#------------------------------------------------------------------------------ #$Date: 2016-04-02 23:02:37 +0300 (Sat, 02 Apr 2016) $ #$Revision: 180909 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/10/50/2105021.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2105021_Fobs loop_ _publ_author_name 'Siegler, Maxime A.' 'Hao, Xiang' 'Parkin, Sean' 'Brock, Carolyn Pratt' _publ_section_title ; [Ni(H~2~O)~6~](NO~3~)~2~·(15-crown-5)·2H~2~O: three phase transitions and an intermediate modulated phase stable over a range of ca 40K ; _journal_issue 6 _journal_name_full 'Acta Crystallographica Section B' _journal_page_first 486 _journal_page_last 498 _journal_volume 67 _journal_year 2011 _space_group_IT_number 12 _symmetry_space_group_name_Hall '-I 2y' _symmetry_space_group_name_H-M 'I 1 2/m 1' _cell_angle_alpha 90.000 _cell_angle_beta 101.680 _cell_angle_gamma 90.000 _cell_length_a 12.3790 _cell_length_b 12.5580 _cell_length_c 8.1200 _exptl_crystal_F_000 580.00 _reflns_d_resolution_high 0.7736 _cod_data_source_file hw5018303K_Isup29.hkl _cod_data_source_block 303K_I #BEGIN Tags that were not found in dictionaries: _shelx_title ' k06205 in I2/m' _shelx_refln_list_code 4 _shelx_f_calc_maximum 142.68 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z' 'x+1/2, y+1/2, z+1/2' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z' '-x+1/2, -y+1/2, -z+1/2' 'x+1/2, -y+1/2, z+1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 5144.52 4457.50 74.36 o 4 0 0 960.78 828.36 16.30 o 6 0 0 9192.17 9588.66 161.84 o 8 0 0 1751.42 1814.98 53.28 o 10 0 0 236.05 225.87 12.32 o 12 0 0 62.12 99.82 11.13 o 14 0 0 6.23 -11.53 18.29 o 1 1 0 7711.80 7081.15 135.53 o 3 1 0 1140.81 947.11 11.66 o 5 1 0 663.62 567.08 6.97 o 7 1 0 875.98 764.99 11.33 o 9 1 0 969.20 968.24 38.58 o 11 1 0 123.28 130.56 10.96 o 13 1 0 86.52 70.12 14.52 o 15 1 0 25.42 42.30 15.56 o 0 2 0 12664.85 12047.85 311.67 o 2 2 0 60.44 42.85 3.58 o 4 2 0 2510.65 2362.08 29.89 o 6 2 0 1995.39 1981.65 26.84 o 8 2 0 825.07 866.33 16.88 o 10 2 0 266.96 281.14 10.89 o 12 2 0 101.18 112.16 9.17 o 14 2 0 15.86 13.40 10.22 o 1 3 0 58.93 84.31 3.58 o 3 3 0 10761.50 10819.96 177.36 o 5 3 0 5275.43 5181.77 58.49 o 7 3 0 349.55 378.46 6.88 o 9 3 0 306.41 306.36 8.66 o 11 3 0 410.00 447.18 13.96 o 13 3 0 121.97 123.93 12.12 o 15 3 0 26.70 19.16 21.92 o 0 4 0 775.76 737.30 13.49 o 2 4 0 