#------------------------------------------------------------------------------
#$Date: 2016-02-20 02:53:41 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176768 $
#$URL: svn://www.crystallography.net/cod/cif/2/10/43/2104303.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2104303
loop_
_publ_author_name
'Daszkiewicz, Marek'
'Gulay, Lubomir D.'
'Lychmanyuk, Olga S.'
_publ_section_title
;
 Ln₃M~1{-~δ}TX₇ -- quasi-isostructural compounds:
 stereochemistry and silver-ion motion in the Ln₃Ag~1{-~δ}GeS₇ (Ln
 = La--Nd, Sm, Gd--Er and Y; δ = 0.11--0.50) compounds
;
_journal_coeditor_code           BP5017
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              126
_journal_page_last               133
_journal_paper_doi               10.1107/S010876810900144X
_journal_volume                  65
_journal_year                    2009
_chemical_formula_moiety         'Ag0.82 Ge La3 S7'
_chemical_formula_sum            'Ag0.82 Ge La3 S7'
_chemical_formula_weight         802.19
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           173
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  'P 6c'
_symmetry_space_group_name_H-M   'P 63'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            2
_cell_length_a                   10.4056(15)
_cell_length_b                   10.4056(15)
_cell_length_c                   5.8280(12)
_cell_measurement_reflns_used    729
_cell_measurement_temperature    295(2)
_cell_measurement_theta_max      26.36
_cell_measurement_theta_min      4.16
_cell_volume                     546.49(16)
_computing_cell_refinement       'CrysAlis RED'
_computing_data_collection       'CrysAlis CCD (Oxford Diffraction, 2007)'
_computing_data_reduction        'CrysAlis RED'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      295(2)
_diffrn_detector_area_resol_mean '1024x1024 with blocks 2x2, 33.133pixel/mm'
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'KUMA KM-4 with area CCD detector'
_diffrn_measurement_method       ω-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0387
_diffrn_reflns_av_sigmaI/netI    0.0175
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       7
_diffrn_reflns_limit_l_min       -7
_diffrn_reflns_number            5858
_diffrn_reflns_theta_full        26.36
_diffrn_reflns_theta_max         26.36
_diffrn_reflns_theta_min         4.16
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    16.910
_exptl_absorpt_correction_T_max  0.599
_exptl_absorpt_correction_T_min  0.097
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'CrysAlis (Oxford Diffraction, 2007)'
_exptl_crystal_colour            'dark red'
_exptl_crystal_density_diffrn    4.875
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             707
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.03
_refine_diff_density_max         0.370
_refine_diff_density_min         -0.440
_refine_ls_abs_structure_details
'Flack H D (1983), Acta Cryst. A39, 876-881, 334 Friedel pairs'
_refine_ls_abs_structure_Flack   0.014(12)
_refine_ls_extinction_coef       0.0042(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     43
_refine_ls_number_reflns         743
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.0118
_refine_ls_R_factor_gt           0.0113
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         <0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0107P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0223
_refine_ls_wR_factor_ref         0.0224
_reflns_number_gt                729
_reflns_number_total             743
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            bp5017.cif
_cod_data_source_block           la
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Hexagonal' changed to 'hexagonal'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Hexagonal' changed to 'hexagonal'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_database_code               2104303
_cod_database_fobs_code          2104303
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x, -y, z+1/2'
'y, -x+y, z+1/2'
'x-y, x, z+1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
La La 0.875611(18) 0.641442(18) 0.24144(6) 0.00881(6) Uani d . 1 . .
Ag Ag1 0.0000 0.0000 0.18424(19) 0.0387(6) Uani d SP 0.719(3) . .
Ag Ag2 0.0000 0.0000 0.9766(13) 0.018(2) Uani d SP 0.102(3) . .
Ge Ge1 0.3333 0.6667 0.32488(9) 0.00826(14) Uani d S 1 . .
S S1 0.3333 0.6667 0.9515(2) 0.0114(3) Uani d S 1 . .
S S2 0.90929(9) 0.73775(9) 0.72749(15) 0.01254(16) Uani d . 1 . .
