#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/10/40/2104032.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2104032_Fobs loop_ _publ_author_name 'Redhammer, G\"unther J.' 'Ohashi, Haruo' 'Roth, Georg' _publ_section_title ; Single-crystal structure refinement of NaTiSi~2~O~6~ clinopyroxene at low temperatures (298<T<100K) ; _journal_issue 6 _journal_name_full 'Acta Crystallographica Section B' _journal_page_first 730 _journal_page_last 746 _journal_volume 59 _journal_year 2003 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 106.850 _cell_angle_gamma 90.000 _cell_length_a 9.7033 _cell_length_b 8.8774 _cell_length_c 5.3038 _exptl_crystal_F_000 436.00 _reflns_d_resolution_high 0.6716 _[local]_cod_data_source_file ws5001240sup4.hkl _[local]_cod_data_source_block 240 #BEGIN Tags that were not found in dictionaries: _shelx_title ' NaTiSi2O6 Haruo OHASI' _shelx_refln_list_code 4 _shelx_F_calc_maximum 127.90 _shelx_F_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 157.92 135.31 18.54 o 8 0 0 5038.65 4879.41 28.76 o 10 0 0 4060.31 4173.15 30.59 o 1 1 0 1247.06 1195.09 20.72 o 5 1 0 1814.60 1940.71 29.73 o 7 1 0 3940.90 3881.24 38.37 o 9 1 0 384.42 401.31 11.59 o 11 1 0 1259.61 1273.06 15.58 o 0 2 0 4421.18 4247.76 31.41 o 2 2 0 1516.18 1426.08 29.07 o 4 2 0 25.19 32.72 8.12 o 6 2 0 2.63 8.99 7.58 o 8 2 0 60.01 62.40 8.26 o 10 2 0 362.40 380.18 12.21 o 12 2 0 101.77 105.10 12.72 o 1 3 0 219.78 262.37 9.17 o 3 3 0 1569.20 1593.59 13.54 o 5 3 0 164.01 141.53 7.47 o 7 3 0 546.92 556.26 8.71 o 9 3 0 194.35 188.92 9.36 o 11 3 0 46.55 46.53 10.79 o 13 3 0 175.11 174.67 14.64 o 2 4 0 329.08 386.10 11.00 o 4 4 0 8597.86 8488.67 21.52 o 6 4 0 8.07 17.96 6.93 o 8 4 0 17.44 19.55 7.50 o 10 4 0 4680.63 4723.30 103.11 o 12 4 0 4.90 6.54 10.78 o 1 5 0 10053.53 9778.32 348.84 o 3 5 0 6143.82 5790.56 209.93 o 5 5 0 37.82 27.56 6.42 o 7 5 0 13620.27 13896.31 180.87 o 9 5 0 389.64 398.20 15.54 o 11 5 0 1122.87 1132.68 35.63 o 0 6 0 14395.24 13804.31 30.41 o 2 6 0 175.51 171.20 7.54 o 4 6 0 953.02 984.59 14.10 o 6 6 0 301.77 300.84 9.35 o 8 6 0 418.32 412.87 12.70 o 10 6 0 3598.50 3598.27 68.79 o 12 6 0 603.22 609.90 15.94 o 1 7 0 433.54 460.91 8.59 o 3 7 0 5.98 14.39 7.86 o 5 7 0 2077.03 2100.40 37.22 o 7 7 0 2896.69 2825.23 22.70 o 9 7 0 67.85 73.06 7.59 o 11 