#------------------------------------------------------------------------------ #$Date: 2016-04-02 23:00:40 +0300 (Sat, 02 Apr 2016) $ #$Revision: 180898 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/10/38/2103859.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2103859_Fobs loop_ _publ_author_name 'Bowes, Katharine F.' 'Ferguson, George' 'Lough, Alan J.' 'Glidewell, Christopher' _publ_section_title ; Phosphonopropionic acid as a building block in supramolecular chemistry: salts with organic diamines ; _journal_issue 2 _journal_name_full 'Acta Crystallographica Section B' _journal_page_first 248 _journal_page_last 262 _journal_volume 59 _journal_year 2003 _space_group_IT_number 42 _symmetry_space_group_name_Hall 'F 2 -2' _symmetry_space_group_name_H-M 'F m m 2' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 18.7267 _cell_length_b 22.6805 _cell_length_c 7.0893 _exptl_crystal_F_000 1440.00 _reflns_d_resolution_high 0.7694 _cod_data_source_file bm0061IIsup3.hkl _cod_data_source_block II #BEGIN Tags that were not found in dictionaries: _shelx_title ' 221 KFB33' _shelx_refln_list_code 4 _shelx_f_calc_maximum 382.16 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, z' '-x, y, z' 'x, -y, z' 'x, y+1/2, z+1/2' '-x, -y+1/2, z+1/2' '-x, y+1/2, z+1/2' 'x, -y+1/2, z+1/2' 'x+1/2, y, z+1/2' '-x+1/2, -y, z+1/2' '-x+1/2, y, z+1/2' 'x+1/2, -y, z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, -y+1/2, z' '-x+1/2, y+1/2, z' 'x+1/2, -y+1/2, z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 1 -9 4.17 14.96 35.59 o 3 1 -9 89.51 53.11 55.41 o 1 3 -9 25.27 54.29 73.13 o 3 3 -9 27.27 59.72 53.16 o 1 5 -9 36.34 88.88 57.17 o 3 5 -9 76.76 110.40 48.82 o 0 0 -8 880.66 872.14 155.35 o 2 0 -8 171.96 75.89 36.12 o 4 0 -8 2161.86 1971.75 318.43 o 6 0 -8 3795.46 3716.10 488.39 o 8 0 -8 58.94 173.85 84.77 o 10 0 -8 580.15 357.62 93.81 o 0 2 -8 212.12 295.16 108.57 o 2 2 -8 293.81 249.11 38.17 o 4 2 -8 101.87 126.63 72.92 o 6 2 -8 249.98 276.09 53.65 o 8 2 -8 253.28 184.28 47.81 o 10 2 -8 382.51 197.79 74.28 o 0 4 -8 270.94 381.05 96.34 o 2 4 -8 345.11 307.37 40.56 o 4 4 -8 641.33 627.22 62.56 o 6 4 -8 180.54 163.62 67.90 o 8 4 -8 155.04 126.52 62.65 o 10 4 -8 473.78 214.05 116.72 o 0 6 -8 287.57 220.26 53.86 o 2 6 -8 70.70 132.46 43.94 o 4 6 -8 24.43 -9.21 32.14 o 6 6 -8 220.32 117.48 80.47 o 8 6 -8 29.53 -38.76 79.49 o 10 6 -8 238.28 185.03 88.31 o 0 8 -8 537.69 484.33 105.37 o 2 8 -8 23.28 -11.33 31.35 o 4 8 -8 232.93 252.42 51.58 o 8 8 -8 328.54 209.72 104.96 o 10 8 -8 0.23 59.91 83.40 o 0 10 -8 870.49 831.16 160.04 o 2 10 -8 271.87 203.10 47.64 o 4 10 -8 49.25 19.12 47.77 o 8 10 -8 501.64 328.03 115.15 o 0 12 -8 14.07 -42.09 42.09 o 2 12 -8 23.33 20.95 50.31 o 4 12 -8 220.01 156.64 65.59 o 6 12 -8 703.87 867.68 146.90 o 0 14 -8 459.21 365.62 90.47 o 2 14 -8 223.50 152.88 50.04 o 1 1 -7 178.59 226.47 34.92 o 3 1 -7 515.93 474.78 44.45 o 5 1 -7 195.66 65.55 53.06 o 7 1 -7 1237.64 1219.06 157.36 o 9 1 -7 140.77 -19.58 76.36 o 11 1 -7 426.51 404.39 104.97 o 13 1 -7 250.79 210.49 67.94 o 15 1 -7 201.59 63.24 104.56 o 1 3 -7 193.16 168.44 35.99 o 3 3 -7 643.47 680.56 54.78 o 5 3 -7 251.38 258.04 50.71 o 7 3 -7 569.43 491.28 60.46 o 9 3 -7 115.77 274.11 60.89 o 11 3 -7 314.39 337.56 74.22 o 13 3 -7 470.44 379.87 68.88 o 15 3 -7 128.69 142.73 70.29 o 1 5 -7 34.70 60.16 20.61 o 3 5 -7 73.55 58.62 