#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/10/40/2104030.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2104030_Fobs loop_ _publ_author_name 'Redhammer, G\"unther J.' 'Ohashi, Haruo' 'Roth, Georg' _publ_section_title ; Single-crystal structure refinement of NaTiSi~2~O~6~ clinopyroxene at low temperatures (298<T<100K) ; _journal_issue 6 _journal_name_full 'Acta Crystallographica Section B' _journal_page_first 730 _journal_page_last 746 _journal_volume 59 _journal_year 2003 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 106.754 _cell_angle_gamma 90.000 _cell_length_a 9.6995 _cell_length_b 8.8833 _cell_length_c 5.3059 _exptl_crystal_F_000 436.00 _reflns_d_resolution_high 0.6721 _[local]_cod_data_source_file ws5001298sup2.hkl _[local]_cod_data_source_block 298 #BEGIN Tags that were not found in dictionaries: _shelx_title ' NaTiSi2O6 Haruo OHASI' _shelx_refln_list_code 4 _shelx_F_calc_maximum 157.85 _shelx_F_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 147.61 144.20 19.01 o 8 0 0 4803.16 4654.57 28.13 o 10 0 0 3815.56 4067.89 29.55 o 1 1 0 1238.92 1186.01 27.61 o 5 1 0 1811.47 1973.07 13.26 o 7 1 0 3887.61 3884.58 15.81 o 9 1 0 384.08 403.23 11.76 o 11 1 0 1219.23 1258.89 21.05 o 0 2 0 4418.96 4290.88 31.68 o 2 2 0 1534.72 1387.64 48.73 o 4 2 0 24.74 25.52 7.87 o 6 2 0 3.88 10.59 7.65 o 8 2 0 51.64 58.84 8.27 o 10 2 0 357.38 387.49 12.24 o 12 2 0 91.04 97.91 12.91 o 1 3 0 220.80 262.45 9.10 o 3 3 0 1524.32 1549.28 12.64 o 5 3 0 134.20 121.16 7.49 o 7 3 0 556.17 567.10 11.48 o 9 3 0 178.05 175.55 9.25 o 11 3 0 34.85 36.97 10.28 o 13 3 0 184.87 173.20 14.88 o 2 4 0 352.73 388.56 12.08 o 4 4 0 8550.54 8581.12 50.81 o 6 4 0 6.60 8.68 7.03 o 8 4 0 10.66 13.47 7.58 o 10 4 0 4507.26 4463.58 71.44 o 12 4 0 4.79 6.10 11.50 o 1 5 0 9999.57 9778.59 375.61 o 3 5 0 6012.67 5898.88 172.77 o 5 5 0 39.00 39.09 7.03 o 7 5 0 13216.50 13448.55 276.38 o 9 5 0 352.06 364.97 10.92 o 11 5 0 1029.55 1030.50 27.36 o 0 6 0 14219.29 12795.42 29.64 o 2 6 0 182.13 220.07 25.95 o 4 6 0 925.52 987.09 33.23 o 6 6 0 288.77 291.52 11.05 o 8 6 0 405.61 411.51 10.92 o 10 6 0 3446.55 3504.55 27.43 o 12 6 0 568.09 565.29 25.25 o 1 7 0 404.37 417.40 8.63 o 3 7 0 4.90 1.97 12.64 o 5 7 0 2032.92 2088.25 99.27 o 7 7 0 2800.23 2793.05 65.28 o 9 7 0 67.53 67.02 7.71 o 11 