#------------------------------------------------------------------------------ #$Date: 2011-09-16 18:46:08 +0300 (Fri, 16 Sep 2011) $ #$Revision: 26025 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2102172.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2102172_Fobs loop_ _publ_author_name 'Chisholm, Greig' 'Kennedy, Alan R.' 'Wilson, Sharon' 'Teat, Simon J.' _publ_section_title ; Comparison of the structural motifs of acetoacetanilides and related azo pigments ; _journal_coeditor_code BM0031 _journal_issue 6 _journal_name_full 'Acta Crystallographica Section B' _journal_page_first 1046 _journal_page_last 1053 _journal_volume 56 _journal_year 2000 _space_group_IT_number 11 _symmetry_space_group_name_Hall '-P 2yb' _symmetry_space_group_name_H-M 'P 1 21/m 1' _cell_angle_alpha 90.000 _cell_angle_beta 97.804 _cell_angle_gamma 90.000 _cell_length_a 8.8636 _cell_length_b 6.6053 _cell_length_c 9.2381 _exptl_crystal_F_000 220.00 _reflns_d_resolution_high 0.7826 _[local]_cod_data_source_file bm003110sup3.hkl _[local]_cod_data_source_block 10 #BEGIN Tags that were not found in dictionaries: _shelx_title ' Ciba AAMX' _shelx_refln_list_code 4 _shelx_f_calc_maximum 142.33 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z' '-x, -y, -z' 'x, -y-1/2, z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 49.08 49.83 1.47 o 3 0 0 167.53 171.45 3.99 o 4 0 0 56.69 73.73 2.09 o 5 0 0 93.69 90.19 2.52 o 6 0 0 110.59 129.57 3.47 o 7 0 0 87.28 72.38 3.39 o 8 0 0 21.90 23.26 1.16 o 9 0 0 16.89 16.00 0.78 o 10 0 0 61.21 58.57 2.61 o 11 0 0 4.93 3.26 2.54 o 1 1 0 241.36 232.27 5.14 o 2 1 0 1423.41 1372.51 29.36 o 3 1 0 1215.68 1249.94 26.85 o 4 1 0 886.16 941.03 20.39 o 5 1 0 51.15 57.65 1.88 o 6 1 0 9.41 11.35 0.99 o 7 1 0 83.56 76.31 2.51 o 8 1 0 83.92 69.64 2.58 o 9 1 0 167.75 159.62 4.55 o 10 1 0 0.00 -0.26 1.37 o 11 1 0 6.94 7.21 0.65 o 0 2 0 20257.96 20228.19 432.21 o 1 2 0 869.22 839.26 18.09 o 2 2 0 3.25 5.43 0.36 o 3 2 0 90.75 92.35 2.45 o 4 2 0 73.90 95.13 6.40 o 5 2 0 76.10 76.29 2.51 o 6 2 0 74.59 81.98 2.56 o 7 2 0 73.42 66.48 2.37 o 8 2 0 15.82 18.05 0.87 o 9 2 0 15.77 13.81 0.68 o 10 2 0 54.11 57.43 2.52 o 1 3 0 113.79 115.49 2.94 o 2 3 0 371.25 394.61 8.89 