#------------------------------------------------------------------------------
#$Date: 2016-02-20 02:53:41 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176768 $
#$URL: svn://www.crystallography.net/cod/cif/2/10/43/2104307.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2104307
loop_
_publ_author_name
'Daszkiewicz, Marek'
'Gulay, Lubomir D.'
'Lychmanyuk, Olga S.'
_publ_section_title
;
 Ln₃M~1{-~δ}TX₇ -- quasi-isostructural compounds:
 stereochemistry and silver-ion motion in the Ln₃Ag~1{-~δ}GeS₇ (Ln
 = La--Nd, Sm, Gd--Er and Y; δ = 0.11--0.50) compounds
;
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              126
_journal_page_last               133
_journal_paper_doi               10.1107/S010876810900144X
_journal_volume                  65
_journal_year                    2009
_chemical_formula_moiety         'Ag0.74 Ge S7 Sm3'
_chemical_formula_sum            'Ag0.74 Ge S7 Sm3'
_chemical_formula_weight         827.34
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           173
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  'P 6c'
_symmetry_space_group_name_H-M   'P 63'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            2
_cell_length_a                   10.0809(14)
_cell_length_b                   10.0809(14)
_cell_length_c                   5.7604(12)
_cell_measurement_reflns_used    601
_cell_measurement_temperature    295(2)
_cell_measurement_theta_max      25.31
_cell_measurement_theta_min      4.24
_cell_volume                     506.97(15)
_computing_cell_refinement       'CrysAlis RED'
_computing_data_collection       'CrysAlis CCD (Oxford Diffraction, 2007)'
_computing_data_reduction        'CrysAlis RED'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      295(2)
_diffrn_detector_area_resol_mean '1024x1024 with blocks 2x2, 33.133pixel/mm'
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'KUMA KM-4 with area CCD detector'
_diffrn_measurement_method       ω-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0461
_diffrn_reflns_av_sigmaI/netI    0.0193
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       6
_diffrn_reflns_limit_l_min       -6
_diffrn_reflns_number            4935
_diffrn_reflns_theta_full        25.31
_diffrn_reflns_theta_max         25.31
_diffrn_reflns_theta_min         4.24
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    22.803
_exptl_absorpt_correction_T_max  0.242
_exptl_absorpt_correction_T_min  0.029
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'CrysAlis (Oxford Diffraction, 2007)'
_exptl_crystal_colour            'dark red'
_exptl_crystal_density_diffrn    5.420
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             729
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.09
_refine_diff_density_max         0.699
_refine_diff_density_min         -0.511
_refine_ls_abs_structure_details
'Flack H D (1983), Acta Cryst. A39, 876-881, 270 Friedel pairs'
_refine_ls_abs_structure_Flack   -0.029(18)
_refine_ls_extinction_coef       0.0097(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.169
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     43
_refine_ls_number_reflns         604
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.168
_refine_ls_R_factor_all          0.0142
_refine_ls_R_factor_gt           0.0140
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         <0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0181P)²+0.5015P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0344
_refine_ls_wR_factor_ref         0.0344
_reflns_number_gt                601
_reflns_number_total             604
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            bp5017.cif
_cod_data_source_block           sm
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Hexagonal' changed to 'hexagonal'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Hexagonal' changed to 'hexagonal'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_database_code               2104307
_cod_database_fobs_code          2104307
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x, -y, z+1/2'
'y, -x+y, z+1/2'
'x-y, x, z+1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sm Sm 0.87145(3) 0.64163(2) 0.24346(12) 0.00914(12) Uani d . 1 . .
Ag Ag1 0.0000 0.0000 0.137(3) 0.075(5) Uani d SP 0.548(18) . .
Ag Ag2 0.0000 0.0000 0.967(3) 0.020(4) Uani d SP 0.187(18) . .
Ge Ge1 0.3333 0.6667 0.32606(16) 0.0069(2) Uani d S 1 . .
S S1 0.3333 0.6667 0.9482(4) 0.0092(5) Uani d S 1 . .
S S2 0.90414(13) 0.73662(14) 0.7212(2) 0.0140(3) Uani d . 1 . .
S S3 0.58278(15) 0.47996(14) 0.9828(2) 0.0091(3) Uani d . 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sm Sm -0.1638 3.4418 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
S3 Sm S2 3_664 6_654 104.33(4) ?
