cell_measurement_reflns_used 3068 _cell_measurement_temperature 99.99(10) _cell_measurement_theta_max 72.1720 _cell_measurement_theta_min 4.5350 _cell_volume 1411.26(13) _computing_cell_refinement ; CrysAlis PRO (Rigaku OD, 2019) ; _computing_data_collection ; CrysAlis PRO (Rigaku OD, 2019) ; _computing_data_reduction ; CrysAlis PRO (Rigaku OD, 2019) ; _computing_molecular_graphics ; OLEX2 (Dolomanov et al., 2009) ; _computing_publication_material ; OLEX2 (Dolomanov et al., 2009) ; _computing_structure_refinement ; SHELXL2017 (Sheldrick, 2015b) ; _computing_structure_solution ; SHELXT (Sheldrick, 2015a) ; _diffrn_ambient_temperature 99.99(10) _diffrn_detector 'CCD plate' _diffrn_detector_area_resol_mean 10.0000 _diffrn_measured_fraction_theta_full 0.999 _diffrn_measured_fraction_theta_max 0.999 _diffrn_measurement_device 'four-circle diffractometer' _diffrn_measurement_device_type 'XtaLAB Synergy Dualflex HyPix' _diffrn_measurement_method '\w scans' _diffrn_radiation_monochromator mirror _diffrn_radiation_probe x-ray _diffrn_radiation_type CuK\a _diffrn_radiation_wavelength 1.54184 _diffrn_reflns_av_R_equivalents 0.0571 _diffrn_reflns_av_unetI/netI 0.0744 _diffrn_reflns_limit_h_max 5 _diffrn_reflns_limit_h_min -5 _diffrn_reflns_limit_k_max 41 _diffrn_reflns_limit_k_min -46 _diffrn_reflns_limit_l_max 9 _diffrn_reflns_limit_l_min -8 _diffrn_reflns_number 8132 _diffrn_reflns_theta_full 67.107 _diffrn_reflns_theta_max 67.107 _diffrn_reflns_theta_min 4.578 _diffrn_source 'micro-focus sealed X-ray tube' _exptl_absorpt_coefficient_mu 1.258 _exptl_absorpt_correction_T_max 1.00000 _exptl_absorpt_correction_T_min 0.80433 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; (CrysAlis PRO; Rigaku OD, 2019) ; _exptl_crystal_colour colourless _exptl_crystal_density_diffrn 1.611 _exptl_crystal_description 'clear block' _exptl_crystal_F_000 728 _exptl_crystal_size_max 0.076 _exptl_crystal_size_mid 0.024 _exptl_crystal_size_min 0.018 _refine_diff_density_max 0.382 _refine_diff_density_min -0.251 _refine_ls_abs_structure_details ; Flack x determined using 989 quotients [(I+)-(I-)]/[(I+)+(I-)] (Parsons et al., 2013) ; _refine_ls_abs_structure_Flack -0.3(2) _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.015 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 431 _refine_ls_number_reflns 3861 _refine_ls_number_restraints 2 _refine_ls_restrained_S_all 1.015 _refine_ls_R_factor_all 0.0576 _refine_ls_R_factor_gt 0.0475 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.0705P)^2^] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.1149 _refine_ls_wR_factor_ref 0.1198 _reflns_number_gt 3316 _reflns_number_total 3861 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file ky3180sup1.cif _cod_data_source_block I _cod_database_code 2021671 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_estimated_absorpt_t_min 0.917 _shelx_estimated_absorpt_t_max 0.981 _shelx_hkl_file ; 0 -46 0 178.084 16.2366 8 0 -45 0 4.56060 12.6705 8 0 -45 0-2.55096 10.0836 7 0 -45 -1 29.0363 10.7209 7 0 -44 0 23.2495 11.6514 7 0 -44 0 26.7575 14.2905 8 0 -44 -1 35.3818 12.1028 7 0 -44 1 53.0108 13.0694 8 0 -44 -2 204.331 18.4399 8 0 -43 0-5.89487 12.2449 7 0 -43 0-8.02757 15.0183 8 0 -43 1 54.0562 14.2627 8 0 -43 -1 51.9962 13.7283 7 0 -43 1 47.1416 12.1326 7 0 -43 -2 105.324 16.1293 8 0 -43 -3-11.2825 11.5734 8 0 -42 0 527.623 35.7166 8 0 -42 0 548.392 34.4400 7 0 -42 1 35.0863 15.1308 8 0 -42 1 18.9611 12.5947 7 0 -42 -2 403.021 28.6950 8 0 -42 -3 129.664 15.3543 8 0 -41 0 6.32780 14.4280 7 0 -41 0-1.16311 16.9671 8 0 -41 1 152.051 16.8674 7 0 -41 1 165.714 19.4113 8 0 -41 2 42.9887 12.5474 7 0 -41 -2 43.9452 16.2724 8 0 -41 -3 301.219 20.4557 8 0 -41 -3 185.180 18.6585 15 0 -41 -4 299.733 20.6751 8 0 -40 0 157.379 20.8545 8 0 -40 0 140.242 18.4029 7 0 -40 1-1.20508 13.7893 7 0 -40 -1-4.89913 17.5555 9 0 -40 1-5.77587 16.3010 8 0 -40 2 68.9949 14.0008 7 0 -40 -2 94.7376 17.1353 9 0 -40 -2 78.5348 17.9069 8 0 -40 -3 85.5809 15.4763 8 0 -40 -3 57.7687 14.2449 15 0 -40 -4 42.6780 11.6503 8 0 -40 -4 18.1408 12.4573 15 0 -39 0-5.21256 18.4407 8 0 -39 1 182.265 21.2803 8 0 -39 1 158.299 18.5961 7 0 -39 -1 196.169 22.3624 9 0 -39 -2 78.7992 17.0788 9 0 -39 2 66.2116 15.7371 8 0 -39 2 85.0447 14.6363 7 0 -39 -2 85.6032 17.8362 8 0 -39 -2 52.1450 14.5048 15 0 -39 -3 193.862 19.3380 8 0 -39 -3 160.961 17.8538 9 0 -39 -4 131.059 17.1475 15 0 -39 -4 186.963 16.1820 8 0 -38 0 192.318 22.6366 8 0 -38 -1 76.5251 18.9853 9 0 -38 1 49.5975 17.7294 8 0 -38 1 57.5222 15.7022 7 0 -38 -2 246.017 23.7546 8 0 -38 -2 235.680 22.9627 9 0 -38 2 244.110 22.1937 8 0 -38 2 247.874 20.9895 7 0 -38 -3-13.4352 15.5008 8 0 -38 -3 8.38128 14.0975 9 0 -38 -4 90.2918 14.4562 8 0 -37 0-7.51820 18.4251 8 0 -37 1 590.434 37.3214 8 0 -37 -1 598.667 37.7094 9 0 -37 1 598.044 36.0821 7 0 -37 -2 25.1332 17.8676 8 0 -37 -2 12.2018 16.6570 9 0 -37 2 7.28083 15.3940 8 0 -37 2 7.62770 14.0329 7 0 -37 -3 319.748 24.7538 9 0 -37 -3 326.000 26.0272 8 0 -37 -4 132.698 16.2746 8 0 -37 -5 13.3298 9.72883 8 0 -37 -5 28.8727 13.5907 15 0 -36 0 17.9500 17.9851 8 0 -36 1 135.835 18.2773 7 0 -36 -1 142.659 20.8548 9 0 -36 1 137.848 20.0744 8 0 -36 2-5.00695 13.9897 7 0 -36 -2-7.08567 17.2570 8 0 -36 2 16.8314 15.7338 8 0 -36 -2 17.3135 16.9771 9 0 -36 -3 336.759 25.7050 9 0 -36 -3 355.659 26.7763 8 0 -36 3 325.938 24.6489 7 0 -36 -4 81.9867 13.1284 9 0 -36 -4 98.7574 15.5934 8 0 -36 -5 22.8434 10.5509 8 0 -35 0-7.90429 17.2676 8 0 -35 1 362.675 29.8673 9 0 -35 1 408.777 29.9602 8 0 -35 -1 405.475 30.0462 9 0 -35 1 366.162 28.2167 7 0 -35 2 1320.09 76.4235 7 0 -35 -2 1340.96 77.5454 9 0 -35 -2 1328.35 77.6735 8 0 -35 2 1333.88 77.2138 8 0 -35 -3 78.6817 16.3248 9 0 -35 -3 98.6923 17.6850 8 0 -35 3 64.1934 14.7472 7 0 -35 -4 323.416 23.2381 9 0 -35 -4 321.678 24.9093 8 0 -35 -5 121.363 13.9738 8 0 -34 0 18.0112 17.2047 8 0 -34 1 390.901 29.2713 9 0 -34 -1 357.768 29.2181 9 0 -34 1 383.086 29.0966 8 0 -34 -2 156.527 19.7796 9 0 -34 -2 170.019 20.5632 8 0 -34 2 148.164 19.1005 8 0 -34 2 145.971 17.9326 7 0 -34 3 157.404 17.6254 7 0 -34 -3 159.238 18.8269 9 0 -34 -4 58.7145 13.1227 9 0 -34 -5 13.0185 11.6628 8 0 -33 0 2.65678 16.7440 8 0 -33 -1 336.188 26.7187 9 0 -33 1 308.059 26.4925 8 0 -33 1 331.544 26.9148 9 0 -33 -2 1314.13 77.0551 9 0 -33 2 1332.94 76.1905 7 0 -33 2 1324.86 76.7771 8 0 -33 3 2.09183 13.9582 7 0 -33 -3 21.2189 14.7411 9 0 -33 -4 107.016 14.8187 9 0 -33 -5 8.07071 12.1594 8 0 -33 -6 32.2758 13.0989 15 0 -32 0 318.701 26.1572 8 0 -32 1 118.993 18.2718 8 0 -32 -1 111.356 18.1011 9 0 -32 1 99.7705 17.7382 9 0 -32 2 1449.85 82.5213 7 0 -32 2 1476.27 83.0691 8 0 -32 -2 1401.41 83.2276 9 0 -32 -3 143.583 17.5657 9 0 -32 3 129.840 16.8256 7 0 -32 -4 102.258 14.8194 9 0 -31 0-16.8333 16.0093 8 0 -31 -1 271.282 24.0196 9 0 -31 1 273.282 24.2270 9 0 -31 -1 276.064 24.1147 8 0 -31 1 313.422 24.0503 8 0 -31 2 120.386 17.2029 8 0 -31 -2 113.652 17.6318 9 0 -31 2 121.009 16.3440 7 0 -31 -3 1067.86 62.6585 9 0 -31 3 1059.11 62.1238 7 0 -31 -4 174.497 17.6592 9 0 -31 -6 27.9848 8.76721 8 0 -30 0 1121.11 65.8798 8 0 -30 -1 649.545 40.2333 9 0 -30 1 604.585 40.2547 9 0 -30 1 633.754 40.2747 8 0 -30 -2 1409.30 80.7421 9 0 -30 2 1383.37 80.0215 7 0 -30 2 1417.16 80.5945 8 0 -30 -3 71.7514 15.5477 9 0 -30 3 112.010 15.3571 7 0 -30 4 69.7784 15.6690 4 0 -30 4 49.6204 14.9630 6 0 -30 -4 57.5488 13.6236 9 0 -30 5 137.693 17.1416 4 0 -30 -6 6.51919 9.11921 8 0 -29 0 2.58711 13.9079 8 0 -29 -1 363.740 25.5627 9 0 -29 1 337.565 25.9208 9 0 -29 1 311.303 25.3226 8 0 -29 -2 34.6730 14.4015 9 0 -29 2 21.1822 13.1607 7 0 -29 2 30.6797 14.2585 8 0 -29 3 347.985 27.2881 4 0 -29 -3 381.711 26.9962 9 0 -29 3 385.371 26.6208 7 0 -29 -4 679.984 41.4187 9 0 -29 4 628.715 42.9211 6 0 -29 4 718.861 43.0103 4 0 -29 5 95.2136 15.8850 4 0 -29 5 77.1689 17.8560 6 0 -29 6 72.2005 13.2990 4 0 -28 0 605.895 38.1212 8 0 -28 1 611.912 38.7241 8 0 -28 -1 620.848 39.0636 9 0 -28 1 631.570 39.2237 9 0 -28 -2 55.3888 14.3132 9 0 -28 2 55.7649 13.4425 7 0 -28 2 72.9898 14.1697 5 0 -28 2 77.0122 14.4102 8 0 -28 -3 102.981 15.3864 9 0 -28 3 92.0330 14.8926 7 0 -28 3 77.9615 15.5395 4 0 -28 3 95.5625 14.6811 8 0 -28 4 970.878 62.3424 6 0 -28 -4 1074.97 60.9802 9 0 -28 4 1085.86 62.3766 4 0 -28 5 64.6278 15.8616 4 0 -28 5 82.1478 18.7060 6 0 -28 6 131.932 15.7004 4 0 -27 0 8.87986 12.8557 8 0 -27 -1 362.785 26.0498 9 0 -27 1 365.562 26.4924 5 0 -27 1 361.923 25.9485 8 0 -27 1 378.335 26.2477 9 0 -27 1 392.145 33.9751 16 0 -27 2 1849.29 106.056 16 0 -27 2 1825.78 102.523 7 0 -27 2 1804.65 102.984 5 0 -27 -2 1833.99 103.034 9 0 -27 2 1822.00 102.957 8 0 -27 2 1816.78 103.045 9 0 -27 2 1863.41 103.359 4 0 -27 3 473.820 30.5414 7 0 -27 3 464.520 31.5842 4 0 -27 -3 484.061 30.9041 9 0 -27 3 462.286 30.3605 5 0 -27 3 455.066 30.5099 8 0 -27 3 444.890 30.8921 6 0 -27 4 426.280 28.8700 4 0 -27 4 368.829 29.5934 6 0 -27 -4 385.298 26.7989 9 0 -27 5 41.3871 15.5056 4 0 -27 5 39.6420 18.6842 6 0 -27 6-2.32754 13.4405 4 0 -27 7 96.5358 17.6609 3 0 -26 0 78.6914 13.8485 8 0 -26 1 390.176 27.4799 5 0 -26 -1 418.622 27.2567 9 0 -26 1 415.247 34.7155 16 0 -26 1 384.070 27.0447 8 0 -26 1 401.940 27.4788 9 0 -26 2 79.7486 14.1634 4 0 -26 2 112.826 14.4736 8 0 -26 2 85.2747 21.7522 16 0 -26 -2 85.7792 14.1458 9 0 -26 2 104.421 13.7163 7 0 -26 2 106.371 14.5120 9 0 -26 2 85.8290 13.8161 5 0 -26 -3 214.338 17.7836 9 0 -26 3 180.003 18.2055 4 0 -26 3 163.549 18.0260 6 0 -26 3 174.700 16.8841 5 0 -26 3 190.916 17.6332 7 0 -26 3 187.299 17.2529 8 0 -26 -4 239.907 19.9390 9 0 -26 4 209.961 23.2115 6 0 -26 5 159.631 19.2393 4 0 -26 5 174.902 22.2535 6 0 -26 6 18.2057 14.1177 4 0 -26 7 146.344 19.8594 3 0 -25 0 4.46886 23.7902 16 0 -25 1 229.984 19.2996 9 0 -25 1 235.613 27.0918 16 0 -25 1 230.913 18.9686 5 0 -25 -1 235.631 19.0837 9 0 -25 1 251.041 18.9908 8 0 -25 2 1026.68 61.3211 9 0 -25 2 1094.85 64.9215 16 0 -25 2 1028.19 61.1633 8 0 -25 2 1074.49 61.3406 5 0 -25 2 1086.99 61.8519 4 0 -25 -2 1059.70 61.3430 9 0 -25 2 1066.62 60.9333 7 0 -25 3 176.807 16.8046 8 0 -25 3 189.381 17.1004 7 0 -25 3 198.944 18.3708 4 0 -25 -3 192.523 17.5044 9 0 -25 3 180.299 16.6525 5 0 -25 3 186.898 18.0851 6 0 -25 4 865.651 52.7609 4 0 -25 -4 870.773 51.3108 9 0 -25 4 881.033 53.8035 6 0 -25 5 451.523 30.4973 4 0 -25 5 368.618 32.5235 6 0 -25 6 299.561 24.0697 4 0 -25 7 186.675 21.3317 3 0 -25 7 149.303 15.2018 4 0 -24 0 1916.92 111.092 16 0 -24 1 193.994 25.9029 16 0 -24 -1 206.555 17.1342 9 0 -24 2 460.879 29.4274 8 0 -24 -2 535.289 61.9917 19 0 -24 2 442.780 29.5569 9 0 -24 2 452.730 29.1412 7 0 -24 2 460.238 29.9754 4 0 -24 2 442.178 29.3008 5 0 -24 -2 487.156 29.6540 9 0 -24 2 453.424 34.2676 16 0 -24 3 491.796 32.6588 6 0 -24 3 467.765 31.8275 8 0 -24 3 520.921 32.9291 4 0 -24 3 498.061 31.7564 7 0 -24 3 514.494 31.6840 5 0 -24 -3 522.788 31.9866 9 0 -24 4 1080.67 62.4367 4 0 -24 4 1042.13 63.0111 6 0 -24 -4 1036.92 60.6963 9 0 -24 5 85.0804 17.0886 4 0 -24 5 86.8848 21.1396 6 0 -24 6 55.8087 15.7179 4 0 -24 7 5.96693 11.5856 4 0 -24 7 22.2477 19.2611 3 0 -23 0-1.18764 21.9106 16 0 -23 1 247.701 26.1709 16 0 -23 -2 2207.24 135.716 19 0 -23 2 1873.78 111.505 16 0 -23 -2 1993.15 109.415 9 0 -23 3 118.088 14.1692 7 0 -23 -3 135.704 14.0404 9 0 -23 3 125.546 14.0599 8 0 -23 -3 121.090 41.1264 19 0 -23 3 119.889 13.2510 5 0 -23 3 144.887 15.3816 4 0 -23 3 123.349 15.5124 6 0 -23 4 1099.57 63.7165 4 0 -23 4 1055.33 64.2741 6 0 -23 5 454.874 32.2828 4 0 -23 5 469.703 35.2759 6 0 -23 6 23.9980 15.7391 4 0 -23 7 19.6103 12.4822 4 0 -23 7 23.1402 19.6926 3 0 -22 0 3622.53 201.722 16 0 -22 1 146.318 22.0234 16 0 -22 -1 162.686 50.0486 19 0 -22 2 831.150 52.4800 16 