#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/10/38/2103839.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2103839_Fobs loop_ _publ_author_name 'Bowes, Katharine F.' 'Ferguson, George' 'Lough, Alan J.' 'Glidewell, Christopher' _publ_section_title ; Salts of maleic and fumaric acids with organic polyamines: comparison of isomeric acids as building blocks in supramolecular chemistry ; _journal_issue 1 _journal_name_full 'Acta Crystallographica Section B' _journal_page_first 100 _journal_page_last 117 _journal_volume 59 _journal_year 2003 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 116.465 _cell_angle_gamma 90.000 _cell_length_a 22.4349 _cell_length_b 4.6045 _cell_length_c 17.1156 _exptl_crystal_F_000 664.00 _reflns_d_resolution_high 0.7706 _[local]_cod_data_source_file na0143VIIIsup9.hkl _[local]_cod_data_source_block VIII #BEGIN Tags that were not found in dictionaries: _shelx_title ' 217 - SHELXL' _shelx_refln_list_code 4 _shelx_F_calc_maximum 128.86 _shelx_F_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 4 0 0 4078.30 2712.49 525.70 o 6 0 0 1170.07 1009.62 72.83 o 8 0 0 1287.86 1063.04 108.88 o 10 0 0 53.92 64.41 7.97 o 12 0 0 272.23 203.42 14.95 o 14 0 0 1523.48 1624.42 134.17 o 16 0 0 186.90 182.42 15.24 o 18 0 0 46.53 43.20 5.94 o 20 0 0 40.15 43.45 6.13 o 22 0 0 687.31 804.50 58.65 o 24 0 0 25.67 31.98 7.69 o 26 0 0 14.22 12.47 7.95 o 1 1 0 3448.82 1941.38 100.23 o 3 1 0 1252.90 822.77 70.86 o 5 1 0 2011.85 1342.34 73.09 o 7 1 0 1991.71 1950.55 211.61 o 9 1 0 2026.77 2053.35 118.83 o 11 1 0 1304.96 1278.38 54.77 o 13 1 0 681.79 801.98 32.84 o 15 1 0 529.62 595.48 31.03 o 17 1 0 119.29 113.91 8.42 o 19 1 0 70.69 73.27 6.79 o 21 1 0 28.89 36.78 11.99 o 23 1 0 233.75 243.21 25.52 o 25 1 0 27.71 13.08 7.57 o 0 2 0 1325.23 907.81 54.98 o 2 2 0 541.09 399.31 32.68 o 4 2 0 840.80 605.82 59.92 o 6 2 0 1328.58 1169.47 50.59 o 8 2 0 225.48 193.89 13.09 o 10 2 0 21.47 25.67 3.34 o 12 2 0 65.27 50.58 15.25 o 14 2 0 1183.97 1280.73 94.60 o 16 2 0 10.32 2.51 5.67 o 18 2 0 2.93 3.27 5.59 o 20 2 0 12.69 13.87 6.81 o 22 2 0 14.46 14.08 16.28 o 24 2 0 20.92 34.54 18.50 o 1 3 0 796.98 651.69 65.52 o 3 3 0 252.36 216.64 15.91 o 5 3 0 3.14 0.26 3.92 o 7 3 0 31.33 37.48 3.95 o 9 3 0 194.58 224.57 11.58 o 11 3 0 0.32 -1.79 4.11 o 13 3 0 1039.97 1082.42 