S3 Sm S2 3_664 5_564 141.02(5) ?
S2 Sm S2 6_654 5_564 90.15(5) ?
S3 Sm S2 3_664 . 137.02(4) ?
S2 Sm S2 6_654 . 80.83(4) ?
S2 Sm S2 5_564 . 80.38(4) ?
S3 Sm S3 3_664 1_554 75.34(5) ?
S2 Sm S3 6_654 1_554 141.56(4) ?
S2 Sm S3 5_564 1_554 71.24(4) ?
S2 Sm S3 . 1_554 126.16(4) ?
S3 Sm S1 3_664 4_664 70.70(4) ?
S2 Sm S1 6_654 4_664 148.01(4) ?
S2 Sm S1 5_564 4_664 113.86(3) ?
S2 Sm S1 . 4_664 82.71(5) ?
S3 Sm S1 1_554 4_664 69.31(4) ?
S3 Sm S3 3_664 6_654 72.32(3) ?
S2 Sm S3 6_654 6_654 69.33(3) ?
S2 Sm S3 5_564 6_654 145.90(4) ?
S2 Sm S3 . 6_654 69.94(4) ?
S3 Sm S3 1_554 6_654 140.72(3) ?
S1 Sm S3 4_664 6_654 79.31(3) ?
S3 Sm S2 3_664 1_554 72.34(4) ?
S2 Sm S2 6_654 1_554 76.69(4) ?
S2 Sm S2 5_564 1_554 76.31(4) ?
S2 Sm S2 . 1_554 147.33(5) ?
S3 Sm S2 1_554 1_554 66.51(4) ?
S1 Sm S2 4_664 1_554 127.74(5) ?
S3 Sm S2 6_654 1_554 121.84(3) ?
S3 Sm Ag1 3_664 1_665 130.3(3) ?
S2 Sm Ag1 6_654 1_665 45.60(4) ?
S2 Sm Ag1 5_564 1_665 45.47(4) ?
S2 Sm Ag1 . 1_665 83.9(3) ?
S3 Sm Ag1 1_554 1_665 104.81(18) ?
S1 Sm Ag1 4_664 1_665 157.29(18) ?
S3 Sm Ag1 6_654 1_665 112.96(14) ?
S2 Sm Ag1 1_554 1_665 63.4(3) ?
S3 Sm Ag2 3_664 4_664 154.81(13) ?
S2 Sm Ag2 6_654 4_664 50.57(10) ?
S2 Sm Ag2 5_564 4_664 50.43(10) ?
S2 Sm Ag2 . 4_664 50.9(3) ?
S3 Sm Ag2 1_554 4_664 121.66(11) ?
S1 Sm Ag2 4_664 4_664 130.6(2) ?
S3 Sm Ag2 6_654 4_664 96.56(15) ?
S2 Sm Ag2 1_554 4_664 96.4(3) ?
Ag1 Sm Ag2 1_665 4_664 33.03(12) ?
S3 Sm Ag2 3_664 1_664 116.2(2) ?
S2 Sm Ag2 6_654 1_664 49.52(9) ?
S2 Sm Ag2 5_564 1_664 49.42(9) ?
S2 Sm Ag2 . 1_664 99.7(2) ?
S3 Sm Ag2 1_554 1_664 95.24(15) ?
S1 Sm Ag2 4_664 1_664 161.57(3) ?
S3 Sm Ag2 6_654 1_664 118.78(8) ?
S2 Sm Ag2 1_554 1_664 47.7(2) ?
Ag1 Sm Ag2 1_665 1_664 15.75(13) ?
Ag2 Sm Ag2 4_664 1_664 48.78(2) ?
Ag2 Ag1 Ag2 1_554 4_554 180.000(2) ?
Ag2 Ag1 S2 1_554 4_664 101.8(4) ?
Ag2 Ag1 S2 4_554 4_664 78.2(4) ?
Ag2 Ag1 S2 1_554 6_544 101.8(4) ?
Ag2 Ag1 S2 4_554 6_544 78.2(4) ?
S2 Ag1 S2 4_664 6_544 116.0(3) ?
Ag2 Ag1 S2 1_554 5_454 101.8(4) ?
Ag2 Ag1 S2 4_554 5_454 78.2(4) ?