S S3 0.58764(10) 0.47816(10) 0.97462(12) 0.00978(18) Uani d . 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
S3 La S2 3_664 5_564 140.33(3) ?
S3 La S2 3_664 6_654 107.53(2) ?
S2 La S2 5_564 6_654 89.89(3) ?
S3 La S2 3_664 . 137.75(2) ?
S2 La S2 5_564 . 79.46(2) ?
S2 La S2 6_654 . 79.38(2) ?
S3 La S3 3_664 1_554 73.14(3) ?
S2 La S3 5_564 1_554 71.59(2) ?
S2 La S3 6_654 1_554 142.08(3) ?
S2 La S3 . 1_554 126.57(2) ?
S3 La S3 3_664 6_654 73.508(19) ?
S2 La S3 5_564 6_654 145.66(3) ?
S2 La S3 6_654 6_654 68.66(2) ?
S2 La S3 . 6_654 70.65(2) ?
S3 La S3 1_554 6_654 140.85(2) ?
S3 La S1 3_664 4_664 70.13(2) ?
S2 La S1 5_564 4_664 112.021(18) ?
S2 La S1 6_654 4_664 148.62(2) ?
S2 La S1 . 4_664 82.82(3) ?
S3 La S1 1_554 4_664 68.65(2) ?
S3 La S1 6_654 4_664 81.15(2) ?
S3 La S2 3_664 1_554 72.98(2) ?
S2 La S2 5_564 1_554 76.97(2) ?
S2 La S2 6_654 1_554 76.90(2) ?
S2 La S2 . 1_554 146.34(3) ?
S3 La S2 1_554 1_554 66.96(2) ?
S3 La S2 6_654 1_554 120.71(2) ?
S1 La S2 4_664 1_554 128.42(3) ?
S3 La Ag1 3_664 1_665 136.06(3) ?
S2 La Ag1 5_564 1_665 45.071(16) ?
S2 La Ag1 6_654 1_665 45.044(16) ?
S2 La Ag1 . 1_665 78.53(3) ?
S3 La Ag1 1_554 1_665 107.52(2) ?
S3 La Ag1 6_654 1_665 110.62(2) ?
S1 La Ag1 4_664 1_665 152.74(2) ?
S2 La Ag1 1_554 1_665 67.81(3) ?
S3 La Ag2 3_664 4_664 157.44(6) ?
S2 La Ag2 5_564 4_664 50.08(5) ?
S2 La Ag2 6_654 4_664 50.05(5) ?
S2 La Ag2 . 4_664 50.06(11) ?
S3 La Ag2 1_554 4_664 121.66(5) ?
S3 La Ag2 6_654 4_664 96.59(6) ?
S1 La Ag2 4_664 4_664 129.39(11) ?
S2 La Ag2 1_554 4_664 96.28(12) ?
Ag1 La Ag2 1_665 4_664 28.47(11) ?
S3 La Ag2 3_664 1_664 118.48(10) ?
S2 La Ag2 5_564 1_664 49.34(4) ?
S2 La Ag2 6_654 1_664 49.32(4) ?
S2 La Ag2 . 1_664 97.92(11) ?
S3 La Ag2 1_554 1_664 95.89(7) ?
S3 La Ag2 6_654 1_664 117.90(4) ?
S1 La Ag2 4_664 1_664 160.202(7) ?
S2 La Ag2 1_554 1_664 48.42(11) ?
Ag1 La Ag2 1_665 1_664 19.39(10) ?
Ag2 La Ag2 4_664 1_664 47.861(12) ?
Ag2 Ag1 Ag2 1_554 4_554 180.0000(10) ?
Ag2 Ag1 S2 1_554 5_454 95.99(3) ?
Ag2 Ag1 S2 4_554 5_454 84.01(3) ?
Ag2 Ag1 S2 1_554 4_664 95.99(3) ?
Ag2 Ag1 S2 4_554 4_664 84.01(3) ?
S2 Ag1 S2 5_454 4_664 118.924(11) ?
Ag2 Ag1 S2 1_554 6_544 95.99(3) ?
Ag2 Ag1 S2 4_554 6_544 84.01(3) ?