7 0 0.41 6.82 9.27 o 0 8 0 26.24 33.58 11.00 o 2 8 0 27.36 19.07 7.53 o 4 8 0 703.28 711.94 8.83 o 6 8 0 239.54 212.74 6.59 o 8 8 0 77.80 88.88 8.67 o 10 8 0 746.22 764.18 9.66 o 1 9 0 79.76 86.47 6.56 o 3 9 0 1818.63 1854.60 85.67 o 5 9 0 113.51 117.96 12.59 o 7 9 0 420.28 423.93 7.55 o 9 9 0 124.79 122.16 8.47 o 0 10 0 5680.97 5884.44 20.22 o 2 10 0 200.53 197.48 17.47 o 4 10 0 2814.28 2848.40 91.79 o 6 10 0 1311.87 1297.37 45.09 o 8 10 0 335.55 334.07 10.69 o 1 11 0 114.52 106.08 7.97 o 3 11 0 2660.03 2700.19 108.75 o 5 11 0 283.88 291.28 7.95 o 7 11 0 1561.56 1540.23 38.02 o 0 12 0 4105.97 4047.78 17.51 o 2 12 0 463.28 486.93 14.06 o 4 12 0 40.16 65.96 8.04 o 1 13 0 8.04 20.29 13.35 o -9 1 1 233.54 231.80 13.78 o -7 1 1 66.99 60.12 11.21 o -5 1 1 2234.93 2137.93 24.44 o -3 1 1 2439.32 2374.79 80.33 o -1 1 1 1711.26 1762.37 23.59 o 1 1 1 1248.15 1305.33 20.12 o 3 1 1 2348.93 2425.94 18.14 o 5 1 1 1263.17 1316.42 7.84 o 7 1 1 1.73 9.39 6.72 o 9 1 1 489.04 499.45 8.24 o 11 1 1 120.35 112.65 10.70 o 13 1 1 108.39 118.20 21.20 o -10 2 1 8.82 8.01 11.28 o -8 2 1 3052.48 3106.33 25.36 o -6 2 1 2545.88 2292.75 20.68 o -4 2 1 5793.50 5712.25 28.73 o 0 2 1 466.91 510.04 9.59 o 2 2 1 14655.18 14018.25 253.10 o 4 2 1 2520.01 2479.05 62.67 o 6 2 1 5124.46 5089.92 14.85 o 8 2 1 3322.51 3461.99 45.31 o 10 2 1 54.07 66.38 9.64 o 12 2 1 3559.66 3573.71 20.56 o -11 3 1 2147.26 2060.48 19.26 o -9 3 1 4815.37 4749.72 34.64 o -7 3 1 1756.85 1689.96 12.10 o -3 3 1 9704.03 9936.21 31.68 o -1 3 1 7630.75 6776.89 121.06 o 3 3 1 1908.01 1886.83 37.59 o 7 3 1 261.66 245.95 7.43 o 9 3 1 2273.99 2330.75 15.23 o 11 3 1 780.49 777.52 10.72 o -12 4 1 2458.22 2440.20 16.62 o -10 4 1 265.60 266.43 10.31 o -8 4 1 144.02 157.91 8.54 o -6 4 1 1.19 -3.89 10.97 o -4 4 1 288.00 303.43 17.60 o -2 4 1 4362.60 4524.77 65.43 o 0 4 1 5929.31 5751.77 207.24 o 2 4 1 1619.01 1551.61 19.45 o 4 4 1 4.04 6.66 5.98 o 6 4 1 478.13 478.51 7.32 o 8 4 1 417.73 443.53 7.63 o 10 4 1 623.14 605.72 8.85 o 12 4 1 1225.91 1246.27 17.85 o -13 5 1 59.65 62.55 13.55 o -11 5 1 32.47 29.53 9.39 o -9 5 1 25.75 28.03 8.50 o -7 5 1 11.73 13.93 8.32 o -5 5 1 473.43 454.52 10.72 o -3 5 1 412.98 394.10 8.71 o -1 5 1 664.07 680.30 27.23 o 1 5 1 123.62 109.61 7.90 o 3 5 1 832.57 797.56 18.42 o 5 5 1 653.21 674.53 7.36 o 7 5 1 