7 0 0.35 -3.79 9.55 o 0 8 0 24.45 26.07 10.95 o 2 8 0 18.11 17.82 6.70 o 4 8 0 635.66 628.66 27.08 o 6 8 0 253.87 250.65 6.44 o 8 8 0 84.48 95.53 7.49 o 10 8 0 676.58 721.49 24.98 o 1 9 0 88.81 96.02 7.21 o 3 9 0 1804.84 1787.70 54.01 o 5 9 0 136.00 152.83 8.23 o 7 9 0 413.09 430.50 7.92 o 9 9 0 126.77 129.70 9.82 o 0 10 0 5445.91 5547.32 19.93 o 2 10 0 201.75 224.56 18.13 o 4 10 0 2714.61 2818.20 166.69 o 6 10 0 1244.21 1201.88 26.41 o 8 10 0 320.43 330.40 19.70 o 1 11 0 115.15 117.17 15.91 o 3 11 0 2491.80 2495.89 104.16 o 5 11 0 275.59 283.44 16.02 o 7 11 0 1503.66 1500.38 47.38 o 0 12 0 3874.28 3826.54 17.27 o 2 12 0 452.12 455.04 9.11 o 4 12 0 36.91 69.30 14.62 o 1 13 0 4.10 30.25 10.57 o -9 1 1 249.44 249.72 13.20 o -7 1 1 57.72 56.99 11.33 o -5 1 1 2262.72 2172.61 25.84 o -3 1 1 2389.10 2414.37 42.22 o -1 1 1 1734.69 1789.04 32.51 o 1 1 1 1244.07 1270.02 25.23 o 3 1 1 2300.58 2399.67 45.26 o 5 1 1 1292.62 1325.33 8.00 o 7 1 1 1.02 10.78 6.53 o 9 1 1 493.47 518.57 8.03 o 11 1 1 98.99 94.61 11.41 o 13 1 1 117.52 115.12 17.27 o -10 2 1 7.37 6.46 10.99 o -8 2 1 2928.42 2862.51 61.90 o -6 2 1 2464.48 2164.82 14.57 o -4 2 1 5745.42 5427.41 28.58 o 0 2 1 461.93 510.72 9.69 o 2 2 1 14602.39 14126.02 139.87 o 4 2 1 2500.50 2488.91 31.87 o 6 2 1 5067.95 4896.55 23.35 o 8 2 1 3174.24 3328.71 49.13 o 10 2 1 55.27 55.39 8.17 o 12 2 1 3352.99 3357.45 29.68 o -11 3 1 1989.03 1961.48 15.53 o -9 3 1 4597.31 4478.39 79.10 o -7 3 1 1753.89 1637.66 31.22 o -3 3 1 9548.94 9729.49 32.69 o -1 3 1 7539.50 6689.85 227.55 o 3 3 1 1908.24 1895.66 12.95 o 5 3 1 24915.64 24219.36 44.93 o 7 3 1 269.60 260.01 6.99 o 9 3 1 2203.26 2246.33 34.56 o 11 3 1 706.34 688.31 10.14 o -12 4 1 2363.09 2349.00 16.56 o -10 4 1 243.17 256.02 9.74 o -8 4 1 154.21 162.57 9.28 o -6 4 1 1.04 3.48 9.20 o -4 4 1 275.56 277.03 9.15 o -2 4 1 4351.65 4568.49 115.57 o 0 4 1 5913.21 5484.84 327.85 o 2 4 1 1591.72 1541.30 29.39 o 4 4 1 5.49 12.23 6.06 o 6 4 1 487.68 502.02 7.39 o 8 4 1 419.81 447.52 11.50 o 10 4 1 589.14 589.56 9.13 o 12 4 1 1181.83 1210.90 31.50 o -13 5 1 52.37 41.47 13.80 o -11 5 1 30.81 26.94 10.18 o -9 5 1 21.66 13.48 10.98 o -7 5 1 16.75 17.69 8.77 o -5 5 1 471.75 468.92 10.86 o -3 5 1 424.85 411.08 8.76 o -1 5 1 636.33 627.75 8.74 o 1 5 1 113.23 103.48 7.18 o 3 5 1 846.30 810.67 