#------------------------------------------------------------------------------
#$Date: 2017-01-18 11:18:46 +0200 (Wed, 18 Jan 2017) $
#$Revision: 190627 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/10/09/2100910.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2100910
loop_
_publ_author_name
'Larsen, S.'
'de Diego, H. L.'
'Kozma, D.'
_publ_section_title
;
 Optical resolution through diastereomeric salt formation: the crystal
 structures of cinchoninium (R)-mandelate and cinchoninium
 (S)-mandelate at low temperature
;
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              310
_journal_page_last               316
_journal_paper_doi               10.1107/S0108768192008371
_journal_volume                  49
_journal_year                    1993
_chemical_formula_moiety         'C19 H23 N2 O1,C8 H7 O3'
_chemical_formula_sum            'C27 H30 N2 O4'
_chemical_formula_weight         446.55
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   12.078(4)
_cell_length_b                   17.423(2)
_cell_length_c                   22.136(4)
_cell_volume                     4658.2(18)
_diffrn_radiation_type           Cu
_diffrn_radiation_wavelength     1.5418
_exptl_absorpt_coefficient_mu    0.652
_exptl_crystal_density_diffrn    1.273
_exptl_crystal_F_000             1904
_cod_data_source_file            ab0286.cif
_cod_data_source_block           ab0286b
_cod_depositor_comments
;
 Adding the _atom_site_type_symbol data item.

 Antanas Vaitkus,
 2017-01-18
;
_cod_original_cell_volume        4658(3)
_cod_database_code               2100910
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
O(1A) O .6076(2) .2266(2) .98050(10) .0352(7)
O(2A) O .7329(2) .2098(2) .90720(10) .0299(6)
C(1A) C .6999(3) .2386(2) .9559(2) .0270(8)
C(2A) C .7786(3) .2929(2) .9901(2) .0290(8)
O(3A) O .7368(3) .3057(2) 1.04960(10) .0370(7)
C(3A) C .7917(3) .3693(2) .9587(2) .0295(8)
C(4A) C .8953(3) .3934(3) .9387(2) .0320(9)
C(5A) C .9082(4) .4657(3) .9136(2) .0420(10)
C(6A) C .8180(4) .5141(3) .9067(2) .0490(10)
C(7A) C .7133(4) .4895(3) .9261(3) .0480(10)
C(8A) C .7010(4) .4185(3) .9528(2) .0390(10)
O(1B) O .9794(3) .9984(2) .9628(2) .0474(8)
O(2B) O .8149(2) 1.0049(2) .91640(10) .0414(7)
C(1B) C .8814(4) .9780(3) .9553(2) .0400(10)
C(2B) C .8383(5) .9144(3) .9984(2) .0540(10)
O(3B) O .9260(4) .8909(2) 1.0360(2) .0770(10)
C(3B) C .7901(5) .8468(3) .9647(2) .0520(10)
C(4B) C .6783(5) .8328(4) .9604(3) .0670(10)
C(5B) C .6358(5) .7674(4) .9310(3) .0630(10)
C(6B) C .7103(5) .7161(3) .9055(3) .0650(10)
C(7B) C .8213(5) .7291(3) .9076(3) .0580(10)
C(8B) C .8606(5) .7944(3) .9366(2) .0530(10)
C(9A) C .4177(3) .2732(2) .8030(2) .0252(8)
C(10A) C .3640(3) .3207(2) .8471(2) .0233(8)
C(11A) C .4002(3) .3296(2) .9066(2) .0277(8)
C(12A) C .3421(4) .3743(2) .9467(2) .0319(9)
C(13A) C .2436(4) .4108(2) .9284(2) .0357(9)
C(14A) C .2084(4) .4055(2) .8704(2) .0341(9)
C(15A) C .2678(3) .3615(2) .8283(2) .0267(8)