147.57 o 15 3 0 32.10 8.72 14.24 o 17 3 0 12.46 14.34 10.76 o 19 3 0 38.93 56.72 16.22 o 21 3 0 41.38 63.71 19.21 o 0 4 0 132.93 146.86 17.15 o 2 4 0 40.34 39.66 7.24 o 4 4 0 45.31 46.95 5.86 o 6 4 0 407.79 406.35 39.59 o 8 4 0 176.39 155.69 11.99 o 10 4 0 562.62 684.37 36.01 o 12 4 0 34.52 32.79 6.17 o 14 4 0 91.03 97.56 21.84 o 16 4 0 7.63 11.68 14.48 o 18 4 0 1.03 8.24 13.76 o 1 5 0 4.25 -0.94 7.08 o 3 5 0 39.42 56.27 14.38 o 5 5 0 1.42 4.69 5.27 o 7 5 0 139.39 172.14 11.89 o 9 5 0 13.56 15.01 5.37 o 11 5 0 63.33 59.63 7.27 o 13 5 0 24.15 23.40 20.51 o -25 1 1 3.93 -0.91 5.23 o -23 1 1 6.76 11.94 7.39 o -21 1 1 47.88 57.73 8.68 o -19 1 1 56.31 47.90 6.21 o -17 1 1 40.81 40.32 6.59 o -15 1 1 121.13 115.77 10.87 o -13 1 1 161.86 211.54 9.41 o -11 1 1 713.56 682.41 63.57 o -9 1 1 137.93 143.20 19.14 o -7 1 1 778.80 565.85 148.20 o -5 1 1 11061.47 6707.74 630.76 o -3 1 1 1491.26 947.24 171.36 o -1 1 1 6101.41 4372.75 321.92 o 1 1 1 7851.40 6270.89 531.23 o 3 1 1 211.68 128.61 11.49 o 5 1 1 258.11 192.56 40.39 o 7 1 1 996.71 660.73 144.04 o 9 1 1 1897.11 1381.47 222.60 o 11 1 1 62.15 70.14 4.96 o 13 1 1 405.49 439.47 26.95 o 15 1 1 295.07 303.92 15.14 o 17 1 1 32.06 15.48 5.09 o 19 1 1 34.08 33.65 7.03 o 21 1 1 135.06 139.23 13.27 o 23 1 1 78.25 70.22 20.68 o 25 1 1 0.89 -5.60 7.66 o -24 2 1 122.36 98.52 24.76 o -22 2 1 75.19 88.51 11.08 o -20 2 1 1.92 6.86 5.69 o -18 2 1 13.70 8.35 12.18 o -16 2 1 130.37 140.02 21.54 o -14 2 1 45.15 42.37 7.02 o -12 2 1 524.36 548.72 40.06 o -10 2 1 689.68 770.92 56.45 o -8 2 1 23.62 24.73 5.03 o -6 2 1 158.87 160.15 24.36 o -4 2 1 1090.70 770.96 113.29 o -2 2 1 5119.27 3308.51 695.52 o 0 2 1 27.80 10.87 3.91 o 2 2 1 251.43 141.94 21.34 o 4 2 1 0.11 3.21 1.85 o 6 2 1 73.05 60.53 21.92 o 8 2 1 1030.25 871.28 121.52 o 12 2 1 134.96 117.81 9.48 o 14 2 1 412.02 432.22 23.44 o 16 2 1 117.35 109.35 21.59 o 18 2 1 35.41 23.05 6.16 o 20 2 1 18.35 11.93 4.99 o 22 2 1 7.66 8.17 6.27 o -23 3 1 18.85 33.69 22.07 o -21 3 1 29.52 40.40 17.99 o -19 3 1 7.36 6.54 13.08 o -15 3 1 6.68 -2.01 8.48 o -13 3 1 931.39 1069.80 78.01 o -11 3 1 1590.70 1656.51 97.05 o -9 3 1 599.08 593.48 30.53 o -7 3 1 10.29 11.21 4.35 o -5 3 1 29.18 26.05 4.49 o -3 3 1 119.94 109.87 6.60 o -1 3 1 667.56 576.02 55.56 o 1 3 1 2264.78 1760.18 119.64 o 3 3 1 132.31 129.63 