36.30 o 5 5 -7 9.76 16.45 23.51 o 11 5 -7 288.57 133.17 43.56 o 13 5 -7 236.34 156.08 67.08 o 15 5 -7 32.39 30.00 56.48 o 1 7 -7 214.59 208.84 31.62 o 3 7 -7 35.83 0.72 35.55 o 5 7 -7 72.41 95.10 29.08 o 7 7 -7 254.40 180.93 56.46 o 9 7 -7 1113.07 904.02 198.09 o 11 7 -7 116.82 134.51 103.57 o 1 9 -7 152.79 161.64 30.75 o 3 9 -7 7.15 23.60 50.28 o 5 9 -7 27.68 63.67 25.72 o 7 9 -7 224.22 208.14 85.37 o 9 9 -7 128.27 242.00 76.95 o 1 11 -7 73.64 10.57 46.40 o 3 11 -7 129.32 94.96 94.76 o 5 11 -7 76.48 80.86 98.28 o 7 11 -7 464.17 339.97 89.89 o 9 11 -7 66.95 114.53 92.60 o 1 13 -7 195.91 174.85 50.52 o 3 13 -7 217.75 186.80 52.48 o 5 13 -7 21.06 13.52 43.56 o 7 13 -7 271.53 120.81 105.35 o 1 15 -7 123.83 130.59 44.25 o 5 15 -7 50.38 91.04 36.02 o 3 17 -7 123.35 94.57 42.09 o 1 19 -7 87.21 71.66 56.97 o 0 0 -6 2550.21 2353.48 334.98 o 2 0 -6 3696.99 3509.88 335.03 o 4 0 -6 11170.96 11448.21 1246.63 o 6 0 -6 1585.05 1666.19 214.47 o 8 0 -6 1337.62 1188.70 175.81 o 12 0 -6 46.10 1.46 64.80 o 14 0 -6 1940.67 1697.90 224.87 o 16 0 -6 591.52 710.56 101.84 o 18 0 -6 165.96 92.76 66.29 o 0 2 -6 6177.98 6327.76 592.26 o 2 2 -6 247.42 308.67 41.31 o 4 2 -6 4665.41 4827.50 427.56 o 6 2 -6 1134.64 1078.97 108.27 o 8 2 -6 322.22 312.54 85.38 o 10 2 -6 383.47 312.80 58.79 o 12 2 -6 359.90 328.79 67.95 o 14 2 -6 293.26 334.21 45.67 o 16 2 -6 413.58 431.05 47.04 o 18 2 -6 116.63 141.77 58.56 o 0 4 -6 2996.19 3235.09 336.77 o 2 4 -6 742.51 819.24 67.73 o 4 4 -6 386.43 384.19 47.54 o 6 4 -6 899.98 813.41 90.81 o 8 4 -6 28.09 30.74 65.78 o 10 4 -6 733.42 739.21 72.06 o 12 4 -6 2.21 -2.35 40.85 o 14 4 -6 139.50 164.80 49.90 o 16 4 -6 344.14 384.96 87.34 o 18 4 -6 20.96 -0.04 55.89 o 0 6 -6 116.19 141.75 53.65 o 2 6 -6 242.01 306.73 34.82 o 4 6 -6 175.14 136.51 48.27 o 6 6 -6 270.06 268.66 74.21 o 10 6 -6 579.06 563.15 49.11 o 12 6 -6 85.67 48.57 57.17 o 14 6 -6 483.03 477.24 135.23 o 16 6 -6 214.98 183.11 82.43 o 0 8 -6 11.43 17.20 37.39 o 2 8 -6 251.30 209.23 66.97 o 4 8 -6 185.38 182.25 27.10 o 6 8 -6 589.85 526.36 58.75 o 8 8 -6 620.24 433.26 105.57 o 10 8 -6 151.90 212.83 70.29 o 12 8 -6 158.43 73.68 115.72 o 14 8 -6 149.14 100.90 61.44 o 16 8 -6 5.48 73.81 48.55 o 0 10 -6 7812.78 8691.34 1065.46 o 2 10 -6 868.44 803.48 132.05 o 4 10 -6 510.56 519.25 63.85 o 6 10 -6 291.94 242.89 81.66 o 8 10 -6 152.91 68.14 79.10 o 10 10 -6 2978.03 2791.75 252.13 o 12 10 -6 164.48 229.08 95.55 o 14 10 -6 312.30 306.65 103.59 o 16 10 -6 722.33 681.61 118.30 o 2 12 -6 108.12 93.00 33.87 o 4 12 -6 937.55 953.96 98.32 o 6 12 -6 641.52 622.18 107.53 o 8 12 -6 231.35 185.04 79.30 o 10 12 -6 406.77 342.00 60.78 o 12 12 -6 311.93 250.90 64.98 o 14 12 -6 114.91 235.14 82.62 o 2 14 -6 295.13 312.92 57.18 o 4 14 -6 367.48 393.22 61.10 o 6 14 -6 898.84 913.87 167.79 o 8 14 -6 289.03 281.97 94.77 o 10 14 -6 1062.05 926.41 118.44 o 12 14 -6 127.87 140.38 61.67 o 14 14 -6 389.41 235.38 86.95 o 6 16 -6 939.45 1137.23 123.62 o 8 16 -6 118.93 77.14 85.95 o 10 16 -6 1638.56 1666.25 293.30 o 12 16 -6 99.31 -5.70 64.74 o 4 18 -6 536.95 422.25 84.61 o 6 18 -6 169.81 178.17 29.76 o 1 1 -5 1063.42 1043.60 60.85 o 3 1 -5 1309.16 1206.94 70.18 o 5 1 -5 536.05 538.24 47.50 o 7 1 -5 2492.25 2386.22 239.03 o 9 1 -5 868.54 904.64 73.79 o 11 1 -5 1239.84 1171.75 87.64 o 13 1 -5 799.52 793.61 58.09 o 15 1 -5 651.42 670.87 61.28 o 17 1 -5 929.50 888.32 