N(1A) N .2300(3) .3602(2) .7696(2) .0312(8)
C(16A) C .2850(4) .3190(3) .7301(2) .0366(9)
C(17A) C .3780(4) .2739(2) .7453(2) .0325(9)
C(18A) C .5167(3) .2241(2) .8195(2) .0248(8)
O(4A) O .5737(2) .1990(2) .76730(10) .0296(6)
C(19A) C .4783(3) .1541(2) .8557(2) .0228(8)
C(20A) C .3931(3) .1022(2) .8254(2) .0299(8)
C(21A) C .4131(3) .0192(2) .8453(2) .0360(10)
C(22A) C .4290(4) .0179(2) .9136(2) .0357(9)
C(23A) C .5403(4) .0576(2) .9285(2) .0304(9)
N(2A) N .5748(3) .1040(2) .87480(10) .0233(7)
C(24A) C .6103(3) .0498(2) .8254(2) .0284(8)
C(25A) C .5186(3) -.0099(2) .8142(2) .0336(9)
C(26A) C .5020(4) -.0291(3) .7490(2) .0470(10)
C(27A) C .5373(5) .0052(3) .7011(2) .0600(10)
C(9B) C .1010(3) -.0908(2) .7879(2) .0260(8)
C(10B) C .1696(3) -.1212(2) .8345(2) .0251(8)
C(11B) C .1544(3) -.1081(2) .8966(2) .0319(9)
C(12B) C .2225(4) -.1411(3) .9388(2) .0380(10)
C(13B) C .3091(4) -.1902(3) .9210(2) .0420(10)
C(14B) C .3282(4) -.2037(3) .8609(2) .0360(10)
C(15B) C .2600(3) -.1694(2) .8164(2) .0272(8)
N(1B) N .2814(3) -.1861(2) .7574(2) .0332(8)
C(16B) C .2170(4) -.1551(3) .7162(2) .0390(10)
C(17B) C .1254(4) -.1083(2) .7295(2) .0336(9)
C(18B) C .0010(3) -.0405(2) .8022(2) .0279(8)
O(4B) O -.0705(2) -.0329(2) .75170(10) .0333(7)
C(19B) C .0407(3) .0411(2) .8183(2) .0247(8)
C(20B) C .0955(3) .0839(2) .7658(2) .0300(9)
C(21B) C .0621(3) .1681(2) .7673(2) .0342(9)
C(22B) C .0766(3) .1995(2) .8315(2) .0380(10)
C(23B) C -.0029(4) .1572(2) .8742(2) .0331(9)
N(2B) N -.0530(3) .0907(2) .8416(2) .0258(7)
C(24B) C -.1269(3) .1220(2) .7922(2) .0298(9)
C(25B) C -.0612(4) .1752(3) .7500(2) .0450(10)
C(26B) C -.0835(5) .1620(6) .6849(3) .106(2)
C(27B) C -.1346(9) .1329(6) .6533(4) .189(2)
H2A H .850 .268 .992 ?
HO3A H .666 .283 1.041 ?
H4A H .960 .360 .943 ?
H5A H .980 .483 .900 ?
H6A H .828 .564 .888 ?
H7A H .648 .523 .920 ?
H8A H .630 .403 .969 ?
H2B H .778 .936 1.023 ?
HO3B H 1.000 .934 1.043 ?
H4B H .626 .869 .980 ?
H5B H .554 .758 .928 ?
H6B H .682 .668 .884 ?
H7B H .874 .693 .889 ?
H8B H .940 .804 .937 ?
H11A H .467 .304 .920 ?
H12A H .371 .382 .987 ?
H13A H .199 .438 .958 ?
H14A H .143 .434 .857 ?
H16A H .261 .320 .688 ?
H17A H .414 .241 .715 ?
H18A H .567 .255 .844 ?
HO4A H .641 .234 .750 ?
H19A H .443 .177 .890 ?
H20A H .319 .118 .835 ?
H2OA' H .401 .106 .782 ?
H21A H .351 -.013 .834 ?
H22A H .370 .045 .934 ?
H22A' H .430 -.033 .929 ?
H23A H .532 .091 .963 ?
H23A' H .596 .020 .938 ?
HN2A H .636 .136 .883 ?
H24A H .623 .078 .789 ?
H24A' H .677 .025 .837 ?
H25A H .541 -.059 .832 ?
H26A H .458 -.074 .740 ?
H27A H .611 .049 .709 ?
H27A' H .529 .000 .654 ?
H11B H .095 -.075 .909 ?
H12B H .210 -.132 .981 ?
H13B H .357 -.214 .951 ?
H14B H .389 -.236 .849 ?
H16B H .233 -.166 .674 ?
H17B H .081 -.088 .697 ?
H18B H -.039 .063 .836 ?
HO4B H -.141 -.082 .750 ?
H19B H .094 .034 .850 ?
H20B H .174 .079 .768 ?
H20B' H .071 .061 .728 ?
H21B H .107 .197 .739 ?
H22B H .152 .192 .844 ?
H22B' H .061 .253 .833 ?
