#------------------------------------------------------------------------------ #$Date: 2013-10-24 17:51:33 +0300 (Thu, 24 Oct 2013) $ #$Revision: 89414 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/10/54/2105480.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2105480_Fobs loop_ _publ_author_name 'Jones, Peter G.' 'Taouss, Christina' 'Teschmit, Nicole' 'Thomas, Lena' _publ_section_title ; Methylthioureas and their morpholine and dioxane adducts; hydrogen-bonding patterns ; _journal_coeditor_code GP5065 _journal_issue 4 _journal_name_full 'Acta Crystallographica Section B' _journal_page_first 405 _journal_page_last 413 _journal_volume 69 _journal_year 2013 _space_group_IT_number 61 _symmetry_space_group_name_Hall '-P 2ac 2ab' _symmetry_space_group_name_H-M 'P b c a' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 6.1588 _cell_length_b 11.5953 _cell_length_c 14.6390 _exptl_crystal_F_000 448.00 _reflns_d_resolution_high 0.6912 _[local]_cod_data_source_file gp5065fichtesup3.hkl _[local]_cod_data_source_block fichte #BEGIN Tags that were not found in dictionaries: _shelx_title ' Fichte in Pbca' _shelx_refln_list_code 4 _shelx_f_calc_maximum 177.40 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y, z+1/2' '-x, y+1/2, -z+1/2' 'x+1/2, -y+1/2, -z' '-x, -y, -z' 'x-1/2, y, -z-1/2' 'x, -y-1/2, z-1/2' '-x-1/2, y-1/2, z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 680.05 665.29 4.08 o 4 0 0 1235.78 1119.36 8.29 o 6 0 0 775.09 799.23 17.20 o 8 0 0 517.60 530.65 24.26 o 2 1 0 8046.95 8210.43 15.81 o 4 1 0 2.09 2.58 0.58 o 6 1 0 612.28 618.88 10.75 o 8 1 0 86.40 93.80 7.58 o 0 2 0 4900.72 4706.50 10.74 o 2 2 0 1894.10 1902.15 7.18 o 4 2 0 1110.41 1093.36 8.62 o 6 2 0 91.70 81.57 3.72 o 8 2 0 3.31 6.25 3.45 o 2 3 0 441.89 496.41 4.02 o 4 3 0 3.15 1.95 0.90 o 6 3 0 83.17 78.22 3.94 o 8 3 0 31.85 27.78 4.66 o 0 4 0 945.76 977.90 5.47 o 2 4 0 128.19 173.55 2.08 o 4 4 0 749.11 709.17 7.67 o 6 4 0 81.66 79.69 3.84 o 8 4 0 215.17 233.25 14.76 o 2 5 0 11086.40 11397.32 31.43 o 4 5 0 338.12 332.42 5.25 o 6 5 0 1075.84 1100.03 14.08 o 8 5 0 486.03 458.58 20.58 o 0 6 0 1779.24 1564.19 9.12 o 2 6 0 98.72 123.13 2.07 o 4 6 0 5295.77 5335.96 21.44 o 6 6 0 57.87 52.77 3.33 o 8 6 0 102.82 77.39 13.66 o 2 7 0 794.18 743.90 6.21 o 4 7 0 120.24 135.48 3.77 o 6 7 0 81.31 83.65 4.28 o 8 7 0 5.46 -1.42 10.45 o 0 8 0 4103.77 4126.20 23.07 o 2 8 0 0.01 -0.69 0.69 o 4 8 0 516.66 481.04 8.04 o 6 8 0 0.06 1.70 2.42 o 2 9 0 56.66 61.34 2.53 o 4 9 0 67.49 54.85 3.32 o 6 9 0 224.42 228.57 8.18 o 0 10 0 4122.87 4059.59 29.94 o 2 10 0 766.67 721.57 9.88 o 4 10 0 596.65 636.69 11.47 o 6 10 0 217.87 222.09 9.07 o 2 11 0 2171.69 2081.93 18.28 o 4 11 0 347.83 362.60 9.87 o 6 11 0 993.63 1006.82 22.59 o 0 12 0 859.90 851.58 17.16 o 2 12 0 88.74 71.84 3.76 o 4 12 0 437.09 437.60 11.43 o 6 12 0 144.68 111.99 17.16 o 2 13 0 80.26 84.76 5.01 o 4 13 0 1.30 2.18 2.96 o 0 14 0 276.40 292.53 12.30 o 2 14 0 1.25 1.07 2.48 o 4 14 0 14.21 12.97 5.70 o 2 15 0 374.39 408.96 11.79 o 0 16 0 142.21 106.74 13.39 o 2 16 0 10.93 0.01 6.51 o 1 1 1 816.93 755.62 1.85 o 2 1 1 1564.10 1606.95 4.12 o 3 1 1 233.78 216.18 1.54 o 4 1 1 52.10 54.47 0.97 o 5 1 1 971.89 981.24 5.98 o 6 1 1 388.93 392.04 5.88 o 7 1 1 273.16 285.61 6.76 o 8 1 1 46.67 45.03 3.63 o 0 2 1 6436.50 6691.37 12.04 o 1 2 1 