0 -22 -2 1009.67 79.2708 19 0 -22 3 7.61170 12.6822 6 0 -22 3 17.1557 10.2366 8 0 -22 -3 58.1889 36.6685 19 0 -22 -3 43.4433 10.9458 9 0 -22 3 19.4734 10.7729 7 0 -22 3 29.9070 12.4005 4 0 -22 4 79.8625 17.8326 6 0 -22 4 99.7415 15.7504 4 0 -22 5 837.928 51.7710 4 0 -22 5 850.992 53.9284 6 0 -22 6 192.871 21.0982 4 0 -22 7 218.485 24.5112 3 0 -22 7 190.376 18.7585 4 0 -21 0 0.34672 20.3139 16 0 -21 -1 792.829 73.0483 19 0 -21 1 644.692 43.6504 16 0 -21 2 204.369 21.8179 16 0 -21 -2 323.415 50.4799 19 0 -21 -3 399.715 50.3853 19 0 -21 3 315.311 24.5636 6 0 -21 3 363.468 24.8218 4 0 -21 3 361.251 23.5191 7 0 -21 3 348.823 23.4378 8 0 -21 4 2164.71 122.150 6 0 -21 4 2166.59 121.656 4 0 -21 5 2214.92 127.737 6 0 -21 5 2264.76 126.383 4 0 -21 6 255.041 27.9020 6 0 -21 6 244.053 23.5027 4 0 -21 7 93.0630 15.8741 4 0 -21 7 99.4858 22.6058 3 0 -20 0 707.686 46.0782 16 0 -20 -1 1562.39 107.033 19 0 -20 1 1423.48 83.2876 16 0 -20 2 1711.50 98.3884 16 0 -20 -2 1863.67 119.759 19 0 -20 3 188.598 17.0859 4 0 -20 -3 185.409 42.4335 19 0 -20 4 270.821 22.4061 4 0 -20 4 277.290 24.0596 6 0 -20 5 593.071 38.2798 4 0 -20 5 556.991 40.5316 6 0 -20 6 276.341 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0 -18 8 245.050 22.3639 3 0 -17 0 58.3192 46.4761 19 0 -17 -1 961.616 79.2309 19 0 -17 -2 260.148 45.5908 19 0 -17 -2 223.970 23.7663 14 0 -17 -3 539.313 48.5963 14 0 -17 -3 585.622 57.7213 19 0 -17 4 175.514 17.0143 4 0 -17 4 166.039 18.9015 6 0 -17 -4 163.983 39.6389 14 0 -17 5 109.264 21.6133 6 0 -17 5 73.5995 16.4522 4 0 -17 -5 64.1898 40.8928 14 0 -17 6 374.906 33.4941 6 0 -17 6 384.134 29.5716 4 0 -17 7 168.752 20.3321 4 0 -17 7 208.532 27.4509 3 0 -17 8 14.4638 11.4182 4 0 -17 8 46.2807 18.7245 3 0 -16 0 6135.61 349.949 19 0 -16 -1 4032.00 241.838 19 0 -16 -1 4140.66 227.355 16 0 -16 -2 1146.93 73.1216 14 0 -16 -2 1258.72 88.7054 19 0 -16 -3 1202.11 87.9128 19 0 -16 -3 1245.01 84.6528 14 0 -16 4 23.5998 12.1491 4 0 -16 4 12.0589 14.8084 6 0 -16 -4 14.3764 37.3087 14 0 -16 5 127.507 21.8759 6 0 -16 5 107.767 17.2281 4 0 -16 -5 148.995 46.1917 14 0 -16 6 69.8033 23.3178 6 0 -16 -6 84.1190 44.0941 14 0 -16 6 78.7051 18.5436 4 0 -16 7 78.8031 17.9116 4 0 -16 7 87.9830 25.5045 3 0 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95.6836 22.0976 2 1 13 -6 24.9108 49.7298 14 -1 13 6 94.6488 23.4041 2 -1 13 4 121.307 35.8860 13 -1 13 4 112.277 14.5621 17 -1 13 3 2272.77 125.254 17 -1 13 3 2240.32 137.758 13 -1 13 2 622.619 47.7491 13 -1 13 1 2261.20 129.333 13 1 13 2 176.220 45.8103 1 1 13 3 400.033 61.3811 1 1 13 4 52.1981 56.2662 1 1 13 4 31.5621 14.5192 12 1 13 5 1800.92 142.611 1 1 13 5 1823.56 104.177 12 -1 13 -7 42.1732 17.5670 20 -1 14 7 350.750 31.1141 2 1 14 -6 243.552 60.4843 14 -1 14 6 238.926 28.4966 2 -1 14 3 913.369 52.1729 17 -1 14 3 897.517 66.4047 13 -1 14 2 3445.95 196.327 13 -1 14 1 1613.32 94.3767 13 -1 14 0 2038.86 117.103 13 1 14 2 1237.60 90.2874 1 1 14 3 18.4573 48.3140 1 1 14 4 181.179 18.7943 12 1 14 4 133.773 57.4393 1 1 14 5 133.745 63.3221 1 1 14 5 132.892 20.3447 12 -1 14 -7 182.601 20.8861 20 -1 15 7 407.753 33.6428 2 1 15 -6 230.532 58.9273 14 -1 15 6 294.454 30.5812 2 -1 15 3 783.955 59.3560 13 -1 15 2 1937.11 114.954 13 -1 15 1 333.229 27.6544 13 1 15 -1 317.967 26.1161 11 -1 15 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60.1431 20.7584 6 -2 -15 -4 69.5033 17.6211 15 2 -15 4 60.0970 60.3856 1 2 -15 4 55.5130 17.6182 12 -2 -15 -5 224.989 22.1121 15 2 -15 5 285.071 25.4695 12 -2 -15 -5 263.779 24.5856 20 -2 -15 -6 5.48379 14.3908 20 2 -15 6 31.6247 20.5645 6 2 -15 6 17.6613 19.4815 3 -2 -14 8 77.2498 16.9993 4 -2 -14 7 18.2127 18.2926 4 -2 -14 7 12.8934 16.7180 3 -2 -14 6 254.808 24.6213 4 -2 -14 6 199.603 22.6572 3 -2 -14 6 272.373 20.1163 5 -2 -14 5 51.4853 12.0408 5 -2 -14 5 12.3274 15.2835 17 -2 -14 5 37.5879 15.1382 4 -2 -14 5 45.6152 37.6242 13 -2 -14 4 36.3888 11.0506 5 -2 -14 4 45.5750 13.5001 17 -2 -14 4 50.0168 13.2164 4 -2 -14 4 30.2716 12.3864 10 -2 -14 4 48.8791 36.3433 13 2 -14 -3 634.848 43.5310 16 -2 -14 3 772.848 59.4475 13 -2 -14 2 2706.40 147.772 21 2 -14 -2 2633.10 150.786 16 -2 -14 2 2688.18 159.918 13 2 -14 -1 705.265 93.2902 19 -2 -14 1 696.076 42.5012 15 -2 -14 1 699.070 54.7428 13 2 -14 -1 730.028 55.7183 11 2 -14 0 1143.08 100.572 19 -2 -14 0 1139.15 64.1897 20 2 -14 0 1077.24 77.4201 11 -2 -14 -1 569.473 55.9549 18 -2 -14 -1 561.022 35.3026 20 2 -14 1 532.616 64.4138 19 -2 -14 -1 597.196 36.7006 15 -2 -14 -2 342.482 23.3273 20 -2 -14 -2 289.429 48.9943 18 -2 -14 -2 280.466 23.9558 15 2 -14 2 274.362 21.9461 7 -2 -14 -3 944.178 55.1087 15 -2 -14 -3 929.372 54.2783 20 2 -14 3 830.688 90.7380 1 2 -14 3 840.760 54.0233 12 -2 -14 -4 311.890 26.1797 15 2 -14 4 322.888 28.7918 6 2 -14 4 323.833 27.1524 12 -2 -14 -4 339.007 27.5376 20 -2 -14 -5 3.76781 13.4540 15 2 -14 5-1.23704 22.0055 6 2 -14 5-11.4347 18.4958 12 -2 -14 -5-7.62039 17.8996 20 2 -14 6 6.25642 20.7599 6 -2 -14 -6 12.8860 15.3923 20 2 -14 6 33.9747 20.2570 3 2 -14 6 1.69352 17.5442 12 -2 -13 8 182.764 20.6436 4 -2 -13 7 41.3179 17.6072 3 -2 -13 7 39.5962 9.21180 5 -2 -13 7 61.2993 18.8934 4 -2 -13 6 211.845 22.5502 4 -2 -13 6 155.527 20.9172 3 -2 -13 6 223.445 18.0997 5 -2 -13 5 554.584 40.1369 17 -2 -13 5 643.961 38.4342 5 -2 -13 5 674.612 40.3733 4 -2 -13 5 504.521 62.6906 13 -2 -13 4 253.346 19.1416 5 -2 -13 4 249.137 20.2750 4 -2 -13 4 234.186 20.6246 17 -2 -13 4 237.175 43.5404 13 -2 -13 4 246.003 19.6161 10 2 -13 -3 549.801 39.1709 16 -2 -13 3 715.578 56.5295 13 -2 -13 2 101.475 12.1407 21 -2 -13 2 96.0390 30.5033 13 2 -13 -1 296.940 76.4693 19 -2 -13 1 325.758 23.6176 15 -2 -13 1 351.657 38.6564 13 2 -13 -1 288.932 37.6140 11 -2 -13 0 1177.19 66.3041 20 2 -13 0 1214.64 80.3969 11 -2 -13 -1 306.950 22.6138 20 -2 -13 -1 305.571 22.8296 15 2 -13 1 295.117 52.8659 19 -2 -13 -1 288.453 44.9940 18 -2 -13 -2 1183.55 64.5296 20 -2 -13 -2 1174.59 87.4778 18 -2 -13 -2 1145.36 65.3458 15 2 -13 2 1025.10 63.8595 7 -2 -13 -3 798.583 49.6688 15 2 -13 3 785.907 49.2649 12 2 -13 3 720.689 87.3509 1 -2 -13 -3 841.834 49.7962 20 -2 -13 -4 30.7739 15.3274 15 -2 -13 -4 17.1999 19.0769 20 2 -13 4 22.7019 19.3161 6 2 -13 4 30.7749 17.9458 12 2 -13 4 68.7379 64.0578 1 -2 -13 -5 159.771 22.6283 20 2 -13 5 215.980 26.2678 6 2 -13 5 183.866 23.2196 12 2 -13 6 99.1816 21.2105 3 -2 -13 -6 59.2877 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65.5278 1 -2 -12 -3 224.542 22.3190 20 -2 -12 -3 213.923 20.9679 15 -2 -12 -4 53.3247 15.7916 15 -2 -12 -4 29.2592 19.6332 20 2 -12 4 66.4993 63.3793 1 2 -12 4 46.7346 19.0458 6 2 -12 4 24.9261 18.1397 12 2 -12 5 176.151 67.9959 1 -2 -12 -5 130.984 22.5167 20 2 -12 5 169.064 24.7570 6 2 -12 5 132.900 22.4953 12 2 -12 6 92.9293 21.4082 3 -2 -12 -6 87.3793 18.2237 20 2 -12 6 80.2017 21.7844 6 2 -12 6 75.8689 20.0594 12 2 -12 7 7.08631 14.4009 3 -2 -11 8-8.48783 16.7483 4 -2 -11 7 36.2211 9.83167 5 -2 -11 7 27.8812 18.3181 4 -2 -11 7 28.7291 18.3414 3 -2 -11 6 360.244 24.9578 5 -2 -11 6 385.222 28.6812 4 -2 -11 6 314.816 27.8902 3 -2 -11 5 402.498 27.6632 5 -2 -11 5 462.905 30.6277 17 -2 -11 5 389.882 29.3817 4 -2 -11 5 459.021 57.8315 13 -2 -11 4 432.703 27.8248 4 -2 -11 4 402.706 28.8866 17 -2 -11 4 367.319 52.5205 13 -2 -11 4 415.717 27.1411 5 2 -11 -3 406.144 29.5468 16 -2 -11 3 426.655 47.1336 13 -2 -11 2 502.534 50.1130 13 -2 -11 2 580.518 34.3817 21 -2 -11 1 1384.35 89.0861 13 2 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870.986 54.4790 17 -2 -10 5 804.615 79.3152 13 -2 -10 5 928.495 53.8570 4 -2 -10 5 895.616 52.7618 5 -2 -10 4 564.962 36.1364 17 -2 -10 4 523.367 58.7407 13 2 -10 -3 700.645 44.6044 16 -2 -10 3 872.847 64.6151 13 -2 -10 2 1449.91 81.5299 21 -2 -10 2 1514.41 96.1630 13 -2 -10 1 1421.35 80.3810 15 -2 -10 1 1464.30 93.4895 13 2 -10 -1 1410.49 92.5696 11 -2 -10 0 4242.15 232.426 15 2 -10 0 3897.58 256.012 19 2 -10 0 4159.09 243.334 11 -2 -10 0 4359.39 244.747 18 -2 -10 0 4256.35 231.869 20 -2 -10 -1 265.188 21.3858 20 -2 -10 -1 286.423 21.4381 15 2 -10 1 312.571 48.4273 19 -2 -10 -1 253.705 46.2036 18 -2 -10 -2 92.6939 15.5200 15 -2 -10 -2 104.235 17.1857 20 -2 -10 -3 42.5965 17.6170 20 -2 -10 -3 36.2908 14.1104 15 2 -10 4 465.288 82.5108 1 -2 -10 -4 551.328 35.3347 20 -2 -10 -4 421.391 30.9418 15 2 -10 4 425.470 33.5149 6 2 -10 4 428.252 33.4470 12 2 -10 5 714.290 95.3848 1 2 -10 5 794.202 54.4018 6 -2 -10 -5 894.893 53.9182 20 2 -10 5 830.661 53.2807 12 -2 -10 -6 4.78411 18.3527 20 2 -10 6 30.4824 20.7171 6 2 -10 6 3.03768 20.5562 3 2 -10 6 30.2138 19.8437 12 2 -10 7 216.516 20.6565 3 -2 -9 8 406.364 30.4731 4 -2 -9 7 127.145 20.1565 4 -2 -9 7 87.7891 21.0198 3 -2 -9 7 114.266 12.8895 5 -2 -9 6 639.674 41.9512 4 -2 -9 6 679.931 39.6699 5 -2 -9 6 570.561 41.7928 3 -2 -9 5 636.679 42.5622 17 -2 -9 5 700.875 41.6165 4 -2 -9 4 534.802 35.0258 17 -2 -9 4 571.354 59.2207 13 -2 -9 3 1355.56 93.2402 13 -2 -9 2 323.243 22.3809 21 -2 -9 2 405.800 42.1794 13 -2 -9 1 3652.04 200.882 15 2 -9 -1 3584.41 211.228 11 -2 -9 1 3773.64 212.127 13 2 -9 0 711.261 82.5456 19 -2 -9 0 906.840 51.9731 15 -2 -9 0 848.911 68.2418 18 -2 -9 0 894.651 51.6440 20 2 -9 0 918.894 67.0064 11 2 -9 1 65.9345 38.3903 19 -2 -9 -1 82.9620 42.3948 18 -2 -9 -1 73.9725 13.5268 15 -2 -9 -1 67.2866 13.4055 20 -2 -9 -2 2936.34 161.525 15 -2 -9 -2 2900.79 161.531 20 -2 -9 -3 177.437 18.3631 15 -2 -9 -3 191.931 22.2043 20 -2 -9 -4 625.030 42.8769 20 -2 -9 -4 552.569 39.1788 15 2 -9 4 698.767 42.5001 6 2 -9 4 650.669 41.8645 12 -2 -9 -5 98.1211 23.5087 20 2 -9 5 120.371 23.3276 6 2 -9 5 90.7334 22.0247 12 -2 -9 -6 71.4576 20.1917 20 2 -9 6 122.585 22.7104 6 2 -9 6 111.826 22.0429 12 2 -9 6 123.976 22.3850 3 -2 -9 -7 55.1034 14.2130 20 2 -9 7 54.2571 15.6778 3 -2 -8 8 210.599 21.9035 4 -2 -8 7 25.8187 10.3097 5 -2 -8 7 9.87637 17.8738 4 -2 -8 7-2.54135 19.7348 3 -2 -8 6 386.273 25.6265 5 -2 -8 6 331.124 29.4905 17 -2 -8 6 380.311 28.3718 4 -2 -8 6 340.395 56.6262 13 -2 -8 6 320.388 28.8946 3 -2 -8 5 498.293 33.5065 17 -2 -8 5 445.392 31.2309 4 -2 -8 5 436.525 59.8516 13 -2 -8 4 649.410 63.1557 13 -2 -8 4 654.942 40.7177 17 -2 -8 3 1177.33 84.5414 13 -2 -8 2 1427.93 79.1849 21 -2 -8 2 1313.24 92.8452 13 -2 -8 1 2141.11 123.927 13 2 -8 -1 1871.51 122.021 11 -2 -8 0 223.283 42.2861 18 2 -8 0 148.404 57.6773 19 -2 -8 0 213.266 17.8996 15 2 -8 0 167.128 35.0935 11 2 -8 1 1263.30 92.4563 19 -2 -8 -1 1343.28 96.3985 18 -2 -8 -1 1334.78 76.9978 20 -2 -8 -1 1405.83 77.2533 15 -2 -8 -2-0.24533 12.5875 15 -2 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38.5169 19 -2 -7 -1 208.368 18.1672 15 -2 -7 -1 218.260 18.9183 20 -2 -7 -2 153.981 17.9615 20 -2 -7 -2 122.848 15.0886 15 2 -7 3 105.216 63.9203 1 -2 -7 -3 184.820 17.5984 15 2 -7 4 98.1223 71.5827 1 2 -7 4 107.517 19.2355 6 2 -7 4 77.1205 20.0447 12 -2 -7 -5 2120.28 112.689 20 2 -7 5 1918.55 111.966 12 2 -7 5 1875.70 112.245 6 -2 -7 -6 278.230 28.8262 20 2 -7 6 292.156 29.4343 12 2 -7 6 370.720 29.7275 3 -2 -7 -7 11.0967 14.6073 20 -2 -6 8 470.660 33.4661 4 -2 -6 7 1372.64 75.2702 4 -2 -6 7 1210.88 71.9984 5 -2 -6 6 30.4537 42.9130 13 -2 -6 6 68.1331 16.5810 4 -2 -6 6 81.8666 20.2608 17 -2 -6 6 74.5929 19.2542 3 -2 -6 5 80.5224 15.9264 3 -2 -6 5 61.4197 17.8635 17 -2 -6 5 54.3782 43.8167 13 -2 -6 5 76.4504 14.4740 4 -2 -6 4 965.711 80.7666 13 -2 -6 3 173.876 39.7838 13 -2 -6 2 495.672 30.3023 21 -2 -6 2 471.116 48.5922 13 -2 -6 1 245.422 39.1154 13 -2 -6 0 2215.93 140.047 18 -2 -6 0 2279.04 125.886 15 2 -6 0 2298.23 138.504 11 2 -6 1 442.014 45.8009 19 -2 -6 -1 513.508 56.3999 18 -2 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981.613 53.2111 15 -2 -4 -1 889.207 53.4334 20 -2 -4 -2 2560.21 141.494 15 -2 -4 -2 2556.78 