107.12 o 19 1 -5 126.83 126.65 42.03 o 1 3 -5 2007.81 1898.76 160.14 o 3 3 -5 2437.48 2499.36 157.14 o 5 3 -5 706.22 848.90 100.70 o 7 3 -5 1282.99 1208.42 166.81 o 9 3 -5 215.18 215.64 36.67 o 11 3 -5 958.22 960.85 82.02 o 13 3 -5 724.93 660.39 58.06 o 15 3 -5 66.16 30.90 41.57 o 17 3 -5 1102.97 1164.04 99.65 o 19 3 -5 286.87 269.57 48.96 o 1 5 -5 539.20 577.77 41.88 o 3 5 -5 161.23 141.70 31.36 o 5 5 -5 66.89 106.31 28.88 o 7 5 -5 306.16 244.68 99.19 o 9 5 -5 360.03 394.82 57.97 o 11 5 -5 770.73 671.58 69.32 o 13 5 -5 391.17 413.04 46.34 o 15 5 -5 8.89 88.45 41.62 o 17 5 -5 74.70 80.92 35.30 o 19 5 -5 91.89 86.71 44.54 o 1 7 -5 1602.36 1561.13 114.42 o 3 7 -5 453.51 411.22 45.35 o 5 7 -5 177.44 226.74 50.13 o 7 7 -5 390.52 416.21 78.14 o 9 7 -5 2063.17 1960.67 346.46 o 11 7 -5 881.80 883.99 120.78 o 13 7 -5 384.11 346.26 55.44 o 15 7 -5 983.51 851.11 83.77 o 17 7 -5 342.60 287.30 51.98 o 19 7 -5 266.75 260.51 50.96 o 1 9 -5 382.97 384.45 71.29 o 3 9 -5 63.19 74.91 23.04 o 5 9 -5 598.80 559.72 45.69 o 7 9 -5 542.37 543.34 75.02 o 9 9 -5 152.33 138.23 51.10 o 11 9 -5 70.05 2.58 31.33 o 13 9 -5 172.53 56.71 62.56 o 15 9 -5 14.64 -24.51 48.36 o 17 9 -5 49.29 28.74 43.51 o 19 9 -5 145.34 113.52 35.50 o 3 11 -5 1153.93 1309.77 164.23 o 5 11 -5 1137.26 1182.00 108.84 o 7 11 -5 404.66 359.49 49.63 o 9 11 -5 1299.22 1311.90 136.79 o 11 11 -5 410.90 392.09 45.00 o 13 11 -5 1206.12 1032.03 222.99 o 15 11 -5 152.84 59.85 106.71 o 17 11 -5 193.66 214.99 88.50 o 5 13 -5 242.00 210.24 38.28 o 7 13 -5 1065.54 1028.72 147.25 o 9 13 -5 13.90 27.45 34.24 o 11 13 -5 1376.54 1582.90 181.28 o 13 13 -5 403.57 372.59 67.17 o 15 13 -5 79.92 16.84 50.71 o 17 13 -5 1468.99 1726.04 243.58 o 7 15 -5 679.81 636.94 101.46 o 9 15 -5 764.95 826.78 156.71 o 11 15 -5 1538.16 1451.86 416.97 o 13 15 -5 738.87 675.08 253.75 o 15 15 -5 97.66 63.43 86.73 o 5 17 -5 198.38 214.01 33.87 o 7 17 -5 560.73 552.51 90.29 o 9 17 -5 792.55 990.98 115.77 o 11 17 -5 316.34 299.41 66.59 o 13 17 -5 125.88 30.29 64.61 o 9 19 -5 131.10 265.30 83.41 o 11 19 -5 22.10 -70.28 76.74 o 13 19 -5 728.84 950.54 134.36 o 2 0 -4 47745.34 47748.69 3889.30 o 4 0 -4 12785.75 12982.77 1006.40 o 6 0 -4 345.54 332.56 42.70 o 8 0 -4 188.60 246.14 42.49 o 10 0 -4 3367.99 3488.52 297.01 o 12 0 -4 1349.15 1296.46 95.07 o 14 0 -4 4447.80 4439.44 410.91 o 16 0 -4 1552.59 1731.18 207.58 o 18 0 -4 260.30 127.28 60.51 o 20 0 -4 1123.94 1216.69 265.28 o 2 2 -4 1063.78 1106.12 77.77 o 4 2 -4 4849.44 4868.11 535.76 o 6 2 -4 11069.93 10765.27 641.59 o 8 2 -4 25.63 66.16 23.78 o 10 2 -4 3420.99 3357.93 258.03 o 12 2 -4 825.56 814.11 117.65 o 14 2 -4 493.07 480.08 72.86 o 16 2 -4 665.39 663.58 100.09 o 18 2 -4 221.69 237.80 48.74 o 20 2 -4 106.39 82.05 85.56 o 0 4 -4 10775.89 10521.25 696.40 o 2 4 -4 332.90 338.46 29.45 o 4 4 -4 1206.23 1274.14 125.02 o 6 4 -4 1207.87 1162.18 104.69 o 8 4 -4 307.59 315.66 39.95 o 10 4 -4 790.84 868.68 95.90 o 12 4 -4 431.31 393.42 36.99 o 14 4 -4 237.33 222.04 26.67 o 16 4 -4 303.89 335.68 52.82 o 18 4 -4 102.00 51.88 36.42 o 20 4 -4 286.25 242.23 51.08 o 0 6 -4 175.01 120.23 36.42 o 2 6 -4 483.98 511.24 41.62 o 4 6 -4 3008.16 3322.44 171.45 o 6 6 -4 24.54 14.23 15.59 o 8 6 -4 225.13 251.70 51.79 o 10 6 -4 1617.15 1704.78 207.81 o 12 6 -4 1109.24 967.53 73.19 o 14 6 -4 328.37 327.76 77.55 o 16 6 -4 231.03 196.00 43.55 o 18 6 -4 407.88 345.99 