2726.83 2960.61 4.35 o 2 2 1 1242.97 1317.65 3.84 o 3 2 1 1507.89 1476.22 4.67 o 4 2 1 69.38 49.26 1.06 o 5 2 1 2562.62 2554.07 10.78 o 6 2 1 142.29 139.27 3.40 o 7 2 1 0.35 0.58 1.90 o 8 2 1 11.42 11.97 2.36 o 1 3 1 4073.36 4249.34 8.10 o 2 3 1 1246.94 1279.51 3.95 o 3 3 1 5060.14 5192.99 10.60 o 4 3 1 23.18 22.15 0.86 o 5 3 1 38.57 34.92 1.48 o 6 3 1 3.35 1.91 1.26 o 7 3 1 1065.43 1074.66 12.93 o 8 3 1 0.50 3.62 3.37 o 0 4 1 2743.76 2767.50 7.09 o 1 4 1 1879.64 1922.71 4.84 o 2 4 1 272.37 324.91 2.12 o 3 4 1 2.13 4.97 0.61 o 4 4 1 738.95 747.35 4.93 o 5 4 1 419.33 428.88 4.52 o 6 4 1 211.90 203.86 4.51 o 7 4 1 307.81 299.70 6.95 o 8 4 1 4.43 8.13 3.20 o 1 5 1 77.03 73.54 1.16 o 2 5 1 1085.36 1140.38 4.41 o 3 5 1 4.88 2.79 0.57 o 4 5 1 26.01 28.78 1.17 o 5 5 1 34.78 29.93 1.47 o 6 5 1 0.02 0.44 1.33 o 7 5 1 76.30 80.61 3.86 o 8 5 1 23.75 18.62 6.35 o 0 6 1 26.99 41.55 1.35 o 1 6 1 368.85 391.15 2.77 o 2 6 1 354.74 388.94 3.32 o 3 6 1 7.60 5.53 0.49 o 4 6 1 181.83 169.08 2.84 o 5 6 1 10.87 11.71 1.23 o 6 6 1 0.89 0.21 1.42 o 7 6 1 121.10 117.79 4.82 o 8 6 1 127.67 126.65 13.66 o 1 7 1 2700.66 2754.13 8.21 o 2 7 1 601.07 618.93 4.10 o 3 7 1 959.38 887.64 5.60 o 4 7 1 216.37 197.58 3.40 o 5 7 1 13.12 10.88 1.39 o 6 7 1 85.07 75.20 2.88 o 7 7 1 293.67 319.28 7.37 o 8 7 1 32.77 20.62 8.06 o 0 8 1 53.05 46.12 1.69 o 1 8 1 2579.11 2447.52 8.23 o 2 8 1 85.02 74.21 1.54 o 3 8 1 759.94 785.36 6.17 o 4 8 1 241.11 257.83 4.25 o 5 8 1 1682.35 1737.38 12.91 o 6 8 1 1.01 -0.20 1.52 o 7 8 1 6.87 7.08 2.07 o 1 9 1 286.34 294.98 3.32 o 2 9 1 111.05 105.03 2.37 o 3 9 1 781.46 801.72 7.12 o 4 9 1 53.55 48.34 2.26 o 5 9 1 592.13 577.49 8.58 o 6 9 1 161.40 161.69 5.03 o 7 9 1 639.65 631.49 17.76 o 0 10 1 985.75 996.84 8.92 o 1 10 1 33.64 31.11 1.42 o 2 10 1 202.32 177.49 3.53 o 3 10 1 85.60 100.49 3.05 o 4 10 1 53.35 51.57 2.65 o 5 10 1 217.07 212.90 5.51 o 6 10 1 92.87 87.90 3.96 o 7 10 1 3.32 15.35 10.94 o 1 11 1 35.70 32.82 1.62 o 2 11 1 69.79 75.72 2.55 o 3 11 1 60.72 55.60 2.45 o 4 11 1 0.01 -0.16 1.66 o 5 11 1 101.32 95.58 3.97 o 6 11 1 70.97 72.66 4.31 o 0 12 1 222.42 242.38 5.92 o 1 12 1 219.03 213.74 4.24 o 2 12 1 0.03 1.71 1.38 o 3 12 1 469.08 492.88 7.10 o 4 12 1 143.32 148.28 4.85 o 5 12 1 309.70 314.39 7.45 o 6 12 1 275.69 281.16 15.62 o 1 13 1 553.43 557.73 7.39 o 2 13 1 82.18 75.50 3.08 o 3 13 1 1207.78 1227.42 12.54 o 4 13 1 144.40 152.93 5.22 o 5 13 1 163.46 146.19 7.34 o 0 14 1 6.22 3.44 2.21 o 1 14 1 889.50 887.31 10.52 o 2 14 1 17.78 13.88 1.84 o 3 14 1 188.49 179.60 5.53 o 4 14 1 7.77 4.01 3.59 o 1 15 1 328.20 334.53 6.91 o 2 15 1 82.94 89.12 4.10 o 3 15 1 136.49 128.07 10.09 o 0 16 1 1.94 -2.18 4.29 o 1 16 1 4.33 5.88 5.69 o 2 16 1 52.15 61.67 7.32 o 0 0 2 4159.09 4334.75 19.19 o 1 0 2 6974.49 7159.19 12.35 o 2 0 2 3895.80 3963.24 10.16 o 3 0 2 276.32 336.32 2.73 o 4 0 2 929.13 875.72 5.68 o 5 0 2 568.78 576.73 6.02 o 6 0 2 143.35 133.81 4.85 o 7 0 2 11.88 19.11 3.08 o 8 0 2 210.69 206.79 10.23 o 1 1 2 139.47 124.19 0.84 o 2 1 2 1850.40 1960.21 4.25 o 3 1 2 2787.60 2894.27 6.22 o 4 1 2 356.77 348.60 2.42 o 5 1 2 271.11 280.54 3.17 o 6 1 2 605.12 631.16 7.19 o 7 1 2 425.27 414.78 7.96 o 8 1 2 83.88 76.26 4.48 o 0 2 2 38.00 46.48 0.85 o 1 2 2 171.59 164.97 1.08 o 2 2 2 77.88 69.02 0.82 o 3 2 2 649.52 646.42 3.09 o 4 2 2 632.51 651.18 3.73 o 5 2 2 966.51 