11.28 10.61 6.59 o 9 5 1 26.10 31.71 7.11 o 11 5 1 140.86 151.88 7.98 o -12 6 1 82.65 77.29 10.75 o -10 6 1 2.47 1.32 8.67 o -8 6 1 306.75 302.43 7.50 o -6 6 1 1.07 4.55 8.13 o -4 6 1 41.20 47.27 7.56 o -2 6 1 444.93 404.80 32.12 o 0 6 1 77.37 59.60 14.85 o 2 6 1 107.50 100.63 7.27 o 4 6 1 1.29 5.12 6.83 o 6 6 1 40.69 56.65 6.65 o 8 6 1 41.12 46.29 7.27 o 10 6 1 10.16 6.55 7.07 o -11 7 1 402.83 409.18 28.43 o -9 7 1 1539.14 1465.86 18.45 o -7 7 1 289.77 297.72 12.90 o -5 7 1 7201.67 7056.41 55.58 o -3 7 1 26.54 44.58 7.98 o -1 7 1 3901.49 3877.99 96.90 o 1 7 1 5428.20 5376.19 253.31 o 3 7 1 150.49 173.72 5.93 o 5 7 1 3776.89 3771.67 74.29 o 7 7 1 436.32 422.06 10.31 o 9 7 1 2683.01 2706.87 33.39 o 11 7 1 49.14 58.09 19.55 o -10 8 1 1.51 1.71 8.01 o -8 8 1 2362.99 2315.32 63.70 o -6 8 1 870.75 871.32 10.72 o -4 8 1 731.66 698.30 8.89 o -2 8 1 9147.00 9175.81 72.77 o 0 8 1 120.58 116.81 7.88 o 2 8 1 4809.85 4991.86 336.49 o 4 8 1 583.97 576.10 19.54 o 6 8 1 2542.77 2526.43 37.59 o 8 8 1 1592.32 1541.14 28.26 o 10 8 1 39.60 45.00 9.10 o -9 9 1 563.19 561.75 15.66 o -7 9 1 2068.57 2055.02 20.90 o -5 9 1 3450.15 3431.84 20.00 o -3 9 1 32.54 36.93 8.59 o -1 9 1 88.68 106.20 7.15 o 1 9 1 23.20 21.39 8.99 o 3 9 1 32.12 46.42 6.16 o 5 9 1 3588.45 3610.53 112.76 o 7 9 1 747.79 751.22 26.69 o 9 9 1 468.86 473.37 9.53 o -8 10 1 95.77 101.57 9.96 o -6 10 1 45.26 46.43 8.66 o -4 10 1 12.98 20.92 7.78 o -2 10 1 1592.18 1615.78 21.73 o 0 10 1 1035.20 1072.04 24.27 o 2 10 1 149.02 167.77 13.16 o 4 10 1 29.47 40.55 6.46 o 6 10 1 260.64 260.86 10.74 o 8 10 1 5.83 6.30 7.44 o -7 11 1 45.56 44.31 11.53 o -5 11 1 50.87 49.70 8.32 o -3 11 1 164.84 194.74 9.04 o -1 11 1 27.87 31.72 7.86 o 1 11 1 9.22 2.34 6.21 o 3 11 1 154.41 155.83 19.58 o 5 11 1 31.54 35.25 8.31 o -6 12 1 744.24 724.93 10.71 o -4 12 1 552.12 531.08 16.81 o -2 12 1 1140.25 1131.67 32.80 o 0 12 1 224.49 238.84 9.46 o 2 12 1 2229.40 2268.80 23.85 o 4 12 1 305.26 308.84 8.04 o -1 13 1 1769.18 1802.89 62.08 o 1 13 1 1146.13 1176.33 11.64 o 2 0 2 6694.76 7016.68 47.48 o 4 0 2 11615.40 12122.22 327.91 o 6 0 2 253.08 290.11 8.58 o 8 0 2 986.32 972.86 10.21 o 10 0 2 8195.99 8474.44 28.85 o 12 0 2 10.86 23.90 16.79 o -5 1 2 55.07 52.89 8.64 o -1 1 2 387.30 368.17 7.14 o 1 1 2 8426.33 9392.82 85.56 o 3 1 2 3591.99 3467.58 23.73 