S2 Ag1 S2 5_454 6_544 118.924(11) ?
S2 Ag1 S2 4_664 6_544 118.924(11) ?
Ag2 Ag1 Ag1 1_554 4_554 0.0 ?
Ag2 Ag1 Ag1 4_554 4_554 180.0000(10) ?
S2 Ag1 Ag1 5_454 4_554 95.99(3) ?
S2 Ag1 Ag1 4_664 4_554 95.99(3) ?
S2 Ag1 Ag1 6_544 4_554 95.99(3) ?
Ag2 Ag1 Ag1 1_554 4 180.0 ?
Ag2 Ag1 Ag1 4_554 4 0.0000(10) ?
S2 Ag1 Ag1 5_454 4 84.01(3) ?
S2 Ag1 Ag1 4_664 4 84.01(3) ?
S2 Ag1 Ag1 6_544 4 84.01(3) ?
Ag1 Ag1 Ag1 4_554 4 180.0 ?
Ag2 Ag1 La 1_554 2_655 95.80(2) ?
Ag2 Ag1 La 4_554 2_655 84.20(2) ?
S2 Ag1 La 5_454 2_655 168.21(5) ?
S2 Ag1 La 4_664 2_655 59.715(19) ?
S2 Ag1 La 6_544 2_655 59.586(19) ?
Ag1 Ag1 La 4_554 2_655 95.80(2) ?
Ag1 Ag1 La 4 2_655 84.20(2) ?
Ag2 Ag1 La 1_554 1_445 95.80(2) ?
Ag2 Ag1 La 4_554 1_445 84.20(2) ?
S2 Ag1 La 5_454 1_445 59.586(19) ?
S2 Ag1 La 4_664 1_445 168.21(5) ?
S2 Ag1 La 6_544 1_445 59.715(19) ?
Ag1 Ag1 La 4_554 1_445 95.80(2) ?
Ag1 Ag1 La 4 1_445 84.20(2) ?
La Ag1 La 2_655 1_445 118.992(7) ?
Ag2 Ag1 La 1_554 3_565 95.80(2) ?
Ag2 Ag1 La 4_554 3_565 84.20(2) ?
S2 Ag1 La 5_454 3_565 59.715(19) ?
S2 Ag1 La 4_664 3_565 59.586(19) ?
S2 Ag1 La 6_544 3_565 168.21(5) ?
Ag1 Ag1 La 4_554 3_565 95.80(2) ?
Ag1 Ag1 La 4 3_565 84.20(2) ?
La Ag1 La 2_655 3_565 118.992(7) ?
La Ag1 La 1_445 3_565 118.992(7) ?
Ag1 Ag2 Ag1 1_556 4 180.0000(10) ?
Ag1 Ag2 S2 1_556 1_445 121.16(13) ?
Ag1 Ag2 S2 4 1_445 58.84(13) ?
Ag1 Ag2 S2 1_556 3_565 121.16(13) ?
Ag1 Ag2 S2 4 3_565 58.84(13) ?
S2 Ag2 S2 1_445 3_565 95.64(18) ?
Ag1 Ag2 S2 1_556 2_655 121.16(13) ?
Ag1 Ag2 S2 4 2_655 58.84(13) ?
S2 Ag2 S2 1_445 2_655 95.64(18) ?
S2 Ag2 S2 3_565 2_655 95.64(18) ?
Ag1 Ag2 S2 1_556 4_665 58.65(13) ?
Ag1 Ag2 S2 4 4_665 121.35(13) ?
S2 Ag2 S2 1_445 4_665 179.8(3) ?
S2 Ag2 S2 3_565 4_665 84.483(14) ?
S2 Ag2 S2 2_655 4_665 84.483(14) ?
Ag1 Ag2 S2 1_556 5_455 58.65(13) ?
Ag1 Ag2 S2 4 5_455 121.35(13) ?
S2 Ag2 S2 1_445 5_455 84.483(14) ?
S2 Ag2 S2 3_565 5_455 84.483(14) ?
S2 Ag2 S2 2_655 5_455 179.8(3) ?
S2 Ag2 S2 4_665 5_455 95.39(18) ?