71.55 o 20 6 -4 141.07 147.34 52.27 o 0 8 -4 377.17 306.13 53.86 o 2 8 -4 1158.22 1106.61 121.34 o 4 8 -4 1113.63 1180.16 68.12 o 6 8 -4 176.16 164.28 53.07 o 8 8 -4 327.42 318.22 49.10 o 10 8 -4 919.96 882.87 90.51 o 12 8 -4 154.56 183.36 45.57 o 14 8 -4 577.44 529.32 65.58 o 16 8 -4 121.66 158.35 49.65 o 18 8 -4 375.66 304.72 53.87 o 20 8 -4 42.83 93.26 44.40 o 2 10 -4 6448.58 5778.18 711.43 o 4 10 -4 622.34 576.74 85.61 o 6 10 -4 950.08 992.55 71.50 o 8 10 -4 2028.31 2068.55 294.12 o 10 10 -4 3174.12 3060.82 416.01 o 12 10 -4 1182.79 991.10 134.94 o 14 10 -4 140.67 138.85 28.36 o 16 10 -4 2208.83 2043.84 250.74 o 18 10 -4 339.20 376.03 43.21 o 20 10 -4 333.07 274.87 77.09 o 4 12 -4 2580.65 2438.67 179.76 o 6 12 -4 851.76 756.56 62.65 o 8 12 -4 1745.78 1762.45 137.57 o 10 12 -4 997.11 976.13 116.00 o 12 12 -4 1381.81 1276.58 208.83 o 14 12 -4 514.96 436.58 56.65 o 16 12 -4 3.60 -0.65 30.02 o 18 12 -4 388.50 403.71 65.20 o 4 14 -4 905.75 854.67 116.78 o 6 14 -4 1904.32 1748.68 199.83 o 8 14 -4 748.22 736.27 67.58 o 10 14 -4 552.73 544.10 117.81 o 12 14 -4 225.32 292.64 54.37 o 14 14 -4 681.13 708.53 87.55 o 16 14 -4 348.47 241.56 48.84 o 18 14 -4 177.34 109.84 88.70 o 4 16 -4 5451.92 5484.44 650.25 o 6 16 -4 786.94 934.84 94.82 o 8 16 -4 881.49 923.33 96.39 o 10 16 -4 2501.72 2576.90 410.15 o 12 16 -4 29.21 5.65 46.04 o 14 16 -4 964.41 897.27 233.42 o 16 16 -4 465.11 526.79 129.25 o 6 18 -4 94.62 152.52 47.38 o 8 18 -4 165.70 273.73 72.64 o 10 18 -4 339.42 427.87 89.49 o 12 18 -4 163.67 261.00 76.36 o 14 18 -4 237.70 271.19 72.06 o 16 18 -4 271.06 311.14 110.04 o 6 20 -4 1785.96 2066.91 159.75 o 8 20 -4 507.19 502.73 79.32 o 10 20 -4 399.96 558.11 104.57 o 12 20 -4 472.24 401.46 97.72 o 14 20 -4 94.33 67.74 91.04 o 6 22 -4 52.20 31.83 22.13 o 8 22 -4 63.14 92.02 66.37 o 10 22 -4 21.70 -29.76 70.28 o 12 22 -4 19.36 21.14 110.42 o 6 24 -4 211.49 181.12 35.83 o 8 24 -4 150.72 324.62 91.83 o 1 1 -3 1561.65 1486.23 102.48 o 3 1 -3 18.57 10.98 10.35 o 5 1 -3 3046.80 3158.16 150.99 o 7 1 -3 2300.28 2294.69 113.14 o 9 1 -3 3250.69 3401.51 226.38 o 11 1 -3 6602.38 6623.82 365.40 o 13 1 -3 7788.65 8386.34 500.56 o 15 1 -3 1018.99 1195.60 79.81 o 17 1 -3 2013.09 2004.70 165.67 o 19 1 -3 81.25 33.59 37.40 o 21 1 -3 1070.38 918.85 103.19 o 1 3 -3 1166.97 1128.88 78.15 o 3 3 -3 3642.59 3434.35 189.45 o 5 3 -3 1039.78 977.96 73.08 o 7 3 -3 2754.40 2741.05 187.02 o 9 3 -3 106.19 107.34 26.76 o 11 3 -3 5975.92 6382.94 328.03 o 13 3 -3 3682.43 4111.98 268.02 o 15 3 -3 658.86 625.30 107.74 o 17 3 -3 2472.68 2413.08 267.86 o 19 3 -3 9.20 0.00 58.54 o 21 3 -3 215.91 176.87 88.01 o 1 5 -3 1854.00 1737.71 141.95 o 3 5 -3 1359.03 1347.75 92.40 o 5 5 -3 196.08 202.65 25.23 o 7 5 -3 1416.66 1403.57 160.43 o 9 5 -3 274.08 282.05 46.03 o 11 5 -3 644.96 622.05 43.93 o 13 5 -3 351.69 355.05 47.49 o 15 5 -3 35.05 28.89 27.57 o 17 5 -3 234.56 223.83 66.56 o 19 5 -3 85.65 50.90 36.61 o 21 5 -3 58.00 -29.46 50.92 o 1 7 -3 3078.83 2761.53 305.20 o 3 7 -3 859.14 855.58 112.12 o 5 7 -3 5921.08 5679.02 398.32 o 7 7 -3 963.08 911.51 79.38 o 9 7 -3 461.81 482.62 64.72 o 11 7 -3 2597.11 2675.56 203.62 o 13 7 -3 2012.06 1975.48 114.77 o 15 7 -3 2103.82 1928.38 167.07 o 17 7 -3 553.63 493.16 58.40 o 19 7 -3 278.50 325.57 40.25 o 21 7 -3 37.65 47.96 51.13 o 3 9 -3 966.20 1079.22 77.88 o 5 9 -3 2199.37 2344.63 210.52 o 7 9 -3 482.87 