o 3 3 0 384.31 382.19 15.22 o 4 3 0 342.67 363.00 15.10 o 5 3 0 29.59 32.27 1.52 o 6 3 0 7.40 7.86 0.60 o 7 3 0 42.00 42.64 2.41 o 8 3 0 58.47 55.59 2.35 o 9 3 0 115.65 112.25 3.68 o 10 3 0 0.28 0.95 0.71 o 0 4 0 4346.70 4399.64 93.89 o 1 4 0 274.48 267.68 6.28 o 2 4 0 0.18 -0.86 0.86 o 3 4 0 35.80 39.14 1.58 o 4 4 0 59.48 75.77 4.37 o 5 4 0 26.89 29.06 1.20 o 6 4 0 32.27 31.39 1.30 o 7 4 0 44.16 42.50 2.12 o 8 4 0 6.71 6.97 0.61 o 9 4 0 11.26 12.28 1.33 o 1 5 0 41.76 43.12 1.89 o 2 5 0 121.24 127.69 4.59 o 3 5 0 108.99 106.08 5.58 o 4 5 0 111.84 111.19 3.32 o 5 5 0 6.67 8.26 0.54 o 6 5 0 2.51 3.20 0.51 o 7 5 0 20.66 20.00 2.31 o 8 5 0 28.44 28.48 1.35 o 9 5 0 54.52 56.46 2.68 o 0 6 0 1374.57 1365.99 33.01 o 1 6 0 68.50 68.67 3.54 o 2 6 0 4.16 4.48 0.49 o 3 6 0 16.50 16.05 0.79 o 4 6 0 35.30 41.95 2.00 o 5 6 0 3.48 5.64 0.84 o 6 6 0 11.27 9.43 0.65 o 7 6 0 18.22 17.05 0.84 o 1 7 0 19.70 18.17 0.87 o 2 7 0 50.67 49.02 2.71 o 3 7 0 35.10 35.86 1.49 o 4 7 0 36.60 36.40 2.31 o 5 7 0 0.73 0.07 1.34 o 6 7 0 1.02 2.51 0.57 o 0 8 0 508.23 488.26 11.81 o 1 8 0 22.20 22.04 1.05 o 2 8 0 3.81 2.95 1.13 o 3 8 0 7.20 8.80 0.66 o -11 0 1 43.39 56.08 2.62 o -10 0 1 47.96 47.29 2.28 o -9 0 1 17.89 19.02 0.95 o -8 0 1 108.09 100.07 3.15 o -7 0 1 169.52 171.19 6.63 o -6 0 1 66.42 67.38 2.20 o -5 0 1 17.06 25.65 1.68 o -4 0 1 0.37 1.11 0.53 o -3 0 1 0.33 -0.68 0.81 o -2 0 1 726.89 720.58 15.51 o -1 0 1 461.42 440.93 9.50 o 1 0 1 2101.15 2005.90 43.94 o 2 0 1 7.93 3.27 0.35 o 3 0 1 157.69 167.33 3.93 o 4 0 1 730.75 768.61 16.74 o 5 0 1 87.51 113.89 3.02 o 6 0 1 51.93 53.17 2.04 o 7 0 1 29.96 37.96 1.73 o 8 0 1 77.39 70.67 4.59 o 9 0 1 80.95 76.37 2.77 o 10 0 1 2.35 2.45 0.57 o 11 0 1 0.13 -2.28 2.32 o -11 1 1 0.10 1.02 1.07 o -10 1 1 14.71 16.11 0.81 o -9 1 1 0.21 0.35 0.90 o -8 1 1 37.78 36.90 2.36 o -7 1 1 43.29 41.54 1.84 o -6 1 1 12.52 14.56 0.68 o -5 1 1 1.00 1.29 0.35 o -4 1 1 104.07 100.38 3.92 o -3 1 1 79.27 77.36 2.11 o -2 1 1 224.83 237.12 6.35 o -1 1 1 101.21 99.05 2.40 o 0 1 1 30.44 32.89 0.86 o 1 1 1 1365.65 1279.06 27.34 o 2 1 1 83.44 76.39 2.04 o 3 1 1 585.38 583.97 12.76 o 4 1 1 499.45 562.46 12.39 o 5 1 1 21.83 25.06 1.11 o 6 1 1 0.37 -1.32 1.41 o 7 1 1 0.54 0.28 