12.89 o 5 3 1 78.52 67.54 6.12 o 7 3 1 50.77 46.42 6.27 o 9 3 1 21.05 31.75 4.25 o 11 3 1 599.88 589.54 29.73 o 13 3 1 636.10 695.81 80.75 o 15 3 1 9.35 4.70 12.43 o 17 3 1 172.54 179.32 30.78 o 19 3 1 338.69 390.67 58.92 o 21 3 1 12.67 -2.86 20.44 o -18 4 1 1.34 10.18 19.38 o -16 4 1 8.09 18.33 14.37 o -14 4 1 61.57 64.60 7.09 o -12 4 1 10.13 6.45 2.59 o -10 4 1 0.00 2.10 4.05 o -8 4 1 2.35 -2.86 4.80 o -6 4 1 194.59 173.32 24.95 o -4 4 1 30.02 31.68 6.66 o -2 4 1 69.06 62.89 8.44 o 0 4 1 314.06 356.92 47.30 o 2 4 1 747.69 830.59 58.56 o 4 4 1 66.95 71.51 9.22 o 6 4 1 15.84 17.78 5.30 o 8 4 1 755.42 877.42 49.32 o 10 4 1 103.29 135.82 9.33 o 12 4 1 15.92 20.73 2.31 o 14 4 1 63.67 96.90 21.16 o 16 4 1 2.29 -3.99 17.34 o 18 4 1 9.53 29.84 16.25 o -13 5 1 0.89 2.93 8.86 o -11 5 1 9.51 5.60 4.86 o -9 5 1 1.94 5.54 5.37 o -7 5 1 30.91 43.43 7.10 o -5 5 1 17.78 13.82 7.86 o -3 5 1 114.29 158.68 13.83 o -1 5 1 35.10 32.09 8.64 o 1 5 1 61.30 59.57 10.83 o 3 5 1 150.44 158.72 21.22 o 5 5 1 30.75 22.68 13.40 o 7 5 1 1.79 -1.05 6.55 o 9 5 1 8.48 3.82 5.52 o 11 5 1 0.13 2.50 4.23 o 13 5 1 38.90 35.77 23.54 o -26 0 2 108.99 114.78 16.57 o -24 0 2 3.36 9.90 5.62 o -22 0 2 0.01 2.65 6.08 o -20 0 2 93.53 79.40 6.52 o -18 0 2 125.87 161.74 12.35 o -16 0 2 50.28 58.48 5.25 o -14 0 2 1312.38 1282.40 66.25 o -12 0 2 5215.70 5452.66 731.11 o -10 0 2 266.64 196.55 17.42 o -8 0 2 4.75 -4.67 4.67 o -4 0 2 1049.64 754.76 58.23 o 4 0 2 486.83 510.23 23.00 o 6 0 2 12302.89 14598.19 1127.64 o 8 0 2 305.48 287.41 19.26 o 10 0 2 4642.79 4313.40 226.84 o 12 0 2 235.05 211.99 43.20 o 14 0 2 325.25 205.86 16.35 o 16 0 2 1.08 -4.46 4.46 o 18 0 2 797.78 959.69 92.08 o 20 0 2 209.90 235.27 19.43 o 22 0 2 44.89 47.60 10.88 o 24 0 2 117.89 103.50 18.85 o -25 1 2 156.94 157.84 17.40 o -23 1 2 1.29 3.39 7.20 o -21 1 2 289.28 317.45 31.20 o -19 1 2 39.66 45.52 6.57 o -17 1 2 300.31 308.20 20.77 o -15 1 2 87.67 95.10 18.69 o -13 1 2 921.44 940.87 66.20 o -11 1 2 327.20 270.63 32.73 o -9 1 2 283.47 237.54 34.25 o -7 1 2 807.26 812.65 33.17 o 1 1 2 446.62 491.80 23.53 o 3 1 2 6801.85 5864.12 518.64 o 5 1 2 658.31 729.86 32.82 o 7 1 2 24.22 35.03 2.17 o 9 1 2 675.14 573.72 69.90 o 11 1 2 468.12 419.07 55.68 o 13 1 2 2.61 2.59 2.06 o 15 1 2 22.73 26.50 4.65 o 17 1 2 373.05 358.66 19.17 o 19 1 2 231.16 210.23 