142.170 20 -2 -4 -3 1353.41 77.0297 15 2 -4 3 1349.75 77.5883 6 2 -4 3 1499.50 119.134 1 2 -4 4 339.719 27.4933 6 2 -4 4 367.679 78.6534 1 2 -4 4 338.411 28.3175 12 2 -4 5 293.021 29.3105 6 2 -4 5 327.994 79.8222 1 2 -4 5 304.137 29.8684 12 2 -4 5 364.709 29.6400 3 -2 -4 -6 132.579 24.3614 20 2 -4 6 116.776 23.8184 12 2 -4 6 100.675 22.6628 3 -2 -4 -7-20.3729 16.0742 20 -2 -3 9 24.6496 11.7140 4 -2 -3 8 38.3701 16.9111 4 -2 -3 7 960.847 58.7024 5 -2 -3 7 1108.00 62.0338 4 -2 -3 6 288.392 56.1400 13 -2 -3 6 268.911 23.2139 4 -2 -3 6 235.322 25.4446 3 -2 -3 5 181.042 17.3739 4 -2 -3 5 167.714 19.6347 3 -2 -3 2 791.810 45.9804 21 2 -3 1 95.7388 24.0494 19 -2 -3 -1 138.167 13.5721 15 -2 -3 -2 903.144 52.4862 15 2 -3 3 158.612 17.1563 6 2 -3 4 41.5460 17.3200 6 2 -3 5 154.905 23.8262 3 2 -3 5 147.979 23.7767 6 2 -3 6-1.79844 20.4694 3 -2 -2 9 35.0251 11.7643 4 -2 -2 8 320.916 26.2171 4 -2 -2 7 576.959 39.7185 4 -2 -2 6 50.5197 15.9150 4 -2 -2 6 65.4204 19.8295 3 -2 -2 5 250.998 20.3122 4 -2 -2 5 231.662 22.5565 3 2 -2 1 27.1199 19.0359 19 -2 -2 -2 763.093 44.7886 15 2 -2 4 151.535 20.3186 6 2 -2 5 626.470 43.9949 6 2 -2 5 659.785 44.1430 3 2 -2 6 96.2229 21.9543 3 -2 -1 9 41.4883 11.8211 4 -2 -1 8 45.1256 16.8156 4 -2 -1 7 480.619 34.6370 4 -2 -1 6 100.403 17.7286 4 -2 -1 5 212.864 21.6642 3 2 -1 0 1264.52 84.1758 11 2 -1 1 236.001 25.4205 19 -2 -1 -2 91.0170 12.4160 15 2 -1 4 397.941 29.1273 6 2 -1 4 359.345 28.6271 3 2 -1 5 52.4846 21.4999 3 2 -1 5 43.7985 20.1332 6 2 -1 6 149.484 23.6053 3 -2 0 9 38.9139 11.6808 4 -2 0 8 23.1011 16.0037 4 -2 0 7 107.675 20.2322 4 -2 0 6 453.944 34.0800 17 -2 0 6 330.887 60.0153 13 -2 0 5 119.593 18.6563 17 -2 0 5 69.8113 45.3897 13 -2 0 5 37.4191 17.1797 3 -2 0 4 639.871 64.2971 13 -2 0 3 98.8831 39.9603 13 -2 0 2 497.087 50.2185 13 -2 0 2 529.646 32.1674 21 -2 0 1 4028.18 231.826 13 -2 0 0 21.3534 37.5327 18 2 0 0-1.00806 29.9110 11 2 0 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19.0502 6 2 1 5 63.3888 22.7488 12 -2 1 -6 170.387 25.4972 20 2 1 6 135.043 25.2118 12 -2 1 -7 79.1325 17.5777 20 -2 2 9 19.9195 10.6256 4 -2 2 8 253.561 23.1148 4 -2 2 7 596.923 40.7593 4 -2 2 6 92.6505 21.3847 17 -2 2 6 59.2008 48.8342 13 -2 2 5 285.011 24.6218 17 -2 2 5 205.727 53.3200 13 -2 2 4 621.534 65.0608 13 -2 2 3 46.5303 37.3930 13 -2 2 2 1012.00 58.2310 21 -2 2 2 1121.05 75.0687 13 -2 2 1 9533.56 529.270 13 -2 2 0 4607.81 275.210 18 2 2 0 5026.96 274.626 11 -2 2 -1 32.0685 13.3622 20 2 2 1 25.1733 11.3415 19 -2 2 -2 752.445 45.7932 20 2 2 3 56.6341 62.7685 1 2 2 4 159.212 19.4038 6 2 2 4 160.645 21.8643 12 2 2 5 690.260 45.3708 12 2 2 5 696.947 95.6184 1 2 2 5 641.648 44.4303 3 -2 2 -6 106.770 24.2235 20 2 2 6 102.509 23.6011 12 -2 2 -7 22.5552 16.5907 20 -2 3 9 9.33253 10.3232 4 -2 3 8 10.4423 15.7892 4 -2 3 7 994.801 60.4755 4 -2 3 6 247.661 25.2686 17 -2 3 6 172.689 52.6757 13 -2 3 5 278.017 24.4643 17 -2 3 5 241.551 52.2247 13 -2 3 4 337.964 51.0972 13 -2 3 3 361.020 47.4161 13 -2 3 2 757.588 60.8075 13 -2 3 2 769.551 44.7524 21 -2 3 1 1949.13 120.634 13 -2 3 0 742.219 65.2114 18 2 3 0 849.926 62.3161 11 -2 3 -1 131.216 15.6063 20 -2 3 -2 838.012 50.2866 20 2 3 3 216.875 66.3148 1 2 3 4 9.81340 70.6591 1 2 3 4 48.6019 18.0728 12 2 3 5 144.137 72.3247 1 2 3 5 173.792 24.9228 12 2 3 5 191.216 23.4770 3 -2 3 -6 15.1511 22.6966 20 2 3 6 37.0603 22.3174 12 -2 3 -7-8.79370 16.0717 20 -2 4 9 17.6461 10.2183 4 -2 4 8 216.016 21.3545 4 -2 4 7 153.813 20.0785 4 -2 4 6 25.5055 19.7676 17 -2 4 6 25.8147 47.2963 13 -2 4 5 64.5462 17.8377 17 -2 4 5 26.4515 43.1763 13 -2 4 5 65.6460 15.2058 2 -2 4 4 25.8679 41.6877 13 -2 4 3 185.559 41.2636 13 -2 4 2 2602.78 157.275 13 -2 4 2 2628.20 144.523 21 -2 4 1 158.352 35.0254 13 -2 4 0 202.844 42.5005 18 2 4 0 240.134 37.9123 11 -2 4 -1 877.627 51.1562 20 -2 4 -2 2436.37 135.505 20 2 4 3 1347.79 117.242 1 2 4 4 467.834 81.9065 1 2 4 4 354.559 29.3340 12 2 4 5 391.697 81.8311 1 2 4 5 332.487 30.3231 12 2 4 5 317.335 28.4614 3 -2 4 -6 127.360 24.4328 20 2 4 6 114.682 24.1534 12 -2 4 -7 13.3861 15.8688 20 -2 5 9 12.4895 9.63536 4 -2 5 8 234.994 22.5022 4 -2 5 6 4.71319 19.6035 17 -2 5 6-2.58466 45.3920 13 -2 5 6 24.4092 15.8775 2 -2 5 5 30.5567 17.4733 17 -2 5 5 3.90403 14.9031 2 -2 5 4 1918.10 129.069 13 -2 5 3 357.896 46.4420 13 -2 5 2 283.177 20.2669 21 -2 5 2 343.993 40.6328 13 -2 5 1 509.398 48.4533 13 -2 5 0 448.106 47.9627 18 2 5 0 421.449 44.7838 11 -2 5 -1 297.840 22.2158 20 -2 5 -2 456.388 31.1355 20 2 5 3 477.170 77.4274 1 2 5 4 91.3795 69.1443 1 2 5 4 102.990 20.4264 12 -2 5 -5 676.281 44.8483 20 2 5 5 633.557 90.8186 1 2 5 5 637.963 42.9411 12 2 5 5 551.347 41.0621 3 -2 5 -6 121.353 23.8171 20 2 5 6 101.131 23.4713 12 -2 5 -7 18.9743 15.8558 20 -2 6 8 405.042 29.0909 4 -2 6 6 92.0001 21.0525 17 -2 6 6 129.276 49.0336 13 -2 6 6 72.4853 18.1008 2 -2 6 5 101.199 17.6134 2 -2 6 5 48.6882 17.9054 17 -2 6 5 59.8920 44.8148 13 -2 6 4 1038.65 83.7743 13 -2 6 3 187.013 38.2738 13 -2 6 2 477.548 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2.07269 14.9673 20 -2 8 8 168.399 18.9324 4 -2 8 7 9.59957 13.9380 2 -2 8 6 381.136 28.5665 2 -2 8 6 304.630 56.6229 13 -2 8 6 288.960 28.8923 17 -2 8 5 458.148 32.3390 17 -2 8 5 423.811 32.0098 2 -2 8 5 399.474 59.2436 13 -2 8 4 588.791 61.3993 13 -2 8 3 1190.87 85.7313 13 -2 8 2 1372.34 76.8359 21 -2 8 2 1346.09 91.5213 13 -2 8 1 2115.17 128.055 13 2 8 -1 2043.43 126.880 11 -2 8 0 177.764 39.2491 18 2 8 0 141.861 33.3031 11 -2 8 -1 1320.91 91.1554 18 -2 8 -1 1263.61 71.8618 20 -2 8 -2-0.47995 14.5014 20 -2 8 -3 741.185 46.1817 20 2 8 3 571.289 84.3470 1 2 8 4 107.247 69.5302 1 2 8 4 163.122 21.6841 12 -2 8 -5 30.8221 23.4744 20 2 8 5 24.5924 65.4896 1 2 8 5 43.8006 20.7944 12 -2 8 -6-7.19105 20.6372 20 2 8 6 17.8998 20.9873 12 -2 8 -7 82.4904 15.7839 20 -2 9 8 301.215 24.1634 4 -2 9 7 140.642 18.9229 2 -2 9 6 623.040 42.0481 2 -2 9 5 648.007 44.0190 17 -2 9 5 749.919 44.7882 2 -2 9 5 564.839 68.6591 13 -2 9 4 518.907 34.2169 17 -2 9 4 554.264 58.4832 13 -2 9 3 1360.59 94.1235 13 -2 9 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200.864 21.9746 2 -2 17 3 177.062 35.5914 13 -2 17 2 674.935 53.3873 13 2 17 -2 654.897 51.9187 11 -2 17 1 991.415 70.9722 13 2 17 -1 1099.27 70.8654 11 -2 17 0 91.3540 27.4309 13 -2 17 -1 180.953 36.4885 18 -2 17 -2 92.3380 36.4916 18 2 17 2 123.842 50.5268 1 -2 17 -3 426.898 29.9989 20 -2 17 -3 357.728 54.0508 18 -2 17 -4 151.972 19.7319 20 2 17 4 126.589 18.7603 12 -2 17 -5 41.2113 17.0588 20 2 17 5 20.0148 16.6970 12 -2 18 7 189.929 24.4395 2 -2 18 6 385.416 34.5783 2 -2 18 5 213.929 28.5735 2 -2 18 4 74.7655 31.8896 13 -2 18 3 123.835 20.9786 2 -2 18 3 135.768 32.0282 13 -2 18 2 559.604 47.7605 13 -2 18 1 509.940 43.4424 13 -2 18 0 815.628 60.3710 13 -2 18 -1 143.371 32.9180 18 2 18 2-12.1466 45.3852 1 -2 18 -4 121.910 18.5833 20 -2 19 7 123.804 23.0023 2 -2 19 6 40.8261 24.5515 2 -2 19 5 33.4322 24.3095 2 -2 19 3 720.468 46.7205 2 -2 19 2 177.356 20.7267 2 -2 20 7 209.534 25.3249 2 -2 20 6 175.039 27.8008 2 -2 20 4 6.58760 22.1915 2 -2 20 3 504.288 36.3036 2 -2 20 2 364.278 28.8630 2 -2 21 7 35.9417 20.9422 2 -2 21 6 204.947 29.2954 2 -2 21 4 130.767 24.8341 2 -2 21 3 914.532 57.1310 2 -2 21 2 997.029 60.3172 2 -2 21 1 122.975 17.6118 2 -2 22 7 291.326 27.9011 2 -2 22 6 124.957 27.2407 2 -2 22 4 41.8235 23.5661 2 -2 22 3 138.481 23.4570 2 -2 22 2 265.263 25.4649 2 -2 22 1 228.111 21.3959 2 -2 23 7-0.29805 20.1583 2 -2 23 6 278.451 31.6936 2 -2 23 4 3.52654 24.4685 2 -2 23 3 61.4206 22.2774 2 -2 23 2 143.995 21.2629 2 -2 23 1 52.4657 15.8419 2 -2 24 7 138.965 22.2531 2 -2 24 6 69.8788 26.1307 2 -2 24 4 254.542 30.1201 2 -2 24 3 836.869 54.3686 2 -2 24 2 1259.96 74.8080 2 -2 24 1 191.194 20.3810 2 -2 25 7 26.4646 19.8232 2 -2 25 5 427.447 38.2641 2 -2 25 4 414.272 36.9030 2 -2 25 3 442.165 35.9249 2 -2 25 2 64.8017 20.0757 2 -2 25 1 253.459 23.0648 2 -2 26 7 51.7482 18.9701 2 -2 26 5 572.921 44.6279 2 -2 26 4 646.908 47.6409 2 -2 26 3 278.204 29.3486 2 -2 26 2 177.191 23.4554 2 -2 26 1 408.117 30.0741 2 -2 27 7 120.179 20.3266 2 -2 27 5 130.902 28.5948 2 -2 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123.394 14.9727 7 -3 -36 1 257.835 20.6913 9 3 -36 -1 214.400 33.2209 16 3 -36 -1 283.701 21.3783 7 -3 -36 0 99.4454 15.3292 9 3 -36 0 117.558 27.4303 16 3 -36 0 102.069 16.1411 7 3 -36 1 19.7704 22.5850 16 3 -36 1 25.4190 14.8510 6 3 -35 -4 67.3990 10.3595 7 3 -35 -3 292.641 22.1511 7 -3 -35 3 369.526 25.6885 5 -3 -35 2 114.757 16.5990 10 -3 -35 2 69.1375 16.7618 5 3 -35 -2 93.1310 14.5477 7 -3 -35 1 207.992 18.8524 9 3 -35 -1 163.361 32.7389 16 3 -35 -1 230.861 19.7783 7 -3 -35 1 214.667 19.1992 10 -3 -35 0 157.286 17.5448 9 3 -35 0 143.864 29.4813 16 3 -35 0 156.700 17.5669 7 -3 -35 0 131.056 14.1132 10 3 -35 1-0.42620 23.8304 16 -3 -35 -1 8.34211 10.4070 8 -3 -35 -2 100.384 14.1624 9 3 -35 2 107.464 16.1577 6 -3 -34 5 44.0396 12.3394 5 3 -34 -4 65.8595 10.7898 7 -3 -34 3 11.8207 15.6697 5 3 -34 -3 20.6832 11.9234 7 -3 -34 2 45.0519 16.4967 5 -3 -34 2 12.5475 15.5710 10 3 -34 -2-1.69645 30.0628 16 3 -34 -2 32.1153 13.7604 7 3 -34 -1 391.205 41.0950 16 3 -34 -1 446.883 29.4238 7 -3 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20.6519 5 -3 -29 3 361.767 27.9563 5 -3 -29 3 376.131 30.1935 10 3 -29 -2 211.885 71.9916 19 3 -29 -2 206.915 36.4632 16 3 -29 -2 166.157 18.6697 7 -3 -29 2 196.330 20.8507 5 -3 -29 2 160.485 17.3282 9 -3 -29 2 209.110 22.1992 10 3 -29 -1 141.769 64.8437 19 3 -29 -1 104.312 35.0312 16 3 -29 -1 114.292 17.2164 7 -3 -29 1 111.238 17.9362 5 -3 -29 1 112.126 18.3002 10 -3 -29 0 301.900 27.6001 15 -3 -29 0 284.683 23.4679 10 3 -29 0 291.445 24.4994 7 3 -29 1 66.1929 30.0293 16 -3 -29 -1 90.3808 21.4186 15 3 -29 1 124.792 18.3574 7 -3 -29 -1 63.1153 13.3194 10 3 -29 2 41.4557 25.8388 16 -3 -29 -2-3.72961 18.8356 15 -3 -29 -3 44.3570 16.0760 15 -3 -28 6 24.7947 12.2852 5 -3 -28 5 16.6413 14.8664 5 -3 -28 3 28.7008 16.6933 5 3 -28 -3 82.3061 31.4707 16 -3 -28 3 64.7935 20.3872 10 3 -28 -2 286.626 74.1905 19 -3 -28 2 275.423 22.2502 9 3 -28 -2 247.641 39.0123 16 3 -28 -2 293.917 23.1662 7 -3 -28 2 289.578 24.7677 5 -3 -28 2 312.520 26.4592 10 -3 -28 1 206.575 21.6937 10 3 -28 -1 202.471 20.0446 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1 163.788 33.4922 16 3 -27 1 167.188 20.6502 7 3 -27 2 71.2772 28.2751 16 -3 -27 -2 64.2745 19.4270 15 3 -27 3 99.8618 24.0831 16 -3 -27 -3 138.337 19.6853 15 -3 -27 -4 73.0453 13.7328 15 -3 -26 6 221.998 19.2888 5 -3 -26 5 17.6505 15.4747 5 -3 -26 4 397.307 31.7681 10 3 -26 -3 623.385 92.9178 19 3 -26 -3 555.659 49.6766 16 -3 -26 3 607.801 40.0184 5 -3 -26 3 638.500 42.0011 10 3 -26 -2 311.408 40.6941 16 3 -26 -2 352.642 25.6168 7 -3 -26 2 345.097 28.6322 10 -3 -26 2 343.580 27.1630 5 3 -26 -1 331.229 40.0000 16 -3 -26 1 336.717 28.3790 15 3 -26 -1 299.963 24.5173 7 -3 -26 1 300.659 24.9604 5 -3 -26 1 335.827 26.4348 10 -3 -26 0 656.841 41.9722 10 3 -26 0 670.466 85.9070 19 -3 -26 0 750.789 45.8349 15 3 -26 0 647.590 41.7868 7 -3 -26 0 619.029 41.2451 5 -3 -26 -1 132.252 16.0881 10 3 -26 1 143.600 33.4158 16 3 -26 1 129.317 18.8121 7 3 -26 2 134.530 30.9115 16 -3 -26 -2 169.558 23.0442 15 3 -26 3-0.43508 22.4708 16 -3 -26 -3-17.4376 17.1113 15 -3 -26 -4 348.650 27.5267 15 3 -26 4 514.265 30.8883 6 -3 -25 6 121.300 15.7154 5 -3 -25 5 29.6245 15.3459 5 3 -25 -4 412.571 85.0034 19 -3 -25 4 555.364 38.5522 10 -3 -25 3 44.1222 19.0341 10 -3 -25 3 39.6562 15.4222 5 3 -25 -3 33.3432 67.2496 19 3 -25 -3 32.4094 30.1480 16 3 -25 -2 252.003 80.1153 19 3 -25 -2 257.825 36.9341 16 3 -25 -2 245.013 21.7752 7 -3 -25 2 293.164 25.5313 10 -3 -25 2 295.062 23.4289 5 -3 -25 1 185.180 20.6244 10 3 -25 -1 153.863 18.4771 7 3 -25 -1 206.016 35.0431 16 -3 -25 1 186.374 22.8625 15 -3 -25 1 152.146 18.7697 5 3 -25 0 293.078 66.8684 19 -3 -25 0 215.264 26.5863 15 3 -25 0 227.788 21.5221 7 -3 -25 0 214.384 21.6842 10 -3 -25 0 271.237 21.1604 5 -3 -25 -1 70.0119 14.8840 10 3 -25 1 95.0834 32.9795 16 3 -25 1 85.2724 17.6099 7 3 -25 2 639.192 51.0202 16 -3 -25 -2 672.062 45.1856 15 3 -25 3 276.357 33.1967 16 -3 -25 -3 338.753 29.0979 15 -3 -25 -4 99.5301 15.6176 15 3 -25 4 142.644 20.1995 6 -3 -24 6 37.6331 13.9571 5 -3 -24 6 45.4896 15.8381 4 -3 -24 5 179.123 19.4916 5 3 -24 -4 193.976 74.5077 19 -3 -24 4 35.3891 19.1532 10 3 -24 -3 278.450 79.6653 19 3 -24 -3 219.868 34.4040 16 -3 -24 3 223.703 21.3356 5 3 -24 -2 401.179 86.0906 19 3 -24 -2 388.275 39.9580 16 3 -24 -2 336.429 25.1989 7 -3 -24 2 323.106 26.0828 5 -3 -24 2 376.098 28.8905 10 3 -24 -1 1854.49 152.289 19 -3 -24 1 1931.77 107.987 10 3 -24 -1 1894.84 114.455 16 -3 -24 1 1916.33 108.877 15 3 -24 -1 1837.97 106.465 7 -3 -24 1 1910.49 107.092 5 3 -24 0 161.682 62.5971 19 -3 -24 0 186.890 23.7071 15 3 -24 0 131.174 17.5267 7 -3 -24 0 99.8730 15.8894 5 -3 -24 0 134.517 18.0677 10 3 -24 1 54.6760 17.1905 7 -3 -24 -1 68.0184 14.6403 10 -3 -24 -2 312.535 23.5169 10 3 -24 2 361.256 38.7124 16 -3 -24 -2 375.205 30.5740 15 3 -24 3 89.3773 26.4054 16 -3 -24 -3 118.681 20.0092 15 3 -24 3 102.267 22.0396 6 -3 -24 -4 57.6973 14.7979 15 3 -24 4 65.3915 19.0829 6 -3 -23 6 65.7492 14.4365 5 -3 -23 6 44.0536 15.7894 4 -3 -23 5 82.6505 16.3386 5 -3 -23 5 83.3913 18.0273 4 3 -23 -4 589.037 94.5138 19 3 -23 -4 452.902 40.8266 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378.121 31.0819 20 -3 3 -2 431.293 65.3085 18 -3 3 -3 179.827 25.8139 20 -3 3 -3 237.587 60.3243 18 3 3 3 89.6840 68.5566 1 -3 3 -4 610.966 43.1352 20 -3 3 -4 626.237 75.7135 18 3 3 4 614.389 42.7288 12 -3 3 -5 137.978 23.0168 20 3 3 5 136.764 23.0595 12 -3 3 -6 57.2496 15.9290 20 3 3 6 51.2876 17.2891 12 -3 4 8 86.7723 12.9481 5 -3 4 6 331.545 24.5892 2 -3 4 6 307.727 29.4847 17 -3 4 5 33.8727 19.6008 17 -3 4 5 2.03238 15.4561 2 -3 4 5 20.5668 46.3387 13 -3 4 4 448.927 30.3728 2 -3 4 4 297.837 55.6029 13 -3 4 3 469.601 35.3289 21 -3 4 3 632.342 36.0669 2 -3 4 3 509.357 60.9803 13 -3 4 2 1951.47 139.030 13 -3 4 2 2163.22 119.572 21 -3 4 1 3188.87 196.469 13 3 4 -1 3197.18 195.828 11 -3 4 0 289.205 24.6711 20 -3 4 0 268.625 53.1694 18 3 4 0 325.320 49.6351 11 -3 4 -1 329.837 27.7422 20 -3 4 -1 329.628 58.8672 18 -3 4 -2 391.694 31.6284 20 -3 4 -2 414.327 63.5740 18 -3 4 -3 260.460 27.9041 20 -3 4 -3 323.760 63.0284 18 3 4 3 248.348 74.6453 1 -3 4 -4 1144.98 69.9040 20 -3 4 -4 1057.44 100.626 18 3 4 4 934.583 111.351 1 3 4 4 1161.14 69.2209 12 -3 4 -5 177.940 24.0213 20 3 4 5 184.992 24.2108 12 -3 4 -6 14.7692 15.7148 20 3 4 6 1.61914 16.6433 12 -3 5 8 392.274 25.7756 5 -3 5 6 95.0581 22.1522 17 -3 5 6 104.044 17.8918 2 -3 5 6 61.3588 46.6817 13 -3 5 5 466.099 30.5195 17 -3 5 5 394.069 62.3621 13 -3 5 4 396.096 29.0723 2 -3 5 4 394.288 56.6638 13 -3 5 3 1160.69 68.1623 21 -3 5 3 1179.73 68.1037 2 -3 5 3 1160.20 90.7457 13 -3 5 2 143.525 17.8431 21 -3 5 2 186.659 46.0623 13 3 5 -2 221.342 45.2436 11 -3 5 1 44.1674 40.7205 13 3 5 -1 88.6364 42.2233 11 -3 5 0 249.303 22.8754 20 -3 5 0 291.016 52.7650 18 3 5 0 230.612 47.2232 11 -3 5 -1 435.170 32.3371 20 -3 5 -1 452.053 63.2645 18 -3 5 -2 832.937 52.0473 20 -3 5 -2 740.149 81.7894 18 -3 5 -3 1196.46 71.8915 20 -3 5 -3 1278.88 104.900 18 3 5 3 1081.46 115.836 1 -3 5 -4 396.598 35.3245 20 -3 5 -4 368.741 65.9323 18 3 5 4 471.340 35.0600 12 -3 5 -5 55.1671 20.4051 20 3 5 5 44.9757 20.6877 12 -3 5 -6 38.8174 15.7138 20 3 5 6 57.0247 17.2811 12 -3 6 6 636.148 40.4099 2 -3 6 6 603.757 42.8884 17 -3 6 6 590.534 71.5586 13 -3 6 5 1563.69 102.357 17 -3 6 5 1387.81 126.991 13 -3 6 4 211.813 21.7292 2 -3 6 4 228.954 51.0077 13 -3 6 3 960.010 53.0810 21 -3 6 3 794.027 52.7392 2 -3 6 3 964.285 78.6865 13 -3 6 2 1068.00 86.0414 13 3 6 -2 1101.23 86.3695 11 -3 6 2 1088.41 63.4790 21 -3 6 1 3026.30 192.572 13 3 6 -1 3251.60 193.254 11 -3 6 0 481.752 34.3218 20 3 6 0 665.030 61.1635 11 -3 6 -1 79.7335 19.2228 20 -3 6 -1 147.157 50.6504 18 -3 6 -2 42.1002 19.9714 20 -3 6 -2-7.18106 49.9840 18 3 6 3 148.392 71.5633 1 -3 6 -3 32.8007 21.5264 20 -3 6 -3 59.5818 51.7846 18 -3 6 -4 695.094 44.8642 20 3 6 4 635.867 43.7921 12 -3 6 -5 167.948 23.1678 20 3 6 5 164.804 23.2003 12 -3 6 -6 15.7019 15.0101 20 3 6 6 18.1553 16.2019 12 -3 7 6 327.706 28.0764 17 -3 7 6 244.749 24.4307 2 -3 7 6 265.158 55.3282 13 -3 7 5 1343.72 71.7727 17 -3 7 5 1067.84 69.8929 2 -3 7 5 1256.86 102.408 13 -3 7 4 567.481 37.5610 2 -3 7 4 536.380 64.4465 13 -3 7 3 458.487 29.9069 21 -3 7 3 377.930 29.7409 2 -3 7 3 471.638 57.5655 13 -3 7 2 1331.65 76.0614 21 -3 7 2 1260.88 97.0195 13 3 7 -2 1323.12 97.6389 11 -3 7 1 161.863 44.7503 13 3 7 -1 170.909 43.5437 11 -3 7 0 628.180 39.7906 20 3 7 0 544.070 61.4239 11 -3 7 -1 187.836 21.6500 20 -3 7 -1 200.988 51.2504 18 -3 7 -2 1778.48 100.671 20 -3 7 -2 1595.85 127.541 18 -3 7 -3 408.496 33.1080 20 -3 7 -3 380.413 63.6754 18 3 7 3 334.813 77.9334 1 -3 7 -4 71.6801 22.8542 20 -3 7 -4 22.3543 49.3929 18 3 7 4 127.875 68.0561 1 3 7 4 69.4306 21.8565 12 -3 7 -5 126.380 22.1318 20 3 7 5 153.764 22.3055 12 -3 7 -6 69.6008 15.5842 20 3 7 6 73.0949 16.5545 12 -3 8 6 27.3386 19.9490 17 -3 8 6 52.4398 18.0065 2 -3 8 6 57.4542 46.6072 13 -3 8 5 15.3627 18.7003 17 -3 8 5 12.9438 45.2098 13 -3 8 5 27.8560 18.1166 2 -3 8 4 321.037 25.9707 2 -3 8 4 220.415 51.0750 13 -3 8 3 107.832 16.2014 21 -3 8 3 96.4238 41.6374 13 -3 8 3 82.2482 16.8944 2 -3 8 2 2004.81 112.825 21 -3 8 2 2055.34 133.975 13 3 8 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31.8501 20 -3 9 -1 439.251 60.5703 18 -3 9 -2 1393.81 80.8706 20 -3 9 -2 1323.82 108.266 18 -3 9 -3 78.7467 21.7255 20 -3 9 -3 29.3692 52.0369 18 3 9 3 72.0296 64.3487 1 -3 9 -4 304.163 29.5267 20 3 9 4 323.330 29.0536 12 -3 9 -5 397.289 32.0993 20 3 9 5 444.411 32.0485 12 3 9 6 28.7843 14.7389 12 -3 10 7 76.3381 15.9406 2 -3 10 6 128.741 21.7719 17 -3 10 6 194.222 22.4254 2 -3 10 6 181.291 49.3566 13 -3 10 5 634.942 47.9986 17 -3 10 5 542.153 73.2316 13 -3 10 4 86.9262 43.7963 13 -3 10 4 39.7561 18.4472 2 -3 10 3 179.601 21.4000 2 -3 10 3 282.543 45.9186 13 -3 10 2 865.803 57.3942 2 -3 10 2 999.652 80.4325 13 3 10 -2 956.125 78.9967 11 -3 10 2 1071.29 57.4223 21 -3 10 1 71.9087 15.9246 21 -3 10 1 139.295 16.8221 2 -3 10 1 113.224 40.5397 13 3 10 -1 100.586 38.3669 11 -3 10 0 158.876 19.4424 20 3 10 0 200.943 43.5505 11 -3 10 -1 109.122 19.3947 20 -3 10 -1 134.478 47.5767 18 -3 10 -2 537.651 37.0213 20 -3 10 -2 469.748 65.0927 18 -3 10 -3 178.553 24.0854 20 -3 10 -3 206.605 56.1073 18 3 10 3 129.518 69.4497 1 -3 10 -4 419.480 34.9056 20 3 10 4 484.650 34.7902 12 -3 10 -5 77.8801 19.2956 20 3 10 5 97.0656 19.4492 12 3 10 6 130.716 16.7003 12 -3 11 7 245.964 22.3132 2 -3 11 6 79.0817 19.5796 17 -3 11 6 75.9139 43.8035 13 -3 11 6 104.825 20.6362 2 -3 11 5 1303.64 73.6119 17 -3 11 5 1203.68 73.5263 2 -3 11 4 85.0294 44.3383 13 -3 11 4 121.751 20.9481 2 -3 11 3 7.82576 38.0866 13 -3 11 2 424.738 29.1499 2 -3 11 2 369.409 50.0827 13 3 11 -2 343.163 51.4139 11 -3 11 2 386.652 27.7206 21 -3 11 1 41.1370 14.8701 21 -3 11 1 64.4992 15.6381 2 -3 11 1 46.8799 37.5302 13 3 11 -1 67.2076 35.8550 11 -3 11 0 486.684 33.0834 20 -3 11 -1 558.610 36.9497 20 -3 11 -1 445.848 62.4354 18 -3 11 -2 962.403 57.8098 20 -3 11 -2 830.763 84.0250 18 -3 11 -3 2.57686 19.9649 20 -3 11 -3 73.3282 48.3854 18 3 11 3 23.6475 63.9005 1 -3 11 -4 215.392 24.5014 20 3 11 4 162.975 23.0869 12 -3 11 -5 68.0716 18.8486 20 3 11 5 96.8975 19.1580 12 -3 12 7 103.399 18.2168 2 -3 12 6 108.054 20.5867 17 -3 12 6 69.1258 42.2712 13 -3 12 6 176.877 22.1399 2 -3 12 5 47.9644 18.0034 17 -3 12 5 45.9072 42.4112 13 -3 12 5 55.3968 20.5342 2 -3 12 4 522.179 37.0853 2 -3 12 4 515.965 61.2122 13 -3 12 3 707.976 67.5189 13 -3 12 2 748.697 40.5153 21 -3 12 2 674.560 63.7289 13 3 12 -2 736.046 64.2327 11 -3 12 1 664.082 43.1019 2 -3 12 1 719.208 42.7246 21 -3 12 1 634.311 64.6797 13 3 12 -1 723.638 64.8696 11 -3 12 0 57.6302 39.3879 13 -3 12 -1 142.157 20.0377 20 -3 12 -1 148.300 48.2867 18 -3 12 -2 546.472 37.8533 20 -3 12 -2 526.953 65.9834 18 -3 12 -3 176.238 23.3783 20 -3 12 -3 123.930 51.3184 18 3 12 3 183.057 22.5955 12 -3 12 -4 97.9505 21.1747 20 3 12 4 79.7058 20.1160 12 -3 12 -5 4.33962 17.1418 20 3 12 5 19.8330 17.3100 12 -3 13 7 202.223 21.4442 2 -3 13 6 210.045 22.5085 17 -3 13 6 228.051 47.3514 13 -3 13 6 158.047 24.0806 2 -3 13 5 338.295 28.9873 17 -3 13 5 395.422 31.2899 2 -3 13 5 310.008 55.5950 13 -3 13 4 963.247 60.7348 2 -3 13 4 1135.68 86.6940 13 -3 13 3 248.918 46.3516 13 -3 13 2 480.013 29.1489 21 -3 13 2 366.689 30.1092 2 -3 13 2 364.866 51.0781 13 3 13 -2 428.827 51.3373 11 -3 13 1 373.206 27.4733 2 -3 13 1 315.862 49.1124 13 3 13 -1 351.419 47.6843 11 -3 13 1 356.782 25.9518 21 -3 13 0 192.043 44.4848 13 -3 13 -1 496.187 34.0892 20 -3 13 -1 426.761 59.1040 18 -3 13 -2 59.0844 18.9120 20 -3 13 -2 37.0951 45.3443 18 -3 13 -3 173.078 23.2487 20 -3 13 -3 177.610 51.7068 18 3 13 3 184.399 22.7763 12 3 13 3 264.133 68.3916 1 -3 13 -4 202.955 24.3124 20 3 13 4 234.557 23.7000 12 -3 13 -5 23.9702 16.4458 20 3 13 5 32.0387 16.6659 12 -3 14 7 15.9132 16.9111 2 -3 14 6 112.662 19.7457 17 -3 14 6 153.825 44.4697 13 -3 14 6 143.047 22.7807 2 -3 14 5 164.973 20.7568 17 -3 14 5 143.886 45.8332 13 -3 14 5 128.726 24.1558 2 -3 14 4 811.793 51.4053 2 -3 14 4 719.889 72.6921 13 -3 14 3 564.836 59.3472 13 3 14 -3 546.414 58.2878 11 -3 14 2 295.068 23.8901 21 -3 14 2 378.608 26.8456 2 -3 14 2 362.733 48.5334 13 3 14 -2 274.356 45.9241 11 -3 14 1 1539.47 88.2911 2 -3 14 1 1493.80 107.494 13 -3 14 1 1570.18 87.7439 21 3 14 -1 1455.72 106.330 11 -3 14 0 673.453 66.1292 13 -3 14 -1 490.742 33.9897 20 3 14 2 57.0389 60.8382 1 -3 14 -2 148.060 20.6975 20 -3 14 -2 105.111 44.5231 18 -3 14 -3 45.0184 19.4202 20 -3 14 -3 19.8392 45.1722 18 3 14 3 56.6008 18.7054 12 3 14 3 48.5595 62.1861 1 -3 14 -4 504.221 36.5535 20 3 14 4 524.736 35.8919 12 -3 14 -5 55.7776 16.3027 20 3 14 5 87.0792 16.7322 12 -3 15 7 155.156 20.4377 2 -3 15 6 25.0342 16.7199 17 -3 15 6 17.4979 20.7271 2 -3 15 5 106.858 19.3466 17 -3 15 5 130.842 44.0997 13 -3 15 5 119.355 23.5001 2 -3 15 4 176.247 44.1155 13 -3 15 4 95.8525 22.4230 2 -3 15 3 1055.01 77.4925 13 3 15 -3 1090.71 77.0684 11 -3 15 2 422.272 28.5794 21 -3 15 2 406.821 31.2101 2 -3 15 2 456.159 52.0655 13 3 15 -2 433.965 50.8927 11 -3 15 1 546.696 58.3260 13 3 15 -1 594.744 58.8846 11 -3 15 1 505.157 37.2342 21 -3 15 0 109.686 39.1617 13 -3 15 -1 103.939 17.6415 20 -3 15 -2 28.9069 17.8833 20 -3 15 -2 24.6891 41.9211 18 3 15 2 50.3067 59.7344 1 -3 15 -3 172.678 22.0086 20 -3 15 -3 147.013 48.3625 18 3 15 3 155.419 64.8716 1 3 15 3 154.402 20.7747 12 -3 15 -4 292.440 26.8266 20 3 15 4 318.074 26.0340 12 -3 15 -5 33.4781 14.9674 20 3 15 5 38.2740 15.1468 12 -3 16 7 25.3948 17.9514 2 -3 16 6 177.046 24.8309 2 -3 16 5 57.9356 16.5458 17 -3 16 5 39.9595 38.4189 13 -3 16 5 29.3453 22.7451 2 -3 16 4 813.063 49.9050 17 -3 16 4 775.681 73.7125 13 -3 16 3 80.9684 36.1416 13 -3 16 3 56.2978 19.9841 2 3 16 -3 66.7886 35.1984 11 -3 16 2 604.728 40.1706 21 -3 16 2 735.217 43.0352 2 -3 16 2 655.351 61.4979 13 3 16 -2 691.232 61.0970 11 -3 16 1 101.134 15.4783 21 -3 16 1 179.115 19.3898 2 -3 16 1 141.449 37.1231 13 3 16 -1 129.098 37.0808 11 -3 16 0 158.746 39.8057 13 -3 16 -1 541.551 35.9157 20 -3 16 -2 30.4064 16.9735 20 -3 16 -2 43.9541 41.6037 18 3 16 2 26.0746 55.9838 1 -3 16 -3 7.71906 18.0728 20 3 16 3-11.7856 16.7730 12 -3 16 -4 37.1833 17.6465 20 3 16 