21.24 o 5 5 1 646.36 662.11 15.03 o 7 5 1 7.36 10.15 6.35 o 9 5 1 22.70 21.33 7.28 o 11 5 1 134.60 127.71 9.46 o -12 6 1 86.90 74.43 11.72 o -10 6 1 5.46 6.81 12.43 o -8 6 1 326.40 315.16 15.88 o -6 6 1 3.99 4.79 8.54 o -4 6 1 32.22 36.31 7.41 o -2 6 1 438.26 396.74 17.05 o 0 6 1 56.07 51.25 6.54 o 2 6 1 127.19 96.87 8.17 o 4 6 1 2.54 3.08 6.55 o 6 6 1 45.27 49.52 6.34 o 8 6 1 49.37 45.65 6.72 o 10 6 1 18.53 19.18 7.37 o -11 7 1 379.58 357.99 18.81 o -9 7 1 1480.09 1444.36 26.91 o -7 7 1 281.73 286.58 9.39 o -5 7 1 6959.54 6773.83 98.94 o -3 7 1 31.36 52.86 12.87 o -1 7 1 3910.82 3687.78 69.43 o 1 7 1 5337.03 5371.78 166.94 o 3 7 1 158.50 181.78 5.91 o 5 7 1 3708.26 3665.67 55.66 o 7 7 1 425.51 419.62 11.66 o 9 7 1 2526.00 2602.62 57.73 o -10 8 1 1.29 0.15 8.29 o -8 8 1 2194.01 2173.68 51.30 o -6 8 1 829.01 837.47 9.75 o -4 8 1 722.69 708.76 8.89 o -2 8 1 8853.17 8900.87 68.53 o 0 8 1 126.82 140.43 29.62 o 2 8 1 4706.84 4959.18 314.72 o 4 8 1 570.54 578.80 26.37 o 6 8 1 2429.01 2531.35 65.36 o 8 8 1 1470.89 1430.31 35.93 o 10 8 1 36.24 32.67 8.65 o -9 9 1 552.42 547.91 9.11 o -7 9 1 1973.48 2022.84 44.47 o -5 9 1 3308.64 3344.72 18.01 o -3 9 1 30.40 37.45 13.60 o -1 9 1 89.75 103.49 7.10 o 1 9 1 25.70 12.22 7.16 o 3 9 1 34.53 32.81 7.67 o 5 9 1 3478.71 3469.42 138.67 o 7 9 1 707.05 741.10 32.48 o 9 9 1 447.73 463.43 14.58 o -8 10 1 83.70 84.79 8.46 o -6 10 1 45.86 55.89 7.92 o -4 10 1 9.10 15.81 7.46 o -2 10 1 1495.83 1498.56 48.46 o 0 10 1 1040.15 1089.42 41.16 o 2 10 1 146.96 156.57 8.36 o 4 10 1 20.66 33.05 6.09 o 6 10 1 228.81 231.99 6.96 o 8 10 1 5.58 2.08 7.53 o -7 11 1 62.37 63.04 11.68 o -5 11 1 38.24 52.12 8.50 o -3 11 1 176.73 181.13 8.22 o -1 11 1 31.42 32.05 7.92 o 1 11 1 3.49 1.82 6.61 o 3 11 1 181.46 183.71 11.38 o 5 11 1 29.68 32.42 7.98 o -6 12 1 714.01 703.21 10.70 o -4 12 1 521.78 467.63 39.38 o -2 12 1 1101.99 1089.23 22.11 o 0 12 1 248.56 234.00 14.91 o 2 12 1 2129.12 2160.51 14.43 o 4 12 1 297.35 307.69 8.13 o -1 13 1 1642.35 1644.88 54.50 o 1 13 1 1089.52 1125.57 9.01 o 2 0 2 6590.07 7026.82 34.67 o 4 0 2 11545.72 11774.18 52.88 o 6 0 2 230.54 272.62 12.91 o 8 0 2 936.96 960.15 10.22 o 10 0 2 7790.70 7883.21 27.66 o 12 0 2 12.59 22.29 17.03 o -5 1 2 51.82 48.69 8.30 o -1 1 2 373.44 356.03 6.97 o 1 1 2 8390.90 9253.16 203.47 o 3 1 2 3537.41 