967.48 6.55 o 6 2 2 174.16 166.62 3.97 o 7 2 2 56.64 60.16 3.17 o 8 2 2 131.77 132.96 5.84 o 1 3 2 82.97 100.61 1.09 o 2 3 2 393.69 431.62 2.28 o 3 3 2 727.93 762.58 3.45 o 4 3 2 7.53 6.33 0.48 o 5 3 2 434.71 435.13 4.44 o 6 3 2 6.09 5.88 1.40 o 7 3 2 37.12 28.93 2.36 o 8 3 2 0.18 2.89 2.27 o 0 4 2 3367.03 3483.09 9.23 o 1 4 2 1854.56 1841.02 4.82 o 2 4 2 78.27 65.48 1.07 o 3 4 2 527.72 533.97 3.07 o 4 4 2 1070.55 1047.68 5.47 o 5 4 2 767.43 761.34 6.63 o 6 4 2 112.48 113.71 3.43 o 7 4 2 22.99 21.16 2.29 o 8 4 2 135.15 127.01 7.75 o 1 5 2 2520.27 2733.77 7.15 o 2 5 2 1706.30 1594.86 5.56 o 3 5 2 480.96 440.42 3.19 o 4 5 2 263.31 260.50 3.54 o 5 5 2 20.63 17.50 1.35 o 6 5 2 588.72 590.18 7.25 o 7 5 2 661.72 665.77 10.78 o 8 5 2 142.06 132.98 8.27 o 0 6 2 637.89 573.44 4.56 o 1 6 2 0.41 2.59 0.59 o 2 6 2 46.89 53.95 1.34 o 3 6 2 281.87 266.97 2.60 o 4 6 2 885.56 895.30 6.75 o 5 6 2 921.40 957.18 8.60 o 6 6 2 241.58 255.38 5.02 o 7 6 2 66.95 65.57 3.70 o 8 6 2 204.78 216.75 12.83 o 1 7 2 100.41 86.21 1.58 o 2 7 2 516.99 500.22 3.91 o 3 7 2 460.66 444.61 4.67 o 4 7 2 180.66 189.46 3.60 o 5 7 2 72.05 68.29 2.53 o 6 7 2 315.30 321.36 5.86 o 7 7 2 386.81 398.05 8.72 o 8 7 2 35.97 37.19 15.20 o 0 8 2 92.14 86.07 2.26 o 1 8 2 628.34 636.76 4.43 o 2 8 2 598.74 591.34 4.66 o 3 8 2 453.54 419.17 4.56 o 4 8 2 1.22 2.45 1.14 o 5 8 2 33.81 35.12 2.12 o 6 8 2 3.92 3.63 1.61 o 7 8 2 4.39 7.32 2.82 o 1 9 2 1524.48 1495.75 7.23 o 2 9 2 818.53 834.06 6.22 o 3 9 2 43.14 43.81 1.75 o 4 9 2 1.14 1.20 1.33 o 5 9 2 18.57 19.43 2.05 o 6 9 2 135.49 139.36 4.88 o 7 9 2 221.85 244.30 10.68 o 0 10 2 2743.27 2710.68 15.21 o 1 10 2 2426.29 2367.28 10.65 o 2 10 2 175.97 163.68 3.29 o 3 10 2 90.12 108.86 3.09 o 4 10 2 428.97 425.13 6.96 o 5 10 2 184.24 202.34 5.51 o 6 10 2 43.74 45.98 3.07 o 7 10 2 1.56 2.23 11.29 o 1 11 2 46.45 45.85 1.73 o 2 11 2 854.09 844.06 7.86 o 3 11 2 609.72 583.51 7.28 o 4 11 2 25.52 26.10 2.22 o 5 11 2 245.97 256.38 6.54 o 6 11 2 137.98 135.35 6.66 o 0 12 2 312.36 342.50 7.00 o 1 12 2 71.22 77.95 2.56 o 2 12 2 1.67 1.03 1.35 o 3 12 2 270.69 265.70 5.36 o 4 12 2 427.19 416.00 7.97 o 5 12 2 154.13 150.50 5.22 o 6 12 2 30.38 31.81 11.07 o 1 13 2 136.88 152.93 3.89 o 2 13 2 104.76 102.63 3.73 o 3 13 2 139.80 150.46 4.56 o 4 13 2 31.08 27.86 2.62 o 5 13 2 14.17 5.92 5.20 o 0 14 2 138.35 148.05 6.08 o 1 14 2 118.02 133.13 4.13 o 2 14 2 8.14 8.39 1.75 o 3 14 2 60.50 60.05 3.24 o 4 14 2 59.43 60.74 6.50 o 1 15 2 304.19 317.46 6.73 o 2 15 2 552.30 562.33 11.34 o 3 15 2 545.88 597.92 17.32 o 0 16 2 359.11 324.30 17.30 o 1 16 2 43.09 27.35 7.49 o 2 16 2 23.99 13.86 7.53 o 1 1 3 8707.05 8864.64 14.03 o 2 1 3 217.47 184.44 1.45 o 3 1 3 140.45 111.95 1.33 o 4 1 3 62.59 91.61 1.45 o 5 1 3 16.37 13.71 0.89 o 6 1 3 916.15 943.50 8.93 o 7 1 3 390.33 391.29 7.23 o 8 1 3 112.07 127.20 5.54 o 0 2 3 6406.34 6721.59 19.19 o 1 2 3 347.02 381.83 1.78 o 2 2 3 177.64 195.25 1.51 o 3 2 3 496.91 464.80 2.94 o 4 2 3 2338.74 2231.73 8.55 o 5 2 3 92.89 80.97 1.67 o 6 2 3 718.13 704.75 7.81 o 7 2 3 4.45 2.79 1.73 o 8 2 3 189.20 198.81 6.98 o 1 3 3 646.27 655.67 2.94 o 2 3 3 5778.18 6041.60 12.25 o 3 3 3 55.88 48.63 0.88 o 4 3 3 699.79 732.53 4.28 o 5 3 3 111.02 101.83 2.39 o 6 3 3 652.44 645.59 7.58 o 7 3 3 3.70 5.82 1.98 o 8 3 3 114.31 122.44 6.05 o 0 4 3 2656.00 2522.83 7.98 o 1 4 3 