o 5 1 2 1413.01 1414.24 7.02 o 7 1 2 5167.14 5317.06 63.40 o 9 1 2 5.54 5.32 9.06 o 11 1 2 846.14 874.88 12.40 o -10 2 2 1947.71 1984.53 22.37 o -8 2 2 207.80 210.12 15.63 o -6 2 2 1072.64 1110.68 16.83 o -4 2 2 1847.33 1891.56 32.83 o -2 2 2 0.67 5.19 6.12 o 0 2 2 1419.74 1658.71 34.86 o 2 2 2 629.24 583.66 5.87 o 4 2 2 3741.92 3890.40 71.37 o 6 2 2 537.10 521.38 6.11 o 8 2 2 991.42 977.42 12.97 o 10 2 2 1318.34 1312.66 16.03 o 12 2 2 3.16 2.57 11.99 o -11 3 2 97.85 99.67 13.56 o -9 3 2 34.84 29.82 9.45 o -7 3 2 306.93 280.04 13.75 o -5 3 2 231.30 250.61 7.33 o -3 3 2 1057.62 1195.95 12.72 o -1 3 2 646.92 653.10 8.87 o 1 3 2 1169.37 1228.92 13.46 o 3 3 2 356.56 400.89 6.93 o 5 3 2 15.95 14.01 6.49 o 7 3 2 128.79 138.32 6.98 o 9 3 2 0.16 4.14 7.02 o 11 3 2 100.46 98.94 9.62 o -12 4 2 14.74 20.68 13.67 o -10 4 2 1665.43 1608.63 43.90 o -8 4 2 130.95 140.34 12.60 o -6 4 2 1477.55 1488.58 14.40 o -4 4 2 1297.64 1286.34 8.63 o -2 4 2 2.52 7.31 5.67 o 0 4 2 6811.47 6766.63 205.44 o 2 4 2 65.56 86.80 5.95 o 4 4 2 2326.01 2270.41 42.80 o 6 4 2 700.00 724.06 22.21 o 8 4 2 18.20 26.84 7.07 o 10 4 2 1062.30 1052.10 10.53 o -13 5 2 827.61 777.14 66.57 o -11 5 2 1293.46 1268.39 36.38 o -9 5 2 757.61 707.48 14.46 o -7 5 2 8342.77 8209.87 181.15 o -5 5 2 88.15 105.70 6.65 o -3 5 2 14229.51 13868.67 76.06 o -1 5 2 818.75 738.32 9.15 o 1 5 2 3215.01 3138.79 23.43 o 3 5 2 15419.91 15196.13 78.50 o 5 5 2 18.86 37.41 6.17 o 7 5 2 3486.05 3548.71 65.57 o 9 5 2 384.16 390.93 8.34 o 11 5 2 3349.31 3332.29 16.71 o -12 6 2 183.72 200.14 11.67 o -10 6 2 489.65 473.31 10.04 o -8 6 2 162.70 167.28 8.28 o -6 6 2 6102.24 5977.52 49.30 o -4 6 2 213.01 242.91 6.80 o -2 6 2 3889.58 3893.95 45.74 o 0 6 2 16357.75 16161.92 171.68 o 2 6 2 73.60 67.98 8.79 o 4 6 2 426.80 438.98 6.79 o 6 6 2 108.21 102.62 12.93 o 8 6 2 520.48 536.89 7.86 o 10 6 2 1872.70 1911.20 21.13 o -11 7 2 6.36 2.35 17.63 o -9 7 2 34.86 36.35 8.89 o -7 7 2 1219.00 1265.94 9.38 o -5 7 2 709.12 714.33 10.00 o -3 7 2 861.56 854.37 10.57 o -1 7 2 750.91 697.74 25.23 o 1 7 2 1.59 1.80 10.32 o 3 7 2 2100.75 2068.50 20.83 o 5 7 2 1086.70 1050.38 24.23 o 7 7 2 121.05 130.45 6.99 o 9 7 2 11.25 16.07 7.90 o -10 8 2 6.19 31.05 10.25 o -8 8 2 1.21 5.69 7.81 o -6 8 2 114.46 114.03 6.65 o -4 8 2 2.21 6.72 6.54 o -2 8 2 69.63 61.22 6.84 