3411.71 36.10 o 5 1 2 1373.09 1349.79 17.57 o 7 1 2 5099.35 5257.28 53.76 o 9 1 2 6.65 5.30 7.05 o 11 1 2 824.18 844.15 11.79 o -10 2 2 1904.93 1930.63 56.96 o -8 2 2 187.05 176.48 10.13 o -6 2 2 1017.81 1036.75 16.87 o -4 2 2 1841.16 1911.57 11.36 o -2 2 2 1.39 -0.44 6.18 o 0 2 2 1414.65 1657.87 53.58 o 2 2 2 608.06 551.85 5.96 o 4 2 2 3715.96 3888.83 66.74 o 6 2 2 546.12 525.19 6.17 o 8 2 2 924.35 920.85 14.08 o 10 2 2 1310.31 1312.71 14.63 o 12 2 2 2.18 0.46 15.30 o -11 3 2 107.88 107.19 12.85 o -9 3 2 45.88 40.07 10.02 o -7 3 2 283.22 267.80 12.26 o -5 3 2 209.16 219.92 6.80 o -3 3 2 1086.62 1240.83 25.37 o -1 3 2 614.28 619.61 7.99 o 1 3 2 1137.80 1224.59 10.06 o 3 3 2 359.83 405.06 5.63 o 5 3 2 11.43 11.94 6.59 o 7 3 2 117.20 122.17 6.51 o 9 3 2 0.35 9.53 7.09 o 11 3 2 106.84 111.64 9.26 o -12 4 2 10.22 6.97 12.87 o -10 4 2 1599.29 1553.69 31.21 o -8 4 2 132.84 130.75 11.18 o -6 4 2 1492.41 1456.80 25.89 o -4 4 2 1314.46 1306.38 20.62 o -2 4 2 1.46 7.16 5.77 o 0 4 2 6790.74 6744.81 185.43 o 2 4 2 56.30 67.45 6.14 o 4 4 2 2324.13 2331.60 17.49 o 6 4 2 691.23 721.41 6.83 o 8 4 2 25.40 24.04 6.56 o 10 4 2 1019.95 1017.17 20.26 o -13 5 2 738.95 659.86 29.39 o -11 5 2 1164.30 1132.91 12.41 o -9 5 2 696.81 673.20 14.46 o -7 5 2 8056.42 8131.02 115.48 o -5 5 2 78.23 98.15 7.34 o -3 5 2 13903.83 13451.80 79.89 o -1 5 2 800.82 712.82 20.00 o 1 5 2 3246.35 3185.67 47.78 o 3 5 2 15100.06 15223.09 94.55 o 5 5 2 15.06 20.31 6.29 o 7 5 2 3361.87 3369.85 40.87 o 9 5 2 365.10 384.09 8.52 o 11 5 2 3131.95 3055.39 37.20 o -12 6 2 170.75 177.52 11.74 o -10 6 2 475.65 441.68 9.45 o -8 6 2 150.30 146.21 8.61 o -6 6 2 5922.72 5736.68 27.05 o -4 6 2 207.87 224.61 6.84 o -2 6 2 3831.97 3825.71 68.26 o 0 6 2 16051.32 16130.24 157.14 o 2 6 2 62.81 58.82 6.04 o 4 6 2 428.87 459.14 6.90 o 6 6 2 104.47 108.82 6.55 o 8 6 2 493.51 493.47 10.18 o 10 6 2 1764.27 1787.83 19.38 o -11 7 2 6.62 17.75 13.08 o -9 7 2 32.71 44.02 9.31 o -7 7 2 1194.16 1178.44 9.21 o -5 7 2 702.57 665.06 18.81 o -3 7 2 850.58 842.65 19.53 o -1 7 2 754.89 700.57 13.15 o 1 7 2 1.05 8.00 5.77 o 3 7 2 2050.10 2064.72 81.45 o 5 7 2 1064.27 1062.04 27.85 o 7 7 2 118.97 128.22 11.22 o 9 7 2 11.99 23.15 8.03 o -10 8 2 2.84 11.20 19.99 o -8 8 2 0.12 -0.02 7.44 o -6 8 2 98.48 92.37 6.21 o -4 8 2 1.08 10.48 6.47 o -2 8 2 88.98 90.07 8.00 o 0 8 2 392.12 382.29 20.81 o 2 8 2 12.08 8.74 5.79 o 4 8 2 84.71 78.96 6.23 o 6 8 2 1.98 1.38 6.49 o 8 8 2 73.06 77.25 7.64 o -9 9 2 15.25 20.45 9.50 o -7 9 2 1344.36 1342.68 18.15 o -5 9 2 95.42 94.27 6.49 o -3 9 2 400.24 361.00 16.25 o -1 9 2 525.70 517.77 11.43 o 1 9 2 752.62 795.25 22.39 o 3 9 2 210.59 216.09 6.20 o 5 9 2 46.32 58.16 7.17 o 7 9 2 1581.44 1654.59 36.62 o -8 10 2 226.79 225.35 11.69 o -6 10 2 448.61 439.82 39.77 o -4 10 2 3516.86 3443.43 87.54 o -2 10 2 721.10 723.94 9.11 o 0 10 2 2377.46 2319.44 83.57 o 2 10 2 107.42 107.86 10.22 o 4 10 2 4798.32 4906.49 165.32 o 6 10 2 513.22 538.62 26.97 o -7 11 2 3241.80 3232.53 83.11 o -5 11 2 83.16 99.70 7.35 o -3 11 2 999.74 1003.08 21.47 o -1 11 2 60.40 47.64 6.88 o 1 11 2 686.60 662.67 31.76 o 3 11 2 1385.69 1397.64 77.62 o 5 11 2 186.65 205.90 10.04 o -4 12 2 137.29 130.61 8.03 o -2 12 2 788.34 805.26 16.00 o 0 12 2 1219.28 1232.34 16.61 o 2 12 2 13.44 2.07 7.89 o -7 1 3 118.63 129.52 9.49 o -5 1 3 2217.46 2207.21 23.87 o -3 1 3 1697.95 1779.73 15.15 o -1 1 3 581.20 604.77 6.11 o 1 1 3 1106.32 1127.93 6.31 o 3 1 3 555.80 558.65 5.76 o 5 1 3 191.87 200.01 5.28 o 7 1 3 8.17 11.13 6.19 o 9 1 3 1123.64 1125.53 12.81 o 11 1 3 89.73 89.93 8.87 o -10 2 3 114.75 105.70 15.04 o -8 2 3 5262.08 5274.55 28.91 o -6 2 3 461.25 444.87 8.42 o -4 2 3 1154.51 1059.92 14.33 o -2 2 3 17884.56 18854.67 37.90 o 0 2 3 289.10 254.39 5.70 o 2 2 3 7322.28 7580.36 46.65 o 4 2 3 66.05 83.91 5.39 o 6 2 3 3515.70 3539.31 21.07 o 8 2 3 2871.56 2875.07 30.08 o 10 2 3 1.27 1.76 8.06 o -11 3 3 2016.06 1950.31 19.62 o -9 3 3 6889.33 6981.07 31.07 o -7 3 3 794.29 779.41 12.45 o -5 3 3 6213.96 6227.57 146.54 o -3 3 3 2035.89 2016.61 56.00 o -1 3 3 13462.80 14485.56 225.35 o 1 3 3 961.58 864.27 8.93 o 3 3 3 1.77 5.84 5.05 o 5 3 3 10448.85 10784.51 144.55 o 7 3 3 22.36 31.59 6.53 o 9 3 3 2659.73 2671.39 22.88 o -12 4 3 1230.02 1221.47 17.97 o -10 4 3 32.43 20.93 13.14 o -8 4 3 1437.90 1393.85 15.25 o -6 4 3 385.52 365.53 21.30 o -4 4 3 167.74 169.36 6.67 o -2 4 3 5086.49 4971.70 53.70 o 0 4 3 823.41 732.31 13.23 o 2 4 3 644.95 619.26 12.56 o 4 4 3 554.75 557.19 6.93 o 6 4 3 696.22 700.16 6.98 o 8 4 3 607.18 602.87 12.90 o 10 4 3 233.64 232.85 9.12 o -13 5 3 10.24 12.85 16.25 o -11 5 3 32.09 32.46 10.33 o -9 