9285.25 8771.86 116.86 o 4 4 0 7412.24 7366.44 99.14 o 6 4 0 1071.62 1045.69 19.29 o 8 4 0 579.60 574.64 12.74 o 10 4 0 139.87 144.87 14.52 o 12 4 0 101.14 97.88 11.93 o 14 4 0 39.69 46.20 11.94 o 1 5 0 366.81 365.72 6.97 o 3 5 0 533.17 661.04 14.12 o 5 5 0 2435.32 2314.26 29.70 o 7 5 0 218.58 268.42 6.57 o 9 5 0 5.77 -1.59 6.36 o 11 5 0 310.28 287.73 16.36 o 13 5 0 79.87 94.70 14.10 o 0 6 0 1756.89 1743.14 32.54 o 2 6 0 5978.91 6005.47 72.69 o 4 6 0 1791.02 1808.76 24.45 o 6 6 0 591.38 534.14 9.70 o 8 6 0 384.42 383.93 10.58 o 10 6 0 135.11 158.50 9.23 o 12 6 0 42.69 36.67 9.94 o 14 6 0 25.51 24.77 13.77 o 1 7 0 1777.00 1607.41 21.57 o 3 7 0 392.54 402.25 7.03 o 5 7 0 1104.62 1091.61 19.54 o 7 7 0 296.47 304.79 8.36 o 9 7 0 88.04 79.04 6.76 o 11 7 0 207.59 215.14 13.28 o 13 7 0 18.62 34.06 17.10 o 0 8 0 1331.08 1235.90 37.34 o 2 8 0 671.32 685.67 12.00 o 4 8 0 61.39 67.62 4.01 o 6 8 0 167.06 164.02 7.58 o 8 8 0 312.55 301.11 10.96 o 10 8 0 186.82 196.95 11.73 o 12 8 0 2.11 9.57 14.48 o 1 9 0 715.64 772.96 18.43 o 3 9 0 70.47 65.00 4.19 o 5 9 0 107.78 124.56 6.76 o 7 9 0 238.15 228.86 15.90 o 9 9 0 202.20 184.38 10.92 o 11 9 0 28.37 20.65 9.91 o 13 9 0 10.41 -1.42 23.33 o 0 10 0 1410.18 1603.49 71.65 o 2 10 0 170.60 187.94 6.84 o 4 10 0 34.79 44.74 5.20 o 6 10 0 312.17 333.17 12.11 o 8 10 0 169.22 165.15 9.45 o 10 10 0 39.36 42.60 10.74 o 12 10 0 7.33 7.56 16.03 o 1 11 0 65.87 78.93 10.34 o 3 11 0 83.40 83.69 6.32 o 5 11 0 115.03 137.48 6.96 o 7 11 0 55.26 42.67 7.75 o 9 11 0 21.47 27.25 8.12 o 11 11 0 9.74 18.61 15.44 o 0 12 0 215.71 205.69 17.29 o 2 12 0 98.00 105.63 7.55 o 4 12 0 189.04 195.69 9.55 o 6 12 0 111.54 101.64 9.55 o 8 12 0 4.96 -2.51 17.89 o 10 12 0 9.15 17.05 14.15 o 1 13 0 45.95 54.00 7.35 o 3 13 0 231.56 289.53 12.61 o 5 13 0 109.75 136.11 15.11 o 7 13 0 6.83 3.02 8.88 o 9 13 0 10.65 -5.04 12.73 o 0 14 0 2.30 15.31 15.11 o 2 14 0 17.49 17.90 7.11 o 4 14 0 32.92 13.29 11.16 o 6 14 0 10.22 28.77 14.71 o 1 15 0 4.14 -0.80 8.75 o 3 15 0 10.38 4.87 11.84 o 5 15 0 7.66 15.53 24.66 o 0 16 0 35.24 21.48 17.50 o 2 16 0 24.22 33.40 16.70 o -15 0 1 46.16 40.56 19.88 o -13 0 1 46.98 39.77 17.50 o -11 0 1 550.95 611.22 29.82 o -9 0 1 2639.16 2962.65 60.84 o -7 0 1 3209.28 3441.04 53.28 o -5 0 1 562.52 460.11 7.95 o -3 0 1 20357.51 20704.78 736.48 o -1 0 1 1717.29 1320.66 20.69 o 1 0 1 326.78 266.83 5.96 o 3 0 1 1830.56 1707.20 