1.24 o 8 1 1 67.65 56.29 2.24 o 9 1 1 6.06 4.64 0.56 o 10 1 1 1.12 0.40 0.96 o -10 2 1 38.98 39.96 2.16 o -9 2 1 17.18 16.23 0.77 o -8 2 1 90.71 89.73 4.91 o -7 2 1 115.52 117.90 4.29 o -6 2 1 54.44 57.80 2.05 o -5 2 1 28.13 28.11 1.39 o -4 2 1 0.84 -1.27 1.41 o -3 2 1 22.93 23.89 1.14 o -2 2 1 286.11 291.04 6.55 o -1 2 1 214.28 214.85 4.90 o 0 2 1 1198.34 1157.18 17.56 o 1 2 1 1041.35 1007.83 28.44 o 2 2 1 3.54 2.85 0.34 o 3 2 1 64.80 74.38 2.11 o 4 2 1 450.86 487.96 10.89 o 5 2 1 68.07 88.22 2.59 o 6 2 1 29.12 30.54 1.94 o 7 2 1 15.61 19.23 1.40 o 8 2 1 66.81 62.96 2.42 o 9 2 1 72.97 70.14 2.73 o 10 2 1 1.23 0.61 0.77 o -10 3 1 9.31 11.43 0.66 o -9 3 1 0.02 -1.38 1.38 o -8 3 1 34.15 30.02 1.56 o -7 3 1 27.09 27.67 2.16 o -6 3 1 9.16 10.14 0.85 o -5 3 1 0.07 -0.95 0.95 o -4 3 1 68.85 63.11 2.07 o -3 3 1 3.32 2.50 0.36 o -2 3 1 235.07 225.47 5.27 o -1 3 1 53.06 60.40 1.81 o 0 3 1 46.72 47.03 1.19 o 1 3 1 355.99 365.64 8.21 o 2 3 1 5.79 6.80 0.42 o 3 3 1 170.78 152.99 4.05 o 4 3 1 237.14 251.99 6.00 o 5 3 1 1.24 1.56 1.89 o 6 3 1 0.24 0.39 1.08 o 7 3 1 1.04 -1.16 1.16 o 8 3 1 55.11 50.97 2.27 o 9 3 1 6.23 5.04 2.29 o 10 3 1 0.45 0.96 1.00 o -9 4 1 11.19 9.64 0.68 o -8 4 1 58.93 60.18 3.32 o -7 4 1 62.50 65.58 2.52 o -6 4 1 21.05 24.28 1.16 o -5 4 1 16.03 13.66 1.40 o -4 4 1 3.14 2.96 0.56 o -3 4 1 26.52 32.32 3.35 o -2 4 1 67.53 80.40 3.55 o -1 4 1 58.17 60.09 1.95 o 0 4 1 404.58 406.21 6.50 o 1 4 1 328.45 354.48 8.13 o 2 4 1 2.67 1.97 1.11 o 3 4 1 29.98 34.41 1.56 o 4 4 1 190.77 205.02 5.15 o 5 4 1 32.93 40.54 1.87 o 6 4 1 7.87 8.61 0.79 o 7 4 1 1.71 -0.38 1.06 o 8 4 1 41.55 39.68 1.62 o 9 4 1 48.13 47.75 2.38 o -9 5 1 0.00 0.17 1.40 o -8 5 1 27.80 26.68 1.19 o -7 5 1 12.52 12.97 0.68 o -6 5 1 2.18 2.61 0.63 o -5 5 1 0.00 0.68 0.64 o -4 5 1 24.90 24.52 1.15 o -3 5 1 0.02 -0.74 1.06 o -2 5 1 53.46 50.56 3.19 o -1 5 1 8.63 10.28 0.52 o 0 5 1 20.74 21.72 0.72 o 1 5 1 97.74 100.41 5.13 o 2 5 1 3.83 4.43 0.45 o 3 5 1 44.98 44.67 2.52 o 4 5 1 90.85 92.09 7.43 o 5 5 1 0.16 -1.30 1.50 o 6 5 1 0.02 0.46 0.76 o 7 5 1 0.00 -1.29 1.29 o 8 5 1 35.39 35.75 1.63 o -7 6 1 36.76 35.05 1.68 o -6 6 1 3.46 2.97 0.56 o -5 6 1 2.35 2.18 0.90 o -4 6 1 1.77 1.57 0.63 o -3 6 1 7.97 8.13 