4 29.6104 16.7154 12 3 16 5 78.9293 15.2293 12 -3 17 7 213.364 22.5017 2 -3 17 6 342.794 31.1231 2 -3 17 5 744.672 46.7633 17 -3 17 5 752.214 50.2526 2 -3 17 4 428.651 30.0567 17 -3 17 4 346.639 52.5018 13 -3 17 3 494.668 34.3766 2 -3 17 3 395.899 50.7180 13 3 17 -3 369.645 49.3455 11 -3 17 2 832.284 52.8116 2 -3 17 2 882.333 71.2937 13 -3 17 2 862.892 50.5078 21 3 17 -2 837.888 69.9096 11 -3 17 1 549.378 32.5177 2 -3 17 1 403.796 50.8598 13 3 17 -1 441.234 49.1193 11 -3 17 1 398.393 29.2695 21 -3 17 0 638.439 40.5600 21 -3 17 0 782.203 63.8372 13 -3 17 -1 121.241 38.4692 13 -3 17 -2 994.708 59.5289 20 -3 17 -3 136.404 19.7490 20 3 17 3 139.176 18.8064 12 -3 17 -4 13.1630 16.2224 20 3 17 4 24.6168 15.5879 12 -3 18 7 100.720 19.3743 2 -3 18 6 57.6046 22.6002 2 -3 18 5 89.6350 16.4192 17 -3 18 5 158.932 25.6475 2 -3 18 4 135.337 17.4447 17 -3 18 3 186.470 24.0610 2 -3 18 2 475.277 33.0731 2 -3 18 2 323.725 47.7447 13 -3 18 1 675.551 42.4520 2 -3 18 1 596.419 59.0969 13 -3 18 0 559.390 55.8961 13 -3 19 7 165.937 21.0833 2 -3 19 6 51.0352 22.5306 2 -3 19 5 20.3360 23.6912 2 -3 19 3 115.507 22.8676 2 -3 19 2 90.7136 19.5666 2 -3 19 1 184.054 21.0162 2 -3 20 7 38.6480 18.0677 2 -3 20 6 45.0909 22.6485 2 -3 20 4 198.708 27.0718 2 -3 20 3 156.842 24.2064 2 -3 20 2 661.346 44.0686 2 -3 20 1 114.918 18.9101 2 -3 21 7 412.946 30.3379 2 -3 21 6 140.848 24.6446 2 -3 21 4 323.740 31.6145 2 -3 21 3 100.774 22.9870 2 -3 21 2 1010.78 61.8722 2 -3 21 1 113.064 19.2815 2 -3 22 7 528.586 35.4587 2 -3 22 6 127.339 24.3035 2 -3 22 4 328.213 31.6577 2 -3 22 3 247.417 27.2242 2 -3 22 2 328.056 29.1980 2 -3 22 1 743.408 46.9774 2 -3 23 7 111.526 18.4876 2 -3 23 6 48.1990 22.1392 2 -3 23 4 564.369 42.0241 2 -3 23 3 347.806 31.6682 2 -3 23 2 223.647 25.2155 2 -3 23 1 313.778 26.7173 2 -3 24 7 8.01915 16.0503 2 -3 24 6 60.5604 22.1485 2 -3 24 4 107.975 25.5129 2 -3 24 3 222.711 26.9634 2 -3 24 2 327.058 29.3754 2 -3 24 1 1942.32 110.263 2 -3 25 7 248.537 21.9484 2 -3 25 5 27.7302 24.1420 2 -3 25 4 415.156 35.8431 2 -3 25 3 72.8678 23.4656 2 -3 25 2 287.321 27.6702 2 -3 25 1 126.488 19.8673 2 -3 26 5 0.36779 23.7284 2 -3 26 4 409.502 35.5167 2 -3 26 3 581.462 42.0681 2 -3 26 2 412.173 32.9487 2 -3 26 1 313.687 26.6188 2 -3 27 5 145.592 26.0089 2 -3 27 4 232.363 28.6986 2 -3 27 3 22.5330 22.3700 2 -3 27 2 308.710 28.2864 2 -3 28 5 31.5624 22.8277 2 -3 28 4 384.712 33.6780 2 -3 28 3 42.6445 22.6018 2 -3 28 2 333.629 29.3568 2 -3 29 5 216.491 25.9084 2 -3 29 4 141.388 24.9328 2 -3 29 3 339.829 31.0335 2 -3 29 2 196.925 23.8932 2 -3 30 6 206.716 21.7542 2 -3 30 5 34.6752 21.0487 2 -3 30 4 84.1163 23.1155 2 -3 30 3 187.510 25.1510 2 -3 30 2 226.562 24.2839 2 -3 31 6 35.0970 16.3901 2 -3 31 5 62.6645 20.2461 2 -3 31 4 314.110 29.1947 2 -3 31 3 109.706 22.3518 2 -3 31 2 132.350 20.6601 2 -3 32 5 4.91134 18.9167 2 -3 32 4 11.3760 20.1847 2 -3 32 3 98.3855 21.1437 2 -3 32 2 58.4343 18.1816 2 -3 33 5 5.38006 17.6688 2 -3 33 4 18.0608 19.0473 2 -3 33 3 91.3205 19.8566 2 -3 34 5 68.3078 16.9882 2 -3 34 4 128.664 20.1237 2 -3 34 3 26.2501 17.6481 2 -3 35 4 70.8707 17.4260 2 -3 35 3 320.123 25.5117 2 -3 36 4 68.3438 16.1695 2 -3 37 4 53.4332 13.5768 2 -4 -34 2 49.9609 11.9274 10 -4 -34 1 31.5963 10.0412 10 4 -34 -1 45.0115 20.3142 16 -4 -33 3 61.3795 12.0181 5 -4 -33 2 40.1021 12.9829 10 4 -33 -2 52.1567 21.9372 16 4 -33 -1 135.334 25.1489 16 -4 -33 1 157.344 14.9954 10 -4 -33 0 17.7514 7.75205 10 -4 -33 0 29.3450 10.3413 9 -4 -32 4 13.2999 11.7641 5 -4 -32 3 303.241 21.8890 5 -4 -32 3 286.555 22.9154 10 4 -32 -2 178.507 26.6449 16 -4 -32 2 182.277 18.0837 10 -4 -32 1 89.0702 13.9777 10 -4 -32 1 104.813 12.1764 9 4 -32 -1 111.763 25.4033 16 -4 -32 0 157.166 14.3688 9 -4 -32 0 133.768 12.9954 10 -4 -31 4 33.3828 12.5191 5 -4 -31 3 403.445 28.8146 5 -4 -31 3 483.065 30.4094 10 -4 -31 2 9.20899 11.6114 5 -4 -31 2 4.52621 14.6282 10 4 -31 -2 26.6999 24.4728 16 -4 -31 1 134.892 16.0838 10 -4 -31 1 147.917 13.9668 9 4 -31 -1 112.036 26.7042 16 -4 -31 0 22.2655 10.4629 10 -4 -31 0 26.7111 11.7038 9 -4 -31 -1 84.3583 12.5368 9 -4 -30 4 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26.6002 16 -4 -28 0 38.2310 12.8183 10 -4 -28 -1 46.2126 10.0354 10 4 -28 1 53.1907 24.2347 16 4 -28 2 5.57606 14.2204 6 -4 -27 5 43.3602 13.4957 5 -4 -27 4 36.6127 16.5675 10 -4 -27 4 33.9688 14.3416 5 -4 -27 3 84.7374 18.5997 10 -4 -27 3 87.2409 15.3186 5 4 -27 -2 207.420 31.9268 16 -4 -27 2 212.563 19.8680 5 -4 -27 2 262.132 23.0451 10 4 -27 -1 203.987 31.6451 16 -4 -27 1 150.799 16.2206 5 -4 -27 1 243.248 20.5331 10 -4 -27 0 119.661 15.6657 10 4 -27 0 87.6562 28.9782 16 -4 -27 -1 32.2584 10.9230 10 4 -27 1 55.2676 25.1037 16 4 -27 2 43.8892 20.4291 16 4 -27 2 106.269 16.6686 6 -4 -26 5 227.204 19.8843 5 -4 -26 4 121.276 19.5399 10 -4 -26 4 150.413 17.4483 5 -4 -26 3 83.8727 15.5102 5 4 -26 -3 85.2257 26.4483 16 -4 -26 2 36.6669 13.6348 5 -4 -26 2 45.1085 17.8881 10 4 -26 -2-0.54149 27.4705 16 -4 -26 1 22.3835 11.6631 5 -4 -26 1 50.7729 16.7056 10 -4 -26 0 14.9442 14.3072 10 4 -26 0 7.35549 28.0297 16 -4 -26 -1 20.5196 11.2646 10 4 -26 1 19.1733 26.2412 16 4 -26 2 14.4802 21.6919 16 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7 187.629 19.3745 5 -4 -3 7 176.018 21.7933 17 -4 -3 5 982.103 90.8775 13 -4 -3 4 56.7553 12.0374 10 -4 -3 4 80.9754 47.9486 13 -4 -3 3 561.245 36.0191 10 -4 -3 3 479.346 68.2170 13 -4 -3 2 807.651 48.0773 5 -4 -3 2 1016.35 85.0915 13 -4 -3 1 243.390 56.1085 13 -4 -3 0 78.9071 49.9260 13 -4 -2 8 58.6375 10.8471 5 -4 -2 7 73.7468 16.0489 5 -4 -2 3 204.017 19.4499 10 -4 -2 2 6.93321 9.76866 5 -4 -1 8 2.89640 9.91878 5 -4 -1 7 92.3513 16.6665 5 4 -1 -4 132.401 50.5399 11 -4 -1 3 1124.57 67.6585 21 -4 -1 3 1105.77 65.1955 10 4 -1 -3 1177.72 99.3111 11 -4 -1 2 85.6323 21.3434 21 4 -1 -2 33.7402 47.5478 11 4 -1 -1 62.1052 49.1676 11 -4 -1 1 136.949 22.6794 21 -4 0 8 39.6862 10.6797 5 -4 0 7 66.5217 16.0164 5 -4 0 7 34.2639 18.0242 17 -4 0 6 54.1092 21.4771 17 -4 0 5 532.532 69.7499 13 -4 0 4 100.005 47.6418 13 4 0 -4 118.531 51.9272 11 -4 0 3 297.467 25.3682 21 -4 0 3 138.473 17.6540 10 -4 0 3 218.871 55.9472 13 4 0 -3 252.133 55.2411 11 -4 0 2 452.528 64.1419 13 4 0 -2 483.316 64.9107 11 -4 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629.479 73.1991 13 4 2 -4 635.771 74.0802 11 -4 2 3 221.901 25.2598 21 -4 2 3 296.848 58.0975 13 4 2 -3 243.831 56.1868 11 -4 2 2 1.11841 19.2432 21 -4 2 2-17.9756 48.0083 13 4 2 -2-5.20738 46.2391 11 -4 2 1 86.4296 21.5758 21 -4 2 1 93.8606 48.5196 13 4 2 -1 140.193 49.5318 11 -4 2 0 2.71369 47.0092 13 -4 2 -1 937.944 59.7506 20 -4 2 -2 409.775 34.8911 20 -4 2 -3 116.021 23.1127 20 -4 2 -4 156.268 21.2886 20 4 2 4 157.307 21.6267 12 -4 3 8 112.126 12.9686 5 -4 3 7 178.357 21.5328 17 -4 3 6 58.2054 21.3228 17 -4 3 5 993.549 92.9257 13 -4 3 4 45.9459 45.9354 13 4 3 -4 28.2347 45.7831 11 -4 3 3 541.029 39.3771 21 -4 3 3 593.385 69.1689 13 4 3 -3 620.485 71.9615 11 -4 3 2 848.815 86.8403 13 4 3 -2 1099.47 92.8936 11 -4 3 2 976.984 59.9162 21 -4 3 1 348.989 60.4927 13 4 3 -1 322.168 58.7608 11 -4 3 1 351.930 30.1367 21 -4 3 0 105.667 50.2932 13 -4 3 -1 635.170 45.0743 20 -4 3 -2 32.4743 22.7726 20 -4 3 -3 35.6994 21.5384 20 4 3 3 28.8638 21.8041 12 -4 3 -4 74.6975 18.6964 20 4 3 4 75.8107 19.2674 12 -4 4 8 226.472 17.3032 5 -4 4 7 112.797 19.4141 17 -4 4 6 6.02664 19.7269 17 -4 4 5 503.829 67.5946 13 -4 4 4 118.748 49.1727 13 4 4 -4 39.4545 48.1368 11 -4 4 3 348.042 29.6946 21 -4 4 3 273.124 57.0137 13 4 4 -3 389.964 62.3115 11 -4 4 2 88.4216 20.2436 21 -4 4 2 35.8746 46.7132 13 4 4 -2 72.9294 48.6379 11 -4 4 1-19.9029 19.3751 21 -4 4 1 5.20243 47.6403 13 4 4 -1 36.4152 44.7954 11 -4 4 0 5.38956 46.9561 13 -4 4 -1 376.073 33.4722 20 -4 4 -2 35.4599 23.0573 20 -4 4 -3 141.410 23.6516 20 4 4 3 120.281 23.0354 12 -4 4 -4 126.535 19.5680 20 4 4 4 120.829 20.3934 12 -4 5 8 9.89395 10.2306 5 -4 5 7 24.0335 17.0962 17 -4 5 6 19.1006 20.7777 17 -4 5 5 437.188 63.3524 13 -4 5 4 70.0215 48.0238 13 4 5 -4 89.7844 47.2541 11 -4 5 3 1138.67 69.3431 21 -4 5 3 1132.92 97.8707 13 4 5 -3 1298.73 101.042 11 -4 5 2 183.426 23.1427 21 -4 5 2 253.455 54.9688 13 4 5 -2 226.519 51.3287 11 -4 5 1 223.008 54.6101 13 4 5 -1 176.838 50.8422 11 -4 5 1 191.653 23.9786 21 -4 5 0 395.196 61.7922 13 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277.321 55.8283 13 4 7 -2 277.398 55.6298 11 -4 7 2 242.135 24.9428 21 -4 7 1 66.1576 19.4871 21 -4 7 1 28.3601 46.1564 13 4 7 -1 57.0943 44.6321 11 -4 7 0 508.411 67.1035 13 -4 7 -1 1078.74 64.3856 20 -4 7 -1 818.794 88.9139 13 -4 7 -2 69.8878 22.7119 20 -4 7 -3 55.5937 20.8688 20 4 7 3 26.5055 20.4348 12 -4 7 -4-0.53443 16.5585 20 4 7 4-2.52598 17.2873 12 -4 8 8 223.331 17.1937 5 -4 8 7 104.648 18.1177 17 -4 8 6 54.2411 19.8697 17 -4 8 5 89.0195 45.7225 13 -4 8 4 194.961 50.0014 13 4 8 -4 172.979 50.7421 11 -4 8 3 472.242 33.5587 21 -4 8 3 371.844 60.9433 13 4 8 -3 388.444 61.3580 11 -4 8 2 505.051 63.6341 13 4 8 -2 423.154 63.5590 11 -4 8 2 448.440 33.6806 21 -4 8 1 159.027 50.7769 13 4 8 -1 274.347 53.6169 11 -4 8 1 227.658 24.4409 21 -4 8 0 280.332 56.4411 13 -4 8 -1 390.965 60.9291 13 -4 8 -2 96.4177 22.3999 20 -4 8 -3 170.177 22.7988 20 4 8 3 148.760 22.2299 12 -4 8 -4 14.5534 16.3844 20 4 8 4 17.8195 17.0810 12 -4 9 6 288.227 26.7300 17 -4 9 5 79.5952 21.4542 17 -4 9 5 135.756 21.2361 2 -4 9 5 85.4174 47.6076 13 4 9 -5 102.990 45.6239 11 -4 9 4 131.194 22.3856 2 -4 9 4 58.4854 45.5613 13 4 9 -4 94.9136 46.7381 11 -4 9 3 231.047 24.9615 21 -4 9 3 257.000 52.9549 13 4 9 -3 330.110 56.9069 11 -4 9 2 130.068 20.2564 21 -4 9 2 93.4353 45.9527 13 4 9 -2 151.343 48.4526 11 -4 9 1 435.532 60.8021 13 4 9 -1 311.564 57.0352 11 -4 9 1 413.797 31.3041 21 -4 9 0 76.1090 43.1863 13 -4 9 -1 257.291 56.3240 13 -4 9 -2 262.712 27.4513 20 -4 9 -3-13.6793 18.9920 20 4 9 3-11.3071 18.9497 12 -4 9 -4 896.335 56.3506 20 4 9 4 1000.54 56.4722 12 -4 10 6 267.587 25.8167 17 -4 10 5 227.143 24.5943 2 -4 10 5 217.332 24.4665 17 -4 10 5 204.150 49.8580 13 4 10 -5 198.982 48.5829 11 -4 10 4 192.865 24.2139 2 -4 10 4 177.037 47.2502 13 4 10 -4 133.483 48.0679 11 -4 10 3 227.448 52.8019 13 4 10 -3 250.279 54.0248 11 -4 10 2 859.453 52.1215 21 -4 10 2 785.840 80.0936 13 4 10 -2 712.094 77.9270 11 -4 10 1 273.655 54.9833 13 4 10 -1 321.757 54.6788 11 -4 10 1 295.784 26.8204 21 -4 10 0 62.4072 43.7396 13 -4 10 -1 473.918 63.7142 13 -4 10 -2 143.072 23.2154 20 -4 10 -3 28.3066 19.3086 20 4 10 3 32.2270 18.6292 12 4 10 4 79.8341 16.8916 12 -4 11 6 107.076 19.8731 17 -4 11 6 145.655 20.1883 2 -4 11 5-6.28850 18.6318 17 -4 11 5-14.3913 19.7607 2 -4 11 4 197.813 24.8926 2 -4 11 4 172.829 47.2023 13 4 11 -4 130.928 47.2011 11 -4 11 3 826.546 78.0999 13 4 11 -3 791.714 78.9104 11 -4 11 2 415.571 31.4180 21 -4 11 2 418.533 58.8094 13 4 11 -2 414.873 58.6444 11 -4 11 1 463.581 62.7237 13 4 11 -1 489.923 61.5640 11 -4 11 1 480.437 34.4255 21 -4 11 0 27.5717 18.8513 21 -4 11 0 108.105 44.4655 13 -4 11 -1 292.864 54.8123 13 -4 11 -2 318.411 28.7483 20 -4 11 -3 139.622 20.9984 20 4 11 3 139.984 21.2125 12 4 11 4 26.7868 15.0947 12 -4 12 6 280.163 23.7350 2 -4 12 6 186.439 22.7750 17 -4 12 5 337.420 28.9338 2 -4 12 5 308.169 28.0333 17 -4 12 4 266.162 28.1222 2 -4 12 4 263.944 51.9585 13 4 12 -4 306.843 53.0866 11 -4 12 3 283.460 51.8355 13 4 12 -3 336.383 53.6958 11 -4 12 2 127.913 19.9275 21 -4 12 2 88.8008 43.8544 13 4 12 -2 163.613 47.0057 11 -4 12 1 178.594 47.8247 13 -4 12 1 186.150 21.6516 21 -4 12 0 106.717 46.2382 13 -4 12 0 155.122 21.0924 21 -4 12 -1 755.356 76.1709 13 4 12 3 44.5855 18.0552 12 4 12 4 67.9311 15.2573 12 -4 13 6 278.904 24.2308 2 -4 13 6 220.760 22.8011 17 -4 13 5-0.37177 17.6364 17 -4 13 