38.58 o 5 0 1 49.20 42.55 1.99 o 7 0 1 184.89 192.47 8.75 o 9 0 1 942.23 1036.73 37.77 o 11 0 1 19.02 30.62 9.15 o 13 0 1 0.50 -4.38 13.92 o 15 0 1 41.13 7.95 34.99 o -14 1 1 42.53 39.27 13.28 o -12 1 1 65.81 54.19 7.95 o -10 1 1 713.74 797.82 36.19 o -8 1 1 710.06 636.36 11.73 o -6 1 1 421.03 593.28 17.69 o -4 1 1 437.82 423.41 6.04 o -2 1 1 146.61 147.25 5.17 o 0 1 1 148.53 191.68 6.16 o 2 1 1 16489.62 14614.27 247.04 o 4 1 1 1857.71 2165.42 34.40 o 6 1 1 727.47 724.53 11.75 o 8 1 1 1855.72 1932.44 69.99 o 10 1 1 351.63 358.17 16.11 o 12 1 1 41.05 43.88 7.01 o 14 1 1 30.07 29.88 12.36 o -15 2 1 47.39 46.04 15.91 o -13 2 1 87.15 93.66 9.91 o -11 2 1 247.49 234.71 9.45 o -9 2 1 871.99 939.99 14.06 o -7 2 1 2653.59 2476.71 32.28 o -5 2 1 307.82 300.90 4.50 o -3 2 1 8731.91 9930.78 132.61 o -1 2 1 10263.29 9338.88 116.13 o 1 2 1 1789.00 1763.15 24.70 o 3 2 1 32.57 52.29 3.18 o 5 2 1 604.31 440.05 6.19 o 7 2 1 74.67 68.35 4.57 o 9 2 1 45.36 46.36 6.16 o 11 2 1 4.61 2.42 7.53 o 13 2 1 26.89 14.60 22.87 o 15 2 1 22.80 27.55 20.65 o -14 3 1 130.15 145.47 12.23 o -12 3 1 133.97 140.64 10.94 o -10 3 1 52.10 46.54 4.45 o -8 3 1 474.87 411.80 9.36 o -6 3 1 3858.74 3991.48 46.03 o -4 3 1 2384.44 2508.54 29.54 o -2 3 1 4415.56 4308.32 55.36 o 0 3 1 6704.71 6772.32 79.42 o 2 3 1 5440.91 5362.13 74.72 o 4 3 1 2881.77 3033.06 38.29 o 6 3 1 1150.92 1139.79 16.39 o 8 3 1 197.52 209.68 6.97 o 10 3 1 183.20 137.97 8.01 o 12 3 1 119.92 122.06 11.72 o 14 3 1 47.11 23.05 14.10 o -15 4 1 32.40 39.73 11.80 o -13 4 1 160.84 184.22 12.23 o -11 4 1 285.37 293.41 14.12 o -9 4 1 282.96 259.42 7.64 o -7 4 1 448.28 430.68 7.70 o -5 4 1 4310.19 4387.79 53.41 o -3 4 1 5579.45 5159.60 68.12 o -1 4 1 201.01 168.72 2.66 o 1 4 1 7.52 7.01 1.24 o 3 4 1 1306.57 1210.80 18.10 o 5 4 1 1800.44 1809.96 22.64 o 7 4 1 88.63 91.41 3.51 o 9 4 1 21.08 12.05 3.79 o 11 4 1 34.78 32.41 12.28 o 13 4 1 123.19 114.58 18.06 o -14 5 1 107.87 94.77 13.31 o -12 5 1 150.99 129.28 23.66 o -10 5 1 47.93 50.38 12.73 o -8 5 1 173.93 179.73 13.72 o -6 5 1 573.49 631.29 10.54 o -4 5 1 589.31 602.31 8.55 o -2 5 1 297.46 336.34 4.91 o 0 5 1 1681.15 1690.03 21.78 o 2 5 1 47.11 66.46 2.98 o 4 5 1 5301.47 5322.22 68.37 o 6 5 1 9.54 10.04 2.38 o 8 5 1 61.78 57.54 4.47 o 10 5 1 280.25 302.52 12.49 o 12 5 1 98.88 102.90 12.51 o 14 5 1 24.45 29.93 21.28 o -13 6 1 74.93 97.82 12.23 o -11 6 1 243.70 