5 3 2.67 0.74 11.33 o -7 5 3 81.42 80.24 7.51 o -5 5 3 733.54 698.00 7.14 o -3 5 3 617.84 569.90 13.13 o -1 5 3 150.41 154.83 5.82 o 1 5 3 592.01 566.45 6.65 o 3 5 3 265.90 248.55 7.78 o 5 5 3 0.06 -0.04 6.44 o 7 5 3 5.96 7.37 6.89 o 9 5 3 451.68 459.86 8.93 o -12 6 3 258.24 241.03 12.25 o -10 6 3 0.50 7.95 12.57 o -8 6 3 97.32 99.15 8.95 o -6 6 3 71.27 75.22 7.02 o -4 6 3 43.21 58.60 5.82 o -2 6 3 56.97 65.19 5.47 o 0 6 3 82.41 92.25 5.82 o 2 6 3 438.97 448.97 14.48 o 4 6 3 0.60 -0.87 6.03 o 6 6 3 12.66 18.31 6.82 o 8 6 3 80.94 73.54 7.85 o -11 7 3 434.81 423.92 15.11 o -9 7 3 1574.27 1571.31 21.69 o -7 7 3 248.26 228.90 7.06 o -5 7 3 4731.67 4893.26 98.53 o -3 7 3 15.06 21.33 5.53 o -1 7 3 3702.87 3627.79 68.23 o 1 7 3 2788.36 2738.06 52.64 o 3 7 3 163.68 177.47 6.72 o 5 7 3 2543.76 2480.68 55.67 o 7 7 3 201.71 196.63 7.94 o -10 8 3 38.23 37.04 14.00 o -8 8 3 2181.24 2142.10 11.12 o -6 8 3 435.78 435.07 12.91 o -4 8 3 589.97 609.29 15.27 o -2 8 3 5370.12 5371.55 101.89 o 0 8 3 2.77 7.63 6.43 o 2 8 3 4863.59 4924.14 96.88 o 4 8 3 2.34 10.46 9.18 o 6 8 3 1498.80 1459.01 41.96 o -9 9 3 1979.63 1933.73 13.98 o -7 9 3 953.45 951.17 9.34 o -5 9 3 528.42 522.13 9.76 o -3 9 3 2.61 5.52 7.62 o -1 9 3 2079.95 2082.11 96.65 o 1 9 3 55.93 54.84 6.31 o 3 9 3 539.86 534.23 23.14 o 5 9 3 2805.38 2778.11 112.40 o -8 10 3 152.53 153.42 8.61 o -6 10 3 101.12 102.38 7.29 o -4 10 3 3.21 4.07 7.41 o -2 10 3 844.63 845.01 26.98 o 0 10 3 231.25 238.16 6.56 o 2 10 3 324.15 325.95 10.75 o 4 10 3 201.97 194.94 8.79 o -7 11 3 36.46 34.47 14.80 o -5 11 3 49.16 37.48 7.65 o -3 11 3 174.56 170.46 7.52 o -1 11 3 21.80 35.50 7.89 o 1 11 3 0.92 -4.68 5.93 o 3 11 3 307.91 316.09 13.00 o -4 12 3 351.97 377.31 9.84 o -2 12 3 1441.09 1450.07 41.17 o 0 12 3 169.03 182.78 12.64 o -8 0 4 25.75 23.86 10.71 o -6 0 4 14049.66 13765.68 38.04 o -4 0 4 6856.38 6820.94 310.81 o -2 0 4 934.85 993.47 9.80 o 0 0 4 15138.91 16510.85 101.51 o 2 0 4 1114.16 1129.11 26.47 o 4 0 4 5255.11 5439.80 37.79 o 6 0 4 716.55 725.44 11.98 o 8 0 4 870.71 877.18 10.66 o -9 1 4 6.98 13.18 16.85 o -7 1 4 2355.90 2285.17 47.73 o -5 1 4 34.36 40.49 5.85 o -3 1 4 9228.16 9535.85 133.52 o -1 1 4 432.55 440.87 5.88 o 1 1 4 6.60 85.27 41.16 o 3 1 4 5682.38 5773.71 83.34 o 5 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