3383.12 3514.58 7.68 o 2 4 3 1446.43 1532.43 5.28 o 3 4 3 740.81 763.28 3.97 o 4 4 3 661.95 640.08 3.99 o 5 4 3 37.88 40.51 1.84 o 6 4 3 26.74 24.68 1.74 o 7 4 3 16.80 12.22 2.09 o 8 4 3 405.83 410.06 12.41 o 1 5 3 252.81 229.63 2.01 o 2 5 3 220.69 199.36 2.23 o 3 5 3 452.35 472.38 3.04 o 4 5 3 46.24 32.06 1.02 o 5 5 3 162.84 165.80 3.63 o 6 5 3 19.18 20.64 1.61 o 7 5 3 8.18 8.89 2.35 o 8 5 3 5.42 8.70 5.42 o 0 6 3 480.88 490.28 4.62 o 1 6 3 369.30 400.18 3.10 o 2 6 3 130.41 145.67 2.11 o 3 6 3 1.86 2.15 0.58 o 4 6 3 51.48 31.88 1.56 o 5 6 3 310.39 320.50 5.17 o 6 6 3 72.09 77.44 3.16 o 7 6 3 2.96 3.82 2.15 o 8 6 3 171.11 160.27 12.46 o 1 7 3 94.68 111.80 1.82 o 2 7 3 2762.44 2679.01 9.22 o 3 7 3 1319.30 1285.58 7.29 o 4 7 3 348.06 323.49 4.75 o 5 7 3 210.03 209.19 4.38 o 6 7 3 193.34 202.99 5.23 o 7 7 3 62.70 53.22 3.54 o 0 8 3 2921.86 2818.61 12.78 o 1 8 3 63.65 63.26 1.50 o 2 8 3 143.91 122.44 2.32 o 3 8 3 60.06 67.26 1.93 o 4 8 3 1934.79 2008.91 12.97 o 5 8 3 64.09 60.23 2.52 o 6 8 3 233.45 237.52 5.72 o 7 8 3 2.54 1.83 2.42 o 1 9 3 555.31 545.33 4.41 o 2 9 3 812.96 802.36 6.07 o 3 9 3 33.27 37.54 1.63 o 4 9 3 7.38 5.58 1.53 o 5 9 3 0.44 -0.07 1.58 o 6 9 3 989.49 1010.22 12.54 o 7 9 3 86.03 71.77 6.25 o 0 10 3 351.33 347.55 5.81 o 1 10 3 223.87 213.88 3.35 o 2 10 3 52.79 52.35 1.89 o 3 10 3 189.31 181.63 4.00 o 4 10 3 211.08 209.03 4.86 o 5 10 3 103.73 104.89 3.94 o 6 10 3 149.31 148.65 4.97 o 7 10 3 1.78 10.98 10.72 o 1 11 3 82.52 73.64 2.18 o 2 11 3 3.18 3.16 1.25 o 3 11 3 52.65 46.54 2.27 o 4 11 3 110.09 96.24 3.76 o 5 11 3 0.13 -0.56 1.92 o 6 11 3 99.94 94.89 5.79 o 0 12 3 693.09 712.70 10.11 o 1 12 3 56.48 51.58 2.23 o 2 12 3 35.33 35.26 1.86 o 3 12 3 4.45 3.20 1.52 o 4 12 3 590.00 627.60 9.65 o 5 12 3 418.86 439.13 8.72 o 6 12 3 239.92 215.53 18.37 o 1 13 3 102.74 100.41 3.20 o 2 13 3 1299.74 1324.73 12.08 o 3 13 3 36.60 35.05 2.46 o 4 13 3 133.65 132.65 4.76 o 5 13 3 23.29 16.57 4.55 o 0 14 3 1087.94 1075.58 16.77 o 1 14 3 60.15 64.70 2.92 o 2 14 3 41.91 44.43 2.62 o 3 14 3 5.38 4.76 2.02 o 4 14 3 290.33 278.86 14.95 o 1 15 3 2.72 2.40 2.01 o 2 15 3 368.89 380.84 10.51 o 3 15 3 250.18 250.80 13.95 o 0 16 3 4.68 -1.25 7.53 o 1 16 3 6.65 1.69 4.81 o 2 16 3 18.81 14.24 12.00 o 0 0 4 11791.96 12044.63 34.11 o 1 0 4 31469.19 30823.58 59.16 o 2 0 4 80.49 90.92 1.51 o 3 0 4 953.76 873.04 5.17 o 4 0 4 331.08 341.84 3.64 o 5 0 4 1469.33 1447.49 10.64 o 6 0 4 104.73 98.88 4.57 o 7 0 4 46.82 38.66 3.50 o 8 0 4 2.15 5.48 3.32 o 1 1 4 6955.33 6943.99 11.76 o 2 1 4 11.59 8.06 0.48 o 3 1 4 1178.81 1147.03 4.43 o 4 1 4 50.65 54.82 1.10 o 5 1 4 231.10 225.33 2.89 o 6 1 4 2.34 3.91 1.37 o 7 1 4 382.16 389.82 7.34 o 8 1 4 12.47 11.80 2.73 o 0 2 4 2550.77 2633.57 10.00 o 1 2 4 992.87 991.61 3.45 o 2 2 4 53.39 63.84 1.08 o 3 2 4 1354.20 1347.94 5.33 o 4 2 4 28.57 34.04 1.11 o 5 2 4 43.12 42.41 1.50 o 6 2 4 189.96 178.57 4.30 o 7 2 4 0.01 1.74 1.69 o 8 2 4 18.69 13.62 2.82 o 1 3 4 3.89 7.11 0.59 o 2 3 4 197.23 251.20 2.02 o 3 3 4 24.22 32.51 0.87 o 4 3 4 51.39 41.29 1.00 o 5 3 4 23.35 24.14 1.31 o 6 3 4 21.65 19.16 1.57 o 7 3 4 37.84 43.15 2.80 o 8 3 4 13.94 4.87 2.92 o 0 4 4 198.04 206.46 2.81 o 1 4 4 409.11 375.79 2.81 o 2 4 4 99.71 106.48 1.49 o 3 4 4 552.79 559.03 3.19 o 4 4 4 64.26 67.88 1.59 o 5 4 4 496.00 484.00 5.85 o 6 4 4 8.99 7.51 1.41 o 7 4 4 43.03 