37.46 o 21 1 2 39.03 32.87 7.08 o 23 1 2 37.22 30.71 7.02 o -24 2 2 50.61 44.33 19.67 o -22 2 2 0.01 -1.45 8.31 o -20 2 2 0.28 7.41 6.19 o -18 2 2 1116.91 1256.15 125.70 o -16 2 2 127.07 113.23 13.29 o -14 2 2 963.44 1040.45 60.87 o -12 2 2 141.86 133.64 7.56 o -10 2 2 233.14 264.33 22.26 o -8 2 2 1148.54 1041.04 79.58 o -6 2 2 79.36 78.12 17.12 o -4 2 2 8598.56 7011.03 1065.08 o -2 2 2 648.04 411.19 105.42 o 0 2 2 186.11 127.57 33.54 o 2 2 2 580.64 418.16 96.61 o 4 2 2 39.54 28.69 4.87 o 6 2 2 177.69 136.99 28.16 o 8 2 2 94.99 77.96 24.03 o 10 2 2 32.05 19.76 11.63 o 12 2 2 92.15 66.09 14.01 o 14 2 2 90.23 95.76 8.23 o 16 2 2 79.32 76.84 9.29 o 18 2 2 12.99 12.49 4.53 o 20 2 2 25.94 18.57 4.31 o 22 2 2 12.29 12.47 16.08 o -23 3 2 1.77 -18.32 18.32 o -21 3 2 0.27 -4.80 14.95 o -19 3 2 88.47 76.78 21.86 o -17 3 2 113.68 186.60 28.15 o -15 3 2 61.27 61.83 14.26 o -13 3 2 11.78 17.09 6.39 o -11 3 2 2766.69 3054.35 233.89 o -9 3 2 25.25 29.45 8.61 o -7 3 2 0.00 4.24 3.78 o -5 3 2 94.56 97.93 14.61 o -3 3 2 327.12 274.85 63.14 o -1 3 2 219.92 162.89 30.18 o 1 3 2 785.99 781.38 58.67 o 3 3 2 0.40 12.70 8.89 o 5 3 2 0.33 9.02 4.29 o 7 3 2 49.86 37.36 3.65 o 9 3 2 194.39 213.02 10.36 o 11 3 2 616.82 647.13 31.20 o 13 3 2 19.97 20.58 13.18 o 15 3 2 147.42 162.97 26.52 o 17 3 2 81.19 84.51 15.61 o 19 3 2 68.28 80.21 16.70 o 21 3 2 15.63 55.66 22.48 o -20 4 2 1.20 7.49 16.01 o -18 4 2 11.56 5.69 22.17 o -16 4 2 10.28 20.08 23.09 o -14 4 2 103.17 118.58 20.14 o -12 4 2 66.48 72.25 9.68 o -10 4 2 157.03 155.58 10.23 o -8 4 2 142.41 155.15 9.98 o -6 4 2 124.71 122.85 16.36 o -4 4 2 146.42 145.95 26.93 o -2 4 2 97.18 107.36 9.51 o 0 4 2 20.94 26.77 7.89 o 2 4 2 4.24 15.24 7.28 o 4 4 2 85.12 68.49 7.02 o 6 4 2 12.69 14.36 5.37 o 8 4 2 944.93 1025.70 81.30 o 10 4 2 169.86 193.58 15.15 o 12 4 2 315.60 348.66 16.27 o 14 4 2 53.16 56.90 18.16 o 16 4 2 110.63 123.74 26.27 o 18 4 2 8.69 6.37 20.78 o -15 5 2 46.81 43.95 20.68 o -13 5 2 40.01 50.12 19.96 o -11 5 2 23.15 20.26 6.12 o -9 5 2 8.26 22.16 5.31 o -7 5 2 16.84 1.71 7.58 o -5 5 2 55.72 40.79 8.18 o -3 5 2 18.84 26.60 11.68 o -1 5 2 2.73 1.05 11.13 o 1 5 2 51.16 56.75 10.87 o 3 5 2 257.41 326.13 38.66 o 5 5 2 2.61 -0.71 7.03 o 7 5 2 1.93 14.20 6.27 o 9 5 2 0.26 -2.54 4.50 o 11 5 2 27.07 22.69 8.89 o -27 1 3 91.58 88.22 12.27 o -25 1 3 24.86 25.26 6.75 o -23 1 3 60.99 50.36 7.57 o -21 1 3 8.40 2.09 4.07 o -19 1 3 17.34 5.71 8.62 o -17 1 3 1178.22 1317.08 48.56 o -15 1 3 125.26 122.11 5.60 o -13 1 3 834.79 795.14 65.14 o -11 1 3 204.24 257.97 34.95 o -9 1 3 2447.91 2437.43 85.52 o -7 1 3 539.81 670.89 27.01 o -5 1 3 8380.40 9136.00 465.41 o -3 1 3 15419.95 17760.88 796.27 o -1 1 3 21.67 30.55 5.03 o 1 1 3 85.23 70.09 4.83 o 3 1 3 48.77 36.02 4.98 o 5 1 3 2758.50 2630.93 108.28 o 7 1 3 5.00 2.48 3.75 o 9 1 3 233.92 174.70 10.51 o 11 1 3 187.00 169.14 17.79 o 13 1 3 533.84 438.37 45.13 o 15 1 3 37.45 27.15 4.99 o 17 1 3 2.40 -2.09 4.89 o 19 1 3 0.13 -4.25 4.25 o 21 1 3 24.15 16.52 14.53 o 23 1 3 10.77 3.99 13.73 o -26 2 3 20.85 17.13 9.72 o -24 2 3 38.30 49.61 9.26 o -22 2 3 38.45 33.92 8.84 o -20 2 3 72.78 45.90 9.90 o -18 2 3 5.92 -1.26 7.96 o -16 2 3 1210.64 1281.20 74.46 o -14 2 3 449.55 435.42 77.82 o -12 2 3 368.67 321.29 94.33 o -10 2 3 3360.40 3172.00 647.53 o -8 2 3 4.41 3.56 2.35 o -6 2 3 72.89 56.55 13.97 o -4 2 3 519.41 496.14 30.45 o -2 2 3 2932.59 2768.76 170.34 o 0 2 3 209.67 168.12 23.30 o 2 2 3 218.31 214.04 26.66 o 4 2 3 3196.36 3165.55 246.41 o 6 2 3 2870.92 2927.17 233.26 o 8 2 3 95.66 86.62 22.24 o 10 2 3 807.18 728.25 152.31 o 12 2 3 35.37 34.13 15.06 o 14 2 3 311.05 304.63 27.78 o 16 2 3 53.17 54.07 12.30 o 18 2 3 78.27 87.30 16.83 o 20 2 3 1.41 3.61 9.26 o 22 2 3 0.65 11.44 14.71 o -23 3 3 0.69 -11.82 17.71 o -21 3 3 0.50 4.19 12.02 o -19 3 3 0.23 4.01 6.98 o -17 3 3 61.59 62.51 8.99 o -15 3 3 5.20 1.60 5.12 o -13 3 3 83.89 92.33 11.18 o -11 3 3 0.08 5.36 3.22 o -9 3 3 17.30 21.32 6.37 o -7 3 3 336.80 355.25 26.92 o -5 3 3 1543.43 1626.50 153.98 o -3 3 3 202.19 155.01 31.20 o -1 3 3 743.23 698.39 296.23 o 1 3 3 13.71 16.05 5.01 o 3 3 3 2.41 -4.47 4.47 o 5 3 3 474.75 349.47 86.57 o 7 3 3 667.81 390.48 57.79 o 9 3 3 197.46 169.97 11.75 o 11 3 3 138.34 129.31 7.36 o 13 3 3 63.17 49.92 15.61 o 15 3 3 0.00 -12.77 12.77 o 17 3 3 235.61 252.51 35.74 o 19 3 3 257.78 268.41 41.40 o -20 4 3 0.65 -0.54 14.37 o -18 4 3 2.83 20.91 15.94 o -16 4 3 19.85 4.77 6.95 o -14 4 3 22.45 14.62 10.07 o -12 4 3 16.39 12.85 5.64 o -10 4 3 13.98 6.74 9.81 o -8 4 3 4.96 1.67 4.86 o -6 4 3 54.04 51.14 6.97 o -4 4 3 167.71 159.58 25.81 o -2 4 3 14.98 15.82 6.44 o 0 4 3 57.02 63.22 12.42 o 2 4 3 