o 0 8 2 422.13 423.76 17.61 o 2 8 2 8.55 17.08 6.62 o 4 8 2 95.06 108.86 6.15 o 6 8 2 5.20 4.54 6.88 o 8 8 2 63.24 75.91 7.60 o -9 9 2 11.06 11.52 9.11 o -7 9 2 1422.67 1399.79 9.49 o -5 9 2 82.80 73.27 7.33 o -3 9 2 374.63 368.17 6.15 o -1 9 2 508.43 512.22 26.14 o 1 9 2 754.05 797.43 16.25 o 3 9 2 210.70 212.57 5.45 o 5 9 2 32.87 39.37 6.13 o 7 9 2 1629.36 1681.26 37.56 o -8 10 2 242.46 251.23 9.12 o -6 10 2 467.69 475.80 8.19 o -4 10 2 3714.57 3615.79 77.96 o -2 10 2 739.45 749.68 34.49 o 0 10 2 2448.21 2411.68 92.06 o 2 10 2 106.44 117.60 10.19 o 4 10 2 5052.88 5041.90 178.30 o 6 10 2 551.42 593.51 25.32 o -7 11 2 3437.33 3589.68 59.84 o -5 11 2 87.71 100.96 7.26 o -3 11 2 1054.10 1022.25 20.15 o -1 11 2 66.84 73.79 6.38 o 1 11 2 705.04 689.95 18.81 o 3 11 2 1463.93 1420.86 45.00 o 5 11 2 189.88 215.23 19.13 o -4 12 2 152.65 152.10 7.48 o -2 12 2 813.82 838.92 18.80 o 0 12 2 1274.37 1272.90 33.99 o 2 12 2 11.03 18.82 7.23 o -7 1 3 138.18 143.24 9.27 o -5 1 3 2216.26 2216.24 35.40 o -3 1 3 1746.65 1799.95 12.87 o -1 1 3 543.33 551.31 8.81 o 1 1 3 1124.20 1118.96 6.11 o 3 1 3 568.93 561.52 13.24 o 5 1 3 176.48 174.63 5.46 o 7 1 3 11.39 15.14 5.99 o 9 1 3 1159.32 1146.01 10.21 o 11 1 3 103.19 107.20 15.21 o -10 2 3 130.93 120.82 16.92 o -8 2 3 5472.78 5600.83 29.22 o -6 2 3 497.50 488.64 8.33 o -4 2 3 1167.47 1073.92 9.93 o 0 2 3 297.45 262.59 5.59 o 2 2 3 7362.65 7476.80 52.22 o 4 2 3 69.44 75.35 5.60 o 6 2 3 3565.47 3582.49 8.43 o 8 2 3 3024.84 3018.97 38.72 o 10 2 3 1.30 -1.76 8.24 o -11 3 3 2176.66 2137.85 45.29 o -9 3 3 7259.01 7410.35 31.35 o -7 3 3 789.33 764.51 15.45 o -5 3 3 6364.21 6355.57 72.92 o -3 3 3 2134.56 2110.13 29.12 o -1 3 3 13616.10 14203.48 64.48 o 3 3 3 1.77 65.84 27.71 o 5 3 3 10761.20 10987.32 131.44 o 7 3 3 26.25 40.78 6.10 o 9 3 3 2742.73 2759.22 10.84 o -12 4 3 1265.75 1224.11 18.44 o -10 4 3 36.39 40.92 12.90 o -8 4 3 1438.88 1381.84 16.29 o -6 4 3 408.57 398.98 51.38 o -4 4 3 176.76 172.92 6.30 o -2 4 3 5179.15 5121.06 110.94 o 0 4 3 819.62 775.49 6.27 o 2 4 3 626.20 631.98 11.64 o 4 4 3 553.09 557.84 9.12 o 6 4 3 711.44 730.09 17.57 o 8 4 3 619.66 616.80 9.38 o 10 4 3 261.20 271.44 10.52 o -13 5 3 15.84 11.83 17.01 o -11 5 3 36.55 39.62 10.91 o -9 5 3 2.18 -9.79 13.00 o -7 5 3 75.30 78.63 7.43 o -5 5 3 780.08 736.07 10.99 o -3 5 3 600.37 557.19 18.63 o -1 5 3 142.24 146.81 7.95 o 1 5 3 618.37 590.51 8.28 o 3 5 3 241.21 210.71 6.00 o 5 5 3 0.16 9.93 6.34 o 7 5 3 6.95 15.34 5.83 o 9 5 3 493.61 517.59 8.53 o -12 6 3 259.77 254.09 12.82 o -10 6 3 0.67 4.68 14.25 o -8 6 3 83.16 88.46 8.00 o -6 6 3 56.73 71.83 6.89 o -4 6 3 33.85 27.30 5.88 o -2 6 3 53.62 73.76 11.19 o 0 6 3 103.73 118.10 5.68 o 2 6 3 428.00 437.55 6.68 o 4 6 3 0.56 7.17 8.13 o 6 6 3 7.75 4.92 8.30 o 8 6 3 76.83 80.93 7.44 o -11 7 3 466.01 460.51 15.70 o -9 7 3 1678.02 1613.58 19.11 o -7 7 3 260.00 252.57 10.56 o -5 7 3 4878.82 4936.09 91.49 o -3 7 3 13.14 10.08 7.74 o -1 7 3 3768.10 3729.20 113.71 o 1 7 3 2885.68 2842.83 80.71 o 3 7 3 150.11 152.09 12.24 o 5 7 3 2602.58 2508.91 63.58 o 7 7 3 210.93 208.04 11.98 o -10 8 3 42.74 53.29 13.85 o -8 8 3 2303.45 2244.95 17.48 o -6 8 3 485.48 486.05 6.80 o -4 8 3 619.97 637.77 8.32 o -2 8 3 5519.45 5485.40 96.52 o 0 8 3 3.12 1.30 6.33 o 2 8 3 5090.24 4964.84 74.79 o 4 8 3 2.88 6.82 5.92 o 6 8 3 1514.60 1503.65 36.48 o -9 9 3 2107.01 2112.37 28.65 o -7 9 3 1000.57 1009.85 8.91 o -5 9 3 523.76 510.58 16.46 o -3 9 3 2.08 7.21 7.31 o -1 9 3 2179.57 2160.98 57.79 o 1 9 3 57.15 56.92 5.49 o 3 9 3 578.45 566.29 18.68 o 5 9 3 2962.08 2987.01 72.99 o -8 10 3 159.77 156.86 9.22 o -6 10 3 96.69 100.84 8.41 o -4 10 3 0.87 -5.55 7.36 o -2 10 3 889.76 892.58 29.69 o 0 10 3 230.75 233.26 5.34 o 2 10 3 346.82 336.55 10.39 o 4 10 3 187.32 189.54 7.86 o -5 11 3 44.18 49.88 8.15 o -3 11 3 158.73 162.30 7.50 o -1 11 3 30.74 37.12 7.82 o 1 11 3 0.39 11.23 6.89 o 3 11 3 288.73 299.76 14.83 o -2 12 3 1563.94 1570.04 34.58 o 0 12 3 167.77 168.25 12.55 o -8 0 4 16.61 27.83 10.66 o -6 0 4 14582.11 15171.78 39.96 o -4 0 4 7144.52 7287.22 127.22 o -2 0 4 955.82 1019.19 13.26 o 0 0 4 15304.87 16325.91 159.71 o 2 0 4 1204.74 1202.80 8.83 o 4 0 4 5338.98 5197.69 29.25 o 6 0 4 737.86 690.79 30.77 o 8 0 4 918.99 924.06 14.64 o -9 1 4 6.37 2.33 16.75 o -7 1 4 2402.34 2447.49 12.72 o -5 1 4 32.68 34.28 5.55 o -3 1 4 9300.46 9423.81 79.86 o -1 1 4 426.13 421.97 6.72 o 1 1 4 5.11 19.65 6.33 o 3 1 4 5790.82 5813.54 56.69 o 5 1 4 6.77 19.75 10.57 o 7 1 4 923.84 900.12 8.13 o 9 1 4 81.85 89.39 7.12 o -10 2 4 114.14 108.80 18.01 o -8 2 4 90.70 78.68 8.09 o -6 2 4 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