482.76 47.50 o 9 9 -3 916.28 850.26 96.90 o 11 9 -3 429.07 468.44 39.72 o 13 9 -3 1901.84 1870.33 108.71 o 15 9 -3 1046.47 1117.38 77.93 o 17 9 -3 50.45 61.00 21.82 o 19 9 -3 54.97 40.52 39.28 o 21 9 -3 212.55 141.49 48.21 o 3 11 -3 1400.74 1440.65 126.28 o 5 11 -3 581.93 563.74 41.99 o 7 11 -3 364.77 316.03 57.68 o 9 11 -3 458.94 442.02 65.91 o 11 11 -3 4576.52 4585.19 426.67 o 13 11 -3 4298.73 4759.06 459.47 o 15 11 -3 242.43 194.61 33.59 o 17 11 -3 326.08 349.14 90.76 o 19 11 -3 37.45 56.30 35.43 o 21 11 -3 440.16 432.78 87.14 o 3 13 -3 2679.99 2819.53 247.57 o 5 13 -3 97.54 91.45 23.40 o 7 13 -3 2856.80 3068.62 323.73 o 9 13 -3 236.97 215.63 40.83 o 11 13 -3 3411.28 3470.48 556.35 o 13 13 -3 1763.42 1655.81 131.74 o 15 13 -3 626.81 491.25 53.05 o 17 13 -3 2353.40 2669.55 323.57 o 19 13 -3 38.29 41.56 38.52 o 3 15 -3 2174.29 2291.10 195.60 o 5 15 -3 488.85 450.29 62.28 o 7 15 -3 1791.29 1781.30 113.73 o 9 15 -3 337.06 347.51 141.29 o 11 15 -3 2155.79 2043.65 165.46 o 13 15 -3 993.51 945.44 149.39 o 15 15 -3 79.41 105.80 46.60 o 17 15 -3 533.61 494.11 122.50 o 19 15 -3 59.34 23.07 45.06 o 3 17 -3 901.35 976.14 147.15 o 5 17 -3 910.43 901.67 109.72 o 7 17 -3 1676.91 1889.75 169.19 o 9 17 -3 681.77 658.36 76.59 o 11 17 -3 83.10 36.02 52.86 o 13 17 -3 234.51 183.38 43.52 o 15 17 -3 78.39 119.12 49.57 o 17 17 -3 298.38 298.42 129.04 o 3 19 -3 3318.26 3740.84 319.80 o 5 19 -3 170.69 287.63 60.11 o 7 19 -3 417.80 426.43 55.72 o 9 19 -3 46.35 42.48 57.36 o 11 19 -3 192.06 180.14 76.36 o 13 19 -3 121.91 -16.84 78.32 o 15 19 -3 359.63 435.90 84.79 o 5 21 -3 111.66 203.82 51.49 o 7 21 -3 901.89 1023.02 156.14 o 9 21 -3 341.90 274.15 114.75 o 11 21 -3 404.80 504.46 89.10 o 13 21 -3 84.16 135.48 74.01 o 15 21 -3 33.88 -8.42 91.04 o 5 23 -3 91.87 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15 3 77.62 39.26 70.78 o 17 15 3 553.11 546.36 132.49 o 19 15 3 55.61 -2.13 57.58 o 1 17 3 1912.99 1953.60 75.00 o 3 17 3 889.33 866.20 59.83 o 5 17 3 907.87 857.17 55.04 o 7 17 3 1682.37 1589.10 101.22 o 9 17 3 672.24 575.56 111.47 o 11 17 3 79.89 98.54 33.70 o 13 17 3 249.89 312.08 57.18 o 15 17 3 80.27 118.92 39.98 o 17 17 3 315.40 206.05 60.27 o 1 19 3 1539.68 1494.93 87.62 o 3 19 3 3313.12 3630.87 191.05 o 5 19 3 170.00 146.91 26.15 o 7 19 3 423.96 303.06 36.18 o 9 19 3 50.72 47.51 22.55 o 11 19 3 201.85 156.03 37.58 o 13 19 3 114.42 21.22 31.91 o 15 19 3 357.18 297.65 82.44 o 1 21 3 155.38 132.66 25.17 o 3 21 3 68.94 66.33 19.49 o 5 21 3 111.56 81.24 27.33 o 7 21 3 885.07 869.76 59.11 o 9 21 3 339.83 342.47 61.15 o 11 21 3 405.42 433.27 88.18 o 13 21 3 80.79 31.20 38.17 o 15 21 3 33.36 -2.31 92.50 o 1 23 3 129.21 169.85 25.56 o 3 23 3 94.89 73.56 23.93 o 5 23 3 91.39 75.42 26.78 o 7 23 3 136.04 109.51 26.86 o 9 23 3 300.41 305.78 36.97 o 11 23 3 330.95 306.90 46.47 o 13 23 3 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111.50 o 10 10 4 3206.65 3623.81 180.12 o 12 10 4 1188.37 1320.48 132.12 o 14 10 4 149.19 163.87 32.62 o 16 10 4 2196.06 2492.29 256.10 o 18 10 4 343.99 381.62 71.71 o 20 10 4 340.65 511.34 98.69 o 0 12 4 3426.72 3299.80 205.59 o 2 12 4 1139.35 1149.74 51.43 o 4 12 4 2612.48 2651.80 124.83 o 6 12 4 852.63 821.84 36.12 o 8 12 4 1742.66 2024.09 86.76 o 10 12 4 974.03 1050.93 75.71 o 12 12 4 1373.50 1560.50 104.59 o 14 12 4 514.21 410.76 65.56 o 16 12 4 5.28 44.39 54.03 o 18 12 4 383.70 