242.75 24.65 o -9 6 1 569.93 613.31 17.51 o -7 6 1 139.40 134.06 5.25 o -5 6 1 2505.86 2511.37 35.59 o -3 6 1 2875.83 2885.82 34.99 o -1 6 1 760.05 752.86 9.42 o 1 6 1 1075.57 976.70 13.07 o 3 6 1 1166.38 1259.35 16.81 o 5 6 1 406.55 369.30 6.73 o 7 6 1 385.88 391.39 12.53 o 9 6 1 39.12 37.71 6.36 o 11 6 1 26.50 24.80 13.65 o 13 6 1 64.36 93.44 38.18 o -14 7 1 33.54 45.86 16.20 o -12 7 1 50.54 53.47 11.33 o -10 7 1 85.97 82.29 7.05 o -8 7 1 646.22 701.30 17.94 o -6 7 1 284.66 240.14 16.50 o -4 7 1 159.99 140.43 10.34 o -2 7 1 1366.82 1318.10 29.23 o 0 7 1 1216.81 1195.03 16.43 o 2 7 1 778.61 829.52 11.38 o 4 7 1 716.24 713.15 24.45 o 6 7 1 50.29 55.38 4.77 o 8 7 1 435.34 475.26 20.28 o 10 7 1 150.18 171.19 10.26 o 12 7 1 31.28 28.46 16.70 o -13 8 1 19.07 17.51 13.06 o -11 8 1 64.74 48.20 9.28 o -9 8 1 273.16 253.40 10.12 o -7 8 1 200.45 194.42 19.69 o -5 8 1 85.00 76.34 8.35 o -3 8 1 108.63 118.90 4.22 o -1 8 1 759.96 847.02 17.89 o 1 8 1 627.64 697.30 11.89 o 3 8 1 7.01 5.81 1.99 o 5 8 1 2.60 5.99 3.60 o 7 8 1 313.07 360.88 11.95 o 9 8 1 45.94 41.59 6.88 o 11 8 1 12.04 10.88 14.48 o 13 8 1 9.30 11.27 14.75 o -12 9 1 21.57 12.26 11.33 o -10 9 1 59.86 54.67 9.74 o -8 9 1 256.43 239.16 9.63 o -6 9 1 155.53 136.68 6.57 o -4 9 1 183.40 179.04 5.62 o -2 9 1 375.66 387.93 14.52 o 0 9 1 992.62 971.27 22.42 o 2 9 1 736.58 735.26 22.66 o 4 9 1 34.05 27.46 3.51 o 6 9 1 90.03 102.29 8.21 o 8 9 1 208.95 172.68 8.70 o 10 9 1 65.00 62.61 11.61 o 12 9 1 12.08 7.53 19.69 o -11 10 1 41.29 31.31 12.43 o -9 10 1 123.65 110.78 9.94 o -7 10 1 191.21 158.10 12.92 o -5 10 1 164.01 161.18 6.60 o -3 10 1 643.18 752.02 21.20 o -1 10 1 786.48 772.12 21.07 o 1 10 1 463.75 449.04 12.78 o 3 10 1 344.94 390.94 11.49 o 5 10 1 119.86 117.77 7.25 o 7 10 1 91.09 91.59 8.14 o 9 10 1 59.23 48.51 10.74 o 11 10 1 16.07 11.53 15.47 o -10 11 1 28.92 36.15 12.07 o -8 11 1 49.04 52.67 10.94 o -6 11 1 45.33 47.20 8.21 o -4 11 1 144.89 154.77 8.69 o -2 11 1 24.55 23.49 9.15 o 0 11 1 38.99 46.99 13.92 o 2 11 1 234.24 255.01 8.83 o 4 11 1 29.67 28.44 5.20 o 6 11 1 49.69 46.76 15.71 o 8 11 1 55.91 38.73 8.26 o 10 11 1 20.52 34.04 15.31 o -9 12 1 22.97 22.86 9.96 o -7 12 1 62.28 58.48 9.39 o -5 12 1 24.04 20.45 8.75 o -3 12 1 92.62 73.35 6.88 o -1 12 1 18.56 19.16 5.15 o 1 12 1 0.71 -5.98 9.15 o 3 12 1 70.48 59.62 6.97 o 5 12 1 77.46 63.62 8.10 o 7 12 1 27.76 23.41 8.21 o 9 