41.64 3.01 o 8 4 4 2.78 1.00 3.18 o 1 5 4 2851.48 2824.40 8.31 o 2 5 4 200.77 205.98 2.29 o 3 5 4 4236.02 4250.04 9.89 o 4 5 4 15.56 14.55 0.91 o 5 5 4 554.50 560.19 6.52 o 6 5 4 22.08 19.41 1.68 o 7 5 4 862.59 886.83 13.35 o 8 5 4 2.18 4.08 3.72 o 0 6 4 600.73 672.25 5.24 o 1 6 4 1870.81 1869.42 6.55 o 2 6 4 51.10 58.08 1.34 o 3 6 4 2236.57 2283.47 7.77 o 4 6 4 222.16 223.93 3.18 o 5 6 4 1458.43 1460.20 12.18 o 6 6 4 100.95 102.37 3.57 o 7 6 4 6.31 7.72 2.23 o 8 6 4 26.28 33.00 12.84 o 1 7 4 615.91 602.72 4.08 o 2 7 4 95.55 105.31 1.88 o 3 7 4 144.09 139.72 2.35 o 4 7 4 160.60 172.82 3.54 o 5 7 4 123.44 136.50 3.82 o 6 7 4 5.17 3.18 1.70 o 7 7 4 24.50 24.16 2.85 o 0 8 4 823.33 814.50 6.66 o 1 8 4 658.30 662.83 4.71 o 2 8 4 21.30 21.64 1.11 o 3 8 4 32.05 30.97 1.50 o 4 8 4 206.68 193.96 4.00 o 5 8 4 172.18 168.14 4.24 o 6 8 4 20.31 18.20 2.13 o 7 8 4 0.24 2.37 2.58 o 1 9 4 6.89 6.03 0.96 o 2 9 4 94.75 87.28 2.14 o 3 9 4 359.31 343.94 4.73 o 4 9 4 2.86 5.66 1.39 o 5 9 4 76.01 78.41 3.19 o 6 9 4 0.31 2.09 1.95 o 7 9 4 110.68 112.62 10.78 o 0 10 4 66.65 68.30 2.70 o 1 10 4 2202.32 2112.98 10.34 o 2 10 4 45.92 39.94 1.72 o 3 10 4 12.17 15.21 1.54 o 4 10 4 27.07 23.58 1.97 o 5 10 4 755.99 787.85 10.50 o 6 10 4 4.57 3.98 2.35 o 1 11 4 1250.79 1215.30 8.95 o 2 11 4 6.20 8.01 1.25 o 3 11 4 1337.18 1355.42 11.81 o 4 11 4 0.00 1.06 1.67 o 5 11 4 68.38 61.39 3.25 o 6 11 4 20.00 19.64 7.61 o 0 12 4 8.94 9.59 1.84 o 1 12 4 256.66 270.11 4.86 o 2 12 4 120.93 112.14 3.34 o 3 12 4 295.05 283.95 5.83 o 4 12 4 35.79 35.82 2.50 o 5 12 4 454.98 457.52 9.27 o 1 13 4 16.75 13.23 1.59 o 2 13 4 0.32 4.38 1.65 o 3 13 4 30.22 25.92 2.83 o 4 13 4 1.19 0.78 1.88 o 5 13 4 11.07 24.98 8.13 o 0 14 4 23.64 26.82 3.00 o 1 14 4 61.81 68.65 2.95 o 2 14 4 33.01 27.96 2.29 o 3 14 4 6.15 7.41 1.97 o 4 14 4 71.87 47.59 8.36 o 1 15 4 137.19 141.48 4.80 o 2 15 4 1.33 -0.16 2.54 o 3 15 4 299.92 313.20 14.63 o 0 16 4 116.25 94.29 20.20 o 1 16 4 162.85 185.73 29.88 o 1 1 5 39.01 45.06 0.90 o 2 1 5 159.17 141.54 1.53 o 3 1 5 25.43 21.64 0.81 o 4 1 5 6.17 4.73 0.54 o 5 1 5 583.76 592.42 4.90 o 6 1 5 298.51 300.98 5.44 o 7 1 5 121.71 127.61 4.45 o 8 1 5 92.88 84.87 5.17 o 0 2 5 356.12 349.89 3.80 o 1 2 5 344.95 360.04 2.43 o 2 2 5 753.42 832.29 4.10 o 3 2 5 397.08 370.57 2.93 o 4 2 5 4361.87 4318.03 12.10 o 5 2 5 185.78 178.95 2.94 o 6 2 5 244.13 241.69 4.87 o 7 2 5 19.78 17.39 2.00 o 8 2 5 190.94 187.35 8.63 o 1 3 5 827.98 843.67 4.08 o 2 3 5 5128.20 5037.64 10.64 o 3 3 5 220.51 212.20 2.14 o 4 3 5 1027.55 1041.99 5.59 o 5 3 5 0.01 1.22 0.93 o 6 3 5 1409.49 1425.63 12.03 o 7 3 5 0.93 1.57 1.93 o 8 3 5 225.36 221.86 10.26 o 0 4 5 5316.06 5404.01 14.57 o 1 4 5 322.99 336.07 2.76 o 2 4 5 34.12 29.73 0.85 o 3 4 5 209.98 210.71 2.17 o 4 4 5 31.01 36.31 1.09 o 5 4 5 36.19 34.51 1.66 o 6 4 5 340.17 343.28 6.33 o 7 4 5 156.45 151.84 5.66 o 8 4 5 602.10 599.88 23.44 o 1 5 5 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5 49.43 54.81 1.80 o 2 10 5 163.76 146.81 3.23 o 3 10 5 144.47 155.85 4.03 o 4 10 5 413.92 414.19 6.85 o 5 10 5 56.39 50.18 2.72 o 6 10 5 0.69 -2.23 2.94 o 1 11 5 45.20 46.90 1.94 o 2 11 5 57.03 61.81 2.28 o 3 11 5 44.62 49.32 2.54 o 4 11 5 47.78 44.11 2.56 o 5 11 5 55.36 58.50 3.19 o 6 11 5 11.38 -0.59 4.37 o 0 12 5 130.23 115.75 4.60 o 1 12 5 53.05 52.75 2.25 o 2 12 5 1.23 0.40 