5 20.0414 20.1809 2 -4 13 4 45.0401 21.9888 2 -4 13 4-17.8341 41.2214 13 4 13 -4 59.5614 40.9599 11 -4 13 3 543.935 63.9918 13 4 13 -3 563.999 64.5221 11 -4 13 2 287.790 24.9950 21 -4 13 2 277.839 50.5457 13 4 13 -2 202.164 47.3062 11 -4 13 1 154.791 20.1573 21 -4 13 1 173.826 46.2553 13 -4 13 0 6.90524 17.5784 21 -4 13 0 25.0047 39.0303 13 -4 13 -1 156.706 46.8201 13 4 13 3 9.80572 16.6579 12 4 13 4 214.835 18.9830 12 -4 14 6 125.926 17.7658 17 -4 14 6 100.138 20.0186 2 -4 14 5 122.501 20.1538 17 -4 14 5 164.754 23.4306 2 -4 14 4 157.853 24.1992 2 -4 14 4 155.533 45.2756 13 4 14 -4 115.261 42.2929 11 -4 14 3 186.899 46.2905 13 4 14 -3 126.440 42.7931 11 -4 14 2 145.296 19.6022 21 -4 14 2 218.061 47.2447 13 4 14 -2 149.948 43.7000 11 -4 14 1 363.600 54.9634 13 -4 14 1 344.125 27.5015 21 -4 14 0 21.1919 16.8399 21 -4 14 0 56.2701 41.8193 13 -4 14 -1 614.430 67.7102 13 4 14 3 186.287 20.3062 12 4 14 4 87.4540 13.0045 12 -4 15 6 165.239 22.1679 2 -4 15 6 207.005 19.8285 17 -4 15 5 427.428 32.1594 2 -4 15 5 335.340 28.5088 17 -4 15 4 19.5779 38.1180 13 -4 15 3 75.8531 39.8345 13 4 15 -3 23.0696 37.2904 11 -4 15 2 785.402 46.2868 21 -4 15 2 605.151 69.6431 13 4 15 -2 571.610 68.0042 11 -4 15 1 160.103 44.4574 13 -4 15 1 200.275 20.9054 21 -4 15 0 231.400 48.7313 13 -4 15 0 318.275 25.7841 21 -4 15 -1 160.923 20.3324 21 4 15 3 84.5012 16.3486 12 -4 16 6 5.39695 13.2979 17 -4 16 6 30.4768 18.3152 2 -4 16 5 159.901 19.4674 17 -4 16 5 151.192 24.1109 2 -4 16 3 196.936 25.9935 2 -4 16 2 1580.32 90.3675 21 -4 16 2 1550.19 115.149 13 -4 16 1 290.432 49.6651 13 -4 16 1 324.786 25.7175 21 -4 16 0 277.021 24.1579 21 -4 16 -1 126.515 18.2577 21 4 16 2 114.707 18.5296 12 4 16 3 87.5930 15.2439 12 -4 17 6 181.255 22.0381 2 -4 17 5 68.6115 15.9293 17 -4 17 5 79.9708 22.3383 2 -4 17 3 458.205 36.2136 2 -4 17 1 258.530 22.2568 21 -4 17 0-4.71399 14.6656 21 -4 17 -1 128.468 17.7107 21 -4 17 -2 158.317 18.9325 21 4 17 2 229.963 19.9942 12 -4 18 6 31.1465 18.2961 2 -4 18 5 24.8497 21.4020 2 -4 18 4 86.1801 16.3361 17 -4 18 3 162.651 25.2165 2 -4 18 1 238.070 20.9804 21 -4 19 6 47.2830 18.4130 2 -4 19 5 475.644 36.3049 2 -4 19 4 233.327 27.3416 2 -4 19 3 191.934 26.0097 2 -4 20 6 4.80357 17.5288 2 -4 20 4 150.818 25.2940 2 -4 21 6 262.737 24.4049 2 -4 21 4 72.6709 23.5093 2 -4 22 6 192.057 21.3187 2 -4 22 4 24.4603 22.4814 2 -4 23 6 157.389 19.6907 2 -4 23 4 72.3930 22.3397 2 -4 24 6 53.4332 16.7492 2 -4 24 5 295.770 26.8889 2 -4 24 4 146.145 23.9132 2 -4 25 5 233.308 24.3842 2 -4 25 4 47.9720 21.0361 2 -4 26 5 234.069 23.5836 2 -4 26 4 194.079 24.2630 2 -5 -25 2 273.908 20.8312 10 -5 -24 3-9.12967 12.9516 10 -5 -24 2 121.074 15.6041 10 -5 -24 1 3.34032 11.8821 10 -5 -23 4 24.3126 11.7078 10 -5 -23 4 48.7005 9.59981 5 -5 -23 3 83.5536 9.82077 5 -5 -23 3 81.8577 14.9960 10 -5 -23 2 12.5653 13.4810 10 5 -23 -2 7.66101 18.3032 16 5 -23 -1 258.598 28.7338 16 -5 -23 1 363.508 23.7616 10 -5 -22 4 39.0083 12.4447 10 -5 -22 4 33.6518 9.68224 5 -5 -22 3 56.5773 9.46696 5 -5 -22 3 64.9787 14.5830 10 5 -22 -2 31.0314 19.6163 16 5 -22 -1 214.026 27.3559 16 -5 -22 1 320.666 22.3310 10 -5 -22 0 48.0590 11.7351 10 5 -22 0 39.7299 20.1489 16 -5 -21 4 66.3531 13.3925 10 -5 -21 4 57.0773 10.5420 5 -5 -21 3 69.8691 15.3982 10 -5 -21 3 59.4723 9.90275 5 5 -21 -2 33.0364 20.2250 16 -5 -21 1 100.361 15.4671 10 5 -21 -1 51.2569 22.3035 16 -5 -21 0 89.8634 13.5557 10 5 -21 0 83.8168 21.7778 16 -5 -20 5 34.1134 10.1889 5 -5 -20 4 61.8168 13.7968 10 -5 -20 4 61.0854 10.9101 5 -5 -20 3 31.4766 14.7950 10 -5 -20 3-0.48257 9.13758 5 5 -20 -2 78.7597 21.9343 16 -5 -20 1 36.5261 14.8733 10 5 -20 -1 12.9310 22.0662 16 -5 -20 0 65.6946 13.4538 10 5 -20 0 27.8528 22.4099 16 -5 -19 5 52.1253 10.9762 5 -5 -19 4 54.1625 13.5040 10 -5 -19 4 34.5363 10.8399 5 -5 -19 3 137.720 17.2208 10 -5 -19 3 110.026 12.0892 5 5 -19 -2 49.0502 21.4425 16 -5 -19 1 122.650 17.3132 10 5 -19 -1 100.281 24.3493 16 -5 -19 0 149.510 16.3947 10 5 -19 0 95.3330 24.5300 16 -5 -19 -1 2.06050 10.2088 10 5 -19 1 4.59924 19.5715 16 5 -19 1 11.2980 9.94990 6 -5 -18 5 34.7511 11.0517 5 -5 -18 4 76.1961 14.4032 10 -5 -18 4 85.0604 12.2808 5 -5 -18 3 0.53603 14.8902 10 -5 -18 3 10.2270 9.54389 5 5 -18 -2 60.3524 21.9885 16 -5 -18 1 35.3773 15.3306 10 5 -18 -1-10.3330 23.4697 16 -5 -18 0 150.231 17.1671 10 5 -18 0 132.586 26.1123 16 -5 -18 -1 153.039 14.5067 10 5 -18 1 109.750 22.9912 16 5 -18 1 138.362 13.7659 6 -5 -17 5 53.1017 11.7950 5 -5 -17 4 41.5129 13.5228 10 -5 -17 4 6.86065 10.8887 5 -5 -17 3 127.163 17.5265 10 -5 -17 3 110.216 12.4491 5 -5 -17 2 78.0512 17.0658 10 5 -17 -2 52.5881 22.5050 16 -5 -17 1 25.9205 15.6042 10 5 -17 -1-25.4788 25.2588 16 -5 -17 0 71.8532 15.3603 10 -5 -17 -1 67.8245 12.8686 10 5 -17 1 74.0579 11.6914 6 -5 -16 5 99.9427 12.8305 5 -5 -16 4 226.186 18.4584 5 -5 -16 4 260.794 20.5870 10 -5 -16 3 7.63715 15.2464 10 -5 -16 3 14.4644 9.82812 5 -5 -16 2 27.2713 16.7933 10 5 -16 -2 5.90596 22.0481 16 -5 -16 1-16.9622 16.5320 10 5 -16 -1 8.32811 24.1438 16 -5 -16 0 8.34180 14.8175 10 -5 -16 -1 82.9513 13.3461 10 5 -16 1 68.4305 11.8853 6 -5 -15 5 12.6800 11.0280 5 -5 -15 4 18.8610 12.9647 10 -5 -15 4 41.7226 11.1342 5 -5 -15 4 29.5564 12.8258 17 -5 -15 3 68.3453 16.2108 10 -5 -15 3 38.3867 10.3002 5 -5 -15 2 256.524 22.8241 10 5 -15 -2 167.859 27.0809 16 -5 -15 1 37.1160 13.6564 21 -5 -15 0 35.4824 12.5463 21 -5 -15 0 56.7579 16.3886 10 -5 -15 -1 258.036 19.3616 10 5 -15 1 189.287 16.9191 6 -5 -14 6 111.405 12.7407 5 -5 -14 5 0.79257 11.0876 5 -5 -14 5 13.5256 12.1803 17 -5 -14 4 20.2669 13.1018 10 -5 -14 4 13.7615 11.0862 5 -5 -14 4 5.39722 13.6782 17 -5 -14 3 68.1659 16.5449 10 -5 -14 3 69.6695 11.2282 5 -5 -14 2 47.7807 17.4034 10 5 -14 -2-9.36618 23.1520 16 -5 -14 1 158.720 18.0713 21 -5 -14 0 119.099 15.3309 21 -5 -14 0 110.478 17.8686 10 -5 -14 -1 11.7442 10.9655 21 -5 -14 -1 24.5442 13.7336 10 -5 -13 6 226.182 17.4440 5 -5 -13 5 46.5598 12.0870 5 -5 -13 5 47.9094 13.8945 17 -5 -13 4 266.305 19.9233 5 -5 -13 4 259.879 21.2494 10 -5 -13 3 91.1313 16.3683 10 -5 -13 3 75.4100 11.5014 5 -5 -13 2 430.076 30.0385 10 5 -13 -2 324.384 33.7387 16 -5 -13 1 1.44340 14.8943 21 -5 -13 0 27.9588 14.0356 21 -5 -13 0 44.6330 16.9163 10 -5 -13 -1 59.8422 12.7209 21 -5 -13 -1 66.1866 15.1767 10 -5 -12 6 196.283 16.4118 5 -5 -12 5 86.2221 13.1451 5 -5 -12 5 61.8564 15.0044 17 -5 -12 4 104.017 14.4320 10 -5 -12 4 60.5407 12.6776 5 -5 -12 3 108.202 17.2165 10 -5 -12 3 68.1721 11.2004 5 -5 -12 2 461.268 33.3456 10 -5 -12 1 111.196 17.5276 21 -5 -12 0 357.353 27.1390 10 -5 -12 0 306.127 25.2491 21 -5 -12 -1 100.644 14.7446 21 -5 -12 -1 94.7274 16.3505 10 -5 -12 -2 90.2221 12.4245 10 5 -12 2 72.9628 13.7331 12 -5 -11 6 55.8337 11.8777 5 -5 -11 6 11.7151 12.0768 17 -5 -11 5 50.1687 12.1573 5 -5 -11 5 19.4501 15.0821 17 -5 -11 4 114.662 15.6512 10 -5 -11 4 169.575 15.1189 5 -5 -11 3 54.7500 15.9930 10 -5 -11 3 68.4584 10.9874 5 -5 -11 2 45.5046 17.4443 21 -5 -11 2 30.7130 17.2115 10 -5 -11 1 22.5430 16.1464 21 -5 -11 0 293.321 25.6909 10 -5 -11 0 271.051 23.7070 21 -5 -11 -1 336.286 24.3647 10 -5 -11 -1 265.450 22.9679 21 -5 -11 -2 339.727 22.7639 10 5 -11 2 307.294 23.7574 12 -5 -10 6-15.7857 11.2264 5 -5 -10 6 8.45536 12.5622 17 -5 -10 5 6.96384 11.8894 5 -5 -10 5 33.0189 15.5321 17 -5 -10 4 230.379 18.3927 5 -5 -10 4 216.338 19.1713 10 -5 -10 3 164.593 19.0116 10 -5 -10 3 161.999 14.6061 5 -5 -10 2 82.4631 19.5260 21 -5 -10 2 138.722 19.1551 10 -5 -10 1 259.620 24.9425 21 -5 -10 1 312.682 26.3894 10 -5 -10 0 18.3709 16.1451 21 -5 -10 0 28.1635 17.8072 10 -5 -10 -1 108.658 16.9747 21 -5 -10 -1 144.919 18.4004 10 -5 -10 -2 172.814 15.9352 10 5 -10 2 192.722 17.9016 12 -5 -9 6 10.6346 11.3116 5 -5 -9 6 15.1401 13.2555 17 -5 -9 5 279.392 27.3530 17 -5 -9 5 415.174 25.0527 5 -5 -9 4 66.0374 13.2840 10 -5 -9 4 73.3878 12.6482 5 -5 -9 3 61.4331 15.5831 10 -5 -9 3 27.0045 10.0908 5 -5 -9 2 5.94709 18.0189 21 -5 -9 2 3.70665 17.1942 10 -5 -9 1 120.264 19.0204 21 -5 -9 1 72.7062 19.7181 10 -5 -9 0 21.0579 16.6203 21 -5 -9 -1 93.7664 16.5371 21 -5 -9 -2 126.639 15.0227 10 5 -9 2 137.157 17.0184 12 -5 -8 6 87.1571 12.8632 5 -5 -8 6 27.3406 14.6273 17 -5 -8 5 20.8531 12.3413 5 -5 -8 5 46.7637 16.9531 17 -5 -8 4 110.019 13.6474 10 -5 -8 4 73.9697 12.9489 5 -5 -8 3 16.7018 14.5786 10 -5 -8 3 15.9978 9.90981 5 -5 -8 2 136.005 20.7882 21 -5 -8 2 141.513 19.9876 10 -5 -8 1 167.779 21.6429 21 -5 -8 1 176.481 22.2352 10 -5 -8 0 58.0538 17.9815 21 -5 -8 -1 82.7128 16.8672 21 -5 -8 -2 1.96585 12.8172 21 -5 -8 -2 19.1750 13.2028 10 5 -8 2 8.32894 15.4027 12 -5 -7 6 260.189 22.9344 17 -5 -7 6 300.197 21.1981 5 -5 -7 5 59.9510 12.6742 5 -5 -7 5 28.3823 17.4730 17 -5 -7 4 104.406 13.3926 5 -5 -7 3 177.707 17.9259 10 -5 -7 3 100.847 12.6998 5 -5 -7 2 353.221 31.0393 21 -5 -7 2 426.065 30.4010 10 -5 -7 1-0.71500 18.4696 21 -5 -7 1-2.84861 17.6593 10 -5 -7 0 204.304 22.5030 21 -5 -7 -1 16.2356 16.1057 21 -5 -7 -2 107.044 15.4943 21 5 -7 2 122.876 18.2202 12 -5 -6 6 127.515 18.0890 17 -5 -6 6 158.541 15.8165 5 -5 -6 5 14.8860 12.0120 5 -5 -6 5 10.6918 17.5784 17 -5 -6 4 95.4755 13.4095 5 -5 -6 3 152.920 18.6858 10 -5 -6 3 192.791 15.3711 5 -5 -6 2 156.140 22.3583 21 -5 -6 2 167.966 20.5100 10 -5 -6 1 55.2766 19.3332 21 -5 -6 0 100.400 20.1565 21 -5 -6 -1 26.0184 16.2397 21 -5 -6 -2 102.639 15.4944 21 5 -6 2 85.0867 18.1310 12 -5 -5 6 19.6251 11.9053 5 -5 -5 6 2.47618 15.2760 17 -5 -5 5 242.464 23.9416 17 -5 -5 5 217.272 18.8696 5 -5 -5 4 375.353 25.5932 5 -5 -5 3 564.540 32.0844 10 -5 -5 3 409.493 28.6707 5 -5 -5 2 14.1922 19.0421 21 -5 -5 2-11.1685 16.4887 10 -5 -5 1 9.94476 18.7317 21 -5 -5 0 197.079 23.0541 21 -5 -5 -1-1.85795 16.5730 21 -5 -5 -2 44.9078 14.5076 21 5 -5 2 40.8711 17.5036 12 -5 -4 6 35.3824 12.3061 5 -5 -4 6 49.6863 16.1690 17 -5 -4 5 171.652 22.5204 17 -5 -4 5 186.653 17.3244 5 -5 -4 4 116.657 14.1257 5 -5 -4 3 52.4325 14.4678 10 -5 -4 2 65.2628 20.8394 21 -5 -4 2 67.0505 17.2594 10 -5 -4 1 112.381 21.7036 21 -5 -4 0 545.262 38.2418 21 -5 -4 -1 364.904 28.5245 21 -5 -4 -2 76.6067 15.4940 21 -5 -3 6 14.8603 12.2947 5 -5 -3 6 27.4012 15.9506 17 -5 -3 5 52.7133 13.0246 5 -5 -3 4 92.6654 13.2154 5 -5 -3 3 69.3770 14.4634 10 -5 -3 2 250.147 23.3977 10 -5 -2 6 78.2277 13.6730 5 -5 -2 5 301.592 22.3943 5 -5 -2 4 223.170 18.2818 5 -5 -2 3-1.63874 12.8093 10 -5 -2 2 1.32662 16.0901 10 -5 -1 6 562.823 35.0863 5 -5 -1 5 179.495 17.2685 5 -5 -1 4 21.3600 11.3230 5 -5 -1 3 19.9592 12.4775 10 -5 -1 2 79.7477 20.8489 21 -5 0 6 94.6326 14.8960 5 -5 0 5 102.469 14.6159 5 -5 0 4-4.19569 11.0764 5 -5 0 3-3.35107 11.7727 10 -5 0 2 51.8593 20.4170 21 -5 0 1 151.160 22.4919 21 -5 0 0 25.7853 19.2425 21 -5 0 -1 246.474 24.1431 21 -5 0 -2-2.34555 14.7727 21 5 0 2-11.3634 17.6309 12 -5 1 6 527.088 32.2334 5 -5 1 6 471.557 34.2248 17 -5 1 5 192.292 17.8335 5 -5 1 4 31.1142 11.7683 5 -5 1 3 6.48044 10.9754 10 -5 1 2 95.8301 21.1658 21 -5 1 1 157.550 22.6013 21 -5 1 0 531.310 37.7805 21 -5 1 -1 95.5302 19.0353 21 -5 1 -2 36.9717 15.1879 21 5 1 2 48.9132 17.9954 12 -5 2 6 12.9579 12.0015 5 -5 2 6 38.9359 16.2295 17 -5 2 5 310.575 22.9438 5 -5 2 4 214.167 17.8692 5 -5 2 2 2.64922 19.3751 21 -5 2 1 126.873 21.4862 21 -5 2 0 143.220 22.1426 21 -5 2 -1 73.4921 18.3159 21 -5 2 -2 26.4181 14.9710 21 5 2 2 16.0381 17.6751 12 -5 3 6 19.3081 12.2088 5 -5 3 6 5.70931 15.6074 17 -5 3 5 39.5622 12.8200 5 -5 3 4 81.4279 13.0490 5 -5 3 2 239.425 25.5662 21 -5 3 1 11.8940 19.1282 21 -5 3 0 124.479 21.0191 21 -5 3 -1 236.984 23.4953 21 -5 3 -2 60.2816 15.7003 21 5 3 2 88.7417 18.5158 12 -5 4 6 40.6007 12.5161 5 -5 4 6 38.4810 15.8916 17 -5 4 5 154.879 16.1059 5 -5 4 5 131.575 20.8791 17 -5 4 4 120.870 14.4150 5 -5 4 2 96.8429 