0.58 o -2 6 1 31.83 33.30 1.34 o -1 6 1 25.53 22.56 2.25 o 0 6 1 145.11 138.94 2.79 o 1 6 1 151.51 153.18 4.25 o 2 6 1 3.06 1.92 0.63 o 3 6 1 24.13 24.11 2.49 o 4 6 1 82.43 84.89 2.95 o 5 6 1 14.30 16.33 0.80 o 6 6 1 1.42 -1.29 1.89 o 7 6 1 0.05 -0.18 1.33 o -6 7 1 0.40 -0.31 1.39 o -5 7 1 0.02 1.09 1.06 o -4 7 1 7.04 8.54 0.61 o -3 7 1 0.66 1.29 0.85 o -2 7 1 7.82 6.93 0.59 o -1 7 1 0.75 0.84 0.58 o 0 7 1 9.63 9.03 0.43 o 1 7 1 34.75 39.19 1.70 o 2 7 1 4.12 4.51 0.55 o 3 7 1 13.09 12.99 0.68 o 4 7 1 40.34 39.65 3.19 o 5 7 1 0.22 -0.38 1.16 o 6 7 1 0.01 -0.57 1.48 o -3 8 1 3.91 1.43 1.44 o -2 8 1 14.12 13.17 0.73 o -1 8 1 13.16 10.64 0.68 o 0 8 1 64.22 61.99 1.90 o 1 8 1 79.75 77.78 3.17 o 2 8 1 2.34 2.62 0.59 o 3 8 1 12.31 11.92 1.18 o -11 0 2 53.33 59.81 2.71 o -10 0 2 2.82 3.02 0.81 o -9 0 2 25.46 24.53 1.34 o -8 0 2 186.48 179.39 6.24 o -7 0 2 446.75 464.59 10.67 o -6 0 2 7.93 7.49 0.51 o -5 0 2 3.41 2.17 0.36 o -4 0 2 24.34 21.43 1.30 o -3 0 2 472.26 508.91 11.14 o -2 0 2 83.65 85.18 2.21 o -1 0 2 583.04 554.43 11.99 o 0 0 2 4.16 3.58 0.47 o 1 0 2 55.16 56.99 2.97 o 2 0 2 26.17 22.37 1.70 o 3 0 2 0.52 -0.39 0.81 o 4 0 2 156.11 167.48 4.08 o 5 0 2 3.56 1.33 0.49 o 6 0 2 3.91 2.83 0.44 o 7 0 2 4.03 1.29 1.12 o 8 0 2 133.83 116.64 3.54 o 9 0 2 11.12 9.39 0.62 o 10 0 2 16.22 16.73 0.83 o -11 1 2 7.07 6.64 0.65 o -10 1 2 65.76 67.27 2.76 o -9 1 2 0.31 1.30 0.68 o -8 1 2 222.23 223.05 6.95 o -7 1 2 13.47 12.93 0.64 o -6 1 2 237.30 225.93 5.51 o -5 1 2 174.19 175.92 4.33 o -4 1 2 0.00 -0.02 0.85 o -3 1 2 3.47 3.53 0.35 o -2 1 2 14.35 13.28 0.67 o -1 1 2 73.45 74.44 1.99 o 0 1 2 70.04 83.82 1.53 o 1 1 2 1431.57 1436.18 30.74 o 2 1 2 15.49 11.78 0.58 o 3 1 2 0.04 -0.37 0.79 o 4 1 2 114.02 132.50 3.37 o 5 1 2 0.03 -0.62 1.32 o 6 1 2 7.84 6.43 0.47 o 7 1 2 15.28 13.75 0.66 o 8 1 2 121.87 99.73 3.21 o 9 1 2 6.75 5.77 0.76 o 10 1 2 22.27 19.75 0.97 o -10 2 2 2.66 4.23 1.05 o -9 2 2 17.37 16.44 1.29 o -8 2 2 137.43 136.85 3.95 o -7 2 2 366.81 372.30 9.15 o -6 2 2 6.28 6.29 0.47 o -5 2 2 3.76 3.31 0.40 o -4 2 2 10.20 9.57 0.46 o -3 2 2 231.67 243.81 5.63 o -2 2 2 43.40 43.83 1.66 o -1 2 2 295.41 274.23 6.19 o 0 2 2 4.80 4.60 0.28 o 1 2 2 43.78 40.75 1.40 o 2 2 2 29.59 