1.40 o 3 12 5 39.63 36.32 2.61 o 4 12 5 653.55 691.16 10.00 o 5 12 5 315.43 313.01 10.23 o 1 13 5 12.42 7.88 1.49 o 2 13 5 1506.88 1536.45 14.09 o 3 13 5 208.58 214.40 6.07 o 4 13 5 9.91 9.85 2.93 o 5 13 5 1.40 -8.05 8.05 o 0 14 5 2037.37 2133.77 24.69 o 1 14 5 5.39 3.52 1.61 o 2 14 5 76.60 83.81 3.94 o 3 14 5 0.15 -1.30 2.53 o 4 14 5 510.28 489.69 23.48 o 1 15 5 29.21 25.59 2.86 o 2 15 5 291.35 304.18 10.87 o 0 16 5 13.88 2.16 10.02 o 0 0 6 1349.27 1302.36 11.63 o 1 0 6 2222.46 2202.80 9.04 o 2 0 6 4885.93 5189.22 15.07 o 3 0 6 140.91 155.14 2.51 o 4 0 6 451.78 426.09 4.73 o 5 0 6 1017.05 982.57 9.24 o 6 0 6 7.19 8.88 2.08 o 7 0 6 86.06 80.21 5.20 o 8 0 6 88.39 80.22 7.84 o 1 1 6 1879.79 1877.73 6.12 o 2 1 6 844.75 839.30 4.07 o 3 1 6 897.69 845.01 4.49 o 4 1 6 215.64 225.21 2.43 o 5 1 6 5.13 5.29 0.87 o 6 1 6 593.41 601.85 7.70 o 7 1 6 435.20 433.08 7.96 o 8 1 6 37.76 24.21 4.86 o 0 2 6 9.60 6.25 1.24 o 1 2 6 373.02 361.03 2.74 o 2 2 6 426.79 479.29 3.38 o 3 2 6 93.13 106.65 1.80 o 4 2 6 706.52 741.17 4.85 o 5 2 6 249.97 253.64 3.73 o 6 2 6 269.64 267.96 5.58 o 7 2 6 3.26 0.89 1.71 o 8 2 6 291.00 306.74 11.85 o 1 3 6 950.50 1052.39 4.94 o 2 3 6 223.54 221.78 2.34 o 3 3 6 10.98 13.27 0.73 o 4 3 6 44.27 42.93 1.30 o 5 3 6 126.87 116.64 2.78 o 6 3 6 11.80 12.35 1.61 o 7 3 6 42.72 38.65 2.94 o 8 3 6 0.59 0.47 3.37 o 0 4 6 1902.54 1800.22 9.34 o 1 4 6 942.02 892.78 4.94 o 2 4 6 25.82 23.77 0.88 o 3 4 6 211.85 205.96 2.37 o 4 4 6 1097.99 1130.10 6.25 o 5 4 6 475.09 478.80 5.92 o 6 4 6 61.72 64.36 3.06 o 7 4 6 5.68 7.87 2.34 o 8 4 6 138.44 139.48 11.52 o 1 5 6 118.20 91.91 1.71 o 2 5 6 936.19 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270.80 4.34 o 3 10 6 158.87 150.50 3.55 o 4 10 6 242.12 252.51 5.39 o 5 10 6 284.29 282.06 6.51 o 6 10 6 13.79 18.16 3.34 o 1 11 6 900.49 909.25 8.48 o 2 11 6 386.07 395.24 5.83 o 3 11 6 370.73 384.63 6.92 o 4 11 6 5.03 7.52 1.82 o 5 11 6 0.87 -0.02 1.86 o 6 11 6 39.89 46.63 12.26 o 0 12 6 35.22 42.41 3.04 o 1 12 6 340.90 353.34 5.74 o 2 12 6 1.42 2.43 1.53 o 3 12 6 87.57 89.50 3.74 o 4 12 6 392.98 388.84 7.94 o 5 12 6 302.34 300.31 14.05 o 1 13 6 0.11 -0.65 1.64 o 2 13 6 152.76 156.61 4.83 o 3 13 6 22.26 18.75 2.24 o 4 13 6 86.52 86.06 5.50 o 0 14 6 112.36 133.95 6.46 o 1 14 6 55.64 56.04 2.86 o 2 14 6 25.80 31.25 2.57 o 3 14 6 7.72 8.67 2.80 o 4 14 6 99.35 94.68 15.56 o 1 15 6 187.88 173.86 7.49 o 2 15 6 698.60 698.82 20.05 o 0 16 6 187.07 209.75 31.05 o 1 1 7 2156.54 2180.64 7.35 o 2 1 7 2222.11 2181.03 7.10 o 3 1 7 0.12 2.85 0.60 o 4 1 7 240.97 222.57 2.95 o 5 1 7 71.60 85.22 2.15 o 6 1 7 57.10 45.74 2.40 o 7 1 7 805.47 808.10 10.98 o 8 1 7 64.06 46.31 5.63 o 0 2 7 927.46 934.20 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7.80 2.14 o 8 2 8 6.79 29.39 14.53 o 1 3 8 37.86 41.18 1.37 o 2 3 8 104.86 116.78 2.03 o 3 3 8 493.20 499.82 4.13 o 4 3 8 91.42 90.05 2.09 o 5 3 8 17.99 19.10 1.56 o 6 3 8 0.04 0.30 1.75 o 7 3 8 32.37 32.97 2.99 o 8 3 8 1.47 2.72 9.76 o 0 4 8 953.73 922.31 7.23 o 1 4 8 246.93 258.15 2.96 o 2 4 8 22.23 21.91 1.03 o 3 4 8 2.62 3.82 0.84 o 4 4 8 816.61 790.68 6.11 o 5 4 8 89.58 95.79 3.02 o 6 4 8 49.88 54.66 2.87 o 7 4 8 17.52 12.63 2.46 o 1 5 8 18.56 12.80 0.96 o 2 5 8 2856.43 2789.42 10.51 o 3 5 8 299.44 296.81 3.70 o 4 5 8 38.52 35.87 1.72 o 5 5 8 12.93 12.43 1.52 o 6 5 8 1134.74 1138.14 