20.8069 21 -5 4 1 109.015 20.8391 21 -5 4 0 538.745 37.9726 21 -5 4 -1 360.820 28.3874 21 -5 4 -2 55.7017 15.2097 21 5 4 2 93.4290 18.3544 12 -5 5 6 26.2261 12.3361 5 -5 5 6-12.9503 15.2021 17 -5 5 5 178.928 17.7885 5 -5 5 5 225.794 22.5246 17 -5 5 4 336.643 23.2557 5 -5 5 2 18.3905 18.6818 21 -5 5 1 18.1917 18.6477 21 -5 5 0 233.643 24.3589 21 -5 5 -1-17.0795 16.6795 21 -5 5 -2 53.4086 15.0146 21 5 5 2 53.9253 17.7076 12 -5 6 6 166.309 16.0327 5 -5 6 6 143.468 18.3484 17 -5 6 5-0.33483 17.1562 17 -5 6 2 179.917 22.8768 21 -5 6 1 60.2617 19.5934 21 -5 6 0 77.1326 18.9235 21 -5 6 -1 44.3613 16.3588 21 -5 6 -2 89.9066 15.4846 21 5 6 2 111.327 18.2301 12 -5 7 6 256.793 19.5719 5 -5 7 6 245.394 21.8195 17 -5 7 5 29.3848 17.6035 17 -5 7 2 381.776 30.4687 21 -5 7 1 6.34099 17.5989 21 -5 7 0 184.928 21.6551 21 -5 7 -1 0.59409 15.8323 21 -5 7 -2 124.077 15.8261 21 5 7 2 105.005 17.9578 12 -5 8 6 85.3558 12.6193 5 -5 8 6 34.1315 14.5915 17 -5 8 5 28.8353 17.0514 17 -5 8 2 130.113 20.1871 21 -5 8 1 177.608 21.5140 21 -5 8 0 90.5618 18.3446 21 -5 8 -1 85.1712 16.7998 21 -5 8 -2-9.83329 13.0918 21 5 8 2 11.0944 15.7658 12 -5 9 6 13.1948 13.1563 17 -5 9 5 291.464 24.7841 17 -5 9 2 5.14591 17.2181 21 -5 9 1 111.170 18.7439 21 -5 9 0 17.1649 16.6493 21 -5 9 -1 109.110 17.2192 21 -5 9 -2 65.4154 13.9716 21 5 9 2 134.025 16.4854 12 -5 10 6-2.50040 12.7495 17 -5 10 5 65.7738 16.8736 17 -5 10 2 95.8147 18.6242 21 -5 10 1 236.993 22.9482 21 -5 10 0 28.4351 16.1116 21 -5 10 -1 145.082 17.7724 21 5 10 2 172.972 18.1761 12 -5 11 6 44.2960 12.5699 17 -5 11 5 37.2478 15.2211 17 -5 11 2 31.6521 16.9014 21 -5 11 1 9.72398 15.6468 21 -5 11 0 294.765 24.3374 21 -5 11 -1 257.499 21.6013 21 5 11 2 283.271 21.6684 12 -5 12 5 61.0630 15.0901 17 -5 12 1 103.807 16.9889 21 -5 12 0 364.882 26.8342 21 -5 12 -1 96.7355 14.6884 21 5 12 2 76.8374 13.4912 12 -5 13 5 41.4951 14.0781 17 -5 13 1 24.6662 14.8647 21 -5 13 0 23.4781 13.9631 21 -5 13 -1 55.6517 13.2273 21 -5 14 5 15.3484 12.8111 17 -5 14 1 117.231 16.4934 21 -5 14 0 106.274 15.2151 21 -5 14 -1 12.4797 11.2463 21 5 14 1 7.46323 13.3158 12 -5 15 5 17.7059 11.6316 17 -5 15 4 11.9530 13.5342 17 -5 15 1 31.5764 13.6688 21 -5 15 0 29.3514 12.4947 21 5 15 1 149.084 15.6391 12 -5 16 4 192.635 17.8360 17 0 0 0 0.00 0.00 0 TITL exp_111 in P2(1) REM P2(1) (#4 in standard setting) CELL 1.54184 5.003895 38.634386 7.603498 90.0000 106.2006 90.0000 ZERR 2.00 0.000247 0.001308 0.000365 0.0000 0.0049 0.0000 LATT -1 SYMM -x, y+1/2,-z SFAC C H O UNIT 48.00 88.00 44.00 TREF HKLF 4 END ; _shelx_hkl_checksum 36202 _shelx_res_file ; TITL exp_111_a.res in P2(1) exp_111.res created by SHELXL-2017/1 at 17:47:51 on 24-Apr-2019 REM Old TITL exp_111 in P2(1) REM SHELXT solution in P2(1) REM R1 0.085, Rweak 0.030, Alpha 0.002, Orientation as input REM Flack x = -0.088 ( 0.221 ) from Parsons' quotients REM Formula found by SHELXT: C24 O22 CELL 1.54184 5.0044 38.6364 7.6007 90 106.2 90 ZERR 4 0.0003 0.0014 0.0004 0 0.005 0 LATT -1 SYMM -X,0.5+Y,-Z SFAC C H O UNIT 48 88 44 DFIX 2.01 H16 H15 L.S. 8 PLAN 1 SIZE 0.07 0.02 0.015 BOND $H list 4 fmap 2 53 acta OMIT 0 -2 0 REM REM REM WGHT 0.070500 FVAR 1.04684 O15 3 1.001888 0.633480 0.440431 11.00000 0.01727 0.01720 = 0.02092 0.00221 0.00821 -0.00018 O5 3 0.284598 0.469402 0.511840 11.00000 0.01609 0.01644 = 0.02356 -0.00042 0.00196 0.00029 O18 3 0.777517 0.586911 0.285831 11.00000 0.01483 0.01831 = 0.01655 -0.00108 0.00253 -0.00054 O19 3 1.144642 0.595772 0.770478 11.00000 0.02217 0.02102 = 0.01655 -0.00264 0.00246 -0.00092 AFIX 147 H36 2 1.070821 0.602565 0.847849 11.00000 -1.50000 AFIX 0 O4 3 0.245517 0.385849 0.285096 11.00000 0.02012 0.01740 = 0.02334 -0.00166 0.00765 -0.00187 O21 3 0.471152 0.534441 0.433584 11.00000 0.01245 0.01731 = 0.02657 0.00167 0.00730 -0.00045 AFIX 147 H40 2 0.418775 0.516359 0.469732 11.00000 -1.50000 AFIX 0 O2 3 0.513012 0.417677 0.931262 11.00000 0.02276 0.02372 = 0.01955 0.00130 0.00427 0.00073 AFIX 147 H4 2 0.620665 0.402031 0.924954 11.00000 -1.50000 AFIX 0 O22 3 0.608213 0.560714 -0.065219 11.00000 0.01960 0.02950 = 0.01975 0.00276 0.00455 0.00234 AFIX 147 H44 2 0.466259 0.570697 -0.123045 11.00000 -1.50000 AFIX 0 O8 3 -0.073900 0.371570 -0.075605 11.00000 0.02904 0.02326 = 0.01775 0.00506 0.00738 0.00521 AFIX 147 H14 2 -0.012004 0.371203 -0.164754 11.00000 -1.50000 AFIX 0 O6 3 -0.158837 0.461871 0.187799 11.00000 0.01724 0.02863 = 0.02591 -0.00572 0.00117 0.00301 AFIX 147 H11 2 -0.258564 0.452202 0.097042 11.00000 -1.50000 AFIX 0 O1 3 0.733300 0.458778 0.703557 11.00000 0.01863 0.02286 = 0.03164 0.00124 0.00586 -0.00111 AFIX 147 H2 2 0.797135 0.478314 0.703099 11.00000 -1.50000 AFIX 0 O17 3 1.557455 0.701550 0.760329 11.00000 0.02604 0.02731 = 0.02254 -0.00358 0.00901 -0.00522 AFIX 147 H33 2 1.429173 0.705620 0.804827 11.00000 -1.50000 AFIX 0 O16 3 1.484049 0.698941 0.368639 11.00000 0.02617 0.02298 = 0.02122 0.00137 0.00485 -0.00777 O20 3 0.913297 0.526361 0.756191 11.00000 0.02152 0.02142 = 0.01945 0.00070 0.00580 0.00016 AFIX 147 H38 2 0.846224 0.539715 0.816208 11.00000 -1.50000 AFIX 0 O13 3 1.106049 0.689910 -0.113755 11.00000 0.02161 0.03191 = 0.02345 0.00259 0.00559 -0.00178 AFIX 147 H26 2 0.944059 0.695554 -0.125458 11.00000 -1.50000 AFIX 0 O12 3 1.534576 0.726575 0.116050 11.00000 0.03491 0.02517 = 0.03125 -0.00321 0.01195 -0.00969 AFIX 147 H24 2 1.586499 0.744594 0.172184 11.00000 -1.50000 AFIX 0 O3 3 0.225917 0.368743 0.672592 11.00000 0.04008 0.01531 = 0.02402 -0.00019 0.01284 -0.00330 AFIX 147 H6 2 0.244093 0.351721 0.612530 11.00000 -1.50000 AFIX 0 O11 3 0.281763 0.286429 0.667825 11.00000 0.04362 0.02605 = 0.02512 0.00416 0.01018 0.00223 AFIX 147 H22 2 0.150035 0.298206 0.677066 11.00000 -1.50000 AFIX 0 O9 3 -0.159854 0.300409 -0.173440 11.00000 0.02904 0.02823 = 0.01996 -0.00438 0.00004 -0.00206 AFIX 147 H16 2 -0.315580 0.306148 -0.235115 11.00000 -1.50000 AFIX 0 O7 3 0.212700 0.329758 0.368359 11.00000 0.03430 0.01599 = 0.02057 0.00121 0.00304 -0.00008 O14 3 0.948832 0.628450 0.036640 11.00000 0.02988 0.02061 = 0.02257 -0.00085 0.00764 -0.00833 AFIX 147 H28 2 0.880367 0.614191 0.091229 11.00000 -1.50000 AFIX 0 O10 3 0.277433 0.275537 0.113760 11.00000 0.04260 0.02292 = 0.03352 -0.00001 0.01044 0.01122 AFIX 147 H18 2 0.314497 0.255156 0.139478 11.00000 -1.50000 AFIX 0 C20 1 0.935807 0.583515 0.613639 11.00000 0.01435 0.02168 = 0.01615 -0.00203 0.00088 -0.00023 AFIX 13 H35 2 0.750213 0.590714 0.618473 11.00000 -1.20000 AFIX 0 C8 1 0.053399 0.345246 0.047970 11.00000 0.02020 0.01784 = 0.02314 0.00104 0.00538 -0.00118 AFIX 13 H13 2 0.239621 0.340667 0.035068 11.00000 -1.20000 AFIX 0 C24 1 0.554958 0.542499 0.085524 11.00000 0.01774 0.01863 = 0.02087 0.00092 0.00204 0.00017 AFIX 23 H42 2 0.546449 0.517815 0.061304 11.00000 -1.20000 H43 2 0.377551 0.549730 0.101453 11.00000 -1.20000 AFIX 0 C1 1 0.451691 0.460956 0.691856 11.00000 0.01302 0.02406 = 0.02395 0.00126 0.00048 -0.00141 AFIX 13 H1 2 0.426733 0.479139 0.775768 11.00000 -1.20000 AFIX 0 C23 1 0.785969 0.550197 0.257915 11.00000 0.01454 0.01881 = 0.01847 -0.00493 0.00453 0.00197 AFIX 13 H41 2 0.965279 0.544004 0.238128 11.00000 -1.20000 AFIX 0 C21 1 0.952759 0.544001 0.600731 11.00000 0.01357 0.02132 = 0.01700 0.00058 0.00422 0.00051 AFIX 13 H37 2 1.140872 0.538424 0.594368 11.00000 -1.20000 AFIX 0 C19 1 0.998379 0.597496 0.441108 11.00000 0.01677 0.01654 = 0.01693 -0.00223 0.00349 0.00240 AFIX 13 H34 2 1.176610 0.588406 0.431537 11.00000 -1.20000 AFIX 0 C6 1 0.125404 0.458001 0.190043 11.00000 0.02254 0.01997 = 0.02695 -0.00004 0.00958 0.00091 AFIX 23 H9 2 0.198228 0.480200 0.165561 11.00000 -1.20000 H10 2 0.138072 0.442088 0.093988 11.00000 -1.20000 AFIX 0 C14 1 1.228803 0.678928 0.067968 11.00000 0.02399 0.01812 = 0.02073 0.00152 0.00656 -0.00040 AFIX 13 H25 2 1.387599 0.664168 0.066897 11.00000 -1.20000 AFIX 0 C17 1 1.311192 0.680819 0.457865 11.00000 0.01889 0.02153 = 0.02034 0.00136 0.00900 -0.00178 AFIX 13 H30 2 1.159935 0.696013 0.468979 11.00000 -1.20000 AFIX 0 C7 1 0.078414 0.356774 0.244078 11.00000 0.02348 0.01622 = 0.01956 0.00063 0.00679 -0.00221 AFIX 13 H12 2 -0.106122 0.361692 0.259024 11.00000 -1.20000 AFIX 0 C5 1 0.300612 0.444339 0.374922 11.00000 0.01669 0.01925 = 0.02858 0.00154 0.00439 0.00150 AFIX 13 H8 2 0.494524 0.442104 0.372289 11.00000 -1.20000 AFIX 0 C3 1 0.353971 0.398008 0.614418 11.00000 0.02550 0.01855 = 0.02186 0.00146 0.00732 0.00252 AFIX 13 H5 2 0.546689 0.392342 0.619038 11.00000 -1.20000 AFIX 0 C13 1 1.341735 0.710033 0.189816 11.00000 0.02678 0.01838 = 0.01984 0.00381 0.00746 -0.00074 AFIX 13 H23 2 1.190363 0.725882 0.193211 11.00000 -1.20000 AFIX 0 C15 1 1.036409 0.657857 0.149804 11.00000 0.02231 0.02014 = 0.01816 -0.00210 0.00590 0.00057 AFIX 13 H27 2 0.872987 0.671902 0.148950 11.00000 -1.20000 AFIX 0 C22 1 0.749681 0.530441 0.424135 11.00000 0.01115 0.01751 = 0.02449 0.00037 0.00842 -0.00001 AFIX 13 H39 2 0.786548 0.505824 0.410362 11.00000 -1.20000 AFIX 0 C2 1 0.351411 0.426732 0.752129 11.00000 0.01585 0.02022 = 0.02017 0.00200 0.00522 0.00269 AFIX 13 H3 2 0.158699 0.429934 0.755627 11.00000 -1.20000 AFIX 0 C4 1 0.196259 0.409290 0.419496 11.00000 0.02236 0.01584 = 0.01824 -0.00265 0.00246 -0.00061 AFIX 13 H7 2 -0.003568 0.410561 0.407681 11.00000 -1.20000 AFIX 0 C18 1 1.491219 0.671735 0.644945 11.00000 0.02541 0.02061 = 0.02488 0.00275 0.00841 -0.00253 AFIX 23 H31 2 1.395514 0.654941 0.700426 11.00000 -1.20000 H32 2 1.661968 0.661189 0.634382 11.00000 -1.20000 AFIX 0 C16 1 1.188318 0.648553 0.347179 11.00000 0.01949 0.01909 = 0.02668 0.00057 0.01136 -0.00056 AFIX 13 H29 2 1.338142 0.632143 0.348393 11.00000 -1.20000 AFIX 0 C9 1 -0.117923 0.311849 0.011089 11.00000 0.02942 0.01974 = 0.02527 -0.00345 0.00698 -0.00083 AFIX 13 H15 2 -0.300892 0.316837 0.028450 11.00000 -1.20000 AFIX 0 C10 1 0.017817 0.283970 0.146934 11.00000 0.03804 0.01653 = 0.02443 -0.00246 0.00660 -0.00160 AFIX 13 H17 2 -0.101628 0.263421 0.128141 11.00000 -1.20000 AFIX 0 C11 1 0.058678 0.298048 0.342765 11.00000 0.04313 0.01783 = 0.02448 0.00232 0.00880 -0.00315 AFIX 13 H19 2 -0.123605 0.302114 0.363263 11.00000 -1.20000 AFIX 0 C12 1 0.224664 0.273209 0.487532 11.00000 0.04935 0.02344 = 0.02074 0.00147 0.00697 0.00268 AFIX 23 H20 2 0.121673 0.251740 0.480278 11.00000 -1.20000 H21 2 0.399212 0.267975 0.461291 11.00000 -1.20000 AFIX 0 HKLF 4 REM exp_111_a.res in P2(1) REM R1 = 0.0475 for 3316 Fo > 4sig(Fo) and 0.0576 for all 3861 data REM 431 parameters refined using 2 restraints END WGHT 0.0709 0.0000 REM Highest difference peak 0.382, deepest hole -0.251, 1-sigma level 0.062 Q1 1 0.8288 0.5944 0.2187 11.00000 0.05 0.31 ; _shelx_res_checksum 19460 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, y+1/2, -z' loop_ _atom_site_type_symbol _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_occupancy O O15 1.0019(7) 0.63348(8) 0.4404(5) 0.0179(7) Uani d 1 O O5 0.2846(7) 0.46940(8) 0.5118(5) 0.0194(7) Uani d 1 O O18 0.7775(7) 0.58691(8) 0.2858(5) 0.0169(7) Uani d 1 O O19 1.1446(7) 0.59577(9) 0.7705(5) 0.0205(8) Uani d 1 H H36 1.070821 0.602565 0.847849 0.031 Uiso calc 1 O O4 0.2455(7) 0.38585(9) 0.2851(5) 0.0200(7) Uani d 1 O O21 0.4712(7) 0.53444(8) 0.4336(5) 0.0184(7) Uani d 1 H H40 0.418775 0.516359 0.469732 0.028 Uiso calc 1 O O2 0.5130(8) 0.41768(9) 0.9313(5) 0.0223(8) Uani d 1 H H4 0.620665 0.402031 0.924954 0.034 Uiso calc 1 O O22 0.6082(7) 0.56071(10) -0.0652(5) 0.0231(8) Uani d 1 H H44 0.466259 0.570697 -0.123045 0.035 Uiso calc 1 O O8 -0.0739(8) 0.37157(9) -0.0756(5) 0.0232(8) Uani d 1 H H14 -0.012004 0.371203 -0.164754 0.035 Uiso calc 1 O O6 -0.1588(7) 0.46187(10) 0.1878(5) 0.0249(8) Uani d 1 H H11 -0.258564 0.452202 0.097042 0.037 