12 1 11.60 -9.20 10.95 o -8 13 1 16.15 30.48 15.31 o -6 13 1 83.65 93.68 9.34 o -4 13 1 90.96 82.87 11.93 o -2 13 1 34.54 21.48 11.26 o 0 13 1 34.00 33.95 7.01 o 2 13 1 72.76 74.40 8.15 o 4 13 1 74.59 78.45 11.14 o 6 13 1 67.74 75.56 12.50 o 8 13 1 9.92 8.85 11.25 o -7 14 1 14.76 12.58 13.17 o -5 14 1 45.72 60.18 11.37 o -3 14 1 61.18 64.61 11.14 o -1 14 1 38.08 41.12 17.89 o 1 14 1 17.36 23.74 21.47 o 3 14 1 42.72 30.90 9.84 o 5 14 1 49.89 63.17 12.11 o 7 14 1 4.12 7.94 12.90 o -6 15 1 12.06 19.16 12.70 o -4 15 1 24.30 16.10 16.30 o -2 15 1 24.23 26.62 20.68 o 0 15 1 22.58 6.75 10.28 o 2 15 1 20.32 13.52 13.92 o 4 15 1 21.81 27.84 17.10 o -1 16 1 16.97 33.40 25.05 o 1 16 1 16.93 -5.17 16.70 o -16 0 2 24.62 -25.06 25.06 o -14 0 2 78.53 88.28 19.09 o -12 0 2 25.16 38.97 10.74 o -10 0 2 525.27 511.81 15.12 o -8 0 2 1632.41 1281.69 28.64 o -6 0 2 962.11 963.97 17.50 o -4 0 2 296.69 293.48 6.36 o -2 0 2 8987.46 7278.98 112.54 o 0 0 2 11478.25 11929.76 211.96 o 2 0 2 538.61 547.20 11.14 o 4 0 2 65.46 57.66 3.98 o 6 0 2 2.77 5.57 2.39 o 8 0 2 707.96 703.47 27.83 o 10 0 2 96.23 77.94 9.15 o 12 0 2 53.93 40.56 11.13 o 14 0 2 22.79 23.46 33.40 o -15 1 2 28.26 28.63 14.66 o -13 1 2 39.75 44.14 7.55 o -11 1 2 47.98 43.44 3.98 o -9 1 2 496.59 539.60 9.96 o -7 1 2 1422.83 1457.62 19.07 o -5 1 2 13.64 14.90 1.53 o -3 1 2 3238.57 2844.02 32.53 o 1 1 2 347.63 296.95 4.11 o 3 1 2 332.69 269.81 6.97 o 5 1 2 1236.08 1248.95 19.93 o 7 1 2 771.18 780.36 12.21 o 9 1 2 324.39 325.37 14.84 o 11 1 2 127.23 123.61 20.28 o 13 1 2 4.92 -16.98 18.30 o -14 2 2 68.15 44.03 21.28 o -12 2 2 154.51 168.97 9.94 o -10 2 2 323.94 345.47 7.73 o -8 2 2 62.39 64.87 3.15 o -6 2 2 70.48 87.02 7.56 o -4 2 2 316.26 294.45 7.75 o -2 2 2 2333.39 2094.74 24.55 o 0 2 2 5353.75 4850.49 66.41 o 2 2 2 26.27 33.99 2.35 o 4 2 2 132.56 100.53 3.38 o 6 2 2 4.27 2.76 2.20 o 8 2 2 180.53 183.29 7.58 o 10 2 2 139.71 143.18 9.04 o 12 2 2 94.47 100.41 9.70 o 14 2 2 27.64 37.90 14.26 o -15 3 2 23.62 26.24 50.70 o -13 3 2 102.94 102.06 9.63 o -11 3 2 181.42 170.76 7.21 o -9 3 2 238.14 331.02 8.29 o -7 3 2 171.98 211.20 4.76 o -5 3 2 2025.43 1961.61 26.92 o -3 3 2 1083.38 1033.56 14.11 o -1 3 2 35.69 42.01 2.98 o 1 3 2 905.34 891.45 18.10 o 3 3 2 3335.86 3573.61 87.89 o 5 3 2 1601.66 1734.73 25.19 o 7 3 2 823.08 711.10 15.52 o 9 3 2 209.21 215.95 11.44 o 11 3 2 121.86 112.36 17.30 o 13 3 2 