12.53 o 7 5 8 45.79 52.09 3.64 o 0 6 8 4063.39 3997.02 17.91 o 1 6 8 23.81 20.89 1.13 o 2 6 8 85.96 95.03 2.12 o 3 6 8 213.92 219.12 3.42 o 4 6 8 1431.01 1453.60 10.20 o 5 6 8 18.02 16.80 1.67 o 6 6 8 364.16 373.63 7.45 o 7 6 8 0.22 -3.17 3.17 o 1 7 8 24.83 23.07 1.35 o 2 7 8 841.62 881.90 6.67 o 3 7 8 333.34 351.44 4.38 o 4 7 8 17.40 13.29 1.51 o 5 7 8 46.14 54.37 2.67 o 6 7 8 46.14 43.46 2.89 o 7 7 8 77.23 74.78 9.65 o 0 8 8 63.36 61.47 2.76 o 1 8 8 198.55 184.65 3.31 o 2 8 8 105.05 109.67 2.60 o 3 8 8 27.55 27.70 1.51 o 4 8 8 6.26 6.83 1.48 o 5 8 8 74.36 70.14 3.09 o 6 8 8 121.79 124.00 4.55 o 1 9 8 443.07 423.19 5.24 o 2 9 8 194.29 180.20 3.46 o 3 9 8 1.07 4.17 1.26 o 4 9 8 69.28 79.37 3.10 o 5 9 8 21.74 20.02 2.01 o 6 9 8 170.99 162.06 7.56 o 0 10 8 1585.92 1538.94 14.31 o 1 10 8 54.02 46.07 1.93 o 2 10 8 242.39 237.84 4.36 o 3 10 8 154.31 148.01 3.74 o 4 10 8 565.77 566.15 8.63 o 5 10 8 0.36 0.50 1.82 o 6 10 8 31.27 19.79 14.74 o 1 11 8 38.01 29.94 1.81 o 2 11 8 1716.52 1729.41 12.63 o 3 11 8 55.56 53.40 2.86 o 4 11 8 201.27 208.87 5.68 o 5 11 8 5.79 6.71 3.07 o 0 12 8 471.68 483.86 9.24 o 1 12 8 129.87 119.67 3.49 o 2 12 8 37.50 38.43 2.23 o 3 12 8 1.16 2.05 1.76 o 4 12 8 627.91 631.23 11.22 o 5 12 8 7.91 9.98 4.95 o 1 13 8 8.85 8.54 1.64 o 2 13 8 14.21 14.32 1.88 o 3 13 8 1.72 3.39 2.15 o 4 13 8 8.24 2.41 4.04 o 0 14 8 16.56 16.86 2.70 o 1 14 8 5.19 5.17 1.62 o 2 14 8 93.28 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5 9 41.04 48.15 5.88 o 0 6 9 143.53 128.77 3.37 o 1 6 9 543.25 557.84 5.27 o 2 6 9 4.67 5.53 1.00 o 3 6 9 12.20 11.05 1.17 o 4 6 9 31.25 31.70 1.87 o 5 6 9 0.22 0.47 1.59 o 6 6 9 22.51 23.76 2.33 o 7 6 9 5.27 5.70 5.52 o 1 7 9 699.40 669.13 6.13 o 2 7 9 253.85 238.70 3.81 o 3 7 9 243.82 245.20 3.97 o 4 7 9 96.29 91.95 3.14 o 5 7 9 68.36 73.63 3.25 o 6 7 9 15.62 13.52 2.11 o 7 7 9 160.47 172.41 20.20 o 0 8 9 469.94 439.88 7.52 o 1 8 9 1246.36 1215.81 8.64 o 2 8 9 13.82 13.91 1.32 o 3 8 9 646.48 639.45 6.66 o 4 8 9 39.71 40.92 2.30 o 5 8 9 1082.95 1148.02 12.31 o 6 8 9 42.49 49.62 3.59 o 1 9 9 477.65 498.06 5.97 o 2 9 9 8.76 6.58 1.27 o 3 9 9 1247.94 1263.07 10.36 o 4 9 9 105.88 106.83 3.66 o 5 9 9 39.84 39.45 2.64 o 6 9 9 110.38 106.28 8.90 o 0 10 9 62.64 60.59 3.25 o 1 10 9 1.56 5.71 1.32 o 2 10 9 25.07 19.79 1.62 o 3 10 9 2.88 3.76 1.46 o 4 10 9 221.28 230.16 5.71 o 5 10 9 88.35 87.91 4.17 o 1 11 9 135.58 142.11 3.60 o 2 11 9 17.03 16.22 1.62 o 3 11 9 19.36 19.88 2.22 o 4 11 9 31.66 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6.36 o 1 4 12 548.36 561.66 6.07 o 2 4 12 20.46 20.77 1.51 o 3 4 12 190.47 192.40 3.86 o 4 4 12 54.31 50.72 2.37 o 5 4 12 372.14 366.71 7.08 o 6 4 12 57.91 52.68 3.52 o 1 5 12 1151.20 1117.57 8.62 o 2 5 12 28.56 26.56 1.61 o 3 5 12 156.94 148.82 3.50 o 4 5 12 6.43 8.60 1.54 o 5 5 12 215.84 217.15 5.96 o 6 5 12 1.31 2.07 2.38 o 0 6 12 0.78 3.24 1.71 o 1 6 12 795.88 798.73 7.85 o 2 6 12 172.88 172.98 3.83 o 3 6 12 409.83 414.88 5.96 o 4 6 12 9.48 8.11 1.82 o 5 6 12 745.54 775.41 11.07 o 6 6 12 7.55 4.73 4.11 o 1 7 12 379.91 376.96 5.69 o 2 7 12 62.25 56.69 2.42 o 3 7 12 469.15 478.10 6.45 o 4 7 12 204.52 212.55 5.41 o 5 7 12 0.26 3.36 2.01 o 6 7 12 48.93 35.18 5.24 o 0 8 12 175.95 155.86 5.45 o 1 8 12 2.19 2.80 1.43 o 2 8 12 19.06 15.39 1.72 o 3 8 12 0.09 0.49 1.46 o 4 8 12 53.78 56.63 