Uiso calc 1 O O1 0.7333(7) 0.45878(9) 0.7036(5) 0.0246(8) Uani d 1 H H2 0.797135 0.478314 0.703099 0.037 Uiso calc 1 O O17 1.5575(8) 0.70155(9) 0.7603(5) 0.0248(8) Uani d 1 H H33 1.429173 0.705620 0.804827 0.037 Uiso calc 1 O O16 1.4840(8) 0.69894(9) 0.3686(5) 0.0238(8) Uani d 1 O O20 0.9133(7) 0.52636(9) 0.7562(5) 0.0208(7) Uani d 1 H H38 0.846224 0.539715 0.816208 0.031 Uiso calc 1 O O13 1.1060(8) 0.68991(10) -0.1138(5) 0.0258(8) Uani d 1 H H26 0.944059 0.695554 -0.125458 0.039 Uiso calc 1 O O12 1.5346(9) 0.72657(10) 0.1161(6) 0.0299(9) Uani d 1 H H24 1.586499 0.744594 0.172184 0.045 Uiso calc 1 O O3 0.2259(8) 0.36874(9) 0.6726(5) 0.0257(8) Uani d 1 H H6 0.244093 0.351721 0.612530 0.039 Uiso calc 1 O O11 0.2818(9) 0.28643(10) 0.6678(5) 0.0315(9) Uani d 1 H H22 0.150035 0.298206 0.677066 0.047 Uiso calc 1 O O9 -0.1599(8) 0.30041(10) -0.1734(5) 0.0271(8) Uani d 1 H H16 -0.315580 0.306148 -0.235115 0.041 Uiso calc 1 O O7 0.2127(8) 0.32976(9) 0.3684(5) 0.0246(8) Uani d 1 O O14 0.9488(8) 0.62845(9) 0.0366(5) 0.0243(8) Uani d 1 H H28 0.880367 0.614191 0.091229 0.036 Uiso calc 1 O O10 0.2774(9) 0.27554(10) 0.1138(6) 0.0330(9) Uani d 1 H H18 0.314497 0.255156 0.139478 0.050 Uiso calc 1 C C20 0.9358(10) 0.58351(13) 0.6136(7) 0.0181(10) Uani d 1 H H35 0.750213 0.590714 0.618473 0.022 Uiso calc 1 C C8 0.0534(11) 0.34525(13) 0.0480(8) 0.0205(11) Uani d 1 H H13 0.239621 0.340667 0.035068 0.025 Uiso calc 1 C C24 0.5550(11) 0.54250(13) 0.0855(7) 0.0198(11) Uani d 1 H H42 0.546449 0.517815 0.061304 0.024 Uiso calc 1 H H43 0.377551 0.549730 0.101453 0.024 Uiso calc 1 C C1 0.4517(10) 0.46096(14) 0.6919(7) 0.0213(11) Uani d 1 H H1 0.426733 0.479139 0.775768 0.026 Uiso calc 1 C C23 0.7860(10) 0.55020(12) 0.2579(7) 0.0173(10) Uani d 1 H H41 0.965279 0.544004 0.238128 0.021 Uiso calc 1 C C21 0.9528(10) 0.54400(12) 0.6007(7) 0.0173(10) Uani d 1 H H37 1.140872 0.538424 0.594368 0.021 Uiso calc 1 C C19 0.9984(10) 0.59750(12) 0.4411(7) 0.0170(10) Uani d 1 H H34 1.176610 0.588406 0.431537 0.020 Uiso calc 1 C C6 0.1254(11) 0.45800(13) 0.1900(8) 0.0226(11) Uani d 1 H H9 0.198228 0.480200 0.165561 0.027 Uiso calc 1 H H10 0.138072 0.442088 0.093988 0.027 Uiso calc 1 C C14 1.2288(11) 0.67893(13) 0.0680(7) 0.0209(11) Uani d 1 H H25 1.387599 0.664168 0.066897 0.025 Uiso calc 1 C C17 1.3112(10) 0.68082(13) 0.4579(7) 0.0195(10) Uani d 1 H H30 1.159935 0.696013 0.468979 0.023 Uiso calc 1 C C7 0.0784(11) 0.35677(13) 0.2441(7) 0.0196(10) Uani d 1 H H12 -0.106122 0.361692 0.259024 0.024 Uiso calc 1 C C5 0.3006(11) 0.44434(13) 0.3749(7) 0.0219(11) Uani d 1 H H8 0.494524 0.442104 0.372289 0.026 Uiso calc 1 C C3 0.3540(11) 0.39801(13) 0.6144(7) 0.0218(11) Uani d 1 H H5 0.546689 0.392342 0.619038 0.026 Uiso calc 1 C C13 1.3417(11) 0.71003(13) 0.1898(7) 0.0215(11) Uani d 1 H H23 1.190363 0.725882 0.193211 0.026 Uiso calc 1 C C15 1.0364(11) 0.65786(13) 0.1498(7) 0.0202(10) Uani d 1 H H27 0.872987 0.671902 0.148950 0.024 Uiso calc 1 C C22 0.7497(10) 0.53044(13) 0.4241(7) 0.0170(10) Uani d 1 H H39 0.786548 0.505824 0.410362 0.020 Uiso calc 1 C C2 0.3514(11) 0.42673(13) 0.7521(7) 0.0187(10) Uani d 1 H H3 0.158699 0.429934 0.755627 0.022 Uiso calc 1 C C4 0.1963(11) 0.40929(13) 0.4195(7) 0.0195(11) Uani d 1 H H7 -0.003568 0.410561 0.407681 0.023 Uiso calc 1 C C18 1.4912(11) 0.67173(14) 0.6449(7) 0.0234(11) Uani d 1 H H31 1.395514 0.654941 0.700426 0.028 Uiso calc 1 H H32 1.661968 0.661189 0.634382 0.028 Uiso calc 1 C C16 1.1883(11) 0.64855(13) 0.3472(7) 0.0208(11) Uani d 1 H H29 1.338142 0.632143 0.348393 0.025 Uiso calc 1 C C9 -0.1179(12) 0.31185(14) 0.0111(8) 0.0249(11) Uani d 1 H H15 -0.300892 0.316837 0.028450 0.030 Uiso calc 1 C C10 0.0178(12) 0.28397(13) 0.1469(8) 0.0268(12) Uani d 1 H H17 -0.101628 0.263421 0.128141 0.032 Uiso calc 1 C C11 0.0587(13) 0.29805(13) 0.3428(8) 0.0286(12) Uani d 1 H H19 -0.123605 0.302114 0.363263 0.034 Uiso calc 1 C C12 0.2247(14) 0.27321(15) 0.4875(8) 0.0317(13) Uani d 1 H H20 0.121673 0.251740 0.480278 0.038 Uiso calc 1 H H21 0.399212 0.267975 0.461291 0.038 Uiso calc 1 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 O15 0.0173(17) 0.0172(16) 0.0209(18) -0.0002(13) 0.0082(13) 0.0022(14) O5 0.0161(17) 0.0164(16) 0.024(2) 0.0003(13) 0.0020(14) -0.0004(14) O18 0.0148(17) 0.0183(17) 0.0165(17) -0.0005(13) 0.0025(13) -0.0011(14) O19 0.0222(19) 0.0210(17) 0.0166(18) -0.0009(14) 0.0025(14) -0.0026(14) O4 0.0201(18) 0.0174(16) 0.0233(19) -0.0019(14) 0.0077(14) -0.0017(15) O21 0.0125(17) 0.0173(17) 0.027(2) -0.0005(13) 0.0073(14) 0.0017(15) O2 0.023(2) 0.0237(19) 0.0196(19) 0.0007(14) 0.0043(15) 0.0013(15) O22 0.0196(17) 0.029(2) 0.0198(19) 0.0023(15) 0.0045(14) 0.0028(15) O8 0.029(2) 0.0233(18) 0.0177(19) 0.0052(15) 0.0074(15) 0.0051(16) O6 0.0172(18) 0.029(2) 0.026(2) 0.0030(15) 0.0012(14) -0.0057(16) O1 0.0186(18) 0.0229(18) 0.032(2) -0.0011(14) 0.0059(15) 0.0012(17) O17 0.026(2) 0.0273(19) 0.023(2) -0.0052(15) 0.0090(15) -0.0036(16) O16 0.0262(19) 0.0230(19) 0.0212(19) -0.0078(15) 0.0049(15) 0.0014(15) O20 0.0215(19) 0.0214(17) 0.0195(19) 0.0002(14) 0.0058(14) 0.0007(15) O13 0.0216(19) 0.032(2) 0.0235(19) -0.0018(16) 0.0056(15) 0.0026(16) O12 0.035(2) 0.025(2) 0.031(2) -0.0097(17) 0.0120(18) -0.0032(17) O3 0.040(2) 0.0153(16) 0.024(2) -0.0033(16) 0.0128(17) -0.0002(15) O11 0.044(3) 0.026(2) 0.025(2) 0.0022(17) 0.0102(18) 0.0042(17) O9 0.029(2) 0.028(2) 0.0200(19) -0.0021(16) 0.0000(15) -0.0044(16) O7 0.034(2) 0.0160(17) 0.021(2) -0.0001(15) 0.0030(15) 0.0012(15) O14 0.030(2) 0.0206(18) 0.023(2) -0.0083(15) 0.0076(15) -0.0009(15) O10 0.043(2) 0.0229(18) 0.034(2) 0.0112(17) 0.0104(18) 0.0000(17) C20 0.014(2) 0.022(2) 0.016(2) -0.0002(19) 0.0009(18) -0.002(2) C8 0.020(3) 0.018(2) 0.023(3) -0.0012(19) 0.005(2) 0.001(2) C24 0.018(3) 0.019(2) 0.021(3) 0.0002(18) 0.002(2) 0.001(2) C1 0.013(2) 0.024(3) 0.024(3) -0.001(2) 0.000(2) 0.001(2) C23 0.015(2) 0.019(2) 0.018(2) 0.0020(19) 0.0045(18) -0.005(2) C21 0.014(2) 0.021(3) 0.017(2) 0.0005(18) 0.0042(18) 0.001(2) C19 0.017(3) 0.017(2) 0.017(2) 0.0024(18) 0.0035(19) -0.0022(19) C6 0.023(3) 0.020(2) 0.027(3) 0.001(2) 0.010(2) 0.000(2) C14 0.024(3) 0.018(2) 0.021(3) 0.000(2) 0.007(2) 0.002(2) C17 0.019(3) 0.022(3) 0.020(3) -0.0018(19) 0.0090(19) 0.001(2) C7 0.023(3) 0.016(2) 0.020(3) -0.002(2) 0.007(2) 0.001(2) C5 0.017(3) 0.019(2) 0.029(3) 0.001(2) 0.004(2) 0.002(2) C3 0.026(3) 0.019(2) 0.022(3) 0.003(2) 0.007(2) 0.001(2) C13 0.027(3) 0.018(2) 0.020(3) -0.001(2) 0.007(2) 0.004(2) C15 0.022(3) 0.020(2) 0.018(3) 0.001(2) 0.006(2) -0.002(2) C22 0.011(2) 0.018(2) 0.024(3) 0.0000(18) 0.0084(19) 0.000(2) C2 0.016(3) 0.020(2) 0.020(3) 0.0027(19) 0.0052(19) 0.002(2) C4 0.022(3) 0.016(2) 0.018(3) -0.0006(19) 0.0025(19) -0.003(2) C18 0.025(3) 0.021(2) 0.025(3) -0.003(2) 0.008(2) 0.003(2) C16 0.019(3) 0.019(2) 0.027(3) -0.001(2) 0.011(2) 0.001(2) C9 0.029(3) 0.020(2) 0.025(3) -0.001(2) 0.007(2) -0.003(2) C10 0.038(3) 0.017(3) 0.024(3) -0.002(2) 0.007(2) -0.002(2) C11 0.043(3) 0.018(3) 0.024(3) -0.003(2) 0.009(2) 0.002(2) C12 0.049(4) 0.023(3) 0.021(3) 0.003(3) 0.007(2) 0.001(2) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle C19 O15 C16 114.6(4) C1 O5 C5 113.8(4) C19 O18 C23 110.8(3) C20 O19 H36 109.5 C7 O4 C4 117.3(4) C22 O21 H40 109.5 C2 O2 H4 109.5 C24 O22 H44 109.5 C8 O8 H14 109.5 C6 O6 H11 109.5 C1 O1 H2 109.5 C18 O17 H33 109.5 C13 O16 C17 113.4(4) C21 O20 H38 109.5 C14 O13 H26 109.5 C13 O12 H24 109.5 C3 O3 H6 109.5 C12 O11 H22 109.5 C9 O9 H16 109.5 C11 O7 C7 113.3(4) C15 O14 H28 109.5 C10 O10 H18 109.5 O19 C20 H35 110.8 O19 C20 C21 110.0(4) O19 C20 C19 108.7(4) C21 C20 H35 110.8 C19 C20 H35 110.8 C19 C20 C21 105.6(4) O8 C8 H13 109.2 O8 C8 C7 109.8(4) O8 C8 C9 111.1(4) C7 C8 H13 109.2 C7 C8 C9 108.3(4) C9 C8 H13 109.2 O22 C24 H42 109.8 O22 C24 H43 109.8 O22 C24 C23 109.2(4) H42 C24 H43 108.3 C23 C24 H42 109.8 C23 C24 H43 109.8 O5 C1 H1 108.2 O5 C1 C2 109.3(4) O1 C1 O5 112.8(4) O1 C1 H1 108.2 O1 C1 C2 109.9(4) C2 C1 H1 108.2 O18 C23 C24 105.9(4) O18 C23 H41 109.3 O18 C23 C22 110.8(4) C24 C23 H41 109.3 C24 C23 C22 112.2(4) C22 C23 H41 109.3 O20 C21 C20 113.6(4) O20 C21 H37 107.0 O20 C21 C22 110.6(4) C20 C21 H37 107.0 C22 C21 C20 111.2(4) C22 C21 H37 107.0 O15 C19 O18 106.9(4) O15 C19 C20 111.2(4) O15 C19 H34 110.2 O18 C19 C20 108.1(4) O18 C19 H34 110.2 C20 C19 H34 110.2 O6 C6 H9 109.4 O6 C6 H10 109.4 O6 C6 C5 111.2(4) H9 C6 H10 108.0 C5 C6 H9 109.4 C5 C6 H10 109.4 O13 C14 H25 107.4 O13 C14 C13 110.1(4) O13 C14 C15 114.1(4) C13 C14 H25 107.4 C15 C14 H25 107.4 C15 C14 C13 110.1(4) O16 C17 H30 109.5 O16 C17 C18 106.4(4) O16 C17 C16 110.0(4) C18 C17 H30 109.5 C18 C17 C16 111.9(4) C16 C17 H30 109.5 O4 C7 O7 107.4(4) O4 C7 C8 109.7(4) O4 C7 H12 110.3 O7 C7 C8 108.9(4) O7 C7 H12 110.3 C8 C7 H12 110.3 O5 C5 C6 107.4(4) O5 C5 H8 109.2 O5 C5 C4 110.2(4) C6 C5 H8 109.2 C4 C5 C6 111.6(4) C4 C5 H8 109.2 O3 C3 H5 109.5 O3 C3 C2 105.8(4) O3 C3 C4 111.7(4) C2 C3 H5 109.5 C2 C3 C4 110.8(4) C4 C3 H5 109.5 O16 C13 C14 110.3(4) O16 C13 H23 110.5 O12 C13 O16 107.8(4) O12 C13 C14 107.3(4) O12 C13 H23 110.5 C14 C13 H23 110.5 O14 C15 C14 107.7(4) O14 C15 H27 108.9 O14 C15 C16 113.1(4) C14 C15 H27 108.9 C14 C15 C16 109.3(4) C16 C15 H27 108.9 O21 C22 C23 109.3(4) O21 C22 C21 109.8(4) O21 C22 H39 109.1 C23 C22 C21 110.5(4) C23 C22 H39 109.1 C21 C22 H39 109.1 O2 C2 C1 110.7(4) O2 C2 C3 111.5(4) O2 C2 H3 107.9 C1 C2 H3 107.9 C3 C2 C1 110.9(4) C3 C2 H3 107.9 O4 C4 C5 105.4(4) O4 C4 C3 111.3(4) O4 C4 H7 109.8 C5 C4 C3 110.6(4) C5 C4 H7 109.8 C3 C4 H7 109.8 O17 C18 C17 111.6(4) O17 C18 H31 109.3 O17 C18 H32 109.3 C17 C18 H31 109.3 C17 C18 H32 109.3 H31 C18 H32 108.0 O15 C16 C17 105.9(4) O15 C16 C15 111.4(4) O15 C16 H29 109.4 C17 C16 H29 109.4 C15 C16 C17 111.2(4) C15 C16 H29 109.4 O9 C9 C8 111.2(4) O9 C9 H15 107.8 O9 C9 C10 111.3(4) C8 C9 H15 107.8 C10 C9 C8 110.6(4) C10 C9 H15 107.8 O10 C10 C9 107.4(4) O10 C10 H17 109.7 O10 C10 C11 111.6(5) C9 C10 H17 109.7 C9 C10 C11 108.7(4) C11 C10 H17 109.7 O7 C11 C10 110.7(4) O7 C11 H19 109.3 O7 C11 C12 106.1(5) C10 C11 H19 109.3 C12 C11 C10 112.0(4) C12 C11 H19 109.3 O11 C12 C11 113.3(5) O11 C12 H20 108.9 O11 C12 H21 108.9 C11 C12 H20 108.9 C11 C12 H21 108.9 H20 C12 H21 107.7 loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance O15 C19 1.390(6) O15 C16 1.443(6) O5 C1 1.428(6) O5 C5 1.440(6) O18 C23 1.437(6) O18 C19 1.433(6) O19 H36 0.8200 O19 C20 1.429(6) O4 C7 1.383(6) O4 C4 1.437(6) O21 H40 0.8200 O21 C22 1.424(6) O2 H4 0.8200 O2 C2 1.420(7) O22 H44 0.8200 O22 C24 1.432(6) O8 H14 0.8200 O8 C8 1.410(6) O6 H11 0.8200 O6 C6 1.426(6) O1 H2 0.8200 O1 C1 1.390(6) O17 H33 0.8200 O17 C18 1.430(7) O16 C17 1.423(6) O16 C13 1.414(7) O20 H38 0.8200 O20 C21 1.425(6) O13 H26 0.8200 O13 C14 1.411(7) O12 H24 0.8200 O12 C13 1.399(7) O3 H6 0.8200 O3 C3 1.429(7) O11 H22 0.8200 O11 C12 1.415(7) O9 H16 0.8200 O9 C9 1.429(7) O7 C7 1.442(6) O7 C11 1.432(7) O14 H28 0.8200 O14 C15 1.419(6) O10 H18 0.8200 O10 C10 1.428(7) C20 H35 0.9800 C20 C21 1.534(7) C20 C19 1.529(7) C8 H13 0.9800 C8 C7 1.527(8) C8 C9 1.531(7) C24 H42 0.9700 C24 H43 0.9700 C24 C23 1.515(7) C1 H1 0.9800 C1 C2 1.529(7) C23 H41 0.9800 C23 C22 1.530(7) C21 H37 0.9800 C21 C22 1.532(7) C19 H34 0.9800 C6 H9 0.9700 C6 H10 0.9700 C6 C5 1.528(8) C14 H25 0.9800 C14 C13 1.526(7) C14 C15 1.520(7) C17 H30 0.9800 C17 C18 1.497(7) C17 C16 1.533(7) C7 H12 0.9800 C5 H8 0.9800 C5 C4 1.523(7) C3 H5 0.9800 C3 C2 1.528(7) C3 C4 1.535(7) C13 H23 0.9800 C15 H27 0.9800 C15 C16 1.524(8) C22 H39 0.9800 C2 H3 0.9800 C4 H7 0.9800 C18 H31 0.9700 C18 H32 0.9700 C16 H29 0.9800 C9 H15 0.9800 C9 C10 1.515(8) C10 H17 0.9800 C10 C11 1.544(8) C11 H19 0.9800 C11 C12 1.520(8) C12 H20 0.9700 C12 H21 0.9700 _cod_database_fobs_code 2021671