H23B H .038 .138 .909 ?
H23B' H -.059 .190 .889 ?
HN2B H -.099 .059 .867 ?
H24B H -.155 .080 .768 ?
H24B' H -.187 .149 .809 ?
H25B H -.086 .228 .757 ?
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C(10A) C(9A) C(17A) 118.4(4)
C(10A) C(9A) C(18A) 121.1(3)
C(17A) C(9A) C(18A) 120.5(4)
C(9A) C(10A) C(11A) 124.5(3)
C(9A) C(10A) C(15A) 117.2(3)
C(11A) C(10A) C(15A) 118.4(3)
C(10A) C(11A) C(12A) 120.9(4)
C(11A) C(12A) C(13A) 120.1(4)
C(12A) C(13A) C(14A) 120.4(4)
C(13A) C(14A) C(15A) 120.4(4)
C(10A) C(15A) C(14A) 119.7(4)
C(10A) C(15A) N(1A) 122.5(4)
C(14A) C(15A) N(1A) 117.9(4)
C(15A) N(1A) C(16A) 118.1(4)
N(1A) C(16A) O(17A) 123.2(4)
C(9A) C(17A) C(16A) 120.5(4)
C(9A) C(18A) O(4A) 111.1(3)
C(9A) C(18A) C(19A) 109.7(3)
O(1A) C(1A) O(2A) 125.9(4)
O(1A) C(1A) C(2A) 115.8(3)
O(2A) C(1A) C(2A) 118.2(3)
C(1A) C(2A) O(3A) 109.4(3)
C(1A) C(2A) C(3A) 112.3(3)
O(3A) C(2A) C(3A) 108.9(3)
C(2A) C(3A) C(4A) 120.5(4)
C(2A) C(3A) C(8A) 120.2(4)
C(4A) C(3A) C(8A) 119.2(4)
C(3A) C(4A) C(5A) 120.3(4)
O(4A) C(18A) C(19A) 109.2(3)
C(18A) C(19A) C(20A) 116.5(3)
C(18A) C(19A) N(2A) 111.8(3)
C(20A) C(19A) N(2A) 107.5(3)
C(19A) C(20A) C(21A) 109.1(3)
C(20A) C(21A) C(22A) 108.6(3)
C(20A) C(21A) C(25A) 108.3(3)
C(22A) C(21A) C(25A) 109.7(3)
C(21A) C(22A) C(23A) 108.4(3)
C(22A) C(23A) N(2A) 108.2(3)
C(19A) N(2A) C(23A) 108.6(3)
C(19A) N(2A) C(24A) 112.1(3)
C(23A) N(2A) C(24A) 108.6(3)
N(2A) C(24A) C(25A) 109.7(3)
C(21A) C(25A) C(24A) 107.5(3)
C(21A) C(25A) C(26A) 113.4(4)
C(24A) C(25A) C(26A) 113.8(4)
C(25A) C(26A) C(27A) 130.2(5)
C(10B) C(9B) C(17B) 118.6(4)
C(10B) C(9B) C(18B) 121.5(3)
C(17B) C(9B) C(18B) 119.8(4)
C(9B) C(10B) C(11B) 124.9(4)
C(9B) C(10B) C(15B) 117.2(3)
C(11B) C(10B) C(15B) 117.9(4)
C(10B) C(11B) C(12B) 121.3(4)
C(11B) C(12B) C(13B) 120.7(4)
C(12B) C(13B) C(14B) 120.0(4)
C(13B) C(14B) C(15B) 120.5(4)
C(10B) C(15B) C(14B) 119.6(4)
C(10B) C(15B) N(1B) 122.4(4)
C(14B) C(15B) N(1B) 117.9(4)
C(15B) N(1B) C(16B) 117.8(4)
N(1B) C(16B) O(17B) 123.9(4)
C(9B) C(17B) C(16B) 119.9(4)
C(9B) C(18B) O(4B) 110.9(3)
C(9B) C(18B) C(19B) 109.4(3)
O(1B) C(1B) O(2B) 125.9(4)
O(1B) C(1B) C(2B) 116.1(4)
O(2B) C(1B) C(2B) 118.1(4)
C(1B) C(2B) O(3B) 108.6(4)
C(1B) C(2B) C(3B) 112.4(4)
O(3B) C(2B) C(3B) 110.8(4)
C(2B) C(3B) C(4B) 123.4(5)