3.05 o 5 8 12 47.90 40.70 3.63 o 1 9 12 321.31 317.21 5.73 o 2 9 12 205.22 201.63 4.60 o 3 9 12 70.72 74.47 3.11 o 4 9 12 0.29 -0.24 1.81 o 5 9 12 2.31 -2.49 5.41 o 0 10 12 0.28 0.60 2.32 o 1 10 12 432.28 439.02 7.13 o 2 10 12 94.32 82.96 3.15 o 3 10 12 142.55 138.29 4.58 o 4 10 12 50.57 43.23 4.48 o 1 11 12 182.41 182.18 5.01 o 2 11 12 1.94 3.84 1.65 o 3 11 12 1150.73 1198.72 18.43 o 4 11 12 0.24 3.90 7.43 o 0 12 12 126.52 119.43 6.26 o 1 12 12 353.47 363.74 7.22 o 2 12 12 15.30 11.36 2.49 o 3 12 12 109.01 98.40 12.89 o 1 13 12 20.75 19.97 3.64 o 2 13 12 11.84 13.55 11.54 o 1 1 13 84.64 92.06 2.67 o 2 1 13 290.34 294.23 4.57 o 3 1 13 8.36 6.86 1.41 o 4 1 13 182.20 191.62 4.08 o 5 1 13 137.92 135.28 3.96 o 6 1 13 47.02 38.76 3.36 o 0 2 13 1088.60 1062.92 12.31 o 1 2 13 1.03 0.84 1.27 o 2 2 13 1.83 0.11 1.23 o 3 2 13 129.04 119.88 3.20 o 4 2 13 647.47 660.26 7.63 o 5 2 13 69.93 70.57 2.88 o 6 2 13 243.86 236.88 6.66 o 1 3 13 70.30 68.40 2.50 o 2 3 13 1301.09 1300.37 10.15 o 3 3 13 68.38 70.04 2.45 o 4 3 13 258.11 250.41 4.74 o 5 3 13 2.53 1.43 1.70 o 6 3 13 861.23 896.18 14.44 o 0 4 13 436.10 438.95 9.14 o 1 4 13 93.58 97.04 2.99 o 2 4 13 758.80 761.59 7.95 o 3 4 13 51.99 48.90 2.12 o 4 4 13 546.55 559.68 7.42 o 5 4 13 2.30 2.90 1.83 o 6 4 13 109.00 106.54 6.12 o 1 5 13 4.91 3.23 1.44 o 2 5 13 12.45 9.74 1.45 o 3 5 13 23.27 20.54 1.54 o 4 5 13 46.01 46.17 2.49 o 5 5 13 14.76 16.67 2.29 o 6 5 13 18.54 16.45 3.76 o 0 6 13 489.89 521.27 9.06 o 1 6 13 61.82 64.45 2.64 o 2 6 13 58.17 65.69 2.67 o 3 6 13 7.77 8.47 1.44 o 4 6 13 48.75 42.92 2.59 o 5 6 13 23.90 25.65 2.48 o 6 6 13 2.21 -1.50 3.86 o 1 7 13 174.10 160.94 4.04 o 2 7 13 473.35 470.20 6.88 o 3 7 13 3.29 2.41 1.49 o 4 7 13 1.81 1.09 1.80 o 5 7 13 5.49 1.79 2.62 o 0 8 13 989.45 986.30 13.88 o 1 8 13 35.69 32.95 2.13 o 2 8 13 26.36 25.38 2.01 o 3 8 13 55.21 51.84 2.73 o 4 8 13 1050.12 1060.02 13.14 o 5 8 13 42.31 47.54 10.55 o 1 9 13 0.03 -1.54 1.54 o 2 9 13 922.34 935.92 10.49 o 3 9 13 21.58 18.05 1.97 o 4 9 13 269.45 286.34 9.15 o 5 9 13 77.62 51.07 18.89 o 0 10 13 48.70 52.24 4.47 o 1 10 13 21.00 17.00 1.88 o 2 10 13 6.83 7.97 1.68 o 3 10 13 15.87 8.95 1.95 o 4 10 13 0.20 -4.81 4.99 o 1 11 13 11.14 10.59 1.89 o 2 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14 251.43 238.92 23.33 o 1 1 15 259.37 267.05 5.07 o 2 1 15 269.73 261.05 4.89 o 3 1 15 723.55 713.55 8.74 o 4 1 15 42.42 40.42 2.43 o 5 1 15 74.15 81.06 3.72 o 6 1 15 0.94 -1.41 4.31 o 0 2 15 206.50 195.51 6.32 o 1 2 15 131.43 135.23 3.73 o 2 2 15 117.03 124.31 3.53 o 3 2 15 553.19 540.33 7.50 o 4 2 15 233.07 239.25 5.33 o 5 2 15 142.06 148.62 4.59 o 6 2 15 0.07 3.37 3.85 o 1 3 15 436.92 443.54 6.65 o 2 3 15 276.68 267.41 5.02 o 3 3 15 66.98 72.51 2.94 o 4 3 15 13.36 13.86 1.79 o 5 3 15 144.49 139.57 4.76 o 6 3 15 72.66 72.84 8.54 o 0 4 15 604.85 624.45 10.98 o 1 4 15 1227.35 1257.35 11.59 o 2 4 15 64.38 66.69 2.91 o 3 4 15 109.99 113.78 3.56 o 4 4 15 58.64 60.34 2.86 o 5 4 15 89.86 81.64 4.30 o 1 5 15 303.84 319.15 6.16 o 2 5 15 28.90 25.42 1.99 o 3 5 15 13.71 14.98 1.76 o 4 5 15 0.01 4.48 1.73 o 5 5 15 2.88 3.34 2.36 o 0 6 15 73.41 76.53 4.15 o 1 6 15 457.68 469.08 7.13 o 2 6 15 2.20 2.13 1.57 o 3 6 15 14.23 9.75 1.72 o 4 6 15 29.63 26.69 2.34 o 5 6 15 163.72 141.74 12.71 o 1 7 15 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