236.75 117.30 o 0 14 4 7226.61 7809.94 611.58 o 2 14 4 1.16 -5.50 11.27 o 4 14 4 947.40 1009.46 59.12 o 6 14 4 1903.12 1968.64 104.66 o 8 14 4 761.52 702.56 66.36 o 10 14 4 530.76 497.93 49.16 o 12 14 4 226.86 218.48 50.83 o 14 14 4 658.25 603.72 83.19 o 16 14 4 348.67 435.07 73.30 o 18 14 4 181.69 72.37 53.71 o 0 16 4 5474.63 5965.02 464.80 o 2 16 4 1567.29 1625.39 63.22 o 4 16 4 5483.02 5457.81 304.18 o 6 16 4 786.69 770.77 57.10 o 8 16 4 900.86 857.21 73.06 o 10 16 4 2477.19 2325.80 276.12 o 12 16 4 29.62 41.12 28.66 o 14 16 4 941.15 1004.32 103.04 o 16 16 4 479.71 341.77 103.60 o 0 18 4 709.32 715.23 58.12 o 2 18 4 44.59 58.98 19.32 o 4 18 4 829.11 725.40 103.80 o 6 18 4 105.15 114.69 30.10 o 8 18 4 163.71 178.02 27.53 o 10 18 4 336.62 323.77 40.85 o 12 18 4 160.65 167.53 36.81 o 14 18 4 242.35 180.02 72.25 o 16 18 4 274.37 273.52 68.83 o 0 20 4 633.83 641.04 68.57 o 2 20 4 1281.29 1302.18 69.80 o 4 20 4 1485.85 1408.65 83.02 o 6 20 4 1782.60 1707.07 112.21 o 8 20 4 499.24 436.24 46.55 o 10 20 4 412.42 395.27 51.36 o 12 20 4 475.57 450.46 76.47 o 14 20 4 99.65 103.50 54.87 o 0 22 4 444.06 382.50 96.06 o 2 22 4 61.00 34.47 20.97 o 4 22 4 116.16 90.89 32.94 o 6 22 4 51.22 51.79 29.20 o 8 22 4 62.56 50.00 32.21 o 10 22 4 21.79 79.98 52.63 o 12 22 4 19.53 26.78 77.53 o 0 24 4 829.61 796.40 216.65 o 2 24 4 46.93 48.73 26.99 o 4 24 4 537.47 458.28 65.87 o 6 24 4 211.91 180.51 36.77 o 8 24 4 151.99 157.87 39.93 o 0 26 4 997.98 872.94 145.36 o 2 26 4 110.88 -33.01 58.42 o 4 26 4 334.64 250.50 147.55 o 1 1 5 1051.74 1058.10 70.07 o 3 1 5 1274.79 1130.38 87.50 o 5 1 5 534.27 525.23 37.90 o 7 1 5 2478.23 2542.17 126.88 o 9 1 5 890.94 897.57 93.01 o 11 1 5 1241.65 1172.29 75.01 o 13 1 5 813.26 919.45 73.60 o 15 1 5 656.83 706.75 84.18 o 17 1 5 935.87 1009.15 90.09 o 19 1 5 126.89 76.95 27.99 o 1 3 5 2026.17 1962.24 135.33 o 3 3 5 2462.05 2580.84 152.26 o 5 3 5 708.65 682.26 48.50 o 7 3 5 1329.02 1286.92 77.16 o 9 3 5 220.21 210.74 37.65 o 11 3 5 959.44 1068.34 69.50 o 13 3 5 717.28 773.60 74.72 o 15 3 5 67.02 48.06 27.07 o 17 3 5 1115.03 1258.31 117.76 o 19 3 5 285.77 232.63 38.30 o 1 5 5 541.20 523.52 43.68 o 3 5 5 160.35 123.98 30.93 o 5 5 5 67.06 73.93 24.90 o 7 5 5 310.02 355.23 36.14 o 9 5 5 353.08 435.75 48.74 o 11 5 5 769.63 862.51 66.78 o 13 5 5 386.11 579.22 67.84 o 15 5 5 8.53 -3.70 21.95 o 17 5 5 74.70 126.87 32.38 o 19 5 5 91.64 63.34 50.92 o 1 7 5 1604.67 1585.26 64.63 o 3 7 5 458.16 388.32 37.13 o 5 7 5 177.36 153.89 30.07 o 7 7 5 387.84 383.14 40.18 o 9 7 5 2056.10 2147.75 136.48 o 11 7 5 880.92 883.92 75.99 o 13 7 5 382.07 473.58 44.02 o 15 7 5 982.69 1031.49 70.95 o 17 7 5 339.55 354.15 41.09 o 19 7 5 267.45 156.58 43.34 o 1 9 5 388.22 462.01 29.84 o 3 9 5 64.28 92.40 20.04 o 5 9 5 600.02 659.31 54.71 o 7 9 5 538.64 460.46 53.20 o 9 9 5 150.34 164.58 26.46 o 11 9 5 66.77 67.59 23.47 o 13 9 5 172.39 176.16 26.91 o 15 9 5 14.66 14.29 24.40 o 17 9 5 48.39 36.10 32.00 o 19 9 5 146.73 204.73 48.52 o 1 11 5 105.16 78.54 59.16 o 3 11 5 1155.57 1179.55 60.56 o 5 11 5 1139.72 1230.54 116.73 o 7 11 5 419.41 410.45 37.26 o 9 11 5 1305.68 1549.61 122.45 o 11 11 5 403.30 389.15 32.12 o 13 11 5 1191.49 1398.30 80.12 o 15 11 5 153.68 128.86 31.34 o 17 11 5 196.61 160.89 44.98 o 1 13 5 1595.16 1761.16 78.73 o 3 13 5 1385.87 1427.16 128.53 o 5 13 5 242.42 201.70 22.52 o 7 13 5 1093.76 1170.98 83.34 