2.18 8.07 6.37 o 4 4 3 187.57 183.78 15.10 o 6 4 3 289.74 272.28 13.66 o 8 4 3 2.67 -1.80 6.25 o 10 4 3 158.68 189.04 14.92 o 12 4 3 18.92 17.66 2.24 o 14 4 3 38.26 24.32 13.42 o 16 4 3 2.42 13.79 13.79 o -15 5 3 60.31 86.96 17.26 o -13 5 3 1.58 6.15 3.91 o -11 5 3 13.86 8.03 4.18 o -9 5 3 13.76 8.78 8.35 o -7 5 3 52.88 61.31 11.10 o -5 5 3 75.91 87.30 10.74 o -3 5 3 78.88 109.34 17.41 o -1 5 3 36.76 47.37 8.75 o 1 5 3 113.29 124.36 14.80 o 3 5 3 530.58 589.13 48.71 o 5 5 3 11.14 3.99 6.28 o 7 5 3 163.53 180.97 19.41 o 9 5 3 14.45 23.99 3.86 o 11 5 3 3.48 0.89 18.39 o -26 0 4 16.80 18.11 6.02 o -24 0 4 92.22 114.31 10.02 o -22 0 4 1841.95 2267.33 185.63 o -20 0 4 0.11 -4.27 4.48 o -18 0 4 804.26 889.81 56.48 o -16 0 4 498.55 384.19 23.55 o -14 0 4 7.39 -2.59 6.51 o -12 0 4 62.23 82.99 10.91 o -10 0 4 289.32 310.04 20.44 o -8 0 4 2015.12 1823.77 124.77 o -6 0 4 10968.89 11613.90 659.85 o 0 0 4 7307.58 7883.56 532.49 o 2 0 4 1272.95 1596.30 86.60 o 4 0 4 0.51 -3.11 3.11 o 6 0 4 0.04 -2.57 4.24 o 8 0 4 1804.38 2257.00 123.73 o 10 0 4 231.97 245.54 11.89 o 12 0 4 11.78 39.81 18.63 o 14 0 4 433.24 341.21 33.06 o 16 0 4 252.61 164.28 18.97 o 18 0 4 96.75 93.99 14.55 o 20 0 4 522.62 582.72 101.18 o 22 0 4 16.38 -0.40 5.25 o -27 1 4 2.91 3.70 7.93 o -25 1 4 9.63 17.16 7.52 o -23 1 4 3.71 9.26 5.85 o -21 1 4 543.39 581.22 33.11 o -19 1 4 330.03 309.65 15.91 o -17 1 4 245.66 256.52 11.30 o -15 1 4 19.66 21.47 10.64 o -13 1 4 5.87 5.20 4.62 o -11 1 4 127.10 155.90 7.65 o -9 1 4 1411.93 1640.44 71.23 o -7 1 4 8226.30 8738.23 361.95 o -5 1 4 255.42 244.62 13.24 o -3 1 4 16603.62 20103.15 766.49 o -1 1 4 3649.56 3601.66 171.58 o 1 1 4 2942.41 3076.27 114.30 o 3 1 4 4322.03 4404.14 247.40 o 5 1 4 97.98 135.30 8.78 o 7 1 4 9.58 17.47 2.98 o 9 1 4 5.95 18.15 3.63 o 11 1 4 22.60 22.96 4.28 o 13 1 4 2.16 4.34 4.19 o 15 1 4 4.93 -2.56 3.62 o 17 1 4 10.02 10.39 14.56 o 19 1 4 107.80 90.47 18.08 o 21 1 4 17.05 12.60 6.41 o -26 2 4 30.83 22.13 11.47 o -24 2 4 27.91 15.91 17.75 o -22 2 4 31.01 31.12 10.58 o -20 2 4 108.39 110.92 30.95 o -18 2 4 0.00 -7.17 7.17 o -16 2 4 2183.96 2292.46 205.58 o -14 2 4 622.50 643.45 114.52 o -12 2 4 24.12 16.17 11.49 o -10 2 4 362.28 321.03 16.89 o -8 2 4 10847.40 11472.79 375.62 o -6 2 4 182.14 166.34 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