S2 Ag1 S2 4_664 5_454 116.0(3) ?
S2 Ag1 S2 6_544 5_454 116.0(3) ?
Ag2 Ag1 Ag1 1_554 4_554 0.0000(10) ?
Ag2 Ag1 Ag1 4_554 4_554 180.000(2) ?
S2 Ag1 Ag1 4_664 4_554 101.8(4) ?
S2 Ag1 Ag1 6_544 4_554 101.8(4) ?
S2 Ag1 Ag1 5_454 4_554 101.8(4) ?
Ag2 Ag1 Ag1 1_554 4 180.0000(10) ?
Ag2 Ag1 Ag1 4_554 4 0.0000(10) ?
S2 Ag1 Ag1 4_664 4 78.2(4) ?
S2 Ag1 Ag1 6_544 4 78.2(4) ?
S2 Ag1 Ag1 5_454 4 78.2(4) ?
Ag1 Ag1 Ag1 4_554 4 180.000(2) ?
Ag2 Ag1 Sm 1_554 2_655 100.9(3) ?
Ag2 Ag1 Sm 4_554 2_655 79.1(3) ?
S2 Ag1 Sm 4_664 2_655 58.38(8) ?
S2 Ag1 Sm 6_544 2_655 59.04(8) ?
S2 Ag1 Sm 5_454 2_655 157.3(7) ?
Ag1 Ag1 Sm 4_554 2_655 100.9(3) ?
Ag1 Ag1 Sm 4 2_655 79.1(3) ?
Ag2 Ag1 Sm 1_554 1_445 100.9(3) ?
Ag2 Ag1 Sm 4_554 1_445 79.1(3) ?
S2 Ag1 Sm 4_664 1_445 157.3(7) ?
S2 Ag1 Sm 6_544 1_445 58.38(8) ?
S2 Ag1 Sm 5_454 1_445 59.04(8) ?
Ag1 Ag1 Sm 4_554 1_445 100.9(3) ?
Ag1 Ag1 Sm 4 1_445 79.1(3) ?
Sm Ag1 Sm 2_655 1_445 116.48(19) ?
Ag2 Ag1 Sm 1_554 3_565 100.9(3) ?
Ag2 Ag1 Sm 4_554 3_565 79.1(3) ?
S2 Ag1 Sm 4_664 3_565 59.04(8) ?
S2 Ag1 Sm 6_544 3_565 157.3(7) ?
S2 Ag1 Sm 5_454 3_565 58.38(8) ?
Ag1 Ag1 Sm 4_554 3_565 100.9(3) ?
Ag1 Ag1 Sm 4 3_565 79.1(3) ?
Sm Ag1 Sm 2_655 3_565 116.48(19) ?
Sm Ag1 Sm 1_445 3_565 116.48(19) ?
Ag1 Ag2 Ag1 1_556 4 180.000(18) ?
Ag1 Ag2 S2 1_556 1_445 121.3(3) ?
Ag1 Ag2 S2 4 1_445 58.7(3) ?
Ag1 Ag2 S2 1_556 3_565 121.3(3) ?
Ag1 Ag2 S2 4 3_565 58.7(3) ?
S2 Ag2 S2 1_445 3_565 95.5(4) ?
Ag1 Ag2 S2 1_556 2_655 121.3(3) ?
Ag1 Ag2 S2 4 2_655 58.7(3) ?
S2 Ag2 S2 1_445 2_655 95.5(4) ?
S2 Ag2 S2 3_565 2_655 95.5(4) ?
Ag1 Ag2 S2 1_556 4_665 57.8(3) ?
Ag1 Ag2 S2 4 4_665 122.2(3) ?
S2 Ag2 S2 1_445 4_665 179.1(6) ?
S2 Ag2 S2 3_565 4_665 85.13(2) ?
S2 Ag2 S2 2_655 4_665 85.13(2) ?
Ag1 Ag2 S2 1_556 6_545 57.8(3) ?
Ag1 Ag2 S2 4 6_545 122.2(3) ?
S2 Ag2 S2 1_445 6_545 85.13(2) ?
S2 Ag2 S2 3_565 6_545 179.1(6) ?
S2 Ag2 S2 2_655 6_545 85.13(2) ?
S2 Ag2 S2 4_665 6_545 94.2(4) ?