o 9 13 5 11.93 -16.55 19.78 o 11 13 5 1396.03 1487.80 84.58 o 13 13 5 407.39 510.01 53.34 o 15 13 5 81.40 110.77 42.23 o 17 13 5 1479.72 1144.48 160.68 o 1 15 5 832.49 920.26 50.86 o 3 15 5 380.29 421.84 48.23 o 5 15 5 225.89 265.59 31.39 o 7 15 5 700.40 823.43 88.60 o 9 15 5 757.83 836.84 77.77 o 11 15 5 1516.91 1533.29 120.47 o 13 15 5 727.54 836.54 69.21 o 15 15 5 96.22 118.36 52.20 o 1 17 5 692.62 726.30 41.90 o 3 17 5 45.33 63.90 15.05 o 5 17 5 196.86 162.64 37.23 o 7 17 5 556.22 586.24 66.07 o 9 17 5 789.53 723.58 67.01 o 11 17 5 317.13 367.86 44.35 o 13 17 5 126.03 158.46 45.07 o 1 19 5 9.50 -6.37 16.63 o 3 19 5 2078.35 2170.43 146.22 o 5 19 5 136.72 130.86 35.99 o 7 19 5 228.94 198.29 35.01 o 9 19 5 128.23 125.53 71.14 o 11 19 5 24.39 -19.24 52.40 o 13 19 5 727.91 636.04 297.52 o 1 21 5 80.04 75.69 25.28 o 3 21 5 43.82 10.44 29.43 o 5 21 5 171.37 139.30 27.76 o 7 21 5 505.67 420.46 54.17 o 9 21 5 245.36 154.27 98.00 o 1 23 5 212.44 182.04 36.74 o 3 23 5 269.81 197.55 44.97 o 5 23 5 287.74 209.63 46.20 o 7 23 5 331.36 255.09 58.29 o 0 0 6 2510.03 2766.85 305.73 o 2 0 6 3699.30 3942.60 424.91 o 4 0 6 11322.71 13131.38 1449.88 o 6 0 6 1626.77 1947.00 193.31 o 8 0 6 1329.20 1316.68 164.83 o 10 0 6 184.33 186.89 35.52 o 12 0 6 44.23 37.65 26.89 o 14 0 6 1952.51 2155.97 218.60 o 16 0 6 586.69 516.07 91.46 o 18 0 6 171.27 89.09 79.30 o 0 2 6 6178.39 6163.61 544.03 o 2 2 6 248.14 303.07 38.03 o 4 2 6 4606.34 4831.09 361.58 o 6 2 6 1122.12 1182.85 85.77 o 8 2 6 325.74 316.83 47.97 o 10 2 6 403.09 346.44 40.67 o 12 2 6 361.33 351.97 41.69 o 14 2 6 302.67 276.94 37.05 o 16 2 6 407.06 341.79 50.06 o 18 2 6 121.88 140.11 48.28 o 0 4 6 3007.21 2893.92 234.31 o 2 4 6 731.78 715.64 56.74 o 4 4 6 384.37 430.81 37.84 o 6 4 6 924.77 936.53 77.44 o 8 4 6 28.53 -3.68 30.30 o 10 4 6 730.46 748.96 70.21 o 12 4 6 2.06 3.82 26.21 o 14 4 6 147.26 152.09 46.14 o 16 4 6 338.40 367.53 51.81 o 18 4 6 22.72 13.19 66.96 o 0 6 6 111.37 139.35 51.59 o 2 6 6 245.20 219.65 37.62 o 4 6 6 180.47 174.71 42.08 o 6 6 6 270.52 276.09 44.63 o 8 6 6 358.93 411.70 41.06 o 10 6 6 584.64 589.76 54.23 o 12 6 6 85.08 81.86 27.76 o 14 6 6 479.98 547.92 48.79 o 16 6 6 219.47 203.51 45.78 o 0 8 6 11.81 2.89 38.38 o 2 8 6 250.08 215.40 33.35 o 4 8 6 186.53 139.14 32.47 o 6 8 6 591.97 572.73 48.28 o 8 8 6 618.54 678.50 69.39 o 10 8 6 151.53 173.19 60.25 o 12 8 6 158.64 166.20 30.66 o 14 8 6 149.21 163.85 31.52 o 16 8 6 5.58 6.32 37.59 o 0 10 6 7812.45 8526.89 616.47 o 2 10 6 871.71 877.71 70.21 o 4 10 6 517.83 466.41 65.48 o 6 10 6 290.28 310.83 46.23 o 8 10 6 154.60 140.60 29.45 o 10 10 6 3012.92 3115.18 357.21 o 12 10 6 163.00 153.72 34.24 o 14 10 6 318.13 215.64 59.09 o 16 10 6 718.94 633.58 81.97 o 0 12 6 508.41 491.72 51.40 o 2 12 6 105.76 117.87 27.59 o 4 12 6 946.02 1057.79 105.66 o 6 12 6 659.84 577.92 67.57 o 8 12 6 226.37 232.11 28.99 o 10 12 6 386.87 380.87 38.49 o 12 12 6 313.77 403.80 63.65 o 14 12 6 120.51 144.02 35.03 o 0 14 6 2054.44 2310.20 159.17 o 2 14 6 290.01 323.48 29.24 o 4 14 6 369.18 347.32 32.58 o 6 14 6 916.21 930.61 66.72 o 8 14 6 297.99 323.67 106.64 o 10 14 6 1062.79 1210.47 102.05 o 12 14 6 128.85 164.92 31.87 o 14 14 6 389.91 342.14 61.74 o 0 16 6 1061.58 1122.18 117.32 o 2 16 6 365.54 367.53 53.86 o 4 16 6 303.70 348.62 30.16 o 6 16 6 921.08 1024.63 128.67 o 8 16 6 121.97 167.24 20.91 o 10 16 6 1641.08 