27.97 1.20 o 3 2 2 10.60 13.95 0.76 o 4 2 2 109.38 119.55 3.17 o 5 2 2 0.49 1.44 2.15 o 6 2 2 4.26 3.36 1.28 o 7 2 2 8.40 4.80 0.50 o 8 2 2 105.91 99.43 3.22 o 9 2 2 12.73 10.19 0.65 o 10 2 2 12.86 14.79 0.76 o -10 3 2 48.11 50.96 2.49 o -9 3 2 0.78 0.61 0.82 o -8 3 2 181.67 183.11 6.44 o -7 3 2 23.50 20.96 1.15 o -6 3 2 160.39 155.61 4.20 o -5 3 2 45.49 42.43 2.20 o -4 3 2 1.34 2.43 0.92 o -3 3 2 6.09 7.09 0.41 o -2 3 2 6.56 4.85 0.36 o -1 3 2 21.25 24.41 1.18 o 0 3 2 100.53 99.35 1.86 o 1 3 2 310.60 306.80 7.00 o 2 3 2 0.76 0.17 0.85 o 3 3 2 0.51 0.41 0.87 o 4 3 2 57.80 61.81 2.06 o 5 3 2 0.65 1.26 0.92 o 6 3 2 1.45 0.90 0.94 o 7 3 2 7.75 6.38 3.22 o 8 3 2 83.73 82.35 3.05 o 9 3 2 4.75 0.13 1.43 o 10 3 2 13.78 12.23 0.73 o -9 4 2 7.05 6.99 0.62 o -8 4 2 64.77 66.99 4.83 o -7 4 2 241.85 241.77 6.25 o -6 4 2 3.76 3.76 2.83 o -5 4 2 1.16 0.97 0.60 o -4 4 2 0.33 0.54 0.56 o -3 4 2 59.68 58.73 2.06 o -2 4 2 9.88 10.63 0.60 o -1 4 2 74.92 67.42 2.14 o 0 4 2 2.80 2.82 0.26 o 1 4 2 9.18 9.10 0.91 o 2 4 2 10.13 9.38 0.47 o 3 4 2 15.68 17.51 1.54 o 4 4 2 41.85 44.95 1.87 o 5 4 2 7.17 6.70 0.76 o 6 4 2 3.49 4.53 0.49 o 7 4 2 10.29 8.82 0.59 o 8 4 2 61.53 62.98 2.59 o 9 4 2 13.31 10.15 0.72 o -9 5 2 0.31 1.01 0.92 o -8 5 2 123.20 130.48 4.16 o -7 5 2 20.75 18.97 0.92 o -6 5 2 90.49 90.32 3.10 o -5 5 2 14.01 13.72 0.68 o -4 5 2 0.68 -0.24 1.06 o -3 5 2 4.21 5.66 0.47 o -2 5 2 0.84 0.89 0.65 o -1 5 2 2.78 4.59 0.44 o 0 5 2 18.88 18.10 0.67 o 1 5 2 75.21 76.64 3.57 o 2 5 2 0.12 -0.07 1.32 o 3 5 2 0.68 -0.57 1.07 o 4 5 2 40.13 37.53 2.92 o 5 5 2 2.75 3.46 1.15 o 6 5 2 0.01 0.43 0.76 o 7 5 2 3.64 4.10 0.59 o 8 5 2 48.44 48.98 2.14 o -7 6 2 146.72 151.80 7.84 o -6 6 2 2.20 2.42 1.09 o -5 6 2 0.11 1.11 1.43 o -4 6 2 0.47 0.85 1.09 o -3 6 2 17.02 16.69 0.81 o -2 6 2 1.61 2.10 1.23 o -1 6 2 16.79 18.21 0.89 o 0 6 2 0.66 0.32 0.72 o 1 6 2 0.04 -0.34 1.44 o 2 6 2 0.26 0.32 1.13 o 3 6 2 3.46 4.15 0.51 o 4 6 2 9.57 10.47 0.60 o 5 6 2 6.65 6.77 0.59 o 6 6 2 2.08 2.97 2.09 o 7 6 2 6.79 6.56 0.66 o -6 7 2 41.58 44.22 2.93 o -5 7 2 4.59 3.77 1.11 o -4 7 2 4.27 3.16 1.18 o -3 7 2 2.57 0.74 0.91 o -2 7 2 0.01 0.08 0.99 o -1 7 2 0.19 0.86 0.68 o 0 7 2 1.17 0.23 0.90 o 1 7 2 20.37 19.41 1.30 