39.61 47.50 17.50 o -14 4 2 44.58 53.26 10.87 o -12 4 2 324.44 347.98 17.70 o -10 4 2 83.60 58.10 5.32 o -8 4 2 3.78 14.29 3.09 o -6 4 2 1713.63 1781.06 24.74 o -4 4 2 2681.97 2361.84 28.74 o -2 4 2 136.70 127.05 3.78 o 0 4 2 37.49 47.66 3.78 o 2 4 2 185.99 198.34 3.82 o 4 4 2 1201.84 1246.56 17.09 o 6 4 2 503.56 517.03 10.41 o 8 4 2 26.90 13.38 6.36 o 10 4 2 123.07 132.14 13.91 o 12 4 2 139.30 166.03 18.27 o 14 4 2 32.06 27.21 19.29 o -15 5 2 18.45 28.68 14.98 o -13 5 2 57.15 59.02 9.54 o -11 5 2 83.08 80.31 20.08 o -9 5 2 64.71 70.34 4.97 o -7 5 2 74.78 63.40 4.37 o -5 5 2 713.08 779.46 12.00 o -3 5 2 1167.06 1094.66 25.45 o -1 5 2 50.04 57.21 1.81 o 1 5 2 1387.11 1324.13 15.60 o 3 5 2 376.50 428.77 6.39 o 5 5 2 300.26 330.01 6.97 o 7 5 2 371.86 370.46 8.85 o 9 5 2 36.92 28.74 7.55 o 11 5 2 53.39 59.54 19.49 o 13 5 2 52.53 95.97 19.05 o -14 6 2 16.08 20.24 10.12 o -12 6 2 199.49 188.43 15.50 o -10 6 2 50.41 32.64 5.96 o -8 6 2 59.26 61.44 5.37 o -6 6 2 1150.21 1089.85 20.09 o -4 6 2 698.20 719.87 10.00 o -2 6 2 412.82 423.23 7.56 o 0 6 2 1132.10 1170.27 13.30 o 2 6 2 11.27 15.92 2.20 o 4 6 2 621.70 683.16 13.19 o 6 6 2 436.91 451.64 10.26 o 8 6 2 25.35 10.41 4.56 o 10 6 2 162.31 174.17 15.81 o 12 6 2 69.46 105.70 16.83 o -13 7 2 7.19 -0.87 19.88 o -11 7 2 128.93 138.75 10.69 o -9 7 2 213.09 220.20 11.13 o -7 7 2 132.90 117.83 13.32 o -5 7 2 240.36 220.72 5.06 o -3 7 2 1058.12 1008.48 31.61 o -1 7 2 608.38 589.03 8.57 o 1 7 2 1500.44 1427.93 23.60 o 3 7 2 431.81 452.20 9.83 o 5 7 2 228.41 262.35 6.79 o 7 7 2 256.02 259.43 11.32 o 9 7 2 211.64 227.06 12.70 o 11 7 2 27.11 45.30 17.50 o 13 7 2 12.86 14.88 19.24 o -12 8 2 30.85 31.98 13.13 o -10 8 2 139.10 141.95 14.32 o -8 8 2 148.53 159.87 9.42 o -6 8 2 61.24 55.63 5.37 o -4 8 2 7.77 15.04 2.65 o -2 8 2 267.06 273.55 6.00 o 0 8 2 248.96 217.95 5.55 o 2 8 2 22.89 15.12 3.15 o 4 8 2 130.64 150.89 13.12 o 6 8 2 41.77 33.01 4.68 o 8 8 2 90.38 87.67 7.13 o 10 8 2 108.63 119.21 13.47 o 12 8 2 6.93 24.22 38.18 o -13 9 2 1.34 -8.32 12.45 o -11 9 2 37.90 33.44 10.32 o -9 9 2 201.34 165.60 9.74 o -7 9 2 183.61 198.06 8.49 o -5 9 2 4.16 3.33 2.66 o -3 9 2 47.14 44.77 3.37 o -1 9 2 854.57 937.88 36.19 o 1 9 2 512.53 487.19 10.61 o 3 9 2 27.56 32.53 5.97 o 5 9 2 86.30 83.20 6.96 o 7 9 2 229.45 211.13 9.75 o 9 9 2 148.11 162.76 13.09 o 11 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