1778.85 243.97 o 12 16 6 98.05 185.98 68.56 o 0 18 6 69.85 17.35 25.47 o 2 18 6 31.33 51.46 25.13 o 4 18 6 548.96 563.85 45.79 o 6 18 6 176.31 127.59 36.76 o 8 18 6 71.45 17.05 47.44 o 10 18 6 421.19 347.25 76.48 o 0 20 6 108.18 109.46 25.33 o 2 20 6 39.35 54.72 25.01 o 4 20 6 1889.11 1338.54 192.50 o 6 20 6 292.99 249.53 64.60 o 8 20 6 78.39 39.39 47.76 o 2 22 6 9.78 165.43 116.68 o 1 1 7 173.85 223.55 30.38 o 3 1 7 505.51 404.13 50.76 o 5 1 7 194.29 260.50 45.61 o 7 1 7 1250.02 1417.35 133.79 o 9 1 7 147.06 155.75 46.85 o 11 1 7 428.95 535.58 62.83 o 13 1 7 247.56 216.12 39.97 o 15 1 7 204.95 106.72 58.63 o 1 3 7 198.27 152.54 30.88 o 3 3 7 656.68 662.79 58.90 o 5 3 7 253.10 235.56 63.35 o 7 3 7 587.88 587.84 69.18 o 9 3 7 120.24 182.19 46.08 o 11 3 7 318.87 406.87 44.62 o 13 3 7 472.07 527.93 66.33 o 15 3 7 129.36 129.36 48.03 o 1 5 7 35.41 43.48 29.44 o 3 5 7 70.42 65.45 29.46 o 5 5 7 9.72 1.47 30.65 o 7 5 7 41.69 35.49 31.73 o 9 5 7 71.76 112.33 33.03 o 11 5 7 288.72 345.68 59.27 o 13 5 7 233.28 238.77 39.71 o 15 5 7 32.46 -36.91 43.55 o 1 7 7 213.15 303.75 82.71 o 3 7 7 36.74 76.68 33.15 o 5 7 7 72.53 4.54 31.99 o 7 7 7 251.80 237.84 35.09 o 9 7 7 1109.77 1164.80 163.60 o 11 7 7 116.03 138.86 45.74 o 13 7 7 184.86 197.76 45.46 o 1 9 7 151.27 92.10 27.50 o 3 9 7 8.06 22.13 26.45 o 5 9 7 27.89 -6.85 26.73 o 7 9 7 224.14 282.27 41.95 o 9 9 7 126.57 123.94 30.98 o 11 9 7 94.75 81.77 35.04 o 13 9 7 53.61 2.65 42.57 o 1 11 7 68.81 74.08 24.79 o 3 11 7 134.44 221.08 35.06 o 5 11 7 76.95 67.21 34.08 o 7 11 7 478.61 519.04 72.72 o 9 11 7 70.05 24.02 29.37 o 11 11 7 227.62 163.11 45.83 o 1 13 7 196.23 180.39 23.78 o 3 13 7 220.30 219.25 55.68 o 5 13 7 20.86 29.24 26.32 o 7 13 7 282.89 321.53 56.72 o 9 13 7 78.59 66.28 40.41 o 11 13 7 582.66 453.35 65.13 o 1 15 7 121.98 134.48 26.67 o 3 15 7 309.38 334.79 67.40 o 5 15 7 50.33 42.31 80.17 o 7 15 7 186.59 172.44 35.29 o 9 15 7 883.94 982.18 140.26 o 1 17 7 427.74 454.85 61.92 o 3 17 7 118.97 149.44 36.83 o 5 17 7 251.08 201.48 79.30 o 7 17 7 415.97 524.62 124.35 o 1 19 7 84.52 105.33 46.40 o 0 0 8 865.81 985.75 156.13 o 2 0 8 173.36 137.81 54.53 o 4 0 8 2208.96 2080.20 222.02 o 6 0 8 3823.37 4846.27 748.89 o 8 0 8 61.70 54.43 76.55 o 10 0 8 568.40 634.94 102.04 o 0 2 8 225.56 212.71 59.65 o 2 2 8 295.28 361.51 45.95 o 4 2 8 101.18 72.72 37.53 o 6 2 8 240.92 380.40 64.46 o 8 2 8 259.04 279.95 64.82 o 10 2 8 383.88 455.67 80.45 o 0 4 8 268.70 223.42 63.54 o 2 4 8 341.38 308.51 52.35 o 4 4 8 639.75 584.08 66.81 o 6 4 8 184.04 221.49 65.27 o 8 4 8 151.55 33.37 59.38 o 10 4 8 474.35 450.85 210.42 o 0 6 8 290.40 237.80 49.52 o 2 6 8 71.22 91.54 30.77 o 4 6 8 23.09 17.58 38.22 o 6 6 8 223.54 224.78 58.45 o 8 6 8 28.55 -33.79 56.78 o 10 6 8 244.27 272.34 79.75 o 0 8 8 538.50 518.18 92.21 o 2 8 8 23.38 61.32 33.33 o 4 8 8 233.60 246.63 59.60 o 6 8 8 452.95 386.34 56.26 o 8 8 8 328.96 294.79 62.52 o 10 8 8 0.17 34.74 59.49 o 0 10 8 871.47 853.10 144.96 o 2 10 8 270.54 289.79 54.06 o 4 10 8 50.89 31.52 47.42 o 6 10 8 94.16 87.36 41.52 o 8 10 8 503.62 469.96 90.90 o 0 12 8 11.54 90.25 63.63 o 2 12 8 24.33 32.87 50.34 o 4 12 8 228.50 132.65 75.29 o 6 12 8 713.41 684.14 72.45 o 0 14 8 454.79 381.09 79.51 o 2 14 8 222.64 274.65 83.22 o 3 1 9 92.44 31.33 48.22 o 1 3 9 27.78 89.47 79.09 o 3 3 9 29.99 77.50 47.41 o 1 5 9 37.44 5.79 60.49 o 3 5 9 78.01 23.69 68.53 o