o 2 7 2 0.49 -0.04 1.27 o 3 7 2 0.83 -0.20 1.46 o 4 7 2 24.41 21.41 1.24 o 5 7 2 4.88 5.21 0.97 o -3 8 2 4.83 3.33 0.63 o -2 8 2 0.28 0.95 0.66 o -1 8 2 3.20 3.51 0.60 o 0 8 2 0.21 -0.28 1.52 o 1 8 2 1.83 -0.64 1.59 o 2 8 2 0.22 0.95 1.37 o -11 0 3 34.28 38.56 2.68 o -10 0 3 4.32 5.82 2.55 o -9 0 3 1.13 -0.36 1.50 o -8 0 3 3.30 2.98 0.66 o -7 0 3 331.93 324.32 7.74 o -6 0 3 272.64 273.99 6.52 o -5 0 3 78.18 73.07 2.24 o -4 0 3 367.57 431.71 9.65 o -3 0 3 0.43 0.95 0.53 o -2 0 3 1049.76 1035.59 22.30 o -1 0 3 571.48 576.53 12.54 o 0 0 3 443.90 435.89 6.76 o 1 0 3 237.09 240.43 5.46 o 2 0 3 177.93 173.51 4.11 o 3 0 3 15.81 19.17 0.96 o 4 0 3 2.74 -0.78 0.87 o 5 0 3 130.54 124.39 3.36 o 6 0 3 109.06 114.30 3.29 o 7 0 3 10.87 10.56 0.76 o 8 0 3 65.48 60.72 2.42 o 9 0 3 3.17 3.98 1.87 o 10 0 3 0.82 2.05 0.88 o -11 1 3 15.72 16.50 0.81 o -10 1 3 6.08 4.82 0.60 o -9 1 3 11.68 11.66 0.65 o -8 1 3 108.71 108.71 3.39 o -7 1 3 861.78 860.89 20.96 o -6 1 3 132.06 127.46 3.48 o -5 1 3 241.06 235.00 8.31 o -4 1 3 175.00 175.21 4.26 o -3 1 3 1559.54 1687.42 36.21 o -2 1 3 27.40 32.80 2.08 o -1 1 3 6.85 4.73 0.57 o 0 1 3 21.47 19.98 1.01 o 1 1 3 845.46 896.58 19.37 o 2 1 3 128.84 139.64 3.43 o 3 1 3 0.00 -0.37 1.12 o 4 1 3 38.33 38.47 1.54 o 5 1 3 96.17 102.91 3.65 o 6 1 3 114.62 120.63 3.41 o 7 1 3 161.47 170.36 6.05 o 8 1 3 68.79 64.20 2.52 o 9 1 3 8.81 3.81 1.07 o 10 1 3 8.53 10.43 1.24 o -10 2 3 3.83 5.18 0.60 o -9 2 3 1.03 -0.30 1.02 o -8 2 3 3.62 3.34 1.08 o -7 2 3 290.81 287.91 7.04 o -6 2 3 191.92 190.94 6.19 o -5 2 3 60.19 57.87 2.50 o -4 2 3 277.23 299.38 6.93 o -3 2 3 0.43 0.25 0.81 o -2 2 3 391.50 364.79 10.73 o -1 2 3 450.12 446.50 10.25 o 0 2 3 423.65 430.10 6.74 o 1 2 3 102.78 104.79 2.72 o 2 2 3 64.04 67.61 2.00 o 3 2 3 15.03 15.30 0.75 o 4 2 3 2.45 1.96 0.59 o 5 2 3 115.19 116.85 3.28 o 6 2 3 84.49 84.26 2.74 o 7 2 3 9.62 9.12 0.96 o 8 2 3 58.22 50.51 2.36 o 9 2 3 3.03 4.32 1.84 o 10 2 3 0.77 -0.76 1.55 o -10 3 3 3.73 3.31 0.95 o -9 3 3 13.91 14.13 0.72 o -8 3 3 75.18 72.41 2.69 o -7 3 3 631.62 644.03 14.65 o -6 3 3 58.61 58.44 2.19 o -5 3 3 126.10 126.61 3.49 o -4 3 3 81.79 81.30 2.74 o -3 3 3 640.20 650.99 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