Ag1 Ag2 S2 1_556 5_455 57.8(3) ?
Ag1 Ag2 S2 4 5_455 122.2(3) ?
S2 Ag2 S2 1_445 5_455 85.13(2) ?
S2 Ag2 S2 3_565 5_455 85.13(2) ?
S2 Ag2 S2 2_655 5_455 179.1(6) ?
S2 Ag2 S2 4_665 5_455 94.2(4) ?
S2 Ag2 S2 6_545 5_455 94.2(4) ?
Ag1 Ag2 Ag2 1_556 4_554 180.000(16) ?
Ag1 Ag2 Ag2 4 4_554 0.0000(10) ?
S2 Ag2 Ag2 1_445 4_554 58.7(3) ?
S2 Ag2 Ag2 3_565 4_554 58.7(3) ?
S2 Ag2 Ag2 2_655 4_554 58.7(3) ?
S2 Ag2 Ag2 4_665 4_554 122.2(3) ?
S2 Ag2 Ag2 6_545 4_554 122.2(3) ?
S2 Ag2 Ag2 5_455 4_554 122.2(3) ?
Ag1 Ag2 Ag2 1_556 4 0.000(4) ?
Ag1 Ag2 Ag2 4 4 180.000(8) ?
S2 Ag2 Ag2 1_445 4 121.3(3) ?
S2 Ag2 Ag2 3_565 4 121.3(3) ?
S2 Ag2 Ag2 2_655 4 121.3(3) ?
S2 Ag2 Ag2 4_665 4 57.8(3) ?
S2 Ag2 Ag2 6_545 4 57.8(3) ?
S2 Ag2 Ag2 5_455 4 57.8(3) ?
Ag2 Ag2 Ag2 4_554 4 180.000(5) ?
Ag1 Ag2 Sm 1_556 5_455 112.1(3) ?
Ag1 Ag2 Sm 4 5_455 67.9(3) ?
S2 Ag2 Sm 1_445 5_455 53.47(13) ?
S2 Ag2 Sm 3_565 5_455 54.05(14) ?
S2 Ag2 Sm 2_655 5_455 126.6(6) ?
S2 Ag2 Sm 4_665 5_455 126.61(9) ?
S2 Ag2 Sm 6_545 5_455 126.04(9) ?
S2 Ag2 Sm 5_455 5_455 54.29(4) ?
Ag2 Ag2 Sm 4_554 5_455 67.9(3) ?
Ag2 Ag2 Sm 4 5_455 112.1(3) ?
Ag1 Ag2 Sm 1_556 4_665 112.1(3) ?
Ag1 Ag2 Sm 4 4_665 67.9(3) ?
S2 Ag2 Sm 1_445 4_665 126.6(6) ?
S2 Ag2 Sm 3_565 4_665 53.47(13) ?
S2 Ag2 Sm 2_655 4_665 54.05(14) ?
S2 Ag2 Sm 4_665 4_665 54.29(4) ?
S2 Ag2 Sm 6_545 4_665 126.61(9) ?
S2 Ag2 Sm 5_455 4_665 126.04(9) ?
Ag2 Ag2 Sm 4_554 4_665 67.9(3) ?
Ag2 Ag2 Sm 4 4_665 112.1(3) ?
Sm Ag2 Sm 5_455 4_665 106.7(3) ?
S1 Ge1 S3 1_554 5_564 113.90(4) ?
S1 Ge1 S3 1_554 6_554 113.90(4) ?
S3 Ge1 S3 5_564 6_554 104.71(5) ?
S1 Ge1 S3 1_554 4_664 113.90(4) ?
S3 Ge1 S3 5_564 4_664 104.71(5) ?
S3 Ge1 S3 6_554 4_664 104.71(5) ?
Ge1 S1 Sm 1_556 6 113.29(4) ?
Ge1 S1 Sm 1_556 4_665 113.29(4) ?
Sm S1 Sm 6 4_665 105.40(5) ?
Ge1 S1 Sm 1_556 5_565 113.29(4) ?
Sm S1 Sm 6 5_565 105.40(5) ?
Sm S1 Sm 4_665 5_565 105.40(5) ?
Ag2 S2 Ag2 1_665 4_664 63.49(3) ?
Ag1 S2 Sm 4_665 5_565 76.01(6) ?