Ag1 Ag2 S2 1_556 6_545 58.65(13) ?
Ag1 Ag2 S2 4 6_545 121.35(13) ?
S2 Ag2 S2 1_445 6_545 84.483(14) ?
S2 Ag2 S2 3_565 6_545 179.8(3) ?
S2 Ag2 S2 2_655 6_545 84.483(14) ?
S2 Ag2 S2 4_665 6_545 95.39(18) ?
S2 Ag2 S2 5_455 6_545 95.39(18) ?
Ag1 Ag2 Ag2 1_556 4_554 180.000(4) ?
Ag1 Ag2 Ag2 4 4_554 0.0000(10) ?
S2 Ag2 Ag2 1_445 4_554 58.84(13) ?
S2 Ag2 Ag2 3_565 4_554 58.84(13) ?
S2 Ag2 Ag2 2_655 4_554 58.84(13) ?
S2 Ag2 Ag2 4_665 4_554 121.35(13) ?
S2 Ag2 Ag2 5_455 4_554 121.35(13) ?
S2 Ag2 Ag2 6_545 4_554 121.35(13) ?
Ag1 Ag2 Ag2 1_556 4 0.0000(10) ?
Ag1 Ag2 Ag2 4 4 180.000(3) ?
S2 Ag2 Ag2 1_445 4 121.16(13) ?
S2 Ag2 Ag2 3_565 4 121.16(13) ?
S2 Ag2 Ag2 2_655 4 121.16(13) ?
S2 Ag2 Ag2 4_665 4 58.65(13) ?
S2 Ag2 Ag2 5_455 4 58.65(13) ?
S2 Ag2 Ag2 6_545 4 58.65(13) ?
Ag2 Ag2 Ag2 4_554 4 180.000(3) ?
Ag1 Ag2 La 1_556 5_455 112.67(11) ?
Ag1 Ag2 La 4 5_455 67.33(11) ?
S2 Ag2 La 1_445 5_455 53.60(6) ?
S2 Ag2 La 3_565 5_455 53.49(6) ?
S2 Ag2 La 2_655 5_455 126.2(2) ?
S2 Ag2 La 4_665 5_455 126.42(3) ?
S2 Ag2 La 5_455 5_455 54.02(3) ?
S2 Ag2 La 6_545 5_455 126.53(3) ?
Ag2 Ag2 La 4_554 5_455 67.33(11) ?
Ag2 Ag2 La 4 5_455 112.67(11) ?
Ag1 Ag2 La 1_556 4_665 112.67(11) ?
Ag1 Ag2 La 4 4_665 67.33(11) ?
S2 Ag2 La 1_445 4_665 126.2(2) ?
S2 Ag2 La 3_565 4_665 53.60(6) ?
S2 Ag2 La 2_655 4_665 53.49(6) ?
S2 Ag2 La 4_665 4_665 54.02(3) ?
S2 Ag2 La 5_455 4_665 126.53(3) ?
S2 Ag2 La 6_545 4_665 126.42(3) ?
Ag2 Ag2 La 4_554 4_665 67.33(11) ?
Ag2 Ag2 La 4 4_665 112.67(11) ?
La Ag2 La 5_455 4_665 106.09(13) ?
S1 Ge1 S3 1_554 5_564 113.10(2) ?
S1 Ge1 S3 1_554 6_554 113.10(2) ?
S3 Ge1 S3 5_564 6_554 105.61(3) ?
S1 Ge1 S3 1_554 4_664 113.10(2) ?
S3 Ge1 S3 5_564 4_664 105.61(3) ?
S3 Ge1 S3 6_554 4_664 105.61(3) ?
Ge1 S1 La 1_556 6 113.36(2) ?
Ge1 S1 La 1_556 4_665 113.36(2) ?
La S1 La 6 4_665 105.31(3) ?
Ge1 S1 La 1_556 5_565 113.36(2) ?
La S1 La 6 5_565 105.31(3) ?
La S1 La 4_665 5_565 105.31(3) ?
Ag2 S2 Ag2 1_665 4_664 62.51(2) ?