C(2B) C(3B) C(8B) 119.7(5)
C(4B) C(3B) C(8B) 116.9(5)
C(3B) C(4B) C(5B) 122.2(6)
O(4B) C(18B) C(19B) 107.9(3)
C(18B) C(19B) C(20B) 114.1(3)
C(18B) C(19B) N(2B) 111.9(3)
C(20B) C(19B) N(2B) 107.7(3)
C(19B) C(20B) C(21B) 109.7(3)
C(20B) C(21B) C(22B) 109.5(4)
C(20B) C(21B) C(25B) 109.2(3)
C(22B) C(21B) C(25B) 108.2(4)
C(21B) C(22B) C(23B) 109.1(3)
C(22B) C(23B) N(2B) 109.2(4)
C(19B) N(2B) C(23B) 107.8(3)
C(19B) N(2B) C(24B) 113.5(3)
C(23B) N(2B) C(24B) 108.1(3)
N(2B) C(24B) C(25B) 110.6(3)
C(21B) C(25B) C(24B) 107.4(4)
C(21B) C(25B) C(26B) 113.8(4)
C(24B) C(25B) C(26B) 113.8(5)
C(25B) C(26B) C(27B) 145.0(9)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C(9A) C(10A) 1.435(5)
C(9A) C(17A) 1.365(6)
C(9A) C(18A) 1.515(5)
C(10A) C(11A) 1.398(6)
C(10A) C(15A) 1.424(5)
C(11A) C(12A) 1.374(6)
C(12A) C(13A) 1.407(6)
C(13A) C(14A) 1.356(7)
C(14A) C(15A) 1.404(6)
C(15A) N(1A) 1.380(5)
N(1A) C(16A) 1.312(6)
C(16A) C(17A) 1.412(6)
C(18A) O(4A) 1.415(5)
C(18A) C(19A) 1.532(5)
C(19A) C(20A) 1.525(5)
C(19A) N(2A) 1.516(5)
C(20A) C(21A) 1.532(6)
C(21A) C(22A) 1.526(7)
C(21A) C(25A) 1.534(6)
C(22A) C(23A) 1.547(6)
C(23A) N(2A) 1.498(5)
N(2A) C(24A) 1.509(5)
C(24A) C(25A) 1.539(5)
C(25A) C(26A) 1.496(7)
C(26A) C(27A) 1.292(8)
O(1A) C(1A) 1.258(5)
O(2A) C(1A) 1.254(5)
C(1A) C(2A) 1.540(6)
C(2A) O(3A) 1.430(5)
C(2A) C(3A) 1.510(6)
C(3A) C(4A) 1.392(6)
C(3A) C(8A) 1.396(6)
C(4A) C(5A) 1.384(6)
C(5A) C(6A) 1.386(7)
C(6A) C(7A) 1.402(7)
C(7A) C(8A) 1.380(6)
C(9B) C(10B) 1.425(5)
C(9B) C(17B) 1.363(6)
C(9B) C(18B) 1.525(5)
C(10B) C(11B) 1.408(6)
C(10B) C(15B) 1.434(5)
C(11B) C(12B) 1.371(6)
C(12B) C(13B) 1.406(7)
C(13B) C(14B) 1.373(7)
C(14B) C(15B) 1.415(6)
C(15B) N(1B) 1.364(5)
N(1B) C(16B) 1.316(6)
C(16B) C(17B) 1.405(7)
C(18B) O(4B) 1.417(5)
C(18B) C(19B) 1.542(5)
C(19B) C(20B) 1.532(6)
C(19B) N(2B) 1.514(5)
C(20B) C(21B) 1.522(6)
C(21B) C(22B) 1.533(7)
C(21B) C(25B) 1.541(6)
C(22B) C(23B) 1.536(6)
C(23B) N(2B) 1.492(5)
N(2B) C(24B) 1.514(5)
C(24B) C(25B) 1.537(6)
C(25B) C(26B) 1.487(8)
C(26B) C(27B) 1.062(12)
O(1B) C(1B) 1.246(6)
O(2B) C(1B) 1.268(6)
C(1B) C(2B) 1.552(7)
C(2B) O(3B) 1.408(7)
C(2B) C(3B) 1.512(7)
C(3B) C(4B) 1.374(8)
C(3B) C(8B) 1.393(8)
C(4B) C(5B) 1.409(9)
C(5B) C(6B) 1.387(9)
C(6B) C(7B) 1.360(9)
C(7B) C(8B) 1.390(8)