Ag2 S2 Sm 1_665 5_565 75.96(5) ?
Ag2 S2 Sm 4_664 5_565 78.89(7) ?
Ag1 S2 Sm 4_665 6_655 75.49(6) ?
Ag2 S2 Sm 1_665 6_655 75.52(5) ?
Ag2 S2 Sm 4_664 6_655 78.43(7) ?
Sm S2 Sm 5_565 6_655 149.30(5) ?
Ag1 S2 Sm 4_665 . 95.3(4) ?
Ag2 S2 Sm 1_665 . 138.3(3) ?
Ag2 S2 Sm 4_664 . 74.8(3) ?
Sm S2 Sm 5_565 . 97.16(4) ?
Sm S2 Sm 6_655 . 96.56(4) ?
Ag1 S2 Sm 4_665 1_556 117.4(4) ?
Ag2 S2 Sm 1_665 1_556 74.4(3) ?
Ag2 S2 Sm 4_664 1_556 137.8(3) ?
Sm S2 Sm 5_565 1_556 91.80(4) ?
Sm S2 Sm 6_655 1_556 91.29(4) ?
Sm S2 Sm . 1_556 147.33(5) ?
Ge1 S3 Sm 4_665 2_656 91.34(4) ?
Ge1 S3 Sm 4_665 1_556 88.62(4) ?
Sm S3 Sm 2_656 1_556 110.57(5) ?
Ge1 S3 Sm 4_665 5_565 120.21(6) ?
Sm S3 Sm 2_656 5_565 142.07(5) ?
Sm S3 Sm 1_556 5_565 92.04(4) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Sm S3 3_664 2.8332(13) ?
Sm S2 6_654 2.8336(12) ?
Sm S2 5_564 2.8602(12) ?
Sm S2 . 2.8780(17) ?
Sm S3 1_554 2.9389(14) ?
Sm S1 4_664 2.9825(10) ?
Sm S3 6_654 3.0127(13) ?
Sm S2 1_554 3.1243(17) ?
Sm Ag1 1_665 3.229(3) ?
Sm Ag2 4_664 3.421(6) ?
Sm Ag2 1_664 3.548(8) ?
Ag1 Ag2 1_554 0.981(7) ?
Ag1 Ag2 4_554 1.899(7) ?
Ag1 S2 4_664 2.378(4) ?
Ag1 S2 6_544 2.378(4) ?
Ag1 S2 5_454 2.378(4) ?
Ag1 Ag1 4_554 2.8802(6) ?
Ag1 Ag1 4 2.8802(6) ?
Ag1 Sm 2_655 3.229(3) ?
Ag1 Sm 1_445 3.229(3) ?
Ag1 Sm 3_565 3.229(3) ?
Ag2 Ag1 1_556 0.981(7) ?
Ag2 Ag1 4 1.899(7) ?
Ag2 S2 1_445 2.724(9) ?
Ag2 S2 3_565 2.724(9) ?
Ag2 S2 2_655 2.724(9) ?
Ag2 S2 4_665 2.751(9) ?
Ag2 S2 6_545 2.751(9) ?
Ag2 S2 5_455 2.751(9) ?
Ag2 Ag2 4_554 2.8802(6) ?
Ag2 Ag2 4 2.8802(6) ?
Ag2 Sm 5_455 3.421(6) ?
Ag2 Sm 4_665 3.421(6) ?
Ge1 S1 1_554 2.177(2) ?
Ge1 S3 5_564 2.2281(14) ?
Ge1 S3 6_554 2.2281(14) ?
Ge1 S3 4_664 2.2281(14) ?
S1 Ge1 1_556 2.177(2) ?
S1 Sm 6 2.9825(10) ?
S1 Sm 4_665 2.9825(10) ?
S1 Sm 5_565 2.9825(10) ?
S2 Ag1 4_665 2.378(4) ?
S2 Ag2 1_665 2.724(9) ?
S2 Ag2 4_664 2.751(9) ?
S2 Sm 5_565 2.8336(12) ?
S2 Sm 6_655 2.8602(12) ?
S2 Sm 1_556 3.1243(17) ?
S3 Ge1 4_665 2.2281(14) ?
S3 Sm 2_656 2.8332(13) ?
S3 Sm 1_556 2.9389(14) ?
S3 Sm 5_565 3.0127(13) ?