Ag1 S2 La 4_665 6_655 75.34(2) ?
Ag2 S2 La 1_665 6_655 76.44(3) ?
Ag2 S2 La 4_664 6_655 78.15(3) ?
Ag1 S2 La 4_665 5_565 75.24(2) ?
Ag2 S2 La 1_665 5_565 76.35(3) ?
Ag2 S2 La 4_664 5_565 78.06(3) ?
La S2 La 6_655 5_565 149.90(3) ?
Ag1 S2 La 4_665 . 101.28(4) ?
Ag2 S2 La 1_665 . 138.44(13) ?
Ag2 S2 La 4_664 . 75.92(13) ?
La S2 La 6_655 . 95.97(3) ?
La S2 La 5_565 . 95.86(3) ?
Ag1 S2 La 4_665 1_556 112.38(4) ?
Ag2 S2 La 1_665 1_556 75.22(14) ?
Ag2 S2 La 4_664 1_556 137.74(14) ?
La S2 La 6_655 1_556 92.71(2) ?
La S2 La 5_565 1_556 92.61(2) ?
La S2 La . 1_556 146.34(3) ?
Ge1 S3 La 4_665 2_656 92.15(3) ?
Ge1 S3 La 4_665 1_556 89.10(3) ?
La S3 La 2_656 1_556 111.30(3) ?
Ge1 S3 La 4_665 5_565 122.50(3) ?
La S3 La 2_656 5_565 139.09(3) ?
La S3 La 1_556 5_565 91.91(2) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
La S3 3_664 2.9145(9) ?
La S2 5_564 2.9399(9) ?
La S2 6_654 2.9452(9) ?
La S2 . 2.9665(11) ?
La S3 1_554 3.0319(9) ?
La S3 6_654 3.0732(9) ?
La S1 4_664 3.0878(7) ?
La S2 1_554 3.1221(11) ?
La Ag1 1_665 3.2981(5) ?
La Ag2 4_664 3.556(3) ?
La Ag2 1_664 3.626(3) ?
Ag1 Ag2 1_554 1.210(7) ?
Ag1 Ag2 4_554 1.704(7) ?
Ag1 S2 5_454 2.4136(9) ?
Ag1 S2 4_664 2.4136(9) ?
Ag1 S2 6_544 2.4136(9) ?
Ag1 Ag1 4_554 2.9140(6) ?
Ag1 Ag1 4 2.9140(6) ?
Ag1 La 2_655 3.2981(5) ?
Ag1 La 1_445 3.2981(5) ?
Ag1 La 3_565 3.2981(5) ?
Ag2 Ag1 1_556 1.210(7) ?
Ag2 Ag1 4 1.704(7) ?
Ag2 S2 1_445 2.805(4) ?
Ag2 S2 3_565 2.805(4) ?
Ag2 S2 2_655 2.805(4) ?
Ag2 S2 4_665 2.811(4) ?
Ag2 S2 5_455 2.811(4) ?
Ag2 S2 6_545 2.811(4) ?
Ag2 Ag2 4_554 2.9140(6) ?
Ag2 Ag2 4 2.9140(6) ?
Ag2 La 5_455 3.556(3) ?
Ag2 La 4_665 3.556(3) ?
Ge1 S1 1_554 2.1758(14) ?
Ge1 S3 5_564 2.2245(9) ?
Ge1 S3 6_554 2.2245(9) ?
Ge1 S3 4_664 2.2245(9) ?
S1 Ge1 1_556 2.1758(14) ?
S1 La 6 3.0878(7) ?
S1 La 4_665 3.0878(7) ?
S1 La 5_565 3.0878(7) ?
S2 Ag1 4_665 2.4136(9) ?
S2 Ag2 1_665 2.805(4) ?
S2 Ag2 4_664 2.811(4) ?
S2 La 6_655 2.9399(9) ?
S2 La 5_565 2.9452(9) ?
S2 La 1_556 3.1221(11) ?
S3 Ge1 4_665 2.2245(9) ?
S3 La 2_656 2.9145(